We derive the potential energy of gravity waves(GWs)in the upper troposphere and stratosphere at 45°S-45°N from December 2019 to November 2022 by using temperature profiles retrieved from the Constellation O...We derive the potential energy of gravity waves(GWs)in the upper troposphere and stratosphere at 45°S-45°N from December 2019 to November 2022 by using temperature profiles retrieved from the Constellation Observing System for Meteorology,Ionosphere,and Climate-2(COSMIC-2)satellite.Owing to the dense sampling of COSMIC-2,in addition to the strong peaks of gravity wave potential energy(GWPE)above the Andes and Tibetan Plateau,we found weak peaks above the Rocky,Atlas,Caucasus,and Tianshan Mountains.The land-sea contrast is responsible for the longitudinal variations of the GWPE in the lower and upper stratosphere.At 40°N/S,the peaks were mainly above the topographic regions during the winter.At 20°N/S,the peaks were a slight distance away from the topographic regions and might be the combined effect of nontopographic GWs and mountain waves.Near the Equator,the peaks were mainly above the regions with the lowest sea level altitude and may have resulted from convection.Our results indicate that even above the local regions with lower sea level altitudes compared with the Andes and Tibetan Plateau,the GWPE also exhibits fine structures in geographic distributions.We found that dissipation layers above the tropopause jet provide the body force to generate secondary waves in the upper stratosphere,especially during the winter months of each hemisphere and at latitudes of greater than 20°N/S.展开更多
The microphase separation extent of biomedical segmented polyetherurethanes were greatly enhanced due to the presence of sulfoalkyl pendant groups contained in the hard segments,and the hard segments were more orderly...The microphase separation extent of biomedical segmented polyetherurethanes were greatly enhanced due to the presence of sulfoalkyl pendant groups contained in the hard segments,and the hard segments were more orderly aggregated through ionic interaction.展开更多
Seventy-one occurrences of coronal mass ejections （CMEs） associated with radio bursts, seemingly associated with type III bursts/fine structures （FSs）, in the centimeter-metric frequency range during 2003-2005, we...Seventy-one occurrences of coronal mass ejections （CMEs） associated with radio bursts, seemingly associated with type III bursts/fine structures （FSs）, in the centimeter-metric frequency range during 2003-2005, were obtained with the spectrometers at the National Astronomical Observatories, Chinese Academy of Sciences （NAOC） and the Culgoora radio spectrometer and are presented. The statistical results of 68 out of 71 events associated with the radio type III bursts or FSs during the initiation or early stages of the CMEs indicate that most CMEs contain the emissions of radio type III bursts/FSs near the time of the CME＇s onset, in spite of their fast or slow speeds. Therefore, we propose that type III bursts and FSs are possible precursors of the onset of CMEs. We stress that the radio type III bursts/FSs in the centimetermetric wavelength region and the CME transients possibly occurred in conjunction with the origin of the coronal precursor structures. Thus, the statistical results support the suggestions that type III bursts/FSs are indicators of extra energy input into the corona at the CMEs＇ onset, and that the type III bursts/FSs are produced primarily due to a coronal instability which eventually triggers the CME process. This may signify that the centimeter-metric radio bursts corresponding to or near the CME＇s onset are caused by the disturbed corona （possibly including minor magnetic reconnections）.展开更多
The fine and hyperfine structures of pionic helium metastable states is calculated within the formalism of the Breit-Pauli Hamiltonian by using the variationally generated wave functions in Hylleraas coordinates.Our r...The fine and hyperfine structures of pionic helium metastable states is calculated within the formalism of the Breit-Pauli Hamiltonian by using the variationally generated wave functions in Hylleraas coordinates.Our results not only verify the existing values of Hori et al.[Phys.Rev.A 89,042515(2014)]for the fine structure of π^(4)He^(+),but also determine the hyperfine structure of π^(3)He^(+).展开更多
The characteristic of interface depending on the atomic structure exerts an inportant,and sometime controlling,influence on performance of the interacial materials. The present paper reviews the main studies on fine s...The characteristic of interface depending on the atomic structure exerts an inportant,and sometime controlling,influence on performance of the interacial materials. The present paper reviews the main studies on fine structure of both the materials inter- faces and interfacial reaction products in semiconductor uperlattice,metal multilayer ceram- ics and composite materials by mean of selected area electron doffraction patterns and high resolution electron microscopy. The following features of interfaces are reviewed:the orientation relationships;the char- acteristic of steps,facets and ronghness of interfaces;atomic bonding across the interface;the degree of coherency,the structure of misfit dislocations and elastic relaxations at the inter- faces:the presence of defects at the onterfaces:the structure of the interfacial reaction prod- ucts as well as the reaction kinetics and reaetion mechanism.展开更多
A cluster model is used to calculate electron energy-loss fine structures in crystal. The multiple-scattering self-consistent-field method is employed in the calculation. Our theoretical results of N near K-edge energ...A cluster model is used to calculate electron energy-loss fine structures in crystal. The multiple-scattering self-consistent-field method is employed in the calculation. Our theoretical results of N near K-edge energy loss fine structures in hexagonal GaN crystal are in good agreement with the experimental spectra. Future possible experiments in energy-filtered transmission electron microscopy (EFTEM) are discussed and proposed because our theoretical work can provide clear assignments for transmitted electrons with different energy losses.展开更多
Denote by SFin（v） the set of all integer pairs （t, s） for which there exist three symmetric Latin squares of order v on the same set having fine structure （t, s）. We completely determine the set SFin（2n） for a...Denote by SFin（v） the set of all integer pairs （t, s） for which there exist three symmetric Latin squares of order v on the same set having fine structure （t, s）. We completely determine the set SFin（2n） for any integer n ≥ 5.展开更多
Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate...Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate that iron (Fe) and silicon (Si) are the primary mineral elements of the envelopes. Composition of mineral elements was uncorrelated with envelope color, however, it was highly correlated with the microarchitecture of the envelopes. Content of Si was higher than that of Fe in all species of Strombomonas and some species of Trachelomonas with rough surface. In most species of Trachelomonas, especially those with dense and smoothy surface, content of Fe was higher than that of Si. Based on the above results, we propose to assign those species of Strombomonas into Trachelomonas and consider them as a group of the latter. These species were the most primitive among the group with envelopes in Euglenaceae.展开更多
Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ...Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ramp,often occurs severe SWBLIs with a large separation bubble.In this paper,experimental investigations on vortical structures and density fluctuations characteristics of supersonic FFS controlled by self-sustaining dual synthetic jets(SDSJ)are carried out in a Mach number 2.95 wind tunnel.High spatial–temporal resolution flowfield images of FFS without/with active flow control are captured by adopting nano-particle-based planar laser scattering technique.The control effects of the distance between the actuator and the step are mainly compared.The paper finds that the SDSJ can effectively change the feature of flowfield,eliminate the separation shock and the reattachment shock,compel the original shock induced by the step leading edge to distort and reduce its intensity finally.Density fluctuations analysis demonstrates that the whole flows seem to move upstream with the increase of distance(dS-J).Discrete Fourier transformation spectrums results reveal that the fluctuations are mainly located in the low-frequency region at first.High-frequency components and frequency bandwidth increase slightly after the SDSJ are applied.展开更多
An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to captur...An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to capture the shock wave.The numerical results show that with the compression of the wedge wall the detonation wave front structure is divided into three sections：the ZND model-like strcuture,single-sided triple point structure and dual-headed triple point strucuture.The first structure is the smooth straight,and the second has the characteristic of the triple points propagating dowanstream only with the same velocity,while the dual-headed triple point structure is very complicated.The detonation waves facing upstream and downstream propagate with different velocities,in which the periodic collisions of the triple points cause the oscillation of the detonation wave front.This oscillation process has temporal and spatial periodicity.In addition,the triple point trace are recorded to obtain different cell structures in three sections.展开更多
An 1100 MPa grade ultra-high strength steel with different martensite fine structures, characterized by prior austenite grain size, martensite packet size, block width and lath width, was studied by various heat treat...An 1100 MPa grade ultra-high strength steel with different martensite fine structures, characterized by prior austenite grain size, martensite packet size, block width and lath width, was studied by various heat treatment processes. The result shows that with decreasing prior austenite grain size, both the packet size and block width decrease, while the lath width has virtually no change. Accordingly, both strength and toughness increase, while total elongation decreases. The yield strength has a Hall Petch type relationship with the prior austenite grain size, packet size and block width, and the block width may be regarded as a key factor influencing strength. On the other hand, the ductile to brittle transition temperature （DBTT） is found to be more related lo the packet size, which may be considered as a dominant factor influencing toughness.展开更多
The oxidation of antimony （Ⅲ） in soils was studied using X-ray absorption fine structure （XAFS） spectra. An andosol soft sample and artificial soil samples （SiO2 blended with iron （Ⅲ） hydroxide and manganese...The oxidation of antimony （Ⅲ） in soils was studied using X-ray absorption fine structure （XAFS） spectra. An andosol soft sample and artificial soil samples （SiO2 blended with iron （Ⅲ） hydroxide and manganese （Ⅳ） oxide） were used herein. After adding antimony （Ⅲ） oxide to all soil samples, the oxidation process was observed by recording the XAFS spectra of Sb K-edge, Fe Kedge, and Mn K-edge. The results indicated that manganese （Ⅳ） oxide played an important role in the oxidation of Sb（Ⅲ）; however iron （Ⅲ） hydroxide was not directly related to the reaction. During a 2-hr continuous Sb K-edge X-ray absorption near edge structure （XANES） measurement with an interval of I rain of one of the artificial soil samples （SiO2 ＋ MnO2 ＋ Sb2O3）, a pseudo-first-order reaction was determined with an average estimated rate of 0.52 ±0.04 hr-1. Compared to the lower oxidation rate of andosol, it is suggested that because of the low concentration of Mn（Ⅳ） in natural soils, the oxidation process of Sb（Ⅲ） might be relatively slow and require more time to convert Sb（Ⅲ） to Sb（V）.展开更多
Relationship between atomic local structures and Curie temperature of NdFeB permanent magnets was investigated semi-quantitatively using synchrotron radiation technique. Fe K-edge X-ray absorption spectroscopy(XAS) wa...Relationship between atomic local structures and Curie temperature of NdFeB permanent magnets was investigated semi-quantitatively using synchrotron radiation technique. Fe K-edge X-ray absorption spectroscopy(XAS) was employed to study the local structure of Fe atoms for samples before and after doping Dy, Tb or Gd. It is found that the bond lengths and coordination numbers are changed. Thus, the exchange interaction between Fe atoms increases with Dy, Tb or Gd doping, resulting in the improvement of Curie temperature of NdFeB permanent magnets. The doping effect is proven by experimental measurement of the magnetic properties. Microstructural characterization using scanning electron microscopy(SEM) was also used to further analyze the effect of different rare earth elements doping on Curie temperature of NdFeB permanent magnets.展开更多
The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformati...The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformation characteristics in a wide range of cooling rates,with the bainite sheaves consisting of bainite ferrite plates without carbide precipitation and retained austenite in the fast cooling regime.At relatively high cooling rates,which corresponded to low heat inputs,the hardness of the simulated HAZ was above that of the base metal.When the cooling rate was below 9C/s,the welding HAZ would have an obvious softening.The analysis of transformation rates in continuous cooling processes was completed by numerical differential method.The result indicated that the microstructure transformation rate of the HAZ in 800MPa grade ultra fine structured steel changed sharply to slow speeds when the cooling time t8/5 is longer than 7s.展开更多
The fine structure constant α can be extracted from high-precision spectroscopy of the 2^3 P J fine structure splittings in helium and light helium-like ions. In this work, the 2^3 P J fine structure splittings of he...The fine structure constant α can be extracted from high-precision spectroscopy of the 2^3 P J fine structure splittings in helium and light helium-like ions. In this work, the 2^3 P J fine structure splittings of helium and Li^＋ ion are calculated,including relativistic and QED corrections of order mα^4, mα^4（m/M）, mα^5, mα^5（m/M）, and Douglas–Kroll operators of mα^6 and mα^6（m/M）, which provide an independent verification for the previous calculations performed by Drake [Can.J. Phys. 80 1195（2002）] and by Pachucki and Yerokhin [Phys. Rev. A 79 062516（2009）; Phys. Rev. Lett. 104 070403（2010）; Can. J. Phys. 89 1139（2011）]. The results of the three groups agree with each other.展开更多
The layout and characteristics of the hard X-ray spectroscopy beamline(BL11B)at the Shanghai synchrotron radiation facility are described herein.BL11B is a bending-magnet beamline dedicated to conventional and millise...The layout and characteristics of the hard X-ray spectroscopy beamline(BL11B)at the Shanghai synchrotron radiation facility are described herein.BL11B is a bending-magnet beamline dedicated to conventional and millisecond-scale quick-scanning X-ray absorption fine structures.It is equipped with a cylindrical collimating mirror,a double-crystal monochromator comprising Si(111)and Si(311),a channel-cut quick-scanning Si(111)monochromator,a toroidal focusing mirror,and a high harmonics rejection mirror.It can provide 5-30 keV of X-rays with a photon flux of~5×10^(11)photons/s and an energy resolution of~1.31×10^(-4)at 10 keV.The performance of the beamline can satisfy the demands of users in the fields of catalysis,materials,and environmental science.This paper presents an overview of the beamline design and a detailed description of its performance and capabilities.展开更多
Co@Au core shell nanoparticles(NPs) of different shell thicknesses were fabricated by a combination of the displacement process and the reduction-deposition process in a microfluidic reactor. The effect of the shell t...Co@Au core shell nanoparticles(NPs) of different shell thicknesses were fabricated by a combination of the displacement process and the reduction-deposition process in a microfluidic reactor. The effect of the shell thickness on the fine structures(local atom arrangement) of core materials was investigated by X-ray Absorption Near Edge Structure(XANES) and Extended X-ray Absorption Fine Structure(EXAFS).The results indicate that the shell thickness affects the fine structure of the core materials by causing atomic re-arrangement between the hexagonal close pack(hcp) and the face centered cubic(fcc) structure, and forming Co-Au bonds in the core-shell interface.展开更多
The nature and the origin of the fine structure are described. Based on the vortex model and hydrodynamics, a comprehensible interpretation of the fine structure constant is developed. The vacuum considered to have su...The nature and the origin of the fine structure are described. Based on the vortex model and hydrodynamics, a comprehensible interpretation of the fine structure constant is developed. The vacuum considered to have superfluid characteristics and elementary particles such as the electron and Hydrogen molecule are irrotational vortices of this superfluid. In such a vortex, the angular rotation ω is maintained, and the larger the radius, the slower the rotational speed. The fine structure value is derived from the ratio of the rotational speed of the boundaries of the vortex to the speed of the vortex eye in its center. Since the angular rotation is constant, the same value was derived from the ratio between the radius of the constant vortex core and the radius of the hall vortex. Therefore, the constancy of alpha is an expression of the constancy relation in the vortex structure.展开更多
基金the National Natural Science Foundation of China(Grant Nos.41831073,42174196,and 42374205)the Project of Stable Support for Youth Team in Basic Research Field,Chinese Academy of Sciences(CAS+4 种基金Grant No.YSBR-018)the Informatization Plan of CAS(Grant No.CAS-WX2021PY-0101)the Youth Cross Team Scientific Research project of the Chinese Academy of Sciences(Grant No.JCTD-2021-10)the Open Research Project of Large Research Infrastructures of CAS titled“Study on the Interaction Between Low-/Mid-Latitude Atmosphere and Ionosphere Based on the Chinese Meridian Project.”This work was also supported in part by the Specialized Research Fund and the Open Research Program of the State Key Laboratory of Space Weather.
文摘We derive the potential energy of gravity waves(GWs)in the upper troposphere and stratosphere at 45°S-45°N from December 2019 to November 2022 by using temperature profiles retrieved from the Constellation Observing System for Meteorology,Ionosphere,and Climate-2(COSMIC-2)satellite.Owing to the dense sampling of COSMIC-2,in addition to the strong peaks of gravity wave potential energy(GWPE)above the Andes and Tibetan Plateau,we found weak peaks above the Rocky,Atlas,Caucasus,and Tianshan Mountains.The land-sea contrast is responsible for the longitudinal variations of the GWPE in the lower and upper stratosphere.At 40°N/S,the peaks were mainly above the topographic regions during the winter.At 20°N/S,the peaks were a slight distance away from the topographic regions and might be the combined effect of nontopographic GWs and mountain waves.Near the Equator,the peaks were mainly above the regions with the lowest sea level altitude and may have resulted from convection.Our results indicate that even above the local regions with lower sea level altitudes compared with the Andes and Tibetan Plateau,the GWPE also exhibits fine structures in geographic distributions.We found that dissipation layers above the tropopause jet provide the body force to generate secondary waves in the upper stratosphere,especially during the winter months of each hemisphere and at latitudes of greater than 20°N/S.
文摘The microphase separation extent of biomedical segmented polyetherurethanes were greatly enhanced due to the presence of sulfoalkyl pendant groups contained in the hard segments,and the hard segments were more orderly aggregated through ionic interaction.
基金Supported by the National Natural Science Foundation of Chinasupported by the National Basic Research Program of the MOST (Grant No.2011CB811403)the CAS-NSFC Key Project (Grant No. 10978006)
文摘Seventy-one occurrences of coronal mass ejections （CMEs） associated with radio bursts, seemingly associated with type III bursts/fine structures （FSs）, in the centimeter-metric frequency range during 2003-2005, were obtained with the spectrometers at the National Astronomical Observatories, Chinese Academy of Sciences （NAOC） and the Culgoora radio spectrometer and are presented. The statistical results of 68 out of 71 events associated with the radio type III bursts or FSs during the initiation or early stages of the CMEs indicate that most CMEs contain the emissions of radio type III bursts/FSs near the time of the CME＇s onset, in spite of their fast or slow speeds. Therefore, we propose that type III bursts and FSs are possible precursors of the onset of CMEs. We stress that the radio type III bursts/FSs in the centimetermetric wavelength region and the CME transients possibly occurred in conjunction with the origin of the coronal precursor structures. Thus, the statistical results support the suggestions that type III bursts/FSs are indicators of extra energy input into the corona at the CMEs＇ onset, and that the type III bursts/FSs are produced primarily due to a coronal instability which eventually triggers the CME process. This may signify that the centimeter-metric radio bursts corresponding to or near the CME＇s onset are caused by the disturbed corona （possibly including minor magnetic reconnections）.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11974382 and 11474316)the support from NSERC and SHARCnet of Canada
文摘The fine and hyperfine structures of pionic helium metastable states is calculated within the formalism of the Breit-Pauli Hamiltonian by using the variationally generated wave functions in Hylleraas coordinates.Our results not only verify the existing values of Hori et al.[Phys.Rev.A 89,042515(2014)]for the fine structure of π^(4)He^(+),but also determine the hyperfine structure of π^(3)He^(+).
文摘The characteristic of interface depending on the atomic structure exerts an inportant,and sometime controlling,influence on performance of the interacial materials. The present paper reviews the main studies on fine structure of both the materials inter- faces and interfacial reaction products in semiconductor uperlattice,metal multilayer ceram- ics and composite materials by mean of selected area electron doffraction patterns and high resolution electron microscopy. The following features of interfaces are reviewed:the orientation relationships;the char- acteristic of steps,facets and ronghness of interfaces;atomic bonding across the interface;the degree of coherency,the structure of misfit dislocations and elastic relaxations at the inter- faces:the presence of defects at the onterfaces:the structure of the interfacial reaction prod- ucts as well as the reaction kinetics and reaetion mechanism.
基金the National Natural Science Foundation of China ( Grant Nos.19874035, 59831020, 19734030), National 973 Project, National 863 Program, Climbing Project, The Ministry of Science and Technology of China, National High-Tec ICF Committee, the Ministry of
文摘A cluster model is used to calculate electron energy-loss fine structures in crystal. The multiple-scattering self-consistent-field method is employed in the calculation. Our theoretical results of N near K-edge energy loss fine structures in hexagonal GaN crystal are in good agreement with the experimental spectra. Future possible experiments in energy-filtered transmission electron microscopy (EFTEM) are discussed and proposed because our theoretical work can provide clear assignments for transmitted electrons with different energy losses.
基金Supported by National Natural Science Foundation of China （Grant No. 10771013）
文摘Denote by SFin（v） the set of all integer pairs （t, s） for which there exist three symmetric Latin squares of order v on the same set having fine structure （t, s）. We completely determine the set SFin（2n） for any integer n ≥ 5.
文摘Fine structure and elemental composition of envelopes of 10 taxa of Trachelomonas and Strombomonas from natural freshwater bodies in China were studied and phylogeny of both genera were discussed. The results indicate that iron (Fe) and silicon (Si) are the primary mineral elements of the envelopes. Composition of mineral elements was uncorrelated with envelope color, however, it was highly correlated with the microarchitecture of the envelopes. Content of Si was higher than that of Fe in all species of Strombomonas and some species of Trachelomonas with rough surface. In most species of Trachelomonas, especially those with dense and smoothy surface, content of Fe was higher than that of Si. Based on the above results, we propose to assign those species of Strombomonas into Trachelomonas and consider them as a group of the latter. These species were the most primitive among the group with envelopes in Euglenaceae.
基金The present research was supported by the National Natural Science Foundation of China(Grants 11972369,51809271,11872374 and 11602299).
文摘Shock wave/boundary layer interaction(SWBLI)is still one of the unresolved bottlenecks that restrict the development of more advanced flight vehicles.Supersonic forward-facing step(FFS),an extreme case of compression ramp,often occurs severe SWBLIs with a large separation bubble.In this paper,experimental investigations on vortical structures and density fluctuations characteristics of supersonic FFS controlled by self-sustaining dual synthetic jets(SDSJ)are carried out in a Mach number 2.95 wind tunnel.High spatial–temporal resolution flowfield images of FFS without/with active flow control are captured by adopting nano-particle-based planar laser scattering technique.The control effects of the distance between the actuator and the step are mainly compared.The paper finds that the SDSJ can effectively change the feature of flowfield,eliminate the separation shock and the reattachment shock,compel the original shock induced by the step leading edge to distort and reduce its intensity finally.Density fluctuations analysis demonstrates that the whole flows seem to move upstream with the increase of distance(dS-J).Discrete Fourier transformation spectrums results reveal that the fluctuations are mainly located in the low-frequency region at first.High-frequency components and frequency bandwidth increase slightly after the SDSJ are applied.
基金supported by the National Natural Science Foundation of China (10872096)the Open Fund of State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology (KFJJ09-13)
文摘An oblique detonation wave for a Mach 7 inlet flow over a long enough wedge of 30 turning angle is simulated numerically using Euler equation and one-step rection model.The fifth-order WENO scheme is adopted to capture the shock wave.The numerical results show that with the compression of the wedge wall the detonation wave front structure is divided into three sections：the ZND model-like strcuture,single-sided triple point structure and dual-headed triple point strucuture.The first structure is the smooth straight,and the second has the characteristic of the triple points propagating dowanstream only with the same velocity,while the dual-headed triple point structure is very complicated.The detonation waves facing upstream and downstream propagate with different velocities,in which the periodic collisions of the triple points cause the oscillation of the detonation wave front.This oscillation process has temporal and spatial periodicity.In addition,the triple point trace are recorded to obtain different cell structures in three sections.
文摘An 1100 MPa grade ultra-high strength steel with different martensite fine structures, characterized by prior austenite grain size, martensite packet size, block width and lath width, was studied by various heat treatment processes. The result shows that with decreasing prior austenite grain size, both the packet size and block width decrease, while the lath width has virtually no change. Accordingly, both strength and toughness increase, while total elongation decreases. The yield strength has a Hall Petch type relationship with the prior austenite grain size, packet size and block width, and the block width may be regarded as a key factor influencing strength. On the other hand, the ductile to brittle transition temperature （DBTT） is found to be more related lo the packet size, which may be considered as a dominant factor influencing toughness.
基金XAFS measurements were carried out at Photon Factory,Tsukuba,Japan(Nos.2014G066,2016G086).
文摘The oxidation of antimony （Ⅲ） in soils was studied using X-ray absorption fine structure （XAFS） spectra. An andosol soft sample and artificial soil samples （SiO2 blended with iron （Ⅲ） hydroxide and manganese （Ⅳ） oxide） were used herein. After adding antimony （Ⅲ） oxide to all soil samples, the oxidation process was observed by recording the XAFS spectra of Sb K-edge, Fe Kedge, and Mn K-edge. The results indicated that manganese （Ⅳ） oxide played an important role in the oxidation of Sb（Ⅲ）; however iron （Ⅲ） hydroxide was not directly related to the reaction. During a 2-hr continuous Sb K-edge X-ray absorption near edge structure （XANES） measurement with an interval of I rain of one of the artificial soil samples （SiO2 ＋ MnO2 ＋ Sb2O3）, a pseudo-first-order reaction was determined with an average estimated rate of 0.52 ±0.04 hr-1. Compared to the lower oxidation rate of andosol, it is suggested that because of the low concentration of Mn（Ⅳ） in natural soils, the oxidation process of Sb（Ⅲ） might be relatively slow and require more time to convert Sb（Ⅲ） to Sb（V）.
基金financially supported by State High-Tech Development Plan (No. 2011AA061901)the TechnologyLanding Project of Jiangxi Province (No.KJLD13041)+1 种基金the Science and Technology Plan of Ganzhou (No.[2014]131)the Research Support Plan of Jiangxi University of Science and Technology(No. jxxjbs15001)
文摘Relationship between atomic local structures and Curie temperature of NdFeB permanent magnets was investigated semi-quantitatively using synchrotron radiation technique. Fe K-edge X-ray absorption spectroscopy(XAS) was employed to study the local structure of Fe atoms for samples before and after doping Dy, Tb or Gd. It is found that the bond lengths and coordination numbers are changed. Thus, the exchange interaction between Fe atoms increases with Dy, Tb or Gd doping, resulting in the improvement of Curie temperature of NdFeB permanent magnets. The doping effect is proven by experimental measurement of the magnetic properties. Microstructural characterization using scanning electron microscopy(SEM) was also used to further analyze the effect of different rare earth elements doping on Curie temperature of NdFeB permanent magnets.
文摘The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformation characteristics in a wide range of cooling rates,with the bainite sheaves consisting of bainite ferrite plates without carbide precipitation and retained austenite in the fast cooling regime.At relatively high cooling rates,which corresponded to low heat inputs,the hardness of the simulated HAZ was above that of the base metal.When the cooling rate was below 9C/s,the welding HAZ would have an obvious softening.The analysis of transformation rates in continuous cooling processes was completed by numerical differential method.The result indicated that the microstructure transformation rate of the HAZ in 800MPa grade ultra fine structured steel changed sharply to slow speeds when the cooling time t8/5 is longer than 7s.
基金supported by the National Basic Research Program of China(Grant No.2010CB832803)
文摘The fine structure constant α can be extracted from high-precision spectroscopy of the 2^3 P J fine structure splittings in helium and light helium-like ions. In this work, the 2^3 P J fine structure splittings of helium and Li^＋ ion are calculated,including relativistic and QED corrections of order mα^4, mα^4（m/M）, mα^5, mα^5（m/M）, and Douglas–Kroll operators of mα^6 and mα^6（m/M）, which provide an independent verification for the previous calculations performed by Drake [Can.J. Phys. 80 1195（2002）] and by Pachucki and Yerokhin [Phys. Rev. A 79 062516（2009）; Phys. Rev. Lett. 104 070403（2010）; Can. J. Phys. 89 1139（2011）]. The results of the three groups agree with each other.
文摘The layout and characteristics of the hard X-ray spectroscopy beamline(BL11B)at the Shanghai synchrotron radiation facility are described herein.BL11B is a bending-magnet beamline dedicated to conventional and millisecond-scale quick-scanning X-ray absorption fine structures.It is equipped with a cylindrical collimating mirror,a double-crystal monochromator comprising Si(111)and Si(311),a channel-cut quick-scanning Si(111)monochromator,a toroidal focusing mirror,and a high harmonics rejection mirror.It can provide 5-30 keV of X-rays with a photon flux of~5×10^(11)photons/s and an energy resolution of~1.31×10^(-4)at 10 keV.The performance of the beamline can satisfy the demands of users in the fields of catalysis,materials,and environmental science.This paper presents an overview of the beamline design and a detailed description of its performance and capabilities.
基金support from National Science Foundation of China(NSFC,Grant No.50971010)the Fundamental Research Funds for the Central Universities(YWF-11-03-Q-002)
文摘Co@Au core shell nanoparticles(NPs) of different shell thicknesses were fabricated by a combination of the displacement process and the reduction-deposition process in a microfluidic reactor. The effect of the shell thickness on the fine structures(local atom arrangement) of core materials was investigated by X-ray Absorption Near Edge Structure(XANES) and Extended X-ray Absorption Fine Structure(EXAFS).The results indicate that the shell thickness affects the fine structure of the core materials by causing atomic re-arrangement between the hexagonal close pack(hcp) and the face centered cubic(fcc) structure, and forming Co-Au bonds in the core-shell interface.
文摘The nature and the origin of the fine structure are described. Based on the vortex model and hydrodynamics, a comprehensible interpretation of the fine structure constant is developed. The vacuum considered to have superfluid characteristics and elementary particles such as the electron and Hydrogen molecule are irrotational vortices of this superfluid. In such a vortex, the angular rotation ω is maintained, and the larger the radius, the slower the rotational speed. The fine structure value is derived from the ratio of the rotational speed of the boundaries of the vortex to the speed of the vortex eye in its center. Since the angular rotation is constant, the same value was derived from the ratio between the radius of the constant vortex core and the radius of the hall vortex. Therefore, the constancy of alpha is an expression of the constancy relation in the vortex structure.
