Through the analysis of representative samples of field galaxies,both local(z~0.027)and distant(z~0.7),we explore the barred galaxy fraction and its dependence on stellar mass,color,and morphology,aiming to understand...Through the analysis of representative samples of field galaxies,both local(z~0.027)and distant(z~0.7),we explore the barred galaxy fraction and its dependence on stellar mass,color,and morphology,aiming to understand the evolution of these structural components through cosmic time.To this end,two complementary bar detection techniques were employed:elliptical isophote fitting and two-dimensional Fourier analysis,both applied to deep optical images.The observational samples were drawn from previously established and calibrated catalogs to ensure a homogeneous selection in stellar mass,enabling a robust comparison between local galaxies(z~0.027)and those in the distant Universe(z~0.7).This study systematically applies both isophotal fitting and Fourier decomposition across a wide redshift range,offering a comprehensive view of the evolution of bar incidence as a function of stellar mass and morphology.The results indicate that the fraction of barred galaxies is significantly higher in the local Universe than at earlier epochs,particularly among spiral galaxies.Furthermore,a clear correlation is observed between the presence of bars and stellar mass,especially in the high-mass regime(log(M_*/M☉)>10.5).In distant galaxies,this fraction is lower across all mass ranges,which may be related to more active dynamical processes.Overall,the findings reinforce the idea that stellar bars emerge as a consequence of dynamical cooling and the progressive stabilization of galactic disks,playing a key role in gas transport and the internal structural evolution of galaxies from z~1 to the present day.展开更多
Based on a sample of 72 Blue Compact Galaxies （BCGs） observed with the 2.16 m telescope of the National Astronomical Observatories, Chinese Academy of Sciences （NAOC） and about 4000 strong emission line galaxies f...Based on a sample of 72 Blue Compact Galaxies （BCGs） observed with the 2.16 m telescope of the National Astronomical Observatories, Chinese Academy of Sciences （NAOC） and about 4000 strong emission line galaxies from the Sloan Digital Sky Survey, we analyzed their chemical evolution history using the revised chemical evolution model of Larsen et al. Our sample covers a much larger metallicity range （7.2 〈 12 ＋ log（O/H） 〈 9.0）. We found that, in order to reproduce the observed abundance pattern and gas fraction over the whole metallicity range, a relatively continuous star formation history is needed for high metallicity galaxies, while assuming a series of instantaneous bursts with long quiescent periods （some Gyrs） for low metallicity galaxies. Model calculations also show that only the closed-box model is capable of reproducing the observational data over the whole metallicity range. Models that consider the ordinary winds and/or inflow can only fit the observations in the low metallicity range, and a model with enriched wind cannot fit the data in the whole metallicity range. This implies that the current adopted simple wind and inflow models are not applicable to massive galaxies, where the underlying physics of galactic winds or inflow could be more complicated.展开更多
In the past,people did not realize the formation and structure of galaxies.They even mistook the black holes hidden in the center of a galaxy as independent celestial objects,making black holes mysterious and unbeliev...In the past,people did not realize the formation and structure of galaxies.They even mistook the black holes hidden in the center of a galaxy as independent celestial objects,making black holes mysterious and unbelievable.It was only after the author studied and discovered the laws of the formation and evolution of satellites,planets and stars that he put forward the scientific theory of galaxy formation and evolution,therefore revealing the hierarchical structure of galaxy and the existence and characteristics of black holes as the main nodes of galactic structure.展开更多
The coevolution between supermassive black holes(SMBHs) and their host galaxies has been proposed for more than a decade,albeit with little direct evidence about black hole accretion activities regulating galaxy star ...The coevolution between supermassive black holes(SMBHs) and their host galaxies has been proposed for more than a decade,albeit with little direct evidence about black hole accretion activities regulating galaxy star formation at z> 1.In this paper,we study the lifetimes of X-ray active galactic nuclei(AGNs) in UV-selected red sequence(RS),blue cloud(BC) and green valley(GV) galaxies,finding that AGN accretion activities are most prominent in GV galaxies at z ~1.5-2,compared with RS and BC galaxies.We also compare AGN accretion timescales with typical color transition timescales of UV-selected galaxies.We find that the lifetime of GV galaxies at z~1.5-2 is very close to the typical timescale when the AGNs residing in them stay in the high-accretion-rate mode at these redshifts;for BC galaxies,the consistency between the color transition timescale and the black hole strong accretion lifetime is more likely to happen at lower redshifts(z <1).Our results support the scenario where AGN accretion activities govern UV color transitions of host galaxies,making galaxies and their central SMBHs coevolve with each other.展开更多
The discovery of massive galaxies at high redshifts,especially the passive ones,poses a big challenge for the current standard galaxy formation models.Here we use the semi-analytic galaxy formation model developed by ...The discovery of massive galaxies at high redshifts,especially the passive ones,poses a big challenge for the current standard galaxy formation models.Here we use the semi-analytic galaxy formation model developed by Henriques et al.to explore the formation and evolution of massive galaxies(MGs,stellar-mass M*>1011 M⊙).Different from previous works,we focus on the ones just formed(e.g.just reach?1011 M⊙).We find that most of the MGs are formed around z=0.6,with the earliest formation at z>4.Interestingly,although most of the MGs in the local Universe are passive,we find that only 13%of the MGs are quenched at the formation time.Most of the quenched MGs at formation already host a very massive supermassive black hole(SMBH)which could power the very effective AGN feedback.For the star-forming MGs,the ones with more massive SMBH prefer to quench in shorter timescales;in particular,those with MSMBH>107.5 M⊙have a quenching timescale of~0.5 Gyr and the characteristic MSMBH depends on the chosen stellar mass threshold in the definition of MGs as a result of their co-evolution.We also find that the"in-situ"star formation dominates the stellar mass growth of MGs until they are formed.Over the whole redshift range,we find the quiescent MGs prefer to stay in more massive dark matter halos,and have more massive SMBH and less cold gas masses.Our results provide a new angle on the whole life of the growth of MGs in the Universe.展开更多
Using a sample of 13 early-type spiral galaxies hosting nuclear rings,we report remarkable correlations between the properties of the nuclear rings and the central intensity ratio(CIR) of their host galaxies.The CIR,a...Using a sample of 13 early-type spiral galaxies hosting nuclear rings,we report remarkable correlations between the properties of the nuclear rings and the central intensity ratio(CIR) of their host galaxies.The CIR,a function of intensity of light within the central 1.5 and 3 arcsec region,is found to be a vital parameter in galaxy evolution,as it shares strong correlations with many structural and dynamical properties of early-type galaxies,including mass of the central supermassive black hole(SMBH).We use archival HST images for aperture photometry at the centre of the galaxy image to compute the CIR.We observe that the relative sizes of nuclear rings and ring cluster surface densities strongly correlate with the CIR.These correlations suggest reduced star formation in the centres of galaxies hosting small and dense nuclear rings.This scenario appears to be a consequence of strong bars as advocated by the significant connection observed between the CIR and bar strengths.In addition,we observe that the CIR is closely related with the integrated properties of the stellar population in the nuclear rings,associating the rings hosting older and less massive star clusters with low values of CIR.Thus,the CIR can serve as a crucial parameter in unfolding the coupled evolution of bars and rings as it is intimately connected with both their properties.展开更多
We present galactic spectroscopic data from a pencil beam of 10.75×7.5 centered on the X-ray cluster RXJ0054.0–2823 at z=0.29.We study the spectral evolution of galaxies from z=1 down to the cluster redshift in ...We present galactic spectroscopic data from a pencil beam of 10.75×7.5 centered on the X-ray cluster RXJ0054.0–2823 at z=0.29.We study the spectral evolution of galaxies from z=1 down to the cluster redshift in a magnitude-limited sample at R≤23,for which the statistical properties of the sample are well understood.We divide emission-line galaxies into star-forming galaxies,Low Ionization Nuclear Emission line Regions（LINERs） ,and Seyferts by using emission-line ratios of[OII],Hβ,and[OIII],and derive stellar fractions from population synthesis models. We focus our analysis on absorption and low-ionization galaxies.For absorption-line galaxies,we recover the well-known result that these galaxies have had no detectable evolution since z～0.6-0.7,but we also find that in the range z=0.65-1,at least 50% of the stars in bright absorption systems are younger than 2.5 Gyr.Faint absorption-line galaxies in the cluster at z=0.29 also had significant star formation during the previous 2-3 Gyr,but their brighter counterparts seem to be only composed of old stars.At z～0.8,our dynamically young cluster had a truncated red-sequence.This result seems to be consistent with a scenario where the final assembly of E/S0 took place at z1.In the volume-limited range 0.35≤z≤0.65,we find that 23% of the early-type galaxies have LINER-like spectra with Hβin absorption and have a significant component of A stars.The vast majority of LINERs in our sample have significant populations of young and intermediate-aged stars and are thus not related to AGNs,but to the population of‘retired galaxies’recently identified by Cid Fernandes et al.in the Sloan Digital Sky Survey（SDSS） .Early-type LINERs with various fractions of A stars and E＋A galaxies appear to play an important role in the formation of the red sequence.展开更多
Galaxy formation and evolution is one of the most active research areas in astrophysics,so many people have studied this area.But since they didn’t understand thoroughly the evolution law from satellite to planet the...Galaxy formation and evolution is one of the most active research areas in astrophysics,so many people have studied this area.But since they didn’t understand thoroughly the evolution law from satellite to planet then to star,their theories are very weak.In their theories,they proposed that large gas clouds collapsing to form a galaxy or more recently that matter started out in smaller clumps merged to form galaxy,which is incredible.Hence,the author of this paper,through studying the formation and orbit-variation of satellites,planets and stars,has put forward a new theory of galaxy formation and evolution,therefore revealing the hierarchical structure of galaxies and the formation and evolution of black holes and quasars.展开更多
This study will see the resurgence of interest in precise velocity dispersion measurements, both for the study of galactic and active nuclei kinematics. As several works suggest, an excellent tactic to measure σ is t...This study will see the resurgence of interest in precise velocity dispersion measurements, both for the study of galactic and active nuclei kinematics. As several works suggest, an excellent tactic to measure σ is to use the absorption lines of the calcium triplet, as it is a spectral region relatively free from complications. The discovery of an empirical relationship between the mass of the central black hole (M•) and σ was the leading guide of my detailed study of the calcium triplet region. This search for more accurate methods to calculate the dispersion of velocities, in addition to the careful study of uncertainties. After investing so much time in the development and improvement of the method and its application to so many galaxies, it is time to reap the rewards of this effort, using my results to address a series of questions concerning the physics of galaxies.展开更多
A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and...A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.展开更多
The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecul...The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.展开更多
The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
Developing efficient and durable electrocatalysts for acidic oxygen evolution reaction(OER)is pivotal for advancing proton exchange membrane water electrolysis(PEMWEs),yet balancing activity and stability remains a fo...Developing efficient and durable electrocatalysts for acidic oxygen evolution reaction(OER)is pivotal for advancing proton exchange membrane water electrolysis(PEMWEs),yet balancing activity and stability remains a formidable challenge.Herein,we propose a dual-engineering strategy to stabilize Ru-based catalysts by synergizing the oxygen vacancy site-synergized mechanism-lattice oxygen mechanism(OVSM-LOM)with Ru-N bond stabilization.The engineered RuO_(2)@NCC catalyst exhibits exceptional OER performance in 0.5 M H2SO4,achieving an ultralow overpotential of 215 mV at 10 mA cm^(-2) and prolonged stability for over 327 h.The catalyst delivers 300 h of continuous operation at 1 A cm^(-2),with a negligible degradation rate of only 0.067 mV h-1,further demonstrating its potential for practical application.Oxygen vacancies unlock the OVSM-LOM pathway,bypassing the sluggish adsorbate evolution mechanism(AEM)and accelerating reaction kinetics,while the Ru-N bonds suppress Ru dissolution by anchoring low-valent Ru centers.Quasi-in situ X-ray photoelectron spectroscopy(XPS),X-ray absorption spectroscopy(XAS),and isotopic labeling experiments confirm the lattice oxygen participation with *O formation as the rate-determining step.The Ru-N bonds reinforce the structural integrity by stabilizing low-valent Ru centers and inhibiting overoxidation.Theoretical calculations further verify that the synergistic interaction between OVs and Ru-O(N)active sites optimizes the Ru d-band center and stabilizes intermediates,while Ru-N coordination enhances structural integrity.This study establishes a novel paradigm for designing robust acidic OER catalysts through defect and coordination engineering,bridging the gap between activity and stability for sustainable energy technologies.展开更多
Hydrogen production by electrolysis of water is a key technology to achieve green hydrogen energy economy,but it relies on advanced catalyst materials with high efficiency,stability,and wide pH adaptability.In this st...Hydrogen production by electrolysis of water is a key technology to achieve green hydrogen energy economy,but it relies on advanced catalyst materials with high efficiency,stability,and wide pH adaptability.In this study,Ni,Ru,and Pt ternary metals were embedded into nitrogen-doped hollow carbon spheres(NHCSs)by hydrothermal tandem heat treatment to form ternary supported metal nanoparticles with high dispersion and ultra-small particle size(~1.3 nm),which realized efficient hydrogen evolution from multi-scenario electrocatalytic water splitting.In the whole pH range,the performance of NiRuPt/NHCSs is better than that of commercial Pt/C catalyst,and the overpotentials under alkaline,neutral,and acidic conditions are as low as 15.5,20.0,and 29.5 mV,respectively.Under industrial conditions,NiRuPt/NHCSs also have excellent hydrogen evolution reaction(HER)performance,achieving efficient electrolysis of seawater for hydrogen production,and achieving Ampere-level hydrogen production at low voltage(~1.76 V)on integrated membrane electrode assemblies.Density functional theory(DFT)calculations show that in the NiRuPt ternary metal,the Pt site is conducive to promoting the desorption of*H to form H_(2),the Ru site is conducive to promoting the capture of H_(2)O,and the Ni site is conducive to promoting the dissociation of H_(2)O.Therefore,the formed NiRuPt ternary metal synergistically promotes multi-scenario efficient electrolysis of water to produce hydrogen.This study provides a new idea for the design of multi-component metal/carbon-based composite catalysts,and promotes the development of non-noble metal/noble metal composite catalysts in hydrogen production by electrolysis of water.展开更多
Serbisütherapy(ST)is a distinctive external treatment modality within traditional Mongolian medicine(TMM),historically developed within a nomadic cultural framework.This study presents a comprehensive philologica...Serbisütherapy(ST)is a distinctive external treatment modality within traditional Mongolian medicine(TMM),historically developed within a nomadic cultural framework.This study presents a comprehensive philological and historical analysis of ST,tracing its evolution from early battlefield applications to contemporary clinical use.By critically examining classical Mongolian medical texts alongside modern case studies,we aim to systematize ST’s therapeutic methods,indications,and limitations,while exploring its mechanisms of action through both traditional theory and modern biomedical perspectives.ST has undergone significant transformation,shifting from whole-body cavity immersion in the 13th century to targeted,organ-specific applications in modern practice.Its four primary methods–Covering,Mounted,Organ Placement,and Suction–demonstrate efficacy in treating cold-natured diseases,musculoskeletal disorders,gynecological conditions,and certain emergencies.ST embodies the core principles of TMM,particularly the balance of the“Three Roots”and the correction of cold-induced pathologies through heat.Despite challenges related to standardization,cultural translation,and regulatory acceptance,ST holds translational potential for integrative medicine.Future research should prioritize mechanistic validation,clinical standardization,and the development of biocompatible thermal technologies to bridge traditional practice with modern healthcare systems.展开更多
Oxygen evolution reaction(OER)is a key step in hydrogen production by water electrolysis technology.How-ever,developing efficient,stable,and low-cost OER electrocatalysts is still challenging.This article presents the...Oxygen evolution reaction(OER)is a key step in hydrogen production by water electrolysis technology.How-ever,developing efficient,stable,and low-cost OER electrocatalysts is still challenging.This article presents the preparation of a series of novel copper iridium nanocatalysts with heterostructures and low iridium content for OER.The electrochemical tests revealed higher OER of Cu@Ir_(0.3) catalyst under acidic conditions with a generated current density of 10 mA/cm^(2) at only 284 mV overpotential.The corresponding OER mass activity was estimated to be 1.057 A/mgIr,a value 8.39-fold higher than that of the commercial IrO_(2).After 50 h of endurance testing,the Cu@Ir_(0.3) catalyst preserved excellent catalytic activity with a negligible rise in overpotential and maintained a good heterostructures.Cu@Ir_(0.3) The excellent OER activity can be attributed to its heterostructure,as con-firmed by density functional theory(DFT)calculations,indicating that Cu@Ir The coupling between isoquanta causes charge redistribution,optimizing the adsorption energy of unsaturated Ir sites for oxygen intermediates and reducing the energy barrier of OER free energy determining the rate step.In summary,this method provides a new approach for designing efficient,stable,and low iridium content OER catalysts.展开更多
Deep insights into electrocatalytic mechanisms are vital for the rational design of catalysts for oxygen evolution reaction(OER).Mechanistically,the OER driven by adsorbate evolution mechanism(AEM)is limited by the li...Deep insights into electrocatalytic mechanisms are vital for the rational design of catalysts for oxygen evolution reaction(OER).Mechanistically,the OER driven by adsorbate evolution mechanism(AEM)is limited by the linear scaling relationship,thereby exhibiting large overpotentials.In the lattice oxygen mechanism(LOM),the OER can be enhanced by enabling direct O_(2)formation.However,this enhancement is accompanied by the generation of oxygen vacancies,which presents a significant challenge to the long-term stability of LOMOER,particularly when operating at high current densities.Recently,the*O-*O coupling mechanism(OCM)has emerged as a promising alternative;it not only breaks the linear scaling relationship but also ensures catalytic stability.This review encapsulates the cutting-edge advancements in electrocatalysts that are grounded in the OCM,offering a detailed interpretation on the foundational principles guiding the design of OCM-OER catalysts.It also highlights recent theoretical investigations combining machine learning(ML)with density functional theory(DFT)calculations to reveal OER mechanisms.At the end of this review,the challenges and opportunities associated with OCM-OER electrocatalysts are discussed.展开更多
The dissimilar 2B06 and 7B04 Al alloy joints were prepared by refill friction stir spot welding(RFSSW),and the microstructural evolution and corrosion behavior of the joints were investigated.Based on microstructural ...The dissimilar 2B06 and 7B04 Al alloy joints were prepared by refill friction stir spot welding(RFSSW),and the microstructural evolution and corrosion behavior of the joints were investigated.Based on microstructural analysis,the welded joints exhibit distinct microstructural zones,including the stir zone(SZ),thermomechanically affected zone(TMAZ),and heat-affected zone(HAZ).The grain size of each zone is in the order of HAZ>TMAZ>SZ.Notably,the TMAZ and HAZ contain significantly larger secondary-phase particles compared to the SZ,with particle size in the HAZ increasing at higher rotational speeds.Electrochemical tests indicate that corrosion susceptibility follows the sequence of HAZ>TMAZ>SZ>BM,with greater sensitivity observed at increased rotational speeds.Post-corrosion mechanical performance degradation primarily arises from crevice corrosion at joint overlaps,but not from the changes in the microstructure.展开更多
Heterostructure engineering has emerged as a promising strategy to enhance the electrochemical CO_(2)reduction reaction(CO_(2)RR)by optimizing interfacial electron transfer.Herein,we report a novel octahedral SnS_(2)/...Heterostructure engineering has emerged as a promising strategy to enhance the electrochemical CO_(2)reduction reaction(CO_(2)RR)by optimizing interfacial electron transfer.Herein,we report a novel octahedral SnS_(2)/SnO_(2)heterojunction catalyst synthesized via an ion-exchange vulcanization method,which achieves exceptional activity and selectivity for CO_(2)-toformate conversion.Through in-situ Raman spectroscopy,ex-situ X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS),we demonstrate that the octahedral SnS_(2)/SnO_(2)heterojunction dynamically restructures into a sulfur-doped Sn/SnO_(2)(Sn(S)/SnO_(2))heterostructure under operating conditions.Density functional theory(DFT)calculations reveal that the Sn(S)/SnO_(2)interface facilitates electron transfer from SnO_(2)to metallic Sn(S),generating a built-in electric field that stabilizes Sn^(4+)in SnO_(2)and accelerates proton-coupled electron transfer to*OCHO intermediates.Consequently,the catalyst achieves a formate Faradaic efficiency exceeding 90% over a broad potential window(-0.6 to -1.0 V vs.reversible hydrogen electrode(RHE))with a high partial current density of -280 mA·cm^(-2),surpassing most reported Sn-based catalysts.This work elucidates the structural dynamics and interfacial enhancement mechanisms of heterojunction catalysts,offering a rational design principle for advanced CO_(2)RR electrocatalysts.展开更多
Based on a sample of 79 local advanced merger （adv-merger） （U）LIRGs, we search for evidence of quenching processes by investigating the distributions of star formation history indicators （EW（Ha）, EW（HfiA） and...Based on a sample of 79 local advanced merger （adv-merger） （U）LIRGs, we search for evidence of quenching processes by investigating the distributions of star formation history indicators （EW（Ha）, EW（HfiA） and D,（4000）） on the NUV-r color-mass and SFR-M, diagrams. The distributions of EW（Ha） and Dn（4000） on the NUV-r color-mass diagram show clear trends that at a given stellar mass, galaxies with redder NUV-r colors have smaller EW（Ha） and larger Dn （4000）. The reddest adv-merger （U）LIRGs close to the green valley mostly have Dn（4000）〉 1.4. In addition, in the SFR-M, diagram, as the SFR decreases, the EW（Ha） decreases and the Dn （4000） increases, implying that the adv-merger （U）LIRGs on the star formation main sequence have more evolved stellar populations than those above the main sequence. These results indicate that a fraction of the adv-merger （U）LIRGs have already exhibited signs of fading from the starburst phase and that the NUV-r reddest adv-merger （U）LIRGs are likely at the initial stage of post-starbursts with an age of - 1 Gyr, which is consistent with the gas exhaustion time-scales. Therefore, our results offer additional support for the fast evolutionary track from the blue cloud to the red sequence.展开更多
基金financial support from the Secretaría Nacional de Ciencia,Tecnologia e Innovacion(SENACYT),through the Departamento de Fortalecimiento a los Posgrados Nacionalesthe coordination of the program"MOVILIDAD DE INVESTIGACION."+3 种基金the financial support provided by PAPIIT projects IN108323 and IN111825 from DGAPA-UNAMsupport from the Agencia Nacional de Investigación y Desarrollo(ANID)through Basal project FB210003FONDECYT Regular projects 1241426 and 123044Millennium Science Initiative Program NCN2024_112。
文摘Through the analysis of representative samples of field galaxies,both local(z~0.027)and distant(z~0.7),we explore the barred galaxy fraction and its dependence on stellar mass,color,and morphology,aiming to understand the evolution of these structural components through cosmic time.To this end,two complementary bar detection techniques were employed:elliptical isophote fitting and two-dimensional Fourier analysis,both applied to deep optical images.The observational samples were drawn from previously established and calibrated catalogs to ensure a homogeneous selection in stellar mass,enabling a robust comparison between local galaxies(z~0.027)and those in the distant Universe(z~0.7).This study systematically applies both isophotal fitting and Fourier decomposition across a wide redshift range,offering a comprehensive view of the evolution of bar incidence as a function of stellar mass and morphology.The results indicate that the fraction of barred galaxies is significantly higher in the local Universe than at earlier epochs,particularly among spiral galaxies.Furthermore,a clear correlation is observed between the presence of bars and stellar mass,especially in the high-mass regime(log(M_*/M☉)>10.5).In distant galaxies,this fraction is lower across all mass ranges,which may be related to more active dynamical processes.Overall,the findings reinforce the idea that stellar bars emerge as a consequence of dynamical cooling and the progressive stabilization of galactic disks,playing a key role in gas transport and the internal structural evolution of galaxies from z~1 to the present day.
基金Supported by the National Natural Science Foundation of China.
文摘Based on a sample of 72 Blue Compact Galaxies （BCGs） observed with the 2.16 m telescope of the National Astronomical Observatories, Chinese Academy of Sciences （NAOC） and about 4000 strong emission line galaxies from the Sloan Digital Sky Survey, we analyzed their chemical evolution history using the revised chemical evolution model of Larsen et al. Our sample covers a much larger metallicity range （7.2 〈 12 ＋ log（O/H） 〈 9.0）. We found that, in order to reproduce the observed abundance pattern and gas fraction over the whole metallicity range, a relatively continuous star formation history is needed for high metallicity galaxies, while assuming a series of instantaneous bursts with long quiescent periods （some Gyrs） for low metallicity galaxies. Model calculations also show that only the closed-box model is capable of reproducing the observational data over the whole metallicity range. Models that consider the ordinary winds and/or inflow can only fit the observations in the low metallicity range, and a model with enriched wind cannot fit the data in the whole metallicity range. This implies that the current adopted simple wind and inflow models are not applicable to massive galaxies, where the underlying physics of galactic winds or inflow could be more complicated.
文摘In the past,people did not realize the formation and structure of galaxies.They even mistook the black holes hidden in the center of a galaxy as independent celestial objects,making black holes mysterious and unbelievable.It was only after the author studied and discovered the laws of the formation and evolution of satellites,planets and stars that he put forward the scientific theory of galaxy formation and evolution,therefore revealing the hierarchical structure of galaxy and the existence and characteristics of black holes as the main nodes of galactic structure.
基金support from the National Natural Science Foundation of China (grant Nos. 12025303, 11890693,11421303 and 12003031)the CAS Frontier Science Key Research Program (QYZDJ-SSW-SLH006)+2 种基金the K.C. Wong Education Foundationthe science research grants from the China Manned Space Project with No. CMS-CSST-2021-A06support from the Chinese Academy of Sciences President’s International Fellowship Initiative (grant No. 2019PM0020)。
文摘The coevolution between supermassive black holes(SMBHs) and their host galaxies has been proposed for more than a decade,albeit with little direct evidence about black hole accretion activities regulating galaxy star formation at z> 1.In this paper,we study the lifetimes of X-ray active galactic nuclei(AGNs) in UV-selected red sequence(RS),blue cloud(BC) and green valley(GV) galaxies,finding that AGN accretion activities are most prominent in GV galaxies at z ~1.5-2,compared with RS and BC galaxies.We also compare AGN accretion timescales with typical color transition timescales of UV-selected galaxies.We find that the lifetime of GV galaxies at z~1.5-2 is very close to the typical timescale when the AGNs residing in them stay in the high-accretion-rate mode at these redshifts;for BC galaxies,the consistency between the color transition timescale and the black hole strong accretion lifetime is more likely to happen at lower redshifts(z <1).Our results support the scenario where AGN accretion activities govern UV color transitions of host galaxies,making galaxies and their central SMBHs coevolve with each other.
基金supports from National Key R&D Program of China(Grant Nos.2018YFA0404503,2018YFE0202902)the National Key Program for Science and Technology Research and Development of China(2017YFB0203300,2015CB857005)+2 种基金the National Natural Science Foundation of China(NSFC,Nos.11988101,11425312,11503032,11773032,11390372,11873051,118513,11573033,11622325,12033008,and 11622325)funding supports from FONDECYT Postdoctoral Fellowship Project(No.3190354)NSFC(No.11703037)。
文摘The discovery of massive galaxies at high redshifts,especially the passive ones,poses a big challenge for the current standard galaxy formation models.Here we use the semi-analytic galaxy formation model developed by Henriques et al.to explore the formation and evolution of massive galaxies(MGs,stellar-mass M*>1011 M⊙).Different from previous works,we focus on the ones just formed(e.g.just reach?1011 M⊙).We find that most of the MGs are formed around z=0.6,with the earliest formation at z>4.Interestingly,although most of the MGs in the local Universe are passive,we find that only 13%of the MGs are quenched at the formation time.Most of the quenched MGs at formation already host a very massive supermassive black hole(SMBH)which could power the very effective AGN feedback.For the star-forming MGs,the ones with more massive SMBH prefer to quench in shorter timescales;in particular,those with MSMBH>107.5 M⊙have a quenching timescale of~0.5 Gyr and the characteristic MSMBH depends on the chosen stellar mass threshold in the definition of MGs as a result of their co-evolution.We also find that the"in-situ"star formation dominates the stellar mass growth of MGs until they are formed.Over the whole redshift range,we find the quiescent MGs prefer to stay in more massive dark matter halos,and have more massive SMBH and less cold gas masses.Our results provide a new angle on the whole life of the growth of MGs in the Universe.
基金the financial support from Kerala State Council for Science,Technology and Environment(KSCSTE)
文摘Using a sample of 13 early-type spiral galaxies hosting nuclear rings,we report remarkable correlations between the properties of the nuclear rings and the central intensity ratio(CIR) of their host galaxies.The CIR,a function of intensity of light within the central 1.5 and 3 arcsec region,is found to be a vital parameter in galaxy evolution,as it shares strong correlations with many structural and dynamical properties of early-type galaxies,including mass of the central supermassive black hole(SMBH).We use archival HST images for aperture photometry at the centre of the galaxy image to compute the CIR.We observe that the relative sizes of nuclear rings and ring cluster surface densities strongly correlate with the CIR.These correlations suggest reduced star formation in the centres of galaxies hosting small and dense nuclear rings.This scenario appears to be a consequence of strong bars as advocated by the significant connection observed between the CIR and bar strengths.In addition,we observe that the CIR is closely related with the integrated properties of the stellar population in the nuclear rings,associating the rings hosting older and less massive star clusters with low values of CIR.Thus,the CIR can serve as a crucial parameter in unfolding the coupled evolution of bars and rings as it is intimately connected with both their properties.
基金Supported by the National Natural Science Foundation of China(Grant Nos.10878010,10221001 and 10633040)the National Basic Research Program(973 program,No.2007CB815405)
文摘We present galactic spectroscopic data from a pencil beam of 10.75×7.5 centered on the X-ray cluster RXJ0054.0–2823 at z=0.29.We study the spectral evolution of galaxies from z=1 down to the cluster redshift in a magnitude-limited sample at R≤23,for which the statistical properties of the sample are well understood.We divide emission-line galaxies into star-forming galaxies,Low Ionization Nuclear Emission line Regions（LINERs） ,and Seyferts by using emission-line ratios of[OII],Hβ,and[OIII],and derive stellar fractions from population synthesis models. We focus our analysis on absorption and low-ionization galaxies.For absorption-line galaxies,we recover the well-known result that these galaxies have had no detectable evolution since z～0.6-0.7,but we also find that in the range z=0.65-1,at least 50% of the stars in bright absorption systems are younger than 2.5 Gyr.Faint absorption-line galaxies in the cluster at z=0.29 also had significant star formation during the previous 2-3 Gyr,but their brighter counterparts seem to be only composed of old stars.At z～0.8,our dynamically young cluster had a truncated red-sequence.This result seems to be consistent with a scenario where the final assembly of E/S0 took place at z1.In the volume-limited range 0.35≤z≤0.65,we find that 23% of the early-type galaxies have LINER-like spectra with Hβin absorption and have a significant component of A stars.The vast majority of LINERs in our sample have significant populations of young and intermediate-aged stars and are thus not related to AGNs,but to the population of‘retired galaxies’recently identified by Cid Fernandes et al.in the Sloan Digital Sky Survey（SDSS） .Early-type LINERs with various fractions of A stars and E＋A galaxies appear to play an important role in the formation of the red sequence.
文摘Galaxy formation and evolution is one of the most active research areas in astrophysics,so many people have studied this area.But since they didn’t understand thoroughly the evolution law from satellite to planet then to star,their theories are very weak.In their theories,they proposed that large gas clouds collapsing to form a galaxy or more recently that matter started out in smaller clumps merged to form galaxy,which is incredible.Hence,the author of this paper,through studying the formation and orbit-variation of satellites,planets and stars,has put forward a new theory of galaxy formation and evolution,therefore revealing the hierarchical structure of galaxies and the formation and evolution of black holes and quasars.
文摘This study will see the resurgence of interest in precise velocity dispersion measurements, both for the study of galactic and active nuclei kinematics. As several works suggest, an excellent tactic to measure σ is to use the absorption lines of the calcium triplet, as it is a spectral region relatively free from complications. The discovery of an empirical relationship between the mass of the central black hole (M•) and σ was the leading guide of my detailed study of the calcium triplet region. This search for more accurate methods to calculate the dispersion of velocities, in addition to the careful study of uncertainties. After investing so much time in the development and improvement of the method and its application to so many galaxies, it is time to reap the rewards of this effort, using my results to address a series of questions concerning the physics of galaxies.
文摘A composite electrocatalyst,CoMoNiO-S/NF-110(NF is nickel foam),was synthesized through electrodeposition,followed by pyrolysis and then the vulcanization process.CoMoNiO-S/NF-110 exhibited a structure where Ni3S2 and Mo2S3 nanoparticles were integrated at the edges of Co3O4 nanosheets,creating a rich,heterogeneous interface that enhances the synergistic effects of each component.In an alkaline electrolyte,the synthesized CoMoNiO-S/NF-110 exhibited superior electrocatalytic performance for oxygen evolution reaction(OER),achieving current densities of 100 and 200 mA·cm^(-2) with low overpotentials of 199.4 and 224.4 mV,respectively,outperforming RuO2 and several high-performance Mo and Ni-based catalysts.This excellent performance is attributed to the rich interface formed between the components and active sites exposed by the defect structure.
文摘The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
基金support from the National Natural Science Foundation of China(Nos.12305373 and 52276220)the Guangzhou Basic Research Program(No.SL2024A04J00234).
文摘Developing efficient and durable electrocatalysts for acidic oxygen evolution reaction(OER)is pivotal for advancing proton exchange membrane water electrolysis(PEMWEs),yet balancing activity and stability remains a formidable challenge.Herein,we propose a dual-engineering strategy to stabilize Ru-based catalysts by synergizing the oxygen vacancy site-synergized mechanism-lattice oxygen mechanism(OVSM-LOM)with Ru-N bond stabilization.The engineered RuO_(2)@NCC catalyst exhibits exceptional OER performance in 0.5 M H2SO4,achieving an ultralow overpotential of 215 mV at 10 mA cm^(-2) and prolonged stability for over 327 h.The catalyst delivers 300 h of continuous operation at 1 A cm^(-2),with a negligible degradation rate of only 0.067 mV h-1,further demonstrating its potential for practical application.Oxygen vacancies unlock the OVSM-LOM pathway,bypassing the sluggish adsorbate evolution mechanism(AEM)and accelerating reaction kinetics,while the Ru-N bonds suppress Ru dissolution by anchoring low-valent Ru centers.Quasi-in situ X-ray photoelectron spectroscopy(XPS),X-ray absorption spectroscopy(XAS),and isotopic labeling experiments confirm the lattice oxygen participation with *O formation as the rate-determining step.The Ru-N bonds reinforce the structural integrity by stabilizing low-valent Ru centers and inhibiting overoxidation.Theoretical calculations further verify that the synergistic interaction between OVs and Ru-O(N)active sites optimizes the Ru d-band center and stabilizes intermediates,while Ru-N coordination enhances structural integrity.This study establishes a novel paradigm for designing robust acidic OER catalysts through defect and coordination engineering,bridging the gap between activity and stability for sustainable energy technologies.
基金financially supported by the Yunnan Fundamental Research Projects(Nos.202401CF070026 and 202501AT070017)the Scientific Research Fund Project of Yunnan Provincial Education Department(No.2024J0134)+1 种基金the Xingdian Talent Program of Yunnan Province,and the Scientific and Technological Project of Yunnan Precious Metals Laboratory(No.YPML-20240502065)Xinjiang Key Laboratory of Novel Functional Materials Chemistry Open Science Project(No.XJLNFMC-202406).
文摘Hydrogen production by electrolysis of water is a key technology to achieve green hydrogen energy economy,but it relies on advanced catalyst materials with high efficiency,stability,and wide pH adaptability.In this study,Ni,Ru,and Pt ternary metals were embedded into nitrogen-doped hollow carbon spheres(NHCSs)by hydrothermal tandem heat treatment to form ternary supported metal nanoparticles with high dispersion and ultra-small particle size(~1.3 nm),which realized efficient hydrogen evolution from multi-scenario electrocatalytic water splitting.In the whole pH range,the performance of NiRuPt/NHCSs is better than that of commercial Pt/C catalyst,and the overpotentials under alkaline,neutral,and acidic conditions are as low as 15.5,20.0,and 29.5 mV,respectively.Under industrial conditions,NiRuPt/NHCSs also have excellent hydrogen evolution reaction(HER)performance,achieving efficient electrolysis of seawater for hydrogen production,and achieving Ampere-level hydrogen production at low voltage(~1.76 V)on integrated membrane electrode assemblies.Density functional theory(DFT)calculations show that in the NiRuPt ternary metal,the Pt site is conducive to promoting the desorption of*H to form H_(2),the Ru site is conducive to promoting the capture of H_(2)O,and the Ni site is conducive to promoting the dissociation of H_(2)O.Therefore,the formed NiRuPt ternary metal synergistically promotes multi-scenario efficient electrolysis of water to produce hydrogen.This study provides a new idea for the design of multi-component metal/carbon-based composite catalysts,and promotes the development of non-noble metal/noble metal composite catalysts in hydrogen production by electrolysis of water.
基金supported by The China Ethnic Medicine Association Research Grant(No.2023MY055-81)Science and Technology Program of the Joint Fund of Scientific Research for the Public Hospitals of Inner Mongolia Academy of Medical Sciences(2023GLLHD177,2023GLLH0174)Inner Mongolia Autonomous Region Regional Medical Center for Specialized Care(2025).
文摘Serbisütherapy(ST)is a distinctive external treatment modality within traditional Mongolian medicine(TMM),historically developed within a nomadic cultural framework.This study presents a comprehensive philological and historical analysis of ST,tracing its evolution from early battlefield applications to contemporary clinical use.By critically examining classical Mongolian medical texts alongside modern case studies,we aim to systematize ST’s therapeutic methods,indications,and limitations,while exploring its mechanisms of action through both traditional theory and modern biomedical perspectives.ST has undergone significant transformation,shifting from whole-body cavity immersion in the 13th century to targeted,organ-specific applications in modern practice.Its four primary methods–Covering,Mounted,Organ Placement,and Suction–demonstrate efficacy in treating cold-natured diseases,musculoskeletal disorders,gynecological conditions,and certain emergencies.ST embodies the core principles of TMM,particularly the balance of the“Three Roots”and the correction of cold-induced pathologies through heat.Despite challenges related to standardization,cultural translation,and regulatory acceptance,ST holds translational potential for integrative medicine.Future research should prioritize mechanistic validation,clinical standardization,and the development of biocompatible thermal technologies to bridge traditional practice with modern healthcare systems.
基金supported by the Major Science and Technology Special Plan of Yunnan Province(Nos.202302AB080012 and 202402AB080004)the National Natural Science Foundation of China(No.22264025)+1 种基金the Basic Research Foundation of Yunnan Province(Nos.202401AS070033 and 202501AT070055)the Reserve talents for young and middleaged academic and technical leaders project of Yunnan Province(No.202405AC350071).
文摘Oxygen evolution reaction(OER)is a key step in hydrogen production by water electrolysis technology.How-ever,developing efficient,stable,and low-cost OER electrocatalysts is still challenging.This article presents the preparation of a series of novel copper iridium nanocatalysts with heterostructures and low iridium content for OER.The electrochemical tests revealed higher OER of Cu@Ir_(0.3) catalyst under acidic conditions with a generated current density of 10 mA/cm^(2) at only 284 mV overpotential.The corresponding OER mass activity was estimated to be 1.057 A/mgIr,a value 8.39-fold higher than that of the commercial IrO_(2).After 50 h of endurance testing,the Cu@Ir_(0.3) catalyst preserved excellent catalytic activity with a negligible rise in overpotential and maintained a good heterostructures.Cu@Ir_(0.3) The excellent OER activity can be attributed to its heterostructure,as con-firmed by density functional theory(DFT)calculations,indicating that Cu@Ir The coupling between isoquanta causes charge redistribution,optimizing the adsorption energy of unsaturated Ir sites for oxygen intermediates and reducing the energy barrier of OER free energy determining the rate step.In summary,this method provides a new approach for designing efficient,stable,and low iridium content OER catalysts.
基金supported by the National Natural Science Foundation of China(Nos.22373063 and 22302005)Fundamental Research Funds for the Central Universities of China(No.GK202203002)+1 种基金China Postdoctoral Science Foundation(No.2023M730044)Technology Innovation Leading Program of Shaanxi(Program No.2023KXJ-007).
文摘Deep insights into electrocatalytic mechanisms are vital for the rational design of catalysts for oxygen evolution reaction(OER).Mechanistically,the OER driven by adsorbate evolution mechanism(AEM)is limited by the linear scaling relationship,thereby exhibiting large overpotentials.In the lattice oxygen mechanism(LOM),the OER can be enhanced by enabling direct O_(2)formation.However,this enhancement is accompanied by the generation of oxygen vacancies,which presents a significant challenge to the long-term stability of LOMOER,particularly when operating at high current densities.Recently,the*O-*O coupling mechanism(OCM)has emerged as a promising alternative;it not only breaks the linear scaling relationship but also ensures catalytic stability.This review encapsulates the cutting-edge advancements in electrocatalysts that are grounded in the OCM,offering a detailed interpretation on the foundational principles guiding the design of OCM-OER catalysts.It also highlights recent theoretical investigations combining machine learning(ML)with density functional theory(DFT)calculations to reveal OER mechanisms.At the end of this review,the challenges and opportunities associated with OCM-OER electrocatalysts are discussed.
基金supported by the National Natural Science Foundation of China (Nos. 52075449, 51975480)。
文摘The dissimilar 2B06 and 7B04 Al alloy joints were prepared by refill friction stir spot welding(RFSSW),and the microstructural evolution and corrosion behavior of the joints were investigated.Based on microstructural analysis,the welded joints exhibit distinct microstructural zones,including the stir zone(SZ),thermomechanically affected zone(TMAZ),and heat-affected zone(HAZ).The grain size of each zone is in the order of HAZ>TMAZ>SZ.Notably,the TMAZ and HAZ contain significantly larger secondary-phase particles compared to the SZ,with particle size in the HAZ increasing at higher rotational speeds.Electrochemical tests indicate that corrosion susceptibility follows the sequence of HAZ>TMAZ>SZ>BM,with greater sensitivity observed at increased rotational speeds.Post-corrosion mechanical performance degradation primarily arises from crevice corrosion at joint overlaps,but not from the changes in the microstructure.
基金the Natural Science Foundation of Jiangsu Province(No.BK20253049)the Science and Technology Program of Xuzhou(No.KC25028)+3 种基金the Basic Science(Natural Science)Research Project of Higher Education Institutions in Jiangsu Province(No.25KJB430013)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.24KJA150003)the National Natural Science Foundation of China(No.22271122)the Xuzhou Key Research and Development Program(Social Development)(No.KC23298).
文摘Heterostructure engineering has emerged as a promising strategy to enhance the electrochemical CO_(2)reduction reaction(CO_(2)RR)by optimizing interfacial electron transfer.Herein,we report a novel octahedral SnS_(2)/SnO_(2)heterojunction catalyst synthesized via an ion-exchange vulcanization method,which achieves exceptional activity and selectivity for CO_(2)-toformate conversion.Through in-situ Raman spectroscopy,ex-situ X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS),we demonstrate that the octahedral SnS_(2)/SnO_(2)heterojunction dynamically restructures into a sulfur-doped Sn/SnO_(2)(Sn(S)/SnO_(2))heterostructure under operating conditions.Density functional theory(DFT)calculations reveal that the Sn(S)/SnO_(2)interface facilitates electron transfer from SnO_(2)to metallic Sn(S),generating a built-in electric field that stabilizes Sn^(4+)in SnO_(2)and accelerates proton-coupled electron transfer to*OCHO intermediates.Consequently,the catalyst achieves a formate Faradaic efficiency exceeding 90% over a broad potential window(-0.6 to -1.0 V vs.reversible hydrogen electrode(RHE))with a high partial current density of -280 mA·cm^(-2),surpassing most reported Sn-based catalysts.This work elucidates the structural dynamics and interfacial enhancement mechanisms of heterojunction catalysts,offering a rational design principle for advanced CO_(2)RR electrocatalysts.
基金supported by the National Natural Science Foundation of China(Grant Nos11373027,10973011 and 11003015)sponsored by SRF for ROCS, SEM
文摘Based on a sample of 79 local advanced merger （adv-merger） （U）LIRGs, we search for evidence of quenching processes by investigating the distributions of star formation history indicators （EW（Ha）, EW（HfiA） and D,（4000）） on the NUV-r color-mass and SFR-M, diagrams. The distributions of EW（Ha） and Dn（4000） on the NUV-r color-mass diagram show clear trends that at a given stellar mass, galaxies with redder NUV-r colors have smaller EW（Ha） and larger Dn （4000）. The reddest adv-merger （U）LIRGs close to the green valley mostly have Dn（4000）〉 1.4. In addition, in the SFR-M, diagram, as the SFR decreases, the EW（Ha） decreases and the Dn （4000） increases, implying that the adv-merger （U）LIRGs on the star formation main sequence have more evolved stellar populations than those above the main sequence. These results indicate that a fraction of the adv-merger （U）LIRGs have already exhibited signs of fading from the starburst phase and that the NUV-r reddest adv-merger （U）LIRGs are likely at the initial stage of post-starbursts with an age of - 1 Gyr, which is consistent with the gas exhaustion time-scales. Therefore, our results offer additional support for the fast evolutionary track from the blue cloud to the red sequence.
