Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nano...Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nanorods,which had many voids.The S-FeCoTA catalysts exhibited excellent electrochemical oxygen evolution reaction(OER)performance with a low overpotential of 273 mV at 10 mA·cm^(-2)and a small Tafel slope of 36 mV·dec^(-1)in 1 mol·L^(-1)KOH.The potential remained at 1.48 V(vs RHE)at 10 mA·cm^(-2)under continuous testing for 15 h,implying that S-FeCoTA had good stability.The Faraday efficiency of S-FeCoTA was 94%.The outstanding OER activity of S-FeCoTA is attributed to the synergistic effects among S,Fe,and Co,thus promoting electron transfer,reducing the reaction kinetic barrier,and enhancing the OER performance.展开更多
Available online Alkaline water electrolysis(AWE)is a prominent technique for obtaining a sustainable hydrogen source and effectively managing the energy infrastructure.Noble metal-based electrocatalysts,owing to thei...Available online Alkaline water electrolysis(AWE)is a prominent technique for obtaining a sustainable hydrogen source and effectively managing the energy infrastructure.Noble metal-based electrocatalysts,owing to their exceptional hydrogen binding energy,exhibit remarkable catalytic activity and long-term stability in the hydrogen evolution reaction(HER).However,the restricted accessibility and exorbitant cost of noble-metal materials pose obstacles to their extensive adoption in industrial contexts.This review investigates strategies aimed at reducing the dependence on noble-metal electrocatalysts and developing a cost-effective alkaline HER catalyst,while considering the principles of sustainable development.The initial discussion covers the fundamental principle of HER,followed by an overview of prevalent techniques for synthesizing catalysts based on noble metals,along with a thorough examination of recent advancements.The subsequent discussion focuses on the strategies employed to improve noble metalbased catalysts,including enhancing the intrinsic activity at active sites and increasing the quantity of active sites.Ultimately,this investigation concludes by examining the present state and future direction of research in the field of electrocatalysis for the HER.展开更多
Rare earth has a unique electronic structure and brings highly anticipated properties in light,electricity,heat and magnetism.Lanthanum is widely distributed among the rare earth elements and has a great potential for...Rare earth has a unique electronic structure and brings highly anticipated properties in light,electricity,heat and magnetism.Lanthanum is widely distributed among the rare earth elements and has a great potential for the electrocatalytic application.This paper reviews the common types and synthesis methods of lanthanum-based catalysts used in the electrocatalytic oxygen evolution reaction,and highlights the optimization of lanthanum-based catalysts.The electronic structure and active sites of the catalysts can be adjusted through atomic doping,interfacial modulation,and structural defects to enhance the OER.Further,the development of lanthanum-based catalyst is envisioned.展开更多
Purpose–As an important part of the management of railway passenger transport,the rationality and effectiveness of the clearing method of railway passenger transport are directly related to the operating efficiency a...Purpose–As an important part of the management of railway passenger transport,the rationality and effectiveness of the clearing method of railway passenger transport are directly related to the operating efficiency and service quality of railway passenger transport enterprises.This paper aims to comprehensively and deeply discuss the evolution and development process of China’s railway passenger transport clearing method,analyze its characteristics and influences in each stage,identify the main factors affecting its evolution and development and then put forward thoughts on improving the future development of the clearing method.Design/methodology/approach–Through a detailed review of the railway passenger transport clearing methods from the planned economy period to the reform and opening up period and into the new century,the basis,mode,subject and object of clearing in different development stages are systematically compared.Findings–It comprehensively reveals the evolution of the clearing method,sorted out the characteristics and changes of the clearing method at each stage and the adaptability to the development of railway passenger transport at that time.The characteristics of the development of clearing measures for railway passenger transport in different stages and their far-reaching influence on railway passenger transport business are deeply analyzed.Originality/value–This paper summarized the factors influencing the development of China’s railway passenger transportation clearing approach evolution,including the simplified rules of clearing,enhanced the market adaptability,establishing and perfecting the incentive mechanism,strengthening the construction of informatization,etc.This paper puts forward the ways to improve the railway passenger transportation clearing future development thinking.展开更多
Magnesium is distinguished by its highly anisotropic inelastic deformation involving a profuse activity of deformation twinning.Instrumented micro/nano-indentation technique has been widely applied to characterize the...Magnesium is distinguished by its highly anisotropic inelastic deformation involving a profuse activity of deformation twinning.Instrumented micro/nano-indentation technique has been widely applied to characterize the mechanical properties of magnesium,typically through the analysis of the indentation load-depth response,surface topography,and less commonly,the post-mortem microstructure within the bulk material.However,experimental limitations prevent the real-time observation of the evolving microstructure.To bridge this gap,we employ a recently-developed finite-strain model that couples the phase-field method and conventional crystal plasticity to simulate the evolution of the indentation-induced twin microstructure and its interaction with plastic slip in a magnesium single-crystal.Particular emphasis is placed on two aspects:orientation-dependent inelastic deformation and indentation size effects.Several outcomes of our 2D computational study are consistent with prior experimental observations.Chief among them is the intricate morphology of twin microstructure obtained at large spatial scales,which,to our knowledge,represents a level of detail that has not been captured in previous modeling studies.To further elucidate on size effects,we extend the model by incorporating gradient-enhanced crystal plasticity,and re-examine the notion of‘smaller is stronger’.The corresponding results underscore the dominant influence of gradient plasticity over the interfacial energy of twin boundaries in governing the size-dependent mechanical response.展开更多
Casting experiments and macro-micro numerical simulations were conducted to examine the microstructure characteristics of K439B nickel-based superalloy casting with varying cross-sections during the gravity investment...Casting experiments and macro-micro numerical simulations were conducted to examine the microstructure characteristics of K439B nickel-based superalloy casting with varying cross-sections during the gravity investment casting process.Firstly,microstructure analysis was conducted on the casting using scanning electron microscopy(SEM)and electron backscatter diffraction(EBSD).Subsequently,calculation of the phase diagram and differential scanning calorimetry(DSC)tests were conducted to determine the macro-micro simulation parameters of the K439B alloy,and the cellular automaton finite element(CAFE)method was employed to develop macro-micro modeling of K439B nickel-based superalloy casting with varying cross-sections.The experimental results revealed that the ratio of the average grain area increased from the edge to the center of the sections as the ratio of the cross-sectional area increased.The simulation results indicated that the average grain area increased from 0.885 to 0.956 mm^(2)as the ratio of the cross-sections increased from 6꞉1 to 12꞉1.The experiment and simulation results showed that the grain size became more heterogeneous and the grain shape became more irregular with an increase in the ratio of the cross-sectional area of the casting.CAFE modeling was an effective method to simulate the microstructure evolution of the K439B alloy and ensure the accuracy of the simulation.展开更多
Gas storage in abandoned mines is one way to reuse waste space resources.The surrounding rock of gas storage reservoirs in underground roadways undergoes damage and deformation under the cyclic loading of gas charging...Gas storage in abandoned mines is one way to reuse waste space resources.The surrounding rock of gas storage reservoirs in underground roadways undergoes damage and deformation under the cyclic loading of gas charging and discharging,which can pose a risk to the safety of the reservoirs.This study establishes a true triaxial numerical model of rock mass with the discrete element method(DEM)and explores the crack evolution of surrounding rock of underground gas storage during cyclic loading and unloading.Also,a damage evolution model in numerical analysis considering residual deformation is developed to explain the experimental results.As was revealed,cyclic loading and unloading resulted in fatigue damage in the specimen and caused strength deterioration of the specimen.During the loading process,the uniformly distributed force chains of the rock mass redistributed,evolving gradually to mostly transverse force chains.This contributed to the appearance of blank areas in the force chains when through cracks appear.The ratio of tensile cracks to shear cracks gradually decreases and finally stabilizes at 7:1.The damage evolution model considering residual strain can be mutually verified with the numerical simulation results.Based on the DEM model,it was found that there was a certain threshold of confining pressure.When the confining pressure exceeded 30 MPa,the deformation to ductility of sandstone samples began to accelerate,with a greater residual strength.This study provides a theoretical basis for analyzing the long-term mechanical behavior of surrounding rock of gas storage in abandoned mines.展开更多
This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is establi...This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is established considering the flexible deformation of the barrel and the interaction between the projectile and the barrel.Subsequently,the accuracy of the dynamic model is verified based on the external ballistic projectile attitude test platform.Furthermore,the probability density evolution method(PDEM)is developed to high-dimensional uncertainty quantification of projectile motion.The engineering example highlights the results of the proposed method are consistent with the results obtained by the Monte Carlo Simulation(MCS).Finally,the influence of parameter uncertainty on the projectile disturbance at muzzle under different working conditions is analyzed.The results show that the disturbance of the pitch angular,pitch angular velocity and pitch angular of velocity decreases with the increase of launching angle,and the random parameter ranges of both the projectile and coupling model have similar influence on the disturbance of projectile angular motion at muzzle.展开更多
Under the influence of the information technology revolution,the teaching method,as the way to impart teaching content or the means to realize teaching content,has undergone a process of constant evolution and transfo...Under the influence of the information technology revolution,the teaching method,as the way to impart teaching content or the means to realize teaching content,has undergone a process of constant evolution and transformation.This transformation is still ongoing.In order to explain this phenomenon,we establish a three-dimension analysis framework of"ECONOMIC BASE-INFORMATION TECHNOLOGY-CULTURE".All kinds of logics involved in them are closely linked,thus influencing each other.At the same time,these aspects constantly affect the historical trajectory of the evolution.Based on the above analysis framework,the paper uses the historical approach to expound the evolution path on teaching methods in China since ancient times and divides it into four stages.Combined with the practical problems and interview results,we rethink the present information teaching methods.In the end,some suggestions are put forward in order to promote the further development of education-related fields.展开更多
The influence of thermal damage on macroscopic and microscopic characteristics of different rocks has received much attention in the field of rock engineering.When the rocks are subjected to thermal treatment,the chan...The influence of thermal damage on macroscopic and microscopic characteristics of different rocks has received much attention in the field of rock engineering.When the rocks are subjected to thermal treatment,the change of macroscopic characteristics and evolution of micro-structure would be induced,ultimately resulting in different degrees of thermal damage in rocks.To better understand the thermal damage mechanism of different rocks and its effect on the rock performance,this study reviews a large number of test results of rock specimens experiencing heating and cooling treatment in the laboratory.Firstly,the variations of macroscopic behaviors,including physical parameters,mechanical parameters,thermal conductivity and permeability,are examined.The variations of mechanical parameters with thermal treatment variables(i.e.temperature or the number of thermal cycles)are divided into four types.Secondly,several measuring methods for microstructure,such as polarizing microscopy,fluorescent method,scanning electron microscopy(SEM),X-ray computerized tomography(CT),acoustic emission(AE)and ultrasonic technique,are introduced.Furthermore,the effect of thermal damage on the mechanical parameters of rocks in response to different thermal treatments,involving temperature magnitude,cooling method and thermal cycle,are discussed.Finally,the limitations and prospects for the research of rock thermal damage are proposed.展开更多
Electrocatalytic water splitting coupled with sustainable energies is identified as an environmentally friendly and renewable strategy to generate high-quality hydrogen for the fuel cells.However,the main challenge is...Electrocatalytic water splitting coupled with sustainable energies is identified as an environmentally friendly and renewable strategy to generate high-quality hydrogen for the fuel cells.However,the main challenge is to develop high performance,low cost and chemically stable electrocatalysts to decline the energy barriers and enhance the sluggish kinetics of hydrogen evolution reaction(HER).Herein,a three-dimensional hierarchically ordered macroporous Ru-CoP@NC electrocatalyst(3DOM Ru-CoP@NC)derived from ordered macro-microporous metal-organic frameworks has been prepared using the precursor@template and double-solvent methods.The prepared 3DOM Ru-CoP@NC catalyst exhibits an overpotential of 15 mV(j=10 mA·cm^(-2))and a reaction Tafel slope of 38 mV·dec^(-1)in alkaline electrolyte,which are superior to commercial Pt@C catalyst.Additionally,the overpotential and reaction Tafel slope of this catalyst in acidic media are 45 mV and 50 mV·dec^(-1),respectively.The outstanding HER activities of 3DOM Ru-CoP@NC catalysts are ascribed to the 3D highly interconnectedreticular nanospaces that can increase effective reaction active sites.The N dope d carbon framework improves the electronic properties and conductivity.Moreover,the strong interaction of Ru and CoP nanoparticles also boosts the HER process.These results indicate that 3DOM Ru-CoP@NC catalysts with high catalytic activities have a broad application prospect in the future.展开更多
Earthquakes may inflict varied levels of damage on mountains.Understanding the deformation properties of earthquake-damaged rock masses is critical for evaluating rocky slope stability over time.Taking the phyllite of...Earthquakes may inflict varied levels of damage on mountains.Understanding the deformation properties of earthquake-damaged rock masses is critical for evaluating rocky slope stability over time.Taking the phyllite of the Xinmo Village rockslide as the research object,the degradation features of the phyllite are investigated through laboratory tests,and a discrete-element numerical approach that fully accounts for the progressive rock deterioration is presented.The approach is then used to investigate the evolution characteristics of phyllite under various dynamic and static loading circumstances.Results show that the remaining strength of rock decreases with increasing dynamic cyclic loading(DCL)amplitude and times but increases with increasing frequency.As the dynamic damage degree increases,rock failure modes become more complex,and microcracks expand in a more preferential orientation,as well as a denser spatial distribution.Dynamic damage cracks act as the dominant paths for the macroscopic failure surface of the rock.The results indicate that the input energy and dissipated energy increase with fluctuating and linear trends with the advance of the DCL,respectively.The peak strain energy and acoustic emission(AE)magnitude decrease with increasing dynamic damage degrees,and the distribution of AE events displays temporal dispersion and spatial clustering characteristics,which is attributed to a decrease in the rock's potential for storing energy.展开更多
To obtain the precise calculation method for the peak energy density and energy evolution properties of rocks subjected to uniaxial compression(UC)before the post-peak stage,particularly at s0.9sc(s denotes stress and...To obtain the precise calculation method for the peak energy density and energy evolution properties of rocks subjected to uniaxial compression(UC)before the post-peak stage,particularly at s0.9sc(s denotes stress and sc is the peak strength),extensive UC and uniaxial graded cyclical loading-unloading(GCLU)tests were performed on four rock types.In the GCLU tests,four unloading stress levels were designated when σ<0.9σc and six unloading stress levels were designated forσ≥0.9σc.The variations in the elastic energy density(ue),dissipative energy density(ud),and energy storage efficiency(C)for the four rock types under GCLU tests were analyzed.Based on the variation of ue whenσ≥0:9σc,a method for calculating the peak energy density was proposed.The energy evolution in rock under UC condition before the post-peak stage was examined.The relationship between C0.9(C atσ≥0:9σc)and mechanical behavior of rocks was explored,and the damage evolution of rock was analyzed in view of energy.Compared with that of the three existing methods,the accuracy of the calculation method of peak energy density proposed in this study is higher.These findings could provide a theoretical foundation for more accurately revealing the failure behavior of rock from an energy perspective.展开更多
Preexisting cracks inside tight sandstones are one of the most important properties for controlling the mechanical and seepage behaviors.During the cyclic loading process,the rock generally exhibits obvious memorabili...Preexisting cracks inside tight sandstones are one of the most important properties for controlling the mechanical and seepage behaviors.During the cyclic loading process,the rock generally exhibits obvious memorability and irreversible plastic deformation,even in the linear elastic stage.The assessment of the evolution of preexisting cracks under hydrostatic pressure loading and unloading processes is helpful in understanding the mechanism of plastic deformation.In this study,ultrasonic measurements were conducted on two tight sandstone specimens with different bedding orientations subjected to hydrostatic loading and unloading processes.The P-wave velocity was characterized by a similar response with the volumetric strain to the hydrostatic pressure and showed different strain sensitivities at different loading and unloading stages.A numerical model based on the discrete element method(DEM)was proposed to quantitatively clarify the evolution of the crack distribution under different hydrostatic pressures.The numerical model was verified by comparing the evolution of the measured P-wave velocities on two anisotropic specimens.The irreversible plastic deformation that occurred during the hydrostatic unloading stage was mainly due to the permanent closure of plastic-controlled cracks.The closure and reopening of cracks with a small aspect ratio account for the major microstructure evolution during the hydrostatic loading and unloading processes.Such evolution of microcracks is highly dependent on the stress path.The anisotropy of the crack distribution plays an important role in the magnitude and strain sensitivity of the P-wave velocity under stress conditions.The study can provide insight into the microstructure evolution during cyclic loading and unloading processes.展开更多
The continued existence of high-energy radiation in nuclear reactors at high temperatures results in the formation of radiation-induced voids,which will further lead to inevitable swellings of polycrystalline structur...The continued existence of high-energy radiation in nuclear reactors at high temperatures results in the formation of radiation-induced voids,which will further lead to inevitable swellings of polycrystalline structural components and thus premature failures.A deep understanding of the effect of temperature and grain boundary on void evolution in irradiated copper is significant for preventing this kind of failures.Here,the phase-field method was employed to study void evolution in irradiated copper under different temperatures and grain sizes.The results show that,due to the different sensitivities of point defect production rate and vacancy diffusion rate to temperature changes,both the nucleation-growth rate and the coarsening rate during void evolution increase first and then decrease with increasing temperature;moreover,the nucleation mechanism exhibits site-saturated nucleation at low temperatures while continuous nucleation at high temperatures.The presence of grain boundary can accelerate the emergence of void because grain boundaries can absorb more interstitials than vacancies.The finer the grain size,the stronger inhibitory effect of grain boundaries on the growth rate of void,due to the formation of void denuded zone near grain boundaries.At high temperatures,the growth rate of void in fine grains is significantly reduced due to the increase of vacancy diffusion rate and the enhancement of sink effect of grain boundary on vacancy.展开更多
The mechanical properties of interfacial transition zones(ITZs)have traditionally been simplified by reducing the stiffness of cement in previous simulation methods.A novel approach based on the discrete element metho...The mechanical properties of interfacial transition zones(ITZs)have traditionally been simplified by reducing the stiffness of cement in previous simulation methods.A novel approach based on the discrete element method(DEM)has been developed for modeling concrete.This new approach efficiently simulates the meso-structure of ITZs,accurately capturing their heterogeneous properties.Validation against established uniaxial compression experiments confirms the precision of thismodel.The proposedmodel canmodel the process of damage evolution containing cracks initiation,propagation and penetration.Under increasing loads,cracks within ITZs progressively accumulate,culminating in macroscopic fractures that traverse themortarmatrix,forming the complex,serpentine path of cracks.This study reveals four distinct displacement patterns:tensile compliant,tensile opposite,mixed tensile-shear,and shear opposite patterns,each indicative of different stages in concrete’s damage evolution.The widening angle of these patterns delineates the progression of cracks,with the tensile compliant pattern signaling the initial crack appearance and the shear opposite pattern indicating the concrete model’s ultimate failure.展开更多
A thorough understanding of the texture evolution of near-αtitanium alloys during the hot metal forming can help obtain an optimal crystallographic texture and material performance.The strain state has an obvious eff...A thorough understanding of the texture evolution of near-αtitanium alloys during the hot metal forming can help obtain an optimal crystallographic texture and material performance.The strain state has an obvious effect on the texture evolution of near-αtitanium alloys during the hot metal forming.In this paper,the texture evolution of a near-αTA15 titanium alloy during the hot metal forming under different strain states were discussed based on the crystal plasticity finite element method.It is found that the basal and prismatic slip systems are regarded as the dominant slip modes due to the similar low critical resolved shear stress during the hot metal forming of the TA15 sheet rotating the lattice around the[1010]and 0001 axis,respectively.Once both of them cannot be activated,the pyramidal-2 slipping occurs rotating the lattice around the[1010]axis.The relationship between the texture evolution and strain state is established.All the(0001)orientations form a band perpendicular to the direction of the first principal strain.The width of the band along the direction of the second principal strain depends on the ratio of the compressive effect to the tensile effect of the second principal strain.This relationship can help control the crystallographic texture and mechanical properties of the titanium alloys component during the hot metal forming.展开更多
Based on the principle of piecewise linearization, the incremental forms of microstructure evolution models were integrated into the thermo-mechanical coupled finite element（FE） model to simulate nonlinear microstru...Based on the principle of piecewise linearization, the incremental forms of microstructure evolution models were integrated into the thermo-mechanical coupled finite element（FE） model to simulate nonlinear microstructure evolution during multi-pass hot deformation. This is an unsteady-state deformation where dynamic recrystallization（DRX）, meta-dynamic recrystallization（MDRX）, static recrystallization（SRX） and grain growth（GG） take place during hot deformation or deformation interval. The distributions of deformation and microstructure for cylindrical AZ31 sample during single-pass and double-pass hot compressions were quantitatively calculated and compared with the metallographic observation. It is shown that both the deformation and microstructure are non-uniformly distributed due to the presence of friction between the die and the flat end of sample. The average grain size and its standard deviation under the double-pass hot compression are slightly smaller than those under single-pass compression.The simulated average grain sizes agree well with the experiments, which validates that the developed FE model on the basis of incremental forms of microstructure evolution models is reasonable.展开更多
The construction of heterojunction photocatalysts for efficiently utilizing solar energy has attracted considerable attention to solve the energy crisis and reduce environmental pollution.In this study,we use the ener...The construction of heterojunction photocatalysts for efficiently utilizing solar energy has attracted considerable attention to solve the energy crisis and reduce environmental pollution.In this study,we use the energy released from an easily-occurred exothermic chemical reaction to serve as the drive force to trigger the formation of Cd S and C_(3)N_(4) nanocomposites which are successfully fabricated with cadmium nitrate and thiourea without addition of any solvents and protection of inert gas at initial temperature,a little higher than the melting point of thiourea.The as-prepared Cd S/C_(3)N_(4) materials exhibit high efficiency for photocatalytic hydrogen evolution reaction(HER)with the HER rate as high as 15,866μmol/(g·hr)under visible light irradiation(λ>420 nm),which is 89 and 9 times those of pristine C_(3)N_(4) and Cd S,respectively.Also,the apparent quantum efficiency(AQE)of Cd S/C_(3)N_(4)–1:2–200–2(Cd S/C_(3)N_(4)–1:2–200–2 means the ratio of Cd to S is 1:2 and the reaction temperature is set at 200℃ for two hours)reaches 3.25%atλ=420±15 nm.After irradiated for more than 24 hr,the HER efficiencies of Cd S/C_(3)N_(4) do not exhibit any attenuation.The DFT calculation suggests that the charge difference causes an internal electric field from C_(3)N_(4) pointing to Cd S,which can more effectively promote the transfer of photogenerated electrons from Cd S to C_(3)N_(4).Therefore,most HER should occur on C_(3)N_(4) surface where photogenerated electrons accumulate,which largely protects Cd S from photo-corrosion.展开更多
The novel (G'/G)-expansion method is a powerful and simple technique for finding exact traveling wave solutions to nonlinear evolution equations (NLEEs). In this article, we study explicit exact traveling wave sol...The novel (G'/G)-expansion method is a powerful and simple technique for finding exact traveling wave solutions to nonlinear evolution equations (NLEEs). In this article, we study explicit exact traveling wave solutions for the (1 + 1)-dimensional combined KdV-mKdV equation by using the novel (G'/G)-expansion method. Consequently, various traveling wave solutions patterns including solitary wave solutions, periodic solutions, and kinks are detected and exhibited.展开更多
文摘Sulfur-doped iron-cobalt tannate nanorods(S-FeCoTA)derived from metal-organic frameworks(MOFs)as electrocatalysts were synthesized via a one-step hydrothermal method.The optimized S-FeCoTA was interlaced by loose nanorods,which had many voids.The S-FeCoTA catalysts exhibited excellent electrochemical oxygen evolution reaction(OER)performance with a low overpotential of 273 mV at 10 mA·cm^(-2)and a small Tafel slope of 36 mV·dec^(-1)in 1 mol·L^(-1)KOH.The potential remained at 1.48 V(vs RHE)at 10 mA·cm^(-2)under continuous testing for 15 h,implying that S-FeCoTA had good stability.The Faraday efficiency of S-FeCoTA was 94%.The outstanding OER activity of S-FeCoTA is attributed to the synergistic effects among S,Fe,and Co,thus promoting electron transfer,reducing the reaction kinetic barrier,and enhancing the OER performance.
基金financial support by the National Natural Science Foundation of China(No.52102241)Doctor of Suzhou University Scientific Research Foundation(Nos.2022BSK019,2020BS015)+2 种基金the Primary Research and Development Program of Anhui Province(No.201904a05020087)the Natural Science Research Project in Universities of Anhui Province in China(Nos.2022AH051386,KJ2021A1114)the Foundation(No.GZKF202211)of State Key Laboratory of Biobased Material and Green Papermaking Qilu University of Technology。
文摘Available online Alkaline water electrolysis(AWE)is a prominent technique for obtaining a sustainable hydrogen source and effectively managing the energy infrastructure.Noble metal-based electrocatalysts,owing to their exceptional hydrogen binding energy,exhibit remarkable catalytic activity and long-term stability in the hydrogen evolution reaction(HER).However,the restricted accessibility and exorbitant cost of noble-metal materials pose obstacles to their extensive adoption in industrial contexts.This review investigates strategies aimed at reducing the dependence on noble-metal electrocatalysts and developing a cost-effective alkaline HER catalyst,while considering the principles of sustainable development.The initial discussion covers the fundamental principle of HER,followed by an overview of prevalent techniques for synthesizing catalysts based on noble metals,along with a thorough examination of recent advancements.The subsequent discussion focuses on the strategies employed to improve noble metalbased catalysts,including enhancing the intrinsic activity at active sites and increasing the quantity of active sites.Ultimately,this investigation concludes by examining the present state and future direction of research in the field of electrocatalysis for the HER.
基金the National Natural Science Foundation of China(22122113)National Key R&D Program of China(2022YFB3506200).
文摘Rare earth has a unique electronic structure and brings highly anticipated properties in light,electricity,heat and magnetism.Lanthanum is widely distributed among the rare earth elements and has a great potential for the electrocatalytic application.This paper reviews the common types and synthesis methods of lanthanum-based catalysts used in the electrocatalytic oxygen evolution reaction,and highlights the optimization of lanthanum-based catalysts.The electronic structure and active sites of the catalysts can be adjusted through atomic doping,interfacial modulation,and structural defects to enhance the OER.Further,the development of lanthanum-based catalyst is envisioned.
基金supported by the Research and Development Plan Project of China State Railway Group Co.,Ltd.(Project No.P2023X029).
文摘Purpose–As an important part of the management of railway passenger transport,the rationality and effectiveness of the clearing method of railway passenger transport are directly related to the operating efficiency and service quality of railway passenger transport enterprises.This paper aims to comprehensively and deeply discuss the evolution and development process of China’s railway passenger transport clearing method,analyze its characteristics and influences in each stage,identify the main factors affecting its evolution and development and then put forward thoughts on improving the future development of the clearing method.Design/methodology/approach–Through a detailed review of the railway passenger transport clearing methods from the planned economy period to the reform and opening up period and into the new century,the basis,mode,subject and object of clearing in different development stages are systematically compared.Findings–It comprehensively reveals the evolution of the clearing method,sorted out the characteristics and changes of the clearing method at each stage and the adaptability to the development of railway passenger transport at that time.The characteristics of the development of clearing measures for railway passenger transport in different stages and their far-reaching influence on railway passenger transport business are deeply analyzed.Originality/value–This paper summarized the factors influencing the development of China’s railway passenger transportation clearing approach evolution,including the simplified rules of clearing,enhanced the market adaptability,establishing and perfecting the incentive mechanism,strengthening the construction of informatization,etc.This paper puts forward the ways to improve the railway passenger transportation clearing future development thinking.
文摘Magnesium is distinguished by its highly anisotropic inelastic deformation involving a profuse activity of deformation twinning.Instrumented micro/nano-indentation technique has been widely applied to characterize the mechanical properties of magnesium,typically through the analysis of the indentation load-depth response,surface topography,and less commonly,the post-mortem microstructure within the bulk material.However,experimental limitations prevent the real-time observation of the evolving microstructure.To bridge this gap,we employ a recently-developed finite-strain model that couples the phase-field method and conventional crystal plasticity to simulate the evolution of the indentation-induced twin microstructure and its interaction with plastic slip in a magnesium single-crystal.Particular emphasis is placed on two aspects:orientation-dependent inelastic deformation and indentation size effects.Several outcomes of our 2D computational study are consistent with prior experimental observations.Chief among them is the intricate morphology of twin microstructure obtained at large spatial scales,which,to our knowledge,represents a level of detail that has not been captured in previous modeling studies.To further elucidate on size effects,we extend the model by incorporating gradient-enhanced crystal plasticity,and re-examine the notion of‘smaller is stronger’.The corresponding results underscore the dominant influence of gradient plasticity over the interfacial energy of twin boundaries in governing the size-dependent mechanical response.
基金supported by the National Science and Technology Major Project of China(No.J2019-VI-0004-0117)。
文摘Casting experiments and macro-micro numerical simulations were conducted to examine the microstructure characteristics of K439B nickel-based superalloy casting with varying cross-sections during the gravity investment casting process.Firstly,microstructure analysis was conducted on the casting using scanning electron microscopy(SEM)and electron backscatter diffraction(EBSD).Subsequently,calculation of the phase diagram and differential scanning calorimetry(DSC)tests were conducted to determine the macro-micro simulation parameters of the K439B alloy,and the cellular automaton finite element(CAFE)method was employed to develop macro-micro modeling of K439B nickel-based superalloy casting with varying cross-sections.The experimental results revealed that the ratio of the average grain area increased from the edge to the center of the sections as the ratio of the cross-sectional area increased.The simulation results indicated that the average grain area increased from 0.885 to 0.956 mm^(2)as the ratio of the cross-sections increased from 6꞉1 to 12꞉1.The experiment and simulation results showed that the grain size became more heterogeneous and the grain shape became more irregular with an increase in the ratio of the cross-sectional area of the casting.CAFE modeling was an effective method to simulate the microstructure evolution of the K439B alloy and ensure the accuracy of the simulation.
基金National Natural Science Foundation of China,Grant/Award Numbers:U22A20598,52104107National Key Research and Development Program of China,Grant/Award Numbers:2023YFC2907300,2019YFE0118500,2019YFC1904304Natural Science Foundation of Jiangsu Province,Grant/Award Number:BK20200634。
文摘Gas storage in abandoned mines is one way to reuse waste space resources.The surrounding rock of gas storage reservoirs in underground roadways undergoes damage and deformation under the cyclic loading of gas charging and discharging,which can pose a risk to the safety of the reservoirs.This study establishes a true triaxial numerical model of rock mass with the discrete element method(DEM)and explores the crack evolution of surrounding rock of underground gas storage during cyclic loading and unloading.Also,a damage evolution model in numerical analysis considering residual deformation is developed to explain the experimental results.As was revealed,cyclic loading and unloading resulted in fatigue damage in the specimen and caused strength deterioration of the specimen.During the loading process,the uniformly distributed force chains of the rock mass redistributed,evolving gradually to mostly transverse force chains.This contributed to the appearance of blank areas in the force chains when through cracks appear.The ratio of tensile cracks to shear cracks gradually decreases and finally stabilizes at 7:1.The damage evolution model considering residual strain can be mutually verified with the numerical simulation results.Based on the DEM model,it was found that there was a certain threshold of confining pressure.When the confining pressure exceeded 30 MPa,the deformation to ductility of sandstone samples began to accelerate,with a greater residual strength.This study provides a theoretical basis for analyzing the long-term mechanical behavior of surrounding rock of gas storage in abandoned mines.
基金the National Natural Science Foundation of China(Grant No.11472137).
文摘This paper proposed an efficient research method for high-dimensional uncertainty quantification of projectile motion in the barrel of a truck-mounted howitzer.Firstly,the dynamic model of projectile motion is established considering the flexible deformation of the barrel and the interaction between the projectile and the barrel.Subsequently,the accuracy of the dynamic model is verified based on the external ballistic projectile attitude test platform.Furthermore,the probability density evolution method(PDEM)is developed to high-dimensional uncertainty quantification of projectile motion.The engineering example highlights the results of the proposed method are consistent with the results obtained by the Monte Carlo Simulation(MCS).Finally,the influence of parameter uncertainty on the projectile disturbance at muzzle under different working conditions is analyzed.The results show that the disturbance of the pitch angular,pitch angular velocity and pitch angular of velocity decreases with the increase of launching angle,and the random parameter ranges of both the projectile and coupling model have similar influence on the disturbance of projectile angular motion at muzzle.
文摘Under the influence of the information technology revolution,the teaching method,as the way to impart teaching content or the means to realize teaching content,has undergone a process of constant evolution and transformation.This transformation is still ongoing.In order to explain this phenomenon,we establish a three-dimension analysis framework of"ECONOMIC BASE-INFORMATION TECHNOLOGY-CULTURE".All kinds of logics involved in them are closely linked,thus influencing each other.At the same time,these aspects constantly affect the historical trajectory of the evolution.Based on the above analysis framework,the paper uses the historical approach to expound the evolution path on teaching methods in China since ancient times and divides it into four stages.Combined with the practical problems and interview results,we rethink the present information teaching methods.In the end,some suggestions are put forward in order to promote the further development of education-related fields.
基金supported by the National Key Research and Development Plan(Grant No.2022YFC2905700)Natural Science Foundation of Anhui Province(Grant No.2208085ME120)Key Research and Development Plan of Anhui Province(Grant No.2022m07020001).
文摘The influence of thermal damage on macroscopic and microscopic characteristics of different rocks has received much attention in the field of rock engineering.When the rocks are subjected to thermal treatment,the change of macroscopic characteristics and evolution of micro-structure would be induced,ultimately resulting in different degrees of thermal damage in rocks.To better understand the thermal damage mechanism of different rocks and its effect on the rock performance,this study reviews a large number of test results of rock specimens experiencing heating and cooling treatment in the laboratory.Firstly,the variations of macroscopic behaviors,including physical parameters,mechanical parameters,thermal conductivity and permeability,are examined.The variations of mechanical parameters with thermal treatment variables(i.e.temperature or the number of thermal cycles)are divided into four types.Secondly,several measuring methods for microstructure,such as polarizing microscopy,fluorescent method,scanning electron microscopy(SEM),X-ray computerized tomography(CT),acoustic emission(AE)and ultrasonic technique,are introduced.Furthermore,the effect of thermal damage on the mechanical parameters of rocks in response to different thermal treatments,involving temperature magnitude,cooling method and thermal cycle,are discussed.Finally,the limitations and prospects for the research of rock thermal damage are proposed.
基金financially supported by the National Natural Science Foundation of China(Nos.U20A20237,52371218,51863005,52271205,51871065,51971068and52101245)the Scientific Research and Technology Development Program of Guangxi(Nos.AA19182014,AD 17195073,AA17202030-1,AB21220027 and 2021AB17045)+6 种基金the National Natural Science Foundation of Guangxi Province(Nos.2021GXNSFBA075057,2018GXNSFDA281051,2014GXNSFAA118401 and 2013GXNSFBA019244)the Scientific Research and Technology Development Program of Guilin(Nos.20210102-4 and 20210216-1)Guangxi Bagui Scholar FoundationGuilin Lijiang Scholar FoundationGuangxi Collaborative Innovation Centre of Structure and Property for New Energy and MaterialsGuangxi Advanced Functional Materials FoundationApplication Talents Small Highlands and Chinesisch-Deutsche Kooperationsgruppe(No.GZ1528)。
文摘Electrocatalytic water splitting coupled with sustainable energies is identified as an environmentally friendly and renewable strategy to generate high-quality hydrogen for the fuel cells.However,the main challenge is to develop high performance,low cost and chemically stable electrocatalysts to decline the energy barriers and enhance the sluggish kinetics of hydrogen evolution reaction(HER).Herein,a three-dimensional hierarchically ordered macroporous Ru-CoP@NC electrocatalyst(3DOM Ru-CoP@NC)derived from ordered macro-microporous metal-organic frameworks has been prepared using the precursor@template and double-solvent methods.The prepared 3DOM Ru-CoP@NC catalyst exhibits an overpotential of 15 mV(j=10 mA·cm^(-2))and a reaction Tafel slope of 38 mV·dec^(-1)in alkaline electrolyte,which are superior to commercial Pt@C catalyst.Additionally,the overpotential and reaction Tafel slope of this catalyst in acidic media are 45 mV and 50 mV·dec^(-1),respectively.The outstanding HER activities of 3DOM Ru-CoP@NC catalysts are ascribed to the 3D highly interconnectedreticular nanospaces that can increase effective reaction active sites.The N dope d carbon framework improves the electronic properties and conductivity.Moreover,the strong interaction of Ru and CoP nanoparticles also boosts the HER process.These results indicate that 3DOM Ru-CoP@NC catalysts with high catalytic activities have a broad application prospect in the future.
基金the financial support from the National Natural Science Foundation of China(Grant No.U22A20603)the National Key Research and Development Program of China(Grant No.2023YFC3008300).
文摘Earthquakes may inflict varied levels of damage on mountains.Understanding the deformation properties of earthquake-damaged rock masses is critical for evaluating rocky slope stability over time.Taking the phyllite of the Xinmo Village rockslide as the research object,the degradation features of the phyllite are investigated through laboratory tests,and a discrete-element numerical approach that fully accounts for the progressive rock deterioration is presented.The approach is then used to investigate the evolution characteristics of phyllite under various dynamic and static loading circumstances.Results show that the remaining strength of rock decreases with increasing dynamic cyclic loading(DCL)amplitude and times but increases with increasing frequency.As the dynamic damage degree increases,rock failure modes become more complex,and microcracks expand in a more preferential orientation,as well as a denser spatial distribution.Dynamic damage cracks act as the dominant paths for the macroscopic failure surface of the rock.The results indicate that the input energy and dissipated energy increase with fluctuating and linear trends with the advance of the DCL,respectively.The peak strain energy and acoustic emission(AE)magnitude decrease with increasing dynamic damage degrees,and the distribution of AE events displays temporal dispersion and spatial clustering characteristics,which is attributed to a decrease in the rock's potential for storing energy.
基金the National Natural Science Foundation of China(Grant Nos.52104133 and 52304227)the Postdoctoral Foundation of Henan Province(Grant No.HN2022015)are appreciated.
文摘To obtain the precise calculation method for the peak energy density and energy evolution properties of rocks subjected to uniaxial compression(UC)before the post-peak stage,particularly at s0.9sc(s denotes stress and sc is the peak strength),extensive UC and uniaxial graded cyclical loading-unloading(GCLU)tests were performed on four rock types.In the GCLU tests,four unloading stress levels were designated when σ<0.9σc and six unloading stress levels were designated forσ≥0.9σc.The variations in the elastic energy density(ue),dissipative energy density(ud),and energy storage efficiency(C)for the four rock types under GCLU tests were analyzed.Based on the variation of ue whenσ≥0:9σc,a method for calculating the peak energy density was proposed.The energy evolution in rock under UC condition before the post-peak stage was examined.The relationship between C0.9(C atσ≥0:9σc)and mechanical behavior of rocks was explored,and the damage evolution of rock was analyzed in view of energy.Compared with that of the three existing methods,the accuracy of the calculation method of peak energy density proposed in this study is higher.These findings could provide a theoretical foundation for more accurately revealing the failure behavior of rock from an energy perspective.
基金supported by the National Natural Science Foundation of China(Grant No.U2244215)the Knowledge Innovation Program of Wuhan-Basic Research(Grant No.2022010801010159)the Major Project of Inner Mongolia Science and Technology(Grant No.2021ZD0034).
文摘Preexisting cracks inside tight sandstones are one of the most important properties for controlling the mechanical and seepage behaviors.During the cyclic loading process,the rock generally exhibits obvious memorability and irreversible plastic deformation,even in the linear elastic stage.The assessment of the evolution of preexisting cracks under hydrostatic pressure loading and unloading processes is helpful in understanding the mechanism of plastic deformation.In this study,ultrasonic measurements were conducted on two tight sandstone specimens with different bedding orientations subjected to hydrostatic loading and unloading processes.The P-wave velocity was characterized by a similar response with the volumetric strain to the hydrostatic pressure and showed different strain sensitivities at different loading and unloading stages.A numerical model based on the discrete element method(DEM)was proposed to quantitatively clarify the evolution of the crack distribution under different hydrostatic pressures.The numerical model was verified by comparing the evolution of the measured P-wave velocities on two anisotropic specimens.The irreversible plastic deformation that occurred during the hydrostatic unloading stage was mainly due to the permanent closure of plastic-controlled cracks.The closure and reopening of cracks with a small aspect ratio account for the major microstructure evolution during the hydrostatic loading and unloading processes.Such evolution of microcracks is highly dependent on the stress path.The anisotropy of the crack distribution plays an important role in the magnitude and strain sensitivity of the P-wave velocity under stress conditions.The study can provide insight into the microstructure evolution during cyclic loading and unloading processes.
基金supported by the National Natural Science Foundation of China(Grants No.51871183)supported by the Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(Grant No.2020-TS-06).
文摘The continued existence of high-energy radiation in nuclear reactors at high temperatures results in the formation of radiation-induced voids,which will further lead to inevitable swellings of polycrystalline structural components and thus premature failures.A deep understanding of the effect of temperature and grain boundary on void evolution in irradiated copper is significant for preventing this kind of failures.Here,the phase-field method was employed to study void evolution in irradiated copper under different temperatures and grain sizes.The results show that,due to the different sensitivities of point defect production rate and vacancy diffusion rate to temperature changes,both the nucleation-growth rate and the coarsening rate during void evolution increase first and then decrease with increasing temperature;moreover,the nucleation mechanism exhibits site-saturated nucleation at low temperatures while continuous nucleation at high temperatures.The presence of grain boundary can accelerate the emergence of void because grain boundaries can absorb more interstitials than vacancies.The finer the grain size,the stronger inhibitory effect of grain boundaries on the growth rate of void,due to the formation of void denuded zone near grain boundaries.At high temperatures,the growth rate of void in fine grains is significantly reduced due to the increase of vacancy diffusion rate and the enhancement of sink effect of grain boundary on vacancy.
基金funded by the Research Project Supported by Shanxi Scholarship Council of China(2022-067)the Opening Project of State Key Laboratory of Explosion Science and Technology(Beijing Institute of Technology)(KFJJ22-14M).
文摘The mechanical properties of interfacial transition zones(ITZs)have traditionally been simplified by reducing the stiffness of cement in previous simulation methods.A novel approach based on the discrete element method(DEM)has been developed for modeling concrete.This new approach efficiently simulates the meso-structure of ITZs,accurately capturing their heterogeneous properties.Validation against established uniaxial compression experiments confirms the precision of thismodel.The proposedmodel canmodel the process of damage evolution containing cracks initiation,propagation and penetration.Under increasing loads,cracks within ITZs progressively accumulate,culminating in macroscopic fractures that traverse themortarmatrix,forming the complex,serpentine path of cracks.This study reveals four distinct displacement patterns:tensile compliant,tensile opposite,mixed tensile-shear,and shear opposite patterns,each indicative of different stages in concrete’s damage evolution.The widening angle of these patterns delineates the progression of cracks,with the tensile compliant pattern signaling the initial crack appearance and the shear opposite pattern indicating the concrete model’s ultimate failure.
基金financially supported by the National Natural Science Foundation of China(No.51401065).
文摘A thorough understanding of the texture evolution of near-αtitanium alloys during the hot metal forming can help obtain an optimal crystallographic texture and material performance.The strain state has an obvious effect on the texture evolution of near-αtitanium alloys during the hot metal forming.In this paper,the texture evolution of a near-αTA15 titanium alloy during the hot metal forming under different strain states were discussed based on the crystal plasticity finite element method.It is found that the basal and prismatic slip systems are regarded as the dominant slip modes due to the similar low critical resolved shear stress during the hot metal forming of the TA15 sheet rotating the lattice around the[1010]and 0001 axis,respectively.Once both of them cannot be activated,the pyramidal-2 slipping occurs rotating the lattice around the[1010]axis.The relationship between the texture evolution and strain state is established.All the(0001)orientations form a band perpendicular to the direction of the first principal strain.The width of the band along the direction of the second principal strain depends on the ratio of the compressive effect to the tensile effect of the second principal strain.This relationship can help control the crystallographic texture and mechanical properties of the titanium alloys component during the hot metal forming.
基金the funding support from the National Natural Science Foundation of China (Grant No. 51573156, 51675335)
文摘Based on the principle of piecewise linearization, the incremental forms of microstructure evolution models were integrated into the thermo-mechanical coupled finite element（FE） model to simulate nonlinear microstructure evolution during multi-pass hot deformation. This is an unsteady-state deformation where dynamic recrystallization（DRX）, meta-dynamic recrystallization（MDRX）, static recrystallization（SRX） and grain growth（GG） take place during hot deformation or deformation interval. The distributions of deformation and microstructure for cylindrical AZ31 sample during single-pass and double-pass hot compressions were quantitatively calculated and compared with the metallographic observation. It is shown that both the deformation and microstructure are non-uniformly distributed due to the presence of friction between the die and the flat end of sample. The average grain size and its standard deviation under the double-pass hot compression are slightly smaller than those under single-pass compression.The simulated average grain sizes agree well with the experiments, which validates that the developed FE model on the basis of incremental forms of microstructure evolution models is reasonable.
基金supported by National Key Research and Development Program of China(No.2016YFA0203100)the National Natural Science Foundation of China(Nos.21537004,21777169,and 21621064)the Beijing Municipal Natural Science Foundation(No.8202046)。
文摘The construction of heterojunction photocatalysts for efficiently utilizing solar energy has attracted considerable attention to solve the energy crisis and reduce environmental pollution.In this study,we use the energy released from an easily-occurred exothermic chemical reaction to serve as the drive force to trigger the formation of Cd S and C_(3)N_(4) nanocomposites which are successfully fabricated with cadmium nitrate and thiourea without addition of any solvents and protection of inert gas at initial temperature,a little higher than the melting point of thiourea.The as-prepared Cd S/C_(3)N_(4) materials exhibit high efficiency for photocatalytic hydrogen evolution reaction(HER)with the HER rate as high as 15,866μmol/(g·hr)under visible light irradiation(λ>420 nm),which is 89 and 9 times those of pristine C_(3)N_(4) and Cd S,respectively.Also,the apparent quantum efficiency(AQE)of Cd S/C_(3)N_(4)–1:2–200–2(Cd S/C_(3)N_(4)–1:2–200–2 means the ratio of Cd to S is 1:2 and the reaction temperature is set at 200℃ for two hours)reaches 3.25%atλ=420±15 nm.After irradiated for more than 24 hr,the HER efficiencies of Cd S/C_(3)N_(4) do not exhibit any attenuation.The DFT calculation suggests that the charge difference causes an internal electric field from C_(3)N_(4) pointing to Cd S,which can more effectively promote the transfer of photogenerated electrons from Cd S to C_(3)N_(4).Therefore,most HER should occur on C_(3)N_(4) surface where photogenerated electrons accumulate,which largely protects Cd S from photo-corrosion.
文摘The novel (G'/G)-expansion method is a powerful and simple technique for finding exact traveling wave solutions to nonlinear evolution equations (NLEEs). In this article, we study explicit exact traveling wave solutions for the (1 + 1)-dimensional combined KdV-mKdV equation by using the novel (G'/G)-expansion method. Consequently, various traveling wave solutions patterns including solitary wave solutions, periodic solutions, and kinks are detected and exhibited.
