A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental invest...A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental investigations were carried out by varying amount of added particles(0-2%), circulation flow rate(2.15-5.16 m^3/h) and heat flux(8-16 kW/m^2). The comparison of heat transfer performance in different vertical heights of the horizontal bed was also discussed. Results reveal that the glass bead particle can enhance heat transfer compared with vapor-liquid two-phase flow for all beds. At a low heat flux(q = 8 kW/m), the heat-transfer-enhancing factor of the horizontal bed is obviously greater than those of the up-flow and down-flow beds. With the increase in the amount of added particles, the heat-transfer-enhancing factors of the up-flow and down-flow beds increase, whereas that of the horizontal bed initially increases and then decreases. However, at a high heat flux(q=16 kW/m), the heat-transfer-enhancing factors of the three beds show an increasing tendency with the increase in the amount of added particles and become closer than those at a low heat flux. For all beds, the heat-transfer-enhancing factor generally increases with the circulation flow rate but decreases with the increase in heat flux.展开更多
In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when int...In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when integrated with the background process and how to optimize the evaporator is shown. From the case studies, it can be seen that sometimes incomplete integration and heat pump evaporation are better than complete integration so should be considered as candidate retrofit schemes.展开更多
Interfacial solar-driven evaporation technique is an environmental friendly and cost-effective advanced approach for water purification using solar energy.Free energy sources are effectively utilized using the structu...Interfacial solar-driven evaporation technique is an environmental friendly and cost-effective advanced approach for water purification using solar energy.Free energy sources are effectively utilized using the structural design of evaporators and functional materials.In this work,we have fabricated a solar-driven interfacial evaporation device with Banana Pseudo Stem(BPS)and a photothermal layer made up of PVA PDMS Carbon(PPC)is attached to it.High evaporation rate of 2.03 kg m^(−2) h^(−1) is achieved by the system under 1 sun illumination.Heat localization on interfacial surface,reflectance of photothermal layer,presence of micro-fluidic channels in BPS were studied using IR imaging,UV-DRS and SEM characterization techniques,respectively.Effective localization of interfacial temperature around 53℃ and very low reflectance of photothermal layer substantiates high photothermal conversion efficiency of the device.The complete purification of water containing high concentration of Rhodamine-B dye using BPS is a novel and simple approach for water purification.This is an eco-friendly,cost-efficient novel approach in fabrication of interfacial solar-driven evaporation system with high evaporation rate for purification of water containing high concentration of organic dye.展开更多
The use of immobilized lipase from Candida antarctica (Novozymò 435) to catalyze ferulic acid of esterification was investigated in this study. The synthesis product was analyzed using HPLC. The results revealed ...The use of immobilized lipase from Candida antarctica (Novozymò 435) to catalyze ferulic acid of esterification was investigated in this study. The synthesis product was analyzed using HPLC. The results revealed that the major product was 2-ethylhexyl ferulate. Response surface methodology and 3-level-3-factor central composite rotatable design were adopted to evaluate the effects of synthesis variables, including reaction temperature (60℃- 80℃), enzyme amount (500 - 1500 PLU) and reaction time (8 - 24 h) on the percentage molar conversion of 2-ethylhexyl ferulate. The results showed that reaction temperature and reaction time were the most important parameters on percentage molar conversion. Based on ridge max analysis, the optimum conditions for synthesis were: reaction time 23 h, reaction temperature 71℃?and enzyme amount 1422 PLU. The molar conversion of actual experimental values was 98% under optimal conditions.展开更多
By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,t...By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.展开更多
A reliable mathematical model of urea-water-solution(UWS) droplet evaporation and thermolysis is developed.The well known Abramzon–Sirignano evaporation model is corrected by introducing an adjustment coefficient con...A reliable mathematical model of urea-water-solution(UWS) droplet evaporation and thermolysis is developed.The well known Abramzon–Sirignano evaporation model is corrected by introducing an adjustment coefficient considering the different evaporation behaviors of UWS droplet at different ambient temperatures. A semidetailed kinetic scheme of urea thermolysis is developed based on Ebrahimian's work. Sequentially, the evaporation characteristics, decomposition efficiency of a single UWS droplet and deposit formation are simulated. As a result, the relation of evaporation time, relative velocity, exhaust temperature and droplet initial diameter is presented. Synchronously, it indicates that temperature is the decisive factor for urea thermolysis. Different temperatures result in different deposit components, and deposit yield is significantly influenced by temperature and decomposition time. The current work can provide guidance for designing urea injection strategy of SCR systems.展开更多
Pressing need goes ahead for accessing freshwater in insufficient supply countries and regions,which will become a restrictive factor for human development and production.In recent years,solar-driven water evaporation...Pressing need goes ahead for accessing freshwater in insufficient supply countries and regions,which will become a restrictive factor for human development and production.In recent years,solar-driven water evaporation(SDWE)systems have attracted increasing attention for their specialty in no consume conventional energy,pollution-free,and the high purity of fresh water.In particular,carbon-based photothermal conversion materials are preferred light-absorbing material for SDWE systems because of their wide range of spectrum absorption and high photothermal conversion efficiency based on superconjugate effect.Until now,many carbon-based SDWE systems have been reported,and various structures emerged and were designed to enhance light absorption,optimize heat management,and improve the efficient water transport path.In this review,we attempt to give a comprehensive summary and discussions of structure progress of the carbon-based SDWE systems and their working mechanisms,including carbon nanoparticles systems,single-layer photothermal membrane systems,bi-layer structural photothermal systems,porous carbon-based materials systems,and three dimensional(3D)systems.In these systems,the latest 3D systems can expand the light path by allowing light to be reflected multiple times in the microcavity to increase the light absorption rate,and its large heat exchange area can prompt more water to evaporate,which makes them the promising application foreground.We hope our review can spark the probing of underlying principles and inspiring design strategies of these carbonbased SDWE systems,and further guide device optimizations,eventually promoting in extensive practical applications in the future.展开更多
CrN coatings were deposited using cathodic arc evaporation in stationary system on the substrate surface faced to the plasma source and on the back surface.The effect of nitrogen pressure on the structure and phase co...CrN coatings were deposited using cathodic arc evaporation in stationary system on the substrate surface faced to the plasma source and on the back surface.The effect of nitrogen pressure on the structure and phase composition,mechanical and tribological properties of the coatings was investigated.The coating morphology and structure were characterized using SEM and contact profilometry and X-ray diffractometry,respectively.Mechanical properties were studied by nanoindentation.The friction and wear properties of the coatings were investigated by ball-on-disk tribometer.An increase in nitrogen pressure during coating deposition results in phase transformation according to the relation Cr2N→Cr2N+CrN→CrN.The roughness of the coatings deposited on the front side of the substrate is higher than that on the back side,mainly due to larger number of macroparticles.The hardness and elastic modulus are also higher on the front side of the substrate.The adhesion and wear rate of the coatings have an inverse relationship.展开更多
The huge gap between inadequate clean water supply and demanding human needs can be narrowed by sustainable and green methods of solar-driven evaporation,which effectively converts solar energy into thermal energy to ...The huge gap between inadequate clean water supply and demanding human needs can be narrowed by sustainable and green methods of solar-driven evaporation,which effectively converts solar energy into thermal energy to purify seawater and wastewater.Electrospun materials produced from a facile electrospinning technique can be combined with functional photothermal materials,giving rise to various superior advantages in solar water evaporation.However,to date,few reviews have focused on this topic.This article reviews the recent progress of electrospun nanofiber-based evaporation systems focusing on polymer selection,available solar materials,incorporation strategies of solar materials,system configurations,factors influencing the performance,and applications of electrospun nanofiber evaporation systems.The incorporation strategies of solar materials and system configurations in electrospun nanofiber evaporators are classified and systematically discussed.Finally,the challenges and perspectives of the electrospun nanofiber evaporation systems are also presented.This review updates the progress of electrospun nanofiber evaporation systems and simultaneously stimulates attractive research on designing electrospun nanofiber-based photothermal systems for applications in solar water evaporation,photothermal therapy,electricity generation,and other related areas.展开更多
Interfacial solar evaporation(ISE)is a promising technology to relieve worldwide freshwater shortages owing to its high energy conversion efficiency and environmentally sustainable potential.So far,many innovative mat...Interfacial solar evaporation(ISE)is a promising technology to relieve worldwide freshwater shortages owing to its high energy conversion efficiency and environmentally sustainable potential.So far,many innovative materials and evaporators have been proposed and applied in ISE to enable highly controllable and efficient solar-to-thermal energy conversion.With rational design,solar evaporators can achieve excellent energy management for lowering energy loss,harvesting extra energy,and efficiently utilizing energy in the system to improve freshwater production.Beyond that,a strategy of reducing water vaporization enthalpy by introducing molecular engineering for water-state regulation has also been demonstrated as an effective approach to boost ISE.Based on these,this article discusses the energy nexus in two-dimensional(2D)and three-dimensional(3D)evaporators separately and reviews the strategies for design and fabrication of highly efficient ISE systems.The summarized work offers significant perspectives for guiding the future design of ISE systems with efficient energy management,which pave pathways for practical applications.展开更多
Absorption refrigeration systems driven by low-temperature waste heat is one way to achieve“carbon neutrality.”Meanwhile,the keto-benzene dewaxing equipment needs a cooling capacity of 5 MW,with refrigeration temper...Absorption refrigeration systems driven by low-temperature waste heat is one way to achieve“carbon neutrality.”Meanwhile,the keto-benzene dewaxing equipment needs a cooling capacity of 5 MW,with refrigeration temperature of-10℃and-25℃.This paper researches the feasibility of dual-stage evaporation-ammonia hybrid compressioneabsorption refrigeration system(DSE-AHCARS)replacing the vapor compression refrigeration system for keto-benzene dewaxing process based on energy,exergy,economic,and environmental(4E)analysis.At the primary-and secondary-stage evaporation temperature of 0 and-23℃,respectively,the coefficient of performance(COP)reaches the maximum value of 0.85;however,COP-electricity reaches the minimum value of 8.1.When the secondary-stage refrigeration temperature is-23℃,CO_(2)emission increases from 1150 t·a^(-1)to 3600 t·a^(-1),and life cycle climate performance increases from 3.29×10^(4) to 7.7×10^(4) t,with the primary-stage refrigeration temperature being-15-0℃,as well as matching three parameters to ensure the 4E compromising performance by the multi-objective optimization.To guarantee that the life cycle climate performance is less than 5.5×10^(4)t,the payback period is<2 a,and COP is>0.6 at the optimal operation ranges,such that the refrigeration temperature difference between primary stage and secondary stage is within 20℃.The power of DSE-AHCARS was reduced by 77%compared with the vapor-compression refrigeration system.Therefore,the DSE-AHCARS can reduce CO_(2)emissions by about 6250 t·a^(-1)and save 1.2×10^(5)t of CO_(2)in the life cycle climate performance term.This result shows that the DSE-AHCARS can completely replace the vapor-compression refrigeration system.展开更多
With the escalation of industrialization and population growth,energy and clean water shortages pose an unprecedented threat to sustainable development.Therefore,it is imperative to develop green and effective strateg...With the escalation of industrialization and population growth,energy and clean water shortages pose an unprecedented threat to sustainable development.Therefore,it is imperative to develop green and effective strategies to address these challenges.In this context,solar-driven interfacial water evaporation(SIWE)has emerged as a highly promising low-carbon solution to the water-energy nexus[1].By locating the evaporator at airwater interfaces,heat localization can be achieved,leading to high-efficient water evaporation and freshwater production.More significantly,taking advantage of the special conditions during SIWE has opened numerous opportunities for generation of extra electrical power[2,3].Throughout the processes of SIWE,various elements such as photons,waves,capillary flow,evaporation,vapor motions,condensation,and droplet sliding can all be harnessed to produce electricity through photovoltaic,thermoelectric,thermogalvanic,pyroelectric,piezoelectric,triboelectricity and hydrovoltaic effects[3].Extensive research efforts have provided valuable insights for the development of water-electricity cogeneration(WEG)hybrid systems.展开更多
We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applic...We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applicability of the model.To produce new proton-rich Fl and Lv isotopes through hot fusion reactions in the superheavy element region with Z≥104,we utilized the reactions ^(48)Ca+^(236,238,239) Pu and ^(48)Ca+^(242,243,244,250) Cm.However,owing to the detection limit of available equipment(0.1 pb),only 283Fl and 287−289Lv,which have the maximum evaporation residue cross section values of 0.149,0.130,9.522,and 0.309 pb,respectively,can be produced.Furthermore,to produce neutron-deficient isotopes of actinides near the proton drip line with Z=93−100,we attempted to generate the new isotopes(224−227Pu,228−232,237Cm)using the reactions ^(48)Ca+180,182,183 W and ^(48)Ca+^(184,186,187,192) Os.The maximum evaporation residue cross section values are 0.07,0.06,0.26,and 0.30 nb for the former set of reactions,and 1.96 pb,5.73 pb,12.16 pb,19.39 pb,54.79 pb,and 6.45 nb for the latter,respectively.These results are expected to provide new information for the future synthesis of unknown neutron-deficient isotopes.展开更多
The predictability of pan evaporation and air temperature in the southern part of the Dead-Sea region (Sdom) was investigated according to two approaches, prediction by mesoscale models and with the aid of synoptic cl...The predictability of pan evaporation and air temperature in the southern part of the Dead-Sea region (Sdom) was investigated according to two approaches, prediction by mesoscale models and with the aid of synoptic classification. First, the predicted temperature, wind speed and relative humidity that directly affect the evaporation are obtained from the WRF mesoscale model predictions. Predictions according to multilinear regression equations and a Penman-Monteith approach were also validated against observations in Sdom. The WRF model predicts the temperature reasonably well. However, the wind speed and relative humidity predictions were found to be very poor. The unique approach in this paper is employing a semi-objective synoptic systems classification according to the global GFS model. Relationships were defined between the 19 Eastern Mediterranean’s (EM) synoptic systems and the Sdom evaporation, temperature, wind speed and relative humidity. A monthly evaluation was performed for each of the systems and the semi-objective prediction was verified by the semi-objective classification. Since some synoptic systems affect the evaporation and temperature similarly, the 19 synoptic systems were grouped into seven clusters, each containing systems with similar evaporation and temperature records. This method has yielded a significant improvement in the daily prediction of evaporation and temperature. Semi-objective definitions for the synoptic systems were performed for the ranges of 12 - 132 hours. The synoptic system approach succeeded in the prediction of the evaporation and temperature changes in Sdom for a few days in advance. The predictability skill for the 12 hour forecast achieved about 80% of success, dropping to 70% at 36 hours. For 60 to 132 hours the prediction stabilized at a skill of 60%.The method presented here is a new attempt to predict meteorological parameters by using a synoptic classification approach in the Dead-Sea area where even high-resolution mesoscale modeling forecasts are not very successful.展开更多
The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the p...The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the performance of solar energy evaporation and minimizing material degradation during application can be achieved through the design of novel photothermal materials.In solar interfacial evaporation,photothermal materials exhibit a wide range of additional characteristics,but a systematic overview is lacking.This paper encompasses an examination of various categories and principles pertaining to photothermal materials,as well as the structural design considerations for salt-resistant materials.Additionally,we discuss the versatile uses of this appealing technology in different sectors related to energy and the environment.Furthermore,potential solutions to enhance the durability of photothermal materials are also highlighted,such as the rational design of micro/nano-structures,the use of adhesives,the addition of anti-corrosion coatings,and the preparation of self-healing surfaces.The objective of this review is to offer a viable resolution for the logical creation of high-performance photothermal substances,presenting a guide for the forthcoming advancement of solar evaporation technology.展开更多
UWS （optimized Urea-Water Solution） injection system is required to increase the NH3 conversion efficiency of urea-based SCR （Selective Catalytic Reduction） system of modem automobiles. The focus of the current st...UWS （optimized Urea-Water Solution） injection system is required to increase the NH3 conversion efficiency of urea-based SCR （Selective Catalytic Reduction） system of modem automobiles. The focus of the current study is to do parametric studies by simulation in a three-dimensional model using CFD （Computational Fluid Dynamics） code AVL FIRE. Simulations were carried out to study the characteristics of evaporation and thermolysis UWS considering the effect of injection velocity, duration of injection, injection angle and for different types of injection. In the case of the injection velocities up to 20-50 m/sec, the ammonia concentration continues to increase. It is found that as the duration injection decreases, the concentration of ammonia increases. In case of continuous injection, the flow rate is less which results in lower velocity of injection, lesser atomization and slower evaporation resulting lesser conversion of UWS into NH3. Shorter duration of injection leads better atomization with increased velocity of injection which results in faster evaporation and thermolysis.展开更多
Organic-inorganic hybrid clusters with strong X-ray radioluminescence have exhibited great potential in scintillator field.However,fabricating the X-ray imaging screens of the clusters without sacrificing the scintill...Organic-inorganic hybrid clusters with strong X-ray radioluminescence have exhibited great potential in scintillator field.However,fabricating the X-ray imaging screens of the clusters without sacrificing the scintillation performance is challenging.Herein,we report an effective way to prepare high-quality scintillation films of two synthesized Cu(Ⅰ)clusters through vacuum evaporation deposition.The developed Cu(Ⅰ)clusters with rigid molecular structures show excellent scintillation performance with a high light yield of up to 19356.7 photons/MeV and a low detection limit of 158 nGy/s.The scintillation film based on the Cu(Ⅰ)clusters made by vacuum evaporation deposition is highly uniform with a small surface roughness value of 1.04 nm,which can be applied to X-ray imaging for various objects.These results not only provide important guidance to develop high-performance organic-inorganic hybrid scintillators,but also pave a straightforward way to prepare non-doped scintillation screens for remarkable X-ray imaging applications.展开更多
This review examines the processes of laser heating,melting,evaporation,fragmentation,and breakdown of metal nanoparticles,as well as the dependences and values of the threshold laser parameters that initiate these pr...This review examines the processes of laser heating,melting,evaporation,fragmentation,and breakdown of metal nanoparticles,as well as the dependences and values of the threshold laser parameters that initiate these processes.Literature results are analyzed from experimental studies of these processes with gold,silver,and other nanoparticles,including laser surface melting and evaporation of nanoparticles and Coulomb fragmentation of nanoparticles by ultrashort laser pulses.A theoretical model and description of the thermal mechanisms of mentioned processes with metal(solid)nanoparticles in a liquid(solid)medium,initiated by the action of laser pulses with the threshold fluences,are presented.Comparison of the obtained results with experimental data confirms the accuracy of the model and makes it possible to use them to evaluate the parameters of laser thermal processing of nanoparticles.Applications of the processes include the laser melting,reshaping,and fragmentation of nanoparticles,the formation of nanostructures and nanonetworks,the laser processing of nanoparticles located on substrates,and their cladding on surfaces in various laser nanotechnologies.The use of laser ignition,combustion,and incandescence of nanoparticles is discussed,as is the use of nanoparticle-triggered laser breakdown for spectroscopy.These laser processes are used in photothermal nanotechnologies,nanoenergy,laser processing of nanoparticles,nonlinear optical devices,high-temperature material science,etc.In general,this review presents a modern picture of the state of laser technology and high-temperature processes with nanoparticles and their applications,being focused on the latest publications with an emphasis on recent results from 2021-2024.展开更多
Intense evaporation in areas with loess-like sulfate saline soils has resulted in significant ecological challenges that include water shortages and soil salinization.Investigating evaporation rate in loess-like sulfa...Intense evaporation in areas with loess-like sulfate saline soils has resulted in significant ecological challenges that include water shortages and soil salinization.Investigating evaporation rate in loess-like sulfate saline soils under varying salt contents carries crucial implications for understanding regional water loss processes,predicting soil salinization advancement,and formulating effective ecological management strategies.Therefore,this study sampled the loess-like sulfate saline soil that is widely distributed in western China as experimental materials and investigated the impact of different initial salt contents(0.00%,0.50%,1.50%,3.00%,and 5.00%)on the evaporation rate,water content,and temperature of soil.The results showed that the evaporation rate decreased with increasing initial salt content.After a salt accumulation layer formed on the soil surface,the water content of the surface soil fluctuated.An increase in the initial salt content resulted in a corresponding increase in the surface temperature.Considering the evaporation characteristics of loess-like sulfate saline soil and the impact of an anomalous increase in surface soil water content on soil surface resistance,this study proposed a modified evaporation model on the basis of Fujimaki's evaporation model of saline soil by introducing a correction coefficientβto modify the soil surface resistance.A comparison of the calculated evaporation rates before and after the modification with the measured evaporation rates revealed a significant improvement in the calculation accuracy of the modified model,indicating that the modified model is capable of more accurately simulating the evaporation rate of sulfate saline soil with different initial salt contents.This paper proposes an effective method for calculating the evaporation rate of loess-like sulfate saline soils,providing a theoretical basis for evaporation research in saline soil.展开更多
The evaporation ofmicrometer and millimeter liquid drops,involving a liquid-to-vapor phase transition accompanied by mass and energy transfer through the liquid-vapor interface,is encountered in many natural and indus...The evaporation ofmicrometer and millimeter liquid drops,involving a liquid-to-vapor phase transition accompanied by mass and energy transfer through the liquid-vapor interface,is encountered in many natural and industrial processes as well as in numerous engineering applications.Therefore,understanding and predicting the dynamics of evaporating flows have become of primary importance.Recent efforts have been addressed using the method of Smoothed Particle Hydrodynamics(SPH),which has proven to be very efficient in correctly handling the intrinsic complexity introduced by the multiscale nature of the evaporation process.This paper aims to provide an overview of published work on SPH-based simulations related to the evaporation of drops suspended in static and convective environments and impacting on heated solid surfaces.After a brief theoretical account of the main ingredients necessary for the modeling of drop evaporation,the fundamental aspects of SPH are revisited along with the various existing formulations that have been implemented to address the challenges imposed by the physics of evaporating flows.In the following sections,the paper summarizes the results of SPH-based simulations of drop evaporation and ends with a few comments on the limitations of the current state-of-the-art SPHsimulations and future lines of research.展开更多
基金supported by Tianjin Municipal Science and Technology Commission, China (No. 2009ZCKFGX01900)
文摘A circulating fluidized bed evaporator(including down-flow, horizontal, and up-flow beds) was constructed to study the effect of flow directions on multiphase flow boiling heat transfer. A range of experimental investigations were carried out by varying amount of added particles(0-2%), circulation flow rate(2.15-5.16 m^3/h) and heat flux(8-16 kW/m^2). The comparison of heat transfer performance in different vertical heights of the horizontal bed was also discussed. Results reveal that the glass bead particle can enhance heat transfer compared with vapor-liquid two-phase flow for all beds. At a low heat flux(q = 8 kW/m), the heat-transfer-enhancing factor of the horizontal bed is obviously greater than those of the up-flow and down-flow beds. With the increase in the amount of added particles, the heat-transfer-enhancing factors of the up-flow and down-flow beds increase, whereas that of the horizontal bed initially increases and then decreases. However, at a high heat flux(q=16 kW/m), the heat-transfer-enhancing factors of the three beds show an increasing tendency with the increase in the amount of added particles and become closer than those at a low heat flux. For all beds, the heat-transfer-enhancing factor generally increases with the circulation flow rate but decreases with the increase in heat flux.
文摘In this paper, through two case studies, evaporation systems are considered in the context of overall process, and then are optimized to obtain energy-saving effect. The possible evaporation schemes are given when integrated with the background process and how to optimize the evaporator is shown. From the case studies, it can be seen that sometimes incomplete integration and heat pump evaporation are better than complete integration so should be considered as candidate retrofit schemes.
基金The work was supported by Department of Science and Technology,Government of India(Grant No.-“DST/TMD/CERI/RES/2020/52”)authors acknowledge the IR camera facility from the project(DST/TWF Divi-sion/AFW for EM/C/2017/121)by DST,India.
文摘Interfacial solar-driven evaporation technique is an environmental friendly and cost-effective advanced approach for water purification using solar energy.Free energy sources are effectively utilized using the structural design of evaporators and functional materials.In this work,we have fabricated a solar-driven interfacial evaporation device with Banana Pseudo Stem(BPS)and a photothermal layer made up of PVA PDMS Carbon(PPC)is attached to it.High evaporation rate of 2.03 kg m^(−2) h^(−1) is achieved by the system under 1 sun illumination.Heat localization on interfacial surface,reflectance of photothermal layer,presence of micro-fluidic channels in BPS were studied using IR imaging,UV-DRS and SEM characterization techniques,respectively.Effective localization of interfacial temperature around 53℃ and very low reflectance of photothermal layer substantiates high photothermal conversion efficiency of the device.The complete purification of water containing high concentration of Rhodamine-B dye using BPS is a novel and simple approach for water purification.This is an eco-friendly,cost-efficient novel approach in fabrication of interfacial solar-driven evaporation system with high evaporation rate for purification of water containing high concentration of organic dye.
文摘The use of immobilized lipase from Candida antarctica (Novozymò 435) to catalyze ferulic acid of esterification was investigated in this study. The synthesis product was analyzed using HPLC. The results revealed that the major product was 2-ethylhexyl ferulate. Response surface methodology and 3-level-3-factor central composite rotatable design were adopted to evaluate the effects of synthesis variables, including reaction temperature (60℃- 80℃), enzyme amount (500 - 1500 PLU) and reaction time (8 - 24 h) on the percentage molar conversion of 2-ethylhexyl ferulate. The results showed that reaction temperature and reaction time were the most important parameters on percentage molar conversion. Based on ridge max analysis, the optimum conditions for synthesis were: reaction time 23 h, reaction temperature 71℃?and enzyme amount 1422 PLU. The molar conversion of actual experimental values was 98% under optimal conditions.
基金financially supported by the Science and Technology Innovation Program of Hunan Province(2024RC3003)the Central South University Innovation-Driven Research Programme(2023CXQD012)the Initiative for Sustainable Energy for its financial support。
文摘By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.
基金Supported by the National High Technology Research and Development Program of China(2013AA065301)the Fundamental Research Funds for the Central Universities(2016QNA4014)the State Key Laboratory of Clean Energy Utilization at Zhejiang University(ZJUCEU2016006)
文摘A reliable mathematical model of urea-water-solution(UWS) droplet evaporation and thermolysis is developed.The well known Abramzon–Sirignano evaporation model is corrected by introducing an adjustment coefficient considering the different evaporation behaviors of UWS droplet at different ambient temperatures. A semidetailed kinetic scheme of urea thermolysis is developed based on Ebrahimian's work. Sequentially, the evaporation characteristics, decomposition efficiency of a single UWS droplet and deposit formation are simulated. As a result, the relation of evaporation time, relative velocity, exhaust temperature and droplet initial diameter is presented. Synchronously, it indicates that temperature is the decisive factor for urea thermolysis. Different temperatures result in different deposit components, and deposit yield is significantly influenced by temperature and decomposition time. The current work can provide guidance for designing urea injection strategy of SCR systems.
基金the National Key R&D Program of China(2018YFA0209500)the National Natural Science Foundation of China(21621091 and 21975209)the Fundamental Research Funds for the Central Universities(20720190037)。
文摘Pressing need goes ahead for accessing freshwater in insufficient supply countries and regions,which will become a restrictive factor for human development and production.In recent years,solar-driven water evaporation(SDWE)systems have attracted increasing attention for their specialty in no consume conventional energy,pollution-free,and the high purity of fresh water.In particular,carbon-based photothermal conversion materials are preferred light-absorbing material for SDWE systems because of their wide range of spectrum absorption and high photothermal conversion efficiency based on superconjugate effect.Until now,many carbon-based SDWE systems have been reported,and various structures emerged and were designed to enhance light absorption,optimize heat management,and improve the efficient water transport path.In this review,we attempt to give a comprehensive summary and discussions of structure progress of the carbon-based SDWE systems and their working mechanisms,including carbon nanoparticles systems,single-layer photothermal membrane systems,bi-layer structural photothermal systems,porous carbon-based materials systems,and three dimensional(3D)systems.In these systems,the latest 3D systems can expand the light path by allowing light to be reflected multiple times in the microcavity to increase the light absorption rate,and its large heat exchange area can prompt more water to evaporate,which makes them the promising application foreground.We hope our review can spark the probing of underlying principles and inspiring design strategies of these carbonbased SDWE systems,and further guide device optimizations,eventually promoting in extensive practical applications in the future.
文摘CrN coatings were deposited using cathodic arc evaporation in stationary system on the substrate surface faced to the plasma source and on the back surface.The effect of nitrogen pressure on the structure and phase composition,mechanical and tribological properties of the coatings was investigated.The coating morphology and structure were characterized using SEM and contact profilometry and X-ray diffractometry,respectively.Mechanical properties were studied by nanoindentation.The friction and wear properties of the coatings were investigated by ball-on-disk tribometer.An increase in nitrogen pressure during coating deposition results in phase transformation according to the relation Cr2N→Cr2N+CrN→CrN.The roughness of the coatings deposited on the front side of the substrate is higher than that on the back side,mainly due to larger number of macroparticles.The hardness and elastic modulus are also higher on the front side of the substrate.The adhesion and wear rate of the coatings have an inverse relationship.
基金Jianghui Zhao acknowledges financial support from the Anhui Polytechnic UniversityA research grant from the Ministry of Higher Education Malaysia for Fundamental Research Grant Scheme with Project Code:FRGS/1/2019/TK02/USM/02/1 is gratefully acknowledged.
文摘The huge gap between inadequate clean water supply and demanding human needs can be narrowed by sustainable and green methods of solar-driven evaporation,which effectively converts solar energy into thermal energy to purify seawater and wastewater.Electrospun materials produced from a facile electrospinning technique can be combined with functional photothermal materials,giving rise to various superior advantages in solar water evaporation.However,to date,few reviews have focused on this topic.This article reviews the recent progress of electrospun nanofiber-based evaporation systems focusing on polymer selection,available solar materials,incorporation strategies of solar materials,system configurations,factors influencing the performance,and applications of electrospun nanofiber evaporation systems.The incorporation strategies of solar materials and system configurations in electrospun nanofiber evaporators are classified and systematically discussed.Finally,the challenges and perspectives of the electrospun nanofiber evaporation systems are also presented.This review updates the progress of electrospun nanofiber evaporation systems and simultaneously stimulates attractive research on designing electrospun nanofiber-based photothermal systems for applications in solar water evaporation,photothermal therapy,electricity generation,and other related areas.
基金Authors acknowledge the support of the National Natural Science Foundation of China(Nos.52125201 and 21975141)the National Key Basic Research and Development Program(No.2020YFA0210702)+1 种基金Shenzhen Science and Technology Research Project(No.JCYJ20180508152903208)Australian Research Council(Nos.FT190100485 and DP220100583).
文摘Interfacial solar evaporation(ISE)is a promising technology to relieve worldwide freshwater shortages owing to its high energy conversion efficiency and environmentally sustainable potential.So far,many innovative materials and evaporators have been proposed and applied in ISE to enable highly controllable and efficient solar-to-thermal energy conversion.With rational design,solar evaporators can achieve excellent energy management for lowering energy loss,harvesting extra energy,and efficiently utilizing energy in the system to improve freshwater production.Beyond that,a strategy of reducing water vaporization enthalpy by introducing molecular engineering for water-state regulation has also been demonstrated as an effective approach to boost ISE.Based on these,this article discusses the energy nexus in two-dimensional(2D)and three-dimensional(3D)evaporators separately and reviews the strategies for design and fabrication of highly efficient ISE systems.The summarized work offers significant perspectives for guiding the future design of ISE systems with efficient energy management,which pave pathways for practical applications.
文摘Absorption refrigeration systems driven by low-temperature waste heat is one way to achieve“carbon neutrality.”Meanwhile,the keto-benzene dewaxing equipment needs a cooling capacity of 5 MW,with refrigeration temperature of-10℃and-25℃.This paper researches the feasibility of dual-stage evaporation-ammonia hybrid compressioneabsorption refrigeration system(DSE-AHCARS)replacing the vapor compression refrigeration system for keto-benzene dewaxing process based on energy,exergy,economic,and environmental(4E)analysis.At the primary-and secondary-stage evaporation temperature of 0 and-23℃,respectively,the coefficient of performance(COP)reaches the maximum value of 0.85;however,COP-electricity reaches the minimum value of 8.1.When the secondary-stage refrigeration temperature is-23℃,CO_(2)emission increases from 1150 t·a^(-1)to 3600 t·a^(-1),and life cycle climate performance increases from 3.29×10^(4) to 7.7×10^(4) t,with the primary-stage refrigeration temperature being-15-0℃,as well as matching three parameters to ensure the 4E compromising performance by the multi-objective optimization.To guarantee that the life cycle climate performance is less than 5.5×10^(4)t,the payback period is<2 a,and COP is>0.6 at the optimal operation ranges,such that the refrigeration temperature difference between primary stage and secondary stage is within 20℃.The power of DSE-AHCARS was reduced by 77%compared with the vapor-compression refrigeration system.Therefore,the DSE-AHCARS can reduce CO_(2)emissions by about 6250 t·a^(-1)and save 1.2×10^(5)t of CO_(2)in the life cycle climate performance term.This result shows that the DSE-AHCARS can completely replace the vapor-compression refrigeration system.
文摘With the escalation of industrialization and population growth,energy and clean water shortages pose an unprecedented threat to sustainable development.Therefore,it is imperative to develop green and effective strategies to address these challenges.In this context,solar-driven interfacial water evaporation(SIWE)has emerged as a highly promising low-carbon solution to the water-energy nexus[1].By locating the evaporator at airwater interfaces,heat localization can be achieved,leading to high-efficient water evaporation and freshwater production.More significantly,taking advantage of the special conditions during SIWE has opened numerous opportunities for generation of extra electrical power[2,3].Throughout the processes of SIWE,various elements such as photons,waves,capillary flow,evaporation,vapor motions,condensation,and droplet sliding can all be harnessed to produce electricity through photovoltaic,thermoelectric,thermogalvanic,pyroelectric,piezoelectric,triboelectricity and hydrovoltaic effects[3].Extensive research efforts have provided valuable insights for the development of water-electricity cogeneration(WEG)hybrid systems.
基金National Natural Science Foundation of China(Nos.12175064 and U2167203)Hunan Outstanding Youth Science Foundation(No.2022JJ10031).
文摘We systematically studied the evaporation residue cross sections of ^(48)Ca-induced reactions on lanthanide and actinide target nuclei under the Dinuclear System(DNS)model framework to check the reliability and applicability of the model.To produce new proton-rich Fl and Lv isotopes through hot fusion reactions in the superheavy element region with Z≥104,we utilized the reactions ^(48)Ca+^(236,238,239) Pu and ^(48)Ca+^(242,243,244,250) Cm.However,owing to the detection limit of available equipment(0.1 pb),only 283Fl and 287−289Lv,which have the maximum evaporation residue cross section values of 0.149,0.130,9.522,and 0.309 pb,respectively,can be produced.Furthermore,to produce neutron-deficient isotopes of actinides near the proton drip line with Z=93−100,we attempted to generate the new isotopes(224−227Pu,228−232,237Cm)using the reactions ^(48)Ca+180,182,183 W and ^(48)Ca+^(184,186,187,192) Os.The maximum evaporation residue cross section values are 0.07,0.06,0.26,and 0.30 nb for the former set of reactions,and 1.96 pb,5.73 pb,12.16 pb,19.39 pb,54.79 pb,and 6.45 nb for the latter,respectively.These results are expected to provide new information for the future synthesis of unknown neutron-deficient isotopes.
文摘The predictability of pan evaporation and air temperature in the southern part of the Dead-Sea region (Sdom) was investigated according to two approaches, prediction by mesoscale models and with the aid of synoptic classification. First, the predicted temperature, wind speed and relative humidity that directly affect the evaporation are obtained from the WRF mesoscale model predictions. Predictions according to multilinear regression equations and a Penman-Monteith approach were also validated against observations in Sdom. The WRF model predicts the temperature reasonably well. However, the wind speed and relative humidity predictions were found to be very poor. The unique approach in this paper is employing a semi-objective synoptic systems classification according to the global GFS model. Relationships were defined between the 19 Eastern Mediterranean’s (EM) synoptic systems and the Sdom evaporation, temperature, wind speed and relative humidity. A monthly evaluation was performed for each of the systems and the semi-objective prediction was verified by the semi-objective classification. Since some synoptic systems affect the evaporation and temperature similarly, the 19 synoptic systems were grouped into seven clusters, each containing systems with similar evaporation and temperature records. This method has yielded a significant improvement in the daily prediction of evaporation and temperature. Semi-objective definitions for the synoptic systems were performed for the ranges of 12 - 132 hours. The synoptic system approach succeeded in the prediction of the evaporation and temperature changes in Sdom for a few days in advance. The predictability skill for the 12 hour forecast achieved about 80% of success, dropping to 70% at 36 hours. For 60 to 132 hours the prediction stabilized at a skill of 60%.The method presented here is a new attempt to predict meteorological parameters by using a synoptic classification approach in the Dead-Sea area where even high-resolution mesoscale modeling forecasts are not very successful.
基金supported by Zhejiang Provincial Natural Science Foundation of China(No.LR23C160001)Scientific Research Startup Foundation of Zhejiang Ocean University(No.11034150220006).
文摘The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the performance of solar energy evaporation and minimizing material degradation during application can be achieved through the design of novel photothermal materials.In solar interfacial evaporation,photothermal materials exhibit a wide range of additional characteristics,but a systematic overview is lacking.This paper encompasses an examination of various categories and principles pertaining to photothermal materials,as well as the structural design considerations for salt-resistant materials.Additionally,we discuss the versatile uses of this appealing technology in different sectors related to energy and the environment.Furthermore,potential solutions to enhance the durability of photothermal materials are also highlighted,such as the rational design of micro/nano-structures,the use of adhesives,the addition of anti-corrosion coatings,and the preparation of self-healing surfaces.The objective of this review is to offer a viable resolution for the logical creation of high-performance photothermal substances,presenting a guide for the forthcoming advancement of solar evaporation technology.
文摘UWS （optimized Urea-Water Solution） injection system is required to increase the NH3 conversion efficiency of urea-based SCR （Selective Catalytic Reduction） system of modem automobiles. The focus of the current study is to do parametric studies by simulation in a three-dimensional model using CFD （Computational Fluid Dynamics） code AVL FIRE. Simulations were carried out to study the characteristics of evaporation and thermolysis UWS considering the effect of injection velocity, duration of injection, injection angle and for different types of injection. In the case of the injection velocities up to 20-50 m/sec, the ammonia concentration continues to increase. It is found that as the duration injection decreases, the concentration of ammonia increases. In case of continuous injection, the flow rate is less which results in lower velocity of injection, lesser atomization and slower evaporation resulting lesser conversion of UWS into NH3. Shorter duration of injection leads better atomization with increased velocity of injection which results in faster evaporation and thermolysis.
文摘Organic-inorganic hybrid clusters with strong X-ray radioluminescence have exhibited great potential in scintillator field.However,fabricating the X-ray imaging screens of the clusters without sacrificing the scintillation performance is challenging.Herein,we report an effective way to prepare high-quality scintillation films of two synthesized Cu(Ⅰ)clusters through vacuum evaporation deposition.The developed Cu(Ⅰ)clusters with rigid molecular structures show excellent scintillation performance with a high light yield of up to 19356.7 photons/MeV and a low detection limit of 158 nGy/s.The scintillation film based on the Cu(Ⅰ)clusters made by vacuum evaporation deposition is highly uniform with a small surface roughness value of 1.04 nm,which can be applied to X-ray imaging for various objects.These results not only provide important guidance to develop high-performance organic-inorganic hybrid scintillators,but also pave a straightforward way to prepare non-doped scintillation screens for remarkable X-ray imaging applications.
文摘This review examines the processes of laser heating,melting,evaporation,fragmentation,and breakdown of metal nanoparticles,as well as the dependences and values of the threshold laser parameters that initiate these processes.Literature results are analyzed from experimental studies of these processes with gold,silver,and other nanoparticles,including laser surface melting and evaporation of nanoparticles and Coulomb fragmentation of nanoparticles by ultrashort laser pulses.A theoretical model and description of the thermal mechanisms of mentioned processes with metal(solid)nanoparticles in a liquid(solid)medium,initiated by the action of laser pulses with the threshold fluences,are presented.Comparison of the obtained results with experimental data confirms the accuracy of the model and makes it possible to use them to evaluate the parameters of laser thermal processing of nanoparticles.Applications of the processes include the laser melting,reshaping,and fragmentation of nanoparticles,the formation of nanostructures and nanonetworks,the laser processing of nanoparticles located on substrates,and their cladding on surfaces in various laser nanotechnologies.The use of laser ignition,combustion,and incandescence of nanoparticles is discussed,as is the use of nanoparticle-triggered laser breakdown for spectroscopy.These laser processes are used in photothermal nanotechnologies,nanoenergy,laser processing of nanoparticles,nonlinear optical devices,high-temperature material science,etc.In general,this review presents a modern picture of the state of laser technology and high-temperature processes with nanoparticles and their applications,being focused on the latest publications with an emphasis on recent results from 2021-2024.
基金supported by the National Natural Science Foundation of China(51769013,52168052)。
文摘Intense evaporation in areas with loess-like sulfate saline soils has resulted in significant ecological challenges that include water shortages and soil salinization.Investigating evaporation rate in loess-like sulfate saline soils under varying salt contents carries crucial implications for understanding regional water loss processes,predicting soil salinization advancement,and formulating effective ecological management strategies.Therefore,this study sampled the loess-like sulfate saline soil that is widely distributed in western China as experimental materials and investigated the impact of different initial salt contents(0.00%,0.50%,1.50%,3.00%,and 5.00%)on the evaporation rate,water content,and temperature of soil.The results showed that the evaporation rate decreased with increasing initial salt content.After a salt accumulation layer formed on the soil surface,the water content of the surface soil fluctuated.An increase in the initial salt content resulted in a corresponding increase in the surface temperature.Considering the evaporation characteristics of loess-like sulfate saline soil and the impact of an anomalous increase in surface soil water content on soil surface resistance,this study proposed a modified evaporation model on the basis of Fujimaki's evaporation model of saline soil by introducing a correction coefficientβto modify the soil surface resistance.A comparison of the calculated evaporation rates before and after the modification with the measured evaporation rates revealed a significant improvement in the calculation accuracy of the modified model,indicating that the modified model is capable of more accurately simulating the evaporation rate of sulfate saline soil with different initial salt contents.This paper proposes an effective method for calculating the evaporation rate of loess-like sulfate saline soils,providing a theoretical basis for evaporation research in saline soil.
文摘The evaporation ofmicrometer and millimeter liquid drops,involving a liquid-to-vapor phase transition accompanied by mass and energy transfer through the liquid-vapor interface,is encountered in many natural and industrial processes as well as in numerous engineering applications.Therefore,understanding and predicting the dynamics of evaporating flows have become of primary importance.Recent efforts have been addressed using the method of Smoothed Particle Hydrodynamics(SPH),which has proven to be very efficient in correctly handling the intrinsic complexity introduced by the multiscale nature of the evaporation process.This paper aims to provide an overview of published work on SPH-based simulations related to the evaporation of drops suspended in static and convective environments and impacting on heated solid surfaces.After a brief theoretical account of the main ingredients necessary for the modeling of drop evaporation,the fundamental aspects of SPH are revisited along with the various existing formulations that have been implemented to address the challenges imposed by the physics of evaporating flows.In the following sections,the paper summarizes the results of SPH-based simulations of drop evaporation and ends with a few comments on the limitations of the current state-of-the-art SPHsimulations and future lines of research.
