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A note on asymptotic behavior of Galton-Watson branching processes in random environments 被引量:2
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作者 王汉兴 赵飞 卢金余 《Journal of Shanghai University(English Edition)》 CAS 2006年第2期95-99,共5页
In this paper, we investigate Galton-Watson branching processes in random environments. In the case where the environmental process is a Markov chain which is positive recurrent or has a transition matrix Q (θ,α) su... In this paper, we investigate Galton-Watson branching processes in random environments. In the case where the environmental process is a Markov chain which is positive recurrent or has a transition matrix Q (θ,α) such that sup_θ Q (θ,α)> 0 for some α, we prove that the model has the asymptotic behavior being similar to that of Galton-Watson branching processes. In other case where the environments are non-stationary independent, the sufficient conditions are obtained for certain extinction and uncertain extinction for the model. 展开更多
关键词 branching processes random environmental processes extinction probabilities
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THE CONSTRUCTION OF DENUMERABLE q-PROCESSES IN RANDOM ENVIRONMENTS-THE EXISTENCE AND UNIQUENESS 被引量:3
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作者 胡迪鹤 胡晓予 《Acta Mathematica Scientia》 SCIE CSCD 2008年第2期225-235,共11页
The concepts of Markov process in random environment, q-matrix in random environment, and q-process in random environment are introduced. The minimal q-process in random environment is constructed and the necessary an... The concepts of Markov process in random environment, q-matrix in random environment, and q-process in random environment are introduced. The minimal q-process in random environment is constructed and the necessary and sufficient conditions for the uniqueness of q-process in random environment are given. 展开更多
关键词 Markov process in random environment q-matrix in random environment q-process in random environment
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LIMIT THEOREMS FOR A GALTON-WATSON PROCESS IN THE I.I.D. RANDOM ENVIRONMENT 被引量:2
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作者 高振龙 胡晓予 《Acta Mathematica Scientia》 SCIE CSCD 2012年第3期1193-1205,共13页
In this article, we obtain the central limit theorem and the law of the iterated logarithm for Galton-Watson processes in i.i.d, random environments.
关键词 Galton-Watson process in random environment central limit theorem law of the iterated logarithm
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THE ERGODICITY FOR BI-IMMIGRATION BIRTH AND DEATH PROCESSES IN RANDOM ENVIRONMENT 被引量:1
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作者 Hu Dihe Zhang Shuli 《Acta Mathematica Scientia》 SCIE CSCD 2008年第1期43-53,共11页
The concepts of bi-immigration birth and death density matrix in random environment and bi-immigration birth and death process in random environment are introduced.For any bi-immigration birth and death matrix in rand... The concepts of bi-immigration birth and death density matrix in random environment and bi-immigration birth and death process in random environment are introduced.For any bi-immigration birth and death matrix in random environment Q(θ)with birth rateλ〈death rateμ,the following results are proved,(1)there is an unique q-process in random environment,P^-(θ*(0);t)=(p^-(θ^*(0);t,i,j),i,j≥0),which is ergodic,that is,lim t→∞(θ^*(0);t,i,j)=π^-(θ^*(0);j)≥0 does not depend on i≥0 and∑j≥0π(θ*(0);j)=1,(2)there is a bi-immigration birth and death process in random enjvironment(X^*={X^*,t≥0},ε^*={εt,t∈(-∞,∞)})with random transition matrix P^-(θ^*(0);t)such that X^*is a strictly stationary process. 展开更多
关键词 Density matrix in random environment random transition matrix Markov process in random environment bi-immigration birth and death density matrix in random environment bi-immigration birth and death process in random environment
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THE CONSTRUCTION OF DENUMERABLE q-PROCESSES IN RANDOM ENVIRONMENTS SATISFYING (F) OR (B) 被引量:2
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作者 胡迪鹤 胡晓予 《Acta Mathematica Scientia》 SCIE CSCD 2008年第4期975-988,共14页
This article is a continuation of[9].Based on the discussion of random Kolmogorov forward(backward)equations,for any given q-matrix in random environment, Q(θ)=(q(θ;x,y),x,y∈X),an infinite class of q-proces... This article is a continuation of[9].Based on the discussion of random Kolmogorov forward(backward)equations,for any given q-matrix in random environment, Q(θ)=(q(θ;x,y),x,y∈X),an infinite class of q-processes in random environments satisfying the random Kolmogorov forward(backward)equation is constructed.Moreover, under some conditions,all the q-processes in random environments satisfying the random Kolmogorov forward(backward)equation are constructed. 展开更多
关键词 Markov process in random environment q-matrix in random environment q-process in random environment
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Manufacturing Process Oriented Environmental Friendly Assessment with Fuzzy Analytic Hierarchy Process and Fuzzy Technique for Order Preference by Similarity to Ideal Solution 被引量:1
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作者 LI Zhongkai HOU Kunfeng HE Chuntian 《Journal of Donghua University(English Edition)》 EI CAS 2018年第3期202-206,共5页
Green manufacturing is a mode to realize environmental friendliness by considering the environmental impact and energy consumption in manufacturing process.In order to make an environmental friendly assessment for man... Green manufacturing is a mode to realize environmental friendliness by considering the environmental impact and energy consumption in manufacturing process.In order to make an environmental friendly assessment for manufacturing process,a multi-criteria decision making( MCDM) model combined with fuzzy analytic hierarchy process( FAHP) and fuzzy technique for order preference by similarity to ideal solution( FTOPSIS) is proposed in this work.The environmental and resource criteria and manufacturing process objects are identified as the first step.Then,the weights of the criteria are calculated by FAHP.Finally,based on experts' evaluation using fuzzy words,the manufacturing process objects are ranked by FTOPSIS.The proposed methodology is applied to a gear shaft manufacturing.The sensitivity analysis and comparisons are implemented to prove its robustness and effectiveness for the ecofriendly assessment for process objects. 展开更多
关键词 multi-criteria decision making(MCDM) fuzzy evaluation environmental impact assessment manufacturing process
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The Metallogenetic Processes and Environment of a Large Ag-V Deposit in Black Rock Series
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作者 LIU Yuanjun JIN Guanfu +2 位作者 XIE Fapeng YANG Zhenqiang CHEN Kaixu 《资源环境与工程》 2016年第B04期116-118,共3页
Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the ... Located in Western Hubei Province,this deposit is a large-scale Ag-V ore deposit,listed among the fifth type of silver deposit in China.1 Geological Characteristics It lies in the NE sector of the Yangtze flat of the Yangtze paraplatform.There are sporadically magmatic rocks and fold basement made up of upper Archaeozoicmiddle and lower Proterozoic strata.The sedimentary cover consists of Sinian-lower Paleozoic marine sediments,Mesozoic-Cenozoic intercalated marine and nonmarine sediments or nonmarine sediments. 展开更多
关键词 The Metallogenetic processes and environment of a Large Ag-V Deposit in Black Rock Series AG
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The Design of a Graphical User Environment for Numerical Simulation of Powder Forming Processes
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作者 A R Khoei S Keshavarz 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 2002年第S1期-,共2页
As computer simulation increasingly supports engine er ing design and manufacture, the requirement for a computer software environment providing an integration platform for computational engineering software increas e... As computer simulation increasingly supports engine er ing design and manufacture, the requirement for a computer software environment providing an integration platform for computational engineering software increas es. A key component of an integrated environment is the use of computational eng ineering to assist and support solutions for complex design. Computer methods fo r structural, flow and thermal analysis are well developed and have been used in design for many years. Many software packages are now available which provi de an advanced capability. However, they are not designed for modelling of powde r forming processes. This paper describes the powder compaction software (PCS_SU T), which is designed for pre- and post-processing for computational simulatio n of the process compaction of powder. In the PCS_SUT software, the adaptive analysis of transient metal powder forming process is simulated by the finite element method based on deformation theories . The error estimates and adaptive remeshing schemes are applied for updated co -ordinate analysis. A generalized Newmark scheme is used for the time domain di scretization and the final nonlinear equations are solved by a Newton-Raphson p rocedure. An incremental elasto-plastic material model is used to simulate the compaction process. To describe the constitutive model of nonlinear behaviour of powder materials, a combination of Mohr-Coulomb and elliptical yield cap model is applied. This model reflects the yielding, frictional and densification char acteristics of powder along with strain and geometrical hardening which occurs d uring the compaction process. A hardening rule is used to define the dependence of the yield surface on the degree of plastic straining. A plasticity theory for friction is employed in the treatment of the powder-tooling interface. The inv olvement of two different materials, which have contact and relative movement in relation to each other, must be considered. A special formulation for friction modelling is coupled with a material formulation. The interface behaviour betwee n the die and the powder is modelled by using an interface element mesh. In the present paper, we have demonstrated pre- and post-processor finite elem ent software, written in Visual Basic, to generate the graphical model and visua lly display the computed results. The software consist of three main part: · Pre-processor: It is used to create the model, generate an app ropriate finite element grid, apply the appropriate boundary conditions, and vie w the total model. The geometric model can be used to associate the mesh with th e physical attributes such as element properties, material properties, or loads and boundary conditions. · Analysis: It can deal with two-dimensional and axi-symmetric applications for linear and non-linear behaviour of material in static and dyna mic analyses. Both triangular and quadrilateral elements are available in the e lement library, including 3-noded, 6-noded and 7-noded (T6B1) triangles and 4 -noded, 8-noded and 9-noded quadrilaterals. The direct implicit algorithm bas ed on the generalized Newmark scheme is used for the time integration and an aut omatic time step control facility is provided. For non-linear iteration, choice s among fully or modified Newton-Raphson method and quasi-Newton method, using the initial stiffness method, Davidon inverse method or BFGS inverse method, ar e possible. · Post-processor: It provides visualization of the computed resu lts, when the finite element model and analysis have been completed. Post-proce ssing is vital to allow the appropriate interpretation of the completed results of the finite element analysis. It provides the visual means to interpret the va st amounts of computed results generated. Finally, the powder behaviour during the compaction of a multi-level component is numerically simulated by the PCS_SUT software, as shown in Fig.1. The predict ive compaction forces at different displacements are computed and compared with the available experimental 展开更多
关键词 The Design of a Graphical User environment for Numerical Simulation of Powder Forming processes
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Review and Reflection on the Development Process of Soil Environmental Quality Standards in China
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作者 Li Haiyang Zhang Xiaoran Zhang Huanzhen 《Meteorological and Environmental Research》 CAS 2019年第6期50-53,共4页
In this paper,the development process of the construction of soil environmental quality standards in China is reviewed,and the construction situation of soil environmental quality standards in typical developed countr... In this paper,the development process of the construction of soil environmental quality standards in China is reviewed,and the construction situation of soil environmental quality standards in typical developed countries is introduced.According to characteristics of soil environment and practice of soil environment management in China,the relevant suggestions are discussed,thereby further perfecting construction work of soil environmental quality standards in China. 展开更多
关键词 SOIL environmentAL quality STANDARDS Development process SUGGESTION
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REGIONAL CHARACTERISTICS OF ENVIRONMENTAL CAPACITY FOR HEAVY METALS IN SIEROZEM ZONE AND ITS RELATION TO PHYSICALGEOGRAPHIC PROCESSES
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作者 Xu Jialin Yang Jurong Xu hongning(Institute of Environmental Sciences,Bejing Normal University, Bejing 100875People’s Republic of China) 《Journal of Geographical Sciences》 SCIE CSCD 1994年第Z1期146-155,共10页
Soil environmental capacity is defined as the maximumpermitted load of the pollutant in a cettain soil environmental unitwithin a certain temporal period. With that load, the criteria canbe maintained, production and ... Soil environmental capacity is defined as the maximumpermitted load of the pollutant in a cettain soil environmental unitwithin a certain temporal period. With that load, the criteria canbe maintained, production and quality of crops can be gqaranteed.Regional soil capacity is the function of physical geographiccharacteristics. In determining capacity of sierozem, key stepsinclude: (1) establishing the criteria on comprehensive basis, (2)calculating the permitted input with the application of the capacitymodel. Dynamic capacity of Cd, Cu, As and Pb for sierozem isreported and compared with that of phaiozem and red 1oam.According to the results, it is obvious that regional differentiationin capacity is distinct and the distribution pattern of permittedload is closely related to the spacial variation of physicalgeographic processes. 展开更多
关键词 geographic process soil environment sierozem environmental capacity
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基于成分分析的马铃薯淀粉工艺废水农田利用环境风险研究
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作者 赵博超 王雪婷 +1 位作者 周添红 潘涔轩 《环境保护科学》 2026年第1期161-166,共6页
研究不同地区马铃薯淀粉工艺废水中重金属、盐分、养分元素等成分的含量,并从废水还田的土壤重金属积累、盐碱化两方面进行对标分析,评估废水农田利用环境风险。文章分别在陕西省定边县(SD)、甘肃省安定区(GA)、宁夏回族自治区固原市(NG... 研究不同地区马铃薯淀粉工艺废水中重金属、盐分、养分元素等成分的含量,并从废水还田的土壤重金属积累、盐碱化两方面进行对标分析,评估废水农田利用环境风险。文章分别在陕西省定边县(SD)、甘肃省安定区(GA)、宁夏回族自治区固原市(NG)、河北省张家口市(HZ)、黑龙江省九三(HJ)马铃薯原淀粉加工主要产区选择一家代表性企业采集马铃薯原淀粉加工废水样品,检测废水的养分、重金属含量、主要盐分离子等成分含量。结果表明,工艺废水中主要可检出的重金属为砷,部分地区还检出镉、汞,但各项检出值均符合《农田灌溉水质标准》(GB 5084—2021)要求。废水中阳离子以K^(+)为主,浓度在1 120~3 000 mg/L,占常见阳离子(K^(+)、Ca^(2+)、Na^(+)、Mg^(2+))的90%以上;阴离子主要为Cl^(-)、SO_(4)^(2-),Cl^(-)浓度在106~300 mg/L,SO_(4)^(2-)浓度在311~474 mg/L,已检出的阴阳离子浓度合计大于1 800 mg/L,属于微咸水。各区马铃薯淀粉工艺废水中全氮浓度为1.59~2.52 g/L,全磷浓度为0.22~0.43 g/L,全钾浓度为1.12~3.00 g/L,总养分含量为4.68~6.09 g/L,各区域在全氮、全钾、全磷及总养分含量方面存在显著差异。研究显示,马铃薯淀粉工艺废水是一种无重金属毒害的具有一定肥效的弱酸性微咸废水,可以将其作为“水肥”进行适当利用,但施用过程中应科学确定施用量及施用方法,并重点关注废水施用后土壤盐分变化及对作物的影响,以避免环境污染和农田破坏的风险。 展开更多
关键词 马铃薯淀粉工艺废水 养分 盐分 重金属 环境风险
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多目标海洋环境预报技术发展趋势和启示
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作者 李毅能 朱宇航 +9 位作者 彭世球 陈植武 韦惺 李骏旻 李少钿 谢培炜 廖嘉文 龚延昆 唐世林 蔡树群 《中国科学院院刊》 北大核心 2026年第1期107-119,共13页
随着“海洋强国”战略的稳步推进,以及全球海洋活动的不断拓展,海洋环境安全保障已成为国家的重大战略需求。深海的温度、盐度、声速,以及海浪、内孤立波、近岸裂流等环境信息,对航行安全和水下装备的运用有着至关重要的影响。传统的单... 随着“海洋强国”战略的稳步推进,以及全球海洋活动的不断拓展,海洋环境安全保障已成为国家的重大战略需求。深海的温度、盐度、声速,以及海浪、内孤立波、近岸裂流等环境信息,对航行安全和水下装备的运用有着至关重要的影响。传统的单一要素预报模式,已难以满足多目标环境保障的需求。为此,发展一套涵盖基础海洋要素预报(温盐流场),以及特定过程灾害预警(拍岸浪、裂流、内孤立波等)的多目标、高分辨率预报技术体系,成为必然的发展趋势。近年来,人工智能技术的迅猛发展及其与传统数值模拟、数据同化技术的深度交叉融合,正在成为推动该领域技术革新的新范式。文章系统地梳理了多目标海洋预报技术的发展脉络与前沿动态,总结了国内外的进展情况,剖析了核心挑战,并从观测网络、预报模式和学科融合等维度提出了发展启示,旨在为构建自主可控、世界领先的新一代海洋环境安全保障体系提供参考。 展开更多
关键词 多目标预报技术 特定过程预警 水下环境信息 海洋环境安全保障
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杭州湾地区SE3孔全新世沉积物敏感粒度端元分析方法研究
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作者 周学谦 林春明 +3 位作者 王军 张霞 李绪龙 赵雨潇 《古地理学报》 北大核心 2026年第1期398-411,共14页
本研究以杭州湾地区SE3孔全新世沉积物为研究对象,采用基本端元模型算法、非参数估计分解算法和粒级-标准偏差法对粒度数据进行分析,旨在探讨研究区沉积物粒度端元的组成特征、垂向演化规律及其与物源和沉积环境演化的耦合关系。结果表... 本研究以杭州湾地区SE3孔全新世沉积物为研究对象,采用基本端元模型算法、非参数估计分解算法和粒级-标准偏差法对粒度数据进行分析,旨在探讨研究区沉积物粒度端元的组成特征、垂向演化规律及其与物源和沉积环境演化的耦合关系。结果表明3种粒度端元分析方法具有良好的结果一致性,但基本端元模型算法效果更好。研究层段共识别出5个粒度端元:EM1(黏土和粉砂)、EM2(粗粉砂和极粗粉砂)、EM3(极细砂和细砂)、EM4(细砂和中砂)和EM5(中砂和粗砂)。各粒度端元的垂向展布规律受控于海平面、沉积环境和动力过程演变。粗粒的EM5和EM4端元为推移质,主要由钱塘江提供,分布在河床、河漫滩和古河口湾沉积单元内;且随着海平面上升,代表近源的EM5端元含量逐渐减少,而代表相对远源的EM4端元含量逐渐升高。细粒的粒度端元EM2和EM1端元为悬移质,主要来自长江,分布在近岸浅海和现代河口湾沉积单元;此时海平面较高,来自长江的沉积物可通过沿岸流和潮流搬运至钱塘江下切河谷内。EM3为推移质,分选好、粒度曲线呈正态分布,主要分布在现代河口湾沉积单元内,可能代表潮汐流和风暴潮搬运和筛选的沉积物。该研究揭示了沉积物敏感粒度端元分析在重建河口区海平面变化、环境演变以及源汇过程中的科学价值。 展开更多
关键词 全新世 杭州湾 粒度端元 源汇过程 环境演变
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高碱度钢铁工业废水降硬工艺优化
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作者 杨蕊 宋江锋 周瑞莎 《精细化工中间体》 2026年第1期68-76,共9页
钢铁工业废水的核心问题在于钙、镁等成垢离子在循环过程中不断富集,沉淀软化法是钢铁工业废水除硬的常用方法。系统评估了单一化学药剂(NaOH、Na_(2)CO_(3)、Ca(OH)_(2))及复合药剂方案(Ca(OH)_(2)+NaOH、NaOH+Na_(2)CO_(3))对高碱度... 钢铁工业废水的核心问题在于钙、镁等成垢离子在循环过程中不断富集,沉淀软化法是钢铁工业废水除硬的常用方法。系统评估了单一化学药剂(NaOH、Na_(2)CO_(3)、Ca(OH)_(2))及复合药剂方案(Ca(OH)_(2)+NaOH、NaOH+Na_(2)CO_(3))对高碱度钢铁工业废水硬度去除的研究。研究结果表明,Ca(OH)_(2)+NaOH复合药剂方案的处理效果最为显著,其除硬效率优于传统双碱法(NaOH+Na_(2)CO_(3))方案及各单一药剂。当投加量为Ca(OH)_(2)350 mg/L、NaOH 300 mg/L时,总硬度、钙硬度及镁硬度的去除率分别可达95.49%、94.79%与96.05%,且除硬后的电导率明显低于传统双碱法,有效降低了二次加药引起的高盐特征。通过扫描电镜-能谱(SEM-EDS)与X射线衍射(XRD)对沉淀产物进行了表征,结果显示其主要成分为方解石与氢氧化镁,具备资源化潜力。此外,对高浓度SO_(4)^(2-)反渗透浓水的验证实验显示,在Ca(OH)_(2)2 g/L与NaOH 1 g/L的投加条件下,总硬度、钙硬度和镁硬度去除率分别达到98%、96%和99%,表明SO_(4)^(2-)对除硬效果影响不显著。该研究为高碱度钢铁工业废水除硬及沉淀产物的资源化利用提供了数据支撑。 展开更多
关键词 废水处理 环保 工艺优化 钙镁离子
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Study on the Ecological Construction in the Process of Urbanization——A Case Study of Ecological Protection Green Belt Design for Shanghai A20 Out Ring (Changning Section) 被引量:2
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作者 屠苏莉 《Journal of Landscape Research》 2009年第5期57-61,共5页
With the further development of urbanization,the conflicts between human beings and the nature has been gradually aggravated;it is urgent to establish balanced natural ecology in the process of urbanization,and harmon... With the further development of urbanization,the conflicts between human beings and the nature has been gradually aggravated;it is urgent to establish balanced natural ecology in the process of urbanization,and harmony between human beings and environment.This study took the ecological landscape project of Shanghai A20 Out Ring (Changning Section) for an example to research and rethink about the ecological construction in the process of urbanization. 展开更多
关键词 URBANIZATION process environmental DESTRUCTION ECOLOGICAL construction HARMONIOUS COEXISTENCE
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厚壁聚乙烯管热熔焊接力学性能影响机制建模与仿真研究
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作者 王振超 项爱民 +4 位作者 刘乐 徐璐 尤启江 郄继春 张秋菊 《中国塑料》 北大核心 2026年第2期61-69,共9页
基于聚合物分子结晶动力学理论及分子链蠕动模型,揭示了高密度聚乙烯(HDPE)管热熔焊接的微观作用机理,并确立了焊接界面温度场时空演化规律为决定焊接力学性能的核心作用机制。将焊接界面温度场简化为二维传热模型,构建了焊接过程关键... 基于聚合物分子结晶动力学理论及分子链蠕动模型,揭示了高密度聚乙烯(HDPE)管热熔焊接的微观作用机理,并确立了焊接界面温度场时空演化规律为决定焊接力学性能的核心作用机制。将焊接界面温度场简化为二维传热模型,构建了焊接过程关键影响因素与温度场分布之间的定量关系模型。采用热工仿真软件,通过控制变量法系统研究了环境温度、风速及热源撤除时间等关键变量对热熔焊接界面温度场峰值温度和最低温度的定量影响规律。研究并提出了焊接界面作用力在温度场形成过程中的主导作用机制,同时揭示了熔体最高温度与界面最低温度之间的非线性耦合效应。此外,研究还发现了厚壁管温度场在动态演化过程中受环境因素影响而产生的温度梯度奇异现象。为厚壁聚乙烯管焊接工艺参数和环境因子优化提供了重要的理论支撑。 展开更多
关键词 聚乙烯管 热熔焊接 影响机制 工艺参数 环境因子 建模 仿真
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水质自动监测数据审核中异常数据判定及处理研究
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作者 穆珮华 刘书弟 《科技创新与应用》 2026年第4期164-167,共4页
该文以某水库监测系统为案例,系统梳理水质监测中常见的异常数据成因,涵盖仪器故障、设备老化、采样误差和网络中断等因素;进而建立涵盖预判、审核、佐证、复核的多层级异常数据审核流程,并提出包括标准溶液核查、复测加标、实验室比对... 该文以某水库监测系统为案例,系统梳理水质监测中常见的异常数据成因,涵盖仪器故障、设备老化、采样误差和网络中断等因素;进而建立涵盖预判、审核、佐证、复核的多层级异常数据审核流程,并提出包括标准溶液核查、复测加标、实验室比对等多项技术核实手段。通过完善审核标准与操作规程,提升了数据筛查与处置的规范化与高效性,为保障水质数据的真实、准确、完整提供切实路径。 展开更多
关键词 水质自动监测 异常数据审核 在线监测系统 数据核实流程 环境管理
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微塑料在环境中的影响及处理技术研究进展
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作者 刘云 刘敏 +1 位作者 金启 祝小燕 《山东化工》 2026年第3期139-143,187,共6页
人类对塑料制品的需求高居不下,微塑料带来的威胁层出不穷。解决微塑料危机,需要对其在环境当中的研究现状有全面的认知。本文对水体、土壤、大气三类环境中微塑料的来源、影响以及现有处理技术进行系统整理和评述,并对未来研究方向进... 人类对塑料制品的需求高居不下,微塑料带来的威胁层出不穷。解决微塑料危机,需要对其在环境当中的研究现状有全面的认知。本文对水体、土壤、大气三类环境中微塑料的来源、影响以及现有处理技术进行系统整理和评述,并对未来研究方向进行展望。 展开更多
关键词 微塑料 环境污染 处理技术
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环境友好型铝合金阳极氧化膜层封闭技术:Li、Ce、Mn盐体系工艺研究进展
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作者 李体军 任寿伟 +3 位作者 王健 温泉 王志高 李驰 《材料保护》 2026年第2期13-27,共15页
针对铝合金阳极氧化膜传统重金属封闭体系的环境风险,亟需系统解析环境友好型封闭技术的反应机理与耐蚀机制。通过综述铝合金阳极氧化膜层制备工艺及多孔结构特性,剖析了传统封闭(热水/铬盐/镍盐)的技术局限;进而聚焦Li、Ce、Mn 3类环... 针对铝合金阳极氧化膜传统重金属封闭体系的环境风险,亟需系统解析环境友好型封闭技术的反应机理与耐蚀机制。通过综述铝合金阳极氧化膜层制备工艺及多孔结构特性,剖析了传统封闭(热水/铬盐/镍盐)的技术局限;进而聚焦Li、Ce、Mn 3类环保体系,从封闭反应路径、产物化学特性、耐蚀机制及自修复功能等多个维度展开讨论。Li盐体系存在pH值调控封闭行为,酸性条件下生成LiAlO_(2),碱性条件下形成LiAl-LDH(层状双氢氧化合物),其耐蚀性源于物理屏障以及层间离子交换反应;Ce盐体系凸显其Ce^(3+)/Ce^(4+)价态间的转变赋予的动态自修复能力,耐蚀机制依靠水解产物协同物理封堵与化学钝化效应;锰盐体系通过构建Mn^(2+)-Mn^(4+)-Mn^(7+)之间的多价态循环,模拟了铬酸盐的钝化机制。该循环所产生的氧化还原作用能够在材料表面损伤区被重新触发,从而驱动活性组分的再沉积与再钝化。基于所揭示的Li/Ce/Mn体系的构效关系与机制差异,为无铬封闭技术的设计提供理论框架,并指明通过价态调控与多机制耦合提升环境适应性是未来核心方向。 展开更多
关键词 腐蚀防护 铝合金阳极氧化 膜层 封闭 工艺环境友好
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黄芩质量评价体系局限与道地性形成关键因素探析
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作者 赵楷 孟祥才 《长春中医药大学学报》 2026年第3期367-372,共6页
黄芩是我国临床常用的大宗道地药材,黄酮类化合物为其核心活性成分。然而,由于产地、种质及加工方式存在差异,导致有效成分含量波动显著,进而影响临床疗效。本文指出现行以黄芩苷含量为核心的质量评价体系存在局限,并提出优化评价指标... 黄芩是我国临床常用的大宗道地药材,黄酮类化合物为其核心活性成分。然而,由于产地、种质及加工方式存在差异,导致有效成分含量波动显著,进而影响临床疗效。本文指出现行以黄芩苷含量为核心的质量评价体系存在局限,并提出优化评价指标与技术手段的建议;进一步从遗传、环境、生产加工维度阐明道地黄芩质量形成的关键因素,同时补充道地性分子机制及市场流通管控等方面的内容。可为道地黄芩规范化种植与质量提升提供支撑,从而保障临床用药的安全性与有效性。 展开更多
关键词 黄芩 道地药材 质量评价 种质资源 环境调控 采收加工
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