Emerald mineralization from the Bahutiya and Gurabanda areas of Jharkhand in the eastern part of India is a recent discovery.In this deposit,emerald mineralization occurs along the contact zone between pegmatite and e...Emerald mineralization from the Bahutiya and Gurabanda areas of Jharkhand in the eastern part of India is a recent discovery.In this deposit,emerald mineralization occurs along the contact zone between pegmatite and epidiorite-hornblende schist of the Dhanjori Group(2.1-2.9 Ga).Host rock petrographic characteristics,along with the spatial distribution of the emerald,suggest a metasomatic origin for the emerald mineralization in the study area.The well-developed emerald crystals are found along the S_(2)schistosity plane,suggesting lithological and structural control on the mineralization.Electron microprobe data of the emerald indicates that the green hue is primarily due to the variable chromium content and Be could have been derived from the soda-granite of the Singhbhum Shear Zone.The average Cr_(2)O_(3)and Cr concentration in the emerald is 0.038 wt%and 0.003 apfu,respectively.The ternary diagrams FeO-MgO-Cr_(2)O_(3)and FeO-Cr_(2)O_(3)-V_(2)O_(5)are plotted and superimposed on global emerald data,compiled from the literature,which shows the similarity of this deposit to other emerald deposits of the world.From the present study,it is inferred that the emerald deposits of Bahutiya and Gurabanda,Jharkhand,belong to the Type-IA category.展开更多
Emerald is a green(Cr-bearing)variety of beryl.It has also been one of the highest value and highly demanded gemstones in the world.For this reason,the methods for synthesis emerald(i.e.,hydrothermal,flux grown)have b...Emerald is a green(Cr-bearing)variety of beryl.It has also been one of the highest value and highly demanded gemstones in the world.For this reason,the methods for synthesis emerald(i.e.,hydrothermal,flux grown)have been constantly developed.In many cases,it is hard to distinguish the natural emerald from the synthetic one using the basic instruments.Therefore,with the advantage of non-destructive technique,the infrared spectroscopy has been efficiently applied for the task.In this study,to find the potential technique in FTIR spectroscopy for classifying between natural and synthetic emerald(hydrothermal and flux-grown),the observed spectra from the Attenuated Total Reflectance Radiation(ATR),Diffuse Reflectance(DRIFT),transflectance,and specular reflection techniques were compared.The result showed that the spectra obtained from the transflectance and the DRIFT techniques were similar with equal spectral qualities.Unlike the diffuse reflectance spectra,the transflectance spectra were not affected by the sample orientations.The spectral features associated with water molecule in the crystal structure were clearly observed in both the DRIFT and transflectance spectra.Although the spectral features associated with weak absorption bands of water were not observed in both the DRIFT and transflectance spectra,the position of strong absorption band at 3 800-3 500 cm^(-1) and 1 635 cm^(-1) could be detected in the ATR spectra.In addition,the lack of absorption of water between 4 000 and 3 400 cm^(-1) in flux-grown emerald samples is the clue to separate it from the natural and hydrothermal one.In the meantime,the absence of the strong absorption peaks between 2 300 and 1 400 cm^(-1) in hydrothermal emerald can differentiate it from the natural one.展开更多
Well-formed crystals of emerald, Be3AI2Si6O18:Cr, were easily grown from an Na2O-MoO3 flux by an isothermal technique. The crystal growth was conducted by heating a mixture of solute and flux at 1 100 ℃ for 24 h. The...Well-formed crystals of emerald, Be3AI2Si6O18:Cr, were easily grown from an Na2O-MoO3 flux by an isothermal technique. The crystal growth was conducted by heating a mixture of solute and flux at 1 100 ℃ for 24 h. The evaporation loss of flux depended on the amount of Na2O added to MoO3. Emerald crystals of lengths up to 2.1 mm and widths of 1. 4 mm were grown. The crystal sizes were dependent on the evaporation loss of the flux. The obtained crystals were transparent and exhibited the typical emerald-green color. The form of the emerald crystals was a twelve-sided prism bounded by well-developed faces. The aspect ratios were in the region of 1. 4 to 2. 3. The density was (2. 64±0.02) g/cm3. The IR absorption bands were in good agreement with the literature data.展开更多
Um Solimate emerald deposit is a unique example for the well-known beryl-related schist type.Where,the Be-mineralization is restricted to NNE-trending quartz veins/lenses and as disseminated emerald grains within the ...Um Solimate emerald deposit is a unique example for the well-known beryl-related schist type.Where,the Be-mineralization is restricted to NNE-trending quartz veins/lenses and as disseminated emerald grains within the altered-metasomatic zones of phlogopite-and graphite-schists.The study of fluid inclusions for the mineralized quartz vein revealed three major groups:(i)aqueous(H_(2)O-NaCl),(ii)aqueous-carbonic(H_(2)O-CO_(2)-[CH_(4)]-NaCl),and(iii)aqueous-hydrocarbonic(H_(2)O-CH_(4))FIs.They have been further classified into five types(namely:types 1,2,3,4 and 5)according to number of phases at the room temperature(20℃)as well as microthermometric measurements.Based upon the study of fluid inclusions,the initial-ore forming fluid was supposed to be of magmatic nature,characterized by a relatively high temperature of homogenization(T_(h,tot):269–485℃)and higher salinity(8.4 wt.%–9.6 wt.%NaCl equiv.),followed by development of aqueous-carbonic inclusions at lower temperature(T_(h,tot):241–355℃)and lower salinity(3.3 wt.%–4.9 wt.%NaCl equiv.)through metamorphic dehydration/decarbonation.Methane-rich FIs were suggested to be formed as a result of local re-equilibration of graphite in reduced environment at the contact aureole of the felsic intrusion.The P-T conditions of ore formation were estimated as modal temperature between(330–370℃)and fluid pressures of about 200 MPa,corresponding to an estimated depth ranges from 7 to 10 km.The formation of emerald is closely associated with multiple events through the ore evolution,the deposition is ascribed to destabilization process of continuous metasomatic interactions and elemental substitutions between felsic-derived Be-bearing fluids with the adjacent mafic-ultramafic rocks at the zone of mineralization.展开更多
Rising global temperatures are significantly affecting species distributions worldwide.Properly assessing the threat of invasive species in the context of global warming is crucial.In this study,we quantitatively asse...Rising global temperatures are significantly affecting species distributions worldwide.Properly assessing the threat of invasive species in the context of global warming is crucial.In this study,we quantitatively assessed the potential threat of emerald ash borer(EAB)against global ash tree species(Fraxinus)under multiple future climate scenarios based on the premise of niche conservatism.Through a multidimensional comparison of overlapping distribution areas and niches forecasted by species distribution modeling,we observed that rising temperatures lead to significant shifts in the habitat ranges of both EABs and Fraxinus species,often resulting in increased overlap of both their suitable habitats and niches.These results indicate that global warming,across most climate scenarios,exacerbates the threat of biological invasions by EABs in all main distribution regions.This study highlights the critical importance of considering both invasive species and their potential hosts in predictive modeling.Additionally,our results establish a well theoretical foundation for future research and management strategies aimed at protecting vulnerable ecosystems form the expanding of invasive species.展开更多
基金financial support to setup “DST-FIST Level-Ⅱ Facility” [No. SR/ FST/ESII-014/2012(C)] at the Department of Applied Geology (AGL), IIT(ISM) Dhanbad, India
文摘Emerald mineralization from the Bahutiya and Gurabanda areas of Jharkhand in the eastern part of India is a recent discovery.In this deposit,emerald mineralization occurs along the contact zone between pegmatite and epidiorite-hornblende schist of the Dhanjori Group(2.1-2.9 Ga).Host rock petrographic characteristics,along with the spatial distribution of the emerald,suggest a metasomatic origin for the emerald mineralization in the study area.The well-developed emerald crystals are found along the S_(2)schistosity plane,suggesting lithological and structural control on the mineralization.Electron microprobe data of the emerald indicates that the green hue is primarily due to the variable chromium content and Be could have been derived from the soda-granite of the Singhbhum Shear Zone.The average Cr_(2)O_(3)and Cr concentration in the emerald is 0.038 wt%and 0.003 apfu,respectively.The ternary diagrams FeO-MgO-Cr_(2)O_(3)and FeO-Cr_(2)O_(3)-V_(2)O_(5)are plotted and superimposed on global emerald data,compiled from the literature,which shows the similarity of this deposit to other emerald deposits of the world.From the present study,it is inferred that the emerald deposits of Bahutiya and Gurabanda,Jharkhand,belong to the Type-IA category.
文摘Emerald is a green(Cr-bearing)variety of beryl.It has also been one of the highest value and highly demanded gemstones in the world.For this reason,the methods for synthesis emerald(i.e.,hydrothermal,flux grown)have been constantly developed.In many cases,it is hard to distinguish the natural emerald from the synthetic one using the basic instruments.Therefore,with the advantage of non-destructive technique,the infrared spectroscopy has been efficiently applied for the task.In this study,to find the potential technique in FTIR spectroscopy for classifying between natural and synthetic emerald(hydrothermal and flux-grown),the observed spectra from the Attenuated Total Reflectance Radiation(ATR),Diffuse Reflectance(DRIFT),transflectance,and specular reflection techniques were compared.The result showed that the spectra obtained from the transflectance and the DRIFT techniques were similar with equal spectral qualities.Unlike the diffuse reflectance spectra,the transflectance spectra were not affected by the sample orientations.The spectral features associated with water molecule in the crystal structure were clearly observed in both the DRIFT and transflectance spectra.Although the spectral features associated with weak absorption bands of water were not observed in both the DRIFT and transflectance spectra,the position of strong absorption band at 3 800-3 500 cm^(-1) and 1 635 cm^(-1) could be detected in the ATR spectra.In addition,the lack of absorption of water between 4 000 and 3 400 cm^(-1) in flux-grown emerald samples is the clue to separate it from the natural and hydrothermal one.In the meantime,the absence of the strong absorption peaks between 2 300 and 1 400 cm^(-1) in hydrothermal emerald can differentiate it from the natural one.
文摘Well-formed crystals of emerald, Be3AI2Si6O18:Cr, were easily grown from an Na2O-MoO3 flux by an isothermal technique. The crystal growth was conducted by heating a mixture of solute and flux at 1 100 ℃ for 24 h. The evaporation loss of flux depended on the amount of Na2O added to MoO3. Emerald crystals of lengths up to 2.1 mm and widths of 1. 4 mm were grown. The crystal sizes were dependent on the evaporation loss of the flux. The obtained crystals were transparent and exhibited the typical emerald-green color. The form of the emerald crystals was a twelve-sided prism bounded by well-developed faces. The aspect ratios were in the region of 1. 4 to 2. 3. The density was (2. 64±0.02) g/cm3. The IR absorption bands were in good agreement with the literature data.
文摘Um Solimate emerald deposit is a unique example for the well-known beryl-related schist type.Where,the Be-mineralization is restricted to NNE-trending quartz veins/lenses and as disseminated emerald grains within the altered-metasomatic zones of phlogopite-and graphite-schists.The study of fluid inclusions for the mineralized quartz vein revealed three major groups:(i)aqueous(H_(2)O-NaCl),(ii)aqueous-carbonic(H_(2)O-CO_(2)-[CH_(4)]-NaCl),and(iii)aqueous-hydrocarbonic(H_(2)O-CH_(4))FIs.They have been further classified into five types(namely:types 1,2,3,4 and 5)according to number of phases at the room temperature(20℃)as well as microthermometric measurements.Based upon the study of fluid inclusions,the initial-ore forming fluid was supposed to be of magmatic nature,characterized by a relatively high temperature of homogenization(T_(h,tot):269–485℃)and higher salinity(8.4 wt.%–9.6 wt.%NaCl equiv.),followed by development of aqueous-carbonic inclusions at lower temperature(T_(h,tot):241–355℃)and lower salinity(3.3 wt.%–4.9 wt.%NaCl equiv.)through metamorphic dehydration/decarbonation.Methane-rich FIs were suggested to be formed as a result of local re-equilibration of graphite in reduced environment at the contact aureole of the felsic intrusion.The P-T conditions of ore formation were estimated as modal temperature between(330–370℃)and fluid pressures of about 200 MPa,corresponding to an estimated depth ranges from 7 to 10 km.The formation of emerald is closely associated with multiple events through the ore evolution,the deposition is ascribed to destabilization process of continuous metasomatic interactions and elemental substitutions between felsic-derived Be-bearing fluids with the adjacent mafic-ultramafic rocks at the zone of mineralization.
基金Science and Technology Basic Resources Investigation Program of China(Grant No.2021FY100200)。
文摘Rising global temperatures are significantly affecting species distributions worldwide.Properly assessing the threat of invasive species in the context of global warming is crucial.In this study,we quantitatively assessed the potential threat of emerald ash borer(EAB)against global ash tree species(Fraxinus)under multiple future climate scenarios based on the premise of niche conservatism.Through a multidimensional comparison of overlapping distribution areas and niches forecasted by species distribution modeling,we observed that rising temperatures lead to significant shifts in the habitat ranges of both EABs and Fraxinus species,often resulting in increased overlap of both their suitable habitats and niches.These results indicate that global warming,across most climate scenarios,exacerbates the threat of biological invasions by EABs in all main distribution regions.This study highlights the critical importance of considering both invasive species and their potential hosts in predictive modeling.Additionally,our results establish a well theoretical foundation for future research and management strategies aimed at protecting vulnerable ecosystems form the expanding of invasive species.
