As lithium-ion batteries(LIBs)continue to evolve toward lower costs and higher energy densities,their potential safety risks have become increasingly apparent.Incidents such as explosions at energy storage facilities,...As lithium-ion batteries(LIBs)continue to evolve toward lower costs and higher energy densities,their potential safety risks have become increasingly apparent.Incidents such as explosions at energy storage facilities,fires in electric vehicles,and building fires ignited by charging two-wheeled vehicles have been occurring with alarming frequency,often resulting in significant casualties and injuries.Conducting indepth investigations into thermal runaway(TR)incidents in LIBs can significantly reduce the risk of future occurrences.However,current investigations into LIB fire and explosion incidents face challenges due to the difficulty of conducting in-depth analyses and the lack of a robust theoretical framework to guide these investigations.To enhance the effectiveness of in-depth investigations into battery fire and explosion incidents and to address the lack of theoretical guidance,this paper is the first to systematically examine the conservation and flow patterns of elements during the TR process of LIBs.The analysis reveals that during TR,the gas products generated include approximately 1.5 g of H_(2),23.6 g of CO,88.4 g of CO_(2),8.9 g of C_(2)H_(4),7.3 g of CH_(4),3.7 g of C_(2)H_(6),and 82 g of electrolyte vapor.After TR,the solid compounds formed consist of approximately 2.5 g of LiF,29–92.2 g of elemental Ni/Co/Mn,11.4 g of Li_(2)CO_(3),200.6 g of graphite,1.4 g of NiO,29.6 g of MnO,30.1 g of CoO,67 g of elemental Cu,0.03 g of LiNiO_(2),and 4.3 g of LiAlO_(2).Importantly,the energy released from reactions forming solid compounds during TR surpasses that from gas-forming reactions.This investigation represents the first application of Hess’s law to verify the conservation of elements during the TR process of lithium-ion batteries.The proposed methodology is also applicable to other types of energy storage batteries,effectively advancing techniques for comprehensively investigating lithium battery fire and explosion incidents.展开更多
In the production and life of ancient Chinese folk artists,through the abstract and geometric arrangement of things,they formed many meaningful patterns.These patterns are widely used in a variety of decorations,refle...In the production and life of ancient Chinese folk artists,through the abstract and geometric arrangement of things,they formed many meaningful patterns.These patterns are widely used in a variety of decorations,reflecting the most simple artistic ideas in the life of the working people,and are also an important embodiment of folk art aesthetics.Many elements of folk patterns have been preserved to this day,and they have an important role in inspiring and guiding today’s art design.This paper mainly analyzes the folk pattern elements and their artistic value,and elaborates on the application of folk pattern elements in architectural design and the specific design methods,to provide certain references for the combination of modern architectural design and traditional folk patterns.展开更多
On the basis of the in situ data of DO2, pH, SiO2. PO4-P, NO3-N and NO2-N collected in the north of the East China Sea during 1987-1988, the following points are mainly expounded.1.The inorgonic nutrients are obviousl...On the basis of the in situ data of DO2, pH, SiO2. PO4-P, NO3-N and NO2-N collected in the north of the East China Sea during 1987-1988, the following points are mainly expounded.1.The inorgonic nutrients are obviously affected by continent runoff in the north of the East China Sea. Their distributions are characteristic of its distribution of terrigenous materials.2.There are three transport paths of nutrients from the shelf to the Kuroshio area. The first is mixing-diffusing-advec-tion and upwelling process, the process of biology and biochemistry belongs to the second, and the sinking process is the last one.3.The swing of the Kuroshio axis affectes both the range of the migration of substances through mixing-diffusing-advec-tion process and the upwelling degree of the subsurface Kuroshio water to the shelf.4.Most part of the substances sink as macroparticles to the deep layer before reaching the Kuroshio area.展开更多
To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for c...To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for content, and analyzed. Coal in northwestern China is characterized by low to extremely low levels of sulfur; the coal of the Taiyuan Formation in northern China mainly has high-sulfur content; that of the Shanxi Formation is mainly characterized by low sulfur coal; and the Late Permian coal in southern China has overall higher sulfur content; other regions have low sulfur coal. The average content of harmful trace elements in the bulk of China＇s coal is similar to the corresponding content in the coal of the North America and the rest of the world, whereas the content of various elements （Hg, Sb and Se） is different in magnitude to the corresponding percentage in the crust. The average content of the elements Cr, Se, Co, Be, U, Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and CI in the coals of Late Carboniferous to Early Permian age in N China are the highest. The average content of Mn in Early and Middle Jurassic coal is higher in NW China. The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.展开更多
Concentrations of sixteen rare earth elements（REEs） in PM2.5 and potential-source samples, collected in Nanchang city in mid-September 2013, were determined by inductively coupled plasma mass spectrometry（ICP-MS）....Concentrations of sixteen rare earth elements（REEs） in PM2.5 and potential-source samples, collected in Nanchang city in mid-September 2013, were determined by inductively coupled plasma mass spectrometry（ICP-MS）. The results showed that the concentrations of total REEs（ΣREE） ranged from 78.76 to 1351 ng/mg. The order of REEs in PM2.5 samples showed the anthropogenic effects, Ce and Eu were affected more than the other REEs according to the enrichment factors. The results of chondrite-normalized REEs patterns and characteristic parameters showed evident light REEs fractionation, and positive anomalies of Ce and Eu in PM2.5. The other non-local pollution sources affected the PM2.5 samples, according to the triangular diagram of La, Ce and Sm compositions and plot of ΣREE vs δEu. Moreover, plot of（La/Sm）N vs（Gd/Yb）N revealed the effects of local sources. In conclusion, the REEs in potential-source samples were close to the background of local soil, while the REEs in PM2.5 samples in Nanchang city were jointly affected by the investigated local sources and other non-local sources.展开更多
By applying the ＇theory of synchronization＇ from the science of complexity to studying the regional regularity of ore formation within the Nanling region of southern China, a characteristic targetpattern regional or...By applying the ＇theory of synchronization＇ from the science of complexity to studying the regional regularity of ore formation within the Nanling region of southern China, a characteristic targetpattern regional ore zonality has been discovered. During the early and late Yanshanian epoch （corresponding respectively to the Jurassic and Cretaceous periods）, two centers of ore formation emerged successively in the Nanling region; the former is mainly for rare metals （W, Sn, Mo, Bi, Nb） and one rare-earth element （La） and was generated in the Jurassic period; whereas the latter is mainly for base metals （Cu, Pb, Zn, Sb, Hg）, noble metals （Au, Ag）, and one radioactive element （U） and was generated in the Cretaceous period. Centers of ore formation were brought about by interface dynamics respectively at the Qitianling and Jiuyishan districts in southern Hunan Province. The characteristic giant nonlinear target-pattern regional ore zonality was generated by spatio-temporal synchronization process of the Nanling complex metallogenic system. It induced the collective dynamics and cooperative behavior of the system and displayed the configuration of the regional ore zonality. Then dynamical clustering transformed the configuration into rudimentary ordered coherent structures. Phase dynamics eventually defined the spatio-temporal structures of the target-pattern regional ore zonality and determined their localization and distribution. A new methodology for revealing regional ore zonality is developed, which will encourage further investigation of the formation of deep-seated ore resources and the onset of large-scale mineralization.展开更多
A combination of Soxhlet extraction, column chromatography and INAA with GC and GC- MS was used in this work for the study of the abundance patterns of 36 trace elements and their correlation in nearly 100 samples of ...A combination of Soxhlet extraction, column chromatography and INAA with GC and GC- MS was used in this work for the study of the abundance patterns of 36 trace elements and their correlation in nearly 100 samples of crude oil and organic materials extracted from oil- forming source rocks from 10 main Chinese oilfields. The low V/Ni ratios of 0.01 to 0.3 state the oil- forming continent environment. The geochemical significance hinted from other trace element abundances is also briefly discussed.展开更多
In our previous work, it was found that large electrospun from chlorinated polypropylene solution doped Bird＇s Nest patterned nanofibrous membranes can be simply with an ionic liquid, and a plausible formation mechan...In our previous work, it was found that large electrospun from chlorinated polypropylene solution doped Bird＇s Nest patterned nanofibrous membranes can be simply with an ionic liquid, and a plausible formation mechanism of Bird＇s Nest patterned architectures was proposed. Here, we use Ansoft Maxwell version 12 software （3D, electrostatic solver） to simulate the electrical field distribution of the electrospinning setup, and to clarify the rationality of proposed formation mechanism. Calculation results clearly show that the introduction of charged nanofibrous bundles would produce a similar patterned electrical field distribution, which definitely confirms the important role of surface residual charges. The proposed mechanism can be well extended to other polymer systems including polystyrene, poly（acrylonitrile-co-acrylic acid） and chitosan/poly（ethylene oxide）.展开更多
Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element (REE) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and d...Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element (REE) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fractionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb, Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low {∑REE}. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization.展开更多
The novel approach of this paper describes the suppression of grating lobe level with the element count optimization in planar antenna array. Rectangular lattice (RL) and triangular lattice (TL) structures are chosen ...The novel approach of this paper describes the suppression of grating lobe level with the element count optimization in planar antenna array. Rectangular lattice (RL) and triangular lattice (TL) structures are chosen for determining the achievable array element patterns (EP) and further suppressing the grating lobe level. The element spacing and number of elements (10 × 20 array) are taken into account for particular lattice. Grating lobe peaks are observed for the 200-element planar array at maximum scan angle (θ) with the set frequency of 3 GHz. Further, it is found that 14°;bore sight elevation of rectangular lattice produces a transformed field of view, which permits a reduction in element count of 20.39% compared with 10° bore sight elevation. Finally, the typical values of elevation, element count and array size (25 cm2) are trained using artificial neural network (ANN) algorithm and element count is predicted after testing the network. The network shows a high success rate.展开更多
Instrument neutron activation analysis (INAA) has been employed in this study to determine 32 elements in soil on the loess plateau. The preliminary results suggest that geochemical characteristics of elements in the ...Instrument neutron activation analysis (INAA) has been employed in this study to determine 32 elements in soil on the loess plateau. The preliminary results suggest that geochemical characteristics of elements in the soil mainly retained those in the parent materials (loess). It has been found that fractional deposition among grain sizes in the process of loess transportation as well as the bioclimate in which the soil developed are main factors affecting the regional variations of elemental distribution in soil on the plateau. Contour maps of element concentrations plotted from the trend analyses exhibit the major patterns of the distributions and variations on the plateau. Furthermore, the study also provides evidence for the aeolian theory of the loess transportation in China.展开更多
基金supported by the National Natural Science Foundation of China(52106284,52422609)the Natural Science Foundation of Hebei Province(B2021507001)Key Research Special Project of CPPU(ZDZX202501)。
文摘As lithium-ion batteries(LIBs)continue to evolve toward lower costs and higher energy densities,their potential safety risks have become increasingly apparent.Incidents such as explosions at energy storage facilities,fires in electric vehicles,and building fires ignited by charging two-wheeled vehicles have been occurring with alarming frequency,often resulting in significant casualties and injuries.Conducting indepth investigations into thermal runaway(TR)incidents in LIBs can significantly reduce the risk of future occurrences.However,current investigations into LIB fire and explosion incidents face challenges due to the difficulty of conducting in-depth analyses and the lack of a robust theoretical framework to guide these investigations.To enhance the effectiveness of in-depth investigations into battery fire and explosion incidents and to address the lack of theoretical guidance,this paper is the first to systematically examine the conservation and flow patterns of elements during the TR process of LIBs.The analysis reveals that during TR,the gas products generated include approximately 1.5 g of H_(2),23.6 g of CO,88.4 g of CO_(2),8.9 g of C_(2)H_(4),7.3 g of CH_(4),3.7 g of C_(2)H_(6),and 82 g of electrolyte vapor.After TR,the solid compounds formed consist of approximately 2.5 g of LiF,29–92.2 g of elemental Ni/Co/Mn,11.4 g of Li_(2)CO_(3),200.6 g of graphite,1.4 g of NiO,29.6 g of MnO,30.1 g of CoO,67 g of elemental Cu,0.03 g of LiNiO_(2),and 4.3 g of LiAlO_(2).Importantly,the energy released from reactions forming solid compounds during TR surpasses that from gas-forming reactions.This investigation represents the first application of Hess’s law to verify the conservation of elements during the TR process of lithium-ion batteries.The proposed methodology is also applicable to other types of energy storage batteries,effectively advancing techniques for comprehensively investigating lithium battery fire and explosion incidents.
文摘In the production and life of ancient Chinese folk artists,through the abstract and geometric arrangement of things,they formed many meaningful patterns.These patterns are widely used in a variety of decorations,reflecting the most simple artistic ideas in the life of the working people,and are also an important embodiment of folk art aesthetics.Many elements of folk patterns have been preserved to this day,and they have an important role in inspiring and guiding today’s art design.This paper mainly analyzes the folk pattern elements and their artistic value,and elaborates on the application of folk pattern elements in architectural design and the specific design methods,to provide certain references for the combination of modern architectural design and traditional folk patterns.
文摘On the basis of the in situ data of DO2, pH, SiO2. PO4-P, NO3-N and NO2-N collected in the north of the East China Sea during 1987-1988, the following points are mainly expounded.1.The inorgonic nutrients are obviously affected by continent runoff in the north of the East China Sea. Their distributions are characteristic of its distribution of terrigenous materials.2.There are three transport paths of nutrients from the shelf to the Kuroshio area. The first is mixing-diffusing-advec-tion and upwelling process, the process of biology and biochemistry belongs to the second, and the sinking process is the last one.3.The swing of the Kuroshio axis affectes both the range of the migration of substances through mixing-diffusing-advec-tion process and the upwelling degree of the subsurface Kuroshio water to the shelf.4.Most part of the substances sink as macroparticles to the deep layer before reaching the Kuroshio area.
文摘To promote the rational development and use of clean coal resources in China, data on the regional and age distribution of sulfur, arsenic and other harmful elements in Chinese coal was broadly collected, tested for content, and analyzed. Coal in northwestern China is characterized by low to extremely low levels of sulfur; the coal of the Taiyuan Formation in northern China mainly has high-sulfur content; that of the Shanxi Formation is mainly characterized by low sulfur coal; and the Late Permian coal in southern China has overall higher sulfur content; other regions have low sulfur coal. The average content of harmful trace elements in the bulk of China＇s coal is similar to the corresponding content in the coal of the North America and the rest of the world, whereas the content of various elements （Hg, Sb and Se） is different in magnitude to the corresponding percentage in the crust. The average content of the elements Cr, Se, Co, Be, U, Br in Late Permian coal in S China ranks first in the country whereas the average content of Hg and CI in the coals of Late Carboniferous to Early Permian age in N China are the highest. The average content of Mn in Early and Middle Jurassic coal is higher in NW China. The high content of harmful elements in some coal should cause particular concern both in the development and utilization of coal.
基金Project supported by the National Natural Science Foundation of China(21477042,21377042)the Natural Science Foundation of Fujian Province(2016J01065)
文摘Concentrations of sixteen rare earth elements（REEs） in PM2.5 and potential-source samples, collected in Nanchang city in mid-September 2013, were determined by inductively coupled plasma mass spectrometry（ICP-MS）. The results showed that the concentrations of total REEs（ΣREE） ranged from 78.76 to 1351 ng/mg. The order of REEs in PM2.5 samples showed the anthropogenic effects, Ce and Eu were affected more than the other REEs according to the enrichment factors. The results of chondrite-normalized REEs patterns and characteristic parameters showed evident light REEs fractionation, and positive anomalies of Ce and Eu in PM2.5. The other non-local pollution sources affected the PM2.5 samples, according to the triangular diagram of La, Ce and Sm compositions and plot of ΣREE vs δEu. Moreover, plot of（La/Sm）N vs（Gd/Yb）N revealed the effects of local sources. In conclusion, the REEs in potential-source samples were close to the background of local soil, while the REEs in PM2.5 samples in Nanchang city were jointly affected by the investigated local sources and other non-local sources.
基金supported by China Geological Survey Grants No. 1212010561603(2005)
文摘By applying the ＇theory of synchronization＇ from the science of complexity to studying the regional regularity of ore formation within the Nanling region of southern China, a characteristic targetpattern regional ore zonality has been discovered. During the early and late Yanshanian epoch （corresponding respectively to the Jurassic and Cretaceous periods）, two centers of ore formation emerged successively in the Nanling region; the former is mainly for rare metals （W, Sn, Mo, Bi, Nb） and one rare-earth element （La） and was generated in the Jurassic period; whereas the latter is mainly for base metals （Cu, Pb, Zn, Sb, Hg）, noble metals （Au, Ag）, and one radioactive element （U） and was generated in the Cretaceous period. Centers of ore formation were brought about by interface dynamics respectively at the Qitianling and Jiuyishan districts in southern Hunan Province. The characteristic giant nonlinear target-pattern regional ore zonality was generated by spatio-temporal synchronization process of the Nanling complex metallogenic system. It induced the collective dynamics and cooperative behavior of the system and displayed the configuration of the regional ore zonality. Then dynamical clustering transformed the configuration into rudimentary ordered coherent structures. Phase dynamics eventually defined the spatio-temporal structures of the target-pattern regional ore zonality and determined their localization and distribution. A new methodology for revealing regional ore zonality is developed, which will encourage further investigation of the formation of deep-seated ore resources and the onset of large-scale mineralization.
文摘A combination of Soxhlet extraction, column chromatography and INAA with GC and GC- MS was used in this work for the study of the abundance patterns of 36 trace elements and their correlation in nearly 100 samples of crude oil and organic materials extracted from oil- forming source rocks from 10 main Chinese oilfields. The low V/Ni ratios of 0.01 to 0.3 state the oil- forming continent environment. The geochemical significance hinted from other trace element abundances is also briefly discussed.
基金financially supported by the National Natural Science Foundation of China (No.50933006)Zhejiang Provincial Innovative Research Team (No.2009R50004)
文摘In our previous work, it was found that large electrospun from chlorinated polypropylene solution doped Bird＇s Nest patterned nanofibrous membranes can be simply with an ionic liquid, and a plausible formation mechanism of Bird＇s Nest patterned architectures was proposed. Here, we use Ansoft Maxwell version 12 software （3D, electrostatic solver） to simulate the electrical field distribution of the electrospinning setup, and to clarify the rationality of proposed formation mechanism. Calculation results clearly show that the introduction of charged nanofibrous bundles would produce a similar patterned electrical field distribution, which definitely confirms the important role of surface residual charges. The proposed mechanism can be well extended to other polymer systems including polystyrene, poly（acrylonitrile-co-acrylic acid） and chitosan/poly（ethylene oxide）.
文摘Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element (REE) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fractionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb, Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low {∑REE}. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization.
文摘The novel approach of this paper describes the suppression of grating lobe level with the element count optimization in planar antenna array. Rectangular lattice (RL) and triangular lattice (TL) structures are chosen for determining the achievable array element patterns (EP) and further suppressing the grating lobe level. The element spacing and number of elements (10 × 20 array) are taken into account for particular lattice. Grating lobe peaks are observed for the 200-element planar array at maximum scan angle (θ) with the set frequency of 3 GHz. Further, it is found that 14°;bore sight elevation of rectangular lattice produces a transformed field of view, which permits a reduction in element count of 20.39% compared with 10° bore sight elevation. Finally, the typical values of elevation, element count and array size (25 cm2) are trained using artificial neural network (ANN) algorithm and element count is predicted after testing the network. The network shows a high success rate.
文摘Instrument neutron activation analysis (INAA) has been employed in this study to determine 32 elements in soil on the loess plateau. The preliminary results suggest that geochemical characteristics of elements in the soil mainly retained those in the parent materials (loess). It has been found that fractional deposition among grain sizes in the process of loess transportation as well as the bioclimate in which the soil developed are main factors affecting the regional variations of elemental distribution in soil on the plateau. Contour maps of element concentrations plotted from the trend analyses exhibit the major patterns of the distributions and variations on the plateau. Furthermore, the study also provides evidence for the aeolian theory of the loess transportation in China.
