The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D i...The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.展开更多
This study investigates prescribed-time position tracking control for electromagnetic satellite formations subject to model uncertainties and external disturbances.Using the Clohessy-Wiltshire equations as the relativ...This study investigates prescribed-time position tracking control for electromagnetic satellite formations subject to model uncertainties and external disturbances.Using the Clohessy-Wiltshire equations as the relative motion dynamics model,a prescribed time output feedback control strategy is proposed.A prescribed-time extended state observer is designed to estimate the relative velocity and external disturbances.The disturbance estimates are then used as the feedforward component of the controller.Building on this framework,a novel prescribed-time active disturbance rejection control strategy for position tracking is developed via a backstepping control design.The convergence of the extended state observer and the stability of the closed-loop system are rigorously analyzed using Lyapunov stability theory.Numerical simulations are performed to validate the effectiveness of the proposed controller.展开更多
The multi-satellite electromagnetic formation flight system is nonlinear and strongly coupled,which makes modeling and optimization challenging.To simplify electromagnetic force evaluation and dynamics modeling,we int...The multi-satellite electromagnetic formation flight system is nonlinear and strongly coupled,which makes modeling and optimization challenging.To simplify electromagnetic force evaluation and dynamics modeling,we introduce a reference frame consistent with each satellite body frame,in which the electromagnetic dipoles and electromagnetic forces are represented as two-dimensional vectors.Then,the maneuver time is divided into time intervals,and different satellite sets are activated in each interval,converting the multi-satellite formation reconfiguration problem into an optimal trajectory problem of each two-satellite subsystem.To this end,a token-based dynamic programming method with a switching penalty of active satellite sets is proposed to determine the sequence of satellite sets participating in each time interval,thereby enabling all satellites to reach their desired states.For the two-satellite subsystem with the objectives of minimizing maneuver time and energy consumption,the Gauss pseudo-spectral method is employed to generate the optimal reconfiguration trajectory.Numerical simulations verify the effectiveness of the proposed optimization method.展开更多
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption ar...With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.展开更多
Designing and preparing a compatible electromagnetic interference(EMI)shielding,radar and infrared stealth material exhibits significant prospect in the military field.Hence,a novel conductive/magnetic polyimide-based...Designing and preparing a compatible electromagnetic interference(EMI)shielding,radar and infrared stealth material exhibits significant prospect in the military field.Hence,a novel conductive/magnetic polyimide-based nonwoven fabric(PFN_y)is prepared by alkali treatment,Fe~(3+)ion exchange,thermal reduction,and electroless nickel(Ni)plating process.Its impedance/insulation characteristics can be easily adjusted by controlling the in situ growth of Fe_(3)O_(4) and electroless nickel plating.Subsequently,a new strategy of constructing hierarchical dual-gradient impedance/insulation structure is implemented to achieve EMI shielding,radar and infrared stealth via stacking PFN_y with gradually decreased impedance/insulation characteristics from top to bottom.The formation of impedance matching gradient structure promotes effective introduction and dissipation of electromagnetic waves,endowing the composite with outstanding EMI shielding and radar stealth performance.Meanwhile,the construction of thermal insulation gradient structure can effectively inhibit thermal radiation from target,bringing an excellent infrared stealth performance.Importantly,the strong interfacial interactions between Fe_(3)O_(4),Ni and polyimide fiber accelerate PFNy to resist the stresses originated from high-temperature heat source,achieving a compatible high-temperature resistant radar/infrared stealth performance.Such excellent comprehensive properties endow it with a great potential in high-temperature military camouflage applications against enemy radar and infrared detection.展开更多
The spontaneous conversion of muonium to antimuonium is an interesting charged lepton flavor violation phenomenon that offers a sensitive probe for potential new physics and serves as a tool to constrain the parameter...The spontaneous conversion of muonium to antimuonium is an interesting charged lepton flavor violation phenomenon that offers a sensitive probe for potential new physics and serves as a tool to constrain the parameter space beyond the Standard Model.The Muonium-to-Antimuonium Conversion Experiment(MACE)was designed to utilize a high-intensity muon beam,a Michel electron magnetic spectrometer,a positron transport system,and a positron detection system to either discover or constrain this rare process with a conversion probability of O(10^(-13)).This article presents an overview of the theoretical framework and a detailed description of the experimental design for muonium-to-antimuonium conversion.展开更多
A methodology for the reduction of radar cross section(RCS)of cambered platforms within the target airspace is presented,which utilizes a dual-polarized ultra-wide-angle artificial electromagnetic absorbing surface.By...A methodology for the reduction of radar cross section(RCS)of cambered platforms within the target airspace is presented,which utilizes a dual-polarized ultra-wide-angle artificial electromagnetic absorbing surface.By applying the theory of generalized Brewster complex wave impedance matching,five distinct unit cell designs are developed to attain more than95%absorption rate for dual-polarized incident waves within five angular ranges:0°-30°,30°-50°,50°-60°,60°-70°,and 70°-80°.To optimally reduce the RCS of a cambered platform,the five types of units can be evenly distributed on the surface based on the local incident angles of plane waves originating from the target airspace.As an illustrative example,the leading edge of an airfoil is taken into account,and experimental measurements validate the efficiency of the proposed structure.Specifically,the absorbing surface achieves more than 10 dB of RCS reduction in the frequency ranges from 5-10 GHz(about66.7%relative bandwidth)for dual polarizations.展开更多
The rapid advancement of 5G/6G communication and radar technology has exacerbated issues of electromagnetic wave(EMW)leakage,interference,and thermal management.Therefore,developing lightweight EMW absorbers that inte...The rapid advancement of 5G/6G communication and radar technology has exacerbated issues of electromagnetic wave(EMW)leakage,interference,and thermal management.Therefore,developing lightweight EMW absorbers that integrate strong absorption,broad bandwidth,and thermal stability is crucial.Herein,a 3D MXene sponge/NiFe@NC heterostructure with tunable pore architecture is constructed by pyrolyzing a polyurethane(PU)foam template uniformly coated with NiFe-decorated Ti_(3)C_(2)T_(x)MXene nanosheets.The resulting porous dielectric-magnetic network integrates interconnected MXene pathways with uniformly dispersed NiFe@NC nanoparticles,enabling a synergistic effect of dielectric-magnetic loss through conduction loss,dipole/interface polarization,and magnetic loss.Precise pore structure design enhances impedance matching and promotes multi-scattering and internal reflection of EMWs.Notably,an“EMW-pore matching”mechanism is proposed,whereby pore size governs the impedance matching at specific frequencies,enabling tunable absorption performance.The optimized absorber achieves a reflection loss(RL)of-67.84 dB,while radar cross-section(RCS)simulations confirm its exceptional attenuation and stealth potential.Additionally,the 3D skeleton derived from PU foam confers remarkable thermal resistance and flame retardancy.This pore-regulation strategy provides a scalable route to designing lightweight,broadband,and thermally stable EMW absorbers for next-generation communication and stealth applications.展开更多
The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbi...The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.展开更多
The present investigation inspects the unsteady,incompressible MHD-induced flow of a ternary hybrid nanofluid made of SiO_(2)(silicon dioxide),ZnO(zinc oxide),and MWCNT(multi-walled carbon nanotubes)suspended in a wat...The present investigation inspects the unsteady,incompressible MHD-induced flow of a ternary hybrid nanofluid made of SiO_(2)(silicon dioxide),ZnO(zinc oxide),and MWCNT(multi-walled carbon nanotubes)suspended in a water-ethylene glycol base fluid between two perforated squeezing Riga plates.This problem is important because it helps us understand the complicated connections between magnetic fields,nanofluid dynamics,and heat transport,all of which are critical for designing thermal management systems.These findings are especially useful for improving the design of innovative cooling technologies in electronics,energy systems,and healthcare applications.No prior study has been done on the theoretical study of the flow of ternary nanofluid(SiO_(2)+ZnO+MWCNT/Water−EthylGl ycol,(60∶40))past a pierced squeezed Riga plates using the boundary value problem solver 4th-order collocation(BVP4C)numerical approach to date.So,the current work has been carried out to fill this gap,and the core purpose of this study is to explore the aspects that enhance the heat transfer of base fluids(H_(2)O/EG)suspended with three nanomaterials SiO_(2),ZnO,and MWCNT.The Riga plates introduce electromagnetic forcing through an embedded array of magnets and electrodes,generating Lorentz forces to regulate the flow.The squeezing effect introduces dynamic boundary movement,which enhances mixing;however,permeability,due to porosity,replicates the true material limits.Similarity transformations of the Navier-Stokes and energy equations result in a highly nonlinear set of ordinary differential equations that govern momentum and thermal energy transport.The subsequent boundary value problem is solved utilizing the BVP4C numerical approach.The study observes the impact of magnetic parameters,squeezing velocity,solid volume percentages of the three nanoparticles,and porous medium factors on velocity and temperature fields.Results show that magnetic fields reduce the velocity profile by 6.75%due to increased squeezing and medium effects.Tri-hybrid nanofluids notice a 9%rise in temperature with higher thermal radiation.展开更多
The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various...The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various applications.Herein,a dual-network(DN)gel was successfully prepared using acrylamide and sodium lignosulphonate as the basic units by simple chemical cross-linking and physical cross-linking methods.Specifically,the hydrogel forms two types of cross-linking networks through metal coordination and hydrogen bonding.Benefiting from the combined effects of dipole polarization and conductivity loss,the gel achieves an effective absorption bandwidth(EAB)of 6.74 GHz at a thickness of only 1.89 mm,demonstrating excellent EMW absorption performance.In addition,this unique structural configuration endows the EMW absorber with multifunctional features,such as remarkable tensile strength,good environmental compatibility,ultraviolet(UV)resistance,and excellent adhesion.Integrating multiple functional features into the EMW gels displays a broad application prospect in a variety of application scenarios.This research reveals the significance of DN structure design in the electromagnetic wave absorption(EWA)performance of gel-based materials,providing a substantial foundation for the multifunctional design of gel-based absorbers.展开更多
Three-dimensional porous foams and aerogels with high compressibilityand elasticity hold great promise for applications in pressure sensing,electromagnetic interference(EMI)shielding,and thermal insulation.However,the...Three-dimensional porous foams and aerogels with high compressibilityand elasticity hold great promise for applications in pressure sensing,electromagnetic interference(EMI)shielding,and thermal insulation.However,their widespread application is often hindered by compromised structural stabilityand inadequate fatigue resistance under repeated compression.Herein,asustainable“top-down”cell wall reconfiguration strategy is proposed to fabricatehighly elastic,fatigue-resistant,and electrically conductive lamellar wood spongefrom natural balsa wood.This strategy involves the conversion of the intrinsiccellular structure of wood into an arch-shaped lamellar architecture reinforcedby chemical cross-linking,followed by coating the lamellar scaffold with conductivepolypyrrole(PPy)via in situ polymerization.The resulting PPy-coatedcross-linked wood sponge(CWS@PPy)demonstrates reversible compressibility,excellent fatigue resistance(∼3.5%plastic deformation after 10,000 cyclesat 40%strain).The strain-induced conductivity changes in CWS@PPy enabletunable EMI shielding effectiveness under cyclic compression and also facilities high-sensitivity pressure sensing(0.72 kPa^(-1)).Additionally,CWS@PPy exhibits a low through-plane thermal conductivity of 0.037 W m^(-1)K^(-1),which can be dynamically tuned for adaptivethermal management.The proposed mechanically robust and conductive wood sponge provides a versatile and sustainable platform fornext-generation smart devices.展开更多
The theoretical implementation aspects of scattered field prediction and angular glint calculation in near-field region are proposed in this work.First of all,a more refined expression of the Green function is develop...The theoretical implementation aspects of scattered field prediction and angular glint calculation in near-field region are proposed in this work.First of all,a more refined expression of the Green function is developed.In this representation,an expansion center is adopted within the neighborhood of the sources.Then a high-frequency electromagnetic scattering evaluation algorithm is formulated,combining the refined physical optics(PO)and equivalent edge current(EEC)algorithm.The modified method not only retains the conciseness and efficiency of the standard code but also can be directly used in the near field(NF)scattering estimation.Afterwards,two basic concepts of the angular glint are briefly introduced and formulated.The proposed procedure makes preparation for the computation of NF linear deviation.Numerical examples demonstrate the accuracy and efficiency of the NF scattering prediction algorithm.The angular glint characteristics in near-field scenarios are also presented and analyzed in the final section.展开更多
This study introduces electromagnetic dynamic self-piercing riveting(ED-SPR),an innovative technique that integrates electromagnetic riveting principles with static self-piercing riveting(S-SPR)for highperformance str...This study introduces electromagnetic dynamic self-piercing riveting(ED-SPR),an innovative technique that integrates electromagnetic riveting principles with static self-piercing riveting(S-SPR)for highperformance structural joints.A dedicated methodology and experimental apparatus for ED-SPR were systematically designed and validated.Quantitative comparative analyses between ED-SPR and S-SPR were conducted on three critical material combinations:CFRP/Al,low-strength steel HC340 LA/Al,and high-strength steel DP590/Al.Key findings demonstrate that the electromagnetic-driven process reduces installation resistance by 60%and achieves a 30%larger interlock distance at the joint base compared to S-SPR.These quantitative advantages directly contribute to an approximately 30%increase in load-bearing capacity and superior damage tolerance in ED-SPR joints,as evidenced by tensile-shear testing of single-lap joints.Furthermore,distinct failure modes were observed:ED-SPR joints exhibited top plate pull-out failure in CFRP/Al and DP590/Al configurations,contrasting with the predominant rivet pull-out failure in S-SPR counterparts.Surface morphology and damage evolution were characterized via scanning electron microscopy(SEM)on post-assembly and tensile-failed specimens.The study establishes a foundation for optimizing electromagnetic-driven riveting parameters to mitigate CFRP delamination and further enhance joint reliability in vehicle body and aircraft fuselage structures.展开更多
Three-dimensional(3D)-printedgraphene aerogels hold promise for electromagneticwave absorption(EWA)engineering due to itsultralow density,outstanding electromagnetic dissipationwith the flexibility and precision of ma...Three-dimensional(3D)-printedgraphene aerogels hold promise for electromagneticwave absorption(EWA)engineering due to itsultralow density,outstanding electromagnetic dissipationwith the flexibility and precision of manufacturingstrategies.However,their high conductivitycauses severe impedance mismatch,limiting EWAperformance.3D printing requirements also constrainthe dielectric properties of printable grapheneinks,hindering the integration of high-performanceabsorbers with advanced manufacturing.This studyproposes a polyacrylic acid(PAA)gel-mediated3D porous graphene oxide(GO)aerogel multiscaleregulation strategy.Precise gel content control enablesdual-gradient tuning of the rheology(Benefitingdirect ink writing(DIW))and dielectric loss(Enhancing EWA)of GO/PAA composites and reduces aerogel density(6.9 mg cm^(-3)from28.2 mg cm^(-3)).Thermal reduction decomposes PAA into amorphous carbon nanoparticles anchored on reduced graphene oxide(rGO),enhancingimpedance matching and absorption via synergistic 0D/2D interfacial polarization and conductive loss.The optimized rGO/PAA aerogelachieves a minimum reflection loss(RL)of-39.86 dB at 2.5 mm and an effective absorption bandwidth(EAB)of 8.36 GHz(9.64-18 GHz)at3.2 mm.Combining DIW and this aerogel,we design a metamaterial absorber(MA)with dual material(dielectric loss)and structural gradients.This MA exhibits an ultrawide EAB of 14 GHz(4-18 GHz)with a total thickness of 7.8 mm.This work establishes a coupled design paradigmof“composition-structure-performance,”providing an engineerable solution for developing lightweight,broadband EWA materials.展开更多
The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)at...The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials.展开更多
With growing concerns regarding electromagnetic pollution,low-cost,environmentally friendly,and high-performance electromagnetic wave absorption(EWA)materials have attracted significant attention.This paper reports on...With growing concerns regarding electromagnetic pollution,low-cost,environmentally friendly,and high-performance electromagnetic wave absorption(EWA)materials have attracted significant attention.This paper reports on the synthesis of porous Fe_(3)O_(4)/C composites that incorporate dielectric and magnetic loss mechanisms via the carbothermal reduction method and optimization of waste ratio to enhance EWA performance.The Fe_(3)O_(4)/C composites with 10wt%soybean residues(Fe_(3)O_(4)/C-10),demonstrated the best EWA performance,achieving the minimum reflection loss of−56.4 dB and a bandwidth of 2.14 GHz at a thickness of 2.23 mm.This enhanced EWA performance is primarily attributable to improved impedance matching and the synergistic effect between dielectric and magnetic losses.Furthermore,radar cross-sectional simulations confirmed the practical feasibility of the porous Fe_(3)O_(4)/C composites.This study proposes a viable strategy for utilizing soybean residue and electrolytic manganese residue,highlighting their potential applications in EWA.展开更多
Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,how...Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.展开更多
Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication,...Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic equipment.In this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.展开更多
基金Supported by the National Natural Science Foundation of China(22378181).
文摘The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.
文摘This study investigates prescribed-time position tracking control for electromagnetic satellite formations subject to model uncertainties and external disturbances.Using the Clohessy-Wiltshire equations as the relative motion dynamics model,a prescribed time output feedback control strategy is proposed.A prescribed-time extended state observer is designed to estimate the relative velocity and external disturbances.The disturbance estimates are then used as the feedforward component of the controller.Building on this framework,a novel prescribed-time active disturbance rejection control strategy for position tracking is developed via a backstepping control design.The convergence of the extended state observer and the stability of the closed-loop system are rigorously analyzed using Lyapunov stability theory.Numerical simulations are performed to validate the effectiveness of the proposed controller.
文摘The multi-satellite electromagnetic formation flight system is nonlinear and strongly coupled,which makes modeling and optimization challenging.To simplify electromagnetic force evaluation and dynamics modeling,we introduce a reference frame consistent with each satellite body frame,in which the electromagnetic dipoles and electromagnetic forces are represented as two-dimensional vectors.Then,the maneuver time is divided into time intervals,and different satellite sets are activated in each interval,converting the multi-satellite formation reconfiguration problem into an optimal trajectory problem of each two-satellite subsystem.To this end,a token-based dynamic programming method with a switching penalty of active satellite sets is proposed to determine the sequence of satellite sets participating in each time interval,thereby enabling all satellites to reach their desired states.For the two-satellite subsystem with the objectives of minimizing maneuver time and energy consumption,the Gauss pseudo-spectral method is employed to generate the optimal reconfiguration trajectory.Numerical simulations verify the effectiveness of the proposed optimization method.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金financially supported by the Natural Science Foundation of Shandong Province(No.ZR2024QE446)。
文摘With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.
基金the financial support from China Postdoctoral Science Foundation(2024M760348)National Natural Science Foundation of China(52373077)。
文摘Designing and preparing a compatible electromagnetic interference(EMI)shielding,radar and infrared stealth material exhibits significant prospect in the military field.Hence,a novel conductive/magnetic polyimide-based nonwoven fabric(PFN_y)is prepared by alkali treatment,Fe~(3+)ion exchange,thermal reduction,and electroless nickel(Ni)plating process.Its impedance/insulation characteristics can be easily adjusted by controlling the in situ growth of Fe_(3)O_(4) and electroless nickel plating.Subsequently,a new strategy of constructing hierarchical dual-gradient impedance/insulation structure is implemented to achieve EMI shielding,radar and infrared stealth via stacking PFN_y with gradually decreased impedance/insulation characteristics from top to bottom.The formation of impedance matching gradient structure promotes effective introduction and dissipation of electromagnetic waves,endowing the composite with outstanding EMI shielding and radar stealth performance.Meanwhile,the construction of thermal insulation gradient structure can effectively inhibit thermal radiation from target,bringing an excellent infrared stealth performance.Importantly,the strong interfacial interactions between Fe_(3)O_(4),Ni and polyimide fiber accelerate PFNy to resist the stresses originated from high-temperature heat source,achieving a compatible high-temperature resistant radar/infrared stealth performance.Such excellent comprehensive properties endow it with a great potential in high-temperature military camouflage applications against enemy radar and infrared detection.
基金supported by National Natural Science Foundation of China(Nos.12075326,11535014,11975017,12475191,11905092,12105132 and 12175039)Guangdong Basic and Applied Basic Research Foundation(No.2025A1515010669)+7 种基金Natural Science Foundation of Guangzhou(No.2024A04J6243)Fundamental Research Funds for the Central Universities(23xkjc017)in Sun Yat-sen UniversityBasic Research Conditions and Major Scientific Instrument and Equipment Research and Development Projects of the Ministry of Science and Technology(No.2022YFF0705602)the State Key Laboratory of Particle Detection and Electronics(SKLPDE-ZZ-202412)Natural Science Foundation of Shandong Province(No.2023HWYQ-010)the“Fundamental Research Funds for the Central Universities”at Southeast Universitythe National Development and Reform Commission of China(Large Research Infrastructures of 12th Five-Year Plan:China initiative Accelerator Driven System)(No.2017-000052-75-01-000590)Innovation Training Program for bachelor students in Sun Yat-sen University。
文摘The spontaneous conversion of muonium to antimuonium is an interesting charged lepton flavor violation phenomenon that offers a sensitive probe for potential new physics and serves as a tool to constrain the parameter space beyond the Standard Model.The Muonium-to-Antimuonium Conversion Experiment(MACE)was designed to utilize a high-intensity muon beam,a Michel electron magnetic spectrometer,a positron transport system,and a positron detection system to either discover or constrain this rare process with a conversion probability of O(10^(-13)).This article presents an overview of the theoretical framework and a detailed description of the experimental design for muonium-to-antimuonium conversion.
基金supported by the National Key Research and Development Program of China(2023YFB3907304-3)the National Natural Science Foundation of China(NSFC)(62271050)。
文摘A methodology for the reduction of radar cross section(RCS)of cambered platforms within the target airspace is presented,which utilizes a dual-polarized ultra-wide-angle artificial electromagnetic absorbing surface.By applying the theory of generalized Brewster complex wave impedance matching,five distinct unit cell designs are developed to attain more than95%absorption rate for dual-polarized incident waves within five angular ranges:0°-30°,30°-50°,50°-60°,60°-70°,and 70°-80°.To optimally reduce the RCS of a cambered platform,the five types of units can be evenly distributed on the surface based on the local incident angles of plane waves originating from the target airspace.As an illustrative example,the leading edge of an airfoil is taken into account,and experimental measurements validate the efficiency of the proposed structure.Specifically,the absorbing surface achieves more than 10 dB of RCS reduction in the frequency ranges from 5-10 GHz(about66.7%relative bandwidth)for dual polarizations.
基金supported by the National Natural Science Foundation of China(52562043)Jiangxi Provincial Natural Science Foundation(20244BAB28050)。
文摘The rapid advancement of 5G/6G communication and radar technology has exacerbated issues of electromagnetic wave(EMW)leakage,interference,and thermal management.Therefore,developing lightweight EMW absorbers that integrate strong absorption,broad bandwidth,and thermal stability is crucial.Herein,a 3D MXene sponge/NiFe@NC heterostructure with tunable pore architecture is constructed by pyrolyzing a polyurethane(PU)foam template uniformly coated with NiFe-decorated Ti_(3)C_(2)T_(x)MXene nanosheets.The resulting porous dielectric-magnetic network integrates interconnected MXene pathways with uniformly dispersed NiFe@NC nanoparticles,enabling a synergistic effect of dielectric-magnetic loss through conduction loss,dipole/interface polarization,and magnetic loss.Precise pore structure design enhances impedance matching and promotes multi-scattering and internal reflection of EMWs.Notably,an“EMW-pore matching”mechanism is proposed,whereby pore size governs the impedance matching at specific frequencies,enabling tunable absorption performance.The optimized absorber achieves a reflection loss(RL)of-67.84 dB,while radar cross-section(RCS)simulations confirm its exceptional attenuation and stealth potential.Additionally,the 3D skeleton derived from PU foam confers remarkable thermal resistance and flame retardancy.This pore-regulation strategy provides a scalable route to designing lightweight,broadband,and thermally stable EMW absorbers for next-generation communication and stealth applications.
基金supported by the National Natural Science Foundation of China(No.52436008)the Inner Mongolia Science and Technology Projects,China(Nos.JMRHZX20210003 and 2023YFCY0009)+3 种基金the Huaneng Group Co Ltd.,China(No.HNKJ23-H50)the National Natural Science Foundation of China(No.22408044)the China Postdoctoral Science Foundation(No.2024M761877)the National Key R&D Program of China(No.SQ2024YFD2200039)。
文摘The electromagnetic wave absorption of silicon carbide nanowires is improved by their uniform and diverse cross-structures.This study introduces a sustainable and high value-added method for synthesizing silicon carbide nanowires using lignite and waste silicon powder as raw materials through carbothermal reduction.The staggered structure of nanowires promotes the creation of interfacial polarization,impedance matching,and multiple loss mechanisms,leading to enhanced electromagnetic absorption performance.The silicon carbide nanowires demonstrate outstanding electromagnetic absorption capabilities with the minimum reflection loss of-48.09 d B at10.08 GHz and an effective absorption bandwidth(the reflection loss less than-10 d B)ranging from 8.54 to 16.68 GHz with a thickness of 2.17 mm.This research presents an innovative approach for utilizing solid waste in an environmentally friendly manner to produce broadband silicon carbide composite absorbers.
基金funded by King Saud University,Riyadh,Saudi Arabia,through the Ongo-ing Research Funding program—Research Chairs(ORF-RC-2025-0127)funded via Princess Nourah bint Abdulrahman University Researchers Supporting Project number(PNURSP2025R443).
文摘The present investigation inspects the unsteady,incompressible MHD-induced flow of a ternary hybrid nanofluid made of SiO_(2)(silicon dioxide),ZnO(zinc oxide),and MWCNT(multi-walled carbon nanotubes)suspended in a water-ethylene glycol base fluid between two perforated squeezing Riga plates.This problem is important because it helps us understand the complicated connections between magnetic fields,nanofluid dynamics,and heat transport,all of which are critical for designing thermal management systems.These findings are especially useful for improving the design of innovative cooling technologies in electronics,energy systems,and healthcare applications.No prior study has been done on the theoretical study of the flow of ternary nanofluid(SiO_(2)+ZnO+MWCNT/Water−EthylGl ycol,(60∶40))past a pierced squeezed Riga plates using the boundary value problem solver 4th-order collocation(BVP4C)numerical approach to date.So,the current work has been carried out to fill this gap,and the core purpose of this study is to explore the aspects that enhance the heat transfer of base fluids(H_(2)O/EG)suspended with three nanomaterials SiO_(2),ZnO,and MWCNT.The Riga plates introduce electromagnetic forcing through an embedded array of magnets and electrodes,generating Lorentz forces to regulate the flow.The squeezing effect introduces dynamic boundary movement,which enhances mixing;however,permeability,due to porosity,replicates the true material limits.Similarity transformations of the Navier-Stokes and energy equations result in a highly nonlinear set of ordinary differential equations that govern momentum and thermal energy transport.The subsequent boundary value problem is solved utilizing the BVP4C numerical approach.The study observes the impact of magnetic parameters,squeezing velocity,solid volume percentages of the three nanoparticles,and porous medium factors on velocity and temperature fields.Results show that magnetic fields reduce the velocity profile by 6.75%due to increased squeezing and medium effects.Tri-hybrid nanofluids notice a 9%rise in temperature with higher thermal radiation.
基金supported by the National Natural Science Foundation of China(Nos.52231007,51872238,52074227,and 21806129)the Fundamental Research Funds for the Central Universities(Nos.3102018zy045,3102019AX11,and 5000220455)the Natural Science Basic Research Plan in Shaanxi Province of China(Nos.2017JQ5116 and 2020JM-118).
文摘The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various applications.Herein,a dual-network(DN)gel was successfully prepared using acrylamide and sodium lignosulphonate as the basic units by simple chemical cross-linking and physical cross-linking methods.Specifically,the hydrogel forms two types of cross-linking networks through metal coordination and hydrogen bonding.Benefiting from the combined effects of dipole polarization and conductivity loss,the gel achieves an effective absorption bandwidth(EAB)of 6.74 GHz at a thickness of only 1.89 mm,demonstrating excellent EMW absorption performance.In addition,this unique structural configuration endows the EMW absorber with multifunctional features,such as remarkable tensile strength,good environmental compatibility,ultraviolet(UV)resistance,and excellent adhesion.Integrating multiple functional features into the EMW gels displays a broad application prospect in a variety of application scenarios.This research reveals the significance of DN structure design in the electromagnetic wave absorption(EWA)performance of gel-based materials,providing a substantial foundation for the multifunctional design of gel-based absorbers.
基金supported by the National Natural Science Foundation of China(Grant Nos.32371796 and W2521030).
文摘Three-dimensional porous foams and aerogels with high compressibilityand elasticity hold great promise for applications in pressure sensing,electromagnetic interference(EMI)shielding,and thermal insulation.However,their widespread application is often hindered by compromised structural stabilityand inadequate fatigue resistance under repeated compression.Herein,asustainable“top-down”cell wall reconfiguration strategy is proposed to fabricatehighly elastic,fatigue-resistant,and electrically conductive lamellar wood spongefrom natural balsa wood.This strategy involves the conversion of the intrinsiccellular structure of wood into an arch-shaped lamellar architecture reinforcedby chemical cross-linking,followed by coating the lamellar scaffold with conductivepolypyrrole(PPy)via in situ polymerization.The resulting PPy-coatedcross-linked wood sponge(CWS@PPy)demonstrates reversible compressibility,excellent fatigue resistance(∼3.5%plastic deformation after 10,000 cyclesat 40%strain).The strain-induced conductivity changes in CWS@PPy enabletunable EMI shielding effectiveness under cyclic compression and also facilities high-sensitivity pressure sensing(0.72 kPa^(-1)).Additionally,CWS@PPy exhibits a low through-plane thermal conductivity of 0.037 W m^(-1)K^(-1),which can be dynamically tuned for adaptivethermal management.The proposed mechanically robust and conductive wood sponge provides a versatile and sustainable platform fornext-generation smart devices.
文摘The theoretical implementation aspects of scattered field prediction and angular glint calculation in near-field region are proposed in this work.First of all,a more refined expression of the Green function is developed.In this representation,an expansion center is adopted within the neighborhood of the sources.Then a high-frequency electromagnetic scattering evaluation algorithm is formulated,combining the refined physical optics(PO)and equivalent edge current(EEC)algorithm.The modified method not only retains the conciseness and efficiency of the standard code but also can be directly used in the near field(NF)scattering estimation.Afterwards,two basic concepts of the angular glint are briefly introduced and formulated.The proposed procedure makes preparation for the computation of NF linear deviation.Numerical examples demonstrate the accuracy and efficiency of the NF scattering prediction algorithm.The angular glint characteristics in near-field scenarios are also presented and analyzed in the final section.
基金sponsored by National Natural Science Foundation of China(Nos.52305146 and 52275165)Natural Science Foundation of Chongqing,China(No.cstb2022nscqmsx1290)+1 种基金the financial support from the Major Special Project for Technological Innovation and Application Development of Chongqing(No.CSTB2024TIAD-STX0015)the Key Laboratory Project of Shaanxi Province(No.2025SYS-SYSZD-064)。
文摘This study introduces electromagnetic dynamic self-piercing riveting(ED-SPR),an innovative technique that integrates electromagnetic riveting principles with static self-piercing riveting(S-SPR)for highperformance structural joints.A dedicated methodology and experimental apparatus for ED-SPR were systematically designed and validated.Quantitative comparative analyses between ED-SPR and S-SPR were conducted on three critical material combinations:CFRP/Al,low-strength steel HC340 LA/Al,and high-strength steel DP590/Al.Key findings demonstrate that the electromagnetic-driven process reduces installation resistance by 60%and achieves a 30%larger interlock distance at the joint base compared to S-SPR.These quantitative advantages directly contribute to an approximately 30%increase in load-bearing capacity and superior damage tolerance in ED-SPR joints,as evidenced by tensile-shear testing of single-lap joints.Furthermore,distinct failure modes were observed:ED-SPR joints exhibited top plate pull-out failure in CFRP/Al and DP590/Al configurations,contrasting with the predominant rivet pull-out failure in S-SPR counterparts.Surface morphology and damage evolution were characterized via scanning electron microscopy(SEM)on post-assembly and tensile-failed specimens.The study establishes a foundation for optimizing electromagnetic-driven riveting parameters to mitigate CFRP delamination and further enhance joint reliability in vehicle body and aircraft fuselage structures.
基金supported by ZJNSF LZ25E030006Zhejiang Provincial Key Research and Development Program(2024C01157)+2 种基金NSFC under Grant Nos.52473267 and 52401249the National Key Research and Development Program of China under Grant No.2021YFB3501504Zhejiang University Ningbo“Five in One”Campus Project(K-20213539)。
文摘Three-dimensional(3D)-printedgraphene aerogels hold promise for electromagneticwave absorption(EWA)engineering due to itsultralow density,outstanding electromagnetic dissipationwith the flexibility and precision of manufacturingstrategies.However,their high conductivitycauses severe impedance mismatch,limiting EWAperformance.3D printing requirements also constrainthe dielectric properties of printable grapheneinks,hindering the integration of high-performanceabsorbers with advanced manufacturing.This studyproposes a polyacrylic acid(PAA)gel-mediated3D porous graphene oxide(GO)aerogel multiscaleregulation strategy.Precise gel content control enablesdual-gradient tuning of the rheology(Benefitingdirect ink writing(DIW))and dielectric loss(Enhancing EWA)of GO/PAA composites and reduces aerogel density(6.9 mg cm^(-3)from28.2 mg cm^(-3)).Thermal reduction decomposes PAA into amorphous carbon nanoparticles anchored on reduced graphene oxide(rGO),enhancingimpedance matching and absorption via synergistic 0D/2D interfacial polarization and conductive loss.The optimized rGO/PAA aerogelachieves a minimum reflection loss(RL)of-39.86 dB at 2.5 mm and an effective absorption bandwidth(EAB)of 8.36 GHz(9.64-18 GHz)at3.2 mm.Combining DIW and this aerogel,we design a metamaterial absorber(MA)with dual material(dielectric loss)and structural gradients.This MA exhibits an ultrawide EAB of 14 GHz(4-18 GHz)with a total thickness of 7.8 mm.This work establishes a coupled design paradigmof“composition-structure-performance,”providing an engineerable solution for developing lightweight,broadband EWA materials.
基金supported by the National Natural Science Foundation of China(22265021,52231007,and 12327804)the Aeronautical Science Foundation of China(2020Z056056003)Jiangxi Provincial Natural Science Foundation(20232BAB212004).
文摘The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials.
基金supported by the National Natural Science Foundation of China(No.52471221)the Natural Science Foundation of Hunan Province,China(No.2024JJ7145)the National Sustainable Development Agenda Innovation Demonstration Zone Hunan special project,China(No.2022sfq09).
文摘With growing concerns regarding electromagnetic pollution,low-cost,environmentally friendly,and high-performance electromagnetic wave absorption(EWA)materials have attracted significant attention.This paper reports on the synthesis of porous Fe_(3)O_(4)/C composites that incorporate dielectric and magnetic loss mechanisms via the carbothermal reduction method and optimization of waste ratio to enhance EWA performance.The Fe_(3)O_(4)/C composites with 10wt%soybean residues(Fe_(3)O_(4)/C-10),demonstrated the best EWA performance,achieving the minimum reflection loss of−56.4 dB and a bandwidth of 2.14 GHz at a thickness of 2.23 mm.This enhanced EWA performance is primarily attributable to improved impedance matching and the synergistic effect between dielectric and magnetic losses.Furthermore,radar cross-sectional simulations confirmed the practical feasibility of the porous Fe_(3)O_(4)/C composites.This study proposes a viable strategy for utilizing soybean residue and electrolytic manganese residue,highlighting their potential applications in EWA.
基金financially supported by the National Natural Science Foundation of China(Grants nos.62201411,62371378,22205168,52302150 and 62304171)the China Postdoctoral Science Foundation(2022M722500)+1 种基金the Fundamental Research Funds for the Central Universities(Grants nos.ZYTS2308 and 20103237929)Startup Foundation of Xidian University(10251220001).
文摘Defects-rich heterointerfaces integrated with adjustable crystalline phases and atom vacancies,as well as veiled dielectric-responsive character,are instrumental in electromagnetic dissipation.Conventional methods,however,constrain their delicate constructions.Herein,an innovative alternative is proposed:carrageenan-assistant cations-regulated(CACR)strategy,which induces a series of sulfides nanoparticles rooted in situ on the surface of carbon matrix.This unique configuration originates from strategic vacancy formation energy of sulfides and strong sulfides-carbon support interaction,benefiting the delicate construction of defects-rich heterostructures in M_(x)S_(y)/carbon composites(M-CAs).Impressively,these generated sulfur vacancies are firstly found to strengthen electron accumulation/consumption ability at heterointerfaces and,simultaneously,induct local asymmetry of electronic structure to evoke large dipole moment,ultimately leading to polarization coupling,i.e.,defect-type interfacial polarization.Such“Janus effect”(Janus effect means versatility,as in the Greek two-headed Janus)of interfacial sulfur vacancies is intuitively confirmed by both theoretical and experimental investigations for the first time.Consequently,the sulfur vacancies-rich heterostructured Co/Ni-CAs displays broad absorption bandwidth of 6.76 GHz at only 1.8 mm,compared to sulfur vacancies-free CAs without any dielectric response.Harnessing defects-rich heterostructures,this one-pot CACR strategy may steer the design and development of advanced nanomaterials,boosting functionality across diverse application domains beyond electromagnetic response.
基金supported by the Fundamental Research Funds for the Central Universities and Heilongjiang Provincial Natural Science Foundation of China(Grant No.YQ2020E009).
文摘Robust, ultra-flexible, and multifunctional MXene-basedelectromagnetic interference (EMI) shielding nanocomposite filmsexhibit enormous potential for applications in artificial intelligence,wireless telecommunication, and portable/wearable electronic equipment.In this work, a nacre-inspired multifunctional heterocyclic aramid(HA)/MXene@polypyrrole (PPy) (HMP) nanocomposite paper withlarge-scale, high strength, super toughness, and excellent tolerance tocomplex conditions is fabricated through the strategy of HA/MXenehydrogel template-assisted in-situ assembly of PPy. Benefiting from the"brick-and-mortar" layered structure and the strong hydrogen-bondinginteractions among MXene, HA, and PPy, the paper exhibits remarkable mechanical performances, including high tensile strength (309.7 MPa),outstanding toughness (57.6 MJ m−3), exceptional foldability, and structural stability against ultrasonication. By using the template effect ofHA/MXene to guide the assembly of conductive polymers, the synthesized paper obtains excellent electronic conductivity. More importantly,the highly continuous conductive path enables the nanocomposite paper to achieve a splendid EMI shielding effectiveness (EMI SE) of 54.1 dBat an ultra-thin thickness (25.4 μm) and a high specific EMI SE of 17,204.7 dB cm2g−1. In addition, the papers also have excellent applicationsin electromagnetic protection, electro-/photothermal de-icing, thermal therapy, and fire safety. These findings broaden the ideas for developinghigh-performance and multifunctional MXene-based films with enormous application potential in EMI shielding and thermal management.
