A flexible copper clad laminate(FCCL) was fabricated using electroless-and electro-Cu plating processes and the effects of pre-treatment time on the adhesion strength of the FCCL were evaluated based on interfacial mo...A flexible copper clad laminate(FCCL) was fabricated using electroless-and electro-Cu plating processes and the effects of pre-treatment time on the adhesion strength of the FCCL were evaluated based on interfacial morphology.The neutralization and catalyst time were varied in the range of 0-20 min and 0.1-10 min,respectively,and the interfacial condition of the FCCL was characterized by atomic force microscopy(AFM) and X-ray photoelectron spectroscopy(XPS).It is observed that the peel strength increases significantly as the neutralization and catalyst time increase.Peel strength as high as 7.2-7.3 N/cm is obtained as the neutralization and catalyst time increase up to 20 min and 10 min,respectively,which is comparable to the strength achieved by the conventional laminating and sputtering processes.These improvements are probably due to an increase in the surface roughness of polyimide(PI),the activated surface condition,and the adsorption of palladium ions/atoms(Pd) on the PI surface which act as nucleation sites for Cu.展开更多
Ceramic thin plates were prepared using kaolin,potassium sodium feldspar and quartz powder as the main raw materials and kaolin,α-Al_(2)O_(3),MoO_(3) and AlF_(3)·3H_(2)O as additives.The experiment examined the ...Ceramic thin plates were prepared using kaolin,potassium sodium feldspar and quartz powder as the main raw materials and kaolin,α-Al_(2)O_(3),MoO_(3) and AlF_(3)·3H_(2)O as additives.The experiment examined the effects of different additives on mullite formation,as well as the microstructure and properties of the ceramic thin plates.Additionally,the study explored the toughening and strengthening mechanisms induced by the additives,providing a theoretical foundation for further optimizing the toughness of ceramic thin plates.The results showed that the D4 sample fired at 1220℃(with an addition of 20 wt% α-Al_(2)O_(3))exhibited the best performance,with a water absorption rate of 0.07%,apparent porosity of 0.18%,bulk density of 2.75 g·cm^(-3),firing shrinkage of 12.76%,bending strength reaching 101.93 MPa,and fracture toughness of 2.51 MPa·m^(1/2).As the amount ofα-Al_(2)O_(3) additive increased,the ceramic thin plates exhibited a greater abundance of short rod-like mullite and corundum grains,which were tightly packed together,forming a framework for the ceramic thin plates.This microstructure enhanced pathways for crack propagation,dispersed internal stresses,and increased fracture surface energy,resulting in significant improvements in both strength and fracture toughness of the ceramic thin plates.展开更多
A 32-channel charge-sensitive amplifier(CSA)is designed for fast timing in the delay-line readout of a parallel plate avalanche counter(PPAC)array.It is realized on a PCB with operational amplifiers and other discrete...A 32-channel charge-sensitive amplifier(CSA)is designed for fast timing in the delay-line readout of a parallel plate avalanche counter(PPAC)array.It is realized on a PCB with operational amplifiers and other discrete components.Each channel consists of an integrator,a pole-zero cancellation net,and a linear amplification stage,which can be adapted to accommodate either positive or negative input signals.The RMS equivalent input noise charges are 3.3 fC,the conversion gains are approximately±2 mV∕fC,and the intrinsic time resolution reaches 32 ps.In the prototype PPAC application,the CSA performs as well as the commercial FTA820A amplifier,providing a position resolution as good as 0.17 mm,and exhibiting reliable stability during several hours of continuous data acquisition.展开更多
A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The resu...A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.展开更多
Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The t...Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.展开更多
Titanium plates with a Ti−O solid solution surface-hardened layer were cold roll-bonded with 304 stainless steel plates with high work hardening rates.The evolution and mechanisms affecting the interfacial bonding str...Titanium plates with a Ti−O solid solution surface-hardened layer were cold roll-bonded with 304 stainless steel plates with high work hardening rates.The evolution and mechanisms affecting the interfacial bonding strength in titanium/stainless steel laminated composites were investigated.Results indicate that the hardened layer reduces the interfacial bonding strength from over 261 MPa to less than 204 MPa.During the cold roll-bonding process,the hardened layer fractures,leading to the formation of multi-scale cracks that are difficult for the stainless steel to fill.This not only hinders the development of an interlocking interface but also leads to the presence of numerous microcracks and hardened blocks along the nearly straight interface,consequently weakening the interfacial bonding strength.In metals with high work hardening rates,the conventional approach of enhancing interface interlocking and improving interfacial bonding strength by using a surface-hardened layer becomes less effective.展开更多
Arc ion plating (AIP) is applied to form Ti/(Ti,Cr)N/CrN multilayer coating on the surface of 316L stainless steel (SS316L) as bipolar plates for proton exchange membrane fuel cells (PEMFCs). The characterizations of ...Arc ion plating (AIP) is applied to form Ti/(Ti,Cr)N/CrN multilayer coating on the surface of 316L stainless steel (SS316L) as bipolar plates for proton exchange membrane fuel cells (PEMFCs). The characterizations of the coating are analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Interfacial contact resistance (ICR) between the coated sample and carbon paper is 4.9 m Omega cm(2) under 150 N/cm(2), which is much lower than that of the SS316L substrate. Potentiodynamic and potentiostatic tests are performed in the simulated PEMFC working conditions to investigate the corrosion behaviors of the coated sample. Superior anticorrosion performance is observed for the coated sample, whose corrosion current density is 0.12 mu A/cm(2). Surface morphology results after corrosion tests indicate that the substrate is well protected by the multilayer coating. Performances of the single cell with the multilayer coated SS316L bipolar plate are improved significantly compared with that of the cell with the uncoated SS316L bipolar plate, presenting a great potential for PEMFC application. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.展开更多
By a great deal of experiments,the misplating problemsof plated knitted fabrics composed of wool and Lycra arediscussed and analyzed.The factors affecting the mis-plating problems on manually operated flat knitting ma...By a great deal of experiments,the misplating problemsof plated knitted fabrics composed of wool and Lycra arediscussed and analyzed.The factors affecting the mis-plating problems on manually operated flat knitting ma-chine include the construction and adjustment of a plat-ing feeder,wool yarn count,feeding tension,takedowntension and the ground fabric structures.Some usefulresults can be derived from these works.展开更多
Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,p...Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,phased array waveform shape,interface structure shape,electronic scanning,and mechanical property testing.Results show that the rolling temperature of zirconiumtitanium complex should be controlled at 760°C,and the rolling reduction of each pass should be controlled at 10%–25%.The explosive velocity to prepare zirconium-titanium-steel composite plates should be controlled at 2450–2500 m/s,the density should be 0.78 g/cm3,the stand-off height should be 12 mm,and the explosive height of Zone A and Zone B should be 45–50 mm.Explosive welding combined with rolling method reduces the impact of explosive welding and multiple heat treatment on material properties.Meanwhile,the problems of surface wrinkling and cracking,which occur during the preparation process of large-sized zirconiumtitanium-steel composite plate,can be solved.展开更多
Proton exchange membrane water electrolysis(PEMWE)is one of the most promising strategies to pro-duce green hydrogen energy,and it is crucial to exploit highly conductive and good corrosion-resistant coatings on bipol...Proton exchange membrane water electrolysis(PEMWE)is one of the most promising strategies to pro-duce green hydrogen energy,and it is crucial to exploit highly conductive and good corrosion-resistant coatings on bipolar plates(BPs),one of the core components in PEMWE cells.In this work,NbN coatings are deposited on Ti BPs by magnetron sputtering to improve the corrosion resistance and conductivity,for which the critical process parameters,such as the working pressure,partial nitrogen pressure and de-position temperature are well optimized.It is found that the compact microstructure,highly conductive δ-NbN and uniform nanoparticles play a dominant role in the synergistic improvement of the corrosion resistance and electrical conductivity of NbN coatings.The optimized NbN coatings exhibit excellent cor-rosion resistance with the low corrosion current density of 1.1×10^(-8) A cm^(-2),a high potential value of-0.005 V vs.SCE and a low ICR value of 15.8 mΩcm2@1.5 MPa.Accordingly,NbN coatings can be a promising candidate for the development of the low-cost and high-anti-corrosion Ti BPs of PEMWE.展开更多
Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer ...Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer composite plate by explosive welding.The microscopic properties of each bonding interface were elucidated through field emission scanning electron microscope and electron backscattered diffraction(EBSD).A methodology combining finite element method-smoothed particle hydrodynamics(FEM-SPH)and molecular dynamics(MD)was proposed for the analysis of the forming and evolution characteristics of explosive welding interfaces at multi-scale.The results demonstrate that the bonding interface morphologies of TC4/Al 6063 and Al 6063/Al 7075 exhibit a flat and wavy configuration,without discernible defects or cracks.The phenomenon of grain refinement is observed in the vicinity of the two bonding interfaces.Furthermore,the degree of plastic deformation of TC4 and Al 7075 is more pronounced than that of Al 6063 in the intermediate layer.The interface morphology characteristics obtained by FEM-SPH simulation exhibit a high degree of similarity to the experimental results.MD simulations reveal that the diffusion of interfacial elements predominantly occurs during the unloading phase,and the simulated thickness of interfacial diffusion aligns well with experimental outcomes.The introduction of intermediate layer in the explosive welding process can effectively produce high-quality titanium/aluminum alloy composite plates.Furthermore,this approach offers a multi-scale simulation strategy for the study of explosive welding bonding interfaces.展开更多
7039 Al alloys are widely used in armor vehicles,given the material’s high specific strength and fracture toughness.However,laminar tearing in the thickness plane of the base metal(BM),specifically in the normal dire...7039 Al alloys are widely used in armor vehicles,given the material’s high specific strength and fracture toughness.However,laminar tearing in the thickness plane of the base metal(BM),specifically in the normal direction(ND)and rolling direction(RD)plane,was occasionally observed after the welding of thick plates,resulting in premature material failure.A vertically metal-inert gas(MIG)-welded laminar tearing component of a 30 mm thick plate was analyzed to determine the factors associated with this phenomenon.The texture,residual stress,microhardness,and tensile properties were also investigated.The results indicated that the crack extended along the RD as a transcrystalline fracture and terminated at the BM.The grains near the crack grew preferentially in the(001)crystal direction.Furthermore,the tensile strength(83 MPa)and elongation(6.8%)in the RD were relatively higher than those in the ND.In particular,the primary factors for crack initiation include stronger texture,higher dislocation density,increased Al_(7)Cu_(2)Fe phases,lower proportion of small-angle grain boundaries,and varying grain sizes in different regions,leading to the fragile microstructure.The higher residual stress of the BM promotes the formation and extension of cracks.The restraining force due to fixation and welding shrinkage force transformed the crack into laminar tearing.Preventive measures of laminar tearing were also proposed.展开更多
In this paper,the work hardening and softening behavior of AZ31 magnesium alloy sheets by hard plate accumulative roll bonding(HP-ARB)process in a specific temperature range was studied for the first time,and the cycl...In this paper,the work hardening and softening behavior of AZ31 magnesium alloy sheets by hard plate accumulative roll bonding(HP-ARB)process in a specific temperature range was studied for the first time,and the cyclic stress relaxation test,EBSD,TEM and other characterization methods were used.When the rolling temperature is 350℃,the grain size of magnesium sheets is refined to 4.32(±0.36)μm on average,and it shows an excellent combination of strength and plasticity.The tensile strength reaches 307(±8.52)MPa and the elongation is 12.73(±0.84)%.At this time,the curve of work hardening rate decreases smoothly and the degree of hardening is the lowest,and the amplitude of stress drop △σ_(p) in work softening test is the smallest with the increase of cycle times,which shows that the well coordination between work hardening and softening behavior has been achieved.Research has found that the combined effect of grain boundary strengthening and fine grain strengthening enhances the yield and tensile strength of magnesium sheets after three passes HP-ARB process at 350℃.This is attributed to the high degree of dislocation slip opening in the pyramidal surfaceand<c+a>,which not only coordinates the c-axis strain of the entire grain,but also promotes the slip transfer of dislocations in the fine-grained region,significantly improving the elongation of the sheets.This study provides a new idea for the forming and manufacturing of high performance magnesium alloy sheets.展开更多
On January 7,2025,01:05:15 UTC(9:05 a.m.local time)southern Tibet was rocked by a M_(W)7.1 earthquake(M_(W)=moment magnitude,USGS)centered(28.639°N 87.361°E)in the Lhasa Block north of the India/Eurasia Plat...On January 7,2025,01:05:15 UTC(9:05 a.m.local time)southern Tibet was rocked by a M_(W)7.1 earthquake(M_(W)=moment magnitude,USGS)centered(28.639°N 87.361°E)in the Lhasa Block north of the India/Eurasia Plate boundary,in a remote area about 180 km SW of Xigaze,in Dingri County of Shigatse of the Xizang Autonomous Region(Figure 1).展开更多
For the first time,the linear and nonlinear vibrations of composite rectangular sandwich plates with various geometric patterns of lattice core have been analytically examined in this work.The plate comprises a lattic...For the first time,the linear and nonlinear vibrations of composite rectangular sandwich plates with various geometric patterns of lattice core have been analytically examined in this work.The plate comprises a lattice core located in the middle and several homogeneous orthotropic layers that are symmetrical relative to it.For this purpose,the partial differential equations of motion have been derived based on the first-order shear deformation theory,employing Hamilton’s principle and Von Kármán’s nonlinear displacement-strain relations.Then,the nonlinear partial differential equations of the plate are converted into a time-dependent nonlinear ordinary differential equation(Duffing equation)by applying the Galerkin method.From the solution of this equation,the natural frequencies are extracted.Then,to calculate the non-linear frequencies of the plate,the non-linear equation of the plate has been solved analytically using the method of multiple scales.Finally,the effect of some critical parameters of the system,such as the thickness,height,and different angles of the stiffeners on the linear and nonlinear frequencies,has been analyzed in detail.To confirmthe solution method,the results of this research have been compared with the reported results in the literature and finite elements in ABAQUS,and a perfect match is observed.The results reveal that the geometry and configuration of core ribs strongly affect the natural frequencies of the plate.展开更多
A typical Whipple shield consists of double-layered plates with a certain gap.The space debris impacts the outer plate and is broken into a debris cloud(shattered,molten,vaporized)with dispersed energy and momentum,wh...A typical Whipple shield consists of double-layered plates with a certain gap.The space debris impacts the outer plate and is broken into a debris cloud(shattered,molten,vaporized)with dispersed energy and momentum,which reduces the risk of penetrating the bulkhead.In the realm of hypervelocity impact,strain rate(>10^(5)s^(-1))effects are negligible,and fluid dynamics is employed to describe the impact process.Efficient numerical tools for precisely predicting the damage degree can greatly accelerate the design and optimization of advanced protective structures.Current hypervelocity impact research primarily focuses on the interaction between projectile and front plate and the movement of debris cloud.However,the damage mechanism of debris cloud impacts on rear plates-the critical threat component-remains underexplored owing to complex multi-physics processes and prohibitive computational costs.Existing approaches,ranging from semi-empirical equations to a machine learningbased ballistic limit prediction method,are constrained to binary penetration classification.Alternatively,the uneven data from experiments and simulations caused these methods to be ineffective when the projectile has irregular shapes and complicate flight attitude.Therefore,it is urgent to develop a new damage prediction method for predicting the rear plate damage,which can help to gain a deeper understanding of the damage mechanism.In this study,a machine learning(ML)method is developed to predict the damage distribution in the rear plate.Based on the unit velocity space,the discretized information of debris cloud and rear plate damage from rare simulation cases is used as input data for training the ML models,while the generalization ability for damage distribution prediction is tested by other simulation cases with different attack angles.The results demonstrate that the training and prediction accuracies using the Random Forest(RF)algorithm significantly surpass those using Artificial Neural Networks(ANNs)and Support Vector Machine(SVM).The RF-based model effectively identifies damage features in sparsely distributed debris cloud and cumulative effect.This study establishes an expandable new dataset that accommodates additional parameters to improve the prediction accuracy.Results demonstrate the model's ability to overcome data imbalance limitations through debris cloud features,enabling rapid and accurate rear plate damage prediction across wider scenarios with minimal data requirements.展开更多
In the process of electroless cobalt plating,the saccharin additive can significantly change the surface morphology,texture orientation,and conductivity of the cobalt coating layer.When the amount of saccharin was 3 m...In the process of electroless cobalt plating,the saccharin additive can significantly change the surface morphology,texture orientation,and conductivity of the cobalt coating layer.When the amount of saccharin was 3 mg·L^(-1),the cobalt coating transformed from disordered large grains to a honeycomb structure,with a preferred orientation of(002)facet on hexago-nal close-packed(HCP)cobalt crystals.The resistivity of the cobalt film decreased to 14.4μΩ·cm,and further decreased to 10.7μΩ·cm after the annealing treatment.When the concentration of saccharin was increased,the grain size was gradually refined and a“stone forest”structure was observed,with the preferred orientation remaining unchanged.The addition of saccharin also slightly improves the purity of cobalt coating to a certain extent.Through the study of the crystallization behavior of cobalt electroless plating,saccharin molecules can adsorb to specific c-sites on the cobalt dense crystal plane,inhibiting the growth of abc stacking arrangement and inducing the crystal growth in ab stacking mode,thereby achieving optimal growth of HCP(002)texture.展开更多
How the subduction direction of the Paleo-Pacific plate beneath the Eurasian plate changes in the Early Cretaceous remains highly controversial due to the disappearance of the subducted oceanic plate.Intraplate deform...How the subduction direction of the Paleo-Pacific plate beneath the Eurasian plate changes in the Early Cretaceous remains highly controversial due to the disappearance of the subducted oceanic plate.Intraplate deformation structures in the east Asian continent,however,provide excellent opportunities for reconstructing paleostress fields in continental interior in relation to the Paleo-Pacific/Eurasian plate interaction.Anisotropy of magnetic susceptibility(AMS),geological,and geochronological analyses of post-kinematic mafic dykes intruding the detachment fault zone of the Wulian metamorphic core complex(WL MCC)in Jiaodong Peninsula exemplify emplacement of mantle-sourced dykes in a WNW-ESE(301°-121°)oriented tectonic extensional setting at ca.120 Ma.In combination with the results from our previous kinematic analysis of the MCC,a ca.21°clockwise change in the direction of intraplate extension is obtained for early(135-122 Ma)extensional exhumation of the MCC to late(122-108 Ma)emplacement of the dykes.Such a change is suggested to be related to the variation in subduction direction of the Paleo-Pacific plate beneath the Eurasian plate,from westward(pre-122 Ma)to west-northwestward(post-122 Ma).展开更多
TaN coatings were deposited on Ti bipolar plates by magnetron sputtering to improve corrosion resistance and service life.The influence of N_(2) flow rate on the surface morphology,hydrophobicity,crystallinity,corrosi...TaN coatings were deposited on Ti bipolar plates by magnetron sputtering to improve corrosion resistance and service life.The influence of N_(2) flow rate on the surface morphology,hydrophobicity,crystallinity,corrosion resistance,and interfacial contact resistance of TaN coatings was studied.Results show that as the N_(2) flow rate increases,the roughness of TaN coatings decreases firstly and then increases,and the hydrophobicity increases firstly and then decreases.At the N_(2) flow rate of 3 mL/min,TaN coating with larger grain size presents lower roughness and high hydrophobicity.The coating possesses the lowest corrosion current density of 2.82µA·cm^(−2) and the highest corrosion potential of−0.184 V vs.SCE in the simulated proton exchange membrane water electrolyser environment.After a potentiostatic polarization test for 10 h,a few corrosion pits are observed on the TaN coatings deposited at an N_(2) flow rate of 3 mL/min.After 75 h of electrolytic water performance testing,the TaN coating on bipolar plate improves the corrosion resistance and thus enhances the electrolysis efficiency(68.87%),greatly reducing the cost of bipolar plates.展开更多
A theoretical analysis on the perforation of Weldox 460E steel plates struck by flat-nosed projectiles is presented using a previously developed model within a unified framework.This model contains a dimensionless emp...A theoretical analysis on the perforation of Weldox 460E steel plates struck by flat-nosed projectiles is presented using a previously developed model within a unified framework.This model contains a dimensionless empirical equation to describe the variation of energy absorbed through global deformation as a function of impact velocity.The study further investigates the energy absorption mechanisms of Weldox 460E steel plates,with particular focus on the“plateau”phenomenon,i.e.,limited increase in ballistic limit with increasing plate thickness.This phenomenon is explained and compared with results from previously studied 2024-T351 aluminium plates.The model predictions agree well with experimental data for Weldox 460E steel plates impacted by flat-nosed projectiles,including:relationship between global deformation and impact velocity,ballistic limit,residual velocity,and critical conditions for the transition of failure modes.Moreover,the model effectively predicts the“plateau”phenomenon observed in intermediate plate thickness range.It is also found that the indentation absorption energy contributes a significantly larger fraction of the total absorption energy in Weldox 460E steel plates perforated by flat-nosed projectiles than in 2024-T351 aluminium plates,due to the differences in material properties.展开更多
基金supported by Grant No.RTI04-03-04 from the Regional Technology Innovation Program of the Ministry of Commerce,Industry and Energy (MOCIE),Korea
文摘A flexible copper clad laminate(FCCL) was fabricated using electroless-and electro-Cu plating processes and the effects of pre-treatment time on the adhesion strength of the FCCL were evaluated based on interfacial morphology.The neutralization and catalyst time were varied in the range of 0-20 min and 0.1-10 min,respectively,and the interfacial condition of the FCCL was characterized by atomic force microscopy(AFM) and X-ray photoelectron spectroscopy(XPS).It is observed that the peel strength increases significantly as the neutralization and catalyst time increase.Peel strength as high as 7.2-7.3 N/cm is obtained as the neutralization and catalyst time increase up to 20 min and 10 min,respectively,which is comparable to the strength achieved by the conventional laminating and sputtering processes.These improvements are probably due to an increase in the surface roughness of polyimide(PI),the activated surface condition,and the adsorption of palladium ions/atoms(Pd) on the PI surface which act as nucleation sites for Cu.
基金Funded by the National Key Technology Research and Development Program of the Ministry of Science and Technology of China(No.2023YFB4204302)。
文摘Ceramic thin plates were prepared using kaolin,potassium sodium feldspar and quartz powder as the main raw materials and kaolin,α-Al_(2)O_(3),MoO_(3) and AlF_(3)·3H_(2)O as additives.The experiment examined the effects of different additives on mullite formation,as well as the microstructure and properties of the ceramic thin plates.Additionally,the study explored the toughening and strengthening mechanisms induced by the additives,providing a theoretical foundation for further optimizing the toughness of ceramic thin plates.The results showed that the D4 sample fired at 1220℃(with an addition of 20 wt% α-Al_(2)O_(3))exhibited the best performance,with a water absorption rate of 0.07%,apparent porosity of 0.18%,bulk density of 2.75 g·cm^(-3),firing shrinkage of 12.76%,bending strength reaching 101.93 MPa,and fracture toughness of 2.51 MPa·m^(1/2).As the amount ofα-Al_(2)O_(3) additive increased,the ceramic thin plates exhibited a greater abundance of short rod-like mullite and corundum grains,which were tightly packed together,forming a framework for the ceramic thin plates.This microstructure enhanced pathways for crack propagation,dispersed internal stresses,and increased fracture surface energy,resulting in significant improvements in both strength and fracture toughness of the ceramic thin plates.
基金supported by the National Natural Science Foundation of China(Nos.U2167202,12225504,12005276)the Natural Science Foundation of Shandong Province(No.ZR2024QA172)the Fundamental Research Funds of Shandong University.
文摘A 32-channel charge-sensitive amplifier(CSA)is designed for fast timing in the delay-line readout of a parallel plate avalanche counter(PPAC)array.It is realized on a PCB with operational amplifiers and other discrete components.Each channel consists of an integrator,a pole-zero cancellation net,and a linear amplification stage,which can be adapted to accommodate either positive or negative input signals.The RMS equivalent input noise charges are 3.3 fC,the conversion gains are approximately±2 mV∕fC,and the intrinsic time resolution reaches 32 ps.In the prototype PPAC application,the CSA performs as well as the commercial FTA820A amplifier,providing a position resolution as good as 0.17 mm,and exhibiting reliable stability during several hours of continuous data acquisition.
基金supported by Guangdong Major Project of Basic and Applied Basic Research, China (No. 2020B0301030006)Fundamental Research Funds for the Central Universities, China (No. SWU-XDJH202313)+1 种基金Chongqing Postdoctoral Science Foundation Funded Project, China (No. 2112012728014435)the Chongqing Postgraduate Research and Innovation Project, China (No. CYS23197)。
文摘A new method was proposed for preparing AZ31/1060 composite plates with a corrugated interface,which involved cold-pressing a corrugated surface on the Al plate and then hot-pressing the assembled Mg/Al plate.The results show that cold-pressing produces intense plastic deformation near the corrugated surface of the Al plate,which promotes dynamic recrystallization of the Al substrate near the interface during the subsequent hot-pressing.In addition,the initial corrugation on the surface of the Al plate also changes the local stress state near the interface during hot pressing,which has a large effect on the texture components of the substrates near the corrugated interface.The construction of the corrugated interface can greatly enhance the shear strength by 2−4 times due to the increased contact area and the strong“mechanical gearing”effect.Moreover,the mechanical properties are largely depended on the orientation relationship between corrugated direction and loading direction.
基金Supported by the National Natural Science Foundation of China under Grant No.51975138the High-Tech Ship Scientific Research Project from the Ministry of Industry and Information Technology under Grant No.CJ05N20the National Defense Basic Research Project under Grant No.JCKY2023604C006.
文摘Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.
基金supported by the National Key R&D Program of China (No. 2018YFA0707300)the National Natural Science Foundation of China (No. 52374376)the Introduction Plan for High end Foreign Experts, China (No. G2023105001L)。
文摘Titanium plates with a Ti−O solid solution surface-hardened layer were cold roll-bonded with 304 stainless steel plates with high work hardening rates.The evolution and mechanisms affecting the interfacial bonding strength in titanium/stainless steel laminated composites were investigated.Results indicate that the hardened layer reduces the interfacial bonding strength from over 261 MPa to less than 204 MPa.During the cold roll-bonding process,the hardened layer fractures,leading to the formation of multi-scale cracks that are difficult for the stainless steel to fill.This not only hinders the development of an interlocking interface but also leads to the presence of numerous microcracks and hardened blocks along the nearly straight interface,consequently weakening the interfacial bonding strength.In metals with high work hardening rates,the conventional approach of enhancing interface interlocking and improving interfacial bonding strength by using a surface-hardened layer becomes less effective.
基金financially supported by the National Basic Research Program of China (973 Program) (no. 2012CB215500)the National Key Technology Research and Development Program of China (no. 2015BAG06B00)+1 种基金Major Program of the National Natural Science Foundation of China (no. 61433013)National Natural Science Foundation of China (no. 21206012)
文摘Arc ion plating (AIP) is applied to form Ti/(Ti,Cr)N/CrN multilayer coating on the surface of 316L stainless steel (SS316L) as bipolar plates for proton exchange membrane fuel cells (PEMFCs). The characterizations of the coating are analyzed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Interfacial contact resistance (ICR) between the coated sample and carbon paper is 4.9 m Omega cm(2) under 150 N/cm(2), which is much lower than that of the SS316L substrate. Potentiodynamic and potentiostatic tests are performed in the simulated PEMFC working conditions to investigate the corrosion behaviors of the coated sample. Superior anticorrosion performance is observed for the coated sample, whose corrosion current density is 0.12 mu A/cm(2). Surface morphology results after corrosion tests indicate that the substrate is well protected by the multilayer coating. Performances of the single cell with the multilayer coated SS316L bipolar plate are improved significantly compared with that of the cell with the uncoated SS316L bipolar plate, presenting a great potential for PEMFC application. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
文摘By a great deal of experiments,the misplating problemsof plated knitted fabrics composed of wool and Lycra arediscussed and analyzed.The factors affecting the mis-plating problems on manually operated flat knitting ma-chine include the construction and adjustment of a plat-ing feeder,wool yarn count,feeding tension,takedowntension and the ground fabric structures.Some usefulresults can be derived from these works.
基金Key R&D Plan of Shaanxi Province(2021LLRH-05-09)Shaanxi Province Youth Talent Support Program Project(CLGC202234)Sponsored by Innovative Pilot Platform for Layered Metal Composite Materials(2024CX-GXPT-20)。
文摘Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,phased array waveform shape,interface structure shape,electronic scanning,and mechanical property testing.Results show that the rolling temperature of zirconiumtitanium complex should be controlled at 760°C,and the rolling reduction of each pass should be controlled at 10%–25%.The explosive velocity to prepare zirconium-titanium-steel composite plates should be controlled at 2450–2500 m/s,the density should be 0.78 g/cm3,the stand-off height should be 12 mm,and the explosive height of Zone A and Zone B should be 45–50 mm.Explosive welding combined with rolling method reduces the impact of explosive welding and multiple heat treatment on material properties.Meanwhile,the problems of surface wrinkling and cracking,which occur during the preparation process of large-sized zirconiumtitanium-steel composite plate,can be solved.
基金supported by the National Key Re-search and Development Program of China(No.2022YFB4002100)the National Natural Science Foundation of China(No.52271136)the Natural Science Foundation of Shaanxi Province(Nos.2019TD-020 and 2021JC-06).
文摘Proton exchange membrane water electrolysis(PEMWE)is one of the most promising strategies to pro-duce green hydrogen energy,and it is crucial to exploit highly conductive and good corrosion-resistant coatings on bipolar plates(BPs),one of the core components in PEMWE cells.In this work,NbN coatings are deposited on Ti BPs by magnetron sputtering to improve the corrosion resistance and conductivity,for which the critical process parameters,such as the working pressure,partial nitrogen pressure and de-position temperature are well optimized.It is found that the compact microstructure,highly conductive δ-NbN and uniform nanoparticles play a dominant role in the synergistic improvement of the corrosion resistance and electrical conductivity of NbN coatings.The optimized NbN coatings exhibit excellent cor-rosion resistance with the low corrosion current density of 1.1×10^(-8) A cm^(-2),a high potential value of-0.005 V vs.SCE and a low ICR value of 15.8 mΩcm2@1.5 MPa.Accordingly,NbN coatings can be a promising candidate for the development of the low-cost and high-anti-corrosion Ti BPs of PEMWE.
基金Opening Foundation of Key Laboratory of Explosive Energy Utilization and Control,Anhui Province(BP20240104)Graduate Innovation Program of China University of Mining and Technology(2024WLJCRCZL049)Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_2701)。
文摘Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer composite plate by explosive welding.The microscopic properties of each bonding interface were elucidated through field emission scanning electron microscope and electron backscattered diffraction(EBSD).A methodology combining finite element method-smoothed particle hydrodynamics(FEM-SPH)and molecular dynamics(MD)was proposed for the analysis of the forming and evolution characteristics of explosive welding interfaces at multi-scale.The results demonstrate that the bonding interface morphologies of TC4/Al 6063 and Al 6063/Al 7075 exhibit a flat and wavy configuration,without discernible defects or cracks.The phenomenon of grain refinement is observed in the vicinity of the two bonding interfaces.Furthermore,the degree of plastic deformation of TC4 and Al 7075 is more pronounced than that of Al 6063 in the intermediate layer.The interface morphology characteristics obtained by FEM-SPH simulation exhibit a high degree of similarity to the experimental results.MD simulations reveal that the diffusion of interfacial elements predominantly occurs during the unloading phase,and the simulated thickness of interfacial diffusion aligns well with experimental outcomes.The introduction of intermediate layer in the explosive welding process can effectively produce high-quality titanium/aluminum alloy composite plates.Furthermore,this approach offers a multi-scale simulation strategy for the study of explosive welding bonding interfaces.
基金supported by the National Key Research and Development Program of China(No.SQ2021YFF 0600011).
文摘7039 Al alloys are widely used in armor vehicles,given the material’s high specific strength and fracture toughness.However,laminar tearing in the thickness plane of the base metal(BM),specifically in the normal direction(ND)and rolling direction(RD)plane,was occasionally observed after the welding of thick plates,resulting in premature material failure.A vertically metal-inert gas(MIG)-welded laminar tearing component of a 30 mm thick plate was analyzed to determine the factors associated with this phenomenon.The texture,residual stress,microhardness,and tensile properties were also investigated.The results indicated that the crack extended along the RD as a transcrystalline fracture and terminated at the BM.The grains near the crack grew preferentially in the(001)crystal direction.Furthermore,the tensile strength(83 MPa)and elongation(6.8%)in the RD were relatively higher than those in the ND.In particular,the primary factors for crack initiation include stronger texture,higher dislocation density,increased Al_(7)Cu_(2)Fe phases,lower proportion of small-angle grain boundaries,and varying grain sizes in different regions,leading to the fragile microstructure.The higher residual stress of the BM promotes the formation and extension of cracks.The restraining force due to fixation and welding shrinkage force transformed the crack into laminar tearing.Preventive measures of laminar tearing were also proposed.
基金supported by the Natural Science Foundation of Heilongjiang Province(No.JQ2022E004).
文摘In this paper,the work hardening and softening behavior of AZ31 magnesium alloy sheets by hard plate accumulative roll bonding(HP-ARB)process in a specific temperature range was studied for the first time,and the cyclic stress relaxation test,EBSD,TEM and other characterization methods were used.When the rolling temperature is 350℃,the grain size of magnesium sheets is refined to 4.32(±0.36)μm on average,and it shows an excellent combination of strength and plasticity.The tensile strength reaches 307(±8.52)MPa and the elongation is 12.73(±0.84)%.At this time,the curve of work hardening rate decreases smoothly and the degree of hardening is the lowest,and the amplitude of stress drop △σ_(p) in work softening test is the smallest with the increase of cycle times,which shows that the well coordination between work hardening and softening behavior has been achieved.Research has found that the combined effect of grain boundary strengthening and fine grain strengthening enhances the yield and tensile strength of magnesium sheets after three passes HP-ARB process at 350℃.This is attributed to the high degree of dislocation slip opening in the pyramidal surfaceand<c+a>,which not only coordinates the c-axis strain of the entire grain,but also promotes the slip transfer of dislocations in the fine-grained region,significantly improving the elongation of the sheets.This study provides a new idea for the forming and manufacturing of high performance magnesium alloy sheets.
文摘On January 7,2025,01:05:15 UTC(9:05 a.m.local time)southern Tibet was rocked by a M_(W)7.1 earthquake(M_(W)=moment magnitude,USGS)centered(28.639°N 87.361°E)in the Lhasa Block north of the India/Eurasia Plate boundary,in a remote area about 180 km SW of Xigaze,in Dingri County of Shigatse of the Xizang Autonomous Region(Figure 1).
文摘For the first time,the linear and nonlinear vibrations of composite rectangular sandwich plates with various geometric patterns of lattice core have been analytically examined in this work.The plate comprises a lattice core located in the middle and several homogeneous orthotropic layers that are symmetrical relative to it.For this purpose,the partial differential equations of motion have been derived based on the first-order shear deformation theory,employing Hamilton’s principle and Von Kármán’s nonlinear displacement-strain relations.Then,the nonlinear partial differential equations of the plate are converted into a time-dependent nonlinear ordinary differential equation(Duffing equation)by applying the Galerkin method.From the solution of this equation,the natural frequencies are extracted.Then,to calculate the non-linear frequencies of the plate,the non-linear equation of the plate has been solved analytically using the method of multiple scales.Finally,the effect of some critical parameters of the system,such as the thickness,height,and different angles of the stiffeners on the linear and nonlinear frequencies,has been analyzed in detail.To confirmthe solution method,the results of this research have been compared with the reported results in the literature and finite elements in ABAQUS,and a perfect match is observed.The results reveal that the geometry and configuration of core ribs strongly affect the natural frequencies of the plate.
基金supported by National Natural Science Foundation of China(Grant No.12432018,12372346)the Innovative Research Groups of the National Natural Science Foundation of China(Grant No.12221002).
文摘A typical Whipple shield consists of double-layered plates with a certain gap.The space debris impacts the outer plate and is broken into a debris cloud(shattered,molten,vaporized)with dispersed energy and momentum,which reduces the risk of penetrating the bulkhead.In the realm of hypervelocity impact,strain rate(>10^(5)s^(-1))effects are negligible,and fluid dynamics is employed to describe the impact process.Efficient numerical tools for precisely predicting the damage degree can greatly accelerate the design and optimization of advanced protective structures.Current hypervelocity impact research primarily focuses on the interaction between projectile and front plate and the movement of debris cloud.However,the damage mechanism of debris cloud impacts on rear plates-the critical threat component-remains underexplored owing to complex multi-physics processes and prohibitive computational costs.Existing approaches,ranging from semi-empirical equations to a machine learningbased ballistic limit prediction method,are constrained to binary penetration classification.Alternatively,the uneven data from experiments and simulations caused these methods to be ineffective when the projectile has irregular shapes and complicate flight attitude.Therefore,it is urgent to develop a new damage prediction method for predicting the rear plate damage,which can help to gain a deeper understanding of the damage mechanism.In this study,a machine learning(ML)method is developed to predict the damage distribution in the rear plate.Based on the unit velocity space,the discretized information of debris cloud and rear plate damage from rare simulation cases is used as input data for training the ML models,while the generalization ability for damage distribution prediction is tested by other simulation cases with different attack angles.The results demonstrate that the training and prediction accuracies using the Random Forest(RF)algorithm significantly surpass those using Artificial Neural Networks(ANNs)and Support Vector Machine(SVM).The RF-based model effectively identifies damage features in sparsely distributed debris cloud and cumulative effect.This study establishes an expandable new dataset that accommodates additional parameters to improve the prediction accuracy.Results demonstrate the model's ability to overcome data imbalance limitations through debris cloud features,enabling rapid and accurate rear plate damage prediction across wider scenarios with minimal data requirements.
基金supported by National Natural Science Foundation of China(22402115,22472094)Shaanxi Special Fund for Talent Introduction(100090/1204071055).
文摘In the process of electroless cobalt plating,the saccharin additive can significantly change the surface morphology,texture orientation,and conductivity of the cobalt coating layer.When the amount of saccharin was 3 mg·L^(-1),the cobalt coating transformed from disordered large grains to a honeycomb structure,with a preferred orientation of(002)facet on hexago-nal close-packed(HCP)cobalt crystals.The resistivity of the cobalt film decreased to 14.4μΩ·cm,and further decreased to 10.7μΩ·cm after the annealing treatment.When the concentration of saccharin was increased,the grain size was gradually refined and a“stone forest”structure was observed,with the preferred orientation remaining unchanged.The addition of saccharin also slightly improves the purity of cobalt coating to a certain extent.Through the study of the crystallization behavior of cobalt electroless plating,saccharin molecules can adsorb to specific c-sites on the cobalt dense crystal plane,inhibiting the growth of abc stacking arrangement and inducing the crystal growth in ab stacking mode,thereby achieving optimal growth of HCP(002)texture.
基金supported by the National Natural Science Foundation of China(Grant Nos:42130801,41430211,90814006,and 42072226)the“Deep-time Digital Earth”Science and Technology Leading Talents Team Funds for the Central Universities for the Frontiers Science Center for Deep-time Digital Earth,CUGB(Fundamental Research Funds for the Central UniversitiesGrant No:2652023001).
文摘How the subduction direction of the Paleo-Pacific plate beneath the Eurasian plate changes in the Early Cretaceous remains highly controversial due to the disappearance of the subducted oceanic plate.Intraplate deformation structures in the east Asian continent,however,provide excellent opportunities for reconstructing paleostress fields in continental interior in relation to the Paleo-Pacific/Eurasian plate interaction.Anisotropy of magnetic susceptibility(AMS),geological,and geochronological analyses of post-kinematic mafic dykes intruding the detachment fault zone of the Wulian metamorphic core complex(WL MCC)in Jiaodong Peninsula exemplify emplacement of mantle-sourced dykes in a WNW-ESE(301°-121°)oriented tectonic extensional setting at ca.120 Ma.In combination with the results from our previous kinematic analysis of the MCC,a ca.21°clockwise change in the direction of intraplate extension is obtained for early(135-122 Ma)extensional exhumation of the MCC to late(122-108 Ma)emplacement of the dykes.Such a change is suggested to be related to the variation in subduction direction of the Paleo-Pacific plate beneath the Eurasian plate,from westward(pre-122 Ma)to west-northwestward(post-122 Ma).
基金National Key Research and Development Program of China(2022YFB4002100)National Natural Science Foundation of China(52271136)Natural Science Foundation of Shaanxi Province(2021JC-06)。
文摘TaN coatings were deposited on Ti bipolar plates by magnetron sputtering to improve corrosion resistance and service life.The influence of N_(2) flow rate on the surface morphology,hydrophobicity,crystallinity,corrosion resistance,and interfacial contact resistance of TaN coatings was studied.Results show that as the N_(2) flow rate increases,the roughness of TaN coatings decreases firstly and then increases,and the hydrophobicity increases firstly and then decreases.At the N_(2) flow rate of 3 mL/min,TaN coating with larger grain size presents lower roughness and high hydrophobicity.The coating possesses the lowest corrosion current density of 2.82µA·cm^(−2) and the highest corrosion potential of−0.184 V vs.SCE in the simulated proton exchange membrane water electrolyser environment.After a potentiostatic polarization test for 10 h,a few corrosion pits are observed on the TaN coatings deposited at an N_(2) flow rate of 3 mL/min.After 75 h of electrolytic water performance testing,the TaN coating on bipolar plate improves the corrosion resistance and thus enhances the electrolysis efficiency(68.87%),greatly reducing the cost of bipolar plates.
文摘A theoretical analysis on the perforation of Weldox 460E steel plates struck by flat-nosed projectiles is presented using a previously developed model within a unified framework.This model contains a dimensionless empirical equation to describe the variation of energy absorbed through global deformation as a function of impact velocity.The study further investigates the energy absorption mechanisms of Weldox 460E steel plates,with particular focus on the“plateau”phenomenon,i.e.,limited increase in ballistic limit with increasing plate thickness.This phenomenon is explained and compared with results from previously studied 2024-T351 aluminium plates.The model predictions agree well with experimental data for Weldox 460E steel plates impacted by flat-nosed projectiles,including:relationship between global deformation and impact velocity,ballistic limit,residual velocity,and critical conditions for the transition of failure modes.Moreover,the model effectively predicts the“plateau”phenomenon observed in intermediate plate thickness range.It is also found that the indentation absorption energy contributes a significantly larger fraction of the total absorption energy in Weldox 460E steel plates perforated by flat-nosed projectiles than in 2024-T351 aluminium plates,due to the differences in material properties.
