The chemical reduction of carbon dioxide(CO2) has always drawn intensive attentions as it can not only remove CO2 which is the primary greenhouse gas but also produce useful fuels. Industrial synthesis of methanol uti...The chemical reduction of carbon dioxide(CO2) has always drawn intensive attentions as it can not only remove CO2 which is the primary greenhouse gas but also produce useful fuels. Industrial synthesis of methanol utilizing copper-based catalysts is a commonly used process for CO2 hydrogenation. Despite extensive efforts on improving its reaction mechanism by identifying the active sites and optimizing the operating temperature and pressure, it is still remains completely unveiled. The selectivities of CO2 electroreduction at copper electrode could mainly be towards carbon monoxide(CO), formic acid(HCOOH), methane(CH4) or ethylene(C2H4), which depends on the chemical potentials of hydrogen controlled by the applied potential. Interestingly, methanol could hardly be produced electrochemically despite utilizing metallic copper as catalysts in both processes. Moreover, the mechanistic researches have also been performed aiming to achieve the higher selectivity towards more desirable higher hydrocarbons. In this work, we review the present proposals of reaction mechanisms of copper catalyzing CO2 reduction in industrial methanol synthesis and electrochemical environment in terms of density functional theory(DFT) calculations, respectively. In addition, the influences of the simulation methods of solvation and electrochemical model at liquid-solid interface on the selectivity are discussed and compared.展开更多
基金supported by the National Natural Science Foundation of China(21333003,21303051)Shanghai Natural Science Foundation(13ZR1453000)the Recruitment Program of Global Experts(B08021)
文摘The chemical reduction of carbon dioxide(CO2) has always drawn intensive attentions as it can not only remove CO2 which is the primary greenhouse gas but also produce useful fuels. Industrial synthesis of methanol utilizing copper-based catalysts is a commonly used process for CO2 hydrogenation. Despite extensive efforts on improving its reaction mechanism by identifying the active sites and optimizing the operating temperature and pressure, it is still remains completely unveiled. The selectivities of CO2 electroreduction at copper electrode could mainly be towards carbon monoxide(CO), formic acid(HCOOH), methane(CH4) or ethylene(C2H4), which depends on the chemical potentials of hydrogen controlled by the applied potential. Interestingly, methanol could hardly be produced electrochemically despite utilizing metallic copper as catalysts in both processes. Moreover, the mechanistic researches have also been performed aiming to achieve the higher selectivity towards more desirable higher hydrocarbons. In this work, we review the present proposals of reaction mechanisms of copper catalyzing CO2 reduction in industrial methanol synthesis and electrochemical environment in terms of density functional theory(DFT) calculations, respectively. In addition, the influences of the simulation methods of solvation and electrochemical model at liquid-solid interface on the selectivity are discussed and compared.
