Low-density short-duration pulsed current-assisted aging treatment was applied to the Ti-6Al-4V-0.5Mo-0.5Zr alloy subjected to different solution treatments.The results show that numerous α_(p) phases redissolve into...Low-density short-duration pulsed current-assisted aging treatment was applied to the Ti-6Al-4V-0.5Mo-0.5Zr alloy subjected to different solution treatments.The results show that numerous α_(p) phases redissolve into the new β phase during the pulsed current-assisted aging process,and then the newly formed β phase is mainly transformed into the β_(t) phase,with occasional transition to new α_(p) phase,leading to a remarkable grain refinement,especially for the lamellarαs phases.In comparison to conventional aging treatment,the pulsed current-assisted aging approach achieves a significant enhancement in strength without degrading ductility,yielding an excellent mechanical property combination:a yield strength of 932 MPa,a tensile strength of 1042 MPa,and an elongation of 12.2%.It is primarily ascribed to the increased fraction of β_(t) phases,the obvious grain refinement effect,and the slip block effect induced by the multiple-variantαs colonies distributed within β_(t) phases.展开更多
Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively invest...Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively investigated.Macroscopic morphology,microstructure,and interfacial structure of the joints were analyzed using scanning electron microscope,energy dispersive spectrometer,and X-ray diffractometer(XRD).The results show that magnetic pulse welding of dissimilar Mg/Fe metals is achieved using an Al interlayer,which acts as a bridge for deformation and diffusion.Specifically,the AZ31B/AA1060 interface exhibits a typical wavy morphology,and a transition zone exists at the joint interface,which may result in an extremely complex microstructure.The microstructure of this transition zone differs from that of AZ31B magnesium and 1060 Al alloys,and it is identified as brittle intermetallic compounds(IMCs)Al_(3)Mg_(2) and Al_(12)Mg_(17).The transition zone is mainly distributed on the Al side,with the maximum thickness of Al-side transition layer reaching approximately 13.53μm.Incomplete melting layers with varying thicknesses are observed at the primary weld interface,while micron-sized hole defects appear in the transition zone of the secondary weld interface.The AA1060/DC56D interface is mainly straight,with only a small number of discontinuous transition zones distributed intermittently along the interface.These transition zones are characterized by the presence of the brittle IMC FeAl_(3),with a maximum thickness of about 4μm.展开更多
Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sust...Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed.展开更多
Experimental study of synthetic jet produced by pulsed direct current （DC） discharge is presented. High velocity jet is acti- vated electro-thermally by high frequency pulsed DC discharge in small cavity. A cavity o...Experimental study of synthetic jet produced by pulsed direct current （DC） discharge is presented. High velocity jet is acti- vated electro-thermally by high frequency pulsed DC discharge in small cavity. A cavity of 2.38 mm diameter cylinder bounded by circular electrode is made in a ceramic plate and a small orifice of 1.78 mm diameter is drilled in the middle of cavity. High frequency pulsed DC discharge instantaneously heats air in the cavity and produces high velocity jet at the exit of the orifice. Schlieren imaging at high framing rate of 100 kHz reveals the presence of supersonic precursor shock followed by the jet emerg- ing from the orifice. The jet velocity reaches as high as about 300 m/s. Jet with smaller cavity volume produces lesser effect and jet velocity reaches maximum at certain cavity volume with given discharge current and orifice size. As duty time of pulse increases from 5 to 20 μs at fixed frequency of 5 kHz, the jet velocity also increases and becomes nearly constant with further increase in duty time. At fixed duty time of 20 μs, higher frequency pulsing of 10 kHz produces degradation of the jet as the discharge pulse continues. The jet developed in this study is demonstrated to be strong enough to penetrate deep into supersonic boundary layer and to produce a bow shock when the jet is issued into Mach 3 supersonic flow.展开更多
The inexhaustible heat deposit in great depths （5-10 km） is a scientific fact. Such deposit occurs around the globe. Thereby, everybody is enabled to generate autonomously clean and renewable energy, ample electrici...The inexhaustible heat deposit in great depths （5-10 km） is a scientific fact. Such deposit occurs around the globe. Thereby, everybody is enabled to generate autonomously clean and renewable energy, ample electricity and heat. The economical exploration and exploitation of this superdeep geothermal heat deposit requires a novel drilling technique, because the currently only deep drilling method （Rotary） is limited to about 5 km, due to the rising costs, depending exponentially on depth. Electro-pulse-boring （EPB） is a valuable option to Rotary drilling. EPB, originally investigated in Russia, is ready to be developed for industrialization. The feasibility of EPB is proven by many boreholes drilled up to 200 m in granite （crystalline）. Estimates show outstanding low costs for drilling by EPB： 100 E/m for a borehole with a large diameter （φ） such as 20 （50 cm）, independent on depth and applicable likewise for sediments and crystalline rocks, such as granite. The current rate of penetration （ROP） of 3 m per hour is planned to be augmented up to 35 m per hour, and again, irrespective whether in sedimentary or crystalline formations. Consequently, a 10 km deep borehole with φ 50 cm will ultimately be drilled within 12 days. EPB will create new markets, such as： （i） EPB shallow drilling for geotechnics, energy piles, measures in order to mitigate natural hazards, etc., （ii） EPB deep drilling （3-5 km） for hydro-geothermics, exploration campaigns etc. and （iii） EPB super-deep drilling （5-10 km） for petro-geothermies, enabling the economic generation of electricity. The autonomous and unlimited supply with cost efficient electricity, besides ample heat, ensures reliably clean and renew- able energy, thus, high supply security. Such development will provide a substantial relief to cope with the global challenge to limit the climate change below 2 ℃. The diminution of fossil fuels, due to the energy transition in order to mitigate the climate change, implies likewise the decrease of air pollution.展开更多
Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,...Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,including bubble,electromagnetic stirring,filtration separation,fluid flow,and sedimentation,often struggle with the removal of fine inclusions.Apart from these known methods,pulsed electric current(PEC),as an emerging technology,has demonstrated immense potential and environmental advantages.PEC offers adjustable current parameters and simple equipment,making it an attractive alternative to traditional methods.Its green energy-saving features and excellent results in regulating inclusion morphology and migration,as well as inhibiting submerged entry nozzle(SEN)clogging,make it a promising technology.In comparison to continuous current technology,PEC has shown significant advantages in regulating inclusions,not only improving purification efficiency but also demonstrating outstanding performance in flow stability and energy consumption.The ability of PEC to efficiently reduce inclusion numbers enhances the purity and quality of molten steel,improving its mechanical properties.Currently,the theoretical basis for controlling the movement of inclusions by current is mainly composed of three major theories:the double electric layer theory,electromagnetic force reverse separation theory,and electric free energy drive theory.These theories together form an important framework for researchers to understand and optimize the behavior of impurity movement controlled by electric current.Looking ahead,PEC is expected to pave the way for new solutions in directional regulation of inclusion migration,efficient inclusion removal,SEN clogging prevention,and the purification of molten steel.展开更多
In this paper,we report an experimental observation of different states of multi-pulse operation in an actively Q-switched Er-doped fiber laser,which has applications in pulse coding in optical communications.The Q fa...In this paper,we report an experimental observation of different states of multi-pulse operation in an actively Q-switched Er-doped fiber laser,which has applications in pulse coding in optical communications.The Q factor is switched by an electro-optic modulator.Completely separated multiple pulses are obtained due to the short response time of the modulator.The influence of pump power and modulation frequency on output pulse state is investigated.In the experiment,the repetition rate of Q-switched pulse is not always consistent with the modulation signal.Single-pulse,single-dual-pulse,dual-pulse,dual-triple pulse,and multiple pulses are observed in one modulation period by increasing pump power.Single-pulse is also observed in two or three modulation periods by increasing the frequency of modulation signal.In addition,the waveform of modulating signal and the polarization state of modulated signal also affect the multi-pulse operation accordingly.展开更多
SnS∶Ag thin films were deposited on ITO glasses by pulse electro-deposition. By studying the effect of duty cycle on the properties of SnS∶Ag thin films, the optimum off-time(toff) is obtained to be 5 s, namely, the...SnS∶Ag thin films were deposited on ITO glasses by pulse electro-deposition. By studying the effect of duty cycle on the properties of SnS∶Ag thin films, the optimum off-time(toff) is obtained to be 5 s, namely, the optimal duty cycle is about 67%. The primary phase of SnS∶Ag films deposited on optimum parameters condition is SnS compound with good crystallization, and the films prefer to grow towards (111) plane. The films are dense, smooth and uniform with good microstructure, and the grains in the films are densely packed together, and their direct bandgap is about 1.40 eV. In addition, the bandgap of the films first rises and then drops with the increase of the duty cycle.展开更多
In a pulsed plasma thruster,the voltage distribution between the electrodes is a key factor that influences the ionization process.However,few researchers have conducted in-depth studies of this phenomenon in the past...In a pulsed plasma thruster,the voltage distribution between the electrodes is a key factor that influences the ionization process.However,few researchers have conducted in-depth studies of this phenomenon in the past.Reported here are measurements of the voltage distribution between the plates of a parallel-plate pulsed plasma thruster under different discharge voltages,based on which the variations in the total circuit inductance and resistance as well as those between the plates are calculated.The results show that the time-averaged voltage across the plates accounts for 28.7%-50.4%of the capacitor voltage.As the capacitor initial voltage increases from 1250 V to 2000 V,the voltage across the plates rises,but its proportion relative to the capacitor voltage decreases.For every 250 V increase in the capacitor initial voltage,the average voltage proportion across the plates decreases by approximately 2%-3%.Additionally,the voltage proportion decreases gradually from the end near the propellant outward.The voltage distribution ratio between the plates is correlated with the proportions of the resistance and inductance between the plates relative to the total circuit.展开更多
The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for...The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for hydrogen production.Despite remarkable advancements in this field,confronting the sluggish electrochemical kinetics and inherent high-energy consumption arising from deteriorated mass transport within PEMWE systems remains a formidable obstacle.This impediment stems primarily from the hindered protons mass transfer and the untimely hydrogen bubbles detachment.To address these challenges,we harness the inherent variability of electrical energy and introduce an innovative pulsed dynamic water electrolysis system.Compared to constant voltage electrolysis(hydrogen production rate:51.6 m L h^(-1),energy consumption:5.37 kWh Nm-^(3)H_(2)),this strategy(hydrogen production rate:66 m L h^(-1),energy consumption:3.83 kWh Nm-^(3)H_(2))increases the hydrogen production rate by approximately 27%and reduces the energy consumption by about 28%.Furthermore,we demonstrate the practicality of this system by integrating it with an off-grid photovoltaic(PV)system designed for outdoor operation,successfully driving a hydrogen production current of up to 500 mA under an average voltage of approximately 2 V.The combined results of in-situ characterization and finite element analysis reveal the performance enhancement mechanism:pulsed dynamic electrolysis(PDE)dramatically accelerates the enrichment of protons at the electrode/solution interface and facilitates the release of bubbles on the electrode surface.As such,PDE-enhanced PEMWE represents a synergistic advancement,concurrently enhancing both the hydrogen generation reaction and associated transport processes.This promising technology not only redefines the landscape of electrolysis-based hydrogen production but also holds immense potential for broadening its application across a diverse spectrum of electrocatalytic endeavors.展开更多
In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not ...In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not only stable single-pulse state, but also special mode-locked pulses with the characteristics of high energy and noisy behaviors at proper pump power and cavity polarization state. In addition, we have deeply investigated the real-time spectral evolutions of the mode-locked pulses through the dispersive Fourier transformation(DFT) technique. It can be found that the pulse regime can actually consist of a lot of small noise pulses with randomly varying intensities. We believe that these results will further enrich the nonlinear dynamical processes in the ultrafast lasers.展开更多
A hybrid control strategy has been designed and developed for the electro-hydraulic posi-tion servo control system with generalized Pulse code modulation(GPCM),which is suitable for the area where the work condition i...A hybrid control strategy has been designed and developed for the electro-hydraulic posi-tion servo control system with generalized Pulse code modulation(GPCM),which is suitable for the area where the work condition is poor and a large flow rate is required.It is difficult to control the GPCM system because the system is discrete.With consideration of the stability and speediness of the GPCM position servo control system,a control strategy is developed through the theoretical and ex-perimental analyses.The control strategy integrates the merits of Bang-Bang control,PID control and fuzzy control.With this hybrid control strategy,the electro hydraulic control system has good per-formances,and the servo control is carried out with GPCM through on-off valves.展开更多
The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front...The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front end.Traditional Chinese Medicine(TCM)practitioners analyze and diagnose the pulse patterns at the replication end.Meanwhile,the obtained pulse waveforms are analyzed and learnt by a neural network based on key diagnostic points in TCM pulse taking,which enables the determination of the corresponding relationships between different pulse waveforms and various pulse patterns in TCM pulse taking.With the support of clinical samples,an auxiliary diagnostic system for TCM pulse patterns ensures the accuracy of pulse pattern replication.展开更多
A mid-infrared femtosecond pulse laser with a single cycle and high intensity is an ideal driving light source for generating isolated attosecond pulses. Due to current experimental limitations, it is difficult to dir...A mid-infrared femtosecond pulse laser with a single cycle and high intensity is an ideal driving light source for generating isolated attosecond pulses. Due to current experimental limitations, it is difficult to directly achieve this type of laser light source in the laboratory. In this paper, we obtain such an ideal light source by adding a Ti sapphire pulse to the combined pulse laser consisting of two mid-infrared pulses. Specifically, by combining the synthesized pulse consisting of 8 fs/1200 nm/1.62 × 10^(14)W cm^(-2)and 12 fs/1800 nm/2.71 × 10^(14)W cm^(-2)with an additional 8 fs/800 nm/1.26 × 10^(14)W cm^(-2)Ti sapphire pulse, the resulting electric field waveform is very close to that of a 1170 nm femtosecond pulse with an intensity of 1.4 × 10^(15)W cm^(-2), a single-cycle pulse width, and a carrier-envelope phase of 0.25π. Numerical simulations show that both cases produce high-order harmonic emission spectra with broadband supercontinuum spectra, however, the bandwidth of the supercontinuum spectra and the harmonic intensities in the synthesized pulses are significantly better than those in the single1170 nm pulse. After inverse Fourier transform, we obtain 66 as a high-intensity isolated attosecond pulse, whose intensity is five orders of magnitude higher than that of a monochromatic field. Here, the phase differences between three combined pulse lasers have little effect on the numerical simulation results when they vary in the range of 0.3π.展开更多
Pulsed magnet technology is the only way to generate ultra-strong magnetic fields higher than 45 T so far.However,the inherently fast-changing field strength(typically on the order of 1000 T/s)poses significant challe...Pulsed magnet technology is the only way to generate ultra-strong magnetic fields higher than 45 T so far.However,the inherently fast-changing field strength(typically on the order of 1000 T/s)poses significant challenges for spectroscopic measurements which rely on time integration of signals to improve spectral qualities.In this work,we report high-sensitivity spectroscopic measurements under pulsed high magnetic fields employing the long flat-top pulsed magnetic field technique.By means of a multiple-capacitor power supply,we were able to generate pulsed high magnetic fields with controllable flat-top pulse width and field stabilities.By synchronizing spectroscopic measurements with the waveform of the flattop magnetic field,the integration time of each spectrum can be increased by up to 100 times compared with that of the conventional spectroscopic measurements under pulsed magnetic fields,thus enabling high-sensitivity spectroscopic measurements under ultra-strong pulsed magnetic fields.These findings promise an efficient way to significantly improve the performance and extend the application of optical measurements under pulsed high magnetic fields.展开更多
Doping with Ga effectively enhances the crystal quality and optical detection efficiency of zinc oxide(Zn O)single crystals,which has attracted considerable research interest in radiation detection.The application of ...Doping with Ga effectively enhances the crystal quality and optical detection efficiency of zinc oxide(Zn O)single crystals,which has attracted considerable research interest in radiation detection.The application of Zn O:Ga(GZO)in nuclear energy is particularly significant and fascinating at the fundamental level,enabling neutron/gamma discrimination while preserving the response time properties of the single crystal in sub-nanoseconds,maximizing the effective counting rate of the pulsed radiation field.In this study,the single-particle waveform discrimination characteristics of GZO were evaluated for five charged particles(α,β,H^(+),Li^(+),and O^(8+)and two prevalent uncharged particles(neutrons and gamma rays).Based on the timecorrelation single-photon counting(TCSPC)method,the luminescence decay time constants of the charged particles in the GZO crystal were determined as follows:1.21 ns for H^(+),1.50 ns for Li^(+),1.70 ns for O^(8+),1.56 ns forαparticles,and 1.09 ns forβparticles.Visible differences in the excitation time spectra curves were observed.Using the conventional time-domain or frequency-domain waveform discrimination techniques,waveform discrimination of 14.9 Me V neutrons and secondary gamma rays generated by the CPNG-6 device based on GZO scintillation was successfully implemented.The neutron signal constituted 77.93%of the total,indicating that GZO exhibited superior neutron/gamma discrimination sensitivity compared with that of a commercial stilbene crystal.Using the neutron/gamma screening outcomes,we reconstructed the voltage pulse height,charge height,and neutron multiplication time spectra of the pulsed neutron radiation field.The reconstructed neutron multiplication time spectrum exhibited a deviation of less than 3%relative to the result obtained using a commercial stilbene scintillator.This is the first report in the open literature on the neutron/gamma discrimination and reconstruction of Zn O pulsed radiation-field information.展开更多
As a critical component of pulse solid rocket motors(SRMs),the soft pulse separation device(PSD)is vital in enabling multi-pulse propulsion and has become a breakthrough in SRM engineering applications.To investigate ...As a critical component of pulse solid rocket motors(SRMs),the soft pulse separation device(PSD)is vital in enabling multi-pulse propulsion and has become a breakthrough in SRM engineering applications.To investigate the opening performance of the PSD,an axial PSD incorporating a star-shaped prefabricated defect was designed.The opening process was simulated using peridynamics,yielding the strain field distribution and the corresponding failure mode.A single-opening verification test was conducted.The simulation results showed good agreement with the experimental data,demonstrating the reliability of the peridynamic modeling approach.Furthermore,the effects of the prefabricated defect shape and depth on the opening performance of the PSD were analyzed through simulation.The research results indicate that the established constitutive model and failure criteria based on peridynamics can reasonably predict the failure location and the opening pressure of the soft PSD.Under the impact loading,the weak zone of the soft PSD firstly ruptures,and the damaged area gradually propagates along with the prefabricated defect,eventually leading to complete separation.A smaller prefabricated defect depth or a wider prefabricated defect distribution can cause a reduction in opening pressure.These research results provide valuable guidance for the preliminary design and optimization of PSDs in pulse solid rocket motors.展开更多
This study examines the high-order harmonic radiation behavior of MgO crystals driven by combined pulses based on the numerical solution of the semiconductor Bloch equation.We found that compared with the monochromati...This study examines the high-order harmonic radiation behavior of MgO crystals driven by combined pulses based on the numerical solution of the semiconductor Bloch equation.We found that compared with the monochromatic pulse,the MgO crystal can radiate a continuous harmonic spectrum with two platforms driven by the three-color combined pulse.The reason is that under the three-color combined pulse,the electron ionization and recombination can be effectively controlled within a half-optical cycle of the laser pulse.Using this continuous spectrum,we synthesized an isolated attosecond pulse with a duration of approximately 370 as.This study provides a new perspective on all-solid-state compact optical devices.展开更多
基金National Key Research and Development Program of China(2021YFB3700801)。
文摘Low-density short-duration pulsed current-assisted aging treatment was applied to the Ti-6Al-4V-0.5Mo-0.5Zr alloy subjected to different solution treatments.The results show that numerous α_(p) phases redissolve into the new β phase during the pulsed current-assisted aging process,and then the newly formed β phase is mainly transformed into the β_(t) phase,with occasional transition to new α_(p) phase,leading to a remarkable grain refinement,especially for the lamellarαs phases.In comparison to conventional aging treatment,the pulsed current-assisted aging approach achieves a significant enhancement in strength without degrading ductility,yielding an excellent mechanical property combination:a yield strength of 932 MPa,a tensile strength of 1042 MPa,and an elongation of 12.2%.It is primarily ascribed to the increased fraction of β_(t) phases,the obvious grain refinement effect,and the slip block effect induced by the multiple-variantαs colonies distributed within β_(t) phases.
文摘Dissimilar AZ31B magnesium alloy and DC56D steel were welded via AA1060 aluminum alloy by magnetic pulse welding.The effects of primary and secondary welding processes on the welded interface were comparatively investigated.Macroscopic morphology,microstructure,and interfacial structure of the joints were analyzed using scanning electron microscope,energy dispersive spectrometer,and X-ray diffractometer(XRD).The results show that magnetic pulse welding of dissimilar Mg/Fe metals is achieved using an Al interlayer,which acts as a bridge for deformation and diffusion.Specifically,the AZ31B/AA1060 interface exhibits a typical wavy morphology,and a transition zone exists at the joint interface,which may result in an extremely complex microstructure.The microstructure of this transition zone differs from that of AZ31B magnesium and 1060 Al alloys,and it is identified as brittle intermetallic compounds(IMCs)Al_(3)Mg_(2) and Al_(12)Mg_(17).The transition zone is mainly distributed on the Al side,with the maximum thickness of Al-side transition layer reaching approximately 13.53μm.Incomplete melting layers with varying thicknesses are observed at the primary weld interface,while micron-sized hole defects appear in the transition zone of the secondary weld interface.The AA1060/DC56D interface is mainly straight,with only a small number of discontinuous transition zones distributed intermittently along the interface.These transition zones are characterized by the presence of the brittle IMC FeAl_(3),with a maximum thickness of about 4μm.
基金financially supported by the Key Research and Development Program of Heilongjiang Province(No.2024ZXJ03C06)National Natural Science Foundation of China(No.52476192,No.52106237)+1 种基金Natural Science Foundation of Heilongjiang Province(No.YQ2022E027)Technology Project of China Datang Technology Innovation Co.,Ltd(No.DTKC-2024-20610).
文摘Pulsed dynamic electrolysis(PDE),driven by renewable energy,has emerged as an innovative electrocatalytic conversion method,demonstrating significant potential in addressing global energy challenges and promoting sustainable development.Despite significant progress in various electrochemical systems,the regulatory mechanisms of PDE in energy and mass transfer and the lifespan extension of electrolysis systems,particularly in water electrolysis(WE)for hydrogen production,remain insufficiently explored.Therefore,there is an urgent need for a deeper understanding of the unique contributions of PDE in mass transfer enhancement,microenvironment regulation,and hydrogen production optimization,aiming to achieve low-energy consumption,high catalytic activity,and long-term stability in the generation of target products.Here,this review critically examines the microenvironmental effects of PDE on energy and mass transfer,the electrode degradation mechanisms in the lifespan extension of electrolysis systems,and the key factors in enhancing WE for hydrogen production,providing a comprehensive summary of current research progress.The review focuses on the complex regulatory mechanisms of frequency,duty cycle,amplitude,and other factors in hydrogen evolution reaction(HER)performance within PDE strategies,revealing the interrelationships among them.Finally,the potential future directions and challenges for transitioning from laboratory studies to industrial applications are proposed.
文摘Experimental study of synthetic jet produced by pulsed direct current （DC） discharge is presented. High velocity jet is acti- vated electro-thermally by high frequency pulsed DC discharge in small cavity. A cavity of 2.38 mm diameter cylinder bounded by circular electrode is made in a ceramic plate and a small orifice of 1.78 mm diameter is drilled in the middle of cavity. High frequency pulsed DC discharge instantaneously heats air in the cavity and produces high velocity jet at the exit of the orifice. Schlieren imaging at high framing rate of 100 kHz reveals the presence of supersonic precursor shock followed by the jet emerg- ing from the orifice. The jet velocity reaches as high as about 300 m/s. Jet with smaller cavity volume produces lesser effect and jet velocity reaches maximum at certain cavity volume with given discharge current and orifice size. As duty time of pulse increases from 5 to 20 μs at fixed frequency of 5 kHz, the jet velocity also increases and becomes nearly constant with further increase in duty time. At fixed duty time of 20 μs, higher frequency pulsing of 10 kHz produces degradation of the jet as the discharge pulse continues. The jet developed in this study is demonstrated to be strong enough to penetrate deep into supersonic boundary layer and to produce a bow shock when the jet is issued into Mach 3 supersonic flow.
文摘The inexhaustible heat deposit in great depths （5-10 km） is a scientific fact. Such deposit occurs around the globe. Thereby, everybody is enabled to generate autonomously clean and renewable energy, ample electricity and heat. The economical exploration and exploitation of this superdeep geothermal heat deposit requires a novel drilling technique, because the currently only deep drilling method （Rotary） is limited to about 5 km, due to the rising costs, depending exponentially on depth. Electro-pulse-boring （EPB） is a valuable option to Rotary drilling. EPB, originally investigated in Russia, is ready to be developed for industrialization. The feasibility of EPB is proven by many boreholes drilled up to 200 m in granite （crystalline）. Estimates show outstanding low costs for drilling by EPB： 100 E/m for a borehole with a large diameter （φ） such as 20 （50 cm）, independent on depth and applicable likewise for sediments and crystalline rocks, such as granite. The current rate of penetration （ROP） of 3 m per hour is planned to be augmented up to 35 m per hour, and again, irrespective whether in sedimentary or crystalline formations. Consequently, a 10 km deep borehole with φ 50 cm will ultimately be drilled within 12 days. EPB will create new markets, such as： （i） EPB shallow drilling for geotechnics, energy piles, measures in order to mitigate natural hazards, etc., （ii） EPB deep drilling （3-5 km） for hydro-geothermics, exploration campaigns etc. and （iii） EPB super-deep drilling （5-10 km） for petro-geothermies, enabling the economic generation of electricity. The autonomous and unlimited supply with cost efficient electricity, besides ample heat, ensures reliably clean and renew- able energy, thus, high supply security. Such development will provide a substantial relief to cope with the global challenge to limit the climate change below 2 ℃. The diminution of fossil fuels, due to the energy transition in order to mitigate the climate change, implies likewise the decrease of air pollution.
基金supported by the Fundamental Research Funds for the Central Universities(No.FRF-BD-23-01).
文摘Non-metallic inclusions in steel are a significant challenge,affecting material properties and leading to issues such as stress concentration,cracking,and accelerated corrosion.Current methods for removing inclusions,including bubble,electromagnetic stirring,filtration separation,fluid flow,and sedimentation,often struggle with the removal of fine inclusions.Apart from these known methods,pulsed electric current(PEC),as an emerging technology,has demonstrated immense potential and environmental advantages.PEC offers adjustable current parameters and simple equipment,making it an attractive alternative to traditional methods.Its green energy-saving features and excellent results in regulating inclusion morphology and migration,as well as inhibiting submerged entry nozzle(SEN)clogging,make it a promising technology.In comparison to continuous current technology,PEC has shown significant advantages in regulating inclusions,not only improving purification efficiency but also demonstrating outstanding performance in flow stability and energy consumption.The ability of PEC to efficiently reduce inclusion numbers enhances the purity and quality of molten steel,improving its mechanical properties.Currently,the theoretical basis for controlling the movement of inclusions by current is mainly composed of three major theories:the double electric layer theory,electromagnetic force reverse separation theory,and electric free energy drive theory.These theories together form an important framework for researchers to understand and optimize the behavior of impurity movement controlled by electric current.Looking ahead,PEC is expected to pave the way for new solutions in directional regulation of inclusion migration,efficient inclusion removal,SEN clogging prevention,and the purification of molten steel.
基金supported by the Key Project of Tianjin Natural Science Foundation(No.20JCZDJC00500)
文摘In this paper,we report an experimental observation of different states of multi-pulse operation in an actively Q-switched Er-doped fiber laser,which has applications in pulse coding in optical communications.The Q factor is switched by an electro-optic modulator.Completely separated multiple pulses are obtained due to the short response time of the modulator.The influence of pump power and modulation frequency on output pulse state is investigated.In the experiment,the repetition rate of Q-switched pulse is not always consistent with the modulation signal.Single-pulse,single-dual-pulse,dual-pulse,dual-triple pulse,and multiple pulses are observed in one modulation period by increasing pump power.Single-pulse is also observed in two or three modulation periods by increasing the frequency of modulation signal.In addition,the waveform of modulating signal and the polarization state of modulated signal also affect the multi-pulse operation accordingly.
基金National Nature Sciences Funding of China(61076063)Key Project of Fujian Provincial Department of Science &Technology(2008I0019)Fujian Provincial Natural Science Foundation of China(2009J01285)
文摘SnS∶Ag thin films were deposited on ITO glasses by pulse electro-deposition. By studying the effect of duty cycle on the properties of SnS∶Ag thin films, the optimum off-time(toff) is obtained to be 5 s, namely, the optimal duty cycle is about 67%. The primary phase of SnS∶Ag films deposited on optimum parameters condition is SnS compound with good crystallization, and the films prefer to grow towards (111) plane. The films are dense, smooth and uniform with good microstructure, and the grains in the films are densely packed together, and their direct bandgap is about 1.40 eV. In addition, the bandgap of the films first rises and then drops with the increase of the duty cycle.
基金supported by the Beijing Natural Science Foundation(No.QY24166).
文摘In a pulsed plasma thruster,the voltage distribution between the electrodes is a key factor that influences the ionization process.However,few researchers have conducted in-depth studies of this phenomenon in the past.Reported here are measurements of the voltage distribution between the plates of a parallel-plate pulsed plasma thruster under different discharge voltages,based on which the variations in the total circuit inductance and resistance as well as those between the plates are calculated.The results show that the time-averaged voltage across the plates accounts for 28.7%-50.4%of the capacitor voltage.As the capacitor initial voltage increases from 1250 V to 2000 V,the voltage across the plates rises,but its proportion relative to the capacitor voltage decreases.For every 250 V increase in the capacitor initial voltage,the average voltage proportion across the plates decreases by approximately 2%-3%.Additionally,the voltage proportion decreases gradually from the end near the propellant outward.The voltage distribution ratio between the plates is correlated with the proportions of the resistance and inductance between the plates relative to the total circuit.
基金National Natural Science Foundation of China(No.52476192,No.52106237)Natural Science Foundation of Heilongjiang Province(No.YQ2022E027)。
文摘The transition of hydrogen sourcing from carbon-intensive to water-based methodologies is underway,with renewable energy-powered proton exchange membrane water electrolysis(PEMWE)emerging as the preeminent pathway for hydrogen production.Despite remarkable advancements in this field,confronting the sluggish electrochemical kinetics and inherent high-energy consumption arising from deteriorated mass transport within PEMWE systems remains a formidable obstacle.This impediment stems primarily from the hindered protons mass transfer and the untimely hydrogen bubbles detachment.To address these challenges,we harness the inherent variability of electrical energy and introduce an innovative pulsed dynamic water electrolysis system.Compared to constant voltage electrolysis(hydrogen production rate:51.6 m L h^(-1),energy consumption:5.37 kWh Nm-^(3)H_(2)),this strategy(hydrogen production rate:66 m L h^(-1),energy consumption:3.83 kWh Nm-^(3)H_(2))increases the hydrogen production rate by approximately 27%and reduces the energy consumption by about 28%.Furthermore,we demonstrate the practicality of this system by integrating it with an off-grid photovoltaic(PV)system designed for outdoor operation,successfully driving a hydrogen production current of up to 500 mA under an average voltage of approximately 2 V.The combined results of in-situ characterization and finite element analysis reveal the performance enhancement mechanism:pulsed dynamic electrolysis(PDE)dramatically accelerates the enrichment of protons at the electrode/solution interface and facilitates the release of bubbles on the electrode surface.As such,PDE-enhanced PEMWE represents a synergistic advancement,concurrently enhancing both the hydrogen generation reaction and associated transport processes.This promising technology not only redefines the landscape of electrolysis-based hydrogen production but also holds immense potential for broadening its application across a diverse spectrum of electrocatalytic endeavors.
基金supported by the Guangdong Basic and Applied Basic Research Foundation (No.2023A1515010093)the Shenzhen Fundamental Research Program (Stable Support Plan Program)(Nos.JCYJ20220809170611004, 20231121110828001 and 20231121113641002)the National Taipei University of Technology-Shenzhen University Joint Research Program (No.2024001)。
文摘In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not only stable single-pulse state, but also special mode-locked pulses with the characteristics of high energy and noisy behaviors at proper pump power and cavity polarization state. In addition, we have deeply investigated the real-time spectral evolutions of the mode-locked pulses through the dispersive Fourier transformation(DFT) technique. It can be found that the pulse regime can actually consist of a lot of small noise pulses with randomly varying intensities. We believe that these results will further enrich the nonlinear dynamical processes in the ultrafast lasers.
文摘A hybrid control strategy has been designed and developed for the electro-hydraulic posi-tion servo control system with generalized Pulse code modulation(GPCM),which is suitable for the area where the work condition is poor and a large flow rate is required.It is difficult to control the GPCM system because the system is discrete.With consideration of the stability and speediness of the GPCM position servo control system,a control strategy is developed through the theoretical and ex-perimental analyses.The control strategy integrates the merits of Bang-Bang control,PID control and fuzzy control.With this hybrid control strategy,the electro hydraulic control system has good per-formances,and the servo control is carried out with GPCM through on-off valves.
基金Key R&D Plan of Liaoning Province(No.202000357-JH13/103):Construction of Liaoning Traditional Chinese Medicine Industry Technology Innovation Research InstituteNational Key Research and Development Plan Special Project(No.2019JH2/10300040)。
文摘The paper is an introduction to the front-end pulse acquisition and the back-end pulse biomimetic reproduction system.This system is capable of faithfully replicating the complete pulse waveform collected at the front end.Traditional Chinese Medicine(TCM)practitioners analyze and diagnose the pulse patterns at the replication end.Meanwhile,the obtained pulse waveforms are analyzed and learnt by a neural network based on key diagnostic points in TCM pulse taking,which enables the determination of the corresponding relationships between different pulse waveforms and various pulse patterns in TCM pulse taking.With the support of clinical samples,an auxiliary diagnostic system for TCM pulse patterns ensures the accuracy of pulse pattern replication.
基金supported by the Natural Science Foundation of Jilin Province under Grant No. 20220101028JC。
文摘A mid-infrared femtosecond pulse laser with a single cycle and high intensity is an ideal driving light source for generating isolated attosecond pulses. Due to current experimental limitations, it is difficult to directly achieve this type of laser light source in the laboratory. In this paper, we obtain such an ideal light source by adding a Ti sapphire pulse to the combined pulse laser consisting of two mid-infrared pulses. Specifically, by combining the synthesized pulse consisting of 8 fs/1200 nm/1.62 × 10^(14)W cm^(-2)and 12 fs/1800 nm/2.71 × 10^(14)W cm^(-2)with an additional 8 fs/800 nm/1.26 × 10^(14)W cm^(-2)Ti sapphire pulse, the resulting electric field waveform is very close to that of a 1170 nm femtosecond pulse with an intensity of 1.4 × 10^(15)W cm^(-2), a single-cycle pulse width, and a carrier-envelope phase of 0.25π. Numerical simulations show that both cases produce high-order harmonic emission spectra with broadband supercontinuum spectra, however, the bandwidth of the supercontinuum spectra and the harmonic intensities in the synthesized pulses are significantly better than those in the single1170 nm pulse. After inverse Fourier transform, we obtain 66 as a high-intensity isolated attosecond pulse, whose intensity is five orders of magnitude higher than that of a monochromatic field. Here, the phase differences between three combined pulse lasers have little effect on the numerical simulation results when they vary in the range of 0.3π.
基金financially supported by the National Key Research and Development Program of China(Grant No.2022YFA1602700)the National Natural Science Foundation of China(Grant No.12274159)。
文摘Pulsed magnet technology is the only way to generate ultra-strong magnetic fields higher than 45 T so far.However,the inherently fast-changing field strength(typically on the order of 1000 T/s)poses significant challenges for spectroscopic measurements which rely on time integration of signals to improve spectral qualities.In this work,we report high-sensitivity spectroscopic measurements under pulsed high magnetic fields employing the long flat-top pulsed magnetic field technique.By means of a multiple-capacitor power supply,we were able to generate pulsed high magnetic fields with controllable flat-top pulse width and field stabilities.By synchronizing spectroscopic measurements with the waveform of the flattop magnetic field,the integration time of each spectrum can be increased by up to 100 times compared with that of the conventional spectroscopic measurements under pulsed magnetic fields,thus enabling high-sensitivity spectroscopic measurements under ultra-strong pulsed magnetic fields.These findings promise an efficient way to significantly improve the performance and extend the application of optical measurements under pulsed high magnetic fields.
基金supported by the National Natural Science Foundation of China(Nos.12205370,62204198,12305205,and 12105230)Young Talents Promotion Program of Shaanxi Provincial Science and Technology Association(No.20220514)。
文摘Doping with Ga effectively enhances the crystal quality and optical detection efficiency of zinc oxide(Zn O)single crystals,which has attracted considerable research interest in radiation detection.The application of Zn O:Ga(GZO)in nuclear energy is particularly significant and fascinating at the fundamental level,enabling neutron/gamma discrimination while preserving the response time properties of the single crystal in sub-nanoseconds,maximizing the effective counting rate of the pulsed radiation field.In this study,the single-particle waveform discrimination characteristics of GZO were evaluated for five charged particles(α,β,H^(+),Li^(+),and O^(8+)and two prevalent uncharged particles(neutrons and gamma rays).Based on the timecorrelation single-photon counting(TCSPC)method,the luminescence decay time constants of the charged particles in the GZO crystal were determined as follows:1.21 ns for H^(+),1.50 ns for Li^(+),1.70 ns for O^(8+),1.56 ns forαparticles,and 1.09 ns forβparticles.Visible differences in the excitation time spectra curves were observed.Using the conventional time-domain or frequency-domain waveform discrimination techniques,waveform discrimination of 14.9 Me V neutrons and secondary gamma rays generated by the CPNG-6 device based on GZO scintillation was successfully implemented.The neutron signal constituted 77.93%of the total,indicating that GZO exhibited superior neutron/gamma discrimination sensitivity compared with that of a commercial stilbene crystal.Using the neutron/gamma screening outcomes,we reconstructed the voltage pulse height,charge height,and neutron multiplication time spectra of the pulsed neutron radiation field.The reconstructed neutron multiplication time spectrum exhibited a deviation of less than 3%relative to the result obtained using a commercial stilbene scintillator.This is the first report in the open literature on the neutron/gamma discrimination and reconstruction of Zn O pulsed radiation-field information.
基金supported by the National Natural Science Foundation of China(No.12202011)the Youth Research fund of Shanghai Academy of Spaceflight Technology(KJW-KT-QNKYJJ-2022-25)China Postdoctoral Science Foundation(Nos.2024T170009,2022M710190).
文摘As a critical component of pulse solid rocket motors(SRMs),the soft pulse separation device(PSD)is vital in enabling multi-pulse propulsion and has become a breakthrough in SRM engineering applications.To investigate the opening performance of the PSD,an axial PSD incorporating a star-shaped prefabricated defect was designed.The opening process was simulated using peridynamics,yielding the strain field distribution and the corresponding failure mode.A single-opening verification test was conducted.The simulation results showed good agreement with the experimental data,demonstrating the reliability of the peridynamic modeling approach.Furthermore,the effects of the prefabricated defect shape and depth on the opening performance of the PSD were analyzed through simulation.The research results indicate that the established constitutive model and failure criteria based on peridynamics can reasonably predict the failure location and the opening pressure of the soft PSD.Under the impact loading,the weak zone of the soft PSD firstly ruptures,and the damaged area gradually propagates along with the prefabricated defect,eventually leading to complete separation.A smaller prefabricated defect depth or a wider prefabricated defect distribution can cause a reduction in opening pressure.These research results provide valuable guidance for the preliminary design and optimization of PSDs in pulse solid rocket motors.
基金supported by the Natural Science Foundation of Zhejiang Province,China(Grant No.Y23A040001)the National Natural Science Foundation of China(Grant Nos.12374029,12074145,and 11975012)+4 种基金the National Key Research and Development Program of China(Grant No.2019YFA0307700)the Research Foundation for Basic Research of Jilin ProvinceChina(Grant No.20220101003JC)the National College Students Innovation and Entrepreneurship Training Program(Grant No.202310350062)the Graduate Innovation Fund of Jilin University(Grant No.2024CX041)。
文摘This study examines the high-order harmonic radiation behavior of MgO crystals driven by combined pulses based on the numerical solution of the semiconductor Bloch equation.We found that compared with the monochromatic pulse,the MgO crystal can radiate a continuous harmonic spectrum with two platforms driven by the three-color combined pulse.The reason is that under the three-color combined pulse,the electron ionization and recombination can be effectively controlled within a half-optical cycle of the laser pulse.Using this continuous spectrum,we synthesized an isolated attosecond pulse with a duration of approximately 370 as.This study provides a new perspective on all-solid-state compact optical devices.
