The size effect rule of roller compacted concrete (RCC) fracture toughness was reached on the analysis of fracture toughness of RCC specimens, which have been done by project team. And then the rule was applied to the...The size effect rule of roller compacted concrete (RCC) fracture toughness was reached on the analysis of fracture toughness of RCC specimens, which have been done by project team. And then the rule was applied to the calculation formula of equivalent strength of crack director in the RCC arch dam, thus a simple and useful formula was reached. The study shows that the equivalent strength of crack directors increases with the increasing intensity of concrete, but the surplus rate of strength of crack directors section decreases with the increasing intensity of concrete and the distance between centers of adjacent crack directors, and that bilateral interval crack directors are more efficient in weakening the strength of section than unidirectional interval crack directors in the case of the same distance between adjacent crack director centers. A good design for crack directors of RCC arch dam is proposed via the rule.展开更多
Ions or molecules are said to be isoelectronic if they are composed of different elements but have the same number of electrons, the same number of covalent bonds and the same structure. This criterion is unfortunatel...Ions or molecules are said to be isoelectronic if they are composed of different elements but have the same number of electrons, the same number of covalent bonds and the same structure. This criterion is unfortunately not sufficient to ensure that a chemical structure is a valid chemical compound. In a previous article, a procedure has been described to draw 2D valid structural formulas: the even-odd rule. This rule has been applied first to single-bonded molecules then to single-charged single-bonded ions. It covers hypovalent, hypervalent or classic Lewis’ octet compounds. The funding principle of the even-odd rule is that each atom of the compound possesses an outer-shell filled only with pairs of electrons. The application of this rule guarantees validity of any single-covalent-bond chemical structure. In the present paper, this even-odd rule and its electron-pair criterion are checked for coherence with an effective-valence isoelectronic rule using numerous known compounds having single-covalent-bond connections. The test addresses Lewis’ octet ions or molecules as well as hypovalent and hypervalent compounds. The article concludes that the even-odd rule and the effective-valence isoelectronicity rule are coherent for known single-covalent-bond chemical compounds.展开更多
In the present research, a simple quasi-continuum model, the Cauchy-Born rule model, is used to investigate the size effects of elastic modulus for fcc metals. By considering a nanoplate model and calculating the stra...In the present research, a simple quasi-continuum model, the Cauchy-Born rule model, is used to investigate the size effects of elastic modulus for fcc metals. By considering a nanoplate model and calculating the strain energy for the nano-sized plate under tension and bending, the relationship between the elastic modulus and the plate thickness is found. Size effects of the elastic modulus are displayed by the relative differences of the elastic modulus between the nano-sized plate sample and the bulk sample. By comparing the present results with those of others, the effectiveness of the Cauchy-Born rule model in studying the size effects of material properties are shown.展开更多
In the course of time, numerous rules were proposed to predict how atoms connect through covalent bonds. Based on the classification of elements in the periodic table, the rule of eight was first proposed to draw form...In the course of time, numerous rules were proposed to predict how atoms connect through covalent bonds. Based on the classification of elements in the periodic table, the rule of eight was first proposed to draw formulas of organic compounds. The later named octet rule exhibited shortcomings when applied to inorganic compounds. Another rule, the rule of two, using covalent bonds between atoms, was proposed as an attempt to unify description of organic and inorganic molecules. This rule unfortunately never managed to expand the field of application of the octet rule to inorganic compounds. In order to conciliate organic and inorganic compounds, the recently put forward even-odd and the isoelectronicity rules suggest the creation of one group of compounds with pairs of electrons. These rules compass the rule of two for covalent bonds as well as the octet rule for organic compounds and suggest transforming bonds of multi-bonded compounds in order to unify representations of both groups of compounds. The aim of the present paper is fourfold: to extend the rule of two to every atom shells;to replace the well-known octet rule by the even-odd rule;to apply the isoelectronicity rule to each atom and to reduce the influence range of the charge of an atom in a compound. According to both rules, the drawing of one atom with its single-covalent bonds is described with electron pairs and charge positions. To illustrate the rules, they are applied to 3D configurations of clusters.展开更多
Experimental obseryations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials . exhibit various degrees of anisotrpy in elasticity and strength, and the anisotropy i...Experimental obseryations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials . exhibit various degrees of anisotrpy in elasticity and strength, and the anisotropy in strengty is normally stronger than that in elasticity.In view of some available experimental data and based on the general formulation of the constitutive equations and .failure criteria of quasi-isotropic materials established by using the theory of repesentations for tensor functions, we postulate several applicable models of the constitutive equations and strength for 3and 4-axial quasi-isotropic materials to reveal the anisotropic effects In a continued work (Part II) the anisotropic effect in strength of an infintely large plate with a single elliptical hole or crack is studied. and the proposed stiffness and strength modelsare verified in terms of micro-mechanical analyses.展开更多
Project-based learning has been in widespread use in education. However, project managers are unaware of the students’ lack of experience and treat them as if they were professional staff. This paper proposes the app...Project-based learning has been in widespread use in education. However, project managers are unaware of the students’ lack of experience and treat them as if they were professional staff. This paper proposes the application of a fuzzy failure mode and effects analysis model for project-based software engineering education. This method integrates the fuzzy rule-based system with learning agents. The agents construct the membership function from historical data. Data are processed by a clustering process that facilitates the construction of the membership function. It helps students who lack experience in risk assessment to develop their expertise in that skill. The paper also suggests a classification technique for a fuzzy rule-based system that can be used to judge risk based on a fuzzy inference system. The student project will thus be further enhanced with respect to risk assessment. We then discuss the design of experiments to verify the proposed model.展开更多
Taking into consideration the changes of the geometric shielding effect in a molecule as the energy of incident electrons varies, this paper presents an empirical fraction, which depends on the energy of incident elec...Taking into consideration the changes of the geometric shielding effect in a molecule as the energy of incident electrons varies, this paper presents an empirical fraction, which depends on the energy of incident electrons, the target＇s molecular dimension and the atomic and electronic numbers in the molecule. Using this empirical fraction, it proposes a new formulation of the additivity rule. Employing the new additivity rule, it calculates the total cross sections of electron scattering by C2H4, C6H6, C6H14 and C8H18 over the energy range from 50 to 5000eV. In order to exclude the calculation deviations caused by solving the radial Schrodinger equation of electron scattering by atoms, here the atomic cross sections are derived from the experimental total cross section results of simple molecules （H2, O2, CO） via the inversion algorithm. The quantitative total cross sections are compared with those obtained by experiments and other theories, and good agreement is obtained over a wide energy range, even at energy of several tens of eV.展开更多
基金Sponsored by the National Natural Science Foundation of China(Grant No.50179002,50709013)Liaoning Province Dr. Fund(Grant No.20071025)
文摘The size effect rule of roller compacted concrete (RCC) fracture toughness was reached on the analysis of fracture toughness of RCC specimens, which have been done by project team. And then the rule was applied to the calculation formula of equivalent strength of crack director in the RCC arch dam, thus a simple and useful formula was reached. The study shows that the equivalent strength of crack directors increases with the increasing intensity of concrete, but the surplus rate of strength of crack directors section decreases with the increasing intensity of concrete and the distance between centers of adjacent crack directors, and that bilateral interval crack directors are more efficient in weakening the strength of section than unidirectional interval crack directors in the case of the same distance between adjacent crack director centers. A good design for crack directors of RCC arch dam is proposed via the rule.
文摘Ions or molecules are said to be isoelectronic if they are composed of different elements but have the same number of electrons, the same number of covalent bonds and the same structure. This criterion is unfortunately not sufficient to ensure that a chemical structure is a valid chemical compound. In a previous article, a procedure has been described to draw 2D valid structural formulas: the even-odd rule. This rule has been applied first to single-bonded molecules then to single-charged single-bonded ions. It covers hypovalent, hypervalent or classic Lewis’ octet compounds. The funding principle of the even-odd rule is that each atom of the compound possesses an outer-shell filled only with pairs of electrons. The application of this rule guarantees validity of any single-covalent-bond chemical structure. In the present paper, this even-odd rule and its electron-pair criterion are checked for coherence with an effective-valence isoelectronic rule using numerous known compounds having single-covalent-bond connections. The test addresses Lewis’ octet ions or molecules as well as hypovalent and hypervalent compounds. The article concludes that the even-odd rule and the effective-valence isoelectronicity rule are coherent for known single-covalent-bond chemical compounds.
基金Project supported by the National Natural Science Foundation of China(Nos.11021262,10932011 and 91216108)the National Basic Research Program of China(2012CB937500)
文摘In the present research, a simple quasi-continuum model, the Cauchy-Born rule model, is used to investigate the size effects of elastic modulus for fcc metals. By considering a nanoplate model and calculating the strain energy for the nano-sized plate under tension and bending, the relationship between the elastic modulus and the plate thickness is found. Size effects of the elastic modulus are displayed by the relative differences of the elastic modulus between the nano-sized plate sample and the bulk sample. By comparing the present results with those of others, the effectiveness of the Cauchy-Born rule model in studying the size effects of material properties are shown.
文摘In the course of time, numerous rules were proposed to predict how atoms connect through covalent bonds. Based on the classification of elements in the periodic table, the rule of eight was first proposed to draw formulas of organic compounds. The later named octet rule exhibited shortcomings when applied to inorganic compounds. Another rule, the rule of two, using covalent bonds between atoms, was proposed as an attempt to unify description of organic and inorganic molecules. This rule unfortunately never managed to expand the field of application of the octet rule to inorganic compounds. In order to conciliate organic and inorganic compounds, the recently put forward even-odd and the isoelectronicity rules suggest the creation of one group of compounds with pairs of electrons. These rules compass the rule of two for covalent bonds as well as the octet rule for organic compounds and suggest transforming bonds of multi-bonded compounds in order to unify representations of both groups of compounds. The aim of the present paper is fourfold: to extend the rule of two to every atom shells;to replace the well-known octet rule by the even-odd rule;to apply the isoelectronicity rule to each atom and to reduce the influence range of the charge of an atom in a compound. According to both rules, the drawing of one atom with its single-covalent bonds is described with electron pairs and charge positions. To illustrate the rules, they are applied to 3D configurations of clusters.
文摘Experimental obseryations show that quasi-isotropic materials, such as N-axial fibre-reinforced composites and woven materials . exhibit various degrees of anisotrpy in elasticity and strength, and the anisotropy in strengty is normally stronger than that in elasticity.In view of some available experimental data and based on the general formulation of the constitutive equations and .failure criteria of quasi-isotropic materials established by using the theory of repesentations for tensor functions, we postulate several applicable models of the constitutive equations and strength for 3and 4-axial quasi-isotropic materials to reveal the anisotropic effects In a continued work (Part II) the anisotropic effect in strength of an infintely large plate with a single elliptical hole or crack is studied. and the proposed stiffness and strength modelsare verified in terms of micro-mechanical analyses.
文摘Project-based learning has been in widespread use in education. However, project managers are unaware of the students’ lack of experience and treat them as if they were professional staff. This paper proposes the application of a fuzzy failure mode and effects analysis model for project-based software engineering education. This method integrates the fuzzy rule-based system with learning agents. The agents construct the membership function from historical data. Data are processed by a clustering process that facilitates the construction of the membership function. It helps students who lack experience in risk assessment to develop their expertise in that skill. The paper also suggests a classification technique for a fuzzy rule-based system that can be used to judge risk based on a fuzzy inference system. The student project will thus be further enhanced with respect to risk assessment. We then discuss the design of experiments to verify the proposed model.
基金Project supported by the National Natural Science Foundation of China (Grant No 10574039)the Program for Science and Technology Innovation Talents in Universities of Henan Province in China (Grant No 2008HASTIT008)
文摘Taking into consideration the changes of the geometric shielding effect in a molecule as the energy of incident electrons varies, this paper presents an empirical fraction, which depends on the energy of incident electrons, the target＇s molecular dimension and the atomic and electronic numbers in the molecule. Using this empirical fraction, it proposes a new formulation of the additivity rule. Employing the new additivity rule, it calculates the total cross sections of electron scattering by C2H4, C6H6, C6H14 and C8H18 over the energy range from 50 to 5000eV. In order to exclude the calculation deviations caused by solving the radial Schrodinger equation of electron scattering by atoms, here the atomic cross sections are derived from the experimental total cross section results of simple molecules （H2, O2, CO） via the inversion algorithm. The quantitative total cross sections are compared with those obtained by experiments and other theories, and good agreement is obtained over a wide energy range, even at energy of several tens of eV.
