The globe faces an urgent need to close the energy demand-supply gap.Addressing this difficulty requires constructing a Hybrid Renewable Energy System(HRES),which has proven to be the most appropriate solution.HRES al...The globe faces an urgent need to close the energy demand-supply gap.Addressing this difficulty requires constructing a Hybrid Renewable Energy System(HRES),which has proven to be the most appropriate solution.HRES allows for integrating two or more renewable energy resources,successfully addressing the issue of intermittent availability of non-conventional energy resources.Optimization is critical for improving the HRES’s performance parameters during implementation.This study focuses on HRES using solar and biomass as renewable energy supplies and appropriate energy storage technologies.However,energy fluctuations present a problem with the power quality of HRES.To address this issue,the research paper introduces the Generalized Dynamic Progressive Neural Fuzzy Controller(GDPNFC),which regulates power flow within the proposed HRES.Furthermore,a unique approach called Enhanced Multi-Objective Monarch Butterfly Optimization(EMMBO)is used to optimize technical parameters.The simulation tool used in the research work is HOMER(Hybrid Optimization of Multiple Energy Resources)-PRO,and the system’s power quality is assessed using MATLAB 2016.The research paper concludes with comparing the performance of existing systems to the proposed system in terms of power loss and Total Harmonic Distortion(THD).It was established that the proposed technique involving EMMBO outperformed existing methods in technical optimization.展开更多
Due to development of distribution systems and increase in electricity demand,the use of capacitor banks increases.From the other point of view,nonlinear loads generate and inject considerable harmonic currents into p...Due to development of distribution systems and increase in electricity demand,the use of capacitor banks increases.From the other point of view,nonlinear loads generate and inject considerable harmonic currents into power system.Under this condition if capacitor banks are not properly selected and placed in the power system,they could amplify and propagate these harmonics and deteriorate power quality to unacceptable levels.With attention of disadvantages of passive filters,such as occurring resonance,nowadays the usage of this type of harmonic compensator is restricted.On the other side,one of parallel multi-function compensating devices which are recently used in distribution system to mitigate voltage sag and harmonic distortion,performs power factor correction,and improves the overall power quality as active power conditioner(APC).Therefore,the utilization of APC in harmonic distorted system can affect and change the optimal location and size of shunt capacitor bank under harmonic distortion condition.This paper presents an optimization algorithm for improvement of power quality using simultaneous optimal placement and sizing of APC and shunt capacitor banks in radial distribution networks in the presence of voltage and current harmonics.The algorithm is based on particle swarm optimization(PSO).The objective function includes the cost of power losses,energy losses and those of the capacitor banks and APCs.展开更多
The generation of photovoltaic(PV)solar energy is increasing continuously because it is renewable,unlimited,and clean energy.In the past,generation systems depended on non-renewable sources such as oil,coal,and gas.Th...The generation of photovoltaic(PV)solar energy is increasing continuously because it is renewable,unlimited,and clean energy.In the past,generation systems depended on non-renewable sources such as oil,coal,and gas.Therefore,this paper assesses the performance of a 51 kW PV solar power plant connected to a low-voltage grid to feed an administrative building in the 6th of October City,Egypt.The performance analysis of the considered grid-connected PV system is carried out using power system simulator for Engineering(PSS/E)software.Where the PSS/E program,monitors and uses the power analyzer that displays the parameters and measures some parameters such as current,voltage,total power,power factor,frequency,and current and voltage harmonics,the used inverter from the type of grid inverter for the considered system.The results conclude that when the maximum solar radiation is reached,the maximum current can be obtained from the solar panels,thus obtaining the maximum power and power factor.Decreasing total voltage harmonic distortion,a current harmonic distortion within permissible limits using active harmonic distortion because this type is fast in processing up to 300 microseconds.The connection between solar stations and the national grid makes the system more efficient.展开更多
To reduce the negative impact of the power amplifier(PA)nonlinear distortion caused by the orthogonal frequency division multiplexing(OFDM)waveform with high peak-to-average power ratio(PAPR)in integrated radar and co...To reduce the negative impact of the power amplifier(PA)nonlinear distortion caused by the orthogonal frequency division multiplexing(OFDM)waveform with high peak-to-average power ratio(PAPR)in integrated radar and communication(RadCom)systems is studied,the channel estimation in passive sensing scenarios.Adaptive channel estimation methods are proposed based on different pilot patterns,considering nonlinear distortion and channel sparsity.The proposed methods achieve sparse channel results by manipulating the least squares(LS)frequency-domain channel estimation results to preserve the most significant taps.The decision-aided method is used to optimize the sparse channel results to reduce the effect of nonlinear distortion.Numerical results show that the channel estimation performance of the proposed methods is better than that of the conventional methods under different pilot patterns.In addition,the bit error rate performance in communication and passive radar detection performance show that the proposed methods have good comprehensive performance.展开更多
As an advanced device for observing atmospheric winds,the spaceborne Doppler Asymmetric Spatial Heterodyne(DASH)interferometer also encounters challenges associated with phase distortion,par-ticularly in limb sounding...As an advanced device for observing atmospheric winds,the spaceborne Doppler Asymmetric Spatial Heterodyne(DASH)interferometer also encounters challenges associated with phase distortion,par-ticularly in limb sounding scenarios.This paper discusses interferogram modeling and phase distortion cor-rection techniques for spaceborne DASH interferometers.The modeling of phase distortion interferograms with and without Doppler shift for limb observation was conducted,and the effectiveness of the analytical expression was verified through numerical simulation.The simulation results indicate that errors propagate layer by layer while using the onion-peeling inversion algorithm to handle phase-distorted interferograms.In contrast,the phase distortion correction algorithm can achieve effective correction.This phase correction method can be successfully applied to correct phase distortions in the interferograms of the spaceborne DASH interferometer,providing a feasible solution to enhance its measurement accuracy.展开更多
Improvements in surgical techniques have led to 90% success in the surgical repair of rhegmatogenous retinal detachment(RRD).However,anatomical reattachment of the retina does not ensure complete recovery of visual fu...Improvements in surgical techniques have led to 90% success in the surgical repair of rhegmatogenous retinal detachment(RRD).However,anatomical reattachment of the retina does not ensure complete recovery of visual function.The incidence of metamorphopsia remains the most common postoperative complaint,from 24% to 88.6%.Currently,the risk factors of metamorphopsia are categorized into macular involvement,retinal shift,outer retinal folds,subretinal fluid,secondary epiretinal membrane,outer retinal layer damage,and surgical approach.The associations of metamorphopsia with postoperative best-corrected visual acuity and postoperative vision-related quality of life were still controversial.The most popular methods for assessment of metamorphopsia remain the Amsler grid and M-Charts.Most treatments cannot progress beyond the management of negative visual sensations,through methods such as occlusion therapy and aniseikonia-correcting spectacles.The main treatment approach involves RRD prevention and the management of risk factors that can lead to postoperative metamorphopsia after RRD repair.Additional research concerning metamorphopsia treatment,further upgrades of auxiliary inspection methods,and more accurate microstructural assessments are needed to address this common complication.展开更多
Sulfide-based all-solid-state lithium batteries suffer from electrochemo-mechanical damage to Ni-rich oxide-based cathode active materials(CAMs),primarily caused by severe volume changes,results in significant stress ...Sulfide-based all-solid-state lithium batteries suffer from electrochemo-mechanical damage to Ni-rich oxide-based cathode active materials(CAMs),primarily caused by severe volume changes,results in significant stress and strain,causes micro-cracks and interfacial contact loss at potentials>4.3 V(vs.Li/Li^(+)).Quantifying micro-cracks and voids in CAMs can reveal the degradation mechanisms of Ni-rich oxidebased cathodes during electrochemical cycling.Nonetheless,the origin of electrochemical-mechanical damage remains unclear.Herein,We have developed a multifunctional PEG-based soft buffer layer(SBL)on the surface of carbon black(CB).This layer functions as a percolation network in the single crystal LiNi_(0.83)Co_(0.07)Mn_(0.1)O_(2)and Li_(6)PS_(5)Cl composite cathode layer,ensuring superior ionic conductivity,reducing void formation and particle cracking,and promoting uniform utilization of the cathode active material in all-solid-state lithium batteries(ASSLBs).High-angle annular dark-field STEM combined with nanoscale X-ray holo-tomography and plasma-focused ion beam scanning electron microscopy confirmed that the PEG-based SBL mitigated strain induced by reaction heterogeneity in the cathode.This strain produces lattice stretches,distortions,and curved transition metal oxide layers near the surface,contributing to structural degradation at elevated voltages.Consequently,ASSLBs with a LiNi_(0.83)Co_(0.07)Mn_(0.1)O_(2)cathode containing LCCB-10(CB/PEG mass ratio:100/10)demonstrate a high areal capacity(2.53 mAh g^(-1)/0.32 mA g^(-1))and remarkable rate capability(0.58 mAh g^(-1)at 1.4 mA g^(-1)),with88%capacity retention over 1000 cycles.展开更多
Intergrowth ferroelectric semiconductors with excellent spontaneous polarization field are highly promising piezo-photocatalytic candidate materials.In addition,developing structural design and revealing polarization ...Intergrowth ferroelectric semiconductors with excellent spontaneous polarization field are highly promising piezo-photocatalytic candidate materials.In addition,developing structural design and revealing polarization enhancement in-depth mechanism are top priorities.Herein,we introduce the intergrowth ferroelectrics Bi_(7)Ti_(4)NbO_(21)thin-layer nanosheets for piezo-photocatalytic CO_(2)reduction.Density functional theory(DFT)calculations indicate that interlayer lattice mismatch leads to increased tilting and rotation angle of Ti/NbO_(6)octahedra on perovskite-like layers,serving as the main reason for increased polarization.Furthermore,the tilting and rotation angle of the interlayer octahedron further increase under stress,suggesting a stronger driving force generated to facilitate charge carrier separation efficiency.Meanwhile,Bi_(7)Ti_(4)NbO_(21)nanosheets provide abundant active sites to effectively adsorb CO_(2)and acquire sensitive stress response,thereby presenting synergistically advanced piezo-photocatalytic CO_(2)reduction activity with a high CO generation rate of 426.97μmol g^(-1)h^(-1).Our work offers new perspectives and directions for initiating and investigating the mechanisms of high-performance intergrowth piezo-photocatalysts.展开更多
1.C.Li,"Holding‘China Inc.’Together:The CCP and The Rise of China’s Yangqi",The China Quarterly,Vol.228,2016,pp.927-949.2.J.Gao,"‘Bypass the Lying Mouths’:How Does the CCP Tackle Information Distor...1.C.Li,"Holding‘China Inc.’Together:The CCP and The Rise of China’s Yangqi",The China Quarterly,Vol.228,2016,pp.927-949.2.J.Gao,"‘Bypass the Lying Mouths’:How Does the CCP Tackle Information Distortion at Local Levels?",The China Quarterly,Vol.228,2016,pp.950-969.3.C.Sorace,"Party Spirit Made Flesh:The Production of Legitimacy in the Aftermath of the 2008Sichuan Earthquake",The China Journal,Vol.76,2016,pp.41-62.4.Y.Yeo,"Complementing the Local Discipline Inspection Commissions of the CCP:Empowerment of the Central Inspection Groups",Journal of Contemporary China,Vol.25,No.97,2016,pp.59-74.展开更多
The conversion of CO_(2)to dimethyl carbonate(DMC)offers a promising route for CO_(2)utilization.In this study,four CeO2 catalysts with distinct nanostructures were synthesized via a template-free hydrothermal method ...The conversion of CO_(2)to dimethyl carbonate(DMC)offers a promising route for CO_(2)utilization.In this study,four CeO2 catalysts with distinct nanostructures were synthesized via a template-free hydrothermal method by systematically varying the types and concentrations of precipitants as well as the hydrothermal reaction conditions,and they were employed for DMC synthesis from CO_(2)and methanol.The atomic arrangements of CeO_(2)varied significantly with its morphology,leading to differences in lattice distortion,which directly influenced the concentration of oxygen vacancies.Notably,the CeO_(2)nanospheres,which exhibited the highest lattice distortion and oxygen vacancy concentration,achieved a DMC yield(11.12 mmol/g)48 times greater than that of the nanocubes(0.23 mmol/g).The results indicated that oxygen vacancies played a pivotal role in the catalytic process by facilitating the adsorption and activation of CO_(2)to form bidentate carbonates,as well as activating methanol to generate methoxy species.These processes collectively promoted the formation of the key intermediate(*CH3OCOO).This study proposes a strategy to enhance the oxygen vacancy concentration by increasing lattice distortion,providing valuable insights for designing high-performance CeO_(2)catalysts for DMC synthesis.展开更多
Despite the global attention towards pollution,it remains a significant global threat and challenge for both developed and developing countries.Urbanization and economic development influence different types of pollut...Despite the global attention towards pollution,it remains a significant global threat and challenge for both developed and developing countries.Urbanization and economic development influence different types of pollution.Visual pollution is considered a new phenomenon referring to the impact of existing and growing mainstream pollution which impairs an individual’s ability to enjoy visits or views.Recently,Jordanian cities have expanded in response to urbanization and ongoing development.Irbid City has the second largest population in Jordan after the capital Amman City highest population density in Jordan.In the modern era,Irbid City dramatically increased in population and dimension.The growth of the demographic population has been significant and has led to overpopulation,rapid urbanization,and unresolved problems associated with spatial planning and infrastructures leading to different types of pollution including visual pollution.The study area focuses on the city center with the most crowded population through field visits and actual observations.The study technique is descriptive and analytical,with a focus on meticulous monitoring and a follow-up-based questionnaire which is a tool for the study,involving data collection,classification,presentation,analysis,interpretation,and exploration to identify new facts and generalizations that can help solve current issues of visual pollution.The study provides recommendations for Irbid Municipal to eliminate visual pollution,in parallel with stricter supervision from the municipality during the building process to ensure proper implementation of the new rules,adopting an integrated policy for the city with the rest of the social,political,sensory,cultural,economic,and functional aspects,so that this policy is in the short and long term.展开更多
Indian Railways have been the largest people moving transport infrastructure in India.Over the years the systems and trains have been upgraded resulting in both better passenger amenities and reduction in travel time....Indian Railways have been the largest people moving transport infrastructure in India.Over the years the systems and trains have been upgraded resulting in both better passenger amenities and reduction in travel time.The newest addition is the Vande Bharat Express,a semi-high-speed train that was introduced in India in 2019.The train currently runs between 10 routes and has brought significant changes to India’s railway network.This article explores the introduction of Vande Bharat Express trains in India and its effects on the country’s interstation time-space shrinkage using cartographic techniques.The cartographic techniques like stepwise multidimensional scaling and interpolation using the distance cartogram plugin in QGIS are mainly used for generating the time-space maps for various speeds.The limitations of these techniques and the methods to overcome those limitations are also explored in this article.展开更多
Images with complementary spectral information can be recorded using image sensors that can identify visible and near-infrared spectrum.The fusion of visible and nearinfrared(NIR)aims to enhance the quality of images ...Images with complementary spectral information can be recorded using image sensors that can identify visible and near-infrared spectrum.The fusion of visible and nearinfrared(NIR)aims to enhance the quality of images acquired by video monitoring systems for the ease of user observation and data processing.Unfortunately,current fusion algorithms produce artefacts and colour distortion since they cannot make use of spectrum properties and are lacking in information complementarity.Therefore,an information complementarity fusion(ICF)model is designed based on physical signals.In order to separate high-frequency noise from important information in distinct frequency layers,the authors first extracted texture-scale and edge-scale layers using a two-scale filter.Second,the difference map between visible and near-infrared was filtered using the extended-DoG filter to produce the initial visible-NIR complementary weight map.Then,to generate a guide map,the near-infrared image with night adjustment was processed as well.The final complementarity weight map was subsequently derived via an arctanI function mapping using the guide map and the initial weight maps.Finally,fusion images were generated with the complementarity weight maps.The experimental results demonstrate that the proposed approach outperforms the state-of-the-art in both avoiding artificial colours as well as effectively utilising information complementarity.展开更多
5-Hydroxymethylfurfural electrooxidation reaction(HMFOR)provides a promising route for producing highvalue-added compounds.It is generally believed that NiOOH is the active species in HMFOR process,but its inherently ...5-Hydroxymethylfurfural electrooxidation reaction(HMFOR)provides a promising route for producing highvalue-added compounds.It is generally believed that NiOOH is the active species in HMFOR process,but its inherently poor electron transfer ability leads to limited catalytic activity.In this work,a W doping strategy is adopted to regulate the electron transfer between NiOOH and reaction molecules.Electrochemical results show that W-doped Ni_(5)P_(4)-R exhibits excellent electrochemical performance for the oxidation of HMF to FDCA with the conversion of HMF and yield of FDCA both close to~100%.Density functional theory and in-situ characterization reveal that the introduction of W causes the distortion of NiOOH lattice,resulting in the Jahn-Teller distortion and the elimination of orbital degeneracy,thereby broadening the e_(g)^(*)band of NiOOH.This feature is beneficial for the electron transfer between W-doped NiOOH and HMF(1.31 e^(-)),thereby promoting the C–H bond activation of the aldehyde group in HMF and effectively reducing the energy barrier of rate-determining step(RDS).展开更多
The traditional orbit determination method based on pulsar profile distortion can determine the six elements of the orbit.However,the estimation accuracies of these methods are limited and the computational load of a ...The traditional orbit determination method based on pulsar profile distortion can determine the six elements of the orbit.However,the estimation accuracies of these methods are limited and the computational load of a six-dimensional search is huge.To solve this problem,the differential-geometry-based Multi-dimensional Joint Position-Velocity Estimation(MJPVE)using Crab pulsar profile distortion is proposed in this paper.Firstly,through theoretical analysis,it is found that the pulsar profile distortion caused by the initial state error in some joint positionvelocity directions is very small.In other words,the accuracies of estimation in these directions are very low.Namely,the search dimension can be reduced,which in turn greatly reduces the computational load.Then,we construct the chi-squared function of the pulsar profile with respect to the estimation error in joint position-velocity direction and use differential geometry to find the joint position-velocity directions corresponding to different degrees of distortion.Finally,we utilize the grid search based on directory folding in these joint position-velocity directions corresponding to large degrees of distortion to obtain the joint position-velocity estimation.The experimental results show that compared with the grouping bi-chi-squared inversion method,MJPVE has high precision and extensive navigation information.展开更多
In response to the complex working conditions of the power grid caused by the high proportion of new energy access,which leads to insufficient output accuracy of the second-order generalized integrator(SOGI)phaselocke...In response to the complex working conditions of the power grid caused by the high proportion of new energy access,which leads to insufficient output accuracy of the second-order generalized integrator(SOGI)phaselocked loop,this article proposes an improved frequency adaptive phase-locked loop structure for SOGI.Firstly,an amplitude compensation branch is introduced to compensate for the SOGI tracking fundamental frequency signal,ensuring the accuracy of the SOGI output orthogonal signal under frequency fluctuation conditions.Secondly,by cascading two adaptive SOGI modules,the suppression capability of low-order harmonics and Direct Current(DC)components has been improved.Finally,the positive and negative sequence separation method of orthogonal signals is introduced to eliminate the influence of unbalanced components on the phase-locked loop.The comparative experiment with the classic SOGI-PLL method shows that the proposed phase-locked loop structure effectively improves the accuracy of power grid synchronization detection under complex working conditions such as harmonic components,unbalanced components,and frequency fluctuations.It can complete frequency detection within 1.5 power frequency cycles,and the detected fundamental frequency positive sequence voltage has a higher sinuosity and harmonic distortion rate within 0.5%.展开更多
Size reduction of the gas turbines(GT)by reducing the inlet S-shaped diffuser length increases the powerto-weight ratio.It improves the techno-economic features of the GT by lesser fuel consumption.However,this Length...Size reduction of the gas turbines(GT)by reducing the inlet S-shaped diffuser length increases the powerto-weight ratio.It improves the techno-economic features of the GT by lesser fuel consumption.However,this Length reduction of a bare S-shaped diffuser to an aggressive S-shaped diffuser would risk flow separation and performance reduction of the diffuser and the air intake of the GT.The objective of this research is to propose and assess fitted energy promoters(EPs)to enhance the S-shaped diffuser performance by controlling and modifying the flow in the high bending zone of the diffuser.After experimental assessment,the work has been extended to cover more cases by numerical investigations on bare,bare aggressive,and aggressive with energy promoters S-shaped diffusers.Three types of EPs,namely co-rotating low-profile,co-rotating streamline sheet,and trapezoidal submerged EPs were tested with various combinations over a range of Reynolds numbers from 40,000 to 75,000.The respective S-shaped diffusers were simulated by computational fluid dynamics(CFD)using ANSYS software adopting a steady,3D,standard k-εturbulence model to acquire the details of the flow structure,which cannot be visualized in the experiment.The diffuser performance has been evaluated by the performance indicators of static pressure recovery coefficient,total pressure loss coefficient,and distortion coefficient(DC(45°)).The enhancements in the static pressure recovery of the S-shaped aggressive diffuser with energy promoters are 19.5%,22.2%,and 24.5%with EPs at planes 3,4 and 5,respectively,compared to the aggressive bare diffuser.In addition,the installation of the EPs resulted in a DC(45°)reduction at the outlet plane of the diffuser of about 43%at Re=40,000.The enhancements in the performance parameters confirm that aggravating the internal flow eliminates the flow separation and enhances the GT intake efficiency.展开更多
The Vienna rectifier is a widely adopted solution for high-power rectification due to its efficiency and straightforward design.However,its performance can degrade under unbalanced three phase voltage conditions,leadi...The Vienna rectifier is a widely adopted solution for high-power rectification due to its efficiency and straightforward design.However,its performance can degrade under unbalanced three phase voltage conditions,leading to current zero-crossing distortion and compromised dynamic response.This paper investigates the causes of these distortions,identifying a phase shift between the input current and the grid voltage as a primary factor,and proposes an effective distortion phase identification strategy.Furthermore,the dynamic performance is enhanced through improved current reference calculations and a refined power feedforward strategy.This approach optimizes the system's response to load changes and maintains output voltage stability under unbalanced conditions.Simulation results validate the effectiveness of the proposed methods in reducing current distortion and improving overall performance.展开更多
This study designs and synthesizes highly dense Li2 Mg_(6)ZnTi_(6)O_(20)microwave dielectric ceramics based on a high-entropy strategy,focusing on achieving stable structures,low sintering temperatures,and excellent c...This study designs and synthesizes highly dense Li2 Mg_(6)ZnTi_(6)O_(20)microwave dielectric ceramics based on a high-entropy strategy,focusing on achieving stable structures,low sintering temperatures,and excellent comprehensive performance.The ceramics exhibit a predominant face-centered cubic disordered phase(Fd-3 m)sintered at 1200-1280°C,alongside an increased presence of the second phase MgTiO3 at higher temperatures.Remarkably,these ceramics demonstrate excellent microwave dielectric properties(ε_(r)=16.69,Q×f=88,230 GHz,andτ_(f)=−36.5 ppm/°C).Additionally,we have explored the addition of x wt%LiF(1≤x≤5)to the Li2 Mg_(6)ZnTi_(6)O_(20)ceramics to enhance their applicability.The ceramics feature a spinel structure for LiF contents up to 3 wt%,while higher LiF concentrations induce the formation of a secondary phase,LiTiO2,characterized by a rock salt structure.Notably,the lattice distortion induced by LiF leads to a constant decrease in ε_(r).A moderate degree of lattice distortion serves to enhance the lattice stability of ceramics,which is reflected in increased lattice energy.Excellent microwave dielectric properties(ε_(r)=16.23,Q×f=89,728 GHz,τ_(f)=−43.5 ppm/°C)were obtained for x=3 ceramic sintered at 1140°C.Even at x=5,the ceramic retains excellent microwave dielectric properties(ε_(r)=16.02,Q×f=63,079 GHz,τ_(f)=−26 ppm/°C)at a low sintering temperature of 900°C.This work realizes the multiple effects of LiF and confirms good chemical compatibility with silver for LTCC(low-temperature co-fired ceramics)applications.展开更多
Fe-N-C catalysts are promising substitutes for precious-metal platinum in acidic oxygen reduction reactions(ORR),yet their moderate intrinsic activity and susceptibility to reactive oxygen species(ROS)-induced degrada...Fe-N-C catalysts are promising substitutes for precious-metal platinum in acidic oxygen reduction reactions(ORR),yet their moderate intrinsic activity and susceptibility to reactive oxygen species(ROS)-induced degradation hinder practical implementation.Herein,we fabricate a Ru-Fe dual-site catalyst(RuFe-N-C)through a two-step pyrolysis strategy.Structural characterization reveals atomic-scale proximity between Ru single atoms and Fe-N_(4) moieties,exhibiting a projected distance of~1.7Å.This configuration induces Fe–N bond elongation accompanied by 2.5%lattice distortion.The optimized RuFe-N-C catalyst exhibits high ORR performance,with a half-wave potential(E_(1/2))of 0.840 V and peak power density(P_(max))of 938 mW cm^(-2) under 150 kPa absolute H_(2)-O_(2).These metrics signify substantial enhancements relative to conventional Fe-N-C benchmarks(+21 mV in E_(1/2) and+42%in P_(max)).Moreover,the catalyst maintains outstanding stability,showing merely 17 mV E_(1/2) decay after 10000 accelerated durability test(ADT)cycles.Experimental analyses reveal a bifunctional mechanism:(1)Adjacent Ru sites substantially enhance the intrinsic ORR activity of Fe-N_(4) moieties,delivering a notable turnover frequency(TOF=17.86 e site^(-1) s^(-1) at 0.85 V vs.RHE)that exceeds state-of-the-art Fe-N-C benchmarks by 1-2 orders of magnitude(<1 e site^(-1) s^(-1));(2)Ru centers function as electron relays that facilitate ROS scavenging,thus suppressing degradation.This work establishes a paradigm for engineering bimetallic single-atom catalysts through synergistic electronic modulation to concurrently enhance activity and stability.展开更多
文摘The globe faces an urgent need to close the energy demand-supply gap.Addressing this difficulty requires constructing a Hybrid Renewable Energy System(HRES),which has proven to be the most appropriate solution.HRES allows for integrating two or more renewable energy resources,successfully addressing the issue of intermittent availability of non-conventional energy resources.Optimization is critical for improving the HRES’s performance parameters during implementation.This study focuses on HRES using solar and biomass as renewable energy supplies and appropriate energy storage technologies.However,energy fluctuations present a problem with the power quality of HRES.To address this issue,the research paper introduces the Generalized Dynamic Progressive Neural Fuzzy Controller(GDPNFC),which regulates power flow within the proposed HRES.Furthermore,a unique approach called Enhanced Multi-Objective Monarch Butterfly Optimization(EMMBO)is used to optimize technical parameters.The simulation tool used in the research work is HOMER(Hybrid Optimization of Multiple Energy Resources)-PRO,and the system’s power quality is assessed using MATLAB 2016.The research paper concludes with comparing the performance of existing systems to the proposed system in terms of power loss and Total Harmonic Distortion(THD).It was established that the proposed technique involving EMMBO outperformed existing methods in technical optimization.
文摘Due to development of distribution systems and increase in electricity demand,the use of capacitor banks increases.From the other point of view,nonlinear loads generate and inject considerable harmonic currents into power system.Under this condition if capacitor banks are not properly selected and placed in the power system,they could amplify and propagate these harmonics and deteriorate power quality to unacceptable levels.With attention of disadvantages of passive filters,such as occurring resonance,nowadays the usage of this type of harmonic compensator is restricted.On the other side,one of parallel multi-function compensating devices which are recently used in distribution system to mitigate voltage sag and harmonic distortion,performs power factor correction,and improves the overall power quality as active power conditioner(APC).Therefore,the utilization of APC in harmonic distorted system can affect and change the optimal location and size of shunt capacitor bank under harmonic distortion condition.This paper presents an optimization algorithm for improvement of power quality using simultaneous optimal placement and sizing of APC and shunt capacitor banks in radial distribution networks in the presence of voltage and current harmonics.The algorithm is based on particle swarm optimization(PSO).The objective function includes the cost of power losses,energy losses and those of the capacitor banks and APCs.
文摘The generation of photovoltaic(PV)solar energy is increasing continuously because it is renewable,unlimited,and clean energy.In the past,generation systems depended on non-renewable sources such as oil,coal,and gas.Therefore,this paper assesses the performance of a 51 kW PV solar power plant connected to a low-voltage grid to feed an administrative building in the 6th of October City,Egypt.The performance analysis of the considered grid-connected PV system is carried out using power system simulator for Engineering(PSS/E)software.Where the PSS/E program,monitors and uses the power analyzer that displays the parameters and measures some parameters such as current,voltage,total power,power factor,frequency,and current and voltage harmonics,the used inverter from the type of grid inverter for the considered system.The results conclude that when the maximum solar radiation is reached,the maximum current can be obtained from the solar panels,thus obtaining the maximum power and power factor.Decreasing total voltage harmonic distortion,a current harmonic distortion within permissible limits using active harmonic distortion because this type is fast in processing up to 300 microseconds.The connection between solar stations and the national grid makes the system more efficient.
基金supported by the National Natural Science Foundation of China(61931015,62071335,62250024)the Natural Science Foundation of Hubei Province of China(2021CFA002)+1 种基金the Fundamental Research Funds for the Central Universities of China(2042022dx0001)the Science and Technology Program of Shenzhen(JCYJ20170818112037398).
文摘To reduce the negative impact of the power amplifier(PA)nonlinear distortion caused by the orthogonal frequency division multiplexing(OFDM)waveform with high peak-to-average power ratio(PAPR)in integrated radar and communication(RadCom)systems is studied,the channel estimation in passive sensing scenarios.Adaptive channel estimation methods are proposed based on different pilot patterns,considering nonlinear distortion and channel sparsity.The proposed methods achieve sparse channel results by manipulating the least squares(LS)frequency-domain channel estimation results to preserve the most significant taps.The decision-aided method is used to optimize the sparse channel results to reduce the effect of nonlinear distortion.Numerical results show that the channel estimation performance of the proposed methods is better than that of the conventional methods under different pilot patterns.In addition,the bit error rate performance in communication and passive radar detection performance show that the proposed methods have good comprehensive performance.
文摘As an advanced device for observing atmospheric winds,the spaceborne Doppler Asymmetric Spatial Heterodyne(DASH)interferometer also encounters challenges associated with phase distortion,par-ticularly in limb sounding scenarios.This paper discusses interferogram modeling and phase distortion cor-rection techniques for spaceborne DASH interferometers.The modeling of phase distortion interferograms with and without Doppler shift for limb observation was conducted,and the effectiveness of the analytical expression was verified through numerical simulation.The simulation results indicate that errors propagate layer by layer while using the onion-peeling inversion algorithm to handle phase-distorted interferograms.In contrast,the phase distortion correction algorithm can achieve effective correction.This phase correction method can be successfully applied to correct phase distortions in the interferograms of the spaceborne DASH interferometer,providing a feasible solution to enhance its measurement accuracy.
文摘Improvements in surgical techniques have led to 90% success in the surgical repair of rhegmatogenous retinal detachment(RRD).However,anatomical reattachment of the retina does not ensure complete recovery of visual function.The incidence of metamorphopsia remains the most common postoperative complaint,from 24% to 88.6%.Currently,the risk factors of metamorphopsia are categorized into macular involvement,retinal shift,outer retinal folds,subretinal fluid,secondary epiretinal membrane,outer retinal layer damage,and surgical approach.The associations of metamorphopsia with postoperative best-corrected visual acuity and postoperative vision-related quality of life were still controversial.The most popular methods for assessment of metamorphopsia remain the Amsler grid and M-Charts.Most treatments cannot progress beyond the management of negative visual sensations,through methods such as occlusion therapy and aniseikonia-correcting spectacles.The main treatment approach involves RRD prevention and the management of risk factors that can lead to postoperative metamorphopsia after RRD repair.Additional research concerning metamorphopsia treatment,further upgrades of auxiliary inspection methods,and more accurate microstructural assessments are needed to address this common complication.
基金supported by the Hainan Province Science and Technology Special Fund(ZDYF2021SHFZ232,ZDYF2023GXJS022)the Hainan Province Postdoctoral Science Foundation(300333)the National Natural Science Foundation of China(21203008,21975025,12274025,22372008)。
文摘Sulfide-based all-solid-state lithium batteries suffer from electrochemo-mechanical damage to Ni-rich oxide-based cathode active materials(CAMs),primarily caused by severe volume changes,results in significant stress and strain,causes micro-cracks and interfacial contact loss at potentials>4.3 V(vs.Li/Li^(+)).Quantifying micro-cracks and voids in CAMs can reveal the degradation mechanisms of Ni-rich oxidebased cathodes during electrochemical cycling.Nonetheless,the origin of electrochemical-mechanical damage remains unclear.Herein,We have developed a multifunctional PEG-based soft buffer layer(SBL)on the surface of carbon black(CB).This layer functions as a percolation network in the single crystal LiNi_(0.83)Co_(0.07)Mn_(0.1)O_(2)and Li_(6)PS_(5)Cl composite cathode layer,ensuring superior ionic conductivity,reducing void formation and particle cracking,and promoting uniform utilization of the cathode active material in all-solid-state lithium batteries(ASSLBs).High-angle annular dark-field STEM combined with nanoscale X-ray holo-tomography and plasma-focused ion beam scanning electron microscopy confirmed that the PEG-based SBL mitigated strain induced by reaction heterogeneity in the cathode.This strain produces lattice stretches,distortions,and curved transition metal oxide layers near the surface,contributing to structural degradation at elevated voltages.Consequently,ASSLBs with a LiNi_(0.83)Co_(0.07)Mn_(0.1)O_(2)cathode containing LCCB-10(CB/PEG mass ratio:100/10)demonstrate a high areal capacity(2.53 mAh g^(-1)/0.32 mA g^(-1))and remarkable rate capability(0.58 mAh g^(-1)at 1.4 mA g^(-1)),with88%capacity retention over 1000 cycles.
基金support from the Natural Science Foundation of Jiangsu Province(BK20220596)Innovative science and technology platform project of cooperation between Yangzhou City and Yangzhou University,China(No.YZ202026305)+1 种基金Natural Science Foundation of China(21922202,21673202 and 22272147)the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘Intergrowth ferroelectric semiconductors with excellent spontaneous polarization field are highly promising piezo-photocatalytic candidate materials.In addition,developing structural design and revealing polarization enhancement in-depth mechanism are top priorities.Herein,we introduce the intergrowth ferroelectrics Bi_(7)Ti_(4)NbO_(21)thin-layer nanosheets for piezo-photocatalytic CO_(2)reduction.Density functional theory(DFT)calculations indicate that interlayer lattice mismatch leads to increased tilting and rotation angle of Ti/NbO_(6)octahedra on perovskite-like layers,serving as the main reason for increased polarization.Furthermore,the tilting and rotation angle of the interlayer octahedron further increase under stress,suggesting a stronger driving force generated to facilitate charge carrier separation efficiency.Meanwhile,Bi_(7)Ti_(4)NbO_(21)nanosheets provide abundant active sites to effectively adsorb CO_(2)and acquire sensitive stress response,thereby presenting synergistically advanced piezo-photocatalytic CO_(2)reduction activity with a high CO generation rate of 426.97μmol g^(-1)h^(-1).Our work offers new perspectives and directions for initiating and investigating the mechanisms of high-performance intergrowth piezo-photocatalysts.
文摘1.C.Li,"Holding‘China Inc.’Together:The CCP and The Rise of China’s Yangqi",The China Quarterly,Vol.228,2016,pp.927-949.2.J.Gao,"‘Bypass the Lying Mouths’:How Does the CCP Tackle Information Distortion at Local Levels?",The China Quarterly,Vol.228,2016,pp.950-969.3.C.Sorace,"Party Spirit Made Flesh:The Production of Legitimacy in the Aftermath of the 2008Sichuan Earthquake",The China Journal,Vol.76,2016,pp.41-62.4.Y.Yeo,"Complementing the Local Discipline Inspection Commissions of the CCP:Empowerment of the Central Inspection Groups",Journal of Contemporary China,Vol.25,No.97,2016,pp.59-74.
基金National Natural Science Foundation of China(22008166)Fundamental Research Program of Shanxi Province(202403021211029,201901D211047).
文摘The conversion of CO_(2)to dimethyl carbonate(DMC)offers a promising route for CO_(2)utilization.In this study,four CeO2 catalysts with distinct nanostructures were synthesized via a template-free hydrothermal method by systematically varying the types and concentrations of precipitants as well as the hydrothermal reaction conditions,and they were employed for DMC synthesis from CO_(2)and methanol.The atomic arrangements of CeO_(2)varied significantly with its morphology,leading to differences in lattice distortion,which directly influenced the concentration of oxygen vacancies.Notably,the CeO_(2)nanospheres,which exhibited the highest lattice distortion and oxygen vacancy concentration,achieved a DMC yield(11.12 mmol/g)48 times greater than that of the nanocubes(0.23 mmol/g).The results indicated that oxygen vacancies played a pivotal role in the catalytic process by facilitating the adsorption and activation of CO_(2)to form bidentate carbonates,as well as activating methanol to generate methoxy species.These processes collectively promoted the formation of the key intermediate(*CH3OCOO).This study proposes a strategy to enhance the oxygen vacancy concentration by increasing lattice distortion,providing valuable insights for designing high-performance CeO_(2)catalysts for DMC synthesis.
文摘Despite the global attention towards pollution,it remains a significant global threat and challenge for both developed and developing countries.Urbanization and economic development influence different types of pollution.Visual pollution is considered a new phenomenon referring to the impact of existing and growing mainstream pollution which impairs an individual’s ability to enjoy visits or views.Recently,Jordanian cities have expanded in response to urbanization and ongoing development.Irbid City has the second largest population in Jordan after the capital Amman City highest population density in Jordan.In the modern era,Irbid City dramatically increased in population and dimension.The growth of the demographic population has been significant and has led to overpopulation,rapid urbanization,and unresolved problems associated with spatial planning and infrastructures leading to different types of pollution including visual pollution.The study area focuses on the city center with the most crowded population through field visits and actual observations.The study technique is descriptive and analytical,with a focus on meticulous monitoring and a follow-up-based questionnaire which is a tool for the study,involving data collection,classification,presentation,analysis,interpretation,and exploration to identify new facts and generalizations that can help solve current issues of visual pollution.The study provides recommendations for Irbid Municipal to eliminate visual pollution,in parallel with stricter supervision from the municipality during the building process to ensure proper implementation of the new rules,adopting an integrated policy for the city with the rest of the social,political,sensory,cultural,economic,and functional aspects,so that this policy is in the short and long term.
文摘Indian Railways have been the largest people moving transport infrastructure in India.Over the years the systems and trains have been upgraded resulting in both better passenger amenities and reduction in travel time.The newest addition is the Vande Bharat Express,a semi-high-speed train that was introduced in India in 2019.The train currently runs between 10 routes and has brought significant changes to India’s railway network.This article explores the introduction of Vande Bharat Express trains in India and its effects on the country’s interstation time-space shrinkage using cartographic techniques.The cartographic techniques like stepwise multidimensional scaling and interpolation using the distance cartogram plugin in QGIS are mainly used for generating the time-space maps for various speeds.The limitations of these techniques and the methods to overcome those limitations are also explored in this article.
基金supports in part by the Natural Science Foundation of China(NSFC)under contract No.62171253the Young Elite Scientists Sponsorship Program by CAST under program No.2022QNRC001,as well as the Fundamental Research Funds for the Central Universities.
文摘Images with complementary spectral information can be recorded using image sensors that can identify visible and near-infrared spectrum.The fusion of visible and nearinfrared(NIR)aims to enhance the quality of images acquired by video monitoring systems for the ease of user observation and data processing.Unfortunately,current fusion algorithms produce artefacts and colour distortion since they cannot make use of spectrum properties and are lacking in information complementarity.Therefore,an information complementarity fusion(ICF)model is designed based on physical signals.In order to separate high-frequency noise from important information in distinct frequency layers,the authors first extracted texture-scale and edge-scale layers using a two-scale filter.Second,the difference map between visible and near-infrared was filtered using the extended-DoG filter to produce the initial visible-NIR complementary weight map.Then,to generate a guide map,the near-infrared image with night adjustment was processed as well.The final complementarity weight map was subsequently derived via an arctanI function mapping using the guide map and the initial weight maps.Finally,fusion images were generated with the complementarity weight maps.The experimental results demonstrate that the proposed approach outperforms the state-of-the-art in both avoiding artificial colours as well as effectively utilising information complementarity.
基金supported by the National Natural Science Foundation of China(22479031,22162004)the Natural Science Foundation of Guangxi(2022JJD120011)the High-performance Computing Platform of Guangxi University.
文摘5-Hydroxymethylfurfural electrooxidation reaction(HMFOR)provides a promising route for producing highvalue-added compounds.It is generally believed that NiOOH is the active species in HMFOR process,but its inherently poor electron transfer ability leads to limited catalytic activity.In this work,a W doping strategy is adopted to regulate the electron transfer between NiOOH and reaction molecules.Electrochemical results show that W-doped Ni_(5)P_(4)-R exhibits excellent electrochemical performance for the oxidation of HMF to FDCA with the conversion of HMF and yield of FDCA both close to~100%.Density functional theory and in-situ characterization reveal that the introduction of W causes the distortion of NiOOH lattice,resulting in the Jahn-Teller distortion and the elimination of orbital degeneracy,thereby broadening the e_(g)^(*)band of NiOOH.This feature is beneficial for the electron transfer between W-doped NiOOH and HMF(1.31 e^(-)),thereby promoting the C–H bond activation of the aldehyde group in HMF and effectively reducing the energy barrier of rate-determining step(RDS).
基金supported in part by the National Natural Science Foundation of China(Nos.61873196,62373030,61772187)the Innovation Program for Quantum Science and Technology(No.2021ZD0303400)。
文摘The traditional orbit determination method based on pulsar profile distortion can determine the six elements of the orbit.However,the estimation accuracies of these methods are limited and the computational load of a six-dimensional search is huge.To solve this problem,the differential-geometry-based Multi-dimensional Joint Position-Velocity Estimation(MJPVE)using Crab pulsar profile distortion is proposed in this paper.Firstly,through theoretical analysis,it is found that the pulsar profile distortion caused by the initial state error in some joint positionvelocity directions is very small.In other words,the accuracies of estimation in these directions are very low.Namely,the search dimension can be reduced,which in turn greatly reduces the computational load.Then,we construct the chi-squared function of the pulsar profile with respect to the estimation error in joint position-velocity direction and use differential geometry to find the joint position-velocity directions corresponding to different degrees of distortion.Finally,we utilize the grid search based on directory folding in these joint position-velocity directions corresponding to large degrees of distortion to obtain the joint position-velocity estimation.The experimental results show that compared with the grouping bi-chi-squared inversion method,MJPVE has high precision and extensive navigation information.
基金supported by the Science and Technology Project of China Southern Power Grid Co.,Ltd.(Grant No.ZBKJXM20232471)the National Key R&D Program of China(Grant No.2021YFB1600200)the Innovation Capability Support Program of Shaanxi(Grant No.2022KXJ-144)。
文摘In response to the complex working conditions of the power grid caused by the high proportion of new energy access,which leads to insufficient output accuracy of the second-order generalized integrator(SOGI)phaselocked loop,this article proposes an improved frequency adaptive phase-locked loop structure for SOGI.Firstly,an amplitude compensation branch is introduced to compensate for the SOGI tracking fundamental frequency signal,ensuring the accuracy of the SOGI output orthogonal signal under frequency fluctuation conditions.Secondly,by cascading two adaptive SOGI modules,the suppression capability of low-order harmonics and Direct Current(DC)components has been improved.Finally,the positive and negative sequence separation method of orthogonal signals is introduced to eliminate the influence of unbalanced components on the phase-locked loop.The comparative experiment with the classic SOGI-PLL method shows that the proposed phase-locked loop structure effectively improves the accuracy of power grid synchronization detection under complex working conditions such as harmonic components,unbalanced components,and frequency fluctuations.It can complete frequency detection within 1.5 power frequency cycles,and the detected fundamental frequency positive sequence voltage has a higher sinuosity and harmonic distortion rate within 0.5%.
文摘Size reduction of the gas turbines(GT)by reducing the inlet S-shaped diffuser length increases the powerto-weight ratio.It improves the techno-economic features of the GT by lesser fuel consumption.However,this Length reduction of a bare S-shaped diffuser to an aggressive S-shaped diffuser would risk flow separation and performance reduction of the diffuser and the air intake of the GT.The objective of this research is to propose and assess fitted energy promoters(EPs)to enhance the S-shaped diffuser performance by controlling and modifying the flow in the high bending zone of the diffuser.After experimental assessment,the work has been extended to cover more cases by numerical investigations on bare,bare aggressive,and aggressive with energy promoters S-shaped diffusers.Three types of EPs,namely co-rotating low-profile,co-rotating streamline sheet,and trapezoidal submerged EPs were tested with various combinations over a range of Reynolds numbers from 40,000 to 75,000.The respective S-shaped diffusers were simulated by computational fluid dynamics(CFD)using ANSYS software adopting a steady,3D,standard k-εturbulence model to acquire the details of the flow structure,which cannot be visualized in the experiment.The diffuser performance has been evaluated by the performance indicators of static pressure recovery coefficient,total pressure loss coefficient,and distortion coefficient(DC(45°)).The enhancements in the static pressure recovery of the S-shaped aggressive diffuser with energy promoters are 19.5%,22.2%,and 24.5%with EPs at planes 3,4 and 5,respectively,compared to the aggressive bare diffuser.In addition,the installation of the EPs resulted in a DC(45°)reduction at the outlet plane of the diffuser of about 43%at Re=40,000.The enhancements in the performance parameters confirm that aggravating the internal flow eliminates the flow separation and enhances the GT intake efficiency.
文摘The Vienna rectifier is a widely adopted solution for high-power rectification due to its efficiency and straightforward design.However,its performance can degrade under unbalanced three phase voltage conditions,leading to current zero-crossing distortion and compromised dynamic response.This paper investigates the causes of these distortions,identifying a phase shift between the input current and the grid voltage as a primary factor,and proposes an effective distortion phase identification strategy.Furthermore,the dynamic performance is enhanced through improved current reference calculations and a refined power feedforward strategy.This approach optimizes the system's response to load changes and maintains output voltage stability under unbalanced conditions.Simulation results validate the effectiveness of the proposed methods in reducing current distortion and improving overall performance.
基金supported by the National Natural Science Foundation of China(No.52102129)the Hunan Provincial Natural Science Foundation of China(No.2023JJ30138)the Science and Technology Innovation Program of Hunan Province(No.2023RC3094).
文摘This study designs and synthesizes highly dense Li2 Mg_(6)ZnTi_(6)O_(20)microwave dielectric ceramics based on a high-entropy strategy,focusing on achieving stable structures,low sintering temperatures,and excellent comprehensive performance.The ceramics exhibit a predominant face-centered cubic disordered phase(Fd-3 m)sintered at 1200-1280°C,alongside an increased presence of the second phase MgTiO3 at higher temperatures.Remarkably,these ceramics demonstrate excellent microwave dielectric properties(ε_(r)=16.69,Q×f=88,230 GHz,andτ_(f)=−36.5 ppm/°C).Additionally,we have explored the addition of x wt%LiF(1≤x≤5)to the Li2 Mg_(6)ZnTi_(6)O_(20)ceramics to enhance their applicability.The ceramics feature a spinel structure for LiF contents up to 3 wt%,while higher LiF concentrations induce the formation of a secondary phase,LiTiO2,characterized by a rock salt structure.Notably,the lattice distortion induced by LiF leads to a constant decrease in ε_(r).A moderate degree of lattice distortion serves to enhance the lattice stability of ceramics,which is reflected in increased lattice energy.Excellent microwave dielectric properties(ε_(r)=16.23,Q×f=89,728 GHz,τ_(f)=−43.5 ppm/°C)were obtained for x=3 ceramic sintered at 1140°C.Even at x=5,the ceramic retains excellent microwave dielectric properties(ε_(r)=16.02,Q×f=63,079 GHz,τ_(f)=−26 ppm/°C)at a low sintering temperature of 900°C.This work realizes the multiple effects of LiF and confirms good chemical compatibility with silver for LTCC(low-temperature co-fired ceramics)applications.
文摘Fe-N-C catalysts are promising substitutes for precious-metal platinum in acidic oxygen reduction reactions(ORR),yet their moderate intrinsic activity and susceptibility to reactive oxygen species(ROS)-induced degradation hinder practical implementation.Herein,we fabricate a Ru-Fe dual-site catalyst(RuFe-N-C)through a two-step pyrolysis strategy.Structural characterization reveals atomic-scale proximity between Ru single atoms and Fe-N_(4) moieties,exhibiting a projected distance of~1.7Å.This configuration induces Fe–N bond elongation accompanied by 2.5%lattice distortion.The optimized RuFe-N-C catalyst exhibits high ORR performance,with a half-wave potential(E_(1/2))of 0.840 V and peak power density(P_(max))of 938 mW cm^(-2) under 150 kPa absolute H_(2)-O_(2).These metrics signify substantial enhancements relative to conventional Fe-N-C benchmarks(+21 mV in E_(1/2) and+42%in P_(max)).Moreover,the catalyst maintains outstanding stability,showing merely 17 mV E_(1/2) decay after 10000 accelerated durability test(ADT)cycles.Experimental analyses reveal a bifunctional mechanism:(1)Adjacent Ru sites substantially enhance the intrinsic ORR activity of Fe-N_(4) moieties,delivering a notable turnover frequency(TOF=17.86 e site^(-1) s^(-1) at 0.85 V vs.RHE)that exceeds state-of-the-art Fe-N-C benchmarks by 1-2 orders of magnitude(<1 e site^(-1) s^(-1));(2)Ru centers function as electron relays that facilitate ROS scavenging,thus suppressing degradation.This work establishes a paradigm for engineering bimetallic single-atom catalysts through synergistic electronic modulation to concurrently enhance activity and stability.
