Photon pairs with large nondegeneracy have recently attracted increasing interest, which gives rise to an urgent demand for revealing their complete and accurate spectral distribution. By thoroughly analyzing parametr...Photon pairs with large nondegeneracy have recently attracted increasing interest, which gives rise to an urgent demand for revealing their complete and accurate spectral distribution. By thoroughly analyzing parametric down-conversion(PDC), we put forward a model to directly describe the spatial-spectral distribution of these photon pairs, which is experimentally demonstrated by a 532-nm pumped type-I PDC in a beta barium borate(BBO) crystal. The measured spectral curves show good agreement with the theoretical predictions over the entire spectral range. We further demonstrate that, as signal wavelength increases, the photon pairs are initially spectrally distinguishable, then partly indistinguishable, finally completely indistinguishable with a maximum bandwidth of approximately 500 nm. Utilizing photon-number-resolving single-photon detectors(SPD), we observe the average photon number decreases significantly more slowly than the spectral intensity as the wavelength deviates from the peak, and the photon numbers follow a quasi-Poisson distribution well for wavelengths around the peak, but a thermal distribution better describes the statistics near the spectral boundaries. Finally,we use the signal photons as the trigger to generate heralded Fock states up to 10 photons in near-infrared range, which are suitable for quantum simulation and quantum key distribution in optical fiber networks.展开更多
The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usu...Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.展开更多
BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Resear...BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Research in developing nations relating to the cost of treatment is scarce when compared with developed countries.Thus,the drug utilization research studies from developing nations are most needed,and their number has been growing.AIM To evaluate patterns of utilization of antipsychotic drugs and direct medical cost analysis in patients newly diagnosed with schizophrenia.METHODS The present study was observational in type and based on a retrospective cohort to evaluate patterns of utilization of antipsychotic drugs using World Health Organization(WHO)core prescribing indicators and anatomical therapeutic chemical/defined daily dose indicators.We also calculated direct medical costs for a period of 6 months.RESULTS This study has found that atypical antipsychotics are the mainstay of treatment for schizophrenia in every age group and subcategories of schizophrenia.The evaluation based on WHO prescribing indicators showed a low average number of drugs per prescription and low prescribing frequency of antipsychotics from the National List of Essential Medicines 2015 and the WHO Essential Medicines List 2019.The total mean drug cost of our study was 1396 Indian rupees.The total mean cost due to the investigation in our study was 1017.34 Indian rupees.Therefore,the total mean direct medical cost incurred on patients in our study was 4337.28 Indian rupees.CONCLUSION The information from the present study can be used for reviewing and updating treatment policy at the institutional level.展开更多
In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles we...In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles were tested at room temperature un-der a near-infrared photo source （980 nm） and UV-vis photo source, respectively.The results indicated thatα-TeO2 NPs were a kind of outstanding host material for both up- and down-conversion luminescence. Theα-TeO2：Ho3＋/Yb3＋nanoparticles showed sharp up-conversion emission at 545 and 660 nm under 980 nm excitation, ascribed to the5S2→5I8 and5F5→5I8（Ho3＋） transitions, and weaker down-conversion emission at 545 nm under 455 nm excitation, ascribed to the5S2→5I8（Ho3＋） transitions. Theα-TeO2：Eu3＋nanoparticles showed strong down-conversion emission at 592 and 615 nm under 395 nm excitation, attributed to the5D0→7F1 and 5D0→7F2 （Eu3＋） transitions. Possessing the advantages of these two luminescent materials, the as-prepared tri-doped samples ofα-TeO2：0.5Ho3＋/10Yb3＋/3Eu3＋ （mol.%）nanoparticles could successfully emit visible light via both up- and down-conversion modes.展开更多
Near-infrared single photon sources in telecommunication bands, especially at 1550 nm, are required for long-distance quantum communication. Here a down-conversion quantum interface is implemented, where the single ph...Near-infrared single photon sources in telecommunication bands, especially at 1550 nm, are required for long-distance quantum communication. Here a down-conversion quantum interface is implemented, where the single photons emitted from single In As quantum dot at 864 nm is down converted to 1552 nm by using a fiber-coupled periodically poled lithium niobate（PPLN） waveguide and a 1.95 μmm pump laser, and the frequency conversion efficiency is ~40%. The singlephoton purity of quantum dot emission is preserved during the down-conversion process, i.e., g^（（2））（0）, only 0.22 at 1552 nm.This present technique advances the Ⅲ-Ⅴ semiconductor quantum dots as a promising platform for long-distance quantum communication.展开更多
We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variati...We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variation models and our simulation results show that thickness variations in several nanometers can induce distinct effects on the central peak of the spectrum,such as narrowing,broadening,and splitting.We also prove that the effects of positive and negative variations can be canceled and thus lead to a variation-robust feature and an ultra-broad bandwidth.Our study may promote the development of on-chip photon sources in the LNOI platform,as well as opens up a way to engineer photon frequency state.展开更多
In recent years, much attention has been paid to software-defined radio （SDR） technologies for multimode wireless systems SDR can be defined as a radio communication system that uses software to modulate and demodul...In recent years, much attention has been paid to software-defined radio （SDR） technologies for multimode wireless systems SDR can be defined as a radio communication system that uses software to modulate and demodulate radio signals. This article describes concepts, theory, and design principles for SDR down-conversion and up-conversion. Design issues in SDR down-conversion are discussed, and two different architectures, super-heterodyne and direct-conversion, are proposed. Design issues in SDR up-conversion are also discussed, and trade-offs in the design of filters, mixers, NCO, DAC, and signal processing are highlighted.展开更多
We studied the process of polariton conversion in a 3-mode nonlinear optomechanical system.Compared with the standard 2-mode optomechanical system,we find a much larger conversion rate of polariton modes can be achiev...We studied the process of polariton conversion in a 3-mode nonlinear optomechanical system.Compared with the standard 2-mode optomechanical system,we find a much larger conversion rate of polariton modes can be achieved under typical dissipation conditions.To obtain a transparent understanding of the relevant physical process,we show that in the large detuned case,the cavity can be eliminated adiabatically,resulting in a parametric down-conversion(PDC)interaction between two phononic polariton modes.By tuning cavity detuning,the nonlinear interaction can be enhanced with the frequency-matching condition.Results from analytical treatment based on the effective PDC model agree with the numerical simulation.Such a system provides potential applications in nonlinear phononics.展开更多
By properly selecting the time-dependent unitary transformation for the linear combination of the number operators, we construct a time-dependent invariant and derive the corresponding auxiliary equations for the dege...By properly selecting the time-dependent unitary transformation for the linear combination of the number operators, we construct a time-dependent invariant and derive the corresponding auxiliary equations for the degenerate and non-degenerate coupled parametric down-conversion system with driving term. By means of this invariant and the Lewis-Riesenfeld quantum invariant theory, we obtain closed formulae of the quantum state and the evolution operator of the system. We show that the time evolution of the quantum system directly leads to production of various generalized one- and two-mode combination squeezed states, and the squeezed effect is independent of the driving term of the Hamiltonian. In some special cases, the current solution can reduce to the results of the previous works.展开更多
High-resolution non-emissive displays based on electrochromic tungsten oxides(WOx)are crucial for future near-eye virtual/augmented reality interactions,given their impressive attributes such as high environmental sta...High-resolution non-emissive displays based on electrochromic tungsten oxides(WOx)are crucial for future near-eye virtual/augmented reality interactions,given their impressive attributes such as high environmental stability,ideal outdoor readability,and low energy consumption.However,the limited intrinsic structure of inorganic materials has presented a significant challenge in achieving precise patterning/pixelation at the micron scale.Here,we successfully developed the direct photolithography for WOx nanoparticles based on in situ photo-induced ligand exchange.This strategy enabled us to achieve ultra-high resolution efficiently(line width<4μm,the best resolution for reported inorganic electrochromic materials).Additionally,the resulting device exhibited impressive electrochromic performance,such as fast response(<1 s at 0 V),high coloration efficiency(119.5 cm^(2) C^(−1)),good optical modulation(55.9%),and durability(>3600 cycles),as well as promising applications in electronic logos,pixelated displays,flexible electronics,etc.The success and advancements presented here are expected to inspire and accelerate research and development(R&D)in high-resolution non-emissive displays and other ultra-fine micro-electronics.展开更多
A four-wavelength Bragg reflection waveguide edge emitting diode based on intracavity spontaneous parametric down-conversion and four-wave mixing （FWM） processes is made. The structure and its tuning characteris- ti...A four-wavelength Bragg reflection waveguide edge emitting diode based on intracavity spontaneous parametric down-conversion and four-wave mixing （FWM） processes is made. The structure and its tuning characteris- tic are designed by the aid of FDTD mode solution. The laser structure is grown by molecular beam epitaxy and processed to laser diode through the semiconductor manufacturing technology. Fourier transform infrared spectroscopy is applied to record wavelength information. Pump around 1.071 μm, signal around 1.77μm, idler around 2.71 μm and FWM signal around 1.35μm are observed at an injection current of 560mA. The influ- ences of temperature, carrier density and pump wavelength on tuning characteristic are shown numerically and experimentally.展开更多
Parametric down-conversion（PDC） sources play an important role in quantum information processing, therefore characterizing their properties is necessary. Here we present a statistical model to assess the properties ...Parametric down-conversion（PDC） sources play an important role in quantum information processing, therefore characterizing their properties is necessary. Here we present a statistical model to assess the properties of the PDC source with certain distribution, such as the brightness and photon channel transmissions, we only need to measure the singles and coincidences counts in a few seconds. Furthermore, we validate the model by applying it to a PDC source generating highly non-degenerate photon pairs. The results of the experiment indicate that our method is more simple, efficient, and less time consuming.展开更多
Large-scale deployment of carbon dioxide(CO_(2))removal technology is an essential step to cope with global warming and achieve carbon neutrality.Direct air capture(DAC)has recently received increasing attention given...Large-scale deployment of carbon dioxide(CO_(2))removal technology is an essential step to cope with global warming and achieve carbon neutrality.Direct air capture(DAC)has recently received increasing attention given the high flexibility to remove CO_(2)from discrete sources.Porous materials with adjustable pore characteristics are promising sorbents with low or no latent heat of vaporization.This review article has summarized the recent development of porous sorbents for DAC,with a focus of pore engineering strategy and adsorption mechanism.Physisorbents such as zeolites,porous carbons,metal-organic frameworks(MOFs),and amine-modified chemisorbents have been discussed and their challenges in practical application have been analyzed.At last,future directions have been proposed,and it is expected to inspire collaborations from chemistry,environment,material science and engineering communities.展开更多
With the approaching of large-scale retirement of power lithium-ion batteries(LIBs),their urgent handling is required for environmental protection and resource reutilization.However,at present,substantial spent power ...With the approaching of large-scale retirement of power lithium-ion batteries(LIBs),their urgent handling is required for environmental protection and resource reutilization.However,at present,substantial spent power batteries,especially for those high recovery value cathode materials,have not been greenly,sustainably,and efficiently recycled.Compared to the traditional recovery method for cathode materials with high energy consumption and severe secondary pollution,the direct repair regeneration,as a new type of short-process and efficient treatment methods,has attracted widespread attention.However,it still faces challenges in homogenization repair,electrochemical performance decline,and scaling-up production.To promote the direct regeneration technology development of failed NCM materials,herein we deeply discuss the failure mechanism of nickel-cobalt-manganese(NCM)ternary cathode materials,including element loss,Li/Ni mixing,phase transformation,structural defects,oxygen release,and surface degradation and reconstruction.Based on this,the detailed analysis and summary of the direct regeneration method embracing solid-phase sintering,eutectic salt assistance,solvothermal synthesis,sol-gel process,spray drying,and redox mediation are provided.Further,the upcycling strategy for regeneration materials,such as single-crystallization and high-nickelization,structural regulation,ion doping,and surface engineering,are discussed in deep.Finally,the challenges faced by the direct regeneration and corresponding countermeasures are pointed out.Undoubtedly,this review provides valuable guidance for the efficient and high-value recovery of failed cathode materials.展开更多
The layer-by-layer deposition strategy of additive manufacturing makes it ideal to fabricate dissimilar alloy components with varying functionality,which has promising application potential in a large number of indust...The layer-by-layer deposition strategy of additive manufacturing makes it ideal to fabricate dissimilar alloy components with varying functionality,which has promising application potential in a large number of industrial areas.In this study,two components composed of ERCuAl-A2 aluminum bronze(CuAl9)and Inconel 718 nickel-based superalloy were fabricated with different deposition orders by wire-arc directed energy deposition.Subject to changes in heat input and thermophysical properties of the substrate,the transition region of the deposited Cu-Ni component with the bottom half of CuAl9 and the top half of Inconel 718 is narrow and serrated.This region features a laminated intermetallic compound layer due to the convection and rapid cooling in the molten pool.In contrast,the Ni-Cu component deposited in the opposite order exhibits a 2 mm gradient transition zone.Within this region,a large number of diverse precipitates were found as well as regional variations in grain size due to the multi-layer partial remelting.Both two components show strong bonds and their tensile specimens tested along the vertical direction always fracture at the softer CuAl9 side.Excellent tensile properties along the horizontal direction were obtained for Cu-Ni(Ultimate tensile strength:573 MPa,yield stress:302 MPa,elongation:22%),while those of Ni-Cu are much lower due to the existence of the solidification cracks in the transition zone.The results from this study provide a reference for the additive manufacturing of Cu/Ni dissimilar alloy components,as well as their microstructure and mechanical properties control.展开更多
For realizing the goals of“carbon peak”and“carbon neutrality”,lithium-ion batteries(LIB)with LiFePO_(4)as the cathode material have been widely applied.However,this has also led to a large number of spent lithium-...For realizing the goals of“carbon peak”and“carbon neutrality”,lithium-ion batteries(LIB)with LiFePO_(4)as the cathode material have been widely applied.However,this has also led to a large number of spent lithium-ion batteries,and the safe disposal of spent lithium-ion batteries is an urgent issue.Currently,the main reason for the capacity decay of LiFePO_(4)materials is the Li deficiency and the formation of the Fe^(3+)phase.In order to address this issue,we performed high-temperature calcination of the discarded lithium iron phosphate cathode material in a carbon dioxide environment to reduce or partially remove the carbon coating on its surface.Subsequently,mechanical grinding was conducted to ensure thorough mixing of the lithium source with the discarded lithium iron phosphate.The reaction between CO_(2)and the carbon coating produced a reducing atmosphere,reducing Fe^(3+)to Fe^(2+)and thereby reducing the content of Fe^(3+).The Fe^(3+)content in the repaired LiFePO_(4)material is reduced.The crystal structure of spent LiFePO_(4)cathode materials was repaired more completely compare with the traditional pretreatment method,and the repaired LiFePO_(4)material shows good electrochemical performance and cycling stability.Under 0.1 C conditions,the initial capacity can reach 149.1 m Ah/g.It can be reintroduced for commercial use.展开更多
Solution and aging treatment were conducted on the laser directed energy deposition(LDED)-prepared carbon nanotubes(CNTs)-reinforced WE43(CNTs/WE43)layers to optimize their microstructure and surface properties in thi...Solution and aging treatment were conducted on the laser directed energy deposition(LDED)-prepared carbon nanotubes(CNTs)-reinforced WE43(CNTs/WE43)layers to optimize their microstructure and surface properties in this study.The microstructure of the WE43 and CNTs/WE43 layers was systematically compared.The dissolution of divorced eutectics at the grain boundaries was retarded by CNTs during solution treatment.The spot segregation composed of Mg_(24)Y_(5),CNTs,and Zr cores in the solution treated CNTs/WE43 layer presented a slight decreasing in Y content.The grain growth of both types of layers underwent three stages:slow,rapid,and steady-state.The significant inhibitory effect of CNTs on the grain growth of the LDED WE43 matrix was more pronounced than the promoting effect of temperature,resulting in a 47%increase at 510℃ and a 35%increase at 540℃ in the grain growth exponent compared to the WE43 layers at 510℃.During the subsequent aging treatment at 225℃,the precipitation sequences from plate-shaped β″to plate-shaped and globular β′ were observed in both types of layers.CNTs can facilitate an increase in the nucleation rate of precipitates,but without accelerating precipitation hardening rate.The long and short diameters of the precipitates in peak-aged state were decreased by 48.5%and 43.1%by addition of CNTs,respectively.The wear resistance of both the WE43 and CNTs/WE43 layers can be significantly enhanced through solution and aging treatment.The enhancement in wear resistance for the CNTs/WE43 layers is considerably greater than that of the WE43 layers.展开更多
This study investigates the development of novel high-entropy alloys(HEAs)with enhanced mechanical properties through an innovative fabrication method of direct energy deposition(DED).The focus is on the creation of m...This study investigates the development of novel high-entropy alloys(HEAs)with enhanced mechanical properties through an innovative fabrication method of direct energy deposition(DED).The focus is on the creation of metastable core-shell precipitation-strengthened HEAs that exhibit a unique multi-stage terrace-like slip wave toughening mechanism,a novel approach to improving both strength and ductility simultaneously.Mechanical testing reveals that the developed HEAs exhibit superior mechanical proper-ties,including high yield strength,ultimate tensile strength,and exceptional ductility.The improvement in these properties is attributed to the multi-stage terrace-like slip wave toughening mechanism activated by the unique microstructural features.This toughening mechanism involves the sequential activation of slip systems,facilitated by the stress concentration around the core-shell precipitates and the subsequent propagation of slip waves across the material.The terrace-like pattern of these slip waves enhances the material's ability to deform plastically,providing a significant toughening effect while maintaining high strength levels.Furthermore,the study delves into the fundamental interactions between the microstruc-tural elements and the deformation mechanisms.It elucidates how the core-shell precipitates and the matrix cooperate to distribute stress uniformly,delay the onset of necking,and prevent premature failure.This synergistic interaction between the microstructural features and the slip wave toughening mecha-nism is central to the remarkable balance of strength and ductility achieved in the HEAs.The introduction of a multi-stage terrace-like slip wave toughening mechanism offers a new pathway to designing HEAs with an exceptional amalgamation of strength and ductility.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 62075010)。
文摘Photon pairs with large nondegeneracy have recently attracted increasing interest, which gives rise to an urgent demand for revealing their complete and accurate spectral distribution. By thoroughly analyzing parametric down-conversion(PDC), we put forward a model to directly describe the spatial-spectral distribution of these photon pairs, which is experimentally demonstrated by a 532-nm pumped type-I PDC in a beta barium borate(BBO) crystal. The measured spectral curves show good agreement with the theoretical predictions over the entire spectral range. We further demonstrate that, as signal wavelength increases, the photon pairs are initially spectrally distinguishable, then partly indistinguishable, finally completely indistinguishable with a maximum bandwidth of approximately 500 nm. Utilizing photon-number-resolving single-photon detectors(SPD), we observe the average photon number decreases significantly more slowly than the spectral intensity as the wavelength deviates from the peak, and the photon numbers follow a quasi-Poisson distribution well for wavelengths around the peak, but a thermal distribution better describes the statistics near the spectral boundaries. Finally,we use the signal photons as the trigger to generate heralded Fock states up to 10 photons in near-infrared range, which are suitable for quantum simulation and quantum key distribution in optical fiber networks.
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
基金financially supported by the National Natural Science Foundation of China(Nos.22475057 and No.52373262).
文摘Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components.
文摘BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Research in developing nations relating to the cost of treatment is scarce when compared with developed countries.Thus,the drug utilization research studies from developing nations are most needed,and their number has been growing.AIM To evaluate patterns of utilization of antipsychotic drugs and direct medical cost analysis in patients newly diagnosed with schizophrenia.METHODS The present study was observational in type and based on a retrospective cohort to evaluate patterns of utilization of antipsychotic drugs using World Health Organization(WHO)core prescribing indicators and anatomical therapeutic chemical/defined daily dose indicators.We also calculated direct medical costs for a period of 6 months.RESULTS This study has found that atypical antipsychotics are the mainstay of treatment for schizophrenia in every age group and subcategories of schizophrenia.The evaluation based on WHO prescribing indicators showed a low average number of drugs per prescription and low prescribing frequency of antipsychotics from the National List of Essential Medicines 2015 and the WHO Essential Medicines List 2019.The total mean drug cost of our study was 1396 Indian rupees.The total mean cost due to the investigation in our study was 1017.34 Indian rupees.Therefore,the total mean direct medical cost incurred on patients in our study was 4337.28 Indian rupees.CONCLUSION The information from the present study can be used for reviewing and updating treatment policy at the institutional level.
基金supported by the National Natural Science Foundation of China(21075053)the"Challenge Cup"Undergraduate Extra-curriculum Academics,Science and Technology Works Competition and Student's Platform for Innovation and Entrepreneurship Training Program(201410559056)in Jinan University
文摘In this study,α-TeO2：Ho3＋/Yb3＋,α-TeO2：Eu3＋ andα-TeO2：Ho3＋/Yb3＋/Eu3＋ nanoparticles were prepared via a simple hydrothermal process. The up- and down-conversion properties of the as-prepared nanoparticles were tested at room temperature un-der a near-infrared photo source （980 nm） and UV-vis photo source, respectively.The results indicated thatα-TeO2 NPs were a kind of outstanding host material for both up- and down-conversion luminescence. Theα-TeO2：Ho3＋/Yb3＋nanoparticles showed sharp up-conversion emission at 545 and 660 nm under 980 nm excitation, ascribed to the5S2→5I8 and5F5→5I8（Ho3＋） transitions, and weaker down-conversion emission at 545 nm under 455 nm excitation, ascribed to the5S2→5I8（Ho3＋） transitions. Theα-TeO2：Eu3＋nanoparticles showed strong down-conversion emission at 592 and 615 nm under 395 nm excitation, attributed to the5D0→7F1 and 5D0→7F2 （Eu3＋） transitions. Possessing the advantages of these two luminescent materials, the as-prepared tri-doped samples ofα-TeO2：0.5Ho3＋/10Yb3＋/3Eu3＋ （mol.%）nanoparticles could successfully emit visible light via both up- and down-conversion modes.
基金Project supported by the National Key Technologies R&D Program of China(Grant No.2018YFA0306101)the Scientific Instrument Developing Project of Chinese Academy of Sciences(Grant No.YJKYYQ20170032)the National Natural Science Foundation of China(Grant No.61505196)
文摘Near-infrared single photon sources in telecommunication bands, especially at 1550 nm, are required for long-distance quantum communication. Here a down-conversion quantum interface is implemented, where the single photons emitted from single In As quantum dot at 864 nm is down converted to 1552 nm by using a fiber-coupled periodically poled lithium niobate（PPLN） waveguide and a 1.95 μmm pump laser, and the frequency conversion efficiency is ~40%. The singlephoton purity of quantum dot emission is preserved during the down-conversion process, i.e., g^（（2））（0）, only 0.22 at 1552 nm.This present technique advances the Ⅲ-Ⅴ semiconductor quantum dots as a promising platform for long-distance quantum communication.
基金Project supported by the National Key R&D Program of China(Grant No.2019YFA0705000)Leading-edge Technology Program of Jiangsu Natural Science Foundation,China(Grant No.BK20192001)the National Natural Science Foundation of China(Grant Nos.51890861,11690031,11974178,and 11627810).
文摘We study the effect of waveguide thickness variations on the frequency spectrum of spontaneous parametric downconversion in the periodically-poled lithium niobate on insulator(LNOI)waveguide.We analyze several variation models and our simulation results show that thickness variations in several nanometers can induce distinct effects on the central peak of the spectrum,such as narrowing,broadening,and splitting.We also prove that the effects of positive and negative variations can be canceled and thus lead to a variation-robust feature and an ultra-broad bandwidth.Our study may promote the development of on-chip photon sources in the LNOI platform,as well as opens up a way to engineer photon frequency state.
文摘In recent years, much attention has been paid to software-defined radio （SDR） technologies for multimode wireless systems SDR can be defined as a radio communication system that uses software to modulate and demodulate radio signals. This article describes concepts, theory, and design principles for SDR down-conversion and up-conversion. Design issues in SDR down-conversion are discussed, and two different architectures, super-heterodyne and direct-conversion, are proposed. Design issues in SDR up-conversion are also discussed, and trade-offs in the design of filters, mixers, NCO, DAC, and signal processing are highlighted.
基金support from the NSFC(Grant No.12275331)the Penghuanwu Innovative Research Center(Grant No.12047503)the Innovation Program for Quantum Science and Technology(Grant No.2021ZD031602)。
文摘We studied the process of polariton conversion in a 3-mode nonlinear optomechanical system.Compared with the standard 2-mode optomechanical system,we find a much larger conversion rate of polariton modes can be achieved under typical dissipation conditions.To obtain a transparent understanding of the relevant physical process,we show that in the large detuned case,the cavity can be eliminated adiabatically,resulting in a parametric down-conversion(PDC)interaction between two phononic polariton modes.By tuning cavity detuning,the nonlinear interaction can be enhanced with the frequency-matching condition.Results from analytical treatment based on the effective PDC model agree with the numerical simulation.Such a system provides potential applications in nonlinear phononics.
基金supported by the National Natural Science Foundation of China under Grant Nos.40674076 and 40474064the Hunan Natural Science Foundation of China under Grant No.07JJ3123the Scientific Research Fund of Hunan Provincial Education Department under Grant Nos.06C163,05B023,and 06B004
文摘By properly selecting the time-dependent unitary transformation for the linear combination of the number operators, we construct a time-dependent invariant and derive the corresponding auxiliary equations for the degenerate and non-degenerate coupled parametric down-conversion system with driving term. By means of this invariant and the Lewis-Riesenfeld quantum invariant theory, we obtain closed formulae of the quantum state and the evolution operator of the system. We show that the time evolution of the quantum system directly leads to production of various generalized one- and two-mode combination squeezed states, and the squeezed effect is independent of the driving term of the Hamiltonian. In some special cases, the current solution can reduce to the results of the previous works.
基金supported by the National Key R&D Program of China(2022YFB3606501,2022YFB3602902)the Key projects of National Natural Science Foundation of China(62234004)+8 种基金the National Natural Science Foundation of China(U23A2092)Pioneer and Leading Goose R&D Program of Zhejiang(2024C01191,2024C01092)Innovation and Entrepreneurship Team of Zhejiang Province(2021R01003)Ningbo Key Technologies R&D Program(2022Z085),Ningbo 3315 Programme(2020A-01-B)YONGJIANG Talent Introduction Programme(2021A-038-B,2021A-159-G)“Innovation Yongjiang 2035”Key R&D Programme(2024Z146)Ningbo JiangBei District public welfare science and technology project(2022C07)the China National Postdoctoral Program for Innovative Talents(grant no.BX20240391)the China Postdoctoral Science Foundation(grant no.2023M743623).
文摘High-resolution non-emissive displays based on electrochromic tungsten oxides(WOx)are crucial for future near-eye virtual/augmented reality interactions,given their impressive attributes such as high environmental stability,ideal outdoor readability,and low energy consumption.However,the limited intrinsic structure of inorganic materials has presented a significant challenge in achieving precise patterning/pixelation at the micron scale.Here,we successfully developed the direct photolithography for WOx nanoparticles based on in situ photo-induced ligand exchange.This strategy enabled us to achieve ultra-high resolution efficiently(line width<4μm,the best resolution for reported inorganic electrochromic materials).Additionally,the resulting device exhibited impressive electrochromic performance,such as fast response(<1 s at 0 V),high coloration efficiency(119.5 cm^(2) C^(−1)),good optical modulation(55.9%),and durability(>3600 cycles),as well as promising applications in electronic logos,pixelated displays,flexible electronics,etc.The success and advancements presented here are expected to inspire and accelerate research and development(R&D)in high-resolution non-emissive displays and other ultra-fine micro-electronics.
基金Supported by the National Key Basic Research Program of China under Grant Nos 2013CB933304 and 2014CB643904the National Natural Science Foundation of China under Grant Nos 61435012 and 61274125the Strategic Priority Research Program(B) of Chinese Academy of Sciences under Grant No XDB01010200
文摘A four-wavelength Bragg reflection waveguide edge emitting diode based on intracavity spontaneous parametric down-conversion and four-wave mixing （FWM） processes is made. The structure and its tuning characteris- tic are designed by the aid of FDTD mode solution. The laser structure is grown by molecular beam epitaxy and processed to laser diode through the semiconductor manufacturing technology. Fourier transform infrared spectroscopy is applied to record wavelength information. Pump around 1.071 μm, signal around 1.77μm, idler around 2.71 μm and FWM signal around 1.35μm are observed at an injection current of 560mA. The influ- ences of temperature, carrier density and pump wavelength on tuning characteristic are shown numerically and experimentally.
基金Project supported by the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(CAS)(Grant Nos.XDB01030100 and XDB01030300)the National Key Research and Development Program of China(Grant No.2016YFA0302600)the National Natural Science Foundation of China(Grant Nos.61475148 and 61575183)
文摘Parametric down-conversion（PDC） sources play an important role in quantum information processing, therefore characterizing their properties is necessary. Here we present a statistical model to assess the properties of the PDC source with certain distribution, such as the brightness and photon channel transmissions, we only need to measure the singles and coincidences counts in a few seconds. Furthermore, we validate the model by applying it to a PDC source generating highly non-degenerate photon pairs. The results of the experiment indicate that our method is more simple, efficient, and less time consuming.
基金financial support from the National Natural Science Foundation of China(Nos.22278011,22225803,22038001 and 22108007)Beijing Natural Science Foundation(No.Z230023)+1 种基金The Science&Technology Project of Beijing Municipal Education Committee(No.KZ201810005004)Beijing Nova Program(No.Z211100002121094)。
文摘Large-scale deployment of carbon dioxide(CO_(2))removal technology is an essential step to cope with global warming and achieve carbon neutrality.Direct air capture(DAC)has recently received increasing attention given the high flexibility to remove CO_(2)from discrete sources.Porous materials with adjustable pore characteristics are promising sorbents with low or no latent heat of vaporization.This review article has summarized the recent development of porous sorbents for DAC,with a focus of pore engineering strategy and adsorption mechanism.Physisorbents such as zeolites,porous carbons,metal-organic frameworks(MOFs),and amine-modified chemisorbents have been discussed and their challenges in practical application have been analyzed.At last,future directions have been proposed,and it is expected to inspire collaborations from chemistry,environment,material science and engineering communities.
基金financially supported by the National Key Research and Development Program of China(2023YFB3809300)。
文摘With the approaching of large-scale retirement of power lithium-ion batteries(LIBs),their urgent handling is required for environmental protection and resource reutilization.However,at present,substantial spent power batteries,especially for those high recovery value cathode materials,have not been greenly,sustainably,and efficiently recycled.Compared to the traditional recovery method for cathode materials with high energy consumption and severe secondary pollution,the direct repair regeneration,as a new type of short-process and efficient treatment methods,has attracted widespread attention.However,it still faces challenges in homogenization repair,electrochemical performance decline,and scaling-up production.To promote the direct regeneration technology development of failed NCM materials,herein we deeply discuss the failure mechanism of nickel-cobalt-manganese(NCM)ternary cathode materials,including element loss,Li/Ni mixing,phase transformation,structural defects,oxygen release,and surface degradation and reconstruction.Based on this,the detailed analysis and summary of the direct regeneration method embracing solid-phase sintering,eutectic salt assistance,solvothermal synthesis,sol-gel process,spray drying,and redox mediation are provided.Further,the upcycling strategy for regeneration materials,such as single-crystallization and high-nickelization,structural regulation,ion doping,and surface engineering,are discussed in deep.Finally,the challenges faced by the direct regeneration and corresponding countermeasures are pointed out.Undoubtedly,this review provides valuable guidance for the efficient and high-value recovery of failed cathode materials.
基金supported by the Key Research and Development Program of Shaanxi Province(2023-YBGY361)the National Natural Science Foundation of China(52275374 and 52205414)+1 种基金the Postdoctoral Fellowship Program of CPSF(GZC20232098)as well as the Xiaomi Foundation through Xiaomi Young Scholar Program。
文摘The layer-by-layer deposition strategy of additive manufacturing makes it ideal to fabricate dissimilar alloy components with varying functionality,which has promising application potential in a large number of industrial areas.In this study,two components composed of ERCuAl-A2 aluminum bronze(CuAl9)and Inconel 718 nickel-based superalloy were fabricated with different deposition orders by wire-arc directed energy deposition.Subject to changes in heat input and thermophysical properties of the substrate,the transition region of the deposited Cu-Ni component with the bottom half of CuAl9 and the top half of Inconel 718 is narrow and serrated.This region features a laminated intermetallic compound layer due to the convection and rapid cooling in the molten pool.In contrast,the Ni-Cu component deposited in the opposite order exhibits a 2 mm gradient transition zone.Within this region,a large number of diverse precipitates were found as well as regional variations in grain size due to the multi-layer partial remelting.Both two components show strong bonds and their tensile specimens tested along the vertical direction always fracture at the softer CuAl9 side.Excellent tensile properties along the horizontal direction were obtained for Cu-Ni(Ultimate tensile strength:573 MPa,yield stress:302 MPa,elongation:22%),while those of Ni-Cu are much lower due to the existence of the solidification cracks in the transition zone.The results from this study provide a reference for the additive manufacturing of Cu/Ni dissimilar alloy components,as well as their microstructure and mechanical properties control.
基金supported by Heilongjiang Province Key R&D Program(No.GA22A014)。
文摘For realizing the goals of“carbon peak”and“carbon neutrality”,lithium-ion batteries(LIB)with LiFePO_(4)as the cathode material have been widely applied.However,this has also led to a large number of spent lithium-ion batteries,and the safe disposal of spent lithium-ion batteries is an urgent issue.Currently,the main reason for the capacity decay of LiFePO_(4)materials is the Li deficiency and the formation of the Fe^(3+)phase.In order to address this issue,we performed high-temperature calcination of the discarded lithium iron phosphate cathode material in a carbon dioxide environment to reduce or partially remove the carbon coating on its surface.Subsequently,mechanical grinding was conducted to ensure thorough mixing of the lithium source with the discarded lithium iron phosphate.The reaction between CO_(2)and the carbon coating produced a reducing atmosphere,reducing Fe^(3+)to Fe^(2+)and thereby reducing the content of Fe^(3+).The Fe^(3+)content in the repaired LiFePO_(4)material is reduced.The crystal structure of spent LiFePO_(4)cathode materials was repaired more completely compare with the traditional pretreatment method,and the repaired LiFePO_(4)material shows good electrochemical performance and cycling stability.Under 0.1 C conditions,the initial capacity can reach 149.1 m Ah/g.It can be reintroduced for commercial use.
基金supported by the National Natural Science Foundation of China(52005264).
文摘Solution and aging treatment were conducted on the laser directed energy deposition(LDED)-prepared carbon nanotubes(CNTs)-reinforced WE43(CNTs/WE43)layers to optimize their microstructure and surface properties in this study.The microstructure of the WE43 and CNTs/WE43 layers was systematically compared.The dissolution of divorced eutectics at the grain boundaries was retarded by CNTs during solution treatment.The spot segregation composed of Mg_(24)Y_(5),CNTs,and Zr cores in the solution treated CNTs/WE43 layer presented a slight decreasing in Y content.The grain growth of both types of layers underwent three stages:slow,rapid,and steady-state.The significant inhibitory effect of CNTs on the grain growth of the LDED WE43 matrix was more pronounced than the promoting effect of temperature,resulting in a 47%increase at 510℃ and a 35%increase at 540℃ in the grain growth exponent compared to the WE43 layers at 510℃.During the subsequent aging treatment at 225℃,the precipitation sequences from plate-shaped β″to plate-shaped and globular β′ were observed in both types of layers.CNTs can facilitate an increase in the nucleation rate of precipitates,but without accelerating precipitation hardening rate.The long and short diameters of the precipitates in peak-aged state were decreased by 48.5%and 43.1%by addition of CNTs,respectively.The wear resistance of both the WE43 and CNTs/WE43 layers can be significantly enhanced through solution and aging treatment.The enhancement in wear resistance for the CNTs/WE43 layers is considerably greater than that of the WE43 layers.
文摘This study investigates the development of novel high-entropy alloys(HEAs)with enhanced mechanical properties through an innovative fabrication method of direct energy deposition(DED).The focus is on the creation of metastable core-shell precipitation-strengthened HEAs that exhibit a unique multi-stage terrace-like slip wave toughening mechanism,a novel approach to improving both strength and ductility simultaneously.Mechanical testing reveals that the developed HEAs exhibit superior mechanical proper-ties,including high yield strength,ultimate tensile strength,and exceptional ductility.The improvement in these properties is attributed to the multi-stage terrace-like slip wave toughening mechanism activated by the unique microstructural features.This toughening mechanism involves the sequential activation of slip systems,facilitated by the stress concentration around the core-shell precipitates and the subsequent propagation of slip waves across the material.The terrace-like pattern of these slip waves enhances the material's ability to deform plastically,providing a significant toughening effect while maintaining high strength levels.Furthermore,the study delves into the fundamental interactions between the microstruc-tural elements and the deformation mechanisms.It elucidates how the core-shell precipitates and the matrix cooperate to distribute stress uniformly,delay the onset of necking,and prevent premature failure.This synergistic interaction between the microstructural features and the slip wave toughening mecha-nism is central to the remarkable balance of strength and ductility achieved in the HEAs.The introduction of a multi-stage terrace-like slip wave toughening mechanism offers a new pathway to designing HEAs with an exceptional amalgamation of strength and ductility.
