U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dime...U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dimethylaminobenzyl)-N-methylaniline and 7-chloronorcarane as the major products. A photoinduced electron transfer mechanism is proposed.展开更多
The degradation and fate of pesticide N' (2,4 dimethylphenyl) N methylformamidine hydrochloride in simulated aquatic ecosystem were investigated. The results showed that the pesticide was not stable in simula...The degradation and fate of pesticide N' (2,4 dimethylphenyl) N methylformamidine hydrochloride in simulated aquatic ecosystem were investigated. The results showed that the pesticide was not stable in simulated aquatic ecosystem with pH value of 7.4—8.9 and water temperature of 18.0—26.5℃. In the first 9 days, 95% of DMAH was disappeared, whereas the concentration of its degradation product 2,4 dimethylformanilide increased with time and was of a maximum value at about 9 days and then decreased. The concentration of 2, 4 dimethylaniline, which is another degradation product of DMAH, nearly did not change in the early of experiment. However, it decreased rapidly after 9 days. The experiment lasted 51 days. At the end of experiment, there were no N' 2, 4 dimethylphenyl) N methylformamidine, 2, 4 dimethylformanilide and 2, 4 dimethylaniline detected in water, but they were all detected in the sediment and water grass, and the total amount of them covered 2%—3% of application amount of DMAH. It indicated that water grass and sediment could absorb and concentrate these compounds.展开更多
A deeper computational mechanistic study of an environmentally friendly metal-free CO_(2)reduction process towards obtaining methanol is presented,employing a previously tested kind of intramolecular frustrated Lewis ...A deeper computational mechanistic study of an environmentally friendly metal-free CO_(2)reduction process towards obtaining methanol is presented,employing a previously tested kind of intramolecular frustrated Lewis pair(2-[bis(R)boryl]-N,N-dimethylaniline)as the catalyst and H_(2)as the reducing agent.The Lewis acid strength of the electrophilic boron atom was adjusted to facilitate hydride release by changing the R group.展开更多
文摘U.V. irradiation of N,N-dimethylaniline (DMA) in the presence of 7,7-dichloronorcarane (DCN) in acetonitrile solution produces N-methyianiline, 4,4'-methylenebis-(N,N-dimethylaniline), N-(4'-N',N'-dimethylaminobenzyl)-N-methylaniline and 7-chloronorcarane as the major products. A photoinduced electron transfer mechanism is proposed.
文摘The degradation and fate of pesticide N' (2,4 dimethylphenyl) N methylformamidine hydrochloride in simulated aquatic ecosystem were investigated. The results showed that the pesticide was not stable in simulated aquatic ecosystem with pH value of 7.4—8.9 and water temperature of 18.0—26.5℃. In the first 9 days, 95% of DMAH was disappeared, whereas the concentration of its degradation product 2,4 dimethylformanilide increased with time and was of a maximum value at about 9 days and then decreased. The concentration of 2, 4 dimethylaniline, which is another degradation product of DMAH, nearly did not change in the early of experiment. However, it decreased rapidly after 9 days. The experiment lasted 51 days. At the end of experiment, there were no N' 2, 4 dimethylphenyl) N methylformamidine, 2, 4 dimethylformanilide and 2, 4 dimethylaniline detected in water, but they were all detected in the sediment and water grass, and the total amount of them covered 2%—3% of application amount of DMAH. It indicated that water grass and sediment could absorb and concentrate these compounds.
基金postdoctoral FONDECYT grant no.3200949 for financial support.RD acknowledges FONDECYT grant no.11230753PJ acknowledges the FONDECYT grant with project no.1181914.
文摘A deeper computational mechanistic study of an environmentally friendly metal-free CO_(2)reduction process towards obtaining methanol is presented,employing a previously tested kind of intramolecular frustrated Lewis pair(2-[bis(R)boryl]-N,N-dimethylaniline)as the catalyst and H_(2)as the reducing agent.The Lewis acid strength of the electrophilic boron atom was adjusted to facilitate hydride release by changing the R group.
