Cuprous oxide(Cu_(2)O) is one of the most promising catalysts for electrochemical conversion of CO_(2) into value-added C_(2) products.The efficiency of CO_(2)-to-C_(2) conversion is highly dependent on the Cu_(2)O cr...Cuprous oxide(Cu_(2)O) is one of the most promising catalysts for electrochemical conversion of CO_(2) into value-added C_(2) products.The efficiency of CO_(2)-to-C_(2) conversion is highly dependent on the Cu_(2)O crystal plane orientation and the corresponding adsorbed ^(*)CO species.Herein,we constructed high-index crystal planes(311) in Cu_(2)O(CO-Cu_(2)O) via a facile self-selective CO-induced strategy under a CO atmosphere,which was verified by high-resolution transmission electron microscopy(HR-TEM) and atomic force microscopy(AFM) results.By exploiting the high surface energy of the high index crystal planes,^(*)CO species are stabilized in CO-Cu_(2)O during CO_(2)RR,resulting in exceptional catalytic performance for CO_(2)-to-C_(2)products.In situ infrared spectroscopy revealed that both atop-type(^(*)CO_(atop)) and hollow-type(^(*)CO_(hollow)) adsorption of ^(*)CO species occurred on the CO-Cu_(2)O.The asymmetric C-C coupling energy barrier between ^(*)CO_(atop) and ^(*)CO_(hollow) in(311) crystal plane decreases by 47.8 % compared to the symmetric coupling of ^(*)CO_(atop) in conventional(100) crystal planes.Consequently,the Faradaic efficiency of C_(2) products generated with CO-Cu_(2)O was increased by as high as 100 % compared to that with pristine Cu_(2)O.展开更多
An in situ coupling strategy to prepare Co_9S_8/S and N dual?doped graphene composite(Co_9S_8/NSG) has been proposed. The key point of this strategy is the function?oriented design of organic compounds. Herein, cobalt...An in situ coupling strategy to prepare Co_9S_8/S and N dual?doped graphene composite(Co_9S_8/NSG) has been proposed. The key point of this strategy is the function?oriented design of organic compounds. Herein, cobalt porphyrin derivatives with sulfo groups are employed as not only the coupling agents to form and anchor Co_9S_8 on the graphene in situ, but also the heteroatom?doped agent to generate S and N dual?doped graphene. The tight coupling of multiple active sites endows the composite materials with fast electrochemical kinetics and excellent stability for both oxygen reduction reaction(ORR) and oxygen evolution reaction(OER). The obtained electrocatalyst exhibits better activity parameter(ΔE = 0.82 V) and smaller Tafel slope(47.7 mV dec^(-1) for ORR and 69.2 mV dec^(-1) for OER) than commercially available Pt/C and RuO_2. Most importantly, as electrocatalyst for rechargeable Zn–air battery, Co_9S_8/NSG displays low charge–discharge voltage gap and outstanding long?term cycle stability over 138 h compared to Pt/C–RuO_2. To further broaden its application scope, a homemade all?solid?state Zn–air battery is also prepared, which displays good charge–discharge performance and cycle performance. The function?oriented design of N_4?metallomacrocycle derivatives might open new avenues to strategic construction of high?performance and long?life multifunctional electrocatalysts for wider electro?chemical energy applications.展开更多
In the process of grid-connected wind and solar power generation,there are problems of high rate of abandoning wind and light and insufficient energy.In order to solve these problems,we construct a grid-connected wind...In the process of grid-connected wind and solar power generation,there are problems of high rate of abandoning wind and light and insufficient energy.In order to solve these problems,we construct a grid-connected wind-solar hydrogen storage(alkaline electrolyzer(AE)-hydrogen storage tank-battery-proton exchange membrane fuel cell(PEMFC))coupled system architecture.A grid-connected compensation/consumption hierarchical control strategy based on wind-solar hydrogen coupling is proposed.During the grid-connected process of wind and solar power generation,the upper-level control allocates power reasonably to the hydrogen energy storage system by dispatching the power of wind and solar power generation.At the same time,the control strategy ensures that the pressure of the hydrogen storage tank is within the safety range limit,and the lower control completes the control of the duty cycle of the converter in the system.Due to the randomness of wind and light,the hydrogen energy storage system is divided into three working conditions,namely compensation,balance and consumption,and five working modes.The simulation results show that the hydrogen energy storage system compensates for 40%of the power shortage,and consumes 27.5%of the abandoned wind and solar energy,which improves the utilization rate of clean energy.展开更多
Coupling adsorption and in-situ Fenton-like oxidation process was developed for Methylene blue(MB) using refined iron-containing lowgrade attapulgite(ATP) clay, and the removal mechanism was investigated. The MB was i...Coupling adsorption and in-situ Fenton-like oxidation process was developed for Methylene blue(MB) using refined iron-containing lowgrade attapulgite(ATP) clay, and the removal mechanism was investigated. The MB was initially adsorbed on the porous ATPs, and then the enriched MB was removed by the H2O2-assisted Fenton-like oxidation with the iron-containing ATP catalyst. Under optimal conditions, the ATP powder exhibits the maximum removal efficiency of 100% with negligible iron leaching(1.5 mg L^(-1)) and no sludge formation. Furthermore,polysulfone/ATP(PSF/ATP) pellets were fabricated through a water-induced phase separation process to construct a fixed-bed reactor(FBR) for continuous contaminant removal. For the first cycle, the maximum adsorption capacity was 15.5 L with an outlet MB concentration of1.973 mg L-1(< 2 mg L^(-1), GB4287-2012) using the PSF/ATP pellets containing 50.0 g of ATP powders, and the maximum Fenton-like oxidation capacity was 35.5 L with the outlet concentration of 0.831 mg L^(-1). After five cycles, the total treated volume of the MB solution was ca. 255 L, and the efficiency remained above 99%. After 10 h of continuous treatment towards practical resin industrial wastewater, the chemical oxygen demand(COD) removal efficiency was still measured at 83.05%, costing 0.398 $ m^(-3). These results demonstrate the practical applicability of iron-containing low-grade ATP clay for textile water treatment.展开更多
A new control strategy named adjacent coupling error strategy is proposed to multi-motor drive system. The adjacent coupling error control scheme is developed considering the tracking speed error in one motor and the ...A new control strategy named adjacent coupling error strategy is proposed to multi-motor drive system. The adjacent coupling error control scheme is developed considering the tracking speed error in one motor and the synchronous error among adjacent motors simultaneously. In the strategy, due to non-linear effects of the two mentioned errors to the motion control of motor i, an adaptive fuzzy logic controller is designed to decide the control variable of the motor drive system. The multi-motor drive system is modeled and simulated by SIMULINK. The simulated researches show that the proposed strategy improves the synchronization, stabilization, and convergence of the multi-motor system.展开更多
Based on analyzing the structure and working principle on electric vehicles （EVs） with dual motors coupled by planetarY gears, the control strategy of mode switching was proposed. The power interruption problem on E...Based on analyzing the structure and working principle on electric vehicles （EVs） with dual motors coupled by planetarY gears, the control strategy of mode switching was proposed. The power interruption problem on EVs with automatic mechanical transmission （AMT） shifting was resolved. Based on the speed-torque characteristics of the planetary gears and the principle of the auxiliary motor＇ s zero speed braking, control features of mode switching were introduced. The mode shifting between the main motor mode and dual motors coupled driving were studied. Matlab/Simulink was adopted as a platform to develop the simulation model of EVs with dual motors drive system and 3 gears AMT. Simulation results demonstrated that the power interruption of dual motors drive system was solved during mode switching. The power requirements of EVs were satisfied, too.展开更多
The present study aimed to clarify the smoking cessation motivations, challenges and coping strategies among pregnant couples. A qualitative design using a grounded theory approach was applied. Data were collected by ...The present study aimed to clarify the smoking cessation motivations, challenges and coping strategies among pregnant couples. A qualitative design using a grounded theory approach was applied. Data were collected by individual semi-structured interviews with 39 married individuals(21 non-smoking pregnant women and 18 smoking or ever-smoking men with a pregnant wife) and 3 imams in an ethnically diverse region of far western China. The most common theme for smoking cessation motivation was 'embryo quality'(i.e., a healthier baby), followed by family's health. Most interviewees reported that husband's withdrawal symptoms were the greatest challenge to smoking cessation, followed by the Chinese tobacco culture. Coping strategies given by the pregnant women typically involved combining emotional, behavioral and social interventions. Social interventions showed advantages in helping to quit smoking. Pregnancy appears to be a positive stimulus for pregnant couples' smoking cessation. Our results suggest that pregnancy, a highly important life event, may help to reduce barriers to smoking cessation at the social level(e.g., limiting access to cigarettes, avoiding temptation to smoke), but does little to help with the withdrawal symptoms. Professional guidance for smoking cessation is still necessary.展开更多
This paper addresses the micro wind-hydrogen coupled system,aiming to improve the power tracking capability of micro wind farms,the regulation capability of hydrogen storage systems,and to mitigate the volatility of w...This paper addresses the micro wind-hydrogen coupled system,aiming to improve the power tracking capability of micro wind farms,the regulation capability of hydrogen storage systems,and to mitigate the volatility of wind power generation.A predictive control strategy for the micro wind-hydrogen coupled system is proposed based on the ultra-short-term wind power prediction,the hydrogen storage state division interval,and the daily scheduled output of wind power generation.The control strategy maximizes the power tracking capability,the regulation capability of the hydrogen storage system,and the fluctuation of the joint output of the wind-hydrogen coupled system as the objective functions,and adaptively optimizes the control coefficients of the hydrogen storage interval and the output parameters of the system by the combined sigmoid function and particle swarm algorithm(sigmoid-PSO).Compared with the real-time control strategy,the proposed predictive control strategy can significantly improve the output tracking capability of the wind-hydrogen coupling system,minimize the gap between the actual output and the predicted output,significantly enhance the regulation capability of the hydrogen storage system,and mitigate the power output fluctuation of the wind-hydrogen integrated system,which has a broad practical application prospect.展开更多
Currently,the renewable energy-driven carbon dioxide reduction reaction(CO_(2)RR)has been identified as a promising carbon neutralization option capable of generating a variety of high-value hydrocarbon products.Impor...Currently,the renewable energy-driven carbon dioxide reduction reaction(CO_(2)RR)has been identified as a promising carbon neutralization option capable of generating a variety of high-value hydrocarbon products.Importantly,high-entropy borides(HEBs),which are similar to high-entropy carbides,have attracted extensive attention because of their outstanding chemical and physical properties,which allow them to be used as potential electrocatalysts,expanding the applications of high-entropy alloy materials.TiCrMnFeMoB is a new class of HEBs derived from Mo_(2)B_(2)MBenes via boro/carbothermal reduction.The electrochemical reduction of nitrate(NO_(3))-integrated CO_(2)to organonitrogen compounds(acetamide and urea)via C-N coupling is attracting increasing attention.This paper outlines a development route and strategy in this area,emphasizing the importance of electrochemical NO_(3)-integrated CO_(2)RR for achieving a carbon-neutral society.C-N coupling proceeds by the interaction between ketene(^(*)CCO)vs.ammonia(NH3)or carbon monoxide(^(*)CO)vs.hydroxylamine(NH_(2)OH)and the K^(+)cation in the acid electrolyte.The^(*)CCO intermediate forms^(*)CC(OH)NH_(2)as a result of the nucleophilic attack by NH3.The K^(+)cation and pH-dependent modulating reaction microenvironments play important roles in the design of high-performance catalysts for C-N bond coupling and C-C bond formation,which is critical for synthesizing valuable C-N chemicals from the CO_(2)RR-integrated NO_(3)reduction reaction(NtrRR).However,this route still faces many challenges in generating crucial intermediates during electrocatalytic C-N coupling.For the first time,we propose a general modeling strategy for K^(+)-induced and pH-dependent microenvironment electroreduction of CO_(2)and NO_(3)to acetamide and urea,respectively,over HEB catalysts under neutral,acidic,and alkaline conditions.Our results identified^(*)CCO and^(*)NH_(2)OH as the key intermediates for acetamide and urea synthesis,respectively,undergoing a nucleophilic reaction.This suggests that C-N coupling can occur via a nucleophilic reaction between^(*)CCO and NH3 to further form acetamide,whereas CO and NH_(2)OH form urea via two C-N coupling steps.This strategy expands the range of products generated from CO_(2)reduction and has been successfully applied to the formation of organonitrogen compounds.展开更多
针对现代化鹅养殖场景中饲料投喂移动小车受动态鹅群干扰,致使同时定位与地图构建(Simultaneous Localization And Mapping,SLAM)算法的定位精度、建图质量下降的问题,提出基于多传感融合目标检测的动态SLAM算法。该算法以LIO-SAM框架...针对现代化鹅养殖场景中饲料投喂移动小车受动态鹅群干扰,致使同时定位与地图构建(Simultaneous Localization And Mapping,SLAM)算法的定位精度、建图质量下降的问题,提出基于多传感融合目标检测的动态SLAM算法。该算法以LIO-SAM框架为基础,融合激光雷达与惯性测量单元搭建SLAM系统,采用前后端架构优化定位与建图性能;运用匈牙利算法实时追踪鹅群运动状态,结合多传感融合目标检测算法,精准识别并剔除动态鹅群产生的特征点,有效降低定位与建图误差。经KITTI、UrbanNav等公共数据集与实际养殖场景数据测试,在KITTI07序列中,较LeGO-LOAM、LIO-SAM和LVI-SAM等经典算法,均方根误差(RMSE)降低33.18%;在实际鹅养殖环境中,可以快速滤除动态鹅群干扰,提升建图质量与导航可靠性。本研究为智能化鹅养殖饲料投喂提供了新的技术方案,推动了畜牧业自动化发展。展开更多
The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)at...The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials.展开更多
基金the financial support from the National Natural Science Foundation of China (Nos.U23A20677,22022610 and 52400137)"Pioneer" and "Leading Goose" R&D Program of Zhejiang (Nos.2022C03146 and 2023C03017)+2 种基金China Postdoctoral Science Foundation (No.2024T170805)Zhejiang Provincial Natural Science Foundation of China (No.LDT23E06015B06)the support of the Research Computing Center in College of Chemical and Biological Engineering at Zhejiang University for assistance with the calculations。
文摘Cuprous oxide(Cu_(2)O) is one of the most promising catalysts for electrochemical conversion of CO_(2) into value-added C_(2) products.The efficiency of CO_(2)-to-C_(2) conversion is highly dependent on the Cu_(2)O crystal plane orientation and the corresponding adsorbed ^(*)CO species.Herein,we constructed high-index crystal planes(311) in Cu_(2)O(CO-Cu_(2)O) via a facile self-selective CO-induced strategy under a CO atmosphere,which was verified by high-resolution transmission electron microscopy(HR-TEM) and atomic force microscopy(AFM) results.By exploiting the high surface energy of the high index crystal planes,^(*)CO species are stabilized in CO-Cu_(2)O during CO_(2)RR,resulting in exceptional catalytic performance for CO_(2)-to-C_(2)products.In situ infrared spectroscopy revealed that both atop-type(^(*)CO_(atop)) and hollow-type(^(*)CO_(hollow)) adsorption of ^(*)CO species occurred on the CO-Cu_(2)O.The asymmetric C-C coupling energy barrier between ^(*)CO_(atop) and ^(*)CO_(hollow) in(311) crystal plane decreases by 47.8 % compared to the symmetric coupling of ^(*)CO_(atop) in conventional(100) crystal planes.Consequently,the Faradaic efficiency of C_(2) products generated with CO-Cu_(2)O was increased by as high as 100 % compared to that with pristine Cu_(2)O.
基金supported by the National Natural Science Foundation of China (Grant No. 21404014)the Science & Technology Department of Jilin Province (No. 20170101177JC)
文摘An in situ coupling strategy to prepare Co_9S_8/S and N dual?doped graphene composite(Co_9S_8/NSG) has been proposed. The key point of this strategy is the function?oriented design of organic compounds. Herein, cobalt porphyrin derivatives with sulfo groups are employed as not only the coupling agents to form and anchor Co_9S_8 on the graphene in situ, but also the heteroatom?doped agent to generate S and N dual?doped graphene. The tight coupling of multiple active sites endows the composite materials with fast electrochemical kinetics and excellent stability for both oxygen reduction reaction(ORR) and oxygen evolution reaction(OER). The obtained electrocatalyst exhibits better activity parameter(ΔE = 0.82 V) and smaller Tafel slope(47.7 mV dec^(-1) for ORR and 69.2 mV dec^(-1) for OER) than commercially available Pt/C and RuO_2. Most importantly, as electrocatalyst for rechargeable Zn–air battery, Co_9S_8/NSG displays low charge–discharge voltage gap and outstanding long?term cycle stability over 138 h compared to Pt/C–RuO_2. To further broaden its application scope, a homemade all?solid?state Zn–air battery is also prepared, which displays good charge–discharge performance and cycle performance. The function?oriented design of N_4?metallomacrocycle derivatives might open new avenues to strategic construction of high?performance and long?life multifunctional electrocatalysts for wider electro?chemical energy applications.
基金Xi’an Key Laboratory of Clean Energy(No.2019219914SYS014CG036)Natural Science Foundation of Xi’an City(No.XA2020-CXRCFW-0247)Yulin Industry-University-Research Cooperation Project(No.2019-173)。
文摘In the process of grid-connected wind and solar power generation,there are problems of high rate of abandoning wind and light and insufficient energy.In order to solve these problems,we construct a grid-connected wind-solar hydrogen storage(alkaline electrolyzer(AE)-hydrogen storage tank-battery-proton exchange membrane fuel cell(PEMFC))coupled system architecture.A grid-connected compensation/consumption hierarchical control strategy based on wind-solar hydrogen coupling is proposed.During the grid-connected process of wind and solar power generation,the upper-level control allocates power reasonably to the hydrogen energy storage system by dispatching the power of wind and solar power generation.At the same time,the control strategy ensures that the pressure of the hydrogen storage tank is within the safety range limit,and the lower control completes the control of the duty cycle of the converter in the system.Due to the randomness of wind and light,the hydrogen energy storage system is divided into three working conditions,namely compensation,balance and consumption,and five working modes.The simulation results show that the hydrogen energy storage system compensates for 40%of the power shortage,and consumes 27.5%of the abandoned wind and solar energy,which improves the utilization rate of clean energy.
基金supported by Gansu Cuihua Technology Co.,Ltd.(H2020292)Science and Technology Planning of Baiyin City,Fundamental Research Funds for the Central Universities (buctrc202208)+2 种基金Engineering Research Center of Non-metallic Minerals of Zhejiang Province and the Beijing Engineering Center for Hierarchical Catalysts. Central Government Guiding Funds for Local Science and Technology Development (2022ZY015)Nanjiang Technology Project(2023AB028)Open Laboratory of State Key Laboratory of Organic and Inorganic Composites (oic-202301006)。
文摘Coupling adsorption and in-situ Fenton-like oxidation process was developed for Methylene blue(MB) using refined iron-containing lowgrade attapulgite(ATP) clay, and the removal mechanism was investigated. The MB was initially adsorbed on the porous ATPs, and then the enriched MB was removed by the H2O2-assisted Fenton-like oxidation with the iron-containing ATP catalyst. Under optimal conditions, the ATP powder exhibits the maximum removal efficiency of 100% with negligible iron leaching(1.5 mg L^(-1)) and no sludge formation. Furthermore,polysulfone/ATP(PSF/ATP) pellets were fabricated through a water-induced phase separation process to construct a fixed-bed reactor(FBR) for continuous contaminant removal. For the first cycle, the maximum adsorption capacity was 15.5 L with an outlet MB concentration of1.973 mg L-1(< 2 mg L^(-1), GB4287-2012) using the PSF/ATP pellets containing 50.0 g of ATP powders, and the maximum Fenton-like oxidation capacity was 35.5 L with the outlet concentration of 0.831 mg L^(-1). After five cycles, the total treated volume of the MB solution was ca. 255 L, and the efficiency remained above 99%. After 10 h of continuous treatment towards practical resin industrial wastewater, the chemical oxygen demand(COD) removal efficiency was still measured at 83.05%, costing 0.398 $ m^(-3). These results demonstrate the practical applicability of iron-containing low-grade ATP clay for textile water treatment.
基金National Natural Science Foundation of China (No.60774023)
文摘A new control strategy named adjacent coupling error strategy is proposed to multi-motor drive system. The adjacent coupling error control scheme is developed considering the tracking speed error in one motor and the synchronous error among adjacent motors simultaneously. In the strategy, due to non-linear effects of the two mentioned errors to the motion control of motor i, an adaptive fuzzy logic controller is designed to decide the control variable of the motor drive system. The multi-motor drive system is modeled and simulated by SIMULINK. The simulated researches show that the proposed strategy improves the synchronization, stabilization, and convergence of the multi-motor system.
基金Supported by Doctoral Fund of Ministry of Education of China(20101101110012)the National Natural Science Foundationof China(51175040)
文摘Based on analyzing the structure and working principle on electric vehicles （EVs） with dual motors coupled by planetarY gears, the control strategy of mode switching was proposed. The power interruption problem on EVs with automatic mechanical transmission （AMT） shifting was resolved. Based on the speed-torque characteristics of the planetary gears and the principle of the auxiliary motor＇ s zero speed braking, control features of mode switching were introduced. The mode shifting between the main motor mode and dual motors coupled driving were studied. Matlab/Simulink was adopted as a platform to develop the simulation model of EVs with dual motors drive system and 3 gears AMT. Simulation results demonstrated that the power interruption of dual motors drive system was solved during mode switching. The power requirements of EVs were satisfied, too.
基金supported by the National Philosophy and Social Science Foundation of China(No.15ZDC037)the National Natural Science Foundation of China(key program)(No.71333005)
文摘The present study aimed to clarify the smoking cessation motivations, challenges and coping strategies among pregnant couples. A qualitative design using a grounded theory approach was applied. Data were collected by individual semi-structured interviews with 39 married individuals(21 non-smoking pregnant women and 18 smoking or ever-smoking men with a pregnant wife) and 3 imams in an ethnically diverse region of far western China. The most common theme for smoking cessation motivation was 'embryo quality'(i.e., a healthier baby), followed by family's health. Most interviewees reported that husband's withdrawal symptoms were the greatest challenge to smoking cessation, followed by the Chinese tobacco culture. Coping strategies given by the pregnant women typically involved combining emotional, behavioral and social interventions. Social interventions showed advantages in helping to quit smoking. Pregnancy appears to be a positive stimulus for pregnant couples' smoking cessation. Our results suggest that pregnancy, a highly important life event, may help to reduce barriers to smoking cessation at the social level(e.g., limiting access to cigarettes, avoiding temptation to smoke), but does little to help with the withdrawal symptoms. Professional guidance for smoking cessation is still necessary.
基金the Key Research&Development Program of Xinjiang(Grant Number 2022B01003).
文摘This paper addresses the micro wind-hydrogen coupled system,aiming to improve the power tracking capability of micro wind farms,the regulation capability of hydrogen storage systems,and to mitigate the volatility of wind power generation.A predictive control strategy for the micro wind-hydrogen coupled system is proposed based on the ultra-short-term wind power prediction,the hydrogen storage state division interval,and the daily scheduled output of wind power generation.The control strategy maximizes the power tracking capability,the regulation capability of the hydrogen storage system,and the fluctuation of the joint output of the wind-hydrogen coupled system as the objective functions,and adaptively optimizes the control coefficients of the hydrogen storage interval and the output parameters of the system by the combined sigmoid function and particle swarm algorithm(sigmoid-PSO).Compared with the real-time control strategy,the proposed predictive control strategy can significantly improve the output tracking capability of the wind-hydrogen coupling system,minimize the gap between the actual output and the predicted output,significantly enhance the regulation capability of the hydrogen storage system,and mitigate the power output fluctuation of the wind-hydrogen integrated system,which has a broad practical application prospect.
基金supported by the Xinjiang Vocational&Technical College of Communications with Grant no.2023YFSY0036Financial support comes from the funding from the XinJiang Tianshan Talent Projet with Grant no.2022SNGGNT104 from Li Liusupported by the Department of Science and Technology of Sichuan Province with Grant no.2023YFSY0036 from Yingchun Ding.
文摘Currently,the renewable energy-driven carbon dioxide reduction reaction(CO_(2)RR)has been identified as a promising carbon neutralization option capable of generating a variety of high-value hydrocarbon products.Importantly,high-entropy borides(HEBs),which are similar to high-entropy carbides,have attracted extensive attention because of their outstanding chemical and physical properties,which allow them to be used as potential electrocatalysts,expanding the applications of high-entropy alloy materials.TiCrMnFeMoB is a new class of HEBs derived from Mo_(2)B_(2)MBenes via boro/carbothermal reduction.The electrochemical reduction of nitrate(NO_(3))-integrated CO_(2)to organonitrogen compounds(acetamide and urea)via C-N coupling is attracting increasing attention.This paper outlines a development route and strategy in this area,emphasizing the importance of electrochemical NO_(3)-integrated CO_(2)RR for achieving a carbon-neutral society.C-N coupling proceeds by the interaction between ketene(^(*)CCO)vs.ammonia(NH3)or carbon monoxide(^(*)CO)vs.hydroxylamine(NH_(2)OH)and the K^(+)cation in the acid electrolyte.The^(*)CCO intermediate forms^(*)CC(OH)NH_(2)as a result of the nucleophilic attack by NH3.The K^(+)cation and pH-dependent modulating reaction microenvironments play important roles in the design of high-performance catalysts for C-N bond coupling and C-C bond formation,which is critical for synthesizing valuable C-N chemicals from the CO_(2)RR-integrated NO_(3)reduction reaction(NtrRR).However,this route still faces many challenges in generating crucial intermediates during electrocatalytic C-N coupling.For the first time,we propose a general modeling strategy for K^(+)-induced and pH-dependent microenvironment electroreduction of CO_(2)and NO_(3)to acetamide and urea,respectively,over HEB catalysts under neutral,acidic,and alkaline conditions.Our results identified^(*)CCO and^(*)NH_(2)OH as the key intermediates for acetamide and urea synthesis,respectively,undergoing a nucleophilic reaction.This suggests that C-N coupling can occur via a nucleophilic reaction between^(*)CCO and NH3 to further form acetamide,whereas CO and NH_(2)OH form urea via two C-N coupling steps.This strategy expands the range of products generated from CO_(2)reduction and has been successfully applied to the formation of organonitrogen compounds.
文摘针对现代化鹅养殖场景中饲料投喂移动小车受动态鹅群干扰,致使同时定位与地图构建(Simultaneous Localization And Mapping,SLAM)算法的定位精度、建图质量下降的问题,提出基于多传感融合目标检测的动态SLAM算法。该算法以LIO-SAM框架为基础,融合激光雷达与惯性测量单元搭建SLAM系统,采用前后端架构优化定位与建图性能;运用匈牙利算法实时追踪鹅群运动状态,结合多传感融合目标检测算法,精准识别并剔除动态鹅群产生的特征点,有效降低定位与建图误差。经KITTI、UrbanNav等公共数据集与实际养殖场景数据测试,在KITTI07序列中,较LeGO-LOAM、LIO-SAM和LVI-SAM等经典算法,均方根误差(RMSE)降低33.18%;在实际鹅养殖环境中,可以快速滤除动态鹅群干扰,提升建图质量与导航可靠性。本研究为智能化鹅养殖饲料投喂提供了新的技术方案,推动了畜牧业自动化发展。
基金supported by the National Natural Science Foundation of China(22265021,52231007,and 12327804)the Aeronautical Science Foundation of China(2020Z056056003)Jiangxi Provincial Natural Science Foundation(20232BAB212004).
文摘The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials.
