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Durability of concrete beams reinforced with CFRP sheet under wet-dry cycles and loading 被引量:2
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作者 李杉 任慧韬 +1 位作者 黄承逵 崔云飞 《Journal of Southeast University(English Edition)》 EI CAS 2009年第3期376-380,共5页
The test results of eight concrete beams reinforced with carbon fiber reinforced polymer (CFRP) sheets subjected to an aggressive environment under a sustained load are presented. The beams are 1 700 mm long with a ... The test results of eight concrete beams reinforced with carbon fiber reinforced polymer (CFRP) sheets subjected to an aggressive environment under a sustained load are presented. The beams are 1 700 mm long with a rectangular cross-section of 120- mm width and 200-mm depth. The beams are precracked with a four-point flexural load, bonded CFRP sheets, and placed into wet-dry saline water( NaCl) either in an unstressed state or loaded to about 30% or 60% of the initial ultimate load. The individual and coupled effects of wet-dry saline water and sustained bending stresses on the long term behaviour of concrete beams reinforced with the CFRP are investigated. The test results show that the coupled action of wet-dry saline water and sustained bending stresses appears to significantly affect the load capacity and the failure mode of beam strengthened with CFRP, mainly due to the degradation of the bond between CFRP and concrete. However, the stiffness is not affected by the coupled action of wet-dry cycles and a sustained load. 展开更多
关键词 reinforced concrete beams REINFORCED carbon fiber reinforced polymers DURABILITY wet-dry cycles sustained load
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GIGACYCLE FATIGUE BEHAVIOR OF CAST ALUMINUM IN TENSION AND TORSION LOADING 被引量:3
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作者 薛红前 吴铁鹰 Bathias C 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2011年第1期32-37,共6页
An improved understanding of fatigue behavior of a cast aluminum alloy(2-AS5U3G-Y35)in very high cycle regime is developed through the ultrasonic fatigue test in axial and torsion loading.The new developed torsion f... An improved understanding of fatigue behavior of a cast aluminum alloy(2-AS5U3G-Y35)in very high cycle regime is developed through the ultrasonic fatigue test in axial and torsion loading.The new developed torsion fatigue system is presented.The effects of loading condition and frequency on the very high cycle fatigue(VHCF)are investigated.The cyclic loading in axial and torsion at 35 Hz and 20 kHz with stress ratio R=-1 is used respectively to demonstrate the effect of loading condition.S-N curves show that the fatigue failure occurs in the range of 105—1010 cycles in axial or torsion loading and the asymptote of S-N curve is inclined,but no fatigue limit exists under the torsion and axial loading condition.The fatigue fracture surface shows that the fatigue crack initiates from the specimen surface subjected to the cyclic torsion loading.It is different from the fatigue fracture characteristic in axial loading in which fatigue crack initiates from subsurface defect in very high cycle regime.The fatigue initiation is on the maximum shear plane,the overall crack orientation is on a typical spiral 45° to the fracture plane and it is the maximum principle stress plane.The clear shear strip in the torsion fatigue fracture surface shows that the torsion fracture is the shear fracture. 展开更多
关键词 fatigue testing torsion fatigue very high cycle fatigue(VHCF) torsion loading cast aluminum
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Macro-micro tests of cohesive soil under varied normal and shear stresses subjected to drying-wetting cycles
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作者 Fangyue Luo Ga Zhang Yangping Yao 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5893-5905,共13页
The mechanical behavior of cohesive soil is sensitized to drying-wetting cycles under confinements.However,the hydromechanical coupling effect has not been considered in current constitutive models.A macro-micro analy... The mechanical behavior of cohesive soil is sensitized to drying-wetting cycles under confinements.However,the hydromechanical coupling effect has not been considered in current constitutive models.A macro-micro analysis scheme is proposed in this paper to investigate the soil deformation behavior under the coupling of stress and drying-wetting cycles.A new device is developed based on CT(computerized tomography)workstation to apply certain normal and shear stresses on a soil specimen during drying-wetting cycles.A series of tests are conducted on a type of loess with various coupling of stress paths and drying-wetting cycles.At macroscopic level,stress sensor and laser sensor are used to acquire stress and strain,respectively.The shear and volumetric strain increase during the first few drying-wetting cycles and then become stable.The increase of the shear stress level or confining pressure would cause higher increase rate and the value of shear strain in the process of drying-wetting cycles.At microscopic level,the grayscale value(GSV)of CT scanning image is characterized as the proportion of soil particles to voids.A fabric state parameter is proposed to characterize soil microstructures under the influence of stress and drying-wetting cycle.Test results indicate that the macroand micro-responses show high consistence and relevance.The stress and drying-wetting cycles would both induce collapse of the soil microstructure,which dominants degradation of the soil mechanical properties.The evolution of the macro-mechanical property of soil exhibits a positive linear relationship with the micro-evolution of the fabric state parameter. 展开更多
关键词 Cohesive soil Drying-wetting cycle Coupled loading Macro and micro test FABRIC
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Effect of flexural loading on degradation progress of recycled aggregate concrete subjected to sulfate attack and wetting-drying cycles 被引量:5
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作者 Zhao Yasong Gao Jianming +1 位作者 Qi Bing Liu Chuanbei 《Journal of Southeast University(English Edition)》 EI CAS 2019年第1期83-88,共6页
The degradation progress of recycled aggregate concrete(RAC) subjected to sulfate attack under wetting-drying cycles and flexural loading is studied. Three different stress ratios(0, 0.3 and 0.5) were applied in this ... The degradation progress of recycled aggregate concrete(RAC) subjected to sulfate attack under wetting-drying cycles and flexural loading is studied. Three different stress ratios(0, 0.3 and 0.5) were applied in this test. The variations of relative dynamic elastic modulus Erd and water-soluble SO2-4 contents in RAC were used to evaluate degradation progress. The changes in mineral products and microstructures of interior concrete were investigated by means of X-ray diffraction(XRD), the environmental scanning electron microscope(ESEM) and X-ray computed tomography(X-CT). The results indicate that flexural loading accelerates the degradation of RAC under sulfate attack and wetting-drying cycles by expediting the transmission of SO2-4 into interior concrete. Furthermore, the accelerated effect of flexural loading is more obvious with the increase of stress ratio, that is because higher stress ratios can accelerate the extension of microcracks and generate more channels for the transmission of SO2-4. Also, more expansive products(gypsum and ettringite) are generated by the reaction of Ca(OH)2 with SO2-4, which can further accelerate the degradation of RAC. 展开更多
关键词 recycled aggregate concrete DEGRADATION sulfate attack flexural loading wetting-drying cycles
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Coupling Mechanism of Saturated Concrete Subjected to Simultaneous Fatigue Loading and Freeze-thaw Cycles 被引量:1
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作者 QIAO Yunfeng SUN Wei +1 位作者 JIANG Jinyang PAN Dongfang 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2018年第5期1121-1128,共8页
The coupling mechanism of saturated concrete subjected to simultaneous 4-point fatigue loading and freeze-thaw cycles was, for the first time, experimentally studied by strain technology. The coupling strain, temperat... The coupling mechanism of saturated concrete subjected to simultaneous 4-point fatigue loading and freeze-thaw cycles was, for the first time, experimentally studied by strain technology. The coupling strain, temperature strain and fatigue strain of concrete specimens were measured at the same time from one sample with stain analysis method and the relationship among these three kinds of strains was studied by fitting data to present coupling mechanism at macro level. The results showed that there was no interaction between fatigue strain and temperature strain and the coupling strain could be written by linear superposition of temperature strain and fatigue strain. 展开更多
关键词 coupling mechanism fatigue loading freeze-thaw cycles strain saturated concrete
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Investigation of Excavator Performance Factors in an Open-Pit Mine Using Loading Cycle Time 被引量:1
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作者 Samwel Victor Manyele 《Engineering(科研)》 2017年第7期599-624,共26页
This study presents the effect of excavator model, loading operation location, shift availability and truck-shovel combination on loading cycle time and productivity of an open-pit mine. The loading cycle time was use... This study presents the effect of excavator model, loading operation location, shift availability and truck-shovel combination on loading cycle time and productivity of an open-pit mine. The loading cycle time was used to assess the material loading system performance which is one of the key components of the total cycle time for material transportation in an open-pit mine. Loading is among the components of cycle time during which material is being handled. The data analyzed?was?collected from a computerized dispatch system at GGM from which 62,000 loading dispatches per month involving several shifts, 14 excavators and 49 trucks were loaded. About 4465 dispatches per excavator and 1276 dispatches per truck were assessed using loading cycle time data for each dispatch for a period of four months (between August and December). Under fixed tonnage loaded and waste type (33 t of non-acid forming waste rock),?it was observed that loading cycle time depends on excavator model, location and truck being loaded. Average cycle times, PDFS?and CDFS of loading cycle time series were used to identify differences in performance under different situations. It was concluded that shift availability for excavators, loading location, excavator model and truck-shovel combinations strongly affect the productivity during loading process in an open-pit mine. 展开更多
关键词 Potentially Acid-Forming (PAF) ROCK Non-Acid FORMING (NAF) ROCK TRUCK Utilization TRUCK Fill-Factor Queuing TIME loading cycle TIME Full and Empty Haul Total cycle TIME Theoretical cycle TIME Non-Productive cycle TIME cycle TIME Performance Ratio
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Performance of Concrete Subjected to Severe Multiple Actions of Composite Salts Solution under Wet-Dry Cycles and Flexural Loading in Lab 被引量:2
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作者 陈燕娟 高建明 +1 位作者 TANG Luping SHEN Daman 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2017年第4期830-837,共8页
Several action regimes were employed, namely, those exposed to solutions containing single and/or composite chloride and sulfate salts, and under wet-dry cycles and/or flexural loading. The variations in dynamic modul... Several action regimes were employed, namely, those exposed to solutions containing single and/or composite chloride and sulfate salts, and under wet-dry cycles and/or flexural loading. The variations in dynamic modulus of elasticity(Erd values) were monitored, as well as the key factor impacting on the chloride ingress when concrete subjected to multiple action regimes was identified by the method of Grey Relation Analysis(GRA). The changes in micro-structures and mineral products of interior concrete after different action regimes were investigated by means of X-ray diffraction(XRD), mercury intrusion technique(MIP), and scanning electron microscopy(SEM). The test results showed that the cyclic wet-dry accelerated the deterioration of OPC concrete more than the action of 35% flexural loading based on the results of Erd values and the GEA. The analyses from micro-structures could give certain explanations to the change in Erd values under different action regimes. 展开更多
关键词 concrete wet-dry cycles flexural loading composite salts solution grey relation analysis
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Euler Loading Formula of LargeDeflection and the Quick Solution for Large Deflection Equation of Beam and Column
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作者 黄平 王培荣 樊卫勇 《International Journal of Mining Science and Technology》 SCIE EI 1997年第1期83-86,共4页
This paper develops Euler ’loadlng formula of large deflection to be easy to measure in-situ and puts forward the differeuce quick iterative solution ror large deflection of beam and column, whick can solve the uon-l... This paper develops Euler ’loadlng formula of large deflection to be easy to measure in-situ and puts forward the differeuce quick iterative solution ror large deflection of beam and column, whick can solve the uon-linear equation like a kind of θ"+K(s)f(θ) =0. 展开更多
关键词 large deflection EULER loading FORMULA non-linear EQUATION interative SOLUTION
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Degradation of Pore Structure and Microstructures in Hardened Cement Paste Subjected to Flexural Loading and Wet-dry Cycles in Sea Water
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作者 张武满 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2009年第6期940-944,共5页
Hardened cement paste was subjected to the flexural loading and wet-dry cycles in sea water. The degradation of microstructures was obtained using scanning electron microscope (SEM), and the energy dispersive spectr... Hardened cement paste was subjected to the flexural loading and wet-dry cycles in sea water. The degradation of microstructures was obtained using scanning electron microscope (SEM), and the energy dispersive spectrum (EDS) analysis was carried to analyze the local composition. Mercury intrusion porosimetry (Poremaster GT-60) was used to analyze the degradation of pore structures. The experimental results show that the synergistic action of the flexural loading, wet-dry cycles and sea water leads to significant deterioration of hardened cement paste. The degradation of microstructures in the tensile region is more serious than that in the compressive region. The flexural loading and wet-dry cycles accelerate the chemical attack of sea water. 展开更多
关键词 hardened cement paste pore structure MICROSTRUCTURES flexural loading wet-dry cycles sea water
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Effect of Reinforcement on Deflection and Cracks in Baked Clay Beams Subjected to Impact Loading
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作者 Nawab Ali Lakho Muhammad Auchar Zardari 《Engineering(科研)》 2016年第10期691-696,共7页
Attempts are being made to utilize Reinforced Baked Clay (RBC) as a substitute of Reinforced Cement Concrete (RCC) for construction of low cost houses in plains of Pakistan. Since baked clay is considered to be more b... Attempts are being made to utilize Reinforced Baked Clay (RBC) as a substitute of Reinforced Cement Concrete (RCC) for construction of low cost houses in plains of Pakistan. Since baked clay is considered to be more brittle as compared to concrete. Therefore, it is necessary to investigate how deflection and crack width of RBC beams subjected to impact loading are governed by amount of reinforcement. This paper presents the behaviour of RBC beams under drop weight impact loading. The beams were reinforced with two steel bars, one in compression zone and the other in tension zone. In group A beams, the diameter of steel bars was 12.7 mm, while the beams of group B were reinforced with steel bars of 15.8 mm diameter. The RBC beams were subjected to repeated impacts of a hammer of mass 21 kg falling from a height of 1000 mm. The results show that 1) three times reduction in deflection, and 2) 2.5 times decrease in crack width, were achieved in RBC beams by increasing the area of steel to 50%. In addition to this, all the RBC beams failed within nine blows of the hammer, irrespective of area of reinforcement. 展开更多
关键词 Reinforced Baked Clay Impact load deflection Cracks Compressive Strength
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Deflection and stress of hollow CRCP slab under concentrated vehicle load 被引量:2
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作者 陈小兵 黄晓明 +1 位作者 丁建明 童金虎 《Journal of Southeast University(English Edition)》 EI CAS 2011年第2期213-216,共4页
Based on the equivalence principle of deflection and stress, the concentrated vehicle load which acts on the center of continuously reinforced concrete pavement (CRCP) is translated into the equivalent half-wave sin... Based on the equivalence principle of deflection and stress, the concentrated vehicle load which acts on the center of continuously reinforced concrete pavement (CRCP) is translated into the equivalent half-wave sine load by the Fourier transform. On the basis of this transform and the small deflection theory of elastic thin plates, the deflection and stress formulae of CRCP under the concentrated vehicle load with a hollow foundation are put forward. The sensitivity of parameters is analyzed. The results show that maximum deflection is directly proportional to the concentrated vehicle load and the slab width, and inversely proportional to the lateral bending stiffness and slab thickness. The effects of slab width and thickness are significant with regard to maximum deflection. Maximum stress is directly proportional to the concentrated vehicle load and the slab width as well as inversely proportional to slab thickness. The effect of slab thickness is significant with regard to maximum stress. According to the calculation results, the most effective measure to reduce maximum deflection and stress is to increase slab thickness. 展开更多
关键词 concentrated vehicle load equivalence principle half-wave sine load elastic thin plates hollow continuouslyreinforced concrete pavement slab deflection and stressformulae slab thickness
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Experimental study of dynamic resilient modulus of subgrade soils under coupling of freeze–thaw cycles and dynamic load 被引量:11
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作者 ZHAO Yang LU Zheng +2 位作者 YAO Hai-lin GU Fan DUAN Ya-hui 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第7期2043-2053,共11页
Although the dynamic properties of subgrade soils in seasonally frozen areas have already been studied, few researchers have considered the influence of shallow groundwater during the freeze–thaw(F–T) cycles. So a m... Although the dynamic properties of subgrade soils in seasonally frozen areas have already been studied, few researchers have considered the influence of shallow groundwater during the freeze–thaw(F–T) cycles. So a multifunctional F–T cycle system was developed to imitate the groundwater recharge in the subgrade during the freezing process and a large number of dynamic triaxial experiments were conducted after the F–T cycles. Some significant factors including the F–T cycle number, compaction degree, confining pressure, cyclic deviator stress, loading frequency, and water content were investigated for the resilient modulus of soils. The experimental results indicated that the dynamic resilient modulus of the subgrade was negatively correlated with the cyclic deviator stress, F–T cycle number, and initial water content, whereas the degree of compaction, confining pressure, and loading frequency could enhance the resilient modulus. Furthermore, a modified model considering the F–T cycle number and stress state was established to predict the dynamic resilient modulus. The calculated results of this modified model were very close to the experimental results. Consequently, calculation of the resilient modulus for F–T cycles considering the dynamic load was appropriate. This study provides reference for research focusing on F–T cycles with groundwater supply and the dynamic resilient moduli of subgrade soils in seasonally frozen areas. 展开更多
关键词 dynamic resilient modulus freeze–thaw cycles dynamic load dynamic triaxial test prediction model
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Development and application of an instrument for simulating wetting-drying cycles of expansive soils under loads 被引量:3
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作者 DONG Jun-gui LV Hai-bo WU Wei 《Journal of Mountain Science》 SCIE CSCD 2018年第11期2552-2560,共9页
Alternating rainfall and evaporation in nature severely impact the shear strength of expansive soils. This study presents an instrument for simulating the effect of wetting–drying cycles on the strength of expansive ... Alternating rainfall and evaporation in nature severely impact the shear strength of expansive soils. This study presents an instrument for simulating the effect of wetting–drying cycles on the strength of expansive soils under different loads, and its testing error is verified. With this instrument,direct shear tests were performed on samples experiencing 0-6 cycles under vertical loads of 0 kPa,5 kPa, 15 kPa, and 30 k Pa. The results found that this instrument provides a new method for evaluating the effects of wetting–drying cycles on soils, and this method represents actual engineering conditions more accurately than do preexisting methods. It accurately controls the water content within 1% while simulating the specified loads at different soil depths.Cohesion is significantly affected by wetting–drying cycles, while the friction angle is not as sensitive to these cycles. Decrease in shear strength can be attributed to the fissures in soils caused by wetting–drying cycles. The existence of vertical loads effectively restricts shrinkage fissuring and cohesion attenuation, consequently inhibiting the attenuation of shear strength. 展开更多
关键词 Expansive soils Wetting-drying cycle Instrument load Shear strength
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Large deflections of non-prismatic nonlinearly elastic cantilever beams subjected to non-uniform continuous load and a concentrated load at the free end 被引量:1
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作者 Miha Brojan Matjaz Cebron Franc Kosel 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2012年第3期863-869,共7页
This work studies large deflections of slen- der, non-prismatic cantilever beams subjected to a combined loading which consists of a non-uniformly distributed con- tinuous load and a concentrated load at the free end ... This work studies large deflections of slen- der, non-prismatic cantilever beams subjected to a combined loading which consists of a non-uniformly distributed con- tinuous load and a concentrated load at the free end of the beam. The material of the cantilever is assumed to be non- linearly elastic. Different nonlinear relations between stress and strain in tensile and compressive domain are considered. The accuracy of numerical solutions is evaluated by com- paring them with results from previous studies and with a laboratory experiment. 展开更多
关键词 Large deflections Non-prismatic beams Com-bined loading - Generalized Ludwick constitutive law ~ Ma-terial and geometrical nonlinearity
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Deflection analysis of reinforced concrete beams strengthened with carbon fibre reinforced polymer under long-term load action
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作者 Mykolas DAUGEVIIUS Juozas VALIVONIS Gediminas MAR IUKAITIS 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2012年第8期571-583,共13页
This paper presents the results of an experimental research on reinforced concrete beams strengthened with an external carbon fibre reinforced polymer(CFRP) layer under long-term load action that lasted for 330 d.We d... This paper presents the results of an experimental research on reinforced concrete beams strengthened with an external carbon fibre reinforced polymer(CFRP) layer under long-term load action that lasted for 330 d.We describe the characteristics of deflection development of the beams strengthened with different additional anchorages of the external carbon fibre composite layer during the period of interest.The conducted experiments showed that the additional anchorage influences the slip of the external layer with respect to the strengthened element.Thus,concrete and carbon fibre composite interface stiffness decreases with a long-term load action.Therefore,the proposed method of analysis based on the built-up-bars theory can be used to estimate concrete and carbon fibre composite interface stiffness in the case of long-term load. 展开更多
关键词 Carbon fibre composite Beam strengthening Beam deflection Long-term load Bending stiffness Concrete and carbon fibre composite interface stiffness Effective inertia moment
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Comparison Between Two Solutions Based on the Relationship of Load-deflection Character of a Large Deflection Rubber Circular Plate
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作者 段浩 胡宗武 +1 位作者 杨赪石 黎佑铭 《Journal of Shanghai Jiaotong university(Science)》 EI 2003年第1期67-70,共4页
The rubber circular plate is considered as a kind of membrane. Based on the character that there exists no bending moment inside a membrane, the geometric behavior of the rubber circular plate in expanding state was d... The rubber circular plate is considered as a kind of membrane. Based on the character that there exists no bending moment inside a membrane, the geometric behavior of the rubber circular plate in expanding state was described with the aid of a group of mathematic method. The relationship between deflection and load was attained by means of calculating stress and strain inside the curved surface of rubber plate. Meantime, based on Hencky method, the relationship between deflection and load was attained and considered as the Hencky solution. The different results given rise by the two different resolving methods were compared. The deviation results from the Hencky method was discussed, and a kind of correcting method was put forward. 展开更多
关键词 rubber circular plate large deflection load geometric character immediate numerical solution Hencky solution
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Development of Experimental Device for Compression Load Deflection of Car Door Seals
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作者 赵建才 朱训生 万德安 《Journal of Donghua University(English Edition)》 EI CAS 2003年第2期116-121,共6页
A new experimental device has been developed for analyzing compression load deflection of the door seal by using stereovision theory. Precision instruments of optical grating and force sensor are also integrated in th... A new experimental device has been developed for analyzing compression load deflection of the door seal by using stereovision theory. Precision instruments of optical grating and force sensor are also integrated in this device. Force-displacement response characteristics of compression at varied speed can be controlled. Solid foundations for characteristic and structure as well as optimization design of the car door seal are elucidated. 展开更多
关键词 experimental device compression load deflection SEALS
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LARGE DEFLECTION PROBLEM OF CIRCULAR PLATES WITH VARIABLE THICKNESS UNDER THE ACTION OF COMBINED LOADS
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作者 王新志 徐鉴 王林祥 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1989年第9期817-827,共11页
By using the modified iteration method of large deflection theory of plates with variable thichness[1], we solve the problem of circular plates with variable thickness subjected to combined loads under the boundary co... By using the modified iteration method of large deflection theory of plates with variable thichness[1], we solve the problem of circular plates with variable thickness subjected to combined loads under the boundary conditions of the clamped edges and get comparatively more accurate second-order approximate analytical solution. If the results of this paper are degraded into the special cases, the results coinciding with those of papers [1,2] can be obtained. In this paper, the characteristic curves are plotted and some comparisons are made. The results of this paper are satisfactory. 展开更多
关键词 WANG LARGE deflection PROBLEM OF CIRCULAR PLATES WITH VARIABLE THICKNESS UNDER THE ACTION OF COMBINED loadS
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Variations in organic carbon loading of surface sediments from the shelf to the slope of the Chukchi Sea,Arctic Ocean 被引量:6
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作者 LI Zhongqiao WANG Xinyi +3 位作者 JIN Haiyan JI Zhongqiang BAI Youcheng CHEN Jianfang 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2017年第8期131-136,共6页
The content of organic carbon (OC) normalized to the specific surface area (SSA) of sediment is widely used to trace variations in OC loading (OC/SSA). This study presents observations of OC/SSA of surface sedim... The content of organic carbon (OC) normalized to the specific surface area (SSA) of sediment is widely used to trace variations in OC loading (OC/SSA). This study presents observations of OC/SSA of surface sediments collected in the Chukchi Sea, a typical Arctic marginal sea. Shelf sediments exhibit much higher OC/SSA values than slope sediments in the study area. Compared with OC/SSA values reported from the East Siberian Shelf and Mackenzie River, the slope sediments possess lower OC loading. This abrupt decrease in OC/SSA is mostly related to the lower primary production on slope as well as possible oxidization processes. The results of linear regression analysis between OC and SSA indicate a sedimentary source rock for the OC in the Chukchi Sea sediments. Moreover, shelf sediments with low SSA possess a larger rock OC fraction than slope sediments do. The dataset of the present study enables a more thorough understanding of regional OC cycling in the Chukchi Sea. 展开更多
关键词 Chukchi Sea ARCTIC surface sediments organic carbon loading carbon cycle
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Effect of electrode Pt-loading and cathode flow-field plate type on the degradation of PEMFC 被引量:6
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作者 Lijuan Qu Zhiqiang Wang +5 位作者 Xiaoqian Guo Wei Song Feng Xie Liang He Zhigang Shao Baolian Yi 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第8期95-103,I0005,共10页
The electrode Pt-loading has an effect on the number of active sites and the thickness of catalyst layer,which has huge influence on the mass transfer and water management during dynamic process in PEMFCs. In this stu... The electrode Pt-loading has an effect on the number of active sites and the thickness of catalyst layer,which has huge influence on the mass transfer and water management during dynamic process in PEMFCs. In this study, membrane electrode assemblies with different Pt-loadings were prepared, and PEMFCs were assembled using those membrane electrode assemblies with traditional solid plate and water transport plate as cathode flow-field plates, respectively. The performance and electrochemical surface area of cells were characterized to evaluate the membrane electrode assemblies degradation after rapid currentvariation cycles. Scanning electron microscope and transmission electron microscope were used to investigate the decay of catalyst layers and Pt/C catalyst. With the increase of Pt-loading, the performance degradation of membrane electrode assemblies will be mitigated. But higher Pt-loading means thicker catalyst layer, which leads to a longer pathway of mass transfer, and it may result in carbon material corrosion in membrane electrode assemblies. The decay of Pt/C catalyst in cathode is mainly caused by the corrosion of carbon support, and the degradation of anode Pt/C catalyst is a consequence of migration and aggregation of Pt particles. And using water transport plate is beneficial to alleviating the age of cathode Pt/C catalyst. 展开更多
关键词 PROTON exchange membrane fuel cell ELECTRODE PLATINUM loading Current-variation cycle Traditional solid PLATE Water transport PLATE
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