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Selenide in 3D structure of polyhedra branching out nanotubes for collaborative facilitated conversion and capturing of polysulfide in Li-S batteries
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作者 Yi-Yang Li Hui Liu +3 位作者 Bo Jin Nan Gao Xing-You Lang Qing Jiang 《Rare Metals》 2025年第1期169-184,共16页
Lithium-sulfur batteries(LSBs)are considered as the promising solution to replace conventional lithium-ion batteries due to satisfactory energy density.In recent times,the LSBs field has been found to face some diffic... Lithium-sulfur batteries(LSBs)are considered as the promising solution to replace conventional lithium-ion batteries due to satisfactory energy density.In recent times,the LSBs field has been found to face some difficulties in exploring practical applications in which cycling stability and cycle life are awful owing to the shuttling effect of lithium polysulfides(LiPSs)and low sulfur utilization.In this work,by synthesizing Co_(3)Se_(4) nanoparticles onto N-doped carbon(NC)polyhedra interconnected with carbon nanotubes(CNTs),NC@Co_(3)Se_(4)/CNTs is proposed as a multifunctional sulfur carrier.The Co_(3)Se_(4) nanoparticles fleetly catalyze the conversion of LiPSs and availably immobilize LiPSs.Meanwhile,the NC polyhedral skeleton enhances the electronic conductivity of active sulfur,while the CNTs facilitate Li+diffusion and supply a mass of conductive channels.Density-functional theory(DFT)calculations demonstrate the relevant mechanisms.That is to say,the NC@Co_(3)Se_(4)/CNTs benefit from the synergistic effect of Co_(3)Se_(4) nanoparticles(highly catalytic ability and strong adsorbability for LiPSs)and the special carbonaceous structure,rapidly converting LiPSs and inhibiting the shuttle of LiPSs.Therefore,lithium-sulfur battery assembled with S/NC@Co_(3)Se_(4)/CNTs cathode as well as nitrogen and sulfur co-doped carbon-coated polypropylene(N,S-C/PP)separator possesses a high initial discharge capacity of 1413 mAh·g-1 at 0.12C and persistently circulates for 1000 cycles at 1C with a capacity attenuation rate per cycle of 0.034%.This work provides a realistic idea for the use of transition metal selenide in the field of high-performance LSBs. 展开更多
关键词 SELENIDE Shutting effect Conversion and capturing Long-term cycling stability Density-functional theory calculation
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Dynamics and experiments of a tendon-actuated flexible robotic arm for capturing a floating target
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作者 Xin Xia Yunpeng Sun Jialiang Sun 《Defence Technology(防务技术)》 2025年第5期216-241,共26页
Reusable and flexible capturing of space debris is highly required in future aerospace technologies.A tendon-actuated flexible robotic arm is therefore proposed for capturing floating targets in this paper.Firstly,an ... Reusable and flexible capturing of space debris is highly required in future aerospace technologies.A tendon-actuated flexible robotic arm is therefore proposed for capturing floating targets in this paper.Firstly,an accurate dynamic model of the flexible robotic arm is established by using the absolute nodal coordinate formulation(ANCF)in the framework of the arbitrary Lagrangian-Eulerian(ALE)description and the natural coordinate formulation(NCF).The contact and self-contact dynamics of the flexible robotic arm when bending and grasping an object are considered via a fast contact detection approach.Then,the dynamic simulations of the flexible robotic arm for capturing floating targets are carried out to study the influence of the position,size,and mass of the target object on the grasping performance.Finally,a principle prototype of the tendon-actuated flexible robotic arm is manufactured to validate the dynamic model.The corresponding grasping experiments for objects of various shapes are also conducted to illustrate the excellent performance of the flexible robotic arm. 展开更多
关键词 Tendon-actuated flexible robotic arm Dynamic modeling Contact dynamics ALE-ANCF variable-length cable element capturing experiments
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Grasping Strategy in Space Robot Capturing Floating Target 被引量:4
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作者 魏承 刘天喜 赵阳 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2010年第5期591-598,共8页
When the space robot captures a floating target, contact impact occurs inevitably and frequently between the manipulator hand and the target, which seriously impacts the position and attitude of the robot and grasping... When the space robot captures a floating target, contact impact occurs inevitably and frequently between the manipulator hand and the target, which seriously impacts the position and attitude of the robot and grasping security. "Dynamic grasping area" is introduced to describe the collision process of manipulator grasping target, and grasping area control equation is established. By analyzing the impact of grasping control parameters, base and target mass on the grasping process and combining the life experience, it is found that if the product of speed control parameter and dB adjustment parameter is close to but smaller than the minimum grasping speed, collision impact in the grasping process could be reduced greatly, and then an ideal grasping strategy is proposed. Simulation results indicate that during the same period, the strategy grasping is superior to the accelerating grasping, in that the amplitude of impact force is reduced to 20%, and the attitude control torque is reduced to 15%, and the impact on the robot is eliminated significantly. The results would have important academic value and engineering significance. 展开更多
关键词 space robot capturing target dynamic grasping area grasping strategy active damping control
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Area-oriented coordinated trajectory planning of dual-arm space robot for capturing a tumbling target 被引量:12
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作者 Wenfu XU Lei YAN +1 位作者 Zhonghua HU Bin LIANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2019年第9期2151-2163,共13页
The growing amount of space debris poses a threat to operational spacecraft and the long-term sustainability of activities in outer space. According to the orbital mechanics, an uncontrolled space object will be tumbl... The growing amount of space debris poses a threat to operational spacecraft and the long-term sustainability of activities in outer space. According to the orbital mechanics, an uncontrolled space object will be tumbling, bringing great challenge to capture and remove it. In this paper, a dual-arm coordinated ‘‘Area-Oriented Capture'(AOC) method is proposed to capture a non-cooperative tumbling target. Firstly, the motion equation of the tumbling target is established, based on which, the dynamic properties are analyzed. Then, the ‘‘Area-Oriented Capture'concept is presented to deal with the problem of large pose(position and attitude) deviation and tumbling motion. An area rather than fixed points/devices is taken as the object to be tracked and captured. As long as the manipulators’ end-effectors move to a specified range of the objective areas(not fixed points on the target, but areas), the target satellite will be hugged by the two arms.At last, the proposed method and the traditional method(i.e. fixed-point oriented capture method)are compared and analyzed through simulation. The results show that the proposed method has larger pose tolerance and takes shorter time for capturing a tumbling target. 展开更多
关键词 Area-oriented capture Dual-arm coordination SPACE DEBRIS removal SPACE robot TUMBLING TARGET capturing
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Impact dynamics analysis of free-floating space manipulator capturing satellite on orbit and robust adaptive compound control algorithm design for suppressing motion 被引量:9
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作者 董楸煌 陈力 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2014年第4期413-422,共10页
The impact dynamics, impact effect, and post-impact unstable motion sup- pression of free-floating space manipulator capturing a satellite on orbit are analyzed. Firstly, the dynamics equation of free-floating space m... The impact dynamics, impact effect, and post-impact unstable motion sup- pression of free-floating space manipulator capturing a satellite on orbit are analyzed. Firstly, the dynamics equation of free-floating space manipulator is derived using the sec- ond Lagrangian equation. Combining the momentum conservation principle, the impact dynamics and effect between the space manipulator end-effector and satellite of the cap- ture process are analyzed with the momentum impulse method. Focusing on the unstable motion of space manipulator due to the above impact effect, a robust adaptive compound control algorithm is designed to suppress the above unstable motion. There is no need to control the free-floating base position to save the jet fuel. Finally, the simulation is proposed to show the impact effect and verify the validity of the control algorithm. 展开更多
关键词 free-floating space manipulator satellite capturing impact dynamics robust adaptive compound control
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Detumbling strategy based on friction control of dual-arm space robot for capturing tumbling target 被引量:13
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作者 Gang CHEN Yuqi WANG +3 位作者 Yifan WANG Ji LIANG Long ZHANG Guangtang PAN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2020年第3期1093-1106,共14页
The rotational motion of a tumbling target brings great challenges to space robot on successfully capturing the tumbling target.Therefore,it is necessary to reduce the target's rotation to a rate at which capture ... The rotational motion of a tumbling target brings great challenges to space robot on successfully capturing the tumbling target.Therefore,it is necessary to reduce the target's rotation to a rate at which capture can be accomplished by the space robot.In this paper,a detumbling strategy based on friction control of dual-arm space robot for capturing tumbling target is proposed.This strategy can reduce the target's rotational velocity while maintaining base attitude stability through the establishment of the rotation attenuation controller and base attitude adjustment controller.The rotation attenuation controller adopts the multi-space hybrid impedance control method to control the friction precisely.The base attitude adjustment controller applies the dual-arm extended Jacobian matrix to stabilize the base attitude.The main contributions of this paper are as follows:(1)The compliant control method is adopted to achieve a precise friction control,which can reduce the target angular velocity steadily;(2)The dual-arm extended Jacobian matrix is applied to stabilize the base attitude without affecting the target capture task;(3)The detumbling strategy of dualarm space robot is designed considering base attitude stabilization,realizing coordinated planning of the base attitude and the arms.The strategy is verified by a dual-arm space robot with two 7-DOF(degrees of freedom)arms.Simulation results show that,target with a rotation velocity of 20(°)/s can be effectively controlled to stop within 30 s,and the final deflection of the base attitude is less than 0.15°without affecting the target capture task,verifying the correctness and effectiveness of the strategy.Except to the tumbling target capture task,the control strategy can also be applied to other typical on-orbit operation tasks such as space debris removal and spacecraft maintenance. 展开更多
关键词 Detumbling strategy Dual-arm space robot Free-floating base Friction control Tumbling target capturing
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Experimental Research on A New Type of Floating Breakwater for Wave-Absorbing and Energy-Capturing 被引量:4
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作者 HUANG Fang-ping GONG Kai +2 位作者 LIU Zuo-shi CHEN Jun-hua HUANG Yan-chen 《China Ocean Engineering》 SCIE EI CSCD 2020年第6期817-827,共11页
To avoid the damage caused by big wind and wave in cage culture, and to solve the problem of energy supply faced by automatic breeding equipment, a new type of floating breakwater, named as Savonius double buoy breakw... To avoid the damage caused by big wind and wave in cage culture, and to solve the problem of energy supply faced by automatic breeding equipment, a new type of floating breakwater, named as Savonius double buoy breakwater(SDBB), is proposed in the paper. The floating breakwater is composed of HDPE cylindrical double buoys and horizontal axis Savonius rotors, and has the functions of wave-absorbing and energy-capturing. Based on the linear wave theory and energy conservation law, the Fourier Transform was applied to separate the two-dimensional wave frequency domain, and the energy captured by the rotors and absorbed by the floating breakwater were calculated.Experiments were conducted in a two-dimensional wave-making flume, and the transmitted waves at different wave heights and periods, the tension of mooring lines, and the rotational torque exerted on the Savonius rotor were measured. A series of performance comparison tests were also performed on the new floating breakwater and the traditional double-floating breakwater. Results show that the new floating breakwater is better than the traditional one in terms of reducing wave transmittance, and the combination of the floating breakwater with Savonius rotors can provide for marine aquaculture equipments with green power supply to a certain degree of self-sufficiency. 展开更多
关键词 floating breakwater Savonius rotor transmission coefficient wave energy capturing mooring force
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Marker-Based and Marker-Less Motion Capturing Video Data: Person and Activity Identification Comparison Based on Machine Learning Approaches 被引量:1
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作者 Syeda Binish Zahra Muhammad Adnan Khan +3 位作者 Sagheer Abbas Khalid Masood Khan Mohammed A.Al-Ghamdi Sultan H.Almotiri 《Computers, Materials & Continua》 SCIE EI 2021年第2期1269-1282,共14页
Biomechanics is the study of physiological properties of data and the measurement of human behavior.In normal conditions,behavioural properties in stable form are created using various inputs of subconscious/conscious... Biomechanics is the study of physiological properties of data and the measurement of human behavior.In normal conditions,behavioural properties in stable form are created using various inputs of subconscious/conscious human activities such as speech style,body movements in walking patterns,writing style and voice tunes.One cannot perform any change in these inputs that make results reliable and increase the accuracy.The aim of our study is to perform a comparative analysis between the marker-based motion capturing system(MBMCS)and the marker-less motion capturing system(MLMCS)using the lower body joint angles of human gait patterns.In both the MLMCS and MBMCS,we collected trajectories of all the participants and performed joint angle computation to identify a person and recognize an activity(walk and running).Using five state of the art machine learning algorithms,we obtained 44.6%and 64.3%accuracy in person identification using MBMCS and MLMCS respectively with an ensemble algorithm(two angles as features).In the second set of experiments,we used six machine learning algorithms to obtain 65.9%accuracy with the k-nearest neighbor(KNN)algorithm(two angles as features)and 74.6%accuracy with an ensemble algorithm.Also,by increasing features(6 angles),we obtained higher accuracy of 99.3%in MBMCS for person recognition and 98.1%accuracy in MBMCS for activity recognition using the KNN algorithm.MBMCS is computationally expensive and if we redesign the model of OpenPose with more body joint points and employ more features,MLMCS(low-cost system)can be an effective approach for video data analysis in a person identification and activity recognition process. 展开更多
关键词 Marker-based motion capturing system marker-less motion capturing system support vector machine K-nearest neighbor
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Hydrodynamic Study on Energy Capturing Performance of Horizontal Axis Blades Under Sub-Low Speed Tidal Current 被引量:2
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作者 GAO Ru-jun CHEN Jun-hua +4 位作者 ZHANG Jun-jie ZHOU Si-yu XU Hua-fei WU Jun-de QIAN Xiao-hua 《China Ocean Engineering》 SCIE EI CSCD 2020年第3期374-386,共13页
The research on the hydrodynamics of blades is mainly focused on sea areas with high-speed current.However,the average velocity in most territorial waters of China is smaller than 1 m/s,and the lift type of airfoil bl... The research on the hydrodynamics of blades is mainly focused on sea areas with high-speed current.However,the average velocity in most territorial waters of China is smaller than 1 m/s,and the lift type of airfoil blades has limited application in most of these conditions.Therefore,it is of great significance to study the tidal current energy capture of blades in sub-low speed sea areas.The effect of flow impact resistance on the blade at sub-low current speed is considered and a new type of thin-walled blade based on the lift type of blade is proposed,and then the lift-impact combined hydrodynamic model of horizontal axis blade is established.Based on this model,and considering the characteristics of tidal current and velocity in the sea area of Yushan Islands,simulation and optimization of blade design are carried out.Additionally,the horizontal axis thin-walled blade and the NACA airfoil contrast blade under the same conditions are developed.By using a synthetical experimental test system,the power,torque,rotational speed and load characteristics of these two blades are tested.The performance of the thin-walled blade and the design theory are verified.It shows that this type of blade has much better energy capture efficiency in the sub-low speed sea area.This research will promote the study and development of turbines that can be used in low-speed current sea areas in the future. 展开更多
关键词 sub-low speed horizontal axis thin-walled blade hydrodynamic model energy capture performance
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Design and experiment of high-productivity two-stage vacuum pressure swing adsorption process for carbon capturing from dry flue gas 被引量:4
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作者 Xiuxin Yu Bing Liu +1 位作者 Yuanhui Shen Donghui Zhang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第3期378-391,共14页
A two-stage vacuum pressure swing adsorption(VPSA)process that coupled kinetically controlled and equilibrium controlled separation process with reflux has been investigated for capturing carbon dioxide from dry flue ... A two-stage vacuum pressure swing adsorption(VPSA)process that coupled kinetically controlled and equilibrium controlled separation process with reflux has been investigated for capturing carbon dioxide from dry flue gas(85%N_(2)/15%CO_(2)).In the first enriching stage,carbon molecular sieve(CMS),which shows kinetic selectivity for CO_(2)/N_(2),is adopted as the adsorbent to remove most N_(2)in feed gas,thereby upgrading CO_(2)and significantly reducing the amount for further refinement.The second stage loads zeolite 13X as adsorbent to purify the CO_(2)-rich flow from the first stage for meeting the requirements of National Energy Technology Laboratory.Series of experiments have been conducted for adsorption isotherms measuring and lab-scale experimental validation as well as analysis.The effect of feed composition on the separation performance of the PSA system was studied experimentally and theoretically here.The optimal results achieved 95.1%purity and 92.9%recovery with a high CO_(2)productivity(1.89 mol CO_(2)·h^(-1)·kg^(-1))and an appropriate energy consumption of 1.07 MJ·(kg CO_(2))^(-1).Further analysis has been carried out by simulation for explicating the temperature,pressure,and concentration distribution at cyclic steady state. 展开更多
关键词 Two-stage VPSA process Binary mixture CO_(2)capture Zeolite 13X Carbon molecular sieve
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Slag design and optimization for iron capturing platinum group metals from alumina-based spent catalysts 被引量:2
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作者 Xue-Feng He Xi-Ping Yin +6 位作者 Yun-Ji Ding Zhi-Sheng Shi Bao-Huai Zhao Huan-Dong Zheng Jin-Xin Jian Shen-Gen Zhang Chein-Chi Chang 《Rare Metals》 SCIE EI CAS CSCD 2023年第6期2093-2103,共11页
Production of petrochemical catalysts accounts for one of the largest shares of platinum group metals(PGMs) consumption;thus,recycling of spent petrochemical catalysts holds great economic value.Conventionally,PGMs ar... Production of petrochemical catalysts accounts for one of the largest shares of platinum group metals(PGMs) consumption;thus,recycling of spent petrochemical catalysts holds great economic value.Conventionally,PGMs are recovered through hydrometallurgical processes which have a low recovery efficiency and produce a large amount of waste.In this regard,this paper proposed a method to use iron-capturing PGMs based on CaO-Al_(2)O_(3)-Na_(2)O slag.This method avoided the formation of Fe-Si alloy and achieved efficient enrichment of PGMs.The droplet force model showed that the recovery efficiency of PGMs could be improved if the slag had low density and low viscosity.Based on this result,FactSage software optimized the composition of slag.Furthermore,the effect of B_(2)O_(3) on the 1400 ℃ liquidus of CaO-Al_(2)O_(3)-Na_(2)O_(3)-B_(2)O_(3) phase diagram was revealed.Moreover,it was found that the recovery efficiency of PGMs exceeded 99% under the following optimized conditions:basicity of 1.0,20 wt%Na_(2)O,15 wt% B_(2)O_(3),15 wt% Fe,3 wt% C and a temperature range of 1400-1500℃.The thermodynamic model revealed the mechanism of iron capture.Different chemical bonds prevented the formation of bonds between the alloy and slag,resulting in the separation of the slag from the alloy.PGMs particles and iron microspheres had significant surface Gibbs free energy.Only when iron microspheres and PGMs particles collided and fused with each other to reduce their surface area could the Gibbs free energy of the system be reduced. 展开更多
关键词 Slag type design Spent catalyst ALUMINA Platinum group metals(PGMs) Iron capture
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Multifunctional interlayer with simultaneously capturing and catalytically converting polysulfides for boosting safety and performance of lithium-sulfur batteries at high-low temperatures 被引量:2
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作者 Xiao-Shuan Chen You Gao +5 位作者 Guo-Rui Zhu Hui-Jun Chen Si-Chong Chen Xiu-Li Wang Gang Wu Yu-Zhong Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2020年第11期248-259,共12页
Lithium-sulfur(Li-S) batteries as extremely promising high-density energy storage devices have attracted extensive concern. However, practical applications of Li-S batteries are severely restricted by not only intrins... Lithium-sulfur(Li-S) batteries as extremely promising high-density energy storage devices have attracted extensive concern. However, practical applications of Li-S batteries are severely restricted by not only intrinsic polysulfides shuttle resulting from their concentration gradient diffusion and sluggish conversion kinetics but also serious safety issue caused by thermolabile and combustible polymer separators.Herein, it is presented for the first time that a robust and multifunctional separator with urchin-like Co-doped Fe OOH microspheres and multiwalled carbon nanotubes(MWCNTs) as an interlayer simultaneously achieves to suppress polysulfides shuttle as well as improves thermotolerance and nonflammability of commercial PP separator. Accordingly, Li-S batteries with modified separator exhibit remarkable performance in a wide range temperatures of-25–100 ℃. Typically, under 25 ℃, ultrahigh initial capacities of 1441 and 827.29 m A h g-1 at 1 C and 2 C are delivered, and remained capacities of 936 and 663.18 mA h g-1 can be obtained after 500 cycles, respectively. At 0.1 C, the S utilization can reach up to 97%. Significantly, at 1 C, the batteries also deliver an excellent performance with remained capacities of high to862.3, 608.4 and 420.6 m A h g-1 after 100, 300 and 450 cycles under 75, 0 and-25 ℃, respectively. This work provides a new insight for developing stable and safe high-performance Li-S batteries. 展开更多
关键词 Lithium-sulfur batteries High-low temperature performances Hierarchically urchin-like microspheres Multifunctional interlayer capturing and converting polysulfides
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New process development and process evaluation for capturing CO2 in flue gas from power plants using ionic liquid[emim][Tf2N] 被引量:2
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作者 Lan Li Xiaoting Huang +3 位作者 Quanda Jiang Luyue Xia Jiawei Wang Ning Ai 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第3期721-732,共12页
Using the ionic liquid[emim][Tf2N]as a physical solvent,it was found by Aspen Plus simulation that it was possible to attempt to capture CO2 from the flue gas discharged from the coal-fired unit of the power plant.Usi... Using the ionic liquid[emim][Tf2N]as a physical solvent,it was found by Aspen Plus simulation that it was possible to attempt to capture CO2 from the flue gas discharged from the coal-fired unit of the power plant.Using the combination of model calculation and experimental determination,the density,isostatic heat capacity,viscosity,vapor pressure,thermal conductivity,surface tension and solubility of[emim][Tf2N]were obtained.Based on the NRTL model,the Henry coefficient and NRTL binary interaction parameters of CO2 dissolved in[emim][Tf2N]were obtained by correlating[emim][Tf2N]with the gas–liquid equilibrium data of CO2.Firstly,the calculated relevant data is imported into Aspen Plus,and the whole process model of the ionic liquid absorption process is established.Then the absorption process is optimized according to the temperature distribution in the absorption tower to obtain a new absorption process.Finally,the density,constant pressure heat capacity,surface tension,thermal conductivity,and viscosity of[emim][Tf2N]were changed to investigate the effect of ionic liquid properties on process energy consumption,solvent circulation and heat exchanger design.The results showed that based on the composition of the inlet gas stream to the absorbers,CO2 with a capture rate of 90%and a mass purity higher than 99.5%was captured.These results indicate that the[emim][Tf2N]could be used as a physical solvent for CO2 capture from coal-fired units.In addition,the results will provide a theoretical basis for the design of new ionic liquids for CO2 capture. 展开更多
关键词 Ionic liquids CO2 capture Aspen Plus process simulation New green physical solvents Flue gas
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A Sub-element Adaptive Shock Capturing Approach for Discontinuous Galerkin Methods 被引量:2
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作者 Johannes Markert Gregor Gassner Stefanie Walch 《Communications on Applied Mathematics and Computation》 2023年第2期679-721,共43页
In this paper,a new strategy for a sub-element-based shock capturing for discontinuous Galerkin(DG)approximations is presented.The idea is to interpret a DG element as a col-lection of data and construct a hierarchy o... In this paper,a new strategy for a sub-element-based shock capturing for discontinuous Galerkin(DG)approximations is presented.The idea is to interpret a DG element as a col-lection of data and construct a hierarchy of low-to-high-order discretizations on this set of data,including a first-order finite volume scheme up to the full-order DG scheme.The dif-ferent DG discretizations are then blended according to sub-element troubled cell indicators,resulting in a final discretization that adaptively blends from low to high order within a single DG element.The goal is to retain as much high-order accuracy as possible,even in simula-tions with very strong shocks,as,e.g.,presented in the Sedov test.The framework retains the locality of the standard DG scheme and is hence well suited for a combination with adaptive mesh refinement and parallel computing.The numerical tests demonstrate the sub-element adaptive behavior of the new shock capturing approach and its high accuracy. 展开更多
关键词 High-order methods Discontinuous Galerkin spectral element method Finite volume method Shock capturing ASTROPHYSICS Stellar physics
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Recycling rare earth from ultrafine NdFeB waste by capturing fluorine ions in wastewater and preparing them into nano-scale neodynium oxyfluoride 被引量:1
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作者 He Sun Tuoyao Wang +1 位作者 Chengxiang Li Yusheng Yang 《Journal of Rare Earths》 SCIE EI CAS CSCD 2022年第5期815-821,I0005,共8页
Ultrafine NdFeB waste is a relatively clean waste produced during NdFeB magnet processing.Fluorinecontaining wastewater is a common type of industrial wastewater,such as stainless steel pickling wastewater.In this wor... Ultrafine NdFeB waste is a relatively clean waste produced during NdFeB magnet processing.Fluorinecontaining wastewater is a common type of industrial wastewater,such as stainless steel pickling wastewater.In this work,rare earth element neodynium was recycled from ultrafine NdFeB waste by capturing fluorine ions in the fluorine-containing wastewater and prepared into neodynium oxyfluoride.The reaction process was investigated through UV-Vis-NIR,thermogravimetry/differential thermogravimetry(TG/DTG),X-ray diffraction(XRD)and X-ray photoelectron spectroscopy(XPS).The neodymium hydroxide in the ultrafine NdFeB waste reacted with fluorine ions to form Nd(OH)_(2) F,and Nd(OH)_(2) F was then transformed into neodymium oxyfluoride after decomposition.The formed neodymium oxyfluoride is found to be particles with rhombohedral structure and a particle size of around 50 nm.The reaction kinetics of forming Nd(OH)_(2) F was investigated.The reaction kinetic equation was established and the reaction activation energy was calculated.The effect of fluorine ion concentration on the reaction rate and products was evaluated.The results show that the reaction rate increases with the increase of fluorine ion concentration in the range of 0.01-1.5 mol/L,but it has little effect.In addition,the fluorine ion concentration affects the crystallinity of formed neodymium oxyfluoride.The recycling process not only realizes the sustainable utilization of rare earths,but also reduces the concentration of fluorine ions in the fluorine-containing wastewater,achieving two goals with one stone. 展开更多
关键词 RECYCLING Ultrafine NdFeB waste capturing fluorine ions Neodymium oxyfluoride Rare earths
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Capturing and storage of CO_2 by micron-nano minerals:Evidence from the nature 被引量:4
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作者 MAO Xumei TIAN Xike YU Chengyong 《Chinese Journal Of Geochemistry》 EI CAS 2011年第4期569-575,共7页
The increase of CO2 in atmosphere is a main factor leading to "greenhouse effect", which causes more and more serious global environmental problems. The reduction of CO2 is a challenge for the survival of hu... The increase of CO2 in atmosphere is a main factor leading to "greenhouse effect", which causes more and more serious global environmental problems. The reduction of CO2 is a challenge for the survival of human beings, and it is also a big technical problem. CO2 fluid-rock interaction is a key scientific problem involved in geo-logical storage. The CO2 fluid-rock interaction has a variety of multi-scale changes. Due to great differences in the quantity of surface atoms and surface energy between micron-nano-sized minerals, and ions and crystals, the speed and efficiency of CO2 fluid-rock interaction on a micron-nano scale are much higher than those on other scales. As is known from the natural world, the micron-nano structures of pores and the surface chemical modification of natural porous minerals (zeolite, diatomite, sepiolite, palygorskite, halloysite, etc.) should be further investigated, which can be used as the micron-nano -mineral porous materials with high capacity and high efficiency for capturing CO2. Through simulating the adsorption capacity and process of CO2 by minerals in the natural world, the micron-nano technology is applied to calcium- and magnesium-based minerals (olivine, pyroxene, feldspar, clay, etc.) so as to improve the activity of calcium and magnesium and enlarge the reaction contact area. In this way, the efficiency of capturing and storage of CO2 by calcium- and magnesium-based minerals can be greatly improved. These minerals can also be used as the micron-nano-mineral materials with large capacity and high efficiency for capturing and storing CO2. 展开更多
关键词 二氧化碳排放量 纳米尺度 矿物质 微米 储存 捕获 纳米矿物材料 证据
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The Fuzzy Neural Network Control Scheme With H∞ Tracking Characteristic of Space Robot System With Dual-arm After Capturing a Spin Spacecraft 被引量:1
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作者 Jing Cheng Li Chen 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2020年第5期1417-1424,共8页
In this paper,the dynamic evolution for a dualarm space robot capturing a spacecraft is studied,the impact effect and the coordinated stabilization control problem for postimpact closed chain system are discussed.At f... In this paper,the dynamic evolution for a dualarm space robot capturing a spacecraft is studied,the impact effect and the coordinated stabilization control problem for postimpact closed chain system are discussed.At first,the pre-impact dynamic equations of open chain dual-arm space robot are established by Lagrangian approach,and the dynamic equations of a spacecraft are obtained by Newton-Euler method.Based on the results,with the process of integral and simplify,the response of the dual-arm space robot impacted by the spacecraft is analyzed by momentum conservation law and force transfer law.The closed chain system is formed in the post-impact phase.Closed chain constraint equations are obtained by the constraints of closed-loop geometry and kinematics.With the closed chain constraint equations,the composite system dynamic equations are derived.Secondly,the recurrent fuzzy neural network control scheme is designed for calm motion of unstable closed chain system with uncertain system parameter.In order to overcome the effects of uncertain system inertial parameters,the recurrent fuzzy neural network is used to approximate the unknown part,the control method with H∞tracking characteristic.According to the Lyapunov theory,the global stability is demonstrated.Meanwhile,the weighted minimum-norm theory is introduced to distribute torques guarantee that cooperative operation between manipulators.At last,numerical examples simulate the response of the collision,and the efficiency of the control scheme is verified by the simulation results. 展开更多
关键词 capturing operation calm motion control closed chain system dual-arm space robot recurrent fuzzy neural network H∞tracking characteristic
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Interaction of weak free-stream disturbance with an oblique shock: validation of the shock-capturing method 被引量:3
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作者 Caihong SU Jinlei GENG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2017年第11期1601-1612,共12页
Transition prediction is of great importance for the design of long distance flying vehicles. It starts from the problem of receptivity, i.e., how external disturbances trigger instability waves in the boundary layer.... Transition prediction is of great importance for the design of long distance flying vehicles. It starts from the problem of receptivity, i.e., how external disturbances trigger instability waves in the boundary layer. For super/hypersonic boundary layers, the external disturbances first interact with the shock ahead of the flying vehicles before entering the boundary layer. Since direct numerical simulation (DNS) is the only available tool for its comprehensive and detailed investigation, an important problem arises whether the numerical scheme, especially the shock-capturing method, can faithfully reproduce the interaction of the external disturbances with the shock, which is so far unknown. This paper is aimed to provide the answer. The interaction of weak disturbances with an oblique shock is investigated, which has a known theoretical solution. Numerical simulation using the shock-capturing method is conducted, and results are compared with those given by theoretical analysis, which shows that the adopted numerical method can faithfully reproduce the interaction of weak external disturbances with the shock. 展开更多
关键词 shock high speed flow free-stream disturbance SHOCK-capturing
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Gradient-augmented hybrid interface capturing method for incompressible two-phase flow
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作者 付峥 吴士玉 刘凯欣 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第6期283-289,共7页
Motivated by inconveniences of present hybrid methods,a gradient-augmented hybrid interface capturing method(GAHM) is presented for incompressible two-phase flow.A front tracking method(FTM) is used as the skeleto... Motivated by inconveniences of present hybrid methods,a gradient-augmented hybrid interface capturing method(GAHM) is presented for incompressible two-phase flow.A front tracking method(FTM) is used as the skeleton of the GAHM for low mass loss and resources.Smooth eulerian level set values are calculated from the FTM interface,and are used for a local interface reconstruction.The reconstruction avoids marker particle redistribution and enables an automatic treatment of interfacial topology change.The cubic Hermit interpolation is employed in all steps of the GAHM to capture subgrid structures within a single spacial cell.The performance of the GAHM is carefully evaluated in a benchmark test.Results show significant improvements of mass loss,clear subgrid structures,highly accurate derivatives(normals and curvatures) and low cost.The GAHM is further coupled with an incompressible multiphase flow solver,Super CE/SE,for more complex and practical applications.The updated solver is evaluated through comparison with an early droplet research. 展开更多
关键词 interface capturing hybrid method mass loss incompressible two-phase flow
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DISCONTINUITY-CAPTURING FINITE ELEMENT COMPUTATION OF UNSTEADY FLOW WITH ADAPTIVE UNSTRUCTURED MESH
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作者 董根金 陆夕云 庄礼贤 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2004年第4期347-353,共7页
A discontinuity-capturing scheme of finite element method(FEM)is proposed.The unstructured-grid technique combined with a new type of adaptive mesh approach is developed for both compressible and incompressible unstea... A discontinuity-capturing scheme of finite element method(FEM)is proposed.The unstructured-grid technique combined with a new type of adaptive mesh approach is developed for both compressible and incompressible unsteady flows,which exhibits the capability of capturing the shock waves and/or thin shear layers accurately in an unsteady viscous flow at high Reynolds number. In particular,a new testing variable,i.e.,the disturbed kinetic energy E,is suggested and used in the adaptive mesh computation,which is universally applicable to the capturing of both shock waves and shear layers in the inviscid flow and viscous flow at high Reynolds number.Based on several calculated examples,this approach has been proved to be effective and efficient for the calculations of compressible and incompressible flows. 展开更多
关键词 finite element method unstructured and adaptive mesh discontinuity capture unsteady viscous flow
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