To surmount the obstacles of traditional Fenton method and synchronously utilize Cu^(2+)and polyphenol in water,an improved Fenton-like reaction applying calcium peroxide(CaO_(2))as H_(2)O_(2)source and regulating by ...To surmount the obstacles of traditional Fenton method and synchronously utilize Cu^(2+)and polyphenol in water,an improved Fenton-like reaction applying calcium peroxide(CaO_(2))as H_(2)O_(2)source and regulating by the complex of Cu^(2+)-tartaric acid(TA,a representative of polyphenol)was constructed.A typical antibiotic,metronidazole(MTZ)could be effectively eliminated by the Cu^(2+)/TA/CaO_(2)system,and the optimized parameters were as follows:0.1 mmol/L Cu^(2+),2 mmol/L TA,2 mmol/L CaO_(2),and initial pH5.UV spectrum confirmed the formation of Cu^(2+)-TA complex,which promoted the Cu^(2+)/Cu+circulation through decreasing the Cu^(2+)/Cu^(+) couple redox potential,which further enhanced the H_(2)O_(2)decomposition and the formation of reactive species.Hydroxyl radical was dominant for MTZ degradation,followed by oxygen and superoxide radical.The degradation intermediates of MTZ were detected and their evolution way was speculated.Furthermore,the ternary process showed a wide p H tolerance(3–8)for removing MTZ and broad applicability for eliminating other dyes and antibiotics.This work provided a reference for Cu-based Fenton-like strategy for organic wastewater settlement.展开更多
A wet catalytic oxidation at room temperature was investigated with solution containing ferric, ferrous and cupric ions for H2S removal. The experiments were carried out in a two step process, and the results obtained...A wet catalytic oxidation at room temperature was investigated with solution containing ferric, ferrous and cupric ions for H2S removal. The experiments were carried out in a two step process, and the results obtained show that the removal efficiency of H2S can always reach 100% in a 300 mm scrubbing column with four sieve plates, and the regeneration of ferric ions in 200 mm bubble column can match the consumed ferric species in absorption. Removal of H2S, production of elemental sulfur and regeneration of ferric, cupric ions can all be accomplished at the same time. No raw material is consumed except O2 in flue gas or air, the process has no secondary pollution and no problem of catalyst degradation and congestion.展开更多
A utility equipment used in soil science is designed and installed.The equipment can be used in research pro- grams of soil water and solute transport.Pressure in pressure chamber of the equipment in which a tested so...A utility equipment used in soil science is designed and installed.The equipment can be used in research pro- grams of soil water and solute transport.Pressure in pressure chamber of the equipment in which a tested soil sam- ple is laid can be adjusted exactly so that we can determine the water content of soil sample.With the equipment we can not only study the problems related water movement in soil but also measure some solute,such as cadmi- um,plumbum and so on,adsorption on surface of soil in saturated and unsaturated state.As an illustration of the use of the equipment,we give the isothermal of cupric ion adsorption in soil.This equipment can be used in the re- search work and application of soil science.展开更多
Dielectric spectroscopy(DS)was utilized to investigate the toxicity of the Cu2+solution to Microcystis aeruginosa.It was found that 0.04 mM Cu2+had no effect on dielectric increment,whereas the Cu2+concentrations abov...Dielectric spectroscopy(DS)was utilized to investigate the toxicity of the Cu2+solution to Microcystis aeruginosa.It was found that 0.04 mM Cu2+had no effect on dielectric increment,whereas the Cu2+concentrations above 0.1 mM decreased the value ofΔε/Δεintact.The toxic effect of Cu2+on M.aeruginosa cells was time-dependent and concentration-dependent.There was a threshold concentration between 0.04 mM and 0.1 mM,which affected the cell membrane,suggesting that Cu2+at the concentrations higher than 0.1 mM caused serious plasmalemma damage to M.aeruginosa cells.The addition of 1 mM Ca2+or Mg2+did not protect M.aeruginosa cells from 1 mM Cu2+toxicity.The study demonstrates that DS monitors cell biomass facilitating observation of the toxic effects of metal ions.展开更多
基金the supports from the National Natural Science Foundation of China(No.51908485)the Central Guidance on Local Science and Technology Development Fund of Hebei Province(No.226Z3603G)Hebei Province Foundation for Returnees(No.C20210502)。
文摘To surmount the obstacles of traditional Fenton method and synchronously utilize Cu^(2+)and polyphenol in water,an improved Fenton-like reaction applying calcium peroxide(CaO_(2))as H_(2)O_(2)source and regulating by the complex of Cu^(2+)-tartaric acid(TA,a representative of polyphenol)was constructed.A typical antibiotic,metronidazole(MTZ)could be effectively eliminated by the Cu^(2+)/TA/CaO_(2)system,and the optimized parameters were as follows:0.1 mmol/L Cu^(2+),2 mmol/L TA,2 mmol/L CaO_(2),and initial pH5.UV spectrum confirmed the formation of Cu^(2+)-TA complex,which promoted the Cu^(2+)/Cu+circulation through decreasing the Cu^(2+)/Cu^(+) couple redox potential,which further enhanced the H_(2)O_(2)decomposition and the formation of reactive species.Hydroxyl radical was dominant for MTZ degradation,followed by oxygen and superoxide radical.The degradation intermediates of MTZ were detected and their evolution way was speculated.Furthermore,the ternary process showed a wide p H tolerance(3–8)for removing MTZ and broad applicability for eliminating other dyes and antibiotics.This work provided a reference for Cu-based Fenton-like strategy for organic wastewater settlement.
文摘A wet catalytic oxidation at room temperature was investigated with solution containing ferric, ferrous and cupric ions for H2S removal. The experiments were carried out in a two step process, and the results obtained show that the removal efficiency of H2S can always reach 100% in a 300 mm scrubbing column with four sieve plates, and the regeneration of ferric ions in 200 mm bubble column can match the consumed ferric species in absorption. Removal of H2S, production of elemental sulfur and regeneration of ferric, cupric ions can all be accomplished at the same time. No raw material is consumed except O2 in flue gas or air, the process has no secondary pollution and no problem of catalyst degradation and congestion.
文摘A utility equipment used in soil science is designed and installed.The equipment can be used in research pro- grams of soil water and solute transport.Pressure in pressure chamber of the equipment in which a tested soil sam- ple is laid can be adjusted exactly so that we can determine the water content of soil sample.With the equipment we can not only study the problems related water movement in soil but also measure some solute,such as cadmi- um,plumbum and so on,adsorption on surface of soil in saturated and unsaturated state.As an illustration of the use of the equipment,we give the isothermal of cupric ion adsorption in soil.This equipment can be used in the re- search work and application of soil science.
基金support from the National Natural Science Foundation of China(Grant Nos 20673014&20976015)
文摘Dielectric spectroscopy(DS)was utilized to investigate the toxicity of the Cu2+solution to Microcystis aeruginosa.It was found that 0.04 mM Cu2+had no effect on dielectric increment,whereas the Cu2+concentrations above 0.1 mM decreased the value ofΔε/Δεintact.The toxic effect of Cu2+on M.aeruginosa cells was time-dependent and concentration-dependent.There was a threshold concentration between 0.04 mM and 0.1 mM,which affected the cell membrane,suggesting that Cu2+at the concentrations higher than 0.1 mM caused serious plasmalemma damage to M.aeruginosa cells.The addition of 1 mM Ca2+or Mg2+did not protect M.aeruginosa cells from 1 mM Cu2+toxicity.The study demonstrates that DS monitors cell biomass facilitating observation of the toxic effects of metal ions.
