The grain boundary diffusion process(GBDP)has proven to be an effective method for enhancing the coercivity of sintered Nd-Fe-B magnets.However,the limited diffusion depth and thicker shell struc-ture have impeded the...The grain boundary diffusion process(GBDP)has proven to be an effective method for enhancing the coercivity of sintered Nd-Fe-B magnets.However,the limited diffusion depth and thicker shell struc-ture have impeded the further development of magnetic properties.Currently,the primary debates re-garding the mechanism of GBDP with Tb revolve around the dissolution-solidification mechanism and the atomic substitution mechanism.To clarify this mechanism,the microstructure evolution of sintered Nd-Fe-B magnets during the heating process of GBDP has been systematically studied by quenching at different tem peratures.In this study,it was found that the formation of TbFe_(2) phase is related to the dis-solution of _(2)Fe_(14)B grains during GBDP with Tb.The theory of mixing heat and phase separation further confirms that the Nd_(2)Fe_(14)B phase dissolves to form a mixed phase of Nd and TbFe_(2),which then solidifies into the(Nd,Tb)_(2)Fe_(14)B phase.Based on the discovery of the TbFe_(2) phase,the dissolution-solidification mechanism is considered the primary mechanism for GBDP.This is supported by the elemental content of the two typical core-shell structures observed.展开更多
In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Usin...In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Using the coupling method,we obtain the existence of a full absorbing set on which continuous time Markov processes are f-geometric ergodic.展开更多
A sintered Nd-Y-Fe-B magnet was designed and manufactured by the multi-main-phase process.Unevenly distributed Y in the magnet decreases the adverse magnetic weakening effect of Y on the coercivity.Grain boundary diff...A sintered Nd-Y-Fe-B magnet was designed and manufactured by the multi-main-phase process.Unevenly distributed Y in the magnet decreases the adverse magnetic weakening effect of Y on the coercivity.Grain boundary diffusion process(GBDP)was conducted to further enhance the coercivity of the Nd-Y-Fe-B magnet.The coercivity increases significantly from 884 to 1741 kA/m after GBDP with Pr_(60)Tb_(10)Cu_(30)alloy.The mechanism of the coercivity enhancement is discussed based on the microstructure analysis.Micromagnetic simulation reveals that when the diffused Tb-rich shell thickness is lower than 12 nm the c-plane shell(perpendicular to the c-axis)is much more effective in enhancing the coercivity than the side plane shell(parallel to the c-axis).But when the Tb-rich shell thickness is above12 nm the side plane shell contributes more to the coercivity enhancement.The results in this work can help to design and manufacture Nd-Fe-B magnets with low cost and high magnetic properties.展开更多
Considering the dynamic variation of roll gap and the transverse distribution of dynamic rolling force along the work roll width direction, the movement and deformation of rolls system, influenced by the coupling of v...Considering the dynamic variation of roll gap and the transverse distribution of dynamic rolling force along the work roll width direction, the movement and deformation of rolls system, influenced by the coupling of vertical chatter and transverse bending vibration, may cause instability and also bring product defect of thickness difference. Therefore, a rigid-flexible coupling vibration model of the rolls system was presented. The influence of dynamic characteristics on the rolling process stability and strip thickness distribution was investigated. Firstly, assuming the symmetry of upper and lower structures of six-high rolling mill, a transverse bending vibration model of three-beam system under simply supported boundary conditions was established, and a semi-analytical solution method was proposed to deal with this model. Then, considering both variation and change rate of the roll gap, a roll vertical chatter model with structure and process coupled was constructed, and the critical rolling speed for self-excited instability was determined by Routh stability criterion. Furthermore, a rigid-flexible coupling vibration model of the rolls system was built by connecting the vertical chatter model and transverse bending vibration model through the distribution of dynamic rolling force, and the dynamic characteristics of rolls system were analyzed. Finally, the strip exit thickness distributions under the stable and unstable rolling process were compared, and the product shape and thickness distribution characteristics were quantitatively evaluated by the crown and maximum longitudinal thickness difference.展开更多
Gelugpa is the most influential extant religious sect of Tibetan Buddhism,which is the spiritual prop for Tibetans,with thousands of monasteries and followers in Tibetan areas of China.Studies on the spatial diffusion...Gelugpa is the most influential extant religious sect of Tibetan Buddhism,which is the spiritual prop for Tibetans,with thousands of monasteries and followers in Tibetan areas of China.Studies on the spatial diffusion processes of Gelugpa can not only reveal its historical geographical development but also lay the foundation for anticipating its future development trend.However,existing studies on Gelugpa lack geographical perspective,making it difficult to explore the spatial characteristics.Furthermore,the prevailing macro-perspective overlooks spatiotemporal heterogeneity in diffusion processes.Therefore,taking monastery as the carrier,this study establishes a multi-level diffusion model to reconstruct the diffusion networks of Gelugpa monasteries,as well as a framework to explore the detailed features in the spatial diffusion processes of Gelugpa in Tibetan areas of China based on a geodatabase of Gelugpa monastery.The results show that the multi-level diffusion model has a considerable applicability in the reconstruction of the diffusion networks of Gelugpa monasteries.Gelugpa monasteries in the Three Tibetan Inhabited Areas present disparate spatial diffusion processes with diverse diffusion bases,speeds,stages,as well as diffusion regions and centers.A powerful single-center diffusion-centered Gandan Monastery was rapidly formed in U-Tsang.Kham experienced a slower and more varied spatial diffusion process with multiple diffusion systems far apart from each other.The spatial diffusion process of Amdo was the most complex,with the highest diffusion intensity.Amdo possessed the most influential diffusion centers,with different diffusion shapes and diffusion ranges crossing and overlapping with each other.Multiple natural and human factors may contribute to the formation of Gelugpa monasteries.This study contributes to the understanding of the geography of Gelugpa and provides reference to studies on religion diffusion.展开更多
Robot-automated spraying is widely used in various fields,such as the automotive,metalworking,furniture,and aero-space industries.Spraying quality is influenced by multiple factors,including robot speed,acceleration,e...Robot-automated spraying is widely used in various fields,such as the automotive,metalworking,furniture,and aero-space industries.Spraying quality is influenced by multiple factors,including robot speed,acceleration,end-effector trajectory,and spraying process constraints.To achieve high-quality spraying under the influence of multiple factors,this study proposes a multi-objective optimization method for the spraying trajectory that integrates spraying process constraints into the optimization process.First,a 7-degree-of-freedom rigid-flexible coupling serial spray painting robot system is introduced,which includes a motion decoupling mechanism and a tension amplification mechanism.Subsequently,a paint deposition model for the spray gun was established,and the influence of process constraints on spraying quality was analyzed.Trajectory planning for the spray painting robot,based on the septic B-spline interpolation method,was then performed.Based on this foundation,objective functions and constraint equations for spraying trajectory optimization were established.A multi-objective trajectory optimization method for spraying by the robot is proposed based on the NSGA-Ⅱ,which integrates the spraying process constraints.Finally,a prototype system of a 7-degree-of-freedom rigid-flexible coupling serial spray painting robot was constructed.Simulations and spraying experiments were conducted to verify the effectiveness of the proposed multi-objective trajectory optimization method.This paper presents a multi-objective optimization method for the spraying trajectory of a robot.In the proposed method,the optimized spraying trajectory is generated with the spraying process as the constraint and time,energy consumption,and impact during the spraying operation of the robot as the optimization objectives.展开更多
The interdiffusion coefficients in Al_(0.2)CoCrFeNi,CoCrCu_(0.2)FeNi,and CoCrFeMn_(0.2)Ni high-entropy alloys were efficiently determined by combining diffusion couple experiments and high-throughput determination of ...The interdiffusion coefficients in Al_(0.2)CoCrFeNi,CoCrCu_(0.2)FeNi,and CoCrFeMn_(0.2)Ni high-entropy alloys were efficiently determined by combining diffusion couple experiments and high-throughput determination of interdiffusion coefficients(HitDIC)software at 1273−1373 K.The results show that the addition of Al,Cu,and Mn to CoCrFeNi high-entropy alloys promotes the diffusion of Co,Cr,and Fe atoms.The comparison of tracer diffusion coefficients indicates that there is no sluggish diffusion in tracer diffusion on the thermodynamic temperature scale for the present Al_(0.2)CoCrFeNi,CoCrCu_(0.2)FeNi,and CoCrFeMn_(0.2)Ni high-entropy alloys.The linear relationship between diffusion entropy and activation energy reveals that the diffusion process of atoms is unaffected by an increase in the number of components as long as the crystal structure remains unchanged.展开更多
Accurately identifying building distribution from remote sensing images with complex background information is challenging.The emergence of diffusion models has prompted the innovative idea of employing the reverse de...Accurately identifying building distribution from remote sensing images with complex background information is challenging.The emergence of diffusion models has prompted the innovative idea of employing the reverse denoising process to distill building distribution from these complex backgrounds.Building on this concept,we propose a novel framework,building extraction diffusion model(BEDiff),which meticulously refines the extraction of building footprints from remote sensing images in a stepwise fashion.Our approach begins with the design of booster guidance,a mechanism that extracts structural and semantic features from remote sensing images to serve as priors,thereby providing targeted guidance for the diffusion process.Additionally,we introduce a cross-feature fusion module(CFM)that bridges the semantic gap between different types of features,facilitating the integration of the attributes extracted by booster guidance into the diffusion process more effectively.Our proposed BEDiff marks the first application of diffusion models to the task of building extraction.Empirical evidence from extensive experiments on the Beijing building dataset demonstrates the superior performance of BEDiff,affirming its effectiveness and potential for enhancing the accuracy of building extraction in complex urban landscapes.展开更多
Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases a...Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases and the precipitation of secondary phases,driven by changes in the chemical environment,often mediated by hydrothermal fluids.The Bailongshan Li deposit,located in the West Kunlun region of northwest China,is a significant geological formation known for its rich lithium content and associated rare metals such as tantalum,niobium,and tin.This study investigates the coupled dissolution-precipitation processes that have played a crucial role in the mineralization of this deposit,focusing on key minerals,including cassiterite(Cst),columbite-group minerals(CGM),and elbaite(Elb).Using a combination of petrographic analysis,back-scattered electron(BSE)imaging,cathodoluminescence(CL)imaging,and micro X-ray fluorescence(XRF)mapping,we examined the textural and chemical characteristics of these minerals.Our findings reveal intricate patchy zoning patterns and element distributions(indicated by the Nb,Ta,W,Mn,Fe,Hf,Ti for CGM;Hf,Ti Rb,W,Nb,Ta for Cst;Ti,Zn,Fe,W,Hf,Mn,K for Elb)that indicate multiple stages of mineral alteration driven by fluid-mediated processes.The coupled dissolution-precipitation mechanisms observed in the Bailongshan deposit have resulted in significant redistribution and enrichment of economically valuable elements.The study highlights the importance of hydrothermal fluids in altering primary mineral phases and precipitating secondary phases with distinct compositions.These processes not only modified the mineralogical makeup of the pegmatite but also enhanced its economic potential by concentrating rare metals.Signatures of coupled dissolutionprecipitation processes can serve as an essential tool for mineral exploration,guiding the search for high-grade zones within similar pegmatitic formations.展开更多
The massless dark photon~γ can only interact with the Standard Model(SM)sector via higherdimensional operators.In this letter,we investigate its production associated with the ordinary photonγfrom the lepton flavor ...The massless dark photon~γ can only interact with the Standard Model(SM)sector via higherdimensional operators.In this letter,we investigate its production associated with the ordinary photonγfrom the lepton flavor violation(LFV)process l_(i)→l_(j)γγ and di-production from the LFV process l_(i)→l_(j)γγ induced by dipole operators.Comparing the obtained numerical results with the corresponding experimental measurements,we obtain the constraints on the effective couplings of γ with the SM charged leptons.The upper limit of the effective coupling|DLμe|2+|DRμe|2coming from the process μ→e~γγis looser than the processμ→eγ by about one order of magnitude.展开更多
In this work,the effect of the Al addition amount in the TbAl coatings on the grain boundary diffusion proces s(GBDP)of Tb were systematically explored.Direct current magnetron sputtering(DCMS)method was utilized in c...In this work,the effect of the Al addition amount in the TbAl coatings on the grain boundary diffusion proces s(GBDP)of Tb were systematically explored.Direct current magnetron sputtering(DCMS)method was utilized in co-sputtering manner to synthesize the TbAl coatings with certain Tb consumption and various Al addition amount.Results show that the moderate Al addition amount significantly improves the wettability of grain boundary(GB)phases,thereby acquiring more continuous and uniform Tb-rich shells and GB phases between matrix phases,as well as deeper diffusion depth and denser microstructure.The largest increase amplitude of intrinsic coercivity(Hcj)is improved by 78.4%in TbAIdiffused magnet compared to the pure Tb-diffused magnet,while the remanence(Br)is expected to show an overall decreasing tendency accompanied with a slight increase in the decreasing process.However,when the Al addition amount is excessive,magnetic dilution effect is enhanced,and the Tbrich shells and GB phases between matrix phases become fuzzy and even invisible,which in turn deteriorates the magnetic properties of diffused magnets.展开更多
To address the significant degradation of Space-Time Adaptive Processing(STAP)performance when the array elements have mutual coupling and gain/phase errors,a STAP algorithm with adaptive calibration for the above two...To address the significant degradation of Space-Time Adaptive Processing(STAP)performance when the array elements have mutual coupling and gain/phase errors,a STAP algorithm with adaptive calibration for the above two array errors is proposed in this article.First,based on a defined error matrix that simultaneously considers both array mutual coupling and gain/phase errors,a STAP signal model including these errors is given.Then,utilizing the defined signal model,it is demonstrated that the estimation of the defined error matrix can be formulized as a standard convex optimization problem with the low-rank structure of the clutter covariance matrix and the subspace projection theory.Once the defined error matrix is estimated by solving the convex optimization problem,it is illustrated that a STAP method with adaptive calibration of the mutual coupling and gain/phase errors is coined.Analyses also show that the proposed adaptive calibration algorithm only needs one training sample to construct the adaptive weight vector.Therefore,it can achieve a good detection performance even with severe non-homogeneous clutter environments.Finally,the simulation experiments verify the effectiveness of the proposed algorithm and the correctness of the analytical results.展开更多
In the 1940s, KIRKENDALL showed that diffusion in binary solid solutions cannot be described by only one diffusion coefficient. Rather, one has to consider the diffusivity of both species. His findings changed the tre...In the 1940s, KIRKENDALL showed that diffusion in binary solid solutions cannot be described by only one diffusion coefficient. Rather, one has to consider the diffusivity of both species. His findings changed the treatment of diffusion data and the theory of diffusion itself. A diffusion-based framework was successfully employed to explain the behaviour of the Kirkendall plane. Nonetheless, the complexity of a multiphase diffusion zone and the morphological evolution during interdiffusion requires a physico-chemical approach. The interactions in binary and more complex systems are key issues from both the fundamental and technological points of view. This paper reviews the Kirkendall effect from the circumstances of its discovery to recent developments in its understanding, with broad applicability in materials science and engineering.展开更多
In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating ...In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating step is addressed to melt the interlayer, followed by the second step to complete isothermal solidification at a low temperature. The most critical feature of our new method is producing a non-planar interface at the T9/ heat resistant steels joint. We propose a transitional liquid phase bonding of T91 heat resistant steels by this approach. Since joint microstructures have been studied, we tested the tensile strength to assess joint mechanical property. The result indicates that the solidified bond may contain a primary solid-solution, similar composition to the parent metal and free from precipitates. Joint tensile strength of the joint is not lower than parent materials. Joint bend's strengths are enhanced due to the higher metal-to-metal junction producing a non-planar bond lines. Nevertheless, the traditional transient liquid phase diffusion bonding produces planar ones. Bonding parameters of new process are 1 260 °C for 0. 5 min and 1 230 °C fo r 4 min.展开更多
The grain boundary diffusion process(GBDP)of Tb can improve the coercivity of sintered Nd-Fe-B magnets.In this study,the effect of AI on the diffusion of Tb in the GBDP was investigated.The content of diffused Tb-Al w...The grain boundary diffusion process(GBDP)of Tb can improve the coercivity of sintered Nd-Fe-B magnets.In this study,the effect of AI on the diffusion of Tb in the GBDP was investigated.The content of diffused Tb-Al was precisely controlled by adjusting the magnetron sputtering process.The Tb equivalent of Al was also studied.Results show that AI promotes the diffusion of Tb deeper into the magnet,reducing the thickness of the shell in the core-shell structure.This study is helpful for further developing the process,reducing the consumption of heavy rare earth elements(Tb),and improving the coercivity of sintered Nd-Fe-B magnets.展开更多
In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The p...In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.展开更多
Grain boundary diffusion process(GBDP)was first proposed for sintered Nd-Fe-B magnets to achieve the high utilization efficiency of heavy rare earth elements.Recent success of fabricating high performance nanocomposit...Grain boundary diffusion process(GBDP)was first proposed for sintered Nd-Fe-B magnets to achieve the high utilization efficiency of heavy rare earth elements.Recent success of fabricating high performance nanocomposite magnets by GBDP indicates that this method also exerts huge applicable potential on hot-deformed Nd-Fe-B magnets.In this review,the development and magnetic property enhancement mechanisms of different diffusion methods proposed on hot-deformed magnets were thoroughly elucidated.Moreover,the improve room for further property enhancement and the accompanying problems of GBDP on hot-deformed magnets are also discussed in this article.展开更多
A class of multi dimensional degenerate diffusion processes X ε(t) in R r(r≥2) are considered and the asymptotic properties of empirical measures are investigated; here X ε(t) saitisfies the stochastic differen...A class of multi dimensional degenerate diffusion processes X ε(t) in R r(r≥2) are considered and the asymptotic properties of empirical measures are investigated; here X ε(t) saitisfies the stochastic differential equation dX ε(t)=σ(X ε(t)) d W(t)+B(X ε(t)) d t+ εσ～(X ε(t)) d W(t),ε>0. X ε(t) are small random perturbations of the degenerate diffusion process X(t), which satisfies the stochastic differential equation dX(t)=σ(X(t)) d W(t)+B(X(t)) d t. A large deviation theorem for projection measures ν on R r-n (n<r) of empirical measures μ are proved展开更多
Let X（1） = {X（1）（s）, s ∈ R＋} and X（2） = {X（2）（t）, t ∈ R＋} be two inde-pendent nondegenerate diffusion processes with values in Rd. The existence and fractal dimension of intersections of the sample pat...Let X（1） = {X（1）（s）, s ∈ R＋} and X（2） = {X（2）（t）, t ∈ R＋} be two inde-pendent nondegenerate diffusion processes with values in Rd. The existence and fractal dimension of intersections of the sample paths of X （1） and X （2） are studied. More gener-ally, let E1, E2？（0,∞） and F ？Rd be Borel sets. A necessary condition and a suffcient condition for P{X（1）（E1）∩X（2）（E2）∩F 6=？}〉0 are proved in terms of the Bessel-Riesz type capacity and Hausdorff measure of E1 × E2 × F in the metric space （R＋× R＋× Rd,ρb）, whereρb is an unsymmetric metric defined in R＋× R＋× Rd. Under reasonable conditions, results resembling those of Browian motion are obtained.展开更多
The segregation of thermal diffusion salt bath chromizing process was analyzed. The experimental chromizing ingredients were prepared by the four groups A, B, C, and D. In order to study the segregation status of this...The segregation of thermal diffusion salt bath chromizing process was analyzed. The experimental chromizing ingredients were prepared by the four groups A, B, C, and D. In order to study the segregation status of this case, the cooling molten salt in the crucible was removed by drilling from the heart core of molten salt. The core of molten salt was analyzed by X-ray fluorescence spectroscopy and XRD. Through the analysis, we can conclude that the Cr element deposited in the bottom was 4.51 times than the top. Chloride added to the molten salt will reduce segregation. Meantime we proposed some measures to overcome the segregation problem.展开更多
基金supported by the National Key Research and Development Program of China(2022YFB3505503)the National Natural Science Foundation of China(52201230)+2 种基金the Key R&D Program of Shandong Province(2022CXGC020307)the China Postdoctoral Science Foundation(2022M71204)the Beijing NOVA Program(Z211100002121092).
文摘The grain boundary diffusion process(GBDP)has proven to be an effective method for enhancing the coercivity of sintered Nd-Fe-B magnets.However,the limited diffusion depth and thicker shell struc-ture have impeded the further development of magnetic properties.Currently,the primary debates re-garding the mechanism of GBDP with Tb revolve around the dissolution-solidification mechanism and the atomic substitution mechanism.To clarify this mechanism,the microstructure evolution of sintered Nd-Fe-B magnets during the heating process of GBDP has been systematically studied by quenching at different tem peratures.In this study,it was found that the formation of TbFe_(2) phase is related to the dis-solution of _(2)Fe_(14)B grains during GBDP with Tb.The theory of mixing heat and phase separation further confirms that the Nd_(2)Fe_(14)B phase dissolves to form a mixed phase of Nd and TbFe_(2),which then solidifies into the(Nd,Tb)_(2)Fe_(14)B phase.Based on the discovery of the TbFe_(2) phase,the dissolution-solidification mechanism is considered the primary mechanism for GBDP.This is supported by the elemental content of the two typical core-shell structures observed.
基金Supported by the Natural Science Foundation of Hubei Province(2021CFB275)National Natural Science Foundation of China(12301667).
文摘In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Using the coupling method,we obtain the existence of a full absorbing set on which continuous time Markov processes are f-geometric ergodic.
基金Project supported by the National Natural Science Foundation of China(51901087)China Postdoctoral Science Foundation(2021M701504)。
文摘A sintered Nd-Y-Fe-B magnet was designed and manufactured by the multi-main-phase process.Unevenly distributed Y in the magnet decreases the adverse magnetic weakening effect of Y on the coercivity.Grain boundary diffusion process(GBDP)was conducted to further enhance the coercivity of the Nd-Y-Fe-B magnet.The coercivity increases significantly from 884 to 1741 kA/m after GBDP with Pr_(60)Tb_(10)Cu_(30)alloy.The mechanism of the coercivity enhancement is discussed based on the microstructure analysis.Micromagnetic simulation reveals that when the diffused Tb-rich shell thickness is lower than 12 nm the c-plane shell(perpendicular to the c-axis)is much more effective in enhancing the coercivity than the side plane shell(parallel to the c-axis).But when the Tb-rich shell thickness is above12 nm the side plane shell contributes more to the coercivity enhancement.The results in this work can help to design and manufacture Nd-Fe-B magnets with low cost and high magnetic properties.
基金supported by the National Natural Science Foundation of China(No.51775038).
文摘Considering the dynamic variation of roll gap and the transverse distribution of dynamic rolling force along the work roll width direction, the movement and deformation of rolls system, influenced by the coupling of vertical chatter and transverse bending vibration, may cause instability and also bring product defect of thickness difference. Therefore, a rigid-flexible coupling vibration model of the rolls system was presented. The influence of dynamic characteristics on the rolling process stability and strip thickness distribution was investigated. Firstly, assuming the symmetry of upper and lower structures of six-high rolling mill, a transverse bending vibration model of three-beam system under simply supported boundary conditions was established, and a semi-analytical solution method was proposed to deal with this model. Then, considering both variation and change rate of the roll gap, a roll vertical chatter model with structure and process coupled was constructed, and the critical rolling speed for self-excited instability was determined by Routh stability criterion. Furthermore, a rigid-flexible coupling vibration model of the rolls system was built by connecting the vertical chatter model and transverse bending vibration model through the distribution of dynamic rolling force, and the dynamic characteristics of rolls system were analyzed. Finally, the strip exit thickness distributions under the stable and unstable rolling process were compared, and the product shape and thickness distribution characteristics were quantitatively evaluated by the crown and maximum longitudinal thickness difference.
基金supported by the Humanities and Social Sciences Foundation of the Ministry of Education of China(Grant No.18YJAZH140).
文摘Gelugpa is the most influential extant religious sect of Tibetan Buddhism,which is the spiritual prop for Tibetans,with thousands of monasteries and followers in Tibetan areas of China.Studies on the spatial diffusion processes of Gelugpa can not only reveal its historical geographical development but also lay the foundation for anticipating its future development trend.However,existing studies on Gelugpa lack geographical perspective,making it difficult to explore the spatial characteristics.Furthermore,the prevailing macro-perspective overlooks spatiotemporal heterogeneity in diffusion processes.Therefore,taking monastery as the carrier,this study establishes a multi-level diffusion model to reconstruct the diffusion networks of Gelugpa monasteries,as well as a framework to explore the detailed features in the spatial diffusion processes of Gelugpa in Tibetan areas of China based on a geodatabase of Gelugpa monastery.The results show that the multi-level diffusion model has a considerable applicability in the reconstruction of the diffusion networks of Gelugpa monasteries.Gelugpa monasteries in the Three Tibetan Inhabited Areas present disparate spatial diffusion processes with diverse diffusion bases,speeds,stages,as well as diffusion regions and centers.A powerful single-center diffusion-centered Gandan Monastery was rapidly formed in U-Tsang.Kham experienced a slower and more varied spatial diffusion process with multiple diffusion systems far apart from each other.The spatial diffusion process of Amdo was the most complex,with the highest diffusion intensity.Amdo possessed the most influential diffusion centers,with different diffusion shapes and diffusion ranges crossing and overlapping with each other.Multiple natural and human factors may contribute to the formation of Gelugpa monasteries.This study contributes to the understanding of the geography of Gelugpa and provides reference to studies on religion diffusion.
基金Supported by National Natural Science Foundation of China(Grant Nos.52335002,51925502)。
文摘Robot-automated spraying is widely used in various fields,such as the automotive,metalworking,furniture,and aero-space industries.Spraying quality is influenced by multiple factors,including robot speed,acceleration,end-effector trajectory,and spraying process constraints.To achieve high-quality spraying under the influence of multiple factors,this study proposes a multi-objective optimization method for the spraying trajectory that integrates spraying process constraints into the optimization process.First,a 7-degree-of-freedom rigid-flexible coupling serial spray painting robot system is introduced,which includes a motion decoupling mechanism and a tension amplification mechanism.Subsequently,a paint deposition model for the spray gun was established,and the influence of process constraints on spraying quality was analyzed.Trajectory planning for the spray painting robot,based on the septic B-spline interpolation method,was then performed.Based on this foundation,objective functions and constraint equations for spraying trajectory optimization were established.A multi-objective trajectory optimization method for spraying by the robot is proposed based on the NSGA-Ⅱ,which integrates the spraying process constraints.Finally,a prototype system of a 7-degree-of-freedom rigid-flexible coupling serial spray painting robot was constructed.Simulations and spraying experiments were conducted to verify the effectiveness of the proposed multi-objective trajectory optimization method.This paper presents a multi-objective optimization method for the spraying trajectory of a robot.In the proposed method,the optimized spraying trajectory is generated with the spraying process as the constraint and time,energy consumption,and impact during the spraying operation of the robot as the optimization objectives.
基金supported by the National Natural Science Foundation of China(No.52374372)the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.23KJB430042)+3 种基金the Jiangsu Province Large Scientific Instruments Open Sharing Autonomous Research Filing Project,China(No.TC2023A037)the Yangzhou City−Yangzhou University Cooperation Foundation,China(No.YZ2022183)High-end Talent Support Program of Yangzhou University,China,Qinglan Project of Yangzhou University,ChinaLvyangjinfeng Talent program of Yangzhou,China.
文摘The interdiffusion coefficients in Al_(0.2)CoCrFeNi,CoCrCu_(0.2)FeNi,and CoCrFeMn_(0.2)Ni high-entropy alloys were efficiently determined by combining diffusion couple experiments and high-throughput determination of interdiffusion coefficients(HitDIC)software at 1273−1373 K.The results show that the addition of Al,Cu,and Mn to CoCrFeNi high-entropy alloys promotes the diffusion of Co,Cr,and Fe atoms.The comparison of tracer diffusion coefficients indicates that there is no sluggish diffusion in tracer diffusion on the thermodynamic temperature scale for the present Al_(0.2)CoCrFeNi,CoCrCu_(0.2)FeNi,and CoCrFeMn_(0.2)Ni high-entropy alloys.The linear relationship between diffusion entropy and activation energy reveals that the diffusion process of atoms is unaffected by an increase in the number of components as long as the crystal structure remains unchanged.
基金supported by the National Natural Science Foundation of China(Nos.61906168,62202429 and 62272267)the Zhejiang Provincial Natural Science Foundation of China(No.LY23F020023)the Construction of Hubei Provincial Key Laboratory for Intelligent Visual Monitoring of Hydropower Projects(No.2022SDSJ01)。
文摘Accurately identifying building distribution from remote sensing images with complex background information is challenging.The emergence of diffusion models has prompted the innovative idea of employing the reverse denoising process to distill building distribution from these complex backgrounds.Building on this concept,we propose a novel framework,building extraction diffusion model(BEDiff),which meticulously refines the extraction of building footprints from remote sensing images in a stepwise fashion.Our approach begins with the design of booster guidance,a mechanism that extracts structural and semantic features from remote sensing images to serve as priors,thereby providing targeted guidance for the diffusion process.Additionally,we introduce a cross-feature fusion module(CFM)that bridges the semantic gap between different types of features,facilitating the integration of the attributes extracted by booster guidance into the diffusion process more effectively.Our proposed BEDiff marks the first application of diffusion models to the task of building extraction.Empirical evidence from extensive experiments on the Beijing building dataset demonstrates the superior performance of BEDiff,affirming its effectiveness and potential for enhancing the accuracy of building extraction in complex urban landscapes.
基金jointly supported by the National Natural Science Foundation of China(Nos.42250202,92162323,42272075)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.24lgqb001)+1 种基金the Natural Science Foundation Project of Guangdong Province(No.2022A1515010003)the Guangdong Province Introduced Innovative R&D Team of Big Data—Mathematical Earth Sciences and Extreme Geological Events Team(No.2021ZT09H399)。
文摘Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases and the precipitation of secondary phases,driven by changes in the chemical environment,often mediated by hydrothermal fluids.The Bailongshan Li deposit,located in the West Kunlun region of northwest China,is a significant geological formation known for its rich lithium content and associated rare metals such as tantalum,niobium,and tin.This study investigates the coupled dissolution-precipitation processes that have played a crucial role in the mineralization of this deposit,focusing on key minerals,including cassiterite(Cst),columbite-group minerals(CGM),and elbaite(Elb).Using a combination of petrographic analysis,back-scattered electron(BSE)imaging,cathodoluminescence(CL)imaging,and micro X-ray fluorescence(XRF)mapping,we examined the textural and chemical characteristics of these minerals.Our findings reveal intricate patchy zoning patterns and element distributions(indicated by the Nb,Ta,W,Mn,Fe,Hf,Ti for CGM;Hf,Ti Rb,W,Nb,Ta for Cst;Ti,Zn,Fe,W,Hf,Mn,K for Elb)that indicate multiple stages of mineral alteration driven by fluid-mediated processes.The coupled dissolution-precipitation mechanisms observed in the Bailongshan deposit have resulted in significant redistribution and enrichment of economically valuable elements.The study highlights the importance of hydrothermal fluids in altering primary mineral phases and precipitating secondary phases with distinct compositions.These processes not only modified the mineralogical makeup of the pegmatite but also enhanced its economic potential by concentrating rare metals.Signatures of coupled dissolutionprecipitation processes can serve as an essential tool for mineral exploration,guiding the search for high-grade zones within similar pegmatitic formations.
基金supported in part by the National Natural Science Foundation of China under Grant Nos.11875157,12147214the Doctoral Start-up Fund of Liaoning Normal University under Grant No.2024BSL018the Universitylevel National Research Project Cultivation Program under Grant No.2024170。
文摘The massless dark photon~γ can only interact with the Standard Model(SM)sector via higherdimensional operators.In this letter,we investigate its production associated with the ordinary photonγfrom the lepton flavor violation(LFV)process l_(i)→l_(j)γγ and di-production from the LFV process l_(i)→l_(j)γγ induced by dipole operators.Comparing the obtained numerical results with the corresponding experimental measurements,we obtain the constraints on the effective couplings of γ with the SM charged leptons.The upper limit of the effective coupling|DLμe|2+|DRμe|2coming from the process μ→e~γγis looser than the processμ→eγ by about one order of magnitude.
基金Project supported by National Key Research and Development Program of China(2021YFB3500100)National Natural Science Foundation of China(52301068)。
文摘In this work,the effect of the Al addition amount in the TbAl coatings on the grain boundary diffusion proces s(GBDP)of Tb were systematically explored.Direct current magnetron sputtering(DCMS)method was utilized in co-sputtering manner to synthesize the TbAl coatings with certain Tb consumption and various Al addition amount.Results show that the moderate Al addition amount significantly improves the wettability of grain boundary(GB)phases,thereby acquiring more continuous and uniform Tb-rich shells and GB phases between matrix phases,as well as deeper diffusion depth and denser microstructure.The largest increase amplitude of intrinsic coercivity(Hcj)is improved by 78.4%in TbAIdiffused magnet compared to the pure Tb-diffused magnet,while the remanence(Br)is expected to show an overall decreasing tendency accompanied with a slight increase in the decreasing process.However,when the Al addition amount is excessive,magnetic dilution effect is enhanced,and the Tbrich shells and GB phases between matrix phases become fuzzy and even invisible,which in turn deteriorates the magnetic properties of diffused magnets.
基金co-supported by the National Natural Science Foundation of China(No.12374431)。
文摘To address the significant degradation of Space-Time Adaptive Processing(STAP)performance when the array elements have mutual coupling and gain/phase errors,a STAP algorithm with adaptive calibration for the above two array errors is proposed in this article.First,based on a defined error matrix that simultaneously considers both array mutual coupling and gain/phase errors,a STAP signal model including these errors is given.Then,utilizing the defined signal model,it is demonstrated that the estimation of the defined error matrix can be formulized as a standard convex optimization problem with the low-rank structure of the clutter covariance matrix and the subspace projection theory.Once the defined error matrix is estimated by solving the convex optimization problem,it is illustrated that a STAP method with adaptive calibration of the mutual coupling and gain/phase errors is coined.Analyses also show that the proposed adaptive calibration algorithm only needs one training sample to construct the adaptive weight vector.Therefore,it can achieve a good detection performance even with severe non-homogeneous clutter environments.Finally,the simulation experiments verify the effectiveness of the proposed algorithm and the correctness of the analytical results.
文摘In the 1940s, KIRKENDALL showed that diffusion in binary solid solutions cannot be described by only one diffusion coefficient. Rather, one has to consider the diffusivity of both species. His findings changed the treatment of diffusion data and the theory of diffusion itself. A diffusion-based framework was successfully employed to explain the behaviour of the Kirkendall plane. Nonetheless, the complexity of a multiphase diffusion zone and the morphological evolution during interdiffusion requires a physico-chemical approach. The interactions in binary and more complex systems are key issues from both the fundamental and technological points of view. This paper reviews the Kirkendall effect from the circumstances of its discovery to recent developments in its understanding, with broad applicability in materials science and engineering.
基金supported by the Natural Science Foundation of Henan Province(Grant No.152107000047)
文摘In this study, a two-step heating process is introduced for transient liquid phase ( TLP) diffusion bonding fo r sound joints with T91 heat resistant steels. At first, a short-time higher temperature heating step is addressed to melt the interlayer, followed by the second step to complete isothermal solidification at a low temperature. The most critical feature of our new method is producing a non-planar interface at the T9/ heat resistant steels joint. We propose a transitional liquid phase bonding of T91 heat resistant steels by this approach. Since joint microstructures have been studied, we tested the tensile strength to assess joint mechanical property. The result indicates that the solidified bond may contain a primary solid-solution, similar composition to the parent metal and free from precipitates. Joint tensile strength of the joint is not lower than parent materials. Joint bend's strengths are enhanced due to the higher metal-to-metal junction producing a non-planar bond lines. Nevertheless, the traditional transient liquid phase diffusion bonding produces planar ones. Bonding parameters of new process are 1 260 °C for 0. 5 min and 1 230 °C fo r 4 min.
基金supported by the National Key R&D Program of China(2021YFB3502902)Ningbo Major Special Projects of Science and Technology Innovation 2025 Plan(2020Z045)Key Research and Development Program of Zhejiang Province(2020C05013)。
文摘The grain boundary diffusion process(GBDP)of Tb can improve the coercivity of sintered Nd-Fe-B magnets.In this study,the effect of AI on the diffusion of Tb in the GBDP was investigated.The content of diffused Tb-Al was precisely controlled by adjusting the magnetron sputtering process.The Tb equivalent of Al was also studied.Results show that AI promotes the diffusion of Tb deeper into the magnet,reducing the thickness of the shell in the core-shell structure.This study is helpful for further developing the process,reducing the consumption of heavy rare earth elements(Tb),and improving the coercivity of sintered Nd-Fe-B magnets.
基金the National Natural Science Foundation of China (No.51178305)Key Projects in the Science & Technology Pillar Program of Tianjin (No.11ZCKFSF00300)
文摘In order to accurately simulate the diffusion of chloride ion in the existing concrete bridge and acquire the precise chloride ion concentration at given time, a cellular automata （CA）-based model is proposed. The process of chloride ion diffusion is analyzed by the CA-based method and a nonlinear solution of the Fick＇s second law is obtained. Considering the impact of various factors such as stress states, temporal and spatial variability of diffusion parameters and water-cement ratio on the process of chloride ion diffusion, the model of chloride ion diffusion under multi-factor coupling actions is presented. A chloride ion penetrating experiment reported in the literature is used to prove the effectiveness and reasonability of the present method, and a T-type beam is taken as an illustrative example to analyze the process of chloride ion diffusion in practical application. The results indicate that CA-based method can simulate the diffusion of chloride ion in the concrete structures with acceptable precision.
基金Project supported by the Pioneer and Leading Goose R&D Program of Zhejiang(2020C01190)the Science and Technology Innovation 2025Major Project of Ningbo(2020Z064)+1 种基金the Zhejiang Province Postdoctoral Science Foundation(ZJ2021080)the Inner Mongolia Major Technology Project(2021ZD0035)。
文摘Grain boundary diffusion process(GBDP)was first proposed for sintered Nd-Fe-B magnets to achieve the high utilization efficiency of heavy rare earth elements.Recent success of fabricating high performance nanocomposite magnets by GBDP indicates that this method also exerts huge applicable potential on hot-deformed Nd-Fe-B magnets.In this review,the development and magnetic property enhancement mechanisms of different diffusion methods proposed on hot-deformed magnets were thoroughly elucidated.Moreover,the improve room for further property enhancement and the accompanying problems of GBDP on hot-deformed magnets are also discussed in this article.
文摘A class of multi dimensional degenerate diffusion processes X ε(t) in R r(r≥2) are considered and the asymptotic properties of empirical measures are investigated; here X ε(t) saitisfies the stochastic differential equation dX ε(t)=σ(X ε(t)) d W(t)+B(X ε(t)) d t+ εσ～(X ε(t)) d W(t),ε>0. X ε(t) are small random perturbations of the degenerate diffusion process X(t), which satisfies the stochastic differential equation dX(t)=σ(X(t)) d W(t)+B(X(t)) d t. A large deviation theorem for projection measures ν on R r-n (n<r) of empirical measures μ are proved
基金supported by National Natural Science Foundation of China(11371321)Zhejiang Provincial Natural Science Foundation of China(Y6100663)the Key Research Base of Humanities and Social Sciences of Zhejiang Provincial High Education Talents(Statis-tics of Zhejiang Gongshang University)
文摘Let X（1） = {X（1）（s）, s ∈ R＋} and X（2） = {X（2）（t）, t ∈ R＋} be two inde-pendent nondegenerate diffusion processes with values in Rd. The existence and fractal dimension of intersections of the sample paths of X （1） and X （2） are studied. More gener-ally, let E1, E2？（0,∞） and F ？Rd be Borel sets. A necessary condition and a suffcient condition for P{X（1）（E1）∩X（2）（E2）∩F 6=？}〉0 are proved in terms of the Bessel-Riesz type capacity and Hausdorff measure of E1 × E2 × F in the metric space （R＋× R＋× Rd,ρb）, whereρb is an unsymmetric metric defined in R＋× R＋× Rd. Under reasonable conditions, results resembling those of Browian motion are obtained.
基金Funded by the National Natural Science Foundation of China (No.50675165)the National Key Technology R&D Program (No.2006BAF02A29)
文摘The segregation of thermal diffusion salt bath chromizing process was analyzed. The experimental chromizing ingredients were prepared by the four groups A, B, C, and D. In order to study the segregation status of this case, the cooling molten salt in the crucible was removed by drilling from the heart core of molten salt. The core of molten salt was analyzed by X-ray fluorescence spectroscopy and XRD. Through the analysis, we can conclude that the Cr element deposited in the bottom was 4.51 times than the top. Chloride added to the molten salt will reduce segregation. Meantime we proposed some measures to overcome the segregation problem.
