Manganese-based perovskite is popular for research on ferromagnetic materials,and its spectroscopic studies are essential for understanding its electronic structure,dielectric,electrical,and magnetic properties.In thi...Manganese-based perovskite is popular for research on ferromagnetic materials,and its spectroscopic studies are essential for understanding its electronic structure,dielectric,electrical,and magnetic properties.In this paper,the M-edge spectra of La ions and the M-edge,L-edge,and K-edge spectra of Mn ions in LaMnO3 are calculated by considering both the free-ion multiplet calculation and the crystal field effects.We analyze spectral shapes,identify peak origins,and estimate the oxidation states of La and Mn ions in LaMnO3 theoretically.It is concluded that La ions in LaMnO3 predominantly exist in the trivalent state,while Mn ions exist primarily in the trivalent state with a minor presence of tetravalent ions.Furthermore,the calculated spectra are in better conformity with the experimental spectra when the proportion of Mn3+is 90%and Mn4+is 10%.This article enhances our comprehension of the oxidation states of La and Mn within the crystal and also provides a valuable guidance for spectroscopic investigations of other manganates.展开更多
Simulators are generally used during the design of computer architectures. Typically, different simulators with different levels of complexity, speed and accuracy are used. However, for early design space exploration,...Simulators are generally used during the design of computer architectures. Typically, different simulators with different levels of complexity, speed and accuracy are used. However, for early design space exploration, simulators with less complexity, high simulation speed and reasonable accuracy are desired. It is also required that these simulators have a short development time and that changes in the design require less effort in the implementation in order to perform experiments and see the effects of changes in the design. These simulators are termed high-level simulators in the context of computer architecture. In this paper, we present multiple levels of abstractions in a high-level simulation of a general-purpose many-core system, where the objective of every level is to improve the accuracy in simulation without significantly affecting the complexity and simulation speed.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.11974253).
文摘Manganese-based perovskite is popular for research on ferromagnetic materials,and its spectroscopic studies are essential for understanding its electronic structure,dielectric,electrical,and magnetic properties.In this paper,the M-edge spectra of La ions and the M-edge,L-edge,and K-edge spectra of Mn ions in LaMnO3 are calculated by considering both the free-ion multiplet calculation and the crystal field effects.We analyze spectral shapes,identify peak origins,and estimate the oxidation states of La and Mn ions in LaMnO3 theoretically.It is concluded that La ions in LaMnO3 predominantly exist in the trivalent state,while Mn ions exist primarily in the trivalent state with a minor presence of tetravalent ions.Furthermore,the calculated spectra are in better conformity with the experimental spectra when the proportion of Mn3+is 90%and Mn4+is 10%.This article enhances our comprehension of the oxidation states of La and Mn within the crystal and also provides a valuable guidance for spectroscopic investigations of other manganates.
文摘Simulators are generally used during the design of computer architectures. Typically, different simulators with different levels of complexity, speed and accuracy are used. However, for early design space exploration, simulators with less complexity, high simulation speed and reasonable accuracy are desired. It is also required that these simulators have a short development time and that changes in the design require less effort in the implementation in order to perform experiments and see the effects of changes in the design. These simulators are termed high-level simulators in the context of computer architecture. In this paper, we present multiple levels of abstractions in a high-level simulation of a general-purpose many-core system, where the objective of every level is to improve the accuracy in simulation without significantly affecting the complexity and simulation speed.
