Traffic at urban intersections frequently encounters unexpected obstructions,resulting in congestion due to uncooperative and priority-based driving behavior.This paper presents an optimal right-turn coordination syst...Traffic at urban intersections frequently encounters unexpected obstructions,resulting in congestion due to uncooperative and priority-based driving behavior.This paper presents an optimal right-turn coordination system for Connected and Automated Vehicles(CAVs)at single-lane intersections,particularly in the context of left-hand side driving on roads.The goal is to facilitate smooth right turns for certain vehicles without creating bottlenecks.We consider that all approaching vehicles share relevant information through vehicular communications.The Intersection Coordination Unit(ICU)processes this information and communicates the optimal crossing or turning times to the vehicles.The primary objective of this coordination is to minimize overall traffic delays,which also helps improve the fuel consumption of vehicles.By considering information from upcoming vehicles at the intersection,the coordination system solves an optimization problem to determine the best timing for executing right turns,ultimately minimizing the total delay for all vehicles.The proposed coordination system is evaluated at a typical urban intersection,and its performance is compared to traditional traffic systems.Numerical simulation results indicate that the proposed coordination system significantly enhances the average traffic speed and fuel consumption compared to the traditional traffic system in various scenarios.展开更多
Due to the stubborn nature of dynamic job shop scheduling problem,a novel ant colony coordination mechanism is proposed in this paper to search for an optimal schedule in dynamic environment.In ant colony coordination...Due to the stubborn nature of dynamic job shop scheduling problem,a novel ant colony coordination mechanism is proposed in this paper to search for an optimal schedule in dynamic environment.In ant colony coordination mechanism,the dynamic job shop is composed of several autonomous ants.These ants coordinate with each other by simulating the ant foraging behavior of spreading pheromone on the trails,by which they can make information available globally,and further more guide ants make optimal decisions.The proposed mechanism is tested by several instances and the results confirm the validity of it.展开更多
At the Third Plenary Session of the 20th Central Committee of the Communist Party of China,the key reform task that'improvements will be made to the system for coordinating administrative and criminal penalties...At the Third Plenary Session of the 20th Central Committee of the Communist Party of China,the key reform task that'improvements will be made to the system for coordinating administrative and criminal penalties'was designated,drawing significant attention from academics and practitioners to China's reverse coordination mechanism between administrative enforcement and criminal justice.By examining the developmental trajectory and practical status of this system,it becomes evident that this unique reform initiative of the rule of law with Chinese characteristics,while showcasing its institutional advantages,also presents areas in urgent need of improvement,such as unclear theoretical foundations,incomplete frameworks,and limited operational effectiveness.Advancing the rule of law for the reverse coordination system between administrative enforcement and criminal justice requires a clear delineation of roles between procuratorial and administrative agencies,grounded in respecting the administrative agency's initial judgment authority.The reform should follow an orderly approach,embracing the model of front-end collaboration and back-end supervision'and adhering to'always establishing new systems before abolishing old ones while attaching equal importance to efforts in both respects'By specifically addressing the prominent issues in the practice of reverse coordination,the ultimate goal is to achieve lawful and efficient bidirectional coordination between administrative penalties and criminal penalties,as well as seamless coordination between administrative enforcement and criminal justice.展开更多
Protecting unregistered trademarks is not only necessary but feasible.Although Articles 2 and 6 of the Anti-Unfair Competition Law of the People's Republic of China currently fail to provide effective protection f...Protecting unregistered trademarks is not only necessary but feasible.Although Articles 2 and 6 of the Anti-Unfair Competition Law of the People's Republic of China currently fail to provide effective protection for unregistered trademarks due to systemic deficiencies,its legal subsumption can be enhanced by reforming the application principles of general provisions,scientifically reconstructing the notion of"unfair competition,"and adopting an open legislative approach featuring"defining unfair competition+key illustrative examples."Meanwhile,by proactively incorporating the concept that unregistered trademarks constitute the property rights of their owners into the trademark law and strengthening regulations against trademark squatting,the application of the antiunfair competition law can be enhanced to provide more effective damage remedies for unregistered trademark holders.This approach would increase the legal costs of squatting,thereby achieving a dual governance effect of both cracking down on and preventing such practice.By rationally delineating the logical boundaries of anti-unfair competition protection in conjunction with the registration-based acquisition system under the trademark law,this approach scientifically resolves conflicts between the protection of unregistered trademarks and registration validity rules while providing proportionate remedies and respect for the former.Consequently,it achieves an organic unity of necessity and rationality,comprehensiveness and restraint,as well as foresight and pertinence in the protection of unregistered trademarks.展开更多
Exploring optimal operational schemes for synergistic development is crucial for sustainable management in river basins.This study introduces a multi-objective synergistic optimization framework aimed at analyzing the...Exploring optimal operational schemes for synergistic development is crucial for sustainable management in river basins.This study introduces a multi-objective synergistic optimization framework aimed at analyzing the interplay among flood control,ecological integrity,and desilting objectives under varying watersediment conditions.The framework encompasses multi-objective reservoir optimal operation,scheme decision,and trade-off analysis among competing objectives.To address the optimization model,an elite mutation-based multiobjective particle swarm optimization(MOPSO)algorithm that integrates genetic algorithms(GA)is developed.The coupling coordination degree is employed for optimal scheme decision-making,allowing for the adjustment of weight ratios to investigate the trade-offs between objectives.This research focuses on the Sanmenxia and Xiaolangdi cascade reservoirs in the Yellow River,utilizing three representative hydrological years:1967,1969,and 2002.The findings reveal that:(1)the proposed model effectively generates Pareto fronts for multi-objective operations,facilitating the recommendation of optimal schemes based on coupling coordination degrees;(2)as water-sediment conditions shift from flooding to drought,competition intensifies between the flood control and desilting objectives.While flood control and ecological objectives compete during flood and dry years,they demonstrate synergies in normal years(r=0.22);conversely,ecological and desilting objectives are consistently competitive across all three typical years,with the strongest competition observed in the normal year(r=-0.95);(3)the advantages conferred to ecological objectives increase as water-sediment conditions shift from flooding to drought.However,the promotion of the desilting objective requires more complex trade-offs.This study provides a model and methodological approach for the multi-objective optimization of flood control,sediment management,and ecological considerations in reservoir clusters.Moreover,the methodologies presented herein can be extended to other water resource systems for multi-objective optimization and decision-making.展开更多
The intermittency and volatility of wind and photovoltaic power generation exacerbate issues such as wind and solar curtailment,hindering the efficient utilization of renewable energy and the low-carbon development of...The intermittency and volatility of wind and photovoltaic power generation exacerbate issues such as wind and solar curtailment,hindering the efficient utilization of renewable energy and the low-carbon development of energy systems.To enhance the consumption capacity of green power,the green power system consumption optimization scheduling model(GPS-COSM)is proposed,which comprehensively integrates green power system,electric boiler,combined heat and power unit,thermal energy storage,and electrical energy storage.The optimization objectives are to minimize operating cost,minimize carbon emission,and maximize the consumption of wind and solar curtailment.The multi-objective particle swarm optimization algorithm is employed to solve the model,and a fuzzy membership function is introduced to evaluate the satisfaction level of the Pareto optimal solution set,thereby selecting the optimal compromise solution to achieve a dynamic balance among economic efficiency,environmental friendliness,and energy utilization efficiency.Three typical operating modes are designed for comparative analysis.The results demonstrate that the mode involving the coordinated operation of electric boiler,thermal energy storage,and electrical energy storage performs the best in terms of economic efficiency,environmental friendliness,and renewable energy utilization efficiency,achieving the wind and solar curtailment consumption rate of 99.58%.The application of electric boiler significantly enhances the direct accommodation capacity of the green power system.Thermal energy storage optimizes intertemporal regulation,while electrical energy storage strengthens the system’s dynamic regulation capability.The coordinated optimization of multiple devices significantly reduces reliance on fossil fuels.展开更多
Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development Goals.In this work,taking Yulin City in China as...Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development Goals.In this work,taking Yulin City in China as a case study and employing the Criteria Importance Through Intercriteria Correlation(CRITIC)method,a modified model of coupling degree was developed to evaluate the car-rying capacity of water and land resources systems endowment and utilization,as well as their coupling coordination degree from 2013 to 2020.Our findings indicate that the water and land resources of Yulin are diminishing due to declines in agriculture,higher industrial water use,and wetland shrinkage.However,reallocating domestic water for ecological sustainability and reducing sloping farmland can mitigate this trend of decline.Temporally,as the coupling coordination between water and land resources system endowment in Yulin continuously improved,the coupling coordination between water and land resources system utilization first decreased and then in-creased with 2016 as the turning point.Spatially,the carrying capacity of water and land resources systems,the coupling coordination degree between water and land resources system endowment,and the coupling coordination degree between water and land resources system utilization in Yulin exhibited the same pattern of being higher in the six northern counties than in the six southern counties.Improving the water resources endowment is vital for the highly efficient use of water and land resources.展开更多
One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem services.While many studies have investigated the effect of cropland intensification on agroeco...One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem services.While many studies have investigated the effect of cropland intensification on agroecosystem service,the interactive coupling and coordination among these factors remain largely unexplored.In view of this,this study performed a case study of the Loess Plateau in Shaanxi Province,China and constructed comprehensive evaluation models to quantify the cropland intensification and agroecosystem service in this area.Balance analysis and the coupling coordination degree model were used to evaluate the interactive relationship between cropland intensification and agroecosystem service,and statistical analysis and spatial autocorrelation were used to analyze the spatial characteristics and potential mechanism of the coupling coordination.Results show that both the cropland intensification and agroecosystem service in the study area were relatively low yet gradually increased from 2000 to 2020.Agroecosystem service lag was identified as the dominant unbalanced development type.Improving the supply capacity of agroecosystem services plays a key role in the balanced development of cropland in the Loess Plateau.The coupling coordination degree between cropland intensification and agroecosystem service ranges from basic coordination to serious incoordination.Therefore,cropland intensification practices in the area should be optimized to enhance this coordination degree.An upward trend was also observed in the coupling coordination degree from2000 to 2020.The withdrawal of marginal cropland in the Grain for Green program is one of the most important reasons for this trend,especially for the northern region.Around 83.6%of the high-high clusters are concentrated in the southern region of the Loess Plateau,whereas 70.5%of the low-low clusters are distributed in the northern region.These clustering characteristics are mainly attributed to the environmental suitability of these areas for agriculture and their degree of economic development.展开更多
Sustainable growth is a prerequisite for high-quality development,and inclusive green growth is regarded as an important way to realize sustainable growth.This paper constructs a tourism inclusive green growth index(I...Sustainable growth is a prerequisite for high-quality development,and inclusive green growth is regarded as an important way to realize sustainable growth.This paper constructs a tourism inclusive green growth index(IGGI)system based on the 2018 Asian Development Bank IGGI.Using Shandong Province from 2017 to 2019,the entropy weight method is utilized to explore the degree of coupling and coordination among the subsystems of tourism inclusive green growth.The study shows that:(1)the tourism IGGI continues to grow;(2)in the tourism inclusive green growth system,the social equity subsystem shows a trend of steady improvement;and(3)in the system,there is a slight discordance between the economic growth subsystem and the environmental sustainability subsystem.The study aims to provide the scientific basis for the high-quality development of tourism and theoretical support for the field of tourism and environmental sustainability.展开更多
Using the coupled coordination degree model,DEA coupled coordination efficiency model,and spatial autocorrelation model,this study explored the dynamic coupled coordination relationship and spatial correlation between...Using the coupled coordination degree model,DEA coupled coordination efficiency model,and spatial autocorrelation model,this study explored the dynamic coupled coordination relationship and spatial correlation between the ice-snow tourism network attention and tourism industry development in 31 Chinese provinces and proposed suggestions pertaining to development.Our findings showed that(1)most provinces have not yet achieved excellent coordinated development between the two systems,and the coupled coordination efficiency is low.Each province's coupled coordination degree and coordination efficiency exhibited a small increase.(2)Spatial differences in the coupled coordination level and coordination efficiency of the two systems in each province were more evident.In seven provinces,including Heilongjiang,tourism industry development demonstrated a relatively high utilization rate and enhanced ice-snow tourism network attention.(3)The rankings of the coupled coordination degree and coordination efficiency of the two systems in each province remained relatively stable at the upper and lower ends,with large changes in the central provinces.The coupled coordination efficiency of Heilongjiang,Beijing,Jilin,and Shanghai remained at the top of the list steadily,whereas Xizang,Anhui,and Qinghai stayed at the bottom.In contrast,the ranking of the coupled coordination efficiency of Inner Mongolia,Henan,and Jiangsu displayed a great change.(4)The spatial correlation analysis revealed a positive correlation that decreased annually.Some provinces exhibited characteristics of spatial aggregation,with a high-high aggregation effect in Liaoning and Jilin,a low-low aggregation effect in Gansu and Qinghai,and no spatial aggregation effect in most other provinces.展开更多
This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expan...This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expansion with environmental protection,a comprehensive evaluation index system is constructed,encompassing two key dimensions:regional economy and ecological environment.Using panel data from 2013 to 2022,the coupling coordination degree model is employed to quantify the interactions and synergy between these dimensions.Additionally,spatial econometric methods are applied to calculate both global and local Moran’s Index,revealing spatial clustering patterns,regional disparities,and heterogeneity.The relative development model further identifies critical factors influencing regional coordination,with a focus on the lagging development of basic infrastructure and public services.The findings demonstrate a positive temporal trend toward improved regional coordination and reduced development gaps,with a spatial pattern characterized by higher coupling degrees in eastern and central regions compared to western areas.Based on these results,this study proposes actionable strategies to enhance coordinated development,emphasizing ecological conservation,the establishment of green production and consumption systems,ecological restoration,and strengthened municipal collaboration.This revised abstract emphasizes the study’s purpose,methods,and key findings more clearly while maintaining a professional and concise tone.Finally,based on the above analysis results,the corresponding coordinated development suggestions of regional economy and ecological environment are given from the aspects of ecological environment protection measures,green production and consumption system construction,ecological environment restoration and municipal coordination.展开更多
With the boom in maritime activities,the need for highly reliable maritime communication is becoming urgent,which is an important component of 5G/6G communication networks.However,the bandwidth reuse characteristic of...With the boom in maritime activities,the need for highly reliable maritime communication is becoming urgent,which is an important component of 5G/6G communication networks.However,the bandwidth reuse characteristic of 5G/6G networks will inevitably lead to severe interference,resulting in degradation in the communication performance of maritime users.In this paper,we propose a safe deep reinforcement learning based interference coordination scheme to jointly optimize the power control and bandwidth allocation in maritime communication systems,and exploit the quality-of-service requirements of users as the risk value references to evaluate the communication policies.In particular,this scheme designs a deep neural network to select the communication policies through the evaluation network and update the parameters using the target network,which improves the communication performance and speeds up the convergence rate.Moreover,the Nash equilibrium of the interference coordination game and the computational complexity of the proposed scheme are analyzed.Simulation and experimental results verify the performance gain of the proposed scheme compared with benchmarks.展开更多
High-entropy alloy(HEA)nanoparticles(NPs)have attracted great attention in electrocatalysis due to their tailorable complex compositions and unique properties.Herein,we introduce Fe,Co,Ni,Cr and Mn into the metal-poly...High-entropy alloy(HEA)nanoparticles(NPs)have attracted great attention in electrocatalysis due to their tailorable complex compositions and unique properties.Herein,we introduce Fe,Co,Ni,Cr and Mn into the metal-polyphenol coordination system to prepare HEA NPs enclosed in N-doped carbon(FeCoNiCrMn)with great potential for catalyzing oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).The unique high-entropy structural characteristics in FeCoNiCrMn facilitate effective interplay between metal species,leading to improved ORR(E_(1/2)=0.89 V)and OER(η=330 mV,j=10 mA·cm^(−2))activity.Additionally,FeCoNiCrMn exhibits excellent open-circuit voltage(1.523 V),power density(110 mW·cm^(−2))and long-term durability,outperforming Pt/C+IrO_(2) electrodes as a cathode catalyst in Zn-air batteries(ZABs).Such polyphenol-assisted alloying method broadens and simplifies the development of HEA electrocatalysts for high-performance ZABs.展开更多
Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoti...Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.展开更多
This work focuses on maximizing the minimum user’s security energy efficiency(SEE)in an unmanned aerial vehicle-mounted reconfigurable intelligent surface(UAV-RIS)enhanced short-packet communication(SPC)system.The ba...This work focuses on maximizing the minimum user’s security energy efficiency(SEE)in an unmanned aerial vehicle-mounted reconfigurable intelligent surface(UAV-RIS)enhanced short-packet communication(SPC)system.The base station(BS)provides short packet services to ground users using the non-orthogonal multiple access(NOMA)protocol through UAV-RIS,while preventing eavesdropper attacks.To optimize SEE,a joint optimization is performed concerning power allocation,UAV position,decoding order,and RIS phase shifts.An iterative algorithm based on block coordinate descent is proposed for mixed-integer non-convex SEE optimization problem.The original problem is decomposed into three sub-problems,solved alternately using successive convex approximation(SCA),quadratic transformation,penalty function,and semi-definite programming(SDP).Simulation results demonstrate the performance of the UAV-RIS-enhanced short-packet system under different parameters and verify the algorithm’s convergence.Compared to benchmark schemes such as orthogonal multiple access,long packet communication,and sum SEE,the proposed UAV-RIS-enhanced short-packet scheme achieves the higher minimum user’s SEE.展开更多
A low-cost 1D cobalt-based coordination polymer(CP)[Co(BGPD)(DMSO)_(2)(H_(2)O)_(2)](Co-BD;H2BGPD=N,N'-bis(glycinyl)pyromellitic diimide;DMSO=dimethyl sulfoxide)was synthesized by a simple method,and its crystal st...A low-cost 1D cobalt-based coordination polymer(CP)[Co(BGPD)(DMSO)_(2)(H_(2)O)_(2)](Co-BD;H2BGPD=N,N'-bis(glycinyl)pyromellitic diimide;DMSO=dimethyl sulfoxide)was synthesized by a simple method,and its crystal structure was characterized.In a three-electrode system,Co-BD,as the electrode material for supercapacitors,achieved a specific capacitance of 830 F·g^(-1)at 1 A·g^(-1),equivalent to a specific capacity of 116.4 mAh·g^(-1),and exhibited high-rate capability,reaching 212 F·g^(-1)at 20 A·g^(-1).Impressively,Co-BD||rGO(reduced graphene oxide),representing an asymmetrical supercapacitor,owns a higher energy density of 14.2 Wh·kg^(-1)at 0.80 kW·kg^(-1),and an excellent cycle performance(After 4000 cycles at 1 A·g^(-1),the capacitance retention was up to 94%).CCDC:2418872.展开更多
Six coordination polymers based on 9,10-di(pyridine-4-yl)-anthracene(DPA)and 1,6-di(1H-imidazol-1-yl)pyrene(DIP)were obtained by solvothermal reactions.{[Zn(DPA)Cl_(2)]·DMF·2H_(2)O}n(1)and{[Zn_(1.5)(DPA)_(1....Six coordination polymers based on 9,10-di(pyridine-4-yl)-anthracene(DPA)and 1,6-di(1H-imidazol-1-yl)pyrene(DIP)were obtained by solvothermal reactions.{[Zn(DPA)Cl_(2)]·DMF·2H_(2)O}n(1)and{[Zn_(1.5)(DPA)_(1.5)Cl_(3)]·5H_(2)O}n(2)are framework isomers,which both contain zigzag chains formed by DPA,Zn^(2+),and Cl-.The zigzag chains in 1 are further assembled by C—H…Cl interactions into layers,and these layers exhibit two different orientations,displaying a rare 2D to 3D interpenetration mode.The zigzag chains in 2 are parallelly arranged.{[Zn_(3)(DPA)_(3)Br_(6)]·2DMF·_(1.5)H_(2)O}n(3)is isostructural to 2.3 was obtained using ZnBr_(2)instead of ZnCl_(2).[M(DPA)(formate)_(2)(H_(2)O)_(2)]n[M=Co(4),Cu(5)]are isostructural,contain chain structures formed by DPA,Cu^(2+)/Co^(2+),and for-mate ions,which were formed in situ in the solvothermal reaction.{[Zn(DIP)_(2)Cl]ClO_(4)}n(6)contains a layer structure formed by DIP and Zn^(2+).Free DPA and DIP ligands exhibited high fluorescence at room temperature,and coordina-tion polymers 3 and 6 displayed enhanced fluorescent emissions.展开更多
Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions an...Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions and 6-(3',4'-dicarboxylphenoxy)-1,2,4-benzenetricarboxylic acid(H_(5)L)in the presence of N-auxiliary ligands 1,10-phenanthroline(phen)and1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib).The structures of coordination polymers 1 and 2 were characterized by infrared spectroscopy,single-crystal X-ray diffraction,thermogravimetric analysis,and powder X-ray diffraction.Single-crystal X-ray diffraction reveals that 1 has a 1D chain structure based on binuclear Mn(Ⅱ)units,while 2 features a(3,8)-connected 3D network structure based on tetranuclear Mn(Ⅱ)units.Magnetic studies show that 1 and 2exhibit antiferromagnetic interactions between manganese ions.2 shows stronger antiferromagnetic interactions due to the shorter Mn…Mn distances within the tetranuclear manganese units.CCDC:2357601,1;2357602,2.展开更多
Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic...Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.展开更多
We report five coordination polymers(CPs)based on fluorescent ligands[1,6-di(1H-imidazol-1-yl)pyrene(dip),9,10-di(1H-imidazol-1-yl)anthracene(dia)]and anionic ligands[cyclohexane-1,4-dicarboxylic acid(H_(2)cda),campho...We report five coordination polymers(CPs)based on fluorescent ligands[1,6-di(1H-imidazol-1-yl)pyrene(dip),9,10-di(1H-imidazol-1-yl)anthracene(dia)]and anionic ligands[cyclohexane-1,4-dicarboxylic acid(H_(2)cda),camphoric acid(H_(2)cpa)].In[Cd(dip)(cda)]·4H_(2)O}_(n)(1),the Cd^(2+)ions,acting as tetrahedral nodes,are linked by dipand cda^(2-)ligands with four Cd^(2+)ions into five-fold interpenetrating network array of topology of dia.In{[Cd(dip)(cpa)]·4H_(2)O}_(n)(2),the Cd^(2+)ions,acting as a 4-connector,are linked by cpa^(2-)and dip ligands into a 3D framework ofcds topology.In{[Ni(dia)_(2)Cl_(2)]·DMF}_(n)(3),the Ni^(2+)ion is linked by four dia ligands into a layer structure,and 1Dchannels of a cross-section of 1.35 nm×0.96 nm are formed.In{[Cd(dia)_(2)(H_(2)O)_(2)](NO_(3))_(2)·2DMSO}n(4),the dia ligandsconnected Cd^(2+)ions into a 2D layer,and 1D channels are formed between adjacent layers with a cross-section of0.87 nm×0.43 nm.In[Zn(dip)Cl_(2)]_(n)(5),the Zn^(2+)ion is linked by dip ligands into an infinite 1D chain.The infrared,thermal gravimetric,and fluorescent emission data were collected and analyzed for these coordination polymers.CCDC:2356055,1;2440075,2;2356057,3;2356057,4;2356059,5.展开更多
基金supported by the Japan Society for the Promotion of Science(JSPS)Grants-in-Aid for Scientific Research(C)23K03898.
文摘Traffic at urban intersections frequently encounters unexpected obstructions,resulting in congestion due to uncooperative and priority-based driving behavior.This paper presents an optimal right-turn coordination system for Connected and Automated Vehicles(CAVs)at single-lane intersections,particularly in the context of left-hand side driving on roads.The goal is to facilitate smooth right turns for certain vehicles without creating bottlenecks.We consider that all approaching vehicles share relevant information through vehicular communications.The Intersection Coordination Unit(ICU)processes this information and communicates the optimal crossing or turning times to the vehicles.The primary objective of this coordination is to minimize overall traffic delays,which also helps improve the fuel consumption of vehicles.By considering information from upcoming vehicles at the intersection,the coordination system solves an optimization problem to determine the best timing for executing right turns,ultimately minimizing the total delay for all vehicles.The proposed coordination system is evaluated at a typical urban intersection,and its performance is compared to traditional traffic systems.Numerical simulation results indicate that the proposed coordination system significantly enhances the average traffic speed and fuel consumption compared to the traditional traffic system in various scenarios.
基金National Natural Science Foundation of China(No.50575137)National Science and Technology Support Project(No.2006BAF01A44)National High Technology Research and Development Program of China(863 Program,No.2007AA04Z109)
文摘Due to the stubborn nature of dynamic job shop scheduling problem,a novel ant colony coordination mechanism is proposed in this paper to search for an optimal schedule in dynamic environment.In ant colony coordination mechanism,the dynamic job shop is composed of several autonomous ants.These ants coordinate with each other by simulating the ant foraging behavior of spreading pheromone on the trails,by which they can make information available globally,and further more guide ants make optimal decisions.The proposed mechanism is tested by several instances and the results confirm the validity of it.
基金a phased result of the General Research Program on Humanities and Social Sciences of the Ministry of Education in 2022,entitled Study on Illegal Evidence Collection in Administrative Punishments(Grant No.22YJA820029)。
文摘At the Third Plenary Session of the 20th Central Committee of the Communist Party of China,the key reform task that'improvements will be made to the system for coordinating administrative and criminal penalties'was designated,drawing significant attention from academics and practitioners to China's reverse coordination mechanism between administrative enforcement and criminal justice.By examining the developmental trajectory and practical status of this system,it becomes evident that this unique reform initiative of the rule of law with Chinese characteristics,while showcasing its institutional advantages,also presents areas in urgent need of improvement,such as unclear theoretical foundations,incomplete frameworks,and limited operational effectiveness.Advancing the rule of law for the reverse coordination system between administrative enforcement and criminal justice requires a clear delineation of roles between procuratorial and administrative agencies,grounded in respecting the administrative agency's initial judgment authority.The reform should follow an orderly approach,embracing the model of front-end collaboration and back-end supervision'and adhering to'always establishing new systems before abolishing old ones while attaching equal importance to efforts in both respects'By specifically addressing the prominent issues in the practice of reverse coordination,the ultimate goal is to achieve lawful and efficient bidirectional coordination between administrative penalties and criminal penalties,as well as seamless coordination between administrative enforcement and criminal justice.
文摘Protecting unregistered trademarks is not only necessary but feasible.Although Articles 2 and 6 of the Anti-Unfair Competition Law of the People's Republic of China currently fail to provide effective protection for unregistered trademarks due to systemic deficiencies,its legal subsumption can be enhanced by reforming the application principles of general provisions,scientifically reconstructing the notion of"unfair competition,"and adopting an open legislative approach featuring"defining unfair competition+key illustrative examples."Meanwhile,by proactively incorporating the concept that unregistered trademarks constitute the property rights of their owners into the trademark law and strengthening regulations against trademark squatting,the application of the antiunfair competition law can be enhanced to provide more effective damage remedies for unregistered trademark holders.This approach would increase the legal costs of squatting,thereby achieving a dual governance effect of both cracking down on and preventing such practice.By rationally delineating the logical boundaries of anti-unfair competition protection in conjunction with the registration-based acquisition system under the trademark law,this approach scientifically resolves conflicts between the protection of unregistered trademarks and registration validity rules while providing proportionate remedies and respect for the former.Consequently,it achieves an organic unity of necessity and rationality,comprehensiveness and restraint,as well as foresight and pertinence in the protection of unregistered trademarks.
基金National Natural Science Foundation of China,Grant/Award Number:U2243228The Belt and Road Special Foundation of the National Key Laboratory of Water Disaster Prevention,Grant/Award Number:2022nkms04+1 种基金MOE(Ministry of Education in China)Liberal Arts and Social Sciences Foundation,Grant/Award Number:23YJCZH332Natural Science Foundation of Anhui Province,Grant/Award Numbers:2208085US03,2308085US13。
文摘Exploring optimal operational schemes for synergistic development is crucial for sustainable management in river basins.This study introduces a multi-objective synergistic optimization framework aimed at analyzing the interplay among flood control,ecological integrity,and desilting objectives under varying watersediment conditions.The framework encompasses multi-objective reservoir optimal operation,scheme decision,and trade-off analysis among competing objectives.To address the optimization model,an elite mutation-based multiobjective particle swarm optimization(MOPSO)algorithm that integrates genetic algorithms(GA)is developed.The coupling coordination degree is employed for optimal scheme decision-making,allowing for the adjustment of weight ratios to investigate the trade-offs between objectives.This research focuses on the Sanmenxia and Xiaolangdi cascade reservoirs in the Yellow River,utilizing three representative hydrological years:1967,1969,and 2002.The findings reveal that:(1)the proposed model effectively generates Pareto fronts for multi-objective operations,facilitating the recommendation of optimal schemes based on coupling coordination degrees;(2)as water-sediment conditions shift from flooding to drought,competition intensifies between the flood control and desilting objectives.While flood control and ecological objectives compete during flood and dry years,they demonstrate synergies in normal years(r=0.22);conversely,ecological and desilting objectives are consistently competitive across all three typical years,with the strongest competition observed in the normal year(r=-0.95);(3)the advantages conferred to ecological objectives increase as water-sediment conditions shift from flooding to drought.However,the promotion of the desilting objective requires more complex trade-offs.This study provides a model and methodological approach for the multi-objective optimization of flood control,sediment management,and ecological considerations in reservoir clusters.Moreover,the methodologies presented herein can be extended to other water resource systems for multi-objective optimization and decision-making.
基金funded by the National Key Research and Development Program of China(2024YFE0106800)Natural Science Foundation of Shandong Province(ZR2021ME199).
文摘The intermittency and volatility of wind and photovoltaic power generation exacerbate issues such as wind and solar curtailment,hindering the efficient utilization of renewable energy and the low-carbon development of energy systems.To enhance the consumption capacity of green power,the green power system consumption optimization scheduling model(GPS-COSM)is proposed,which comprehensively integrates green power system,electric boiler,combined heat and power unit,thermal energy storage,and electrical energy storage.The optimization objectives are to minimize operating cost,minimize carbon emission,and maximize the consumption of wind and solar curtailment.The multi-objective particle swarm optimization algorithm is employed to solve the model,and a fuzzy membership function is introduced to evaluate the satisfaction level of the Pareto optimal solution set,thereby selecting the optimal compromise solution to achieve a dynamic balance among economic efficiency,environmental friendliness,and energy utilization efficiency.Three typical operating modes are designed for comparative analysis.The results demonstrate that the mode involving the coordinated operation of electric boiler,thermal energy storage,and electrical energy storage performs the best in terms of economic efficiency,environmental friendliness,and renewable energy utilization efficiency,achieving the wind and solar curtailment consumption rate of 99.58%.The application of electric boiler significantly enhances the direct accommodation capacity of the green power system.Thermal energy storage optimizes intertemporal regulation,while electrical energy storage strengthens the system’s dynamic regulation capability.The coordinated optimization of multiple devices significantly reduces reliance on fossil fuels.
基金Under the auspices of the National Natural Science Foundation of China(No.42271279,41931293,41801175)。
文摘Quantitatively assessing the carrying capacity of water and land resources systems in arid and semi-arid areas is crucial for achieving the 2030 Sustainable Development Goals.In this work,taking Yulin City in China as a case study and employing the Criteria Importance Through Intercriteria Correlation(CRITIC)method,a modified model of coupling degree was developed to evaluate the car-rying capacity of water and land resources systems endowment and utilization,as well as their coupling coordination degree from 2013 to 2020.Our findings indicate that the water and land resources of Yulin are diminishing due to declines in agriculture,higher industrial water use,and wetland shrinkage.However,reallocating domestic water for ecological sustainability and reducing sloping farmland can mitigate this trend of decline.Temporally,as the coupling coordination between water and land resources system endowment in Yulin continuously improved,the coupling coordination between water and land resources system utilization first decreased and then in-creased with 2016 as the turning point.Spatially,the carrying capacity of water and land resources systems,the coupling coordination degree between water and land resources system endowment,and the coupling coordination degree between water and land resources system utilization in Yulin exhibited the same pattern of being higher in the six northern counties than in the six southern counties.Improving the water resources endowment is vital for the highly efficient use of water and land resources.
基金Under the auspices of the National Natural Science Foundation of China(No.41901262)Natural Science Basic Research Program of Shaanxi(No.2024JC-YBQN-0300)Fundamental Research Funds for the Central Universities(No.GK202103125,GK202207005)。
文摘One of the greatest challenges in the agroecosystem is to improve cropland intensification while preserving agroecosystem services.While many studies have investigated the effect of cropland intensification on agroecosystem service,the interactive coupling and coordination among these factors remain largely unexplored.In view of this,this study performed a case study of the Loess Plateau in Shaanxi Province,China and constructed comprehensive evaluation models to quantify the cropland intensification and agroecosystem service in this area.Balance analysis and the coupling coordination degree model were used to evaluate the interactive relationship between cropland intensification and agroecosystem service,and statistical analysis and spatial autocorrelation were used to analyze the spatial characteristics and potential mechanism of the coupling coordination.Results show that both the cropland intensification and agroecosystem service in the study area were relatively low yet gradually increased from 2000 to 2020.Agroecosystem service lag was identified as the dominant unbalanced development type.Improving the supply capacity of agroecosystem services plays a key role in the balanced development of cropland in the Loess Plateau.The coupling coordination degree between cropland intensification and agroecosystem service ranges from basic coordination to serious incoordination.Therefore,cropland intensification practices in the area should be optimized to enhance this coordination degree.An upward trend was also observed in the coupling coordination degree from2000 to 2020.The withdrawal of marginal cropland in the Grain for Green program is one of the most important reasons for this trend,especially for the northern region.Around 83.6%of the high-high clusters are concentrated in the southern region of the Loess Plateau,whereas 70.5%of the low-low clusters are distributed in the northern region.These clustering characteristics are mainly attributed to the environmental suitability of these areas for agriculture and their degree of economic development.
基金supported by the S&T Program of Hebei(soft science research project)of China[Grant No.21557603D].
文摘Sustainable growth is a prerequisite for high-quality development,and inclusive green growth is regarded as an important way to realize sustainable growth.This paper constructs a tourism inclusive green growth index(IGGI)system based on the 2018 Asian Development Bank IGGI.Using Shandong Province from 2017 to 2019,the entropy weight method is utilized to explore the degree of coupling and coordination among the subsystems of tourism inclusive green growth.The study shows that:(1)the tourism IGGI continues to grow;(2)in the tourism inclusive green growth system,the social equity subsystem shows a trend of steady improvement;and(3)in the system,there is a slight discordance between the economic growth subsystem and the environmental sustainability subsystem.The study aims to provide the scientific basis for the high-quality development of tourism and theoretical support for the field of tourism and environmental sustainability.
基金supported by The Science and Technology program of Gansu Province(Grant No.23ZDFA017).
文摘Using the coupled coordination degree model,DEA coupled coordination efficiency model,and spatial autocorrelation model,this study explored the dynamic coupled coordination relationship and spatial correlation between the ice-snow tourism network attention and tourism industry development in 31 Chinese provinces and proposed suggestions pertaining to development.Our findings showed that(1)most provinces have not yet achieved excellent coordinated development between the two systems,and the coupled coordination efficiency is low.Each province's coupled coordination degree and coordination efficiency exhibited a small increase.(2)Spatial differences in the coupled coordination level and coordination efficiency of the two systems in each province were more evident.In seven provinces,including Heilongjiang,tourism industry development demonstrated a relatively high utilization rate and enhanced ice-snow tourism network attention.(3)The rankings of the coupled coordination degree and coordination efficiency of the two systems in each province remained relatively stable at the upper and lower ends,with large changes in the central provinces.The coupled coordination efficiency of Heilongjiang,Beijing,Jilin,and Shanghai remained at the top of the list steadily,whereas Xizang,Anhui,and Qinghai stayed at the bottom.In contrast,the ranking of the coupled coordination efficiency of Inner Mongolia,Henan,and Jiangsu displayed a great change.(4)The spatial correlation analysis revealed a positive correlation that decreased annually.Some provinces exhibited characteristics of spatial aggregation,with a high-high aggregation effect in Liaoning and Jilin,a low-low aggregation effect in Gansu and Qinghai,and no spatial aggregation effect in most other provinces.
基金support from Guangdong Science and Technology(20230505)Guangdong Provincial Philosophy and Social Science Planning Project(GD20SQ25)Guangdong Provincial Special Fund for Science and Technology Innovation Strategy in 2024(Cultivation of College Students’Science and Technology Innovation)(pdjh2024a391)during preparation of this manuscript.
文摘This study investigates the coordination between regional economic growth and ecological sustainability within the context of high-quality town economy development.To address the challenges of balancing economic expansion with environmental protection,a comprehensive evaluation index system is constructed,encompassing two key dimensions:regional economy and ecological environment.Using panel data from 2013 to 2022,the coupling coordination degree model is employed to quantify the interactions and synergy between these dimensions.Additionally,spatial econometric methods are applied to calculate both global and local Moran’s Index,revealing spatial clustering patterns,regional disparities,and heterogeneity.The relative development model further identifies critical factors influencing regional coordination,with a focus on the lagging development of basic infrastructure and public services.The findings demonstrate a positive temporal trend toward improved regional coordination and reduced development gaps,with a spatial pattern characterized by higher coupling degrees in eastern and central regions compared to western areas.Based on these results,this study proposes actionable strategies to enhance coordinated development,emphasizing ecological conservation,the establishment of green production and consumption systems,ecological restoration,and strengthened municipal collaboration.This revised abstract emphasizes the study’s purpose,methods,and key findings more clearly while maintaining a professional and concise tone.Finally,based on the above analysis results,the corresponding coordinated development suggestions of regional economy and ecological environment are given from the aspects of ecological environment protection measures,green production and consumption system construction,ecological environment restoration and municipal coordination.
文摘With the boom in maritime activities,the need for highly reliable maritime communication is becoming urgent,which is an important component of 5G/6G communication networks.However,the bandwidth reuse characteristic of 5G/6G networks will inevitably lead to severe interference,resulting in degradation in the communication performance of maritime users.In this paper,we propose a safe deep reinforcement learning based interference coordination scheme to jointly optimize the power control and bandwidth allocation in maritime communication systems,and exploit the quality-of-service requirements of users as the risk value references to evaluate the communication policies.In particular,this scheme designs a deep neural network to select the communication policies through the evaluation network and update the parameters using the target network,which improves the communication performance and speeds up the convergence rate.Moreover,the Nash equilibrium of the interference coordination game and the computational complexity of the proposed scheme are analyzed.Simulation and experimental results verify the performance gain of the proposed scheme compared with benchmarks.
基金supported by the Fundamental Research Funds for the Central Universities(No.22120230104).
文摘High-entropy alloy(HEA)nanoparticles(NPs)have attracted great attention in electrocatalysis due to their tailorable complex compositions and unique properties.Herein,we introduce Fe,Co,Ni,Cr and Mn into the metal-polyphenol coordination system to prepare HEA NPs enclosed in N-doped carbon(FeCoNiCrMn)with great potential for catalyzing oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).The unique high-entropy structural characteristics in FeCoNiCrMn facilitate effective interplay between metal species,leading to improved ORR(E_(1/2)=0.89 V)and OER(η=330 mV,j=10 mA·cm^(−2))activity.Additionally,FeCoNiCrMn exhibits excellent open-circuit voltage(1.523 V),power density(110 mW·cm^(−2))and long-term durability,outperforming Pt/C+IrO_(2) electrodes as a cathode catalyst in Zn-air batteries(ZABs).Such polyphenol-assisted alloying method broadens and simplifies the development of HEA electrocatalysts for high-performance ZABs.
基金Supported by the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_0102)the China Scholarship Council Program(202406190114)。
文摘Studying the coupling coordination development of new energy vehicles(NEVs)and the ecological environment in China is helpful in promoting the development of NEVs in the country and is of great significance in promoting high-quality development of new energy in China.This paper constructs an evaluation index system for the development of NEVs and the ecological environment.It uses game theory combining weighting model,particle swarm optimized projection tracking evaluation model,coupling coordination degree model,and machine learning algorithms to calculate and analyze the level of coupling coordination development of NEVs and the ecological environment in China from 2010 to 2021,and identifies the driving factors.The research results show that:(i)From 2010 to 2021,the development index of NEVs in China has steadily increased from 0.085 to 0.634,while the ecological environment level index significantly rose from 0.170 to 0.884,reflecting the continuous development of China in both NEVs and the ecological environment.(ii)From 2010 to 2012,the two systems—new energy vehicle(NEV)development and the ecological environment—were in a period of imbalance and decline.From 2013 to 2016,they underwent a transition period,and from 2017 to 2021,they entered a period of coordinated development showing a trend of benign and continuous improvement.By 2021,they reached a good level of coordination.(iii)Indicators such as the number of patents granted for NEVs,water consumption per unit of GDP,and energy consumption per unit of GDP are the main driving factors affecting the coupling coordination development of NEVs and the ecological environment in China.
基金co-supported by the National Natural Science Foundation of China(Nos.U23A20279,62271094)the National Key R&D Program of China(No.SQ2023YFB2500024)+2 种基金the Science Foundation for Youths of Natural Science Foundation of Sichuan Provincial,China(No.2022NSFSC0936)the China Postdoctoral Science Foundation(No.2022M720666)the Open Fund of Key Laboratory of Big Data Intelligent Computing,Chongqing University of Posts and Telecommunications,China(No.BDIC-2023-B-002).
文摘This work focuses on maximizing the minimum user’s security energy efficiency(SEE)in an unmanned aerial vehicle-mounted reconfigurable intelligent surface(UAV-RIS)enhanced short-packet communication(SPC)system.The base station(BS)provides short packet services to ground users using the non-orthogonal multiple access(NOMA)protocol through UAV-RIS,while preventing eavesdropper attacks.To optimize SEE,a joint optimization is performed concerning power allocation,UAV position,decoding order,and RIS phase shifts.An iterative algorithm based on block coordinate descent is proposed for mixed-integer non-convex SEE optimization problem.The original problem is decomposed into three sub-problems,solved alternately using successive convex approximation(SCA),quadratic transformation,penalty function,and semi-definite programming(SDP).Simulation results demonstrate the performance of the UAV-RIS-enhanced short-packet system under different parameters and verify the algorithm’s convergence.Compared to benchmark schemes such as orthogonal multiple access,long packet communication,and sum SEE,the proposed UAV-RIS-enhanced short-packet scheme achieves the higher minimum user’s SEE.
文摘A low-cost 1D cobalt-based coordination polymer(CP)[Co(BGPD)(DMSO)_(2)(H_(2)O)_(2)](Co-BD;H2BGPD=N,N'-bis(glycinyl)pyromellitic diimide;DMSO=dimethyl sulfoxide)was synthesized by a simple method,and its crystal structure was characterized.In a three-electrode system,Co-BD,as the electrode material for supercapacitors,achieved a specific capacitance of 830 F·g^(-1)at 1 A·g^(-1),equivalent to a specific capacity of 116.4 mAh·g^(-1),and exhibited high-rate capability,reaching 212 F·g^(-1)at 20 A·g^(-1).Impressively,Co-BD||rGO(reduced graphene oxide),representing an asymmetrical supercapacitor,owns a higher energy density of 14.2 Wh·kg^(-1)at 0.80 kW·kg^(-1),and an excellent cycle performance(After 4000 cycles at 1 A·g^(-1),the capacitance retention was up to 94%).CCDC:2418872.
文摘Six coordination polymers based on 9,10-di(pyridine-4-yl)-anthracene(DPA)and 1,6-di(1H-imidazol-1-yl)pyrene(DIP)were obtained by solvothermal reactions.{[Zn(DPA)Cl_(2)]·DMF·2H_(2)O}n(1)and{[Zn_(1.5)(DPA)_(1.5)Cl_(3)]·5H_(2)O}n(2)are framework isomers,which both contain zigzag chains formed by DPA,Zn^(2+),and Cl-.The zigzag chains in 1 are further assembled by C—H…Cl interactions into layers,and these layers exhibit two different orientations,displaying a rare 2D to 3D interpenetration mode.The zigzag chains in 2 are parallelly arranged.{[Zn_(3)(DPA)_(3)Br_(6)]·2DMF·_(1.5)H_(2)O}n(3)is isostructural to 2.3 was obtained using ZnBr_(2)instead of ZnCl_(2).[M(DPA)(formate)_(2)(H_(2)O)_(2)]n[M=Co(4),Cu(5)]are isostructural,contain chain structures formed by DPA,Cu^(2+)/Co^(2+),and for-mate ions,which were formed in situ in the solvothermal reaction.{[Zn(DIP)_(2)Cl]ClO_(4)}n(6)contains a layer structure formed by DIP and Zn^(2+).Free DPA and DIP ligands exhibited high fluorescence at room temperature,and coordina-tion polymers 3 and 6 displayed enhanced fluorescent emissions.
文摘Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions and 6-(3',4'-dicarboxylphenoxy)-1,2,4-benzenetricarboxylic acid(H_(5)L)in the presence of N-auxiliary ligands 1,10-phenanthroline(phen)and1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib).The structures of coordination polymers 1 and 2 were characterized by infrared spectroscopy,single-crystal X-ray diffraction,thermogravimetric analysis,and powder X-ray diffraction.Single-crystal X-ray diffraction reveals that 1 has a 1D chain structure based on binuclear Mn(Ⅱ)units,while 2 features a(3,8)-connected 3D network structure based on tetranuclear Mn(Ⅱ)units.Magnetic studies show that 1 and 2exhibit antiferromagnetic interactions between manganese ions.2 shows stronger antiferromagnetic interactions due to the shorter Mn…Mn distances within the tetranuclear manganese units.CCDC:2357601,1;2357602,2.
文摘Under the condition of solvothermal synthesis,the viologen ligand 1,1′-bis(3-carboxyphenyl)-(4,4′-bipyri-dine)dichloride(H_(2)bcbpy·2Cl)and KI are coordinated with the metal cadmium ions.A case of thermochromic coor-dination polymer[Cd(bcbpy)I_(2)]·2H_(2)O(1)was constructed.Complex 1 displays a 1D chain structure and exhibits thermochromic behavior.Under different temperature stimulation,the complex(ground)slowly changed from green to yellow-green,and with the increase of temperature,the color of complex 1 gradually deepened,and finally became orange-yellow.Therefore,complex 1 was prepared as a thermochromic film.In addition,we also performed electrochemical tests on complex 1,which showed that the complex is a semiconductor material.CCDC:2391802.
文摘We report five coordination polymers(CPs)based on fluorescent ligands[1,6-di(1H-imidazol-1-yl)pyrene(dip),9,10-di(1H-imidazol-1-yl)anthracene(dia)]and anionic ligands[cyclohexane-1,4-dicarboxylic acid(H_(2)cda),camphoric acid(H_(2)cpa)].In[Cd(dip)(cda)]·4H_(2)O}_(n)(1),the Cd^(2+)ions,acting as tetrahedral nodes,are linked by dipand cda^(2-)ligands with four Cd^(2+)ions into five-fold interpenetrating network array of topology of dia.In{[Cd(dip)(cpa)]·4H_(2)O}_(n)(2),the Cd^(2+)ions,acting as a 4-connector,are linked by cpa^(2-)and dip ligands into a 3D framework ofcds topology.In{[Ni(dia)_(2)Cl_(2)]·DMF}_(n)(3),the Ni^(2+)ion is linked by four dia ligands into a layer structure,and 1Dchannels of a cross-section of 1.35 nm×0.96 nm are formed.In{[Cd(dia)_(2)(H_(2)O)_(2)](NO_(3))_(2)·2DMSO}n(4),the dia ligandsconnected Cd^(2+)ions into a 2D layer,and 1D channels are formed between adjacent layers with a cross-section of0.87 nm×0.43 nm.In[Zn(dip)Cl_(2)]_(n)(5),the Zn^(2+)ion is linked by dip ligands into an infinite 1D chain.The infrared,thermal gravimetric,and fluorescent emission data were collected and analyzed for these coordination polymers.CCDC:2356055,1;2440075,2;2356057,3;2356057,4;2356059,5.
