As the development of new power systems accelerates and the impacts of high renewable energy integration and extreme weather intensify,grid-alternative energy storage is garnering increasing attention for its grid-int...As the development of new power systems accelerates and the impacts of high renewable energy integration and extreme weather intensify,grid-alternative energy storage is garnering increasing attention for its grid-interaction benefits and clear business models.Consequently,assessing the value of grid-alternative energy storage in the systemtransition has become critically important.Considering the performance characteristics of storage,we propose a value assessment frame-work for grid-alternative energy storage,quantifying its non-wires-alternative effects from both cost and benefit perspectives.Building on this,we developed a collaborative planning model for energy storage and transmission grids,aimed at maximizing the economic benefits of storage systems while balancing investment and operational costs.The model considers regional grid interconnections and their interactions with system operation.By participating in system operations,grid-alternative energy storage not only maximizes its own economic benefits but also generates social welfare transfer effects.Furthermore,based on multi-regional interconnected planning,grid-alternative energy storage can reduce system costs by approximately 35%,with the most significant changes observed in generation costs.Multi-regional coordinated planning significantly enhances the sys-tem’s flexibility in regulation.However,when the load factor of interconnection lines between regions remains constant,system operational flexibility tends to decrease,leading to a roughly 28.9%increase in storage investment.Additionally,under regional coordinated planning,the greater the disparity in wind power integration across interconnected regions,the more noticeable the reduction in system costs.展开更多
Redox-active organic compounds have received much attention as high-capacity electrodes for rechargeable batteries.However,the high solubility in organic electrolytes during charge and discharge processes hinders the ...Redox-active organic compounds have received much attention as high-capacity electrodes for rechargeable batteries.However,the high solubility in organic electrolytes during charge and discharge processes hinders the practical exploitation of organic compounds.This study presents a cobalt-based metal–organic coordination compound with bifunctional coordinated water(Co-MOC-H_(2)O)for sodium-ion storage.The coordinated water enhances interactions between sodium ions and nitrogen atoms in organic ligands through chelation,activating the inert sodium-ion storage sites(C=N).Moreover,the stable hydrogen bonded framework formed by the coordinated water molecules prevents the active organic compounds from dissolving into the electrolyte,thereby enhancing cycling stability.With the bifunctional coordinated water molecules,the Co-MOC-H_(2)O electrode delivers a high capacity of 403 mAh g^(-1)at 0.2 A g^(-1)over 600 cycles and exhibits a capacity retention of 77.9%at 2 A g^(-1)after 1100 cycles.This work highlights the crucial role of the coordinated water molecules in constructing high capacity and long-life sodium-ion storage materials.展开更多
The coordinated regional development strategy,recognized as one of China’s seven development strategies,plays a crucial role in reducing regional development disparities,optimizing resource allocation,and facilitatin...The coordinated regional development strategy,recognized as one of China’s seven development strategies,plays a crucial role in reducing regional development disparities,optimizing resource allocation,and facilitating high-quality development.This study analyzes a total of 418 relevant publications from China spanning the years 1998 to 2022.Utilizing CiteSpace software,a visualization analysis of keyword cooccurrence,mutation,and other bibliometric characteristics was conducted.The findings indicate that the number of publications during the specified period exhibited a fluctuating upward trend,with a notable increase observed after 2018.Furthermore,the research demonstrated a weak interdisciplinary crossover and a low intensity of collaboration among authors.The primary thematic areas of focus were identified as follows:connotation,mechanisms,countermeasure and suggestion,and evaluation.展开更多
This paper concerns the exponential attitude-orbit coordinated control problems for gravitational-wave detection formation spacecraft systems.Notably,the large-scale communication delays resulting from oversized inter...This paper concerns the exponential attitude-orbit coordinated control problems for gravitational-wave detection formation spacecraft systems.Notably,the large-scale communication delays resulting from oversized inter-satellite distance of space-based laser interferometers are first modeled.Subject to the delayed communication behaviors,a new delay-dependent attitude-orbit coordinated controller is designed.Moreover,by reconstructing the less conservative Lyapunov-Krasovskii functional and free-weight matrices,sufficient criteria are derived to ensure the exponential stability of the closed-loop relative translation and attitude error system.Finally,a simulation example is employed to illustrate the numerical validity of the proposed controller for in-orbit detection missions.展开更多
Ports,the core hub of global supply chains,serve as vital links in the economic and trade exchanges among countries.Efficient,safe,green and smart ports are essential for the smooth operation of global trade.Recently,...Ports,the core hub of global supply chains,serve as vital links in the economic and trade exchanges among countries.Efficient,safe,green and smart ports are essential for the smooth operation of global trade.Recently,ISO established ISO/TC 8/SC 27,Ports and terminals,the secretariat of which is held by China.This is a big breakthrough of China’s participation in the international standardization activities in the area of transportation.展开更多
Designing highly active electrocatalysts for the hydrogen evolution reaction(HER)and oxygen evolution and reduction reactions(OER and ORR)is pivotal to renewable energy technology.Herein,based on density functional th...Designing highly active electrocatalysts for the hydrogen evolution reaction(HER)and oxygen evolution and reduction reactions(OER and ORR)is pivotal to renewable energy technology.Herein,based on density functional theory(DFT)calculations,we systematically investigate the catalytic activity of iron-nitrogen-carbon based covalent organic frameworks(COF)monolayers with axially coordinated ligands(denotes as Fe N_(4)-X@COF,X refers to axial ligand,X=-SCN,-I,-H,-SH,-NO_(2),-Br,-ClO,-Cl,-HCO_(3),-NO,-ClO_(2),-OH,-CN and-F).The calculated results demonstrate that all the catalysts possess good thermodynamic and electrochemical stabilities.The different ligands axially ligated to the Fe active center could induce changes in the charge of the Fe center,which further regulates the interaction strength between intermediates and catalysts that governs the catalytic activity.Importantly,FeN_(4)-SH@COF and Fe N_(4)-OH@COF are efficient bifunctional catalysts for HER and OER,FeN_(4)-OH@COF and FeN_(4)-I@COF are promising bifunctional catalysts for OER and ORR.These findings not only reveal promising bifunctional HER/OER and OER/ORR catalysts but also provide theoretical guidance for designing optimum ironnitrogen-carbon based catalysts.展开更多
A group optimal penetration strategy in complex attack and defense confrontation situation is proposed in this paper to solve the coordinated penetration decision-making problem of endo-atmospheric gliding simultaneou...A group optimal penetration strategy in complex attack and defense confrontation situation is proposed in this paper to solve the coordinated penetration decision-making problem of endo-atmospheric gliding simultaneous multi-missile penetration of interceptors.First,the problem of large search space of multi-missile coordinated penetration maneuvers is fully considered,and the flight corridor of multi-missile coordinated penetration is designed to constrain search space of multi-agent coordinated strategy,comprehensively considering path constraints and anticollision constraints of gliding multi-missile flight.Then,a multi-missile hierarchical coordinated decision-making mechanism based on confrontation situation is proposed,and the swarm penetration strategy is optimized with the goal of maximizing swarm penetration effectiveness.The upper layer plans the swarm penetration formation according to confrontation situation,and generates the swarm coordinated penetration trajectory based on Multi-Agent Deep Deterministic Policy Gradient(MADDPG)method.The lower layer interpolates and smooths penetration trajectory,and generates the penetration guidance command based on Soft Actor-Critic and Extended Proportional Guidance(SAC-EPG)method.Simulation results verify that the proposed multi-missile cooperative penetration method based on hierarchical reinforcement learning converges faster than the penetration method based on MADDPG,and can quickly learn multi-missile cooperative penetration skills.In addition,multi-missile coordination can give full play to the group's detection and maneuverability,and occupy favorable penetration time and space through coordinated ballistic maneuvers.Thus the success rate of group penetration can be improved.展开更多
In this paper,a distributed Event-Triggered(ET)collision avoidance coordinated control for Quadrotor Unmanned Aerial Vehicles(QUAVs)is proposed based on Virtual Tubes(VTs)with flexible boundaries in the presence of un...In this paper,a distributed Event-Triggered(ET)collision avoidance coordinated control for Quadrotor Unmanned Aerial Vehicles(QUAVs)is proposed based on Virtual Tubes(VTs)with flexible boundaries in the presence of unknown external disturbances.Firstly,VTs are constructed for each QUAV,and the QUAV is restricted into the corresponding VT by the artificial potential field,which is distributed around the boundary of the VT.Thus,the collisions between QUAVs are avoided.Besides,the boundaries of the VTs are flexible by the modification signals,which are generated by the self-regulating auxiliary systems,to make the repulsive force smaller and give more buffer space for QUAVs without collision.Then,a novel ET mechanism is designed by introducing the concept of prediction to the traditional fixed threshold ET mechanism.Furthermore,a disturbance observer is proposed to deal with the adverse effects of the unknown external disturbance.On this basis,a distributed ET collision avoidance coordinated controller is proposed.Then,the proposed controller is quantized by the hysteresis uniform quantizer and then sent to the actuator only at the ET instants.The boundedness of the closed-loop signals is verified by the Lyapunov method.Finally,simulation and experimental results are performed to demonstrate the superiority of the proposed control method.展开更多
The disorganized lithium dendrites and unstable solid electrolyte interphase(SEI)severely impede the practical application of lithium metal batteries(LMBs).Herein,the N-Zn-F coordinated triazine-based covalent organic...The disorganized lithium dendrites and unstable solid electrolyte interphase(SEI)severely impede the practical application of lithium metal batteries(LMBs).Herein,the N-Zn-F coordinated triazine-based covalent organic framework(TTA-COF-ZnF_(2))is fabricated for the first time as an artificial SEI layer on the surface of lithium metal anodes(LMAs)to handle these issues.Zn-N coordination in onedimensional(1D)ordered COF can increase lithiophilic sites,reduce the Li-nucleation barrier,and regulate the Li+local coordination environment by optimizing surface charge density around the Zn metal.The electron-rich state induced by strong electron-withdrawing F-groups constructs electronegative nanochannels,which trigger efficient Li+desolvation.These beneficial attributes boost Li^(+)transfer,and homogenize Li^(+)flux,leading to uniform Li deposition.Besides,the lithiophilic triazine ring polar groups in TTA-COF-ZnF_(2)further facilitate the Li^(+)migration.The latent working mechanism of adjusting Li deposition behaviors and stabilizing LMAs for TTA-COF-ZnF_(2)is illustrated by detailed in-situ/ex-situ characterizations and density functional theory(DFT)calculations.As expected,TTA-COF-ZnF_(2)-modified Li|Cu half cells deliver a higher Coulombic efficiency(CE)of 98.4% over 250 cycles and lower nucleation overpotential(11 mV)at 1 mA cm^(-2),while TTA-COF-ZnF_(2)@Li symmetric cells display a long lifespan over3785 h at 2 mA cm^(-2).The TTA-COF-ZnF_(2)@Li|S full cells exert ultra high capacity retention of 81%(837 mA h g^(-1))after 600 cycles at 1C.Besides,the TTA-COF-ZnF_(2)@Li|LFP full cells with a high loading of 7.1 mg cm^(-2)exert ultrahigh capacity retention of 89%(108 mAh g^(-1))after 700 cycles at 5C.This synergistic strategy in N-Zn-F coordinated triazine-based COF provides a new insight to regulate the uniform platins/stripping behaviors for developing ultra-stable and dendrite-free LMBs.展开更多
The exploration of the coupling and coordination between urban innovation capability(IC)and industrial transformation(IF)serves as a novel perspective for interpreting the increasingly severe phenomenon of population ...The exploration of the coupling and coordination between urban innovation capability(IC)and industrial transformation(IF)serves as a novel perspective for interpreting the increasingly severe phenomenon of population shrinkage during the industrialization process.This study investigated the evolutionary characteristics of IC and IF in shrinking and growing cities in Northeast China from 2010 to 2020.It uses entropy weighted model,coupling coordination degree,the Dagum Gini coefficient,and geographic detectors to analyze the coordinated development of IC and IF in the context of population shrinkage.The study analyzed the spatiotemporal patterns and driving mechanisms for their coordinated development.The results show that:1)both urban IC and IF exhibited an overall positive trend during the study period.Shrinking cities depend more on IF to address the challenges of population shrinkage,while growing cities mainly rely on innovation-driven development.2)The coupling gap between IC and IF in shrinking and growing cities has widened over time,with the coordination level of shrinking cities steadily decreasing.Cities with serious disorder are concentrated in northern Heilongjiang Province,while most cities in Jilin Province experience moderate disorder.Liaoning Province,however,shows generally good coupling coordination.3)Human capital is the key factor driving coupling coordination in both types of cities.Shrinking cities rely on economic and financial development,with the‘repair-type’logic that emphasizes short-term economic growth and resource compensation.In contrast,the coupling of growing cities relies on basic support capabilities,with the‘optimization-type’logic focused on enhancing endogenous resilience and systemic coordination.Exploring the coordination between urban innovation capabilities and industrial transformation can provide a new perspective for research on population shrinkage,which holds certain theoretical and practical significance for implementing the new round of revitalization strategy in Northeast China.展开更多
Agricultural insurance plays a key role in promoting the coordinated development of green agriculture and farmers’income growth,which is crucial for China’s high-quality agricultural development.Using the coupling c...Agricultural insurance plays a key role in promoting the coordinated development of green agriculture and farmers’income growth,which is crucial for China’s high-quality agricultural development.Using the coupling coordination degree model,this study empirically demonstrates that the development of agricultural insurance significantly promotes the coordinated development of green agriculture and farmers’income growth once a certain threshold is exceeded.This effect is more pronounced in the major grain-producing regions and the central provinces.Expanding the scale of agricultural production and increasing investment in agricultural technology are the key mechanisms through which agricultural insurance supports the dual goals of green agriculture and income growth in China.In conclusion,this study proposes several policy recommendations,which include increasing investment in agricultural insurance infrastructure,strengthening the policy guidance for agricultural insurance,and designing differentiated agricultural insurance policies.展开更多
Four-electron oxygen evolving reaction is limited by proton adsorption and desorption,making its reaction kinetics sluggish,which poses a major challenge for catalyst design.Here,we present an unsaturated coordination...Four-electron oxygen evolving reaction is limited by proton adsorption and desorption,making its reaction kinetics sluggish,which poses a major challenge for catalyst design.Here,we present an unsaturated coordination interface by constructing a fast electron transfer channel between Cu_(2)V_(2)O_(7)(CVO)and BiVO4(BVO).X-ray absorption spectroscopy(XAS)and theoretical calculations results confirm that CVO and BVO between interfaces are bonded by the way of unsaturated coordination oxygen(Ouc).The Ouc optimizes the O-O coupled energy barrier at the V active site and promotes the disconnection of O-H bond,which increases the photocurrent intensity of CVO by 6 times.In addition,due to the high electronegativity of the Ouc,the bonding energies of Bi-O and Cu-O at the interface are enhanced,resulting in the long-term stability of the photoanode during the water splitting.Finally,by integrating the working electrode with a polysilicon solar cell,we assembled a device that demonstrated exceptional catalytic performance,achieving a hydrogen production rate of 100.6μmol·cm^(-2),and maintaining a hydrogen-to-oxygen volume ratio of 2:1 after continuous operation for 4 h.This discovery aids in a deeper understanding of photoanode design and offers further insights for industrial applications.展开更多
The coordinated control of PM_(2.5)and ozone has become the strategic goal of national air pollution control.Considering the gradual decline in PM_(2.5)concentration and the aggravation of ozone pollution,a better und...The coordinated control of PM_(2.5)and ozone has become the strategic goal of national air pollution control.Considering the gradual decline in PM_(2.5)concentration and the aggravation of ozone pollution,a better understanding of the coordinated control of PM_(2.5)and ozone is urgently needed.Here,we collected and sorted air pollutant data for 337 cities from 2015 to 2020 to explore the characteristics of PM_(2.5)and ozone pollution based on China’s five major air pollution regions.The results show that it is necessary to continue to strengthen the emission reduction in PM_(2.5)and ozone precursors,and control NO_(x) and VOCs while promoting a dramatic emission reduction in PM_(2.5).The primary method of curbing ozone pollution is to strengthen the emission control of VOCs,with a long-term strategy of achieving substantial emission reductions in NO_(x),because VOCs and NO_(x) are also precursors to PM_(2.5);hence,their reductions also contribute to the reduction in PM_(2.5).Therefore,the implementation of a multipollutant emission reduction control strategy aimed at the prevention and control of PM_(2.5)and ozone pollution is the only means to realize the coordinated control of PM_(2.5)and ozone.展开更多
Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was pr...Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was proposed for a wind-PVhydrogen-storage multi-agent energy system.First,a coordinated operation model was formulated for each agent considering peer-to-peer power trading.Second,a coordinated operation interactive framework for a multi-agent energy system was proposed based on the theory of the alternating direction method of multipliers.Third,a distributed interactive algorithm was proposed to protect the privacy of each agent and solve coordinated operation strategies.Finally,the effectiveness of the proposed coordinated operation method was tested on multi-agent energy systems with different structures,and the operational revenues of the wind power,PV,hydrogen,and energy storage agents of the proposed coordinated operation model were improved by approximately 59.19%,233.28%,16.75%,and 145.56%,respectively,compared with the independent operation model.展开更多
The operation efficiency of the manipulator is placed in the primary position in automatic production. This paper proposes a coordinated control strategy for joint servo and visual servo to enable timely transfer and ...The operation efficiency of the manipulator is placed in the primary position in automatic production. This paper proposes a coordinated control strategy for joint servo and visual servo to enable timely transfer and accurate gripping in the working area. Aiming at the issues of chattering and slow convergence of traditional sliding mode controller, a fast variable power reaching rate on the basis of the non-singular fast terminal sliding mode controller is proposed, which can effectively reduce the convergence time and chattering. For the purpose of addressing the problem that the traditional visual servo control method is sensitive to the environment, a visual servo controller based on integral sliding mode is proposed, to ensure the favorable positioning accuracy of the manipulator. Based on the two proposed controllers mentioned above, a coordinated control strategy is used to implement the control of the manipulator. Finally, the upper computer software is developed using the C# programming language to monitor the workstation. The feasibility of the above-mentioned method is verified through multiple simulations and experiments.展开更多
Multi-point array flexible tooling based on multilateration is widely used in the processing and manufacturing of complex curved surface parts. However, during the positioning of workpieces, the force exerted on each ...Multi-point array flexible tooling based on multilateration is widely used in the processing and manufacturing of complex curved surface parts. However, during the positioning of workpieces, the force exerted on each flexible support point is not uniform, and there exists force coupling between the support units. In response to the force coupling problem in the multi-point array positioning support process, a coordinated control method for the support force of multi-point array positioning combining correlation coefficient and regression analysis was proposed in this paper. The Spearman correlation coefficient was adopted in this method to study the force coupling correlation between positioning points, and a mathematical model of force coupling was established between positioning units through regression analysis, which can quickly and accurately perform coordinated control of the multilateration support system, and effectively improve the force interference of the multi-point array positioning support scene.展开更多
This paper primarily concerns the effective coordination of the procedures and methods employed in open pit mining operations under the background of river management.The central objective of this study is to identify...This paper primarily concerns the effective coordination of the procedures and methods employed in open pit mining operations under the background of river management.The central objective of this study is to identify a viable approach for ensuring rational and efficient development of open pit mineral resources while simultaneously protecting and restoring the ecological environment of the river.This approach should facilitate the realization of a harmonious symbiosis between mining and river management.The intricate mutual influence relationship between river management and open pit mining is first analyzed in depth,which provides a solid foundation for the subsequent coordination strategy development.In light of the aforementioned considerations,a set of coordination procedures for open pit mining based on river management conditions is proposed.These procedures emphasize the integration of river protection into the overall layout of mining at the planning stage.The implementation of scientific mining schemes,accompanied by rigorous control of the scope and depth of mining operations,has proven to be an effective means of reducing the impact of mining activities on river environments.This approach has also facilitated the achievement of a balance and coordination between mining and river management.展开更多
The architecture and working principle of coordinated search and rescue system of unmanned/manned aircraft,which is composed of manned/unmanned aircraft and manned aircraft,were first introduced,and they can cooperate...The architecture and working principle of coordinated search and rescue system of unmanned/manned aircraft,which is composed of manned/unmanned aircraft and manned aircraft,were first introduced,and they can cooperate with each other to complete a search and rescue task.Secondly,a threat assessment method based on meteorological data was proposed,and potential meteorological threats,such as storms and rainfall,can be predicted by collecting and analyzing meteorological data.Finally,an experiment was carried out to evaluate the performance of the proposed method in different scenarios.The experimental results show that the coordinated search and rescue system of unmanned/manned aircraft can be used to effectively assess meteorological threats and provide accurate search and rescue guidance.展开更多
With the rapid development of China’s economy,the coordinated development of resident income and GDP has become an important indicator to measure local economic development.How to realize the synergistic growth of th...With the rapid development of China’s economy,the coordinated development of resident income and GDP has become an important indicator to measure local economic development.How to realize the synergistic growth of the two in the new era is of great significance for promoting the sustainable development of the local economy.Based on the theory of the coordinated development of resident income and GDP,this paper will take Shandong Province as an example to analyze the interaction between resident income growth and GDP,find out the influencing factors that restrict the coordinated development of resident income and GDP,and explore the impact of the coordinated development of resident income and GDP on local economic development.Finally,relevant policies will be studied.How to effectively increase residents’income,promote the sustainable and healthy development of the local economy,and put forward relevant suggestions to promote the coordinated development of residents’income and GDP.展开更多
Accelerating green innovation is crucial for achieving high-quality development in China.Despite this importance,empirical evidence on the harmonization techniques in the context of carbon-trading policies has been re...Accelerating green innovation is crucial for achieving high-quality development in China.Despite this importance,empirical evidence on the harmonization techniques in the context of carbon-trading policies has been remarkably thin.To address this gap,we employed the difference-in-difference(DID)and spatial difference-in-difference(S-DID)models using panel data from 2007 to 2017 for 30 Chinese provinces.Our findings reveal that the carbon-trading policy contributes significantly to the coordinated advancement of green technologies across Chinese provinces and exhibits a local siphoning effect.Specifically,the pilot areas of the policy have attracted talent from neighboring regions,which has fostered local cooperation and promoted coordinated innovation in green technologies within the region.展开更多
基金funded by the Technology Project of State Grid Jibei Electric Power Supply Co.,Ltd.(Grant Number:52018F240001).
文摘As the development of new power systems accelerates and the impacts of high renewable energy integration and extreme weather intensify,grid-alternative energy storage is garnering increasing attention for its grid-interaction benefits and clear business models.Consequently,assessing the value of grid-alternative energy storage in the systemtransition has become critically important.Considering the performance characteristics of storage,we propose a value assessment frame-work for grid-alternative energy storage,quantifying its non-wires-alternative effects from both cost and benefit perspectives.Building on this,we developed a collaborative planning model for energy storage and transmission grids,aimed at maximizing the economic benefits of storage systems while balancing investment and operational costs.The model considers regional grid interconnections and their interactions with system operation.By participating in system operations,grid-alternative energy storage not only maximizes its own economic benefits but also generates social welfare transfer effects.Furthermore,based on multi-regional interconnected planning,grid-alternative energy storage can reduce system costs by approximately 35%,with the most significant changes observed in generation costs.Multi-regional coordinated planning significantly enhances the sys-tem’s flexibility in regulation.However,when the load factor of interconnection lines between regions remains constant,system operational flexibility tends to decrease,leading to a roughly 28.9%increase in storage investment.Additionally,under regional coordinated planning,the greater the disparity in wind power integration across interconnected regions,the more noticeable the reduction in system costs.
基金supported by the National Natural Science Foundation of China(22121005,92372203,92372001,52072186,and 52301278)the National Key Research and Development Program of China(2022YFB2402200)+3 种基金the Science and Technology Plans of Tianjin(23JCYBJC00170)the Fundamental Research Funds for the Central Universities,Nankai University(63241206 and 9242000710)Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering(JDSX2023003)the Natural Science Foundation of Jiangsu Province(BK20230937).
文摘Redox-active organic compounds have received much attention as high-capacity electrodes for rechargeable batteries.However,the high solubility in organic electrolytes during charge and discharge processes hinders the practical exploitation of organic compounds.This study presents a cobalt-based metal–organic coordination compound with bifunctional coordinated water(Co-MOC-H_(2)O)for sodium-ion storage.The coordinated water enhances interactions between sodium ions and nitrogen atoms in organic ligands through chelation,activating the inert sodium-ion storage sites(C=N).Moreover,the stable hydrogen bonded framework formed by the coordinated water molecules prevents the active organic compounds from dissolving into the electrolyte,thereby enhancing cycling stability.With the bifunctional coordinated water molecules,the Co-MOC-H_(2)O electrode delivers a high capacity of 403 mAh g^(-1)at 0.2 A g^(-1)over 600 cycles and exhibits a capacity retention of 77.9%at 2 A g^(-1)after 1100 cycles.This work highlights the crucial role of the coordinated water molecules in constructing high capacity and long-life sodium-ion storage materials.
文摘The coordinated regional development strategy,recognized as one of China’s seven development strategies,plays a crucial role in reducing regional development disparities,optimizing resource allocation,and facilitating high-quality development.This study analyzes a total of 418 relevant publications from China spanning the years 1998 to 2022.Utilizing CiteSpace software,a visualization analysis of keyword cooccurrence,mutation,and other bibliometric characteristics was conducted.The findings indicate that the number of publications during the specified period exhibited a fluctuating upward trend,with a notable increase observed after 2018.Furthermore,the research demonstrated a weak interdisciplinary crossover and a low intensity of collaboration among authors.The primary thematic areas of focus were identified as follows:connotation,mechanisms,countermeasure and suggestion,and evaluation.
基金supported by the Na⁃tional Key R&D Program of China(No.2022YFC2204800)the Graduate Student Independent Exploration and Innovation Program of Central South University(No.2024ZZTS 0767).
文摘This paper concerns the exponential attitude-orbit coordinated control problems for gravitational-wave detection formation spacecraft systems.Notably,the large-scale communication delays resulting from oversized inter-satellite distance of space-based laser interferometers are first modeled.Subject to the delayed communication behaviors,a new delay-dependent attitude-orbit coordinated controller is designed.Moreover,by reconstructing the less conservative Lyapunov-Krasovskii functional and free-weight matrices,sufficient criteria are derived to ensure the exponential stability of the closed-loop relative translation and attitude error system.Finally,a simulation example is employed to illustrate the numerical validity of the proposed controller for in-orbit detection missions.
文摘Ports,the core hub of global supply chains,serve as vital links in the economic and trade exchanges among countries.Efficient,safe,green and smart ports are essential for the smooth operation of global trade.Recently,ISO established ISO/TC 8/SC 27,Ports and terminals,the secretariat of which is held by China.This is a big breakthrough of China’s participation in the international standardization activities in the area of transportation.
基金supported by the National Natural Science Foundation of China(Nos.22102167 and U21A20317)。
文摘Designing highly active electrocatalysts for the hydrogen evolution reaction(HER)and oxygen evolution and reduction reactions(OER and ORR)is pivotal to renewable energy technology.Herein,based on density functional theory(DFT)calculations,we systematically investigate the catalytic activity of iron-nitrogen-carbon based covalent organic frameworks(COF)monolayers with axially coordinated ligands(denotes as Fe N_(4)-X@COF,X refers to axial ligand,X=-SCN,-I,-H,-SH,-NO_(2),-Br,-ClO,-Cl,-HCO_(3),-NO,-ClO_(2),-OH,-CN and-F).The calculated results demonstrate that all the catalysts possess good thermodynamic and electrochemical stabilities.The different ligands axially ligated to the Fe active center could induce changes in the charge of the Fe center,which further regulates the interaction strength between intermediates and catalysts that governs the catalytic activity.Importantly,FeN_(4)-SH@COF and Fe N_(4)-OH@COF are efficient bifunctional catalysts for HER and OER,FeN_(4)-OH@COF and FeN_(4)-I@COF are promising bifunctional catalysts for OER and ORR.These findings not only reveal promising bifunctional HER/OER and OER/ORR catalysts but also provide theoretical guidance for designing optimum ironnitrogen-carbon based catalysts.
文摘A group optimal penetration strategy in complex attack and defense confrontation situation is proposed in this paper to solve the coordinated penetration decision-making problem of endo-atmospheric gliding simultaneous multi-missile penetration of interceptors.First,the problem of large search space of multi-missile coordinated penetration maneuvers is fully considered,and the flight corridor of multi-missile coordinated penetration is designed to constrain search space of multi-agent coordinated strategy,comprehensively considering path constraints and anticollision constraints of gliding multi-missile flight.Then,a multi-missile hierarchical coordinated decision-making mechanism based on confrontation situation is proposed,and the swarm penetration strategy is optimized with the goal of maximizing swarm penetration effectiveness.The upper layer plans the swarm penetration formation according to confrontation situation,and generates the swarm coordinated penetration trajectory based on Multi-Agent Deep Deterministic Policy Gradient(MADDPG)method.The lower layer interpolates and smooths penetration trajectory,and generates the penetration guidance command based on Soft Actor-Critic and Extended Proportional Guidance(SAC-EPG)method.Simulation results verify that the proposed multi-missile cooperative penetration method based on hierarchical reinforcement learning converges faster than the penetration method based on MADDPG,and can quickly learn multi-missile cooperative penetration skills.In addition,multi-missile coordination can give full play to the group's detection and maneuverability,and occupy favorable penetration time and space through coordinated ballistic maneuvers.Thus the success rate of group penetration can be improved.
基金supported in part by the National Key R&D Program of China(No.2023YFB4704400)in part by the National Natural Science Foundation of China(Nos.U23B2036,U2013201).
文摘In this paper,a distributed Event-Triggered(ET)collision avoidance coordinated control for Quadrotor Unmanned Aerial Vehicles(QUAVs)is proposed based on Virtual Tubes(VTs)with flexible boundaries in the presence of unknown external disturbances.Firstly,VTs are constructed for each QUAV,and the QUAV is restricted into the corresponding VT by the artificial potential field,which is distributed around the boundary of the VT.Thus,the collisions between QUAVs are avoided.Besides,the boundaries of the VTs are flexible by the modification signals,which are generated by the self-regulating auxiliary systems,to make the repulsive force smaller and give more buffer space for QUAVs without collision.Then,a novel ET mechanism is designed by introducing the concept of prediction to the traditional fixed threshold ET mechanism.Furthermore,a disturbance observer is proposed to deal with the adverse effects of the unknown external disturbance.On this basis,a distributed ET collision avoidance coordinated controller is proposed.Then,the proposed controller is quantized by the hysteresis uniform quantizer and then sent to the actuator only at the ET instants.The boundedness of the closed-loop signals is verified by the Lyapunov method.Finally,simulation and experimental results are performed to demonstrate the superiority of the proposed control method.
基金financially supported by the National Natural Science Foundation of China(52472093,52176185)the Department of Science and Technology of Hubei Province of China(2022CFA069,2022BAA086)。
文摘The disorganized lithium dendrites and unstable solid electrolyte interphase(SEI)severely impede the practical application of lithium metal batteries(LMBs).Herein,the N-Zn-F coordinated triazine-based covalent organic framework(TTA-COF-ZnF_(2))is fabricated for the first time as an artificial SEI layer on the surface of lithium metal anodes(LMAs)to handle these issues.Zn-N coordination in onedimensional(1D)ordered COF can increase lithiophilic sites,reduce the Li-nucleation barrier,and regulate the Li+local coordination environment by optimizing surface charge density around the Zn metal.The electron-rich state induced by strong electron-withdrawing F-groups constructs electronegative nanochannels,which trigger efficient Li+desolvation.These beneficial attributes boost Li^(+)transfer,and homogenize Li^(+)flux,leading to uniform Li deposition.Besides,the lithiophilic triazine ring polar groups in TTA-COF-ZnF_(2)further facilitate the Li^(+)migration.The latent working mechanism of adjusting Li deposition behaviors and stabilizing LMAs for TTA-COF-ZnF_(2)is illustrated by detailed in-situ/ex-situ characterizations and density functional theory(DFT)calculations.As expected,TTA-COF-ZnF_(2)-modified Li|Cu half cells deliver a higher Coulombic efficiency(CE)of 98.4% over 250 cycles and lower nucleation overpotential(11 mV)at 1 mA cm^(-2),while TTA-COF-ZnF_(2)@Li symmetric cells display a long lifespan over3785 h at 2 mA cm^(-2).The TTA-COF-ZnF_(2)@Li|S full cells exert ultra high capacity retention of 81%(837 mA h g^(-1))after 600 cycles at 1C.Besides,the TTA-COF-ZnF_(2)@Li|LFP full cells with a high loading of 7.1 mg cm^(-2)exert ultrahigh capacity retention of 89%(108 mAh g^(-1))after 700 cycles at 5C.This synergistic strategy in N-Zn-F coordinated triazine-based COF provides a new insight to regulate the uniform platins/stripping behaviors for developing ultra-stable and dendrite-free LMBs.
基金Under the auspices of National Natural Science Foundation of China(No.42471227,42171198)。
文摘The exploration of the coupling and coordination between urban innovation capability(IC)and industrial transformation(IF)serves as a novel perspective for interpreting the increasingly severe phenomenon of population shrinkage during the industrialization process.This study investigated the evolutionary characteristics of IC and IF in shrinking and growing cities in Northeast China from 2010 to 2020.It uses entropy weighted model,coupling coordination degree,the Dagum Gini coefficient,and geographic detectors to analyze the coordinated development of IC and IF in the context of population shrinkage.The study analyzed the spatiotemporal patterns and driving mechanisms for their coordinated development.The results show that:1)both urban IC and IF exhibited an overall positive trend during the study period.Shrinking cities depend more on IF to address the challenges of population shrinkage,while growing cities mainly rely on innovation-driven development.2)The coupling gap between IC and IF in shrinking and growing cities has widened over time,with the coordination level of shrinking cities steadily decreasing.Cities with serious disorder are concentrated in northern Heilongjiang Province,while most cities in Jilin Province experience moderate disorder.Liaoning Province,however,shows generally good coupling coordination.3)Human capital is the key factor driving coupling coordination in both types of cities.Shrinking cities rely on economic and financial development,with the‘repair-type’logic that emphasizes short-term economic growth and resource compensation.In contrast,the coupling of growing cities relies on basic support capabilities,with the‘optimization-type’logic focused on enhancing endogenous resilience and systemic coordination.Exploring the coordination between urban innovation capabilities and industrial transformation can provide a new perspective for research on population shrinkage,which holds certain theoretical and practical significance for implementing the new round of revitalization strategy in Northeast China.
基金This paper presents preliminary research findings from two projects:a major project funded by the National Social Science Fund of China,titled“Changes in the Nature of Rural Poverty in China in the New Era and Research on Post-2020 Anti-Poverty Policies”(Project No:19ZDA116)Doctoral Research Project under the Special Program for Talents in Shortage Areas Serving National Needs,Nanjing University of Finance and Economics,titled“The Impact of Policy-Based Agricultural Insurance on Farmers’Income and Welfare Levels”(Project No:BSZX2021-12).
文摘Agricultural insurance plays a key role in promoting the coordinated development of green agriculture and farmers’income growth,which is crucial for China’s high-quality agricultural development.Using the coupling coordination degree model,this study empirically demonstrates that the development of agricultural insurance significantly promotes the coordinated development of green agriculture and farmers’income growth once a certain threshold is exceeded.This effect is more pronounced in the major grain-producing regions and the central provinces.Expanding the scale of agricultural production and increasing investment in agricultural technology are the key mechanisms through which agricultural insurance supports the dual goals of green agriculture and income growth in China.In conclusion,this study proposes several policy recommendations,which include increasing investment in agricultural insurance infrastructure,strengthening the policy guidance for agricultural insurance,and designing differentiated agricultural insurance policies.
基金supported by the Natural Science Foundation of China(Nos.22278094 and 22379033)Guangdong Graduate Education Innovation Program(No.2023JGXM_102)+2 种基金the Basic and Applied Basic Research Program of Guangzhou(No.SL2024A03J00499)the University Innovation Team Scientific Research Project of Guangzhou(No.202235246)Hainan Province Graduate Innovation Research Project(No.Qhyb2023-143).
文摘Four-electron oxygen evolving reaction is limited by proton adsorption and desorption,making its reaction kinetics sluggish,which poses a major challenge for catalyst design.Here,we present an unsaturated coordination interface by constructing a fast electron transfer channel between Cu_(2)V_(2)O_(7)(CVO)and BiVO4(BVO).X-ray absorption spectroscopy(XAS)and theoretical calculations results confirm that CVO and BVO between interfaces are bonded by the way of unsaturated coordination oxygen(Ouc).The Ouc optimizes the O-O coupled energy barrier at the V active site and promotes the disconnection of O-H bond,which increases the photocurrent intensity of CVO by 6 times.In addition,due to the high electronegativity of the Ouc,the bonding energies of Bi-O and Cu-O at the interface are enhanced,resulting in the long-term stability of the photoanode during the water splitting.Finally,by integrating the working electrode with a polysilicon solar cell,we assembled a device that demonstrated exceptional catalytic performance,achieving a hydrogen production rate of 100.6μmol·cm^(-2),and maintaining a hydrogen-to-oxygen volume ratio of 2:1 after continuous operation for 4 h.This discovery aids in a deeper understanding of photoanode design and offers further insights for industrial applications.
基金supported by the National Natural Science Foundation of China(No.91844301)by the Beijing Municipal Natural Science Fund(No.JQ21030)。
文摘The coordinated control of PM_(2.5)and ozone has become the strategic goal of national air pollution control.Considering the gradual decline in PM_(2.5)concentration and the aggravation of ozone pollution,a better understanding of the coordinated control of PM_(2.5)and ozone is urgently needed.Here,we collected and sorted air pollutant data for 337 cities from 2015 to 2020 to explore the characteristics of PM_(2.5)and ozone pollution based on China’s five major air pollution regions.The results show that it is necessary to continue to strengthen the emission reduction in PM_(2.5)and ozone precursors,and control NO_(x) and VOCs while promoting a dramatic emission reduction in PM_(2.5).The primary method of curbing ozone pollution is to strengthen the emission control of VOCs,with a long-term strategy of achieving substantial emission reductions in NO_(x),because VOCs and NO_(x) are also precursors to PM_(2.5);hence,their reductions also contribute to the reduction in PM_(2.5).Therefore,the implementation of a multipollutant emission reduction control strategy aimed at the prevention and control of PM_(2.5)and ozone pollution is the only means to realize the coordinated control of PM_(2.5)and ozone.
基金supported by the Key Research and Development Program of Jiangsu Provincial Department of Science and Technology(BE2020081).
文摘Wind-photovoltaic(PV)-hydrogen-storage multi-agent energy systems are expected to play an important role in promoting renewable power utilization and decarbonization.In this study,a coordinated operation method was proposed for a wind-PVhydrogen-storage multi-agent energy system.First,a coordinated operation model was formulated for each agent considering peer-to-peer power trading.Second,a coordinated operation interactive framework for a multi-agent energy system was proposed based on the theory of the alternating direction method of multipliers.Third,a distributed interactive algorithm was proposed to protect the privacy of each agent and solve coordinated operation strategies.Finally,the effectiveness of the proposed coordinated operation method was tested on multi-agent energy systems with different structures,and the operational revenues of the wind power,PV,hydrogen,and energy storage agents of the proposed coordinated operation model were improved by approximately 59.19%,233.28%,16.75%,and 145.56%,respectively,compared with the independent operation model.
基金supported by the National Natural Science Foundation of China(No.62273189)the Natural Science Foundation of Shandong Province(No.ZR2021MF005).
文摘The operation efficiency of the manipulator is placed in the primary position in automatic production. This paper proposes a coordinated control strategy for joint servo and visual servo to enable timely transfer and accurate gripping in the working area. Aiming at the issues of chattering and slow convergence of traditional sliding mode controller, a fast variable power reaching rate on the basis of the non-singular fast terminal sliding mode controller is proposed, which can effectively reduce the convergence time and chattering. For the purpose of addressing the problem that the traditional visual servo control method is sensitive to the environment, a visual servo controller based on integral sliding mode is proposed, to ensure the favorable positioning accuracy of the manipulator. Based on the two proposed controllers mentioned above, a coordinated control strategy is used to implement the control of the manipulator. Finally, the upper computer software is developed using the C# programming language to monitor the workstation. The feasibility of the above-mentioned method is verified through multiple simulations and experiments.
基金Sponsored by the Program of Shanghai Academic/Technology Research Leader (Grant No. 21XD1431200)。
文摘Multi-point array flexible tooling based on multilateration is widely used in the processing and manufacturing of complex curved surface parts. However, during the positioning of workpieces, the force exerted on each flexible support point is not uniform, and there exists force coupling between the support units. In response to the force coupling problem in the multi-point array positioning support process, a coordinated control method for the support force of multi-point array positioning combining correlation coefficient and regression analysis was proposed in this paper. The Spearman correlation coefficient was adopted in this method to study the force coupling correlation between positioning points, and a mathematical model of force coupling was established between positioning units through regression analysis, which can quickly and accurately perform coordinated control of the multilateration support system, and effectively improve the force interference of the multi-point array positioning support scene.
文摘This paper primarily concerns the effective coordination of the procedures and methods employed in open pit mining operations under the background of river management.The central objective of this study is to identify a viable approach for ensuring rational and efficient development of open pit mineral resources while simultaneously protecting and restoring the ecological environment of the river.This approach should facilitate the realization of a harmonious symbiosis between mining and river management.The intricate mutual influence relationship between river management and open pit mining is first analyzed in depth,which provides a solid foundation for the subsequent coordination strategy development.In light of the aforementioned considerations,a set of coordination procedures for open pit mining based on river management conditions is proposed.These procedures emphasize the integration of river protection into the overall layout of mining at the planning stage.The implementation of scientific mining schemes,accompanied by rigorous control of the scope and depth of mining operations,has proven to be an effective means of reducing the impact of mining activities on river environments.This approach has also facilitated the achievement of a balance and coordination between mining and river management.
基金the Study on the Impact of the Construction and Development of Southwest Plateau Airport on the Ecological Environment(CZKY2023032).
文摘The architecture and working principle of coordinated search and rescue system of unmanned/manned aircraft,which is composed of manned/unmanned aircraft and manned aircraft,were first introduced,and they can cooperate with each other to complete a search and rescue task.Secondly,a threat assessment method based on meteorological data was proposed,and potential meteorological threats,such as storms and rainfall,can be predicted by collecting and analyzing meteorological data.Finally,an experiment was carried out to evaluate the performance of the proposed method in different scenarios.The experimental results show that the coordinated search and rescue system of unmanned/manned aircraft can be used to effectively assess meteorological threats and provide accurate search and rescue guidance.
文摘With the rapid development of China’s economy,the coordinated development of resident income and GDP has become an important indicator to measure local economic development.How to realize the synergistic growth of the two in the new era is of great significance for promoting the sustainable development of the local economy.Based on the theory of the coordinated development of resident income and GDP,this paper will take Shandong Province as an example to analyze the interaction between resident income growth and GDP,find out the influencing factors that restrict the coordinated development of resident income and GDP,and explore the impact of the coordinated development of resident income and GDP on local economic development.Finally,relevant policies will be studied.How to effectively increase residents’income,promote the sustainable and healthy development of the local economy,and put forward relevant suggestions to promote the coordinated development of residents’income and GDP.
基金National Social Science Foundation of China(Grant No.:23BJL108).
文摘Accelerating green innovation is crucial for achieving high-quality development in China.Despite this importance,empirical evidence on the harmonization techniques in the context of carbon-trading policies has been remarkably thin.To address this gap,we employed the difference-in-difference(DID)and spatial difference-in-difference(S-DID)models using panel data from 2007 to 2017 for 30 Chinese provinces.Our findings reveal that the carbon-trading policy contributes significantly to the coordinated advancement of green technologies across Chinese provinces and exhibits a local siphoning effect.Specifically,the pilot areas of the policy have attracted talent from neighboring regions,which has fostered local cooperation and promoted coordinated innovation in green technologies within the region.
