East Africa’s construction boom draws Chinese heavy machinery manufacturers and distributors The booming construction of new housing and commercial units has led to unprecedented demand for heavy construction equipme...East Africa’s construction boom draws Chinese heavy machinery manufacturers and distributors The booming construction of new housing and commercial units has led to unprecedented demand for heavy construction equipment in Nairobi,Kenya.展开更多
At the World Economic Forum Annual Meeting 2026 in Davos,China emerged as a steadfast advocate for multilateral cooperation and constructive dialogue,presenting a clear alternative to divisive rhetoric.CHINA’S role a...At the World Economic Forum Annual Meeting 2026 in Davos,China emerged as a steadfast advocate for multilateral cooperation and constructive dialogue,presenting a clear alternative to divisive rhetoric.CHINA’S role as a key player in shaping global development and trends stood out at the World Economic Forum(WEF)annual meeting 2026 in Davos,Switzerland.展开更多
[Objectives]To explore the control mode of farmland drainage pollutants and investigate the effects of ecological ditch and wetland on reducing farmland drainage pollutants in Hetao Irrigation District.[Methods]Based ...[Objectives]To explore the control mode of farmland drainage pollutants and investigate the effects of ecological ditch and wetland on reducing farmland drainage pollutants in Hetao Irrigation District.[Methods]Based on the demonstration construction project of the ecological ditch-constructed wetland system in the Hetao Irrigation District,an experimental study was conducted from July to September 2023 to investigate the interception and purification effects of ecological ditches,constructed wetlands,and the combined ecological ditch-constructed wetland system on farmland drainage pollutants.Key water quality parameters measured included total nitrogen(TN)concentration and total phosphorus(TP)concentration.[Results]Different treatment modes of ecological ditches and constructed wetlands have a certain removal effect on nitrogen and phosphorus pollutants in water bodies.The ecological ditches treated with Astragalus laxmannii,Melilotus officinalis,Medicago sativa,bio-ball substrate,and bio-sheet substrate showed reduction efficiencies for TN and TP of 21.09% and 23.84%,12.06% and 26.67%,20.08% and 34.15%,23.65% and 20.56%,and 19.92% and 25.83%,respectively.The emergent plant area showed reduction efficiencies of 24.28%for TN and 17.89%for TP,while the submerged plant area achieved a reduction efficiency of 10.21%for both TN and TP.Among the different treatment modes,the ecological ditch with M.sativa performed better in TP removal,whereas the bio-ball substrate treatment mode showed higher effectiveness in TN removal.In addition,the emergent plant area exhibited better TP removal performance,while the submerged plant area was more effective in TN removal.The combined system of ecological ditch and constructed wetland achieved removal rates of 37.55% for TN and 11.47% for TP.It effectively facilitates the step-by-step interception and adsorption purification of pollutants,thereby showing significant removal and purification effects on nitrogen and phosphorus contaminants.This contributes to mitigating agricultural non-point source pollution.[Conclusions]The combined ecological ditch-constructed wetland system serves dual functions of agricultural drainage and pollutant interception and purification.It reduces the pollution load of farmland drainage on receiving water bodies to some extent and mitigates agricultural non-point source pollution.Therefore,it is a relatively suitable technology for managing agricultural non-point source pollution in the Hetao Irrigation District.展开更多
Fluorinated motifs are prevalent in both pharmaceuticals and agrochemicals.The incorporation of fluorine-containing moieties to drug candidates has emerged as a potent strategy for lead optimization in pharmaceutical ...Fluorinated motifs are prevalent in both pharmaceuticals and agrochemicals.The incorporation of fluorine-containing moieties to drug candidates has emerged as a potent strategy for lead optimization in pharmaceutical research and development.While extensive research has been devoted to constructing molecules that incorporate a trifluoromethylthio(SCF_(3)−)group on a stereogenic carbon,the synthesis of trifluoromethylthiolated alkanes featuring a SCF_(3)-substituted stereogenic carbon at non-activated site remains understudied.Herein,we report a Cu-catalyzed regio-and enantioselective hydroallylation of 1-trifluoromethylthiolated alkenes.Important to the process is the regio-and enantioselective Cu-H insertion to SCF_(3)-substituted alkene to form chiralα-SCF_(3) alkyl copper intermediates,outcompeting unproductive insertion to the coupling partner,and eventually proceed to afford optically active homoallylic trifluoromethylthiolated products.展开更多
The historical image of Ouyang Xiu constructed during the Song Dynasty evolved from a multifaceted portrayal that balanced his political and literary achievements into a singular cultural symbol.In the Northern Song D...The historical image of Ouyang Xiu constructed during the Song Dynasty evolved from a multifaceted portrayal that balanced his political and literary achievements into a singular cultural symbol.In the Northern Song Dynasty,writings by Ouyang Xiu's family and epitaphs by his colleagues crafted a balanced narrative emphasizing both his official duties and literary merits,thus constructing a dual image of him as a principled remonstrator and a literary master.In the Southern Song Dynasty,official historiography gradually eroded his complex persona as a political reformer by selectively trimming political disputes and emphasizing his literary lineage,ultimately establishing him as a cultural exemplar beyond factional strife.Throughout this evolution of historical writing,Ouyang Xiu's sharpness as a remonstrator was gradually obscured in historical texts,while his image as a literary master,revered by all,became firmly established.The reshaping of Ouyang Xiu's image in historical writings across the Northern and Southern Song dynasties not only reflects the logic of selecting scholar-official role models under the influence of official ideology but also reveals the inherent pattern whereby individual distinctiveness fades into symbolic construction in historical writing.展开更多
As blockchain technology rapidly evolves,smart contracts have seen widespread adoption in financial transactions and beyond.However,the growing prevalence of malicious Ponzi scheme contracts presents serious security ...As blockchain technology rapidly evolves,smart contracts have seen widespread adoption in financial transactions and beyond.However,the growing prevalence of malicious Ponzi scheme contracts presents serious security threats to blockchain ecosystems.Although numerous detection techniques have been proposed,existing methods suffer from significant limitations,such as class imbalance and insufficient modeling of transaction-related semantic features.To address these challenges,this paper proposes an oversampling-based detection framework for Ponzi smart contracts.We enhance the Adaptive Synthetic Sampling(ADASYN)algorithm by incorporating sample proximity to decision boundaries and ensuring realistic sample distributions.This enhancement facilitates the generation of high-quality minority class samples and effectively mitigates class imbalance.In addition,we design a Contract Transaction Graph(CTG)construction algorithm to preserve key transactional semantics through feature extraction from contract code.A graph neural network(GNN)is then applied for classification.This study employs a publicly available dataset from the XBlock platform,consisting of 318 verified Ponzi contracts and 6498 benign contracts.Sourced from real Ethereum deployments,the dataset reflects diverse application scenarios and captures the varied characteristics of Ponzi schemes.Experimental results demonstrate that our approach achieves an accuracy of 96%,a recall of 92%,and an F1-score of 94%in detecting Ponzi contracts,outperforming state-of-the-art methods.展开更多
Against the backdrop of continuous social development and growing public health demands,the efficiency and scientific nature of the emergency care system are of paramount importance.This paper focuses on researching t...Against the backdrop of continuous social development and growing public health demands,the efficiency and scientific nature of the emergency care system are of paramount importance.This paper focuses on researching the construction of an emergency care system based on the concept of“linkage”,delving into its theoretical foundations,exploring innovative construction models,and analyzing practical cases.The study indicates that an emergency care system under the“linkage”concept can effectively integrate resources and enhance efficiency,providing new insights for improving the construction of the emergency care system.It aims to promote the development of the emergency care system towards a more scientific,efficient,and collaborative direction.展开更多
The distinctive landscape of Zhujiayu Ancient Village in Zhangqiu District,Ji’nan,together with its long-established cultural traditions,has shaped a unique vernacular settlement character,within which traditional dw...The distinctive landscape of Zhujiayu Ancient Village in Zhangqiu District,Ji’nan,together with its long-established cultural traditions,has shaped a unique vernacular settlement character,within which traditional dwellings serve as a primary medium of regional culture.This study examines the residence of Zhu Fengyin,a jinshi degree holder,and adopts field investigation and measured drawing-based analysis.Discussion is organized around three dimensions:an overview of the dwelling,architectural form,and cultural expression.Particular attention is given to the multi-stage,multi-bay compound configuration developed in a mountainous setting,terrain-adaptive courtyard forms,and construction techniques.The analysis further interprets the concepts of ritual order and auspicious symbolism embedded in architectural decoration.By using this representative case,the study aims to deepen understanding of the architectural culture of gentry dwellings in the Ji’nan region and to provide an academic basis for the conservation and inheritance of traditional dwellings in the Ji’nan area.展开更多
Long-life pavement has been introduced to address the urgent need for durable and reliable transportation infrastructure.This review overviews the development of aggregates for long-life pavements and summarizes futur...Long-life pavement has been introduced to address the urgent need for durable and reliable transportation infrastructure.This review overviews the development of aggregates for long-life pavements and summarizes future research directions.The review indicates that natural aggregates,being non-renewable resources,are steadily declining in availability and may need to meet future demands.Construction solid waste aggregates are rapidly developing,with fine separation of reclaimed asphalt pavement(RAP)and reinforcement of cementbased recycled aggregates serving as key strategies to enhance their application.Industry solid waste aggregates possess properties suitable for long-life pavements and offer additional functionalities such as cooling,conductivity,and reflectivity,demonstrating significant development potential.While artificial aggregates exhibit superior performance,their large-scale application requires consideration of economic and environmental impacts.Current aggregate evaluation methods need to address the needs of long-life pavements.Aggregate performance requirements should be graded based on mechanical stress and temperature distribution,with corresponding evaluation methods and indices developed.Evaluating the mechanical properties of aggregates should align more closely with actual stress states.Tests such as triaxial,repeated load,and wheel abrasion polishing are better suited for assessing the strength and durability of long-life pavement aggregates.Similarly,evaluating aggregates'physicochemical properties should be based on studies correlating these properties with road performance,with proposed evaluation criteria.Morphological characteristics of aggregates significantly influence asphalt mixture performance,and efficient evaluation of their profile,angularity,and texture will be a key focus of future research.展开更多
This study investigated the impact of the xu-argument-based continuation on Chinese high school students’English syntactic complexity captured using verb-argument constructions(VACs)over an 8-week period.Participants...This study investigated the impact of the xu-argument-based continuation on Chinese high school students’English syntactic complexity captured using verb-argument constructions(VACs)over an 8-week period.Participants were two comparable groups of students:one group worked with English input texts(i.e.,E-E),while the other worked with Chinese input texts with the same content(i.e.,C-E).The results showed that over time,the E-E group exhibited a greater tendency to use a wider range of VACs,such as caused-motion constructions,attributives,passives,and phrasal verbs.At the same time,they reduced their use of simpler VACs like intransitive-motion and simple transitive constructions,especially when compared to the C-E group.This pattern was also evident in the topic-based writing during the posttest.These findings strongly support the effectiveness of xu-argument-based continuation tasks in promoting the development of L2 VAC knowledge.They suggest that tasks combining language input with output can significantly enhance learners’ability to use more sophisticated VACs.展开更多
To advance intelligent construction,standards must come first.The Ministry of Housing and Urban-Rural Development has issued the List for Replicable Experience and Practices for Developing Intelligent Construction fou...To advance intelligent construction,standards must come first.The Ministry of Housing and Urban-Rural Development has issued the List for Replicable Experience and Practices for Developing Intelligent Construction four times successively and the Technical Guidelines for Intelligent Construction(Trial).展开更多
To investigate the impact of temporary structures on the mechanical behavior of shaped bridge towers during the construction process,the Dianbu River Special Bridge was selected as the engineering background.A finite ...To investigate the impact of temporary structures on the mechanical behavior of shaped bridge towers during the construction process,the Dianbu River Special Bridge was selected as the engineering background.A finite element model of the middle tower column during the construction stage was established using ABAQUS to analyze the effects of key parameters,including the angle and pretension of temporary cables,as well as the wall thickness and diameter of temporary diagonal braces.The study examines how these parameters influence the stresses at the towergirder consolidation.The results indicate that the angle of temporary cables significantly affects the tensile stresses at the tower-girder consolidation,while its impact on compressive stresses is minimal.Among all parameters,the pretension of temporary cables has the most pronounced effect on the stresses at the tower-girder consolidation.In contrast,the wall thickness of temporary diagonal braces has only a minor influence,whereas the diameter of temporary diagonal braces has an almost negligible impact.These findings provide valuable insights for optimizing the design and arrangement of temporary support structures in similar bridge construction projects.展开更多
To fully leverage the advantages of mechanization and informatization in tunnel boring machine(TBM)operations,the authors aim to promote the advancement of tunnel construction technology toward intelligent development...To fully leverage the advantages of mechanization and informatization in tunnel boring machine(TBM)operations,the authors aim to promote the advancement of tunnel construction technology toward intelligent development.This involved exploring the deep integration of next-generation artificial intelligence technologies,such as sensing technology,automatic control technology,big data technology,deep learning,and machine vision,with key operational processes,including TBM excavation,direction adjustment,step changes,inverted arch block assembly,material transportation,and operation status assurance.The results of this integration are summarized as follows.(1)TBM key excavation parameter prediction algorithm was developed with an accuracy rate exceeding 90%.The TBM intelligent step-change control algorithm,based on machine vision,achieved an image segmentation accuracy rate of 95%and gripper shoe positioning error of±5 mm.(2)An automatic positioning system for inverted arch blocks was developed,enabling real-time perception of the spatial position and deviation during the assembly process.The system maintains an elevation positioning deviation within±3 mm and a horizontal positioning deviation within±10 mm,reducing the number of surveyors in each work team.(3)A TBM intelligent rail transportation system that achieves real-time human-machine positioning,automatic switch opening and closing,automatic obstacle avoidance,intelligent transportation planning,and integrated scheduling and command was designed.Each locomotive formation reduces one shunter and improves comprehensive transportation efficiency by more than 20%.(4)Intelligent analysis and prediction algorithms were developed to monitor and predict the trends of the hydraulic and gear oil parameters in real time,enhancing the proactive maintenance and system reliability.展开更多
Scientific and technological advancements are rapidly transforming underground engineering,shifting from labor-intensive,time-consuming methods to automated,real-time systems.This timely and comprehensive review cover...Scientific and technological advancements are rapidly transforming underground engineering,shifting from labor-intensive,time-consuming methods to automated,real-time systems.This timely and comprehensive review covers in-situ testing,intelligent monitoring,and geophysical testing methods,highlighting fundamental principles,testing apparatuses,data processing techniques,and engineering applications.The state-of-the-art summary emphasizes not only cutting-edge innovations for complex and harsh environments but also the transformative role of artificial intelligence and machine learning in data interpretations.The integration of big data and advanced algorithms is particularly impactful,enabling the identification,prediction,and mitigation of potential risks in underground projects.Key aspects of the discussion include detection capabilities,method integration,and data convergence of intelligent technologies to drive enhanced safety,operational efficiency,and predictive reliability.The review also examines future trends in intelligent technologies,emphasizing unified platforms that combine multiple methods,real-time data,and predictive analytics.These advancements are shaping the evolution of underground construction and maintenance,aiming for risk-free,high-efficiency underground engineering.展开更多
Network pharmacology has gained widespread application in drug discovery,particularly in traditional Chinese medicine(TCM)research,which is characterized by its“multi-component,multi-target,and multi-pathway”nature....Network pharmacology has gained widespread application in drug discovery,particularly in traditional Chinese medicine(TCM)research,which is characterized by its“multi-component,multi-target,and multi-pathway”nature.Through the integration of network biology,TCM network pharmacology enables systematic evaluation of therapeutic efficacy and detailed elucidation of action mechanisms,establishing a novel research paradigm for TCM modernization.The rapid advancement of machine learning,particularly revolutionary deep learning methods,has substantially enhanced artificial intelligence(AI)technology,offering significant potential to advance TCM network pharmacology research.This paper describes the methodology of TCM network pharmacology,encompassing ingredient identification,network construction,network analysis,and experimental validation.Furthermore,it summarizes key strategies for constructing various networks and analyzing constructed networks using AI methods.Finally,it addresses challenges and future directions regarding cell-cell communication(CCC)-based network construction,analysis,and validation,providing valuable insights for TCM network pharmacology.展开更多
Construction engineering and management(CEM)has become increasingly complicated with the increasing size of engineering projects under different construction environments,motivating the digital transformation of CEM.T...Construction engineering and management(CEM)has become increasingly complicated with the increasing size of engineering projects under different construction environments,motivating the digital transformation of CEM.To contribute to a better understanding of the state of the art of smart techniques for engineering projects,this paper provides a comprehensive review of multi-criteria decision-making(MCDM)techniques,intelligent techniques,and their applications in CEM.First,a comprehensive framework detailing smart technologies for construction projects is developed.Next,the characteristics of CEM are summarized.A bibliometric review is then conducted to investigate the keywords,journals,and clusters related to the application of smart techniques in CEM during 2000-2022.Recent advancements in intelligent techniques are also discussed under the following six topics:①big data technology;②computer vision;③speech recognition;④natural language processing;⑤machine learning;and⑥knowledge representation,understanding,and reasoning.The applications of smart techniques are then illustrated via underground space exploitation.Finally,future research directions for the sustainable development of smart construction are highlighted.展开更多
Marine infrastructure is increasingly vulnerable to harsh environmental conditions that accelerate the degradation of traditional materials such as Portland cement concrete and carbon steel.This review systematically ...Marine infrastructure is increasingly vulnerable to harsh environmental conditions that accelerate the degradation of traditional materials such as Portland cement concrete and carbon steel.This review systematically investigates recent advancements in sustainable alternatives,including geopolymer concrete,engineered innovacementitious composites(ECC),bio-concrete,fiber-reinforced polymers(FRPs),and bamboo,stainless steel,and steel-CFRP hybrid bars.Each material is evaluated based on marine durability,mechanical performance,environmental impact,and cost feasibility using life cycle assessment,durability modelling,and a multi-criteria decisionsupport framework.The results reveal that geopolymer concrete and FRP reinforcement’s exhibit superior corrosion resistance and environmental benefits,while ECC and steel-CFRP composites offer structural resilience with moderate environmental trade-offs.However,challenges remain in long-term performance validation,standardization,and market integration.The review concludes that a combined approach involving innovative materials,computational tools,and sustainability assessment is essential for advancing marine infrastructure.Outlook recommendations include focused field studies,development of regulatory guidelines,and interdisciplinary collaboration to drive the practical adoption of eco-efficient materials in coastal and offshore construction.展开更多
Zeolite-loaded noble metal catalysts have demonstrated excellent performance in addressing cold-start automotive exhaust NOx emissions and catalytic oxidation of VOCs applications.Pd and Pt are the most commonly used ...Zeolite-loaded noble metal catalysts have demonstrated excellent performance in addressing cold-start automotive exhaust NOx emissions and catalytic oxidation of VOCs applications.Pd and Pt are the most commonly used active metals in PNA and VOC catalysts,respectively.However,despite the same metal/zeolite composition,the efficient active sites for PNA and VOC catalysts have been viewed as mainly Pd^(2+) and Pt^(0),respectively,both of which are different from each other.As a result,various methods need to be applied to dope Pd and Pt in zeolitic support respectively for different usages.No matter which type of metal species is needed,the common requirement for both PNA and VOC catalysts is that the metal species should be highly dispersed in zeolite support and stay stable.The purpose of this paper is to review the progress of synthetic means of zeolite-coated noble metals(Pd,Pt,etc.)as effective PNA or VOC catalysts.To give a better understanding of the relationship between efficient metal species and the introduced methods,the species that contributed to the NOx adsorption(PNA)and VOCs deep catalytic oxidation were first summarized and compared.Then,based on the above discussion,the detailed construction strategies for different active sites in PNA and VOC catalysts,respectively,were elaborated in terms of synthetic routes,precursor selection,and zeolite carrier requirements.It is hoped that this will contribute to a better understanding of noble metal adsorption/catalysis in zeolites and provide promising strategies for the design of adsorption/catalysts with high activity,selectivity and stability.展开更多
To understand the smoke level and NO_(x)emission characteristics of in-use construction machinery in Beijing,we selected 905 construction machines in Beijing from August 2022 to April 2023 to monitor the emission leve...To understand the smoke level and NO_(x)emission characteristics of in-use construction machinery in Beijing,we selected 905 construction machines in Beijing from August 2022 to April 2023 to monitor the emission level of smoke and NO_(x).The exhaust smoke level and excessive emission situation of different machinery types were identified,and their NO_(x)emission levels were monitored according to the free acceleration method.We investigated the correlation of NO_(x)and smoke emission,and proposed suggestions for controlling pollution discharge from construction machinery in the future.The results show that the exhaust smoke level was 0–2.62 m^(−1),followed a log-normal distribution(μ=-1.73,δ=1.09,R^(2)=0.99),with a 5.64%exceedance rate.Differenceswere observed amongmachinery types,with low-power engine forklifts showing higher smoke levels.The NO_(x)emission range was 71–1516 ppm,followed a normal distribution(μ=565.54,δ=309.51,R^(2)=0.83).Differences among machinery types were relatively small.Engine rated net power had the most significant impact on NO_(x)emissions.Thus,NO_(x)emissions from construction machinery need further attention.Furthermore,we found a weak negative correlation(p<0.05)between the emission level of smoke and NO_(x),that is the synergic emission reduction effect is poor,emphasizing the need for NO_(x)emission limits.In the future,the oversight in Beijing should prioritize phasing out ChinaⅠand ChinaⅡmachinery,and monitor emissions from highpower engine ChinaⅢmachinery.展开更多
文摘East Africa’s construction boom draws Chinese heavy machinery manufacturers and distributors The booming construction of new housing and commercial units has led to unprecedented demand for heavy construction equipment in Nairobi,Kenya.
文摘At the World Economic Forum Annual Meeting 2026 in Davos,China emerged as a steadfast advocate for multilateral cooperation and constructive dialogue,presenting a clear alternative to divisive rhetoric.CHINA’S role as a key player in shaping global development and trends stood out at the World Economic Forum(WEF)annual meeting 2026 in Davos,Switzerland.
基金Supported by Special Fund Project for the Transformation of Scientific and Technological Achievements in Inner Mongolia Autonomous Region(2021CG0013)Bayannur City Science and Technology Plan Project(K202014)+1 种基金Inner Mongolia Autonomous Region Science and Technology Plan Project(2022YFHH0088)Research Special Project of the Education Department of Inner Mongolia Autonomous Region(STAQZX202320).
文摘[Objectives]To explore the control mode of farmland drainage pollutants and investigate the effects of ecological ditch and wetland on reducing farmland drainage pollutants in Hetao Irrigation District.[Methods]Based on the demonstration construction project of the ecological ditch-constructed wetland system in the Hetao Irrigation District,an experimental study was conducted from July to September 2023 to investigate the interception and purification effects of ecological ditches,constructed wetlands,and the combined ecological ditch-constructed wetland system on farmland drainage pollutants.Key water quality parameters measured included total nitrogen(TN)concentration and total phosphorus(TP)concentration.[Results]Different treatment modes of ecological ditches and constructed wetlands have a certain removal effect on nitrogen and phosphorus pollutants in water bodies.The ecological ditches treated with Astragalus laxmannii,Melilotus officinalis,Medicago sativa,bio-ball substrate,and bio-sheet substrate showed reduction efficiencies for TN and TP of 21.09% and 23.84%,12.06% and 26.67%,20.08% and 34.15%,23.65% and 20.56%,and 19.92% and 25.83%,respectively.The emergent plant area showed reduction efficiencies of 24.28%for TN and 17.89%for TP,while the submerged plant area achieved a reduction efficiency of 10.21%for both TN and TP.Among the different treatment modes,the ecological ditch with M.sativa performed better in TP removal,whereas the bio-ball substrate treatment mode showed higher effectiveness in TN removal.In addition,the emergent plant area exhibited better TP removal performance,while the submerged plant area was more effective in TN removal.The combined system of ecological ditch and constructed wetland achieved removal rates of 37.55% for TN and 11.47% for TP.It effectively facilitates the step-by-step interception and adsorption purification of pollutants,thereby showing significant removal and purification effects on nitrogen and phosphorus contaminants.This contributes to mitigating agricultural non-point source pollution.[Conclusions]The combined ecological ditch-constructed wetland system serves dual functions of agricultural drainage and pollutant interception and purification.It reduces the pollution load of farmland drainage on receiving water bodies to some extent and mitigates agricultural non-point source pollution.Therefore,it is a relatively suitable technology for managing agricultural non-point source pollution in the Hetao Irrigation District.
基金the National Key R&D Program of China(No.2021YFF0701700)the National Natural Science Foundation of China(Nos.22271264 and 21971228)for financial support.
文摘Fluorinated motifs are prevalent in both pharmaceuticals and agrochemicals.The incorporation of fluorine-containing moieties to drug candidates has emerged as a potent strategy for lead optimization in pharmaceutical research and development.While extensive research has been devoted to constructing molecules that incorporate a trifluoromethylthio(SCF_(3)−)group on a stereogenic carbon,the synthesis of trifluoromethylthiolated alkanes featuring a SCF_(3)-substituted stereogenic carbon at non-activated site remains understudied.Herein,we report a Cu-catalyzed regio-and enantioselective hydroallylation of 1-trifluoromethylthiolated alkenes.Important to the process is the regio-and enantioselective Cu-H insertion to SCF_(3)-substituted alkene to form chiralα-SCF_(3) alkyl copper intermediates,outcompeting unproductive insertion to the coupling partner,and eventually proceed to afford optically active homoallylic trifluoromethylthiolated products.
基金an initial outcome of the Research on the Interactive Relationship Between Biographies and Epitaphs in Ancient China,a project(ID:24BZW023)supported by the National Social Science Fund of China。
文摘The historical image of Ouyang Xiu constructed during the Song Dynasty evolved from a multifaceted portrayal that balanced his political and literary achievements into a singular cultural symbol.In the Northern Song Dynasty,writings by Ouyang Xiu's family and epitaphs by his colleagues crafted a balanced narrative emphasizing both his official duties and literary merits,thus constructing a dual image of him as a principled remonstrator and a literary master.In the Southern Song Dynasty,official historiography gradually eroded his complex persona as a political reformer by selectively trimming political disputes and emphasizing his literary lineage,ultimately establishing him as a cultural exemplar beyond factional strife.Throughout this evolution of historical writing,Ouyang Xiu's sharpness as a remonstrator was gradually obscured in historical texts,while his image as a literary master,revered by all,became firmly established.The reshaping of Ouyang Xiu's image in historical writings across the Northern and Southern Song dynasties not only reflects the logic of selecting scholar-official role models under the influence of official ideology but also reveals the inherent pattern whereby individual distinctiveness fades into symbolic construction in historical writing.
基金supported by the Key Project of Joint Fund of the National Natural Science Foundation of China“Research on Key Technologies and Demonstration Applications for Trusted and Secure Data Circulation and Trading”(U24A20241)the National Natural Science Foundation of China“Research on Trusted Theories and Key Technologies of Data Security Trading Based on Blockchain”(62202118)+4 种基金the Major Scientific and Technological Special Project of Guizhou Province([2024]014)Scientific and Technological Research Projects from the Guizhou Education Department(Qian jiao ji[2023]003)the Hundred-Level Innovative Talent Project of the Guizhou Provincial Science and Technology Department(Qiankehe Platform Talent-GCC[2023]018)the Major Project of Guizhou Province“Research and Application of Key Technologies for Trusted Large Models Oriented to Public Big Data”(Qiankehe Major Project[2024]003)the Guizhou Province Computational Power Network Security Protection Science and Technology Innovation Talent Team(Qiankehe Talent CXTD[2025]029).
文摘As blockchain technology rapidly evolves,smart contracts have seen widespread adoption in financial transactions and beyond.However,the growing prevalence of malicious Ponzi scheme contracts presents serious security threats to blockchain ecosystems.Although numerous detection techniques have been proposed,existing methods suffer from significant limitations,such as class imbalance and insufficient modeling of transaction-related semantic features.To address these challenges,this paper proposes an oversampling-based detection framework for Ponzi smart contracts.We enhance the Adaptive Synthetic Sampling(ADASYN)algorithm by incorporating sample proximity to decision boundaries and ensuring realistic sample distributions.This enhancement facilitates the generation of high-quality minority class samples and effectively mitigates class imbalance.In addition,we design a Contract Transaction Graph(CTG)construction algorithm to preserve key transactional semantics through feature extraction from contract code.A graph neural network(GNN)is then applied for classification.This study employs a publicly available dataset from the XBlock platform,consisting of 318 verified Ponzi contracts and 6498 benign contracts.Sourced from real Ethereum deployments,the dataset reflects diverse application scenarios and captures the varied characteristics of Ponzi schemes.Experimental results demonstrate that our approach achieves an accuracy of 96%,a recall of 92%,and an F1-score of 94%in detecting Ponzi contracts,outperforming state-of-the-art methods.
文摘Against the backdrop of continuous social development and growing public health demands,the efficiency and scientific nature of the emergency care system are of paramount importance.This paper focuses on researching the construction of an emergency care system based on the concept of“linkage”,delving into its theoretical foundations,exploring innovative construction models,and analyzing practical cases.The study indicates that an emergency care system under the“linkage”concept can effectively integrate resources and enhance efficiency,providing new insights for improving the construction of the emergency care system.It aims to promote the development of the emergency care system towards a more scientific,efficient,and collaborative direction.
基金Major Project of the National Social Science Foundation of China“Historical Collation and Research of Cultural Exchanges Between Chinese and Foreign Craftsmen Along the Silk Road”(Approval No.22&ZD227)the Planning Project of Shaanxi Art Institute“Research on National Cultural Park Design”(Project No.YG2025001)part of the phased outcomes of the“Shaanxi Special Support Program for High-Level Talents”(Project Approval No.21HH02).
文摘The distinctive landscape of Zhujiayu Ancient Village in Zhangqiu District,Ji’nan,together with its long-established cultural traditions,has shaped a unique vernacular settlement character,within which traditional dwellings serve as a primary medium of regional culture.This study examines the residence of Zhu Fengyin,a jinshi degree holder,and adopts field investigation and measured drawing-based analysis.Discussion is organized around three dimensions:an overview of the dwelling,architectural form,and cultural expression.Particular attention is given to the multi-stage,multi-bay compound configuration developed in a mountainous setting,terrain-adaptive courtyard forms,and construction techniques.The analysis further interprets the concepts of ritual order and auspicious symbolism embedded in architectural decoration.By using this representative case,the study aims to deepen understanding of the architectural culture of gentry dwellings in the Ji’nan region and to provide an academic basis for the conservation and inheritance of traditional dwellings in the Ji’nan area.
基金sponsored by the National Natural Science Foundation of China(52178420,52408476)Research Project of Liaoning Provincial Transportation Construction Investment Group Co.,Ltd.(202410)+1 种基金Postdoctoral Fellowship Program of CPSF(GZC20242207)the Fundamental Research Funds for the Central Universities(HIT.DZJJ.2023086).
文摘Long-life pavement has been introduced to address the urgent need for durable and reliable transportation infrastructure.This review overviews the development of aggregates for long-life pavements and summarizes future research directions.The review indicates that natural aggregates,being non-renewable resources,are steadily declining in availability and may need to meet future demands.Construction solid waste aggregates are rapidly developing,with fine separation of reclaimed asphalt pavement(RAP)and reinforcement of cementbased recycled aggregates serving as key strategies to enhance their application.Industry solid waste aggregates possess properties suitable for long-life pavements and offer additional functionalities such as cooling,conductivity,and reflectivity,demonstrating significant development potential.While artificial aggregates exhibit superior performance,their large-scale application requires consideration of economic and environmental impacts.Current aggregate evaluation methods need to address the needs of long-life pavements.Aggregate performance requirements should be graded based on mechanical stress and temperature distribution,with corresponding evaluation methods and indices developed.Evaluating the mechanical properties of aggregates should align more closely with actual stress states.Tests such as triaxial,repeated load,and wheel abrasion polishing are better suited for assessing the strength and durability of long-life pavement aggregates.Similarly,evaluating aggregates'physicochemical properties should be based on studies correlating these properties with road performance,with proposed evaluation criteria.Morphological characteristics of aggregates significantly influence asphalt mixture performance,and efficient evaluation of their profile,angularity,and texture will be a key focus of future research.
文摘This study investigated the impact of the xu-argument-based continuation on Chinese high school students’English syntactic complexity captured using verb-argument constructions(VACs)over an 8-week period.Participants were two comparable groups of students:one group worked with English input texts(i.e.,E-E),while the other worked with Chinese input texts with the same content(i.e.,C-E).The results showed that over time,the E-E group exhibited a greater tendency to use a wider range of VACs,such as caused-motion constructions,attributives,passives,and phrasal verbs.At the same time,they reduced their use of simpler VACs like intransitive-motion and simple transitive constructions,especially when compared to the C-E group.This pattern was also evident in the topic-based writing during the posttest.These findings strongly support the effectiveness of xu-argument-based continuation tasks in promoting the development of L2 VAC knowledge.They suggest that tasks combining language input with output can significantly enhance learners’ability to use more sophisticated VACs.
文摘To advance intelligent construction,standards must come first.The Ministry of Housing and Urban-Rural Development has issued the List for Replicable Experience and Practices for Developing Intelligent Construction four times successively and the Technical Guidelines for Intelligent Construction(Trial).
文摘To investigate the impact of temporary structures on the mechanical behavior of shaped bridge towers during the construction process,the Dianbu River Special Bridge was selected as the engineering background.A finite element model of the middle tower column during the construction stage was established using ABAQUS to analyze the effects of key parameters,including the angle and pretension of temporary cables,as well as the wall thickness and diameter of temporary diagonal braces.The study examines how these parameters influence the stresses at the towergirder consolidation.The results indicate that the angle of temporary cables significantly affects the tensile stresses at the tower-girder consolidation,while its impact on compressive stresses is minimal.Among all parameters,the pretension of temporary cables has the most pronounced effect on the stresses at the tower-girder consolidation.In contrast,the wall thickness of temporary diagonal braces has only a minor influence,whereas the diameter of temporary diagonal braces has an almost negligible impact.These findings provide valuable insights for optimizing the design and arrangement of temporary support structures in similar bridge construction projects.
文摘To fully leverage the advantages of mechanization and informatization in tunnel boring machine(TBM)operations,the authors aim to promote the advancement of tunnel construction technology toward intelligent development.This involved exploring the deep integration of next-generation artificial intelligence technologies,such as sensing technology,automatic control technology,big data technology,deep learning,and machine vision,with key operational processes,including TBM excavation,direction adjustment,step changes,inverted arch block assembly,material transportation,and operation status assurance.The results of this integration are summarized as follows.(1)TBM key excavation parameter prediction algorithm was developed with an accuracy rate exceeding 90%.The TBM intelligent step-change control algorithm,based on machine vision,achieved an image segmentation accuracy rate of 95%and gripper shoe positioning error of±5 mm.(2)An automatic positioning system for inverted arch blocks was developed,enabling real-time perception of the spatial position and deviation during the assembly process.The system maintains an elevation positioning deviation within±3 mm and a horizontal positioning deviation within±10 mm,reducing the number of surveyors in each work team.(3)A TBM intelligent rail transportation system that achieves real-time human-machine positioning,automatic switch opening and closing,automatic obstacle avoidance,intelligent transportation planning,and integrated scheduling and command was designed.Each locomotive formation reduces one shunter and improves comprehensive transportation efficiency by more than 20%.(4)Intelligent analysis and prediction algorithms were developed to monitor and predict the trends of the hydraulic and gear oil parameters in real time,enhancing the proactive maintenance and system reliability.
基金supported by Ministry of Education of Singapore,under Academic Research Fund Tier 1(Grant Number RG143/23).
文摘Scientific and technological advancements are rapidly transforming underground engineering,shifting from labor-intensive,time-consuming methods to automated,real-time systems.This timely and comprehensive review covers in-situ testing,intelligent monitoring,and geophysical testing methods,highlighting fundamental principles,testing apparatuses,data processing techniques,and engineering applications.The state-of-the-art summary emphasizes not only cutting-edge innovations for complex and harsh environments but also the transformative role of artificial intelligence and machine learning in data interpretations.The integration of big data and advanced algorithms is particularly impactful,enabling the identification,prediction,and mitigation of potential risks in underground projects.Key aspects of the discussion include detection capabilities,method integration,and data convergence of intelligent technologies to drive enhanced safety,operational efficiency,and predictive reliability.The review also examines future trends in intelligent technologies,emphasizing unified platforms that combine multiple methods,real-time data,and predictive analytics.These advancements are shaping the evolution of underground construction and maintenance,aiming for risk-free,high-efficiency underground engineering.
基金supported by the“Pioneer”and“Leading Goose”R&D Program of Zhejiang(No.2024C03106,X.F.)the National Natural Science Foundation of China(No.82474160,X.S.)+2 种基金the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China(No.LBZ24H270001,X.P.)the Major Joint Projects Supported by the National Administration of TCM and Zhejiang Province(No.GZY-ZI-KJ-23037,X.P.)the Ningbo Top Medical and Health Research Program(No.2022030309,X.P.)。
文摘Network pharmacology has gained widespread application in drug discovery,particularly in traditional Chinese medicine(TCM)research,which is characterized by its“multi-component,multi-target,and multi-pathway”nature.Through the integration of network biology,TCM network pharmacology enables systematic evaluation of therapeutic efficacy and detailed elucidation of action mechanisms,establishing a novel research paradigm for TCM modernization.The rapid advancement of machine learning,particularly revolutionary deep learning methods,has substantially enhanced artificial intelligence(AI)technology,offering significant potential to advance TCM network pharmacology research.This paper describes the methodology of TCM network pharmacology,encompassing ingredient identification,network construction,network analysis,and experimental validation.Furthermore,it summarizes key strategies for constructing various networks and analyzing constructed networks using AI methods.Finally,it addresses challenges and future directions regarding cell-cell communication(CCC)-based network construction,analysis,and validation,providing valuable insights for TCM network pharmacology.
基金funded by the project of Guangdong Provincial Basic and Applied Basic Research Fund Committee(2022A1515240073)the Pearl River Talent Recruitment Program(2019CX01G338),Guangdong Province.
文摘Construction engineering and management(CEM)has become increasingly complicated with the increasing size of engineering projects under different construction environments,motivating the digital transformation of CEM.To contribute to a better understanding of the state of the art of smart techniques for engineering projects,this paper provides a comprehensive review of multi-criteria decision-making(MCDM)techniques,intelligent techniques,and their applications in CEM.First,a comprehensive framework detailing smart technologies for construction projects is developed.Next,the characteristics of CEM are summarized.A bibliometric review is then conducted to investigate the keywords,journals,and clusters related to the application of smart techniques in CEM during 2000-2022.Recent advancements in intelligent techniques are also discussed under the following six topics:①big data technology;②computer vision;③speech recognition;④natural language processing;⑤machine learning;and⑥knowledge representation,understanding,and reasoning.The applications of smart techniques are then illustrated via underground space exploitation.Finally,future research directions for the sustainable development of smart construction are highlighted.
文摘Marine infrastructure is increasingly vulnerable to harsh environmental conditions that accelerate the degradation of traditional materials such as Portland cement concrete and carbon steel.This review systematically investigates recent advancements in sustainable alternatives,including geopolymer concrete,engineered innovacementitious composites(ECC),bio-concrete,fiber-reinforced polymers(FRPs),and bamboo,stainless steel,and steel-CFRP hybrid bars.Each material is evaluated based on marine durability,mechanical performance,environmental impact,and cost feasibility using life cycle assessment,durability modelling,and a multi-criteria decisionsupport framework.The results reveal that geopolymer concrete and FRP reinforcement’s exhibit superior corrosion resistance and environmental benefits,while ECC and steel-CFRP composites offer structural resilience with moderate environmental trade-offs.However,challenges remain in long-term performance validation,standardization,and market integration.The review concludes that a combined approach involving innovative materials,computational tools,and sustainability assessment is essential for advancing marine infrastructure.Outlook recommendations include focused field studies,development of regulatory guidelines,and interdisciplinary collaboration to drive the practical adoption of eco-efficient materials in coastal and offshore construction.
基金supported by Zhongtian Iron and Steel-University of Science and Technology Beijing Youth Science and Technology Innovation Fund(No.FZTNTC2024050005)National Engineering Laboratory for Mobile Source Emission Control Technology,China(No.NELMS2020A07)The Fundamental Research Funds for the Central Universities,China(No.FRF-AT-20-12)。
文摘Zeolite-loaded noble metal catalysts have demonstrated excellent performance in addressing cold-start automotive exhaust NOx emissions and catalytic oxidation of VOCs applications.Pd and Pt are the most commonly used active metals in PNA and VOC catalysts,respectively.However,despite the same metal/zeolite composition,the efficient active sites for PNA and VOC catalysts have been viewed as mainly Pd^(2+) and Pt^(0),respectively,both of which are different from each other.As a result,various methods need to be applied to dope Pd and Pt in zeolitic support respectively for different usages.No matter which type of metal species is needed,the common requirement for both PNA and VOC catalysts is that the metal species should be highly dispersed in zeolite support and stay stable.The purpose of this paper is to review the progress of synthetic means of zeolite-coated noble metals(Pd,Pt,etc.)as effective PNA or VOC catalysts.To give a better understanding of the relationship between efficient metal species and the introduced methods,the species that contributed to the NOx adsorption(PNA)and VOCs deep catalytic oxidation were first summarized and compared.Then,based on the above discussion,the detailed construction strategies for different active sites in PNA and VOC catalysts,respectively,were elaborated in terms of synthetic routes,precursor selection,and zeolite carrier requirements.It is hoped that this will contribute to a better understanding of noble metal adsorption/catalysis in zeolites and provide promising strategies for the design of adsorption/catalysts with high activity,selectivity and stability.
基金supported by the Energy Foundation(No.G-2203-33693).
文摘To understand the smoke level and NO_(x)emission characteristics of in-use construction machinery in Beijing,we selected 905 construction machines in Beijing from August 2022 to April 2023 to monitor the emission level of smoke and NO_(x).The exhaust smoke level and excessive emission situation of different machinery types were identified,and their NO_(x)emission levels were monitored according to the free acceleration method.We investigated the correlation of NO_(x)and smoke emission,and proposed suggestions for controlling pollution discharge from construction machinery in the future.The results show that the exhaust smoke level was 0–2.62 m^(−1),followed a log-normal distribution(μ=-1.73,δ=1.09,R^(2)=0.99),with a 5.64%exceedance rate.Differenceswere observed amongmachinery types,with low-power engine forklifts showing higher smoke levels.The NO_(x)emission range was 71–1516 ppm,followed a normal distribution(μ=565.54,δ=309.51,R^(2)=0.83).Differences among machinery types were relatively small.Engine rated net power had the most significant impact on NO_(x)emissions.Thus,NO_(x)emissions from construction machinery need further attention.Furthermore,we found a weak negative correlation(p<0.05)between the emission level of smoke and NO_(x),that is the synergic emission reduction effect is poor,emphasizing the need for NO_(x)emission limits.In the future,the oversight in Beijing should prioritize phasing out ChinaⅠand ChinaⅡmachinery,and monitor emissions from highpower engine ChinaⅢmachinery.
