This paper studies the consensus control of multiagent systems with binary-valued observations.An algorithm alternating estimation and control is proposed.Each agent estimates the states of its neighbors based on a pr...This paper studies the consensus control of multiagent systems with binary-valued observations.An algorithm alternating estimation and control is proposed.Each agent estimates the states of its neighbors based on a projected empirical measure method for a holding time.Based on the estimates,each agent designs the consensus control with a constant gain at some skipping time.The states of the system are updated by the designed control,and the estimation and control design will be repeated.For the estimation,the projected empirical measure method is proposed for the binary-valued observations.The algorithm can ensure the uniform boundedness of the estimates and the mean square error of the estimation is proved to be at the order of the reciprocal of the holding time(the same order as that in the case of accurate outputs).For the consensus control,a constant gain is designed instead of the stochastic approximation based gain in the existing literature for binary-valued observations.And,there is no need to make modification for control since the uniform boundedness of the estimates ensures the uniform boundedness of the agents’states.Finally,the systems updated by the designed control are proved to achieve consensus and the consensus speed is faster than that in the existing literature.Simulations are given to demonstrate the theoretical results.展开更多
Undoped and Na-doped ZnO films were deposited by sol-gel method.The effects of sodium incorporation on structure,surface morphology and optical constants of the films were investigated.X-ray diffraction patterns show ...Undoped and Na-doped ZnO films were deposited by sol-gel method.The effects of sodium incorporation on structure,surface morphology and optical constants of the films were investigated.X-ray diffraction patterns show the hexagonal wurtzite polycrystalline structure and that the sodium incorporation leads to the change in the structural characteristics of ZnO films.The SEM observations show that the surface morphology of the films is affected by the sodium incorporation.The transmission spectra show that the average transmittance of the films is above 85% in the visible range.The absorption edge initially blue-shifts and then red-shifts with the increase of Na doping content.The optical constants of these films were calculated using transmission spectra.Refractive indices of the films in the visible range decrease at first and then increase with increasing Na doping content.展开更多
Vanadium battery has fast and large capacity charge and discharge characteristics, and the concentration and stability of the battery electrolyte are the key to the electrolyte performance. In actual, with higher acid...Vanadium battery has fast and large capacity charge and discharge characteristics, and the concentration and stability of the battery electrolyte are the key to the electrolyte performance. In actual, with higher acidity and higher concentration of the vanadium battery electrolyte, the ion-pair is dominant. The ion-pair dissociation constant is one of the important thermodynamic data related to battery performance. The vanadyl sulfate conductivity in aqueous solution was determined using the conductance method at 298.15K. Using the origin data fitting, the limiting molar conductance is obtained, and then by the improved Ostwald dilution law and the Davies equation, the activity coefficient is solved so as to obtain the ionic strength of the true solution. Using the Fuoss method, the dissociation constant of vanadyl sulfate ion-pair was calculated. At last, the vanadyl sulfate limiting molar conductance (Λ <sub> 0 </sub>) is 174.8251748 S·dm<sup>2</sup>·mol<sup>?1</sup>, and the vanadyl sulfate ion-pair dissociation constant K <sub>d</sub> is 0.002636367, and then other thermodynamic properties can be studied.展开更多
The fluid-coupled discrete element method(DEM)and the constant volume method as two types of discrete modeling methods for fundamental study of undrained responses of granular materials,have been discussed by many res...The fluid-coupled discrete element method(DEM)and the constant volume method as two types of discrete modeling methods for fundamental study of undrained responses of granular materials,have been discussed by many researchers.The fluid-coupled DEM,which couples the motions of discrete particles with pore fluid movements,is theoretically robust although it requires a large amount of computation time.As a substitution for the complex fluid-coupled DEM,the constant volume method simulates an undrained condition for a saturated granular material by simply preserving the total volume of a granular assembly without considering interactions between fluids and particles;hence,the validity of its results is questionable.In this paper,the undrained behaviors of granular assemblies simulated using the aforementioned two methods are compared.Based on a comparison of both macroscopic and microscopic responses given by the two methods,it is demonstrated that the constant volume method may reasonably simulate the responses of a loose saturated granular material with very coarse grains,which has a high permeability,and thus a rapid pore pressure equalization.However,it is ineffective in simulating the responses of a loose material with fine components due to its failure to capture the process of a slow dissipation of the excess pore pressure among the individual pores.With regard to the dense material adopted,similar behaviors at the early and intermediate shearing stages given by the two methods are displayed.展开更多
In this paper the elastic constants of graphite at elevated temperature were experimentally investigated by using the virtual fields method （VFM）. A new method was presented for the characterization of mechanical pr...In this paper the elastic constants of graphite at elevated temperature were experimentally investigated by using the virtual fields method （VFM）. A new method was presented for the characterization of mechanical properties at elevated temperature. The three-point bending tests were performed on graphite materials by an universal testing machine equipped with heating fumace. Based on the heterogeneous deformation fields measured by the digital image correlation （DIC） technique, the elastic constants were then extracted by using VFM. The measurement results of the elastic constants at 500℃ were obtained. The ef- fect on the experimental results was also analyzed. The successful results verify the feasibility of using the proposed method to measure the properties of graphite at high temperature, and the proposed method is believed to have a good potential for further applications.展开更多
Segmentation of three-dimensional(3D) complicated structures is of great importance for many real applications.In this work we combine graph cut minimization method with a variant of the level set idea for 3D segmenta...Segmentation of three-dimensional(3D) complicated structures is of great importance for many real applications.In this work we combine graph cut minimization method with a variant of the level set idea for 3D segmentation based on the Mumford-Shah model.Compared with the traditional approach for solving the Euler-Lagrange equation we do not need to solve any partial differential equations.Instead,the minimum cut on a special designed graph need to be computed.The method is tested on data with complicated structures.It is rather stable with respect to initial value and the algorithm is nearly parameter free.Experiments show that it can solve large problems much faster than traditional approaches.展开更多
The photoplethysmogram(PPG) of a pulse wave,similar in appearance to the arterial blood pressure(ABP) waveform,contains rich information about the cardiovascular system.The decay time constant RC,equal to the product ...The photoplethysmogram(PPG) of a pulse wave,similar in appearance to the arterial blood pressure(ABP) waveform,contains rich information about the cardiovascular system.The decay time constant RC,equal to the product of peripheral resistance R and total arterial compliance C,is a meaningful cardiovascular model parameter in vascular assessment.Using or ameliorating the existing ABP methods does not achieve a satisfactory estimation of RC from the PPG volume pulse(VRC).Thus,a novel non-iterative shape method(NSM) of evaluating VRC is introduced in this paper.The mathematic expression between a novel,readily available morphological parameter called the area difference ratio(ADR) and VRC was established.As it was difficult to calculate VRC from the complicated expression analytically,we recommend estimating it using a piecewise linear interpolation criterion.Also,since the effect of the PPG magnitude is eliminated in the calculation of ADR,precaliberation or normalization is dispensable in the NSM.Results of human experiments indicated that the NSM was computationally efficient,and the simulation experiments confirmed that the NSM was theoretically available for ABP.展开更多
This paper proposes a new method for determining the intrinsic acidity constants K and K The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these co...This paper proposes a new method for determining the intrinsic acidity constants K and K The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these constants is not dependent on the specific surface area S of the marine solid particles. The new method was used to determine K, K and S for the main inorganic components of marine solid particles, including illite, montmorillonite, kaolinite, goethite, y-AlOOH. amorphous ferric oxide, MnO2, manganite, SiO 2 and calcium carbonate, and can facilitate the study on the effect of solution constituents, solution temperature, ionic strength, etc. on the value展开更多
According to the appearing of isosbestic point in the absorption spectra of Ho/Y-Tribromoarsenazo (TBA)systems,the complexation reaction is considered to be M+nL=ML_n.A method has been proposed based on it for calcula...According to the appearing of isosbestic point in the absorption spectra of Ho/Y-Tribromoarsenazo (TBA)systems,the complexation reaction is considered to be M+nL=ML_n.A method has been proposed based on it for calculating the mole fraction of free complexing agent in the solutions from spectral data.and two linear regression formula have been introduced to determine the composition,the molar absorptivity,the conditional stability constant of the complex and the concentration of the complexing agent. This method has been used in Ho-TBA and Y-TBA systems.Ho^(3+)and Y^(3+)react with TBA and form 1: 2 complexes in HCl-NaAc buffer solution at pH 3.80.Their molar absorptivities determined are 1.03×10~8 and 1.10×10~8 cm^2·mol^(-1),and the conditional stability constants(logβ_2)are 11.37 and 11.15 respectively.After considering the pH effect in TBA complexing,their stability constants(log β_2^(ahs))are 43.23 and 43.01. respectively.The new method is adaptable to such systems where the accurate concentration of the complexing agent can not be known conveniently.展开更多
A new method,dual-series linear regression method,has been used to study the complexation equilibrium of praseodymium(Pr^(3+))with tribromoarsenazo(TBA)without knowing the accurate concentra- tion of the complexing ag...A new method,dual-series linear regression method,has been used to study the complexation equilibrium of praseodymium(Pr^(3+))with tribromoarsenazo(TBA)without knowing the accurate concentra- tion of the complexing agent TBA.In 1.2 mol/L HCl solution, Pr^(3+)reacts with TBA and forms 1:3 com- plex,the conditional stability constant(lgβ_3)of the complex determined is 15.47,and its molar absorptivity(ε_3^(630))is 1.48×10~5 L·mol^(-1)·cm^(-1).展开更多
In order to make the power level angle(PLA)have the same bijection relationship with the thrust when the environment changes before operational limit exceedance,and ensure the pilot's ability of unrestricted throt...In order to make the power level angle(PLA)have the same bijection relationship with the thrust when the environment changes before operational limit exceedance,and ensure the pilot's ability of unrestricted throttle movement as well as the safety of the engine,a method used to design a constant thrust power schedule was proposed.The research was based on a simulink turbofan engine model and the results were organized as look-up tables in different structures with limitations.Simulation was done to confirm the validity and demonstrate the effectiveness of the schedule obtained with the approach.The constant thrust takeoff schedule,constant thrust idle schedule and constant thrust part power schedule with the present constant thrust control(CTC)method were proved to be valid.The results can be applied to this specific engine but the method can be applied to any areoengine and can be even extended to the unmanned plane.展开更多
A new method is proposed for determining the composition and stability constant of coordination compounds of the form M m R n ; it can be used to differentiate mono and poly nuclear coordination compounds. ...A new method is proposed for determining the composition and stability constant of coordination compounds of the form M m R n ; it can be used to differentiate mono and poly nuclear coordination compounds. The equation derived is lg( A i/(A max - A i) m)=n lg c′ R+lg( m·β(c M/A max ) ( m -1) ). The method is based on Bent French limited logarithm method. The demonstration of the proposed method has yielded correct results for Sc 3+ chlorophosphonazo Ⅲ system and Fe 3+ Chromazurol S system.展开更多
The purpose of this paper is to reduce the error when measuring high dielectric constant materials.In this paper,the reason why the error introduced is analyzed firstly.Then,with HFSS,the method of choosing the size o...The purpose of this paper is to reduce the error when measuring high dielectric constant materials.In this paper,the reason why the error introduced is analyzed firstly.Then,with HFSS,the method of choosing the size of cavity and the dimension of dielectric materials is proposed.And several error correction curves are provided for measuring high dielectric constant materials.Finally,the experiment is conducted to validate the feasibility of our analysis.展开更多
The elastic constants of Al single crystal were calculated by ab initio method for calibration. Three deformation directions were selected in order to obtain the different constants of c 11 , c 12 and c 44 . The cohes...The elastic constants of Al single crystal were calculated by ab initio method for calibration. Three deformation directions were selected in order to obtain the different constants of c 11 , c 12 and c 44 . The cohesion energy curves of the three deformation directions were calculated. The results of the second order partial differential at the equilibrium point of the cohesion energy curve provide the elastic constants of the Al single crystal. The changes of crystal symmetry and lattice can lead to the deviations of the calculated cohesion energy curves and the accurate elastic constants can not be obtained, but when the correction is taken into calculation, the calculated results are very close to the literature data. It is very difficult to obtain the elastic constants of thin films by experiment and the data from the handbook are scattered in a large scale. However, the elastic constants calculated by this method can be served as a standard. Though the errors of TiN elastic constants calculated by this method are a little higher than that for Al, the results are acceptable. [展开更多
In ferroelectric liquid crystals, phase transitions can be induced by an electric field. The current constant method allows these transition to be quickly localized and thus the（E, T） phase diagram of the studied pr...In ferroelectric liquid crystals, phase transitions can be induced by an electric field. The current constant method allows these transition to be quickly localized and thus the（E, T） phase diagram of the studied product can be obtained.In this work, we make a slight modification to the measurement principles based on this method. This modification allows the characteristic parameters of ferroelectric liquid crystal to be quantitatively measured. The use of a current square signal highlights a phenomenon of ferroelectric hysteresis with remnant polarization at null field, which points out an effect of memory in this compound.展开更多
A dynamic Bayesian error function of material constants of the structure is developed for thin-walled curve box girders. Combined with the automatic search scheme with an optimal step length for the one-dimensional Fi...A dynamic Bayesian error function of material constants of the structure is developed for thin-walled curve box girders. Combined with the automatic search scheme with an optimal step length for the one-dimensional Fibonacci series, Powell＇s optimization theory is used to perform the stochastic identification of material constants of the thin-walled curve box. Then, the steps in the parameter identification are presented. Powell＇s identification procedure for material constants of the thin-walled curve box is compiled, in which the mechanical analysis of the thin-walled curve box is completed based on the finite curve strip element （FCSE） method. Some classical examples show that Powell＇s identification is numerically stable and convergent, indicating that the present method and the compiled procedure are correct and reliable. During the parameter iterative processes, Powell＇s theory is irrelevant with the calculation of the FCSE partial differentiation, which proves the high computation efficiency of the studied methods. The stochastic performances of the system parameters and responses axe simultaneously considered in the dynamic Bayesian error function. The one-dimensional optimization problem of the optimal step length is solved by adopting the Fibonacci series search method without the need of determining the region, in which the optimized step length lies.展开更多
This paper presents a thorough study of the effect of the Constant Eddy Viscosity(CEV)assumption on the optimization of a discrete adjoint-based design optimization system.First,the algorithms of the adjoint methods w...This paper presents a thorough study of the effect of the Constant Eddy Viscosity(CEV)assumption on the optimization of a discrete adjoint-based design optimization system.First,the algorithms of the adjoint methods with and without the CEV assumption are presented,followed by a discussion of the two methods’solution stability.Second,the sensitivity accuracy,adjoint solution stability,and Root Mean Square(RMS)residual convergence rates at both design and offdesign operating points are compared between the CEV and full viscosity adjoint methods in detail.Finally,a multi-point steady aerodynamic and a multi-objective unsteady aerodynamic and aeroelastic coupled design optimizations are performed to study the impact of the CEV assumption on optimization.Two gradient-based optimizers,the Sequential Least-Square Quadratic Programming(SLSQP)method and Steepest Descent Method(SDM)are respectively used to draw a firm conclusion.The results from the transonic NASA Rotor 67 show that the CEV assumption can deteriorate RMS residual convergence rates and even lead to solution instability,especially at a near stall point.Compared with the steady cases,the effect of the CEV assumption on unsteady sensitivity accuracy is much stronger.Nevertheless,the CEV adjoint solver is still capable of achieving optimization goals to some extent,particularly if the flow under consideration is benign.展开更多
Static dielectric constant is a key parameter to estimate the electro-viscous effect which plays important roles in the flow and convective heat transfer of fluids with ions in microfluidic devices such as micro react...Static dielectric constant is a key parameter to estimate the electro-viscous effect which plays important roles in the flow and convective heat transfer of fluids with ions in microfluidic devices such as micro reactors and heat exchangers.A group contribution method based on 27 groups is developed for the correlation of static dielectric constant of ionic liquids in this paper.The ionic liquids considered include imidazolium,pyridinium,pyrrolidinium,alkylammonium,alkylsulfonium,morpholinium and piperidinium cations and various anions.The data collected cover the temperature ranges of 278.15-343.15 K and static dielectric constant ranges of 9.4-85.6.The results of the method show a satisfactory agreement with the literature data with an average absolute relative deviation of 7.41%,which is generally of the same order of the experimental data accuracy.The method proposed in this paper provides a simple but reliable approach for the prediction of static dielectric constant of ionic liquids at different temperatures.展开更多
To estimate the life of vacuum fluorescent display （VFD） more accurately and reduce test time and cost, four constant stress accelerated life tests （CSALTs） were conducted on an accelerated life test model. In the...To estimate the life of vacuum fluorescent display （VFD） more accurately and reduce test time and cost, four constant stress accelerated life tests （CSALTs） were conducted on an accelerated life test model. In the model, statistical analysis of test data is achieved by applying lognormal function to describe the life distribution, and least square method （LSM） to calculate the mean value and the standard deviation of logarithm. As a result, the accelerated life equation was obtained, and then a self-developed software was developed to predict the VFD life. The data analysis results demonstrate that the VFD life submits to lognormal distribution, that the accelerated model meets the linear Arrhenius equation, and that the precise accelerated parameter makes it possible to acquire the life information of VFD within one month.展开更多
基金supported by the National Natural Science Foundation of China(61803370,61622309)the China Postdoctoral Science Foundation(2018M630216)the National Key Research and Development Program of China(2016YFB0901902)
文摘This paper studies the consensus control of multiagent systems with binary-valued observations.An algorithm alternating estimation and control is proposed.Each agent estimates the states of its neighbors based on a projected empirical measure method for a holding time.Based on the estimates,each agent designs the consensus control with a constant gain at some skipping time.The states of the system are updated by the designed control,and the estimation and control design will be repeated.For the estimation,the projected empirical measure method is proposed for the binary-valued observations.The algorithm can ensure the uniform boundedness of the estimates and the mean square error of the estimation is proved to be at the order of the reciprocal of the holding time(the same order as that in the case of accurate outputs).For the consensus control,a constant gain is designed instead of the stochastic approximation based gain in the existing literature for binary-valued observations.And,there is no need to make modification for control since the uniform boundedness of the estimates ensures the uniform boundedness of the agents’states.Finally,the systems updated by the designed control are proved to achieve consensus and the consensus speed is faster than that in the existing literature.Simulations are given to demonstrate the theoretical results.
基金Project(50872001) supported by the National Natural Science Foundation of ChinaProject(20060357003) supported by Research Fund for the Doctoral Program of Higher Education of ChinaProject(KJ2010A284) supported by the Natural Science Foundation of Anhui Higher Education Institution of China
文摘Undoped and Na-doped ZnO films were deposited by sol-gel method.The effects of sodium incorporation on structure,surface morphology and optical constants of the films were investigated.X-ray diffraction patterns show the hexagonal wurtzite polycrystalline structure and that the sodium incorporation leads to the change in the structural characteristics of ZnO films.The SEM observations show that the surface morphology of the films is affected by the sodium incorporation.The transmission spectra show that the average transmittance of the films is above 85% in the visible range.The absorption edge initially blue-shifts and then red-shifts with the increase of Na doping content.The optical constants of these films were calculated using transmission spectra.Refractive indices of the films in the visible range decrease at first and then increase with increasing Na doping content.
基金financially supported by the National Natural Science Foundation of China(No.21273152)
文摘Vanadium battery has fast and large capacity charge and discharge characteristics, and the concentration and stability of the battery electrolyte are the key to the electrolyte performance. In actual, with higher acidity and higher concentration of the vanadium battery electrolyte, the ion-pair is dominant. The ion-pair dissociation constant is one of the important thermodynamic data related to battery performance. The vanadyl sulfate conductivity in aqueous solution was determined using the conductance method at 298.15K. Using the origin data fitting, the limiting molar conductance is obtained, and then by the improved Ostwald dilution law and the Davies equation, the activity coefficient is solved so as to obtain the ionic strength of the true solution. Using the Fuoss method, the dissociation constant of vanadyl sulfate ion-pair was calculated. At last, the vanadyl sulfate limiting molar conductance (Λ <sub> 0 </sub>) is 174.8251748 S·dm<sup>2</sup>·mol<sup>?1</sup>, and the vanadyl sulfate ion-pair dissociation constant K <sub>d</sub> is 0.002636367, and then other thermodynamic properties can be studied.
基金The authors would like to express their acknowledgments to Dr.Timothy Topper for his insightful com。
文摘The fluid-coupled discrete element method(DEM)and the constant volume method as two types of discrete modeling methods for fundamental study of undrained responses of granular materials,have been discussed by many researchers.The fluid-coupled DEM,which couples the motions of discrete particles with pore fluid movements,is theoretically robust although it requires a large amount of computation time.As a substitution for the complex fluid-coupled DEM,the constant volume method simulates an undrained condition for a saturated granular material by simply preserving the total volume of a granular assembly without considering interactions between fluids and particles;hence,the validity of its results is questionable.In this paper,the undrained behaviors of granular assemblies simulated using the aforementioned two methods are compared.Based on a comparison of both macroscopic and microscopic responses given by the two methods,it is demonstrated that the constant volume method may reasonably simulate the responses of a loose saturated granular material with very coarse grains,which has a high permeability,and thus a rapid pore pressure equalization.However,it is ineffective in simulating the responses of a loose material with fine components due to its failure to capture the process of a slow dissipation of the excess pore pressure among the individual pores.With regard to the dense material adopted,similar behaviors at the early and intermediate shearing stages given by the two methods are displayed.
基金supported by the National Natural Science Foundation of China(11232008,91216301,11227801,and 11172151)the Tsinghua University Initiative Scientific Research Program,and the Major Basic Research Program of Beijing Institute of Technology(2011CX01030)
文摘In this paper the elastic constants of graphite at elevated temperature were experimentally investigated by using the virtual fields method （VFM）. A new method was presented for the characterization of mechanical properties at elevated temperature. The three-point bending tests were performed on graphite materials by an universal testing machine equipped with heating fumace. Based on the heterogeneous deformation fields measured by the digital image correlation （DIC） technique, the elastic constants were then extracted by using VFM. The measurement results of the elastic constants at 500℃ were obtained. The ef- fect on the experimental results was also analyzed. The successful results verify the feasibility of using the proposed method to measure the properties of graphite at high temperature, and the proposed method is believed to have a good potential for further applications.
基金support from the Centre for Integrated Petroleum Research(CIPR),University of Bergen, Norway,and Singapore MOE Grant T207B2202NRF2007IDMIDM002-010
文摘Segmentation of three-dimensional(3D) complicated structures is of great importance for many real applications.In this work we combine graph cut minimization method with a variant of the level set idea for 3D segmentation based on the Mumford-Shah model.Compared with the traditional approach for solving the Euler-Lagrange equation we do not need to solve any partial differential equations.Instead,the minimum cut on a special designed graph need to be computed.The method is tested on data with complicated structures.It is rather stable with respect to initial value and the algorithm is nearly parameter free.Experiments show that it can solve large problems much faster than traditional approaches.
基金Project (No.81070885) supported by the National Natural Science Foundation of China
文摘The photoplethysmogram(PPG) of a pulse wave,similar in appearance to the arterial blood pressure(ABP) waveform,contains rich information about the cardiovascular system.The decay time constant RC,equal to the product of peripheral resistance R and total arterial compliance C,is a meaningful cardiovascular model parameter in vascular assessment.Using or ameliorating the existing ABP methods does not achieve a satisfactory estimation of RC from the PPG volume pulse(VRC).Thus,a novel non-iterative shape method(NSM) of evaluating VRC is introduced in this paper.The mathematic expression between a novel,readily available morphological parameter called the area difference ratio(ADR) and VRC was established.As it was difficult to calculate VRC from the complicated expression analytically,we recommend estimating it using a piecewise linear interpolation criterion.Also,since the effect of the PPG magnitude is eliminated in the calculation of ADR,precaliberation or normalization is dispensable in the NSM.Results of human experiments indicated that the NSM was computationally efficient,and the simulation experiments confirmed that the NSM was theoretically available for ABP.
文摘This paper proposes a new method for determining the intrinsic acidity constants K and K The new method is a great improvement over the modified Langmuir plot method generally adopted in that determination of these constants is not dependent on the specific surface area S of the marine solid particles. The new method was used to determine K, K and S for the main inorganic components of marine solid particles, including illite, montmorillonite, kaolinite, goethite, y-AlOOH. amorphous ferric oxide, MnO2, manganite, SiO 2 and calcium carbonate, and can facilitate the study on the effect of solution constituents, solution temperature, ionic strength, etc. on the value
文摘According to the appearing of isosbestic point in the absorption spectra of Ho/Y-Tribromoarsenazo (TBA)systems,the complexation reaction is considered to be M+nL=ML_n.A method has been proposed based on it for calculating the mole fraction of free complexing agent in the solutions from spectral data.and two linear regression formula have been introduced to determine the composition,the molar absorptivity,the conditional stability constant of the complex and the concentration of the complexing agent. This method has been used in Ho-TBA and Y-TBA systems.Ho^(3+)and Y^(3+)react with TBA and form 1: 2 complexes in HCl-NaAc buffer solution at pH 3.80.Their molar absorptivities determined are 1.03×10~8 and 1.10×10~8 cm^2·mol^(-1),and the conditional stability constants(logβ_2)are 11.37 and 11.15 respectively.After considering the pH effect in TBA complexing,their stability constants(log β_2^(ahs))are 43.23 and 43.01. respectively.The new method is adaptable to such systems where the accurate concentration of the complexing agent can not be known conveniently.
文摘A new method,dual-series linear regression method,has been used to study the complexation equilibrium of praseodymium(Pr^(3+))with tribromoarsenazo(TBA)without knowing the accurate concentra- tion of the complexing agent TBA.In 1.2 mol/L HCl solution, Pr^(3+)reacts with TBA and forms 1:3 com- plex,the conditional stability constant(lgβ_3)of the complex determined is 15.47,and its molar absorptivity(ε_3^(630))is 1.48×10~5 L·mol^(-1)·cm^(-1).
文摘In order to make the power level angle(PLA)have the same bijection relationship with the thrust when the environment changes before operational limit exceedance,and ensure the pilot's ability of unrestricted throttle movement as well as the safety of the engine,a method used to design a constant thrust power schedule was proposed.The research was based on a simulink turbofan engine model and the results were organized as look-up tables in different structures with limitations.Simulation was done to confirm the validity and demonstrate the effectiveness of the schedule obtained with the approach.The constant thrust takeoff schedule,constant thrust idle schedule and constant thrust part power schedule with the present constant thrust control(CTC)method were proved to be valid.The results can be applied to this specific engine but the method can be applied to any areoengine and can be even extended to the unmanned plane.
文摘A new method is proposed for determining the composition and stability constant of coordination compounds of the form M m R n ; it can be used to differentiate mono and poly nuclear coordination compounds. The equation derived is lg( A i/(A max - A i) m)=n lg c′ R+lg( m·β(c M/A max ) ( m -1) ). The method is based on Bent French limited logarithm method. The demonstration of the proposed method has yielded correct results for Sc 3+ chlorophosphonazo Ⅲ system and Fe 3+ Chromazurol S system.
文摘The purpose of this paper is to reduce the error when measuring high dielectric constant materials.In this paper,the reason why the error introduced is analyzed firstly.Then,with HFSS,the method of choosing the size of cavity and the dimension of dielectric materials is proposed.And several error correction curves are provided for measuring high dielectric constant materials.Finally,the experiment is conducted to validate the feasibility of our analysis.
文摘The elastic constants of Al single crystal were calculated by ab initio method for calibration. Three deformation directions were selected in order to obtain the different constants of c 11 , c 12 and c 44 . The cohesion energy curves of the three deformation directions were calculated. The results of the second order partial differential at the equilibrium point of the cohesion energy curve provide the elastic constants of the Al single crystal. The changes of crystal symmetry and lattice can lead to the deviations of the calculated cohesion energy curves and the accurate elastic constants can not be obtained, but when the correction is taken into calculation, the calculated results are very close to the literature data. It is very difficult to obtain the elastic constants of thin films by experiment and the data from the handbook are scattered in a large scale. However, the elastic constants calculated by this method can be served as a standard. Though the errors of TiN elastic constants calculated by this method are a little higher than that for Al, the results are acceptable. [
文摘In ferroelectric liquid crystals, phase transitions can be induced by an electric field. The current constant method allows these transition to be quickly localized and thus the（E, T） phase diagram of the studied product can be obtained.In this work, we make a slight modification to the measurement principles based on this method. This modification allows the characteristic parameters of ferroelectric liquid crystal to be quantitatively measured. The use of a current square signal highlights a phenomenon of ferroelectric hysteresis with remnant polarization at null field, which points out an effect of memory in this compound.
基金Project supported by the National Natural Science Foundation of China(Nos.10472045,10772078, and 11072108)the National High-Tech Research and Development Program of China(863 Program) (No.2007AA11Z106)
文摘A dynamic Bayesian error function of material constants of the structure is developed for thin-walled curve box girders. Combined with the automatic search scheme with an optimal step length for the one-dimensional Fibonacci series, Powell＇s optimization theory is used to perform the stochastic identification of material constants of the thin-walled curve box. Then, the steps in the parameter identification are presented. Powell＇s identification procedure for material constants of the thin-walled curve box is compiled, in which the mechanical analysis of the thin-walled curve box is completed based on the finite curve strip element （FCSE） method. Some classical examples show that Powell＇s identification is numerically stable and convergent, indicating that the present method and the compiled procedure are correct and reliable. During the parameter iterative processes, Powell＇s theory is irrelevant with the calculation of the FCSE partial differentiation, which proves the high computation efficiency of the studied methods. The stochastic performances of the system parameters and responses axe simultaneously considered in the dynamic Bayesian error function. The one-dimensional optimization problem of the optimal step length is solved by adopting the Fibonacci series search method without the need of determining the region, in which the optimized step length lies.
基金supported by the National Science and Technology Major Project,China(No.2017-II-0009-0023)China’s 111 project(No.B17037)sponsored by Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China.
文摘This paper presents a thorough study of the effect of the Constant Eddy Viscosity(CEV)assumption on the optimization of a discrete adjoint-based design optimization system.First,the algorithms of the adjoint methods with and without the CEV assumption are presented,followed by a discussion of the two methods’solution stability.Second,the sensitivity accuracy,adjoint solution stability,and Root Mean Square(RMS)residual convergence rates at both design and offdesign operating points are compared between the CEV and full viscosity adjoint methods in detail.Finally,a multi-point steady aerodynamic and a multi-objective unsteady aerodynamic and aeroelastic coupled design optimizations are performed to study the impact of the CEV assumption on optimization.Two gradient-based optimizers,the Sequential Least-Square Quadratic Programming(SLSQP)method and Steepest Descent Method(SDM)are respectively used to draw a firm conclusion.The results from the transonic NASA Rotor 67 show that the CEV assumption can deteriorate RMS residual convergence rates and even lead to solution instability,especially at a near stall point.Compared with the steady cases,the effect of the CEV assumption on unsteady sensitivity accuracy is much stronger.Nevertheless,the CEV adjoint solver is still capable of achieving optimization goals to some extent,particularly if the flow under consideration is benign.
基金Supported by the National Natural Science Foundation of China(21176206)the Project of Zhejiang Key Scientific and Technological Innovation Team(2010R50017)
文摘Static dielectric constant is a key parameter to estimate the electro-viscous effect which plays important roles in the flow and convective heat transfer of fluids with ions in microfluidic devices such as micro reactors and heat exchangers.A group contribution method based on 27 groups is developed for the correlation of static dielectric constant of ionic liquids in this paper.The ionic liquids considered include imidazolium,pyridinium,pyrrolidinium,alkylammonium,alkylsulfonium,morpholinium and piperidinium cations and various anions.The data collected cover the temperature ranges of 278.15-343.15 K and static dielectric constant ranges of 9.4-85.6.The results of the method show a satisfactory agreement with the literature data with an average absolute relative deviation of 7.41%,which is generally of the same order of the experimental data accuracy.The method proposed in this paper provides a simple but reliable approach for the prediction of static dielectric constant of ionic liquids at different temperatures.
基金Shanghai Municipal Natural Science Foun-dation (NO.09ZR1413000)Undergraduate Education High-land Construction Project of ShanghaiKey Technology R&D Program of Shanghai Municipality (No.08160510600)
文摘To estimate the life of vacuum fluorescent display （VFD） more accurately and reduce test time and cost, four constant stress accelerated life tests （CSALTs） were conducted on an accelerated life test model. In the model, statistical analysis of test data is achieved by applying lognormal function to describe the life distribution, and least square method （LSM） to calculate the mean value and the standard deviation of logarithm. As a result, the accelerated life equation was obtained, and then a self-developed software was developed to predict the VFD life. The data analysis results demonstrate that the VFD life submits to lognormal distribution, that the accelerated model meets the linear Arrhenius equation, and that the precise accelerated parameter makes it possible to acquire the life information of VFD within one month.
基金Supported by National Natural Science Committee and Chinese Engineering Physics Institute Foundation(10576013)Natural Science Foundation of Henan Province(0611053200)Natural Science Study Foundation of Henan University(06YBZR028)
