For coal mines,rock,coal,and rock bolt are the critical constituent materials for surrounding rock in the underground engineering.The stability of the“rock-coal-bolt”(RCB)composite system is affected by the structur...For coal mines,rock,coal,and rock bolt are the critical constituent materials for surrounding rock in the underground engineering.The stability of the“rock-coal-bolt”(RCB)composite system is affected by the structure and fracture of the coal-rock mass.More rock bolts installed on the rock,more complex condition of the engineering stress environment will be(tensile-shear composite stress is principal).In this paper,experimental analysis and theoretical verification were performed on the RCB composite system with different angles.The results revealed that the failure of the rock-coal(RC)composite specimen was caused by tensile and shear cracks.After anchoring,the reinforcement body formed inside the composite system limits the area where the crack could occur in the specimen.Specifically,shearing damage occurred only around the bolt,and the stress-strain curve presented a better post-peak mechanical property.The mechanical mechanism of the bolt under the combined action of tension and shear stress was analyzed.Additionally,a rock-coal-bolt tensile-shear mechanical(RCBTSM)model was established.The relationship(similar to the exponential function)between the bolt tensile-shear stress and the angle was obtained.Moreover,the influences of the dilatancy angle and bolt diameter of the RCB composite system were also considered and analyzed.Most of the bolts are subjected to the tensile-shearing action in the post-peak stage.The implications of these results for engineering practice indicated that the bolts of the RCB composite system should be prevented from entering the limit shearing state early.展开更多
La_(0.67)Ca_(0.33)MnO_3)_x /(ZrO_2)_(1-x) (x is the volume fraction ratio) percolated composites were fabricated by combining La_(0.67)Ca_(0.33)MnO_3 (LCMO) powders with ZrO_2 particles, where LCMO powders were prepar...La_(0.67)Ca_(0.33)MnO_3)_x /(ZrO_2)_(1-x) (x is the volume fraction ratio) percolated composites were fabricated by combining La_(0.67)Ca_(0.33)MnO_3 (LCMO) powders with ZrO_2 particles, where LCMO powders were prepared by sol-gel process. Low field magnetoresistance ( LFMR ) is greatly enhanced at low temperature when the system is close to the metallic percolation threshold of x=0.4. The magnetoresistance ratio of ( LCMO)_(0.4) /( ZrO_2 )_(0.6) in a 10 mT magnetic field at 77 K is 7.8 %, about 7.12 times larger than that of pure LCMO compound. The enhancement of spin-dependent tunneling of electrons at the interfaces between LCMO and ZrO_2 grains is responsible for the enhanced LFMR. With increasing ZrO_2 addition, Curie temperature T_C decreases firstly and then remains constant at about 220 K when (x<60%), showing limited substitution effect of Zr ions on B sites.展开更多
Using nonequilibrium molecular dynamics simulations, a comprehensive study of the asymmetric heat conduction in the composite system consisting of the Frenkel-Kontorova （FK） model and Fermi-Pasta-Ulam （FPU） model ...Using nonequilibrium molecular dynamics simulations, a comprehensive study of the asymmetric heat conduction in the composite system consisting of the Frenkel-Kontorova （FK） model and Fermi-Pasta-Ulam （FPU） model is conducted. The calculated results show that in a larger system, the rectifying direction can be reversed only by adjusting the thermal bias. Moreover, the rectification reversal depends critically on the system size and the properties of the interface. The mechanisms of the two types of asymmetric heat conduction induced by nonlinearity are discussed. Considering the novel asymmetric heat conduction in the system, it may possess possible applications to manage the thermal rectification in situ directionally without re-building the structure.展开更多
This article presents an efficient parallel processing approach for solving the opti- mal control problem of nonlinear composite systems. In this approach, the original high-order coupled nonlinear two-point boundary ...This article presents an efficient parallel processing approach for solving the opti- mal control problem of nonlinear composite systems. In this approach, the original high-order coupled nonlinear two-point boundary value problem （TPBVP） derived from the Pontrya- gin＇s maximum principle is first transformed into a sequence of lower-order deeoupled linear time-invariant TPBVPs. Then, an optimal control law which consists of both feedback and forward terms is achieved by using the modal series method for the derived sequence. The feedback term specified by local states of each subsystem is determined by solving a ma- trix Riccati differential equation. The forward term for each subsystem derived from its local information is an infinite sum of adjoint vectors. The convergence analysis and parallel processing capability of the proposed approach are also provided. To achieve an accurate feedforward-feedbaek suboptimal control, we apply a fast iterative algorithm with low com- putational effort. Finally, some comparative results are included to illustrate the effectiveness of the proposed approach.展开更多
Based on high order dynamic neural network, this paper presents the tracking problem for uncertain nonlinear composite system, which contains external disturbance, whose nonlinearities are assumed to be unknown. A smo...Based on high order dynamic neural network, this paper presents the tracking problem for uncertain nonlinear composite system, which contains external disturbance, whose nonlinearities are assumed to be unknown. A smooth controller is designed to guarantee a uniform ultimate boundedness property for the tracking error and all other signals in the dosed loop. Certain measures are utilized to test its performance. No a priori knowledge of an upper bound on the “optimal” weight and modeling error is required; the weights of neural networks are updated on-line. Numerical simulations performed on a simple example illustrate and clarify the approach.展开更多
The effects of positron diffusion on the measured S parameter have been investigated by a point-source diffusion model and a δ function method. Firstly, the theoretical analyses of the effects are presented for the s...The effects of positron diffusion on the measured S parameter have been investigated by a point-source diffusion model and a δ function method. Firstly, the theoretical analyses of the effects are presented for the samples of a homogeneous semi-infinite medium and a film of definite thickness. Then the results are used to analyze the S parameters in several composite systems and interface models.展开更多
A series of (1-x)La0.6Dy0.1Sr0.3MnO3/0.5x(Sb2O3)(x=0.15) samples were prepared by the solid-state reaction method, and the influence of sintering temperature of the matrix on low-field magnetoresistance of (1-x)La0.6D...A series of (1-x)La0.6Dy0.1Sr0.3MnO3/0.5x(Sb2O3)(x=0.15) samples were prepared by the solid-state reaction method, and the influence of sintering temperature of the matrix on low-field magnetoresistance of (1-x)La0.6Dy0.1Sr0.3MnO3/0.5x (Sb2O3) was studied through the measurements of X-ray diffraction (XRD) patterns, scanning electron microscope (SEM) image, resistivity-temperature (ρ-T) curves, and magnetoresistance-temperature (MR-T) curves. The results indicate that for the samples with low sintering temperature of the matrix, lowfield magnetoresistance effect appears on the whole temperature range and can be explained by grain boundary effect; for the sample with high sintering temperature of the matrix, intrinsic magnetoresistance peak appears on the high-temperature range, low-field magnetore-sistance effect appears on low temperature range, and the magnetoresistance in the magnetic field of 0.2 T and on the comparatively large temperature range between 280 K and 225 K hardly changes with temperature and remains at 4.8%, which can be explained by the competition between the intrinsic magnetoresistance induced by double-exchange function inside grains and the tunneling magnetoresis-tance (TMR) induced by grain boundary effect. The temperature stability of magnetoresistance is beneficial to the practical applications of MR.展开更多
New-old concrete composite system usually exists in concrete repairing structure.In the present work,series of experiments were carried out to investigate permeability and ion diffusion properties of new-old concrete ...New-old concrete composite system usually exists in concrete repairing structure.In the present work,series of experiments were carried out to investigate permeability and ion diffusion properties of new-old concrete composite by measuring 6-hour coulomb charge and chloride diffusivity.The interrelation among transport properties of new-old composites,new,and old concretes was also discussed.Results indicate that the permeability and chloride diffusivity of new-old concrete composite system closely interrelate to the corresponding new concrete and old concrete.The interfacial transition zone between new concrete and old concrete greatly influences the transport property of new-old concrete system.Compared with the corresponding new concrete and old concrete lower permeability and diffusivity values for the new-old concrete composites can be achieved by choosing suitable new concrete.It is possible to design the tailor-made new-old concrete composite system for repair given the transport property.展开更多
The samples ofLa8/9Sr1/45Na4/45MnO3 （LSNMO）/x/2（Sb2O3） were prepared by the solid-state reaction method. The electric transport properties and the temperature stabil-ity of magnetoresistance （MR） of the samples ...The samples ofLa8/9Sr1/45Na4/45MnO3 （LSNMO）/x/2（Sb2O3） were prepared by the solid-state reaction method. The electric transport properties and the temperature stabil-ity of magnetoresistance （MR） of the samples were studied through the measurements of X-ray diffraction patterns, resistivity-temperature （ρ-T） curves, mass magnetization-temperature （σ-T） curves, and magnetoresistance-temper-ature （MR-T） curves. The results indicate that the p-Tcurves of the original material LSNMO show two peaks, and the phenomenon of two peaks of ρ-T curves disappears for the composite samples, which can be explained by a competition between surface-phase resistivity induced by boundary-dependent scattering and body-phase resistivity induced by paramagnetism-ferromagnetism transition. For all the sam-ples in the low temperature range, MR increases continu-ously with the decrease of temperature, which shows a characteristic of low-field magnetoresistance. However, MR basically keeps the same in the high temperature range. The paramagnetism-ferromagnetism transition is observed in the high temperature range due to a composite between perov-skite manganite and insulator, which can enhance the tem-perature of MR appearance in the high temperature range and make it to appear near room temperature. For the sample with x = 0.12, MR remains constant at the value of 7.5 % in the temperature range of 300-260 K, which achieves a tem-perature stability of MR near room temperature. In addition,for the sample with x = 0.16, MR is above 6.8 % in the high temperature range of 318-252 K （△T = 66 K）. MR almost remains constant in this temperature range, which favors the practical application of MR.展开更多
This paper is concerned with fundamental properties of a class of composite systems with fractional degree generalized frequency variables, including controllability, observability and stability. Firstly, some necessa...This paper is concerned with fundamental properties of a class of composite systems with fractional degree generalized frequency variables, including controllability, observability and stability. Firstly, some necessary and sufficient conditions are given to guarantee controllability and observability of such composite systems. Then we prove that the stability problem of such composite systems can be reduced to judging whether a fractional degree polynomial is stable. Finally, the stability analysis result is applied in the supervisory control of fractional-order multi-agent systems, and an example is provided to illustrate the effectiveness of the proposed methods.展开更多
On the base of controllable variable stiffness property,variable stiffness composites were the main components of functional materials in aerospace.However,the relatively low mechanical strength,stiffness range,and re...On the base of controllable variable stiffness property,variable stiffness composites were the main components of functional materials in aerospace.However,the relatively low mechanical strength,stiffness range,and response rate restricted the application of variable stiffness composite.In this work,the novel variable stiffness composite system with characteristics of repeatable high load bearing and response rate was successfully prepared via the double-layer anisotropic structure to solve the bottlenecks of variable stiffness composites.The novel variable stiffness composite systems were composed of variable stiffness layer of polycaprolactone(PCL)and the driven layer of silicone elastomer with alcohol,which continuously changed Young’s modulus from 0.1 to 7.263 MPa(72.63 times variation)in 200 s and maintained maximum weight of 11.52 times its own weight(8.5 g).Attributed to the relatively high variable stiffness range and load bearing value of variable stiffness composite system,the repeatable response process led to the efficient high load driven as“muscle”and diversified precise grab of objects with different shapes as“gripper”,owning widespread application prospects in the field of bionics.展开更多
We synthesize composite systems of multi-wall carbon nanotubes(MWCNTs)/SiO_(2) by using the sol−gel method.The dielectric properties of the systems with different-concentration MWCNTs are studied.In our MWCNTs/SiO_(2)...We synthesize composite systems of multi-wall carbon nanotubes(MWCNTs)/SiO_(2) by using the sol−gel method.The dielectric properties of the systems with different-concentration MWCNTs are studied.In our MWCNTs/SiO_(2) inorganic systems,the twin−percolation phenomenon exists when the concentrations of MWCNTs are 5–10%and 15–20%.The permittivity and conductivity have jumping changes.The twin−percolation phenomenon is attributed to the special transfer mechanism of MWCNTs in the system,determined by hopping and migrating electrons.Variations of dielectric properties and conductance of the MWCNTs/SiO_(2) systems are conformed to the percolation theory.The special percolation phenomenon and electric properties of MWCNTs/SiO_(2) can help us comprehend the conductivity mechanism of the MWCNTs/SiO2 systems effectively,and promote the development of a high performance function composite system.展开更多
The wetting behaviour of titanium carbide by molten nickel was investigated at different oxygen partial pressures by using the sessile drop method.Special attention was paid to the kinetics of wetting.Wetting process ...The wetting behaviour of titanium carbide by molten nickel was investigated at different oxygen partial pressures by using the sessile drop method.Special attention was paid to the kinetics of wetting.Wetting process in the Ni/TiC system is controlled by the dissolution of TiC in the liquid phase.Discussions were made on the basis of the new experimental results achieved in the present investigation and those given in the literature for the Ni/TiC system and for some similar metal/carbon systems to elucidate how the interfacial dissolution reaction influences the wetting process.The reactive wetting process is a complex mat- ter and is very sensitive to the experimental conditions.Implantation of the wetting study in the composite processings was also suggested and the optimum processing is proposed.展开更多
The purpose of this research was to fmd out effectiveness of chloride solid membrane electrode of coated wire system compared to solid membrane electrode of composite system, the Nernstian response and character＇s po...The purpose of this research was to fmd out effectiveness of chloride solid membrane electrode of coated wire system compared to solid membrane electrode of composite system, the Nernstian response and character＇s potential response （detection limit, selectivity and response time）. The chloride ISEs （ion selective electrodes） in this research were the solid membrane chloride ISEs based AgC1. There were two types of chloride ISEs that were developed, namely the chloride ISEs of coated wire and composite systems. Both types of electrodes were characterized. The selectivity was done by comparing Esel of the chloride standard solutions and Esel of the interference ions （Br- and I-）. The measurement of chloride ions in water samples was done by using the coated wire chloride ISE, the composite chloride ISE and the Mohr method. We compared the result of the two chloride ISE methods to that of standard method for chloride determination （Mohr） by using F-test and Post Hoc Test LSD （least significant difference） and Duncan. Analysis by using F-test and Post Hoc Test （LSD and Duncan） and characterization results of both the methods showed that coated wire chloride ISE was more effective compared to composite chloride ISE. Nemstian response was 59.83 mV/decade, linier range measurement was 10-1-10-5 M, limit detection was 1.23 × 10-5 M, response time along was 25 s and interfering ion was 10-4 M Br-.展开更多
A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source di...A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach.展开更多
In chemical science,the vertical ionization potential(VIP)is a crucial metric for understanding the electronegativity,hardness and softness of chemical material systems as well as the electronic structure and stabilit...In chemical science,the vertical ionization potential(VIP)is a crucial metric for understanding the electronegativity,hardness and softness of chemical material systems as well as the electronic structure and stability of molecules.Ever since the last century,the model chemistry composite methods have witnessed tremendous developments in computing the thermodynamic properties as well as the barrier heights.However,their performance in realm of the vertical electron processes of molecular systems has been rarely explored.In this study,we for the first time benchmarked the model chemistry composite methods(e.g.,CBS-QB3,G4 and W1BD)in comparison with the commonly used Koopmans's theorem(KT),electron propagator theory(e.g.,OVGF,D2,P3 and P3+)and CCSD(T)methods in calculating the VIP for up to 613 molecular systems with available experimental measurements.The large-scale test calculations strongly showed that the CBS-QB3 model chemistry composite technique can be well recommended to calculate VIP from the perspectives of accuracy,economy and applicability.Notably,the VIP values of up to 7 molecules were identified to have the absolute errors of larger than 0.3 e V at all calculation levels,which have strong hints that their VIP experimental values should be re-investigated.展开更多
In order to explore the leaching law of different elements in the composite cementitious system composed of ferrous extraction tailing of nickel slag(FETNS)and ordinary Portland cement(OPC),element leaching test under...In order to explore the leaching law of different elements in the composite cementitious system composed of ferrous extraction tailing of nickel slag(FETNS)and ordinary Portland cement(OPC),element leaching test under different influencing factors was designed with the aid of ICP-OES,XRD,and SEM-EDS.The experimental results show that,with the extension of leaching time,the continuous hydration reaction in the system enables the leaching amount of Si,Al,Mg,and Ca elements to show an overall downward trend.In the alkaline environment,the more sufficient hydration reaction consumes more soluble elements,resulting in a significantly smaller leaching amount than that in the neutral environment.Temperature is also an important factor affecting the leaching of elements.The rise of temperature promotes the dissolution of amorphous phases Si,Al,and Mg in the system,leading to increased leaching amount and higher consumption of C_(2)S and C_(3)S,generating more reaction products.In addition,the content and fineness of FETNS also have a significant effect on the element leaching of the composite cementitious system.More importantly,this paper clarifies the leaching safety of internal heavy metal elements when FETNS is used under the above conditions,which provides a scientific guarantee for the safe and efficient application of FETNS in building materials.展开更多
To improve the wettability of Al metal matrix composites（Al-MMCs） by common filler metals,Al-12Si-xTi（x=0.1,0.5,1,3.0;mass fraction,%） system active ternary filler metals were prepared.It was demonstrated that alt...To improve the wettability of Al metal matrix composites（Al-MMCs） by common filler metals,Al-12Si-xTi（x=0.1,0.5,1,3.0;mass fraction,%） system active ternary filler metals were prepared.It was demonstrated that although the added Ti existed within Ti（Al1-xSix）3（0≤x≤0.15） phase,the shear strength and shear fracture surface of the developed Al-12Si-xTi brazes were quite similar to those of traditional Al-12Si braze due to the presence of similar microstructure of Al-Si eutectic microstructure with large volume fraction.So,small Ti addition（～1%） did not make the active brazes brittle and hard compared with the conventional Al-12Si braze.The measured melting range of each Al-12Si-xTi foil was very similar,i.e.,580-590 ℃,because the composition was close to that of eutectic.For wettability improvement,with increasing Ti content,the interfacial gap between the Al2O3 reinforcement and filler metal（R/M） could be eliminated,and the amount of the remainder of the active fillers on the composite substrate decreased after sessile drop test at 610 ℃ for 30 min.So,the wettability improvement became easy to observe repeatedly with increasing Ti content.Additionally,the amount and size of Ti（AlSi）3 phase were sensitive to the Ti content（before brazing） and Si content（after brazing）.展开更多
Al2O3p-Al composites were synthesized using an in-situ reaction in the 80%Al-20%CuO （mass fraction） system. The effects of the CuO particle size on the synthesis temperature and microstructure of the composites were...Al2O3p-Al composites were synthesized using an in-situ reaction in the 80%Al-20%CuO （mass fraction） system. The effects of the CuO particle size on the synthesis temperature and microstructure of the composites were investigated by various methods. The results indicate that the CuO particle size has a significant effect on the temperature at which the complete reaction in the Al-CuO system occurs：the temperature is 200 ℃ lower in the Al-CuO system containing CuO particles with sizes less than 6μm than that containing CuO particles with sizes less than 100μm. The interfacial bonding between Al2O3 particles and Al is not complete when the temperature is below a critical value. The morphology of the Al2O3 particles varies from ribbon-like shape to near spherical shape when the temperature is above a critical value. These two critical temperatures are affected by the particle size of CuO, and the critical temperature of the sample containing CuO particles with sizes less than 6μm is 100 ℃ lower than that of the sample containing CuO particles with sizes less than 100μm.展开更多
Internal thermal insulation composite system(ITICS)can be an important measure for the energy-saving retrofitting of buildings.However,ITICS may cause harmful effects on the hygrothermal performance of building envelo...Internal thermal insulation composite system(ITICS)can be an important measure for the energy-saving retrofitting of buildings.However,ITICS may cause harmful effects on the hygrothermal performance of building envelopes.This work investigated the influence of the materials’hygric properties on the hygrothermal perfor-mance of a typical ITICS in different climate conditions in China.Two base wall materials,the traditional concrete and a new type aerated concrete,were tested and compared for their hygric properties firstly.The influence of the hygroscopicity of exterior plasters,the permeability of insulation materials and the climate conditions were then analyzed with WUFI simulations.The hygrothermal performance was evaluated with consideration of the total water content(TWC)of the walls and the moisture flux strength,the relative humidity(RH)and the mould growth risk at the interface between the base wall and the insulation layer(B-I interface).The numerical analysis implies that the TWC of internal insulated walls depends mainly on the hygroscopicity of exterior plaster and the wind-driven rain intensity.The upper limits for the water absorption coefficient of exterior plasters used in Bei-jing,Shanghai and Fuzhou are 1e-9,1e-10,1e-10 m^(2)/s respectively.When such limits are guaranteed,a vapour tight system created by using insulation materials with a large vapour resistance factor or adding a vapour barrier can improve the hygrothermal performance of ITICS,especially for concrete walls in cold climate.展开更多
基金Beijing Outstanding Young Scientist Program(BJJWZYJH01201911413037)the projects supported by National Natural Science Foundation of China(Grants Nos.41877257,51622404,and 51974117)Shaanxi Coal Group Key Project(2018SMHKJ-A-J-03)。
文摘For coal mines,rock,coal,and rock bolt are the critical constituent materials for surrounding rock in the underground engineering.The stability of the“rock-coal-bolt”(RCB)composite system is affected by the structure and fracture of the coal-rock mass.More rock bolts installed on the rock,more complex condition of the engineering stress environment will be(tensile-shear composite stress is principal).In this paper,experimental analysis and theoretical verification were performed on the RCB composite system with different angles.The results revealed that the failure of the rock-coal(RC)composite specimen was caused by tensile and shear cracks.After anchoring,the reinforcement body formed inside the composite system limits the area where the crack could occur in the specimen.Specifically,shearing damage occurred only around the bolt,and the stress-strain curve presented a better post-peak mechanical property.The mechanical mechanism of the bolt under the combined action of tension and shear stress was analyzed.Additionally,a rock-coal-bolt tensile-shear mechanical(RCBTSM)model was established.The relationship(similar to the exponential function)between the bolt tensile-shear stress and the angle was obtained.Moreover,the influences of the dilatancy angle and bolt diameter of the RCB composite system were also considered and analyzed.Most of the bolts are subjected to the tensile-shearing action in the post-peak stage.The implications of these results for engineering practice indicated that the bolts of the RCB composite system should be prevented from entering the limit shearing state early.
文摘La_(0.67)Ca_(0.33)MnO_3)_x /(ZrO_2)_(1-x) (x is the volume fraction ratio) percolated composites were fabricated by combining La_(0.67)Ca_(0.33)MnO_3 (LCMO) powders with ZrO_2 particles, where LCMO powders were prepared by sol-gel process. Low field magnetoresistance ( LFMR ) is greatly enhanced at low temperature when the system is close to the metallic percolation threshold of x=0.4. The magnetoresistance ratio of ( LCMO)_(0.4) /( ZrO_2 )_(0.6) in a 10 mT magnetic field at 77 K is 7.8 %, about 7.12 times larger than that of pure LCMO compound. The enhancement of spin-dependent tunneling of electrons at the interfaces between LCMO and ZrO_2 grains is responsible for the enhanced LFMR. With increasing ZrO_2 addition, Curie temperature T_C decreases firstly and then remains constant at about 220 K when (x<60%), showing limited substitution effect of Zr ions on B sites.
基金supported by the Natural Science Foundation of Hunan Province,China(Grant No.12JJ3009)the Changsha Science and Technology Plan Projects,Chinathe Science and Technology Plan Projects of Hunan Province,China(Grant No.2013SK3148)
文摘Using nonequilibrium molecular dynamics simulations, a comprehensive study of the asymmetric heat conduction in the composite system consisting of the Frenkel-Kontorova （FK） model and Fermi-Pasta-Ulam （FPU） model is conducted. The calculated results show that in a larger system, the rectifying direction can be reversed only by adjusting the thermal bias. Moreover, the rectification reversal depends critically on the system size and the properties of the interface. The mechanisms of the two types of asymmetric heat conduction induced by nonlinearity are discussed. Considering the novel asymmetric heat conduction in the system, it may possess possible applications to manage the thermal rectification in situ directionally without re-building the structure.
文摘This article presents an efficient parallel processing approach for solving the opti- mal control problem of nonlinear composite systems. In this approach, the original high-order coupled nonlinear two-point boundary value problem （TPBVP） derived from the Pontrya- gin＇s maximum principle is first transformed into a sequence of lower-order deeoupled linear time-invariant TPBVPs. Then, an optimal control law which consists of both feedback and forward terms is achieved by using the modal series method for the derived sequence. The feedback term specified by local states of each subsystem is determined by solving a ma- trix Riccati differential equation. The forward term for each subsystem derived from its local information is an infinite sum of adjoint vectors. The convergence analysis and parallel processing capability of the proposed approach are also provided. To achieve an accurate feedforward-feedbaek suboptimal control, we apply a fast iterative algorithm with low com- putational effort. Finally, some comparative results are included to illustrate the effectiveness of the proposed approach.
基金This work was supported by the National Natural Science Foundation of China(No.60274009)and Specialized Research Fundfor the Doctoral Program of Higher Education(No.20020145007).
文摘Based on high order dynamic neural network, this paper presents the tracking problem for uncertain nonlinear composite system, which contains external disturbance, whose nonlinearities are assumed to be unknown. A smooth controller is designed to guarantee a uniform ultimate boundedness property for the tracking error and all other signals in the dosed loop. Certain measures are utilized to test its performance. No a priori knowledge of an upper bound on the “optimal” weight and modeling error is required; the weights of neural networks are updated on-line. Numerical simulations performed on a simple example illustrate and clarify the approach.
文摘The effects of positron diffusion on the measured S parameter have been investigated by a point-source diffusion model and a δ function method. Firstly, the theoretical analyses of the effects are presented for the samples of a homogeneous semi-infinite medium and a film of definite thickness. Then the results are used to analyze the S parameters in several composite systems and interface models.
基金supported by the National Natural Foundation of China (No. 19934003) the Natural Science Research Key Program of Anhui Educational Committee (No. KJ2011A259)+3 种基金the Opening Program of Cultivating Base of Anhui Key Laboratory of Spintronics and Nanomaterials (Nos. 2010YKF04 2011YKF05)the Professors’and Doctors’Research Startup Foundation of Suzhou University (Nos. 2011jb01 2011jb02)
文摘A series of (1-x)La0.6Dy0.1Sr0.3MnO3/0.5x(Sb2O3)(x=0.15) samples were prepared by the solid-state reaction method, and the influence of sintering temperature of the matrix on low-field magnetoresistance of (1-x)La0.6Dy0.1Sr0.3MnO3/0.5x (Sb2O3) was studied through the measurements of X-ray diffraction (XRD) patterns, scanning electron microscope (SEM) image, resistivity-temperature (ρ-T) curves, and magnetoresistance-temperature (MR-T) curves. The results indicate that for the samples with low sintering temperature of the matrix, lowfield magnetoresistance effect appears on the whole temperature range and can be explained by grain boundary effect; for the sample with high sintering temperature of the matrix, intrinsic magnetoresistance peak appears on the high-temperature range, low-field magnetore-sistance effect appears on low temperature range, and the magnetoresistance in the magnetic field of 0.2 T and on the comparatively large temperature range between 280 K and 225 K hardly changes with temperature and remains at 4.8%, which can be explained by the competition between the intrinsic magnetoresistance induced by double-exchange function inside grains and the tunneling magnetoresis-tance (TMR) induced by grain boundary effect. The temperature stability of magnetoresistance is beneficial to the practical applications of MR.
基金Project(2013CB036201)supported by the National Basic Research Program of ChinaProject(51178467)supported by National Natural Science Foundation of ChinaProject(NCET-10-0839)supported by Program for New Century Excellent Talents in University,China
文摘New-old concrete composite system usually exists in concrete repairing structure.In the present work,series of experiments were carried out to investigate permeability and ion diffusion properties of new-old concrete composite by measuring 6-hour coulomb charge and chloride diffusivity.The interrelation among transport properties of new-old composites,new,and old concretes was also discussed.Results indicate that the permeability and chloride diffusivity of new-old concrete composite system closely interrelate to the corresponding new concrete and old concrete.The interfacial transition zone between new concrete and old concrete greatly influences the transport property of new-old concrete system.Compared with the corresponding new concrete and old concrete lower permeability and diffusivity values for the new-old concrete composites can be achieved by choosing suitable new concrete.It is possible to design the tailor-made new-old concrete composite system for repair given the transport property.
基金financially supported by the National Natural Science Foundation of China(No.19934003)the Natural Science Foundation of the Education Bureau of Anhui Province,China(Nos.KJ2011A259 and KJ2012Z404)+1 种基金Anhui Key Laboratory of Spintronics and Nano-materials Program(Nos.2010YKF01 and 2010YKF04)the Professors’and Doctors’ Research Startup Foundation of Suzhou University(Nos.2011jb01 and 2010jb02)
文摘The samples ofLa8/9Sr1/45Na4/45MnO3 （LSNMO）/x/2（Sb2O3） were prepared by the solid-state reaction method. The electric transport properties and the temperature stabil-ity of magnetoresistance （MR） of the samples were studied through the measurements of X-ray diffraction patterns, resistivity-temperature （ρ-T） curves, mass magnetization-temperature （σ-T） curves, and magnetoresistance-temper-ature （MR-T） curves. The results indicate that the p-Tcurves of the original material LSNMO show two peaks, and the phenomenon of two peaks of ρ-T curves disappears for the composite samples, which can be explained by a competition between surface-phase resistivity induced by boundary-dependent scattering and body-phase resistivity induced by paramagnetism-ferromagnetism transition. For all the sam-ples in the low temperature range, MR increases continu-ously with the decrease of temperature, which shows a characteristic of low-field magnetoresistance. However, MR basically keeps the same in the high temperature range. The paramagnetism-ferromagnetism transition is observed in the high temperature range due to a composite between perov-skite manganite and insulator, which can enhance the tem-perature of MR appearance in the high temperature range and make it to appear near room temperature. For the sample with x = 0.12, MR remains constant at the value of 7.5 % in the temperature range of 300-260 K, which achieves a tem-perature stability of MR near room temperature. In addition,for the sample with x = 0.16, MR is above 6.8 % in the high temperature range of 318-252 K （△T = 66 K）. MR almost remains constant in this temperature range, which favors the practical application of MR.
基金supported by Foundation of Shanxi Scholarship Council(2016-075)Natural Science Foundation of Shanxi Normal University(ZR1601)Fund Program for the Scientific Activities of Selected Returned Overseas Professionals in Shanxi Province(2018-25)
文摘This paper is concerned with fundamental properties of a class of composite systems with fractional degree generalized frequency variables, including controllability, observability and stability. Firstly, some necessary and sufficient conditions are given to guarantee controllability and observability of such composite systems. Then we prove that the stability problem of such composite systems can be reduced to judging whether a fractional degree polynomial is stable. Finally, the stability analysis result is applied in the supervisory control of fractional-order multi-agent systems, and an example is provided to illustrate the effectiveness of the proposed methods.
基金the project of the National Key Research and Development Program of China(2018YFA0703300)the National Natural Science Foundation of China(52105302,52175271,52021003,and 91848204)+1 种基金the team of Innovation and entrepreneurship of Jilin Province(20210509047RQ,20210508057RQ)the Program for JLU Science and Technology Innovative Research Team(2017TD-04).
文摘On the base of controllable variable stiffness property,variable stiffness composites were the main components of functional materials in aerospace.However,the relatively low mechanical strength,stiffness range,and response rate restricted the application of variable stiffness composite.In this work,the novel variable stiffness composite system with characteristics of repeatable high load bearing and response rate was successfully prepared via the double-layer anisotropic structure to solve the bottlenecks of variable stiffness composites.The novel variable stiffness composite systems were composed of variable stiffness layer of polycaprolactone(PCL)and the driven layer of silicone elastomer with alcohol,which continuously changed Young’s modulus from 0.1 to 7.263 MPa(72.63 times variation)in 200 s and maintained maximum weight of 11.52 times its own weight(8.5 g).Attributed to the relatively high variable stiffness range and load bearing value of variable stiffness composite system,the repeatable response process led to the efficient high load driven as“muscle”and diversified precise grab of objects with different shapes as“gripper”,owning widespread application prospects in the field of bionics.
基金Supported by the National Natural Science Foundation of China under Grant Nos.50872159,50972014 and 51072024.
文摘We synthesize composite systems of multi-wall carbon nanotubes(MWCNTs)/SiO_(2) by using the sol−gel method.The dielectric properties of the systems with different-concentration MWCNTs are studied.In our MWCNTs/SiO_(2) inorganic systems,the twin−percolation phenomenon exists when the concentrations of MWCNTs are 5–10%and 15–20%.The permittivity and conductivity have jumping changes.The twin−percolation phenomenon is attributed to the special transfer mechanism of MWCNTs in the system,determined by hopping and migrating electrons.Variations of dielectric properties and conductance of the MWCNTs/SiO_(2) systems are conformed to the percolation theory.The special percolation phenomenon and electric properties of MWCNTs/SiO_(2) can help us comprehend the conductivity mechanism of the MWCNTs/SiO2 systems effectively,and promote the development of a high performance function composite system.
文摘The wetting behaviour of titanium carbide by molten nickel was investigated at different oxygen partial pressures by using the sessile drop method.Special attention was paid to the kinetics of wetting.Wetting process in the Ni/TiC system is controlled by the dissolution of TiC in the liquid phase.Discussions were made on the basis of the new experimental results achieved in the present investigation and those given in the literature for the Ni/TiC system and for some similar metal/carbon systems to elucidate how the interfacial dissolution reaction influences the wetting process.The reactive wetting process is a complex mat- ter and is very sensitive to the experimental conditions.Implantation of the wetting study in the composite processings was also suggested and the optimum processing is proposed.
文摘The purpose of this research was to fmd out effectiveness of chloride solid membrane electrode of coated wire system compared to solid membrane electrode of composite system, the Nernstian response and character＇s potential response （detection limit, selectivity and response time）. The chloride ISEs （ion selective electrodes） in this research were the solid membrane chloride ISEs based AgC1. There were two types of chloride ISEs that were developed, namely the chloride ISEs of coated wire and composite systems. Both types of electrodes were characterized. The selectivity was done by comparing Esel of the chloride standard solutions and Esel of the interference ions （Br- and I-）. The measurement of chloride ions in water samples was done by using the coated wire chloride ISE, the composite chloride ISE and the Mohr method. We compared the result of the two chloride ISE methods to that of standard method for chloride determination （Mohr） by using F-test and Post Hoc Test LSD （least significant difference） and Duncan. Analysis by using F-test and Post Hoc Test （LSD and Duncan） and characterization results of both the methods showed that coated wire chloride ISE was more effective compared to composite chloride ISE. Nemstian response was 59.83 mV/decade, linier range measurement was 10-1-10-5 M, limit detection was 1.23 × 10-5 M, response time along was 25 s and interfering ion was 10-4 M Br-.
基金co-supported by the National Key R&D Program of China(No.2023YFB4704400)the Zhejiang Provincial Natural Science Foundation of China(No.LQ24F030012)the National Natural Science Foundation of China General Project(No.62373033)。
文摘A composite anti-disturbance predictive control strategy employing a Multi-dimensional Taylor Network(MTN)is presented for unmanned systems subject to time-delay and multi-source disturbances.First,the multi-source disturbances are addressed according to their specific characteristics as follows:(A)an MTN data-driven model,which is used for uncertainty description,is designed accompanied with the mechanism model to represent the unmanned systems;(B)an adaptive MTN filter is used to remove the influence of the internal disturbance;(C)an MTN disturbance observer is constructed to estimate and compensate for the influence of the external disturbance;(D)the Extended Kalman Filter(EKF)algorithm is utilized as the learning mechanism for MTNs.Second,to address the time-delay effect,a recursiveτstep-ahead MTN predictive model is designed utilizing recursive technology,aiming to mitigate the impact of time-delay,and the EKF algorithm is employed as its learning mechanism.Then,the MTN predictive control law is designed based on the quadratic performance index.By implementing the proposed composite controller to unmanned systems,simultaneous feedforward compensation and feedback suppression to the multi-source disturbances are conducted.Finally,the convergence of the MTN and the stability of the closed-loop system are established utilizing the Lyapunov theorem.Two exemplary applications of unmanned systems involving unmanned vehicle and rigid spacecraft are presented to validate the effectiveness of the proposed approach.
基金funded by the National Natural Science Foundation of China(Nos.22073069,21773082)Science Research Project of Hebei Education Department(No.QN2024255)。
文摘In chemical science,the vertical ionization potential(VIP)is a crucial metric for understanding the electronegativity,hardness and softness of chemical material systems as well as the electronic structure and stability of molecules.Ever since the last century,the model chemistry composite methods have witnessed tremendous developments in computing the thermodynamic properties as well as the barrier heights.However,their performance in realm of the vertical electron processes of molecular systems has been rarely explored.In this study,we for the first time benchmarked the model chemistry composite methods(e.g.,CBS-QB3,G4 and W1BD)in comparison with the commonly used Koopmans's theorem(KT),electron propagator theory(e.g.,OVGF,D2,P3 and P3+)and CCSD(T)methods in calculating the VIP for up to 613 molecular systems with available experimental measurements.The large-scale test calculations strongly showed that the CBS-QB3 model chemistry composite technique can be well recommended to calculate VIP from the perspectives of accuracy,economy and applicability.Notably,the VIP values of up to 7 molecules were identified to have the absolute errors of larger than 0.3 e V at all calculation levels,which have strong hints that their VIP experimental values should be re-investigated.
基金Funded by the Science and Technology Program of Gansu Province(Nos.23JRRA799 and 24JRRA213)the National Natural Science Foundation of China(Nos.52178216,52008196,and U21A20150)。
文摘In order to explore the leaching law of different elements in the composite cementitious system composed of ferrous extraction tailing of nickel slag(FETNS)and ordinary Portland cement(OPC),element leaching test under different influencing factors was designed with the aid of ICP-OES,XRD,and SEM-EDS.The experimental results show that,with the extension of leaching time,the continuous hydration reaction in the system enables the leaching amount of Si,Al,Mg,and Ca elements to show an overall downward trend.In the alkaline environment,the more sufficient hydration reaction consumes more soluble elements,resulting in a significantly smaller leaching amount than that in the neutral environment.Temperature is also an important factor affecting the leaching of elements.The rise of temperature promotes the dissolution of amorphous phases Si,Al,and Mg in the system,leading to increased leaching amount and higher consumption of C_(2)S and C_(3)S,generating more reaction products.In addition,the content and fineness of FETNS also have a significant effect on the element leaching of the composite cementitious system.More importantly,this paper clarifies the leaching safety of internal heavy metal elements when FETNS is used under the above conditions,which provides a scientific guarantee for the safe and efficient application of FETNS in building materials.
基金Project(50875199) supported by the National Natural Science Foundation of ChinaProject supported by State Key Laboratory of Advanced Welding and Joining,China
文摘To improve the wettability of Al metal matrix composites（Al-MMCs） by common filler metals,Al-12Si-xTi（x=0.1,0.5,1,3.0;mass fraction,%） system active ternary filler metals were prepared.It was demonstrated that although the added Ti existed within Ti（Al1-xSix）3（0≤x≤0.15） phase,the shear strength and shear fracture surface of the developed Al-12Si-xTi brazes were quite similar to those of traditional Al-12Si braze due to the presence of similar microstructure of Al-Si eutectic microstructure with large volume fraction.So,small Ti addition（～1%） did not make the active brazes brittle and hard compared with the conventional Al-12Si braze.The measured melting range of each Al-12Si-xTi foil was very similar,i.e.,580-590 ℃,because the composition was close to that of eutectic.For wettability improvement,with increasing Ti content,the interfacial gap between the Al2O3 reinforcement and filler metal（R/M） could be eliminated,and the amount of the remainder of the active fillers on the composite substrate decreased after sessile drop test at 610 ℃ for 30 min.So,the wettability improvement became easy to observe repeatedly with increasing Ti content.Additionally,the amount and size of Ti（AlSi）3 phase were sensitive to the Ti content（before brazing） and Si content（after brazing）.
基金Project(2012MS0801)supported by the Natural Science Foundation of Inner Mongolia,China
文摘Al2O3p-Al composites were synthesized using an in-situ reaction in the 80%Al-20%CuO （mass fraction） system. The effects of the CuO particle size on the synthesis temperature and microstructure of the composites were investigated by various methods. The results indicate that the CuO particle size has a significant effect on the temperature at which the complete reaction in the Al-CuO system occurs：the temperature is 200 ℃ lower in the Al-CuO system containing CuO particles with sizes less than 6μm than that containing CuO particles with sizes less than 100μm. The interfacial bonding between Al2O3 particles and Al is not complete when the temperature is below a critical value. The morphology of the Al2O3 particles varies from ribbon-like shape to near spherical shape when the temperature is above a critical value. These two critical temperatures are affected by the particle size of CuO, and the critical temperature of the sample containing CuO particles with sizes less than 6μm is 100 ℃ lower than that of the sample containing CuO particles with sizes less than 100μm.
基金This research was funded by National Key R&D Program of China(2017YFC0702800),which is gratefully acknowledged.
文摘Internal thermal insulation composite system(ITICS)can be an important measure for the energy-saving retrofitting of buildings.However,ITICS may cause harmful effects on the hygrothermal performance of building envelopes.This work investigated the influence of the materials’hygric properties on the hygrothermal perfor-mance of a typical ITICS in different climate conditions in China.Two base wall materials,the traditional concrete and a new type aerated concrete,were tested and compared for their hygric properties firstly.The influence of the hygroscopicity of exterior plasters,the permeability of insulation materials and the climate conditions were then analyzed with WUFI simulations.The hygrothermal performance was evaluated with consideration of the total water content(TWC)of the walls and the moisture flux strength,the relative humidity(RH)and the mould growth risk at the interface between the base wall and the insulation layer(B-I interface).The numerical analysis implies that the TWC of internal insulated walls depends mainly on the hygroscopicity of exterior plaster and the wind-driven rain intensity.The upper limits for the water absorption coefficient of exterior plasters used in Bei-jing,Shanghai and Fuzhou are 1e-9,1e-10,1e-10 m^(2)/s respectively.When such limits are guaranteed,a vapour tight system created by using insulation materials with a large vapour resistance factor or adding a vapour barrier can improve the hygrothermal performance of ITICS,especially for concrete walls in cold climate.
