Practical applications of desulfurization gypsum are limited owing to its brittleness and low strength.To overcome these challenges,researchers have developed engineered desulfurization gypsum composites(EDGCs)by inco...Practical applications of desulfurization gypsum are limited owing to its brittleness and low strength.To overcome these challenges,researchers have developed engineered desulfurization gypsum composites(EDGCs)by incorporating ultrahigh molecular weight polyethylene(UHMWPE)fiber and sulfoaluminate cement(SAC).The mix ratio was optimized using response surface methodology(RSM).Experimental testing of EDGC under compressive and tensile loads led to the creation of a regression model that investigates the influence of variables and their interactions on the material’s compressive and tensile strengths.Additionally,microscopic morphology and hydration product composition were analyzed to explore the influence mechanism.The results indicated that EDGC’s compressive strength increased by up to 38.4%owing to a decreased water-binder ratio and higher SAC content.Similarly,tensile strength increased by up to 38.6%owing to increased SAC and fiber content.Moreover,EDGC demonstrated excellent strain-hardening behavior and multiple cracking characteristics,achieving a maximum tensile strain of nearly 3%.The research findings provide valuable insights for optimizing the performance of desulfurization gypsum.展开更多
To investigate the flexural behaviors of steel reinforced engineered cementitious composite （ECC） beams, the behaviors of the steel reinforced ECC beam and the conventional steel reinforced concrete beam subjected t...To investigate the flexural behaviors of steel reinforced engineered cementitious composite （ECC） beams, the behaviors of the steel reinforced ECC beam and the conventional steel reinforced concrete beam subjected to flexural load are experimentally compared. The experimental results show that the flexural strength and ductility of the steel reinforced ECC beam are 24.8% and 187.67% times larger than those of the steel reinforced concrete beam, and the substitution of concrete with ECC can significantly delay the propagation of cracks. Additionally, a simplified constitutive model of the ECC material is used to simulate the flexural behaviors of beams by the finite element analysis （FEA）. The results show a good agreement between the simulation and test results. The crack width of the steel reinforced ECC beam can be limited to 0.4 mm under the service load conditions. The application of ductile ECC can significantly increase the flexural performance in terms of flexural strength, deformation capacity and ductility of the beams.展开更多
In order to reduce the cost of high performance polyvinyl alcohol（PVA） fiber reinforced cementitious material（called engineered cementitious composites,ECC）,a ductile ECC material is developed using domestic PVA f...In order to reduce the cost of high performance polyvinyl alcohol（PVA） fiber reinforced cementitious material（called engineered cementitious composites,ECC）,a ductile ECC material is developed using domestic PVA fibers along with other local ingredients,such as fly ash,cement and sand.In addition to the economic analysis of ECC,the four-point bending test and the optical microscope are employed to investigate the deflection capacity of ECC,its crack width and the occurrence of the self-healing phenomenon.The experimental results suggest that ECC made with domestic ingredients exhibits larger deformability and the average crack width is controlled around 60 μm.Furthermore,the self-healing behavior is observed in cracks of the specimens after cycles of wet and dry curing.The economic analysis shows that the cost of ECC can be greatly reduced via employing domestic PVA fibers.It is,therefore,feasible to produce low cost ECC material employing domestic PVA fibers,while simultaneously retaining high material ductility.展开更多
The split Hopkinson pressure bar （SHPB） testing with diameter 40 mm was used to investigate the dynamic mechanical properties of engineered cementitious composites （ECCs） with different fly ash content. The basic ...The split Hopkinson pressure bar （SHPB） testing with diameter 40 mm was used to investigate the dynamic mechanical properties of engineered cementitious composites （ECCs） with different fly ash content. The basic properties including deformation, energy absorption capacity, strain-stress relationship and failure patterns were discussed. The ECCs showed strain-rate dependency and kept better plastic flow during impact process compared with reactive powder concrete （RPC） and concrete, but the critical compressive strength was lower than that of RPC and concrete. The bridging effect of PVA fiber and addition of fly ash can significantly improve the deformation and energy absorption capacities of ECCs. With the increase of fly ash content in ECCs, the static and dynamic compressive strength lowered and the dynamic increase factor enhanced. Therefore, to meet different engineering needs, the content of fly ash can be an important index to control the static and dynamic mechanical properties of ECCs.展开更多
In order to enhance the durability of steel encased concrete beams, a new type of steel reinforced engineered cementitious composite(SRECC) beam composed of steel shapes, steel bars and ECC is proposed. The theoretica...In order to enhance the durability of steel encased concrete beams, a new type of steel reinforced engineered cementitious composite(SRECC) beam composed of steel shapes, steel bars and ECC is proposed. The theoretical analyses of the SRECC beam including crack propagation and stress-strain distributions along the depth of the composite beam in different loading stages are conducted. A theoretical model and simplified design method are proposed to calculate the load carrying capacity. Based on the proposed theoretical model, the relationship between the moment and corresponding curvature is derived. The theoretical results are verified with the finite element analysis. Finally, an extensive parametric study is performed to study the effect of the matrix type, steel shape ratio, reinforced bar ratio, ECC compressive strength and ECC tensile ductility on the mechanical behavior of SRECC beams. The results show that substitution concrete with ECC can effectively improve the bearing capacity and ductility of composite beams. The steel shape and longitudinal reinforcement can enhance the loading carrying capacity, while the ductility decreases with the increase of steel shape ratio. ECC compressive strength has significant effects on both load carrying capacity and ductility, and changing the ultimate strain of ECC results in a very limited variation in the mechanical behavior of SRECC beams.展开更多
The effects of water/binder ratio （w/b） on the toughness behavior, compressive strength and flexural strength of engineered cementitious composites （ECC） were investigated. The w/b ratios of 0.25, 0.31, 0.33 and 0...The effects of water/binder ratio （w/b） on the toughness behavior, compressive strength and flexural strength of engineered cementitious composites （ECC） were investigated. The w/b ratios of 0.25, 0.31, 0.33 and 0.37 were selected and the specimens were tested at the ages of 7 d and 28 d. The experimental results showed that there was a corresponding increase in first cracking strength, modulus of rupture, compressive strength and flexural strength with the decrease of w/b. Within the w/b range of 0.25-0.37, higher w/b was found to have improved effects on deflection, strain hardening index and toughness index of ECC. In the permission of meeting the requirement of compressive strength grade, selecting higher w/b in mix design will help to obtain robust ECC.展开更多
Inhibition measurement of shrinkage of engineering cementitious composites （ECC） was investigated due to typical ECC with higher free drying shrinkage.The effects of expanded admixture （EA）,shrinkage reducing admi...Inhibition measurement of shrinkage of engineering cementitious composites （ECC） was investigated due to typical ECC with higher free drying shrinkage.The effects of expanded admixture （EA）,shrinkage reducing admixture （SRA）,coarse sand＋stone powder （CS＋SP） and superabsorbent polymer （SAP） on drying shrinkage and mechanical properties were studied.The experimental results show that ECC incorporating EA,SRA and coarse sand can retain around 60% of the typical ECC＇s free drying shrinkage.Superabsorbent polymerl（SAP） can delay the development of free drying shrinkage of ECC at different ages,and the effect of SAP is not distinct like the actions of EA,superabsorbent polymer（SRA） and coarse sand.Significantly,SAP may act as artificial flaw to form a more homogeneous defect system that increases the potential of saturated multiple cracking,hence the ductility of ECC will be improved greatly.展开更多
Tensile properties of fly ash based engineered geopolymer composites(FA-EGC)at different curing ages were studied by uniaxial tensile test and ultrasonic pulse velocity(UPV)methods,which included uniaxial tensile prop...Tensile properties of fly ash based engineered geopolymer composites(FA-EGC)at different curing ages were studied by uniaxial tensile test and ultrasonic pulse velocity(UPV)methods,which included uniaxial tensile properties,the correlation between ultrasonic pulse velocity and tensile properties,and characteristic parameters of microcracks.The experimental results show that obvious strain hardening behavior can be found in FA-EGC at different curing ages.With the increase of curing age,the tensile strength increases,the tensile strain decreases and the toughness becomes worse.The UPV of FA-EGC increases with curing age,and a strong correlation can be found between tensile strength and UPV.With the increase of curing age,the average crack width of FA-EGC decreases and the total number of cracks increases.This is because the strength of geopolymer increases fast at early age,thus the later strength development of FA-EGC tend to be stable.At the same time,the bond strength between fiber and matrix,and the friction of fiber/matrix interface continue to increase with curing age,thus the bridging effect of fiber is gradually strengthened.In conclusion,the increase of curing age is beneficial to the development of tensile properties of FA-EGC.展开更多
Engineered Cementitious Composites(ECC)is a class of high-performance fiber reinforced composites with ultra-ductility designed based on micromechanics,and it has been developed for increasing application in the const...Engineered Cementitious Composites(ECC)is a class of high-performance fiber reinforced composites with ultra-ductility designed based on micromechanics,and it has been developed for increasing application in the construction industry during recent decades.The properties of ECC at room temperature have been tested and studied in depth,however,few studies focus on its performance after high temperature that is one of the worst conditions to ECC.To investigate the change tendency and mechanism for the high temperature flexural properties of hybrid fiber reinforced ECC and the feasibility of calcium carbonate whisker to reduce the cost of ECC materials,polyvinyl alcohol fiber(PVA)reinforced strain hardening cementitious composites(PVA-ECC),steel fiber+PVA fiber reinforced ECC(defined as HyFRECC-A)and steel fiber+PVA fiber+CaCO3 whisker reinforced ECC(defined as HyFRECC-B)subject to room temperature and 200℃,400℃,600℃,800℃elevated temperature exposure were experimentally compared.The results indicate that equally replacing PVA fibers by steel fibers degraded the flexural hardening ability of PVA-ECC at room temperature,while the addition of appropriate amount of CaCO3 whisker improved the flexural strength,toughness and flexural hardening behavior.The elevated temperature posed a significant effect on the flexural strength and toughness of the three types of ECCs.Flexural deflection hardening behavior of the three types of ECCs was eliminated after high temperature exposure.Flexural strength and toughness of PVA-ECC presented an exponential decay along with the increase of temperature.The addition of steel fiber slowed down the decay rate.Although the use of CaCO3 whisker increased the post-temperature flexural strength and toughness of HyFRECC-B,the decay rate was not further decreased.展开更多
Hydroxypropyl methylcellulose （HPMC） and amphoteric polyacrylamide （ACPAM） were respectively used to prepare engineered cementitious composite （ECC） which exhibits strain-hardening behavior under uniaxial tensio...Hydroxypropyl methylcellulose （HPMC） and amphoteric polyacrylamide （ACPAM） were respectively used to prepare engineered cementitious composite （ECC） which exhibits strain-hardening behavior under uniaxial tension. The connections between cement paste structure and the performance of the composite in fresh and hardened state were investigated, aiming at achieving the desirable workability at a given solids concentration. The experimental results of viscosity and miCrostructure of cement pastes show that the intimate connections between flocculation groups lead to the growing increase in viscosity. The results of deformability and fiber dispersion demonstrate that fiber dispersion coefficient is a comprehensive index which can reflect the performance of deformability as well as uniformity. And the desirable fresh mixture can be achieved by optimizing the viscosity of cement paste. At last, the ductile strain-hardening performance of the ECC prepared with HPMC or ACPAM was investigated through uniaxial tensile test.展开更多
Plain concrete is strong in compression but brittle in tension,having a low tensile strain capacity that can significantly degrade the long-term performance of concrete structures,even when steel reinforcing is presen...Plain concrete is strong in compression but brittle in tension,having a low tensile strain capacity that can significantly degrade the long-term performance of concrete structures,even when steel reinforcing is present.In order to address these challenges,short polymer fibers are randomly dispersed in a cement-based matrix to forma highly ductile engineered cementitious composite(ECC).Thismaterial exhibits high ductility under tensile forces,with its tensile strain being several hundred times greater than conventional concrete.Since concrete is inherently weak in tension,the tensile strain capacity(TSC)has become one of the most extensively researched properties.As a result,developing a model to predict the TSC of the ECC and to optimize the mixture proportions becomes challenging.Meanwhile,the effort required for laboratory trial batches to determine the TSC is reduced.To achieve the research objectives,five distinct models,artificial neural network(ANN),nonlinear model(NLR),linear relationship model(LR),multi-logistic model(MLR),and M5P-tree model(M5P),are investigated and employed to predict the TSCof ECCmixtures containing fly ash.Data from115 mixtures are gathered and analyzed to develop a new model.The input variables include mixture proportions,fiber length and diameter,and the time required for curing the various mixtures.The model’s effectiveness is evaluated and verified based on statistical parameters such as R2,mean absolute error(MAE),scatter index(SI),root mean squared error(RMSE),and objective function(OBJ)value.Consequently,the ANN model outperforms the others in predicting the TSC of the ECC,with RMSE,MAE,OBJ,SI,and R2 values of 0.42%,0.3%,0.33%,0.135%,and 0.98,respectively.展开更多
The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolyme...The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolymer composite(EGC)is a promising material featured by eco-friendly,fast-setting and strain-hardening characteristics for emergent strengthening and construction.However,the fiber optimization for preparing EGC and its protective effect on structural elements under blast scenarios are uncertain.In this study,laboratory tests were firstly conducted to evaluate the effects of fiber types on the properties of EGC in terms of workability,dry shrinkage,and mechanical properties in compression,tension and flexure.The experimental results showed that EGC containing PE fiber exhibited suitable workability,acceptable dry shrinkage and superior mechanical properties compared with other types of fibers.After that,a series of field tests were carried out to evaluate the effectiveness of EGC retrofitting layer on the enhancement of blast performance of typical elements.The tests include autoclaved aerated concrete(AAC)masonry walls subjected to vented gas explosion,reinforced AAC panels subjected to TNT explosion and plain concrete slabs subjected to contact explosion.It was found that EGC could effectively enhance the blast resistance of structural elements in different scenarios.For AAC masonry walls and panels,with the existence of EGC,the integrity of specimens could be maintained,and their deflections and damage were significantly reduced.For plain concrete slabs,the EGC overlay could reduce the diameter and depth of the crater and spallation of specimens.展开更多
An engineered cementitious composite （ECC） is introduced to partially substitute concrete in the tension zone of a reinforced concrete beam to form an ECC/reinforced concrete （RC） composite beam, which can increas...An engineered cementitious composite （ECC） is introduced to partially substitute concrete in the tension zone of a reinforced concrete beam to form an ECC/reinforced concrete （RC） composite beam, which can increase the ductility and crack resisting ability of the beam. Based on the assumption of the plane remaining plane and the simplified constitutive models of materials, the stress and strain distributions along the depth of the composite beam in different loading stages are comprehensively investigated to obtain calculation methods of the load-carrying capacities for different stages. Also, a simplified formula for the ultimate load carrying capacity is proposed according to the Chinese code for the design of concrete structures. The relationship between the moment and curvature for the composite beam is also proposed together with a simplified calculation method for ductility of the ECC/RC composite beam. Finally, the calculation method is demonstrated with the test results of a composite beam. Comparison results show that the calculation results have good consistency with the test results, proving that the proposed calculation methods are reliable with a certain theoretical significance and reference value.展开更多
In order to improve the load capacity, seismic performance and performance-cost ratio of the columns, the concrete at the base of reinforced concrete （RC） columns is substituted with engineered cementitious composit...In order to improve the load capacity, seismic performance and performance-cost ratio of the columns, the concrete at the base of reinforced concrete （RC） columns is substituted with engineered cementitious composites （ECC） to form ECC/RC composite columns. Based on the existing material properties, the mechanical behaviors of the ECC columns, ECC/RC composite columns and RC columns were numerically studied under combined vertical and horizontal loading with the software of ATENA. Then, the failure mechanism of ECC columns and ECC/RC composite columns were comprehensively studied and compared with that of the RC columns. Then, the effects of the height of the ECC, the axial compression ratio, and the transverse reinforcement ratio on the mechanical behaviors of the composite or the ECC column are studied. The calculation results show that the ultimate load capacity, ductility and crack resistance of the ECC or ECC/RC composite columns are superior to those of the RC columns. The ECC/RC composite column with a height of the ECC layer of 1.2h （ h is the height of the cross section） can achieve similar mechanical properties of a full ECC column. With high shear strength, ECC can undertake the shear force and significantly reduce the amount of stirrups, avoiding construction issues and promoting its engineering application.展开更多
Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable M...Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable MAMs under some rigorous conditions,while their composites still fail to produce satisfactory microwave absorption performance regardless of the improvements as compared with the individuals.Herein,we have successfully implemented compositional and structural engineering to fabricate hollow Si C/C microspheres with controllable composition.The simultaneous modulation on dielectric properties and impedance matching can be easily achieved as the change in the composition of these composites.The formation of hollow structure not only favors lightweight feature,but also generates considerable contribution to microwave attenuation capacity.With the synergistic effect of composition and structure,the optimized SiC/C composite exhibits excellent performance,whose the strongest reflection loss intensity and broadest effective absorption reach-60.8 dB and 5.1 GHz,respectively,and its microwave absorption properties are actually superior to those of most SiC/C composites in previous studies.In addition,the stability tests of microwave absorption capacity after exposure to harsh conditions and Radar Cross Section simulation data demonstrate that hollow SiC/C microspheres from compositional and structural optimization have a bright prospect in practical applications.展开更多
To improve the seismic performance of columns, engineered cementitious composite （ECC） is introduced to partially substitute concrete at the base of the columns to form ECC,/reinforced concrete （ RC） composite col...To improve the seismic performance of columns, engineered cementitious composite （ECC） is introduced to partially substitute concrete at the base of the columns to form ECC,/reinforced concrete （ RC） composite columns. The mechanical behaviors of the ECC/RC composite columns are numerically studied under low-cyclic loading with the finite element analysis softwareof MSC. MARC. It is found that the ECC/RC composite columns can significantly enhance the load capacity, the ductility ad energy dissipation of columns. Then, the effects of the height of the ECC, the axial compression ratio and the longitudinal reinforcement ratio on the seismic behaviors of the composite columns are parametrically studied. The results show that the ECC/RC composite column with a height of the ECC layer of 0. Sh（h is the height to the cross-section） can achieve similar seismic performance of a full ECC column. The peak load of the composite column increases significantly while the ductility decreases with the increase of the axial compression ratio. Increasing the longitudinal reinforcement ratio within a certain range can improve the ductility and energy dissipation capacity and almost has no effect on load capacity. The aalysis results ae instructive and valuable for reference in designing ECC structures.展开更多
A novel engineered cementitious composite(ECC) was prepared with the complex binder of Portland cement and asphalt emulsion.By adjusting the amount of asphalt emulsion,different mixture proportions were adopted in exp...A novel engineered cementitious composite(ECC) was prepared with the complex binder of Portland cement and asphalt emulsion.By adjusting the amount of asphalt emulsion,different mixture proportions were adopted in experiments,including four-point bending test,compressive test,and scanning electric microscopy(SEM).The SEM observation was conducted to evaluate the contribution of polyvinyl alcohol(PVA) fiber and asphalt emulsion to the composite toughening mechanism.The tests results show that the most remarkable deflection-hardening behavior and saturated multiple cracking are achieved when the content of asphalt emulsion is 10%.However,excessive content of asphalt emulsion causes severe damages on the deformation behavior as well as loss in compressive strength of the mixture.SEM observation indicates that the influence of asphalt emulsion on the fiber/matrix interfacial property changes the dominant fiber failure type from rupture into pull-out mode,and thus causes beneficial effects for strain-hardening behavior.展开更多
In this work,we open an avenue toward rational design of potential efficient catalysts for sustainable ammonia synthesis through composition engineering strategy by exploiting the synergistic effects among the active ...In this work,we open an avenue toward rational design of potential efficient catalysts for sustainable ammonia synthesis through composition engineering strategy by exploiting the synergistic effects among the active sites as exemplified by diatomic metals anchored graphdiyne via the combination of hierarchical high-throughput screening,first-principles calculations,and molecular dynamics simulations.Totally 43 highly efficient catalysts feature ultralow onset potentials(|U_(onset)|≤0.40 V)with Rh-Hf and Rh-Ta showing negligible onset potentials of 0 and-0.04 V,respectively.Extremely high catalytic activities of Rh-Hf and Rh-Ta can be ascribed to the synergistic effects.When forming heteronuclears,the combinations of relatively weak(such as Rh)and relatively strong(such as Hf or Ta)components usually lead to the optimal strengths of adsorption Gibbs free energies of reaction intermediates.The origin can be ascribed to the mediate d-band centers of Rh-Hf and Rh-Ta,which lead to the optimal adsorption strengths of intermediates,thereby bringing the high catalytic activities.Our work provides a new and general strategy toward the architecture of highly efficient catalysts not only for electrocatalytic nitrogen reduction reaction(eNRR)but also for other important reactions.We expect that our work will boost both experimental and theoretical efforts in this direction.展开更多
Exploiting high-efficiency Ni-based materials for electrocatalytic urea oxidation reaction(UOR) is critical for urea-related technologies.The catalytic site density,intrinsic activity,charge transfer,and mass diffusio...Exploiting high-efficiency Ni-based materials for electrocatalytic urea oxidation reaction(UOR) is critical for urea-related technologies.The catalytic site density,intrinsic activity,charge transfer,and mass diffusion determine overall electrocatalytic efficiency.Simultaneous modulation over the above four factors promises advanced electrocatalysis,yet challenging.Herein we propose a systematic regulation tactic over composition and geometric structure,constructing a nanocomposite comprising Mn doped Ni_(3)N nanoparticles anchored on reduced graphene oxide(rGO/Mn-Ni_(3)N),achieving elegant integration of four design principles into one,thereby eminently boosting UOR.Particularly,Mn doping in Ni_(3)N can modulate electronic state to induce intrinsic activity regulation.Combining metallic Mn-Ni_(3)N with rGO to engineer hierarchical architecture not only promotes charge transfer,but also enriches active site population.Intriguingly,improved hydrophilicity could impart better electrolyte penetration and gas escape.Consequently,such system-optimized rGO/Mn-Ni_(3)N demonstrates state-of-the-art-level UOR electrocatalysis.This work offers a novel paradigm to create advanced catalysts via systematic and integrated modulation.展开更多
In order to improve the seismic performance, deformation ability and ultimate load-carrying capacity of columns with rectangular cross section, engineered cementitious composite （ECC） is introduced to partially subs...In order to improve the seismic performance, deformation ability and ultimate load-carrying capacity of columns with rectangular cross section, engineered cementitious composite （ECC） is introduced to partially substitute concrete in the edge zone of reinforced concrete columns and form reinforced ECC/concrete composite columns. Firstly, based on the assumption of plane remaining plane and the simplified constitutive models, the calculation method of the load-carrying capacity of reinforced ECC/concrete columns is proposed. The stress and strain distribu- tions and crack propagation of the composite columns in different states of eccentric compressive loading are ana- lyzed. Then, nonlinear finite element analysis is conducted to study the mechanical performance of reinforced ECC/concrete composite columns with rectangular cross section. It is found that the simulation results are in good agreement with the theoretical results, indicating that the proposed method for calculating the load-carrying capacity of concrete/ECC composite columns is valid. Finally, based on the proposed method, the effects of ECC thickness, com- pressive strength of concrete and longitudinal reinforcement ratio on the mechanical performance of reinforced ECC/ concrete composite columns are analyzed. Calculation results indicate that increasing the thickness of ECC layer or longitudinal reinforcement ratio can effectively increase the ultimate load-carrying capacity of the composite column with both small and large eccentricity, but increasing the strength of concrete can only increase the ultimate Ioad- carrying capacity of the composite column with small eccentricity.展开更多
基金The National Natural Science Foundation of China(No.51978504).
文摘Practical applications of desulfurization gypsum are limited owing to its brittleness and low strength.To overcome these challenges,researchers have developed engineered desulfurization gypsum composites(EDGCs)by incorporating ultrahigh molecular weight polyethylene(UHMWPE)fiber and sulfoaluminate cement(SAC).The mix ratio was optimized using response surface methodology(RSM).Experimental testing of EDGC under compressive and tensile loads led to the creation of a regression model that investigates the influence of variables and their interactions on the material’s compressive and tensile strengths.Additionally,microscopic morphology and hydration product composition were analyzed to explore the influence mechanism.The results indicated that EDGC’s compressive strength increased by up to 38.4%owing to a decreased water-binder ratio and higher SAC content.Similarly,tensile strength increased by up to 38.6%owing to increased SAC and fiber content.Moreover,EDGC demonstrated excellent strain-hardening behavior and multiple cracking characteristics,achieving a maximum tensile strain of nearly 3%.The research findings provide valuable insights for optimizing the performance of desulfurization gypsum.
基金The National Natural Science Foundation of China(No.51278118)the National Basic Research Program of China(973Program)(No.2009CB623200)the Natural Science Foundation of Jiangsu Province(No.BK2012756)
文摘To investigate the flexural behaviors of steel reinforced engineered cementitious composite （ECC） beams, the behaviors of the steel reinforced ECC beam and the conventional steel reinforced concrete beam subjected to flexural load are experimentally compared. The experimental results show that the flexural strength and ductility of the steel reinforced ECC beam are 24.8% and 187.67% times larger than those of the steel reinforced concrete beam, and the substitution of concrete with ECC can significantly delay the propagation of cracks. Additionally, a simplified constitutive model of the ECC material is used to simulate the flexural behaviors of beams by the finite element analysis （FEA）. The results show a good agreement between the simulation and test results. The crack width of the steel reinforced ECC beam can be limited to 0.4 mm under the service load conditions. The application of ductile ECC can significantly increase the flexural performance in terms of flexural strength, deformation capacity and ductility of the beams.
基金The National Natural Science Foundation of China (No.51008071,51278097)the Natural Science Foundation of Jiangsu Province(No.BK2010413)+2 种基金Teaching & Research Excellence Grant for Young Faculty Member at Southeast Universitythe Program for Special Talents in Six Major Fields of Jiangsu Province(No.2011-JZ-011)the Scientific Research Innovation Project for College Graduates in Jiangsu Province(No.CXLX_0136)
文摘In order to reduce the cost of high performance polyvinyl alcohol（PVA） fiber reinforced cementitious material（called engineered cementitious composites,ECC）,a ductile ECC material is developed using domestic PVA fibers along with other local ingredients,such as fly ash,cement and sand.In addition to the economic analysis of ECC,the four-point bending test and the optical microscope are employed to investigate the deflection capacity of ECC,its crack width and the occurrence of the self-healing phenomenon.The experimental results suggest that ECC made with domestic ingredients exhibits larger deformability and the average crack width is controlled around 60 μm.Furthermore,the self-healing behavior is observed in cracks of the specimens after cycles of wet and dry curing.The economic analysis shows that the cost of ECC can be greatly reduced via employing domestic PVA fibers.It is,therefore,feasible to produce low cost ECC material employing domestic PVA fibers,while simultaneously retaining high material ductility.
文摘The split Hopkinson pressure bar （SHPB） testing with diameter 40 mm was used to investigate the dynamic mechanical properties of engineered cementitious composites （ECCs） with different fly ash content. The basic properties including deformation, energy absorption capacity, strain-stress relationship and failure patterns were discussed. The ECCs showed strain-rate dependency and kept better plastic flow during impact process compared with reactive powder concrete （RPC） and concrete, but the critical compressive strength was lower than that of RPC and concrete. The bridging effect of PVA fiber and addition of fly ash can significantly improve the deformation and energy absorption capacities of ECCs. With the increase of fly ash content in ECCs, the static and dynamic compressive strength lowered and the dynamic increase factor enhanced. Therefore, to meet different engineering needs, the content of fly ash can be an important index to control the static and dynamic mechanical properties of ECCs.
基金The National Natural Science Foundation of China(No.51778183)the National Key Research and Development Program of China(No.2016YFC0701907)the Distinguished Young Scholar Foundation of Jiangsu Province(No.BK20160027)
文摘In order to enhance the durability of steel encased concrete beams, a new type of steel reinforced engineered cementitious composite(SRECC) beam composed of steel shapes, steel bars and ECC is proposed. The theoretical analyses of the SRECC beam including crack propagation and stress-strain distributions along the depth of the composite beam in different loading stages are conducted. A theoretical model and simplified design method are proposed to calculate the load carrying capacity. Based on the proposed theoretical model, the relationship between the moment and corresponding curvature is derived. The theoretical results are verified with the finite element analysis. Finally, an extensive parametric study is performed to study the effect of the matrix type, steel shape ratio, reinforced bar ratio, ECC compressive strength and ECC tensile ductility on the mechanical behavior of SRECC beams. The results show that substitution concrete with ECC can effectively improve the bearing capacity and ductility of composite beams. The steel shape and longitudinal reinforcement can enhance the loading carrying capacity, while the ductility decreases with the increase of steel shape ratio. ECC compressive strength has significant effects on both load carrying capacity and ductility, and changing the ultimate strain of ECC results in a very limited variation in the mechanical behavior of SRECC beams.
基金Funded by the National Natural Science Foundation of China (No.50872127)the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
文摘The effects of water/binder ratio （w/b） on the toughness behavior, compressive strength and flexural strength of engineered cementitious composites （ECC） were investigated. The w/b ratios of 0.25, 0.31, 0.33 and 0.37 were selected and the specimens were tested at the ages of 7 d and 28 d. The experimental results showed that there was a corresponding increase in first cracking strength, modulus of rupture, compressive strength and flexural strength with the decrease of w/b. Within the w/b range of 0.25-0.37, higher w/b was found to have improved effects on deflection, strain hardening index and toughness index of ECC. In the permission of meeting the requirement of compressive strength grade, selecting higher w/b in mix design will help to obtain robust ECC.
基金Funded by the National Natural Science Foundation of China (No.50872127)Heilongjiang Provincial Scientific Research Foundation for Returned Overseas Scholars
文摘Inhibition measurement of shrinkage of engineering cementitious composites （ECC） was investigated due to typical ECC with higher free drying shrinkage.The effects of expanded admixture （EA）,shrinkage reducing admixture （SRA）,coarse sand＋stone powder （CS＋SP） and superabsorbent polymer （SAP） on drying shrinkage and mechanical properties were studied.The experimental results show that ECC incorporating EA,SRA and coarse sand can retain around 60% of the typical ECC＇s free drying shrinkage.Superabsorbent polymerl（SAP） can delay the development of free drying shrinkage of ECC at different ages,and the effect of SAP is not distinct like the actions of EA,superabsorbent polymer（SRA） and coarse sand.Significantly,SAP may act as artificial flaw to form a more homogeneous defect system that increases the potential of saturated multiple cracking,hence the ductility of ECC will be improved greatly.
基金Funded by the National Natural Science Foundation of China(Nos.52178241 and 52242807)the Fundamental Research Funds for the Central Universities(No.64522120220599 and 2023-2-YB-20)the National Key Research and Development Program of China during the Fourteenth Five-Year Plan Period(Nos.2021YFB3802001 and 2019YFE0112600)。
文摘Tensile properties of fly ash based engineered geopolymer composites(FA-EGC)at different curing ages were studied by uniaxial tensile test and ultrasonic pulse velocity(UPV)methods,which included uniaxial tensile properties,the correlation between ultrasonic pulse velocity and tensile properties,and characteristic parameters of microcracks.The experimental results show that obvious strain hardening behavior can be found in FA-EGC at different curing ages.With the increase of curing age,the tensile strength increases,the tensile strain decreases and the toughness becomes worse.The UPV of FA-EGC increases with curing age,and a strong correlation can be found between tensile strength and UPV.With the increase of curing age,the average crack width of FA-EGC decreases and the total number of cracks increases.This is because the strength of geopolymer increases fast at early age,thus the later strength development of FA-EGC tend to be stable.At the same time,the bond strength between fiber and matrix,and the friction of fiber/matrix interface continue to increase with curing age,thus the bridging effect of fiber is gradually strengthened.In conclusion,the increase of curing age is beneficial to the development of tensile properties of FA-EGC.
基金This study was supported by the National Natural Science Foundation of China(51908247)Jiangsu Natural Science Foundation Project(BK20170192)Open Fund Project of State Key Laboratory of Green Building Materials(YA-616).
文摘Engineered Cementitious Composites(ECC)is a class of high-performance fiber reinforced composites with ultra-ductility designed based on micromechanics,and it has been developed for increasing application in the construction industry during recent decades.The properties of ECC at room temperature have been tested and studied in depth,however,few studies focus on its performance after high temperature that is one of the worst conditions to ECC.To investigate the change tendency and mechanism for the high temperature flexural properties of hybrid fiber reinforced ECC and the feasibility of calcium carbonate whisker to reduce the cost of ECC materials,polyvinyl alcohol fiber(PVA)reinforced strain hardening cementitious composites(PVA-ECC),steel fiber+PVA fiber reinforced ECC(defined as HyFRECC-A)and steel fiber+PVA fiber+CaCO3 whisker reinforced ECC(defined as HyFRECC-B)subject to room temperature and 200℃,400℃,600℃,800℃elevated temperature exposure were experimentally compared.The results indicate that equally replacing PVA fibers by steel fibers degraded the flexural hardening ability of PVA-ECC at room temperature,while the addition of appropriate amount of CaCO3 whisker improved the flexural strength,toughness and flexural hardening behavior.The elevated temperature posed a significant effect on the flexural strength and toughness of the three types of ECCs.Flexural deflection hardening behavior of the three types of ECCs was eliminated after high temperature exposure.Flexural strength and toughness of PVA-ECC presented an exponential decay along with the increase of temperature.The addition of steel fiber slowed down the decay rate.Although the use of CaCO3 whisker increased the post-temperature flexural strength and toughness of HyFRECC-B,the decay rate was not further decreased.
基金Funded by the National Natural Science Foundation of China(No.50978031)the Special Fund for Basic Scientific Research of Central Colleges(Chang'an University,No.CHD2011TD003,CHD2011ZY002,CHD2011JC018)
文摘Hydroxypropyl methylcellulose （HPMC） and amphoteric polyacrylamide （ACPAM） were respectively used to prepare engineered cementitious composite （ECC） which exhibits strain-hardening behavior under uniaxial tension. The connections between cement paste structure and the performance of the composite in fresh and hardened state were investigated, aiming at achieving the desirable workability at a given solids concentration. The experimental results of viscosity and miCrostructure of cement pastes show that the intimate connections between flocculation groups lead to the growing increase in viscosity. The results of deformability and fiber dispersion demonstrate that fiber dispersion coefficient is a comprehensive index which can reflect the performance of deformability as well as uniformity. And the desirable fresh mixture can be achieved by optimizing the viscosity of cement paste. At last, the ductile strain-hardening performance of the ECC prepared with HPMC or ACPAM was investigated through uniaxial tensile test.
文摘Plain concrete is strong in compression but brittle in tension,having a low tensile strain capacity that can significantly degrade the long-term performance of concrete structures,even when steel reinforcing is present.In order to address these challenges,short polymer fibers are randomly dispersed in a cement-based matrix to forma highly ductile engineered cementitious composite(ECC).Thismaterial exhibits high ductility under tensile forces,with its tensile strain being several hundred times greater than conventional concrete.Since concrete is inherently weak in tension,the tensile strain capacity(TSC)has become one of the most extensively researched properties.As a result,developing a model to predict the TSC of the ECC and to optimize the mixture proportions becomes challenging.Meanwhile,the effort required for laboratory trial batches to determine the TSC is reduced.To achieve the research objectives,five distinct models,artificial neural network(ANN),nonlinear model(NLR),linear relationship model(LR),multi-logistic model(MLR),and M5P-tree model(M5P),are investigated and employed to predict the TSCof ECCmixtures containing fly ash.Data from115 mixtures are gathered and analyzed to develop a new model.The input variables include mixture proportions,fiber length and diameter,and the time required for curing the various mixtures.The model’s effectiveness is evaluated and verified based on statistical parameters such as R2,mean absolute error(MAE),scatter index(SI),root mean squared error(RMSE),and objective function(OBJ)value.Consequently,the ANN model outperforms the others in predicting the TSC of the ECC,with RMSE,MAE,OBJ,SI,and R2 values of 0.42%,0.3%,0.33%,0.135%,and 0.98,respectively.
基金National Natural Science Foundation of China(Grant Nos.51908188 and 51938011).
文摘The recent increase in blast/bombing incidents all over the world has pushed the development of effective strengthening approaches to enhance the blast resistance of existing civil infrastructures.Engineered geopolymer composite(EGC)is a promising material featured by eco-friendly,fast-setting and strain-hardening characteristics for emergent strengthening and construction.However,the fiber optimization for preparing EGC and its protective effect on structural elements under blast scenarios are uncertain.In this study,laboratory tests were firstly conducted to evaluate the effects of fiber types on the properties of EGC in terms of workability,dry shrinkage,and mechanical properties in compression,tension and flexure.The experimental results showed that EGC containing PE fiber exhibited suitable workability,acceptable dry shrinkage and superior mechanical properties compared with other types of fibers.After that,a series of field tests were carried out to evaluate the effectiveness of EGC retrofitting layer on the enhancement of blast performance of typical elements.The tests include autoclaved aerated concrete(AAC)masonry walls subjected to vented gas explosion,reinforced AAC panels subjected to TNT explosion and plain concrete slabs subjected to contact explosion.It was found that EGC could effectively enhance the blast resistance of structural elements in different scenarios.For AAC masonry walls and panels,with the existence of EGC,the integrity of specimens could be maintained,and their deflections and damage were significantly reduced.For plain concrete slabs,the EGC overlay could reduce the diameter and depth of the crater and spallation of specimens.
基金The National Natural Science Foundation of China(No. 50808043)the National Basic Research Program of China (973 Program) (No. 2009CB623200)Foundation of Jiangsu Key Laboratory of Construction Materials,Program for Special Talents in Six Fields of Jiangsu Province(No. 2011-JZ-010)
文摘An engineered cementitious composite （ECC） is introduced to partially substitute concrete in the tension zone of a reinforced concrete beam to form an ECC/reinforced concrete （RC） composite beam, which can increase the ductility and crack resisting ability of the beam. Based on the assumption of the plane remaining plane and the simplified constitutive models of materials, the stress and strain distributions along the depth of the composite beam in different loading stages are comprehensively investigated to obtain calculation methods of the load-carrying capacities for different stages. Also, a simplified formula for the ultimate load carrying capacity is proposed according to the Chinese code for the design of concrete structures. The relationship between the moment and curvature for the composite beam is also proposed together with a simplified calculation method for ductility of the ECC/RC composite beam. Finally, the calculation method is demonstrated with the test results of a composite beam. Comparison results show that the calculation results have good consistency with the test results, proving that the proposed calculation methods are reliable with a certain theoretical significance and reference value.
基金The National Natural Science Foundation of China(No.51278118)the Natural Science Foundation of Jiangsu Province(No.BK2012756)the Key Project of Ministry of Education of China(No.113029A)
文摘In order to improve the load capacity, seismic performance and performance-cost ratio of the columns, the concrete at the base of reinforced concrete （RC） columns is substituted with engineered cementitious composites （ECC） to form ECC/RC composite columns. Based on the existing material properties, the mechanical behaviors of the ECC columns, ECC/RC composite columns and RC columns were numerically studied under combined vertical and horizontal loading with the software of ATENA. Then, the failure mechanism of ECC columns and ECC/RC composite columns were comprehensively studied and compared with that of the RC columns. Then, the effects of the height of the ECC, the axial compression ratio, and the transverse reinforcement ratio on the mechanical behaviors of the composite or the ECC column are studied. The calculation results show that the ultimate load capacity, ductility and crack resistance of the ECC or ECC/RC composite columns are superior to those of the RC columns. The ECC/RC composite column with a height of the ECC layer of 1.2h （ h is the height of the cross section） can achieve similar mechanical properties of a full ECC column. With high shear strength, ECC can undertake the shear force and significantly reduce the amount of stirrups, avoiding construction issues and promoting its engineering application.
基金supported by the National Natural Science Foundation of China(No.21676065 and No.52373262)China Postdoctoral Science Foundation(2021MD703944,2022T150782).
文摘Microwave absorbing materials(MAMs)characterized by high absorption efficiency and good environmental tolerance are highly desirable in practical applications.Both silicon carbide and carbon are considered as stable MAMs under some rigorous conditions,while their composites still fail to produce satisfactory microwave absorption performance regardless of the improvements as compared with the individuals.Herein,we have successfully implemented compositional and structural engineering to fabricate hollow Si C/C microspheres with controllable composition.The simultaneous modulation on dielectric properties and impedance matching can be easily achieved as the change in the composition of these composites.The formation of hollow structure not only favors lightweight feature,but also generates considerable contribution to microwave attenuation capacity.With the synergistic effect of composition and structure,the optimized SiC/C composite exhibits excellent performance,whose the strongest reflection loss intensity and broadest effective absorption reach-60.8 dB and 5.1 GHz,respectively,and its microwave absorption properties are actually superior to those of most SiC/C composites in previous studies.In addition,the stability tests of microwave absorption capacity after exposure to harsh conditions and Radar Cross Section simulation data demonstrate that hollow SiC/C microspheres from compositional and structural optimization have a bright prospect in practical applications.
基金The National Natural Science Foundation of China(No.51278118)the Natural Science Foundation of Jiangsu Province(No.BK2012756)+1 种基金the Key Project of Ministry of Education of China(No.113029A)the Third Five-Year Major Scientific and Technological Project of China Metallurgical Group Corporation
文摘To improve the seismic performance of columns, engineered cementitious composite （ECC） is introduced to partially substitute concrete at the base of the columns to form ECC,/reinforced concrete （ RC） composite columns. The mechanical behaviors of the ECC/RC composite columns are numerically studied under low-cyclic loading with the finite element analysis softwareof MSC. MARC. It is found that the ECC/RC composite columns can significantly enhance the load capacity, the ductility ad energy dissipation of columns. Then, the effects of the height of the ECC, the axial compression ratio and the longitudinal reinforcement ratio on the seismic behaviors of the composite columns are parametrically studied. The results show that the ECC/RC composite column with a height of the ECC layer of 0. Sh（h is the height to the cross-section） can achieve similar seismic performance of a full ECC column. The peak load of the composite column increases significantly while the ductility decreases with the increase of the axial compression ratio. Increasing the longitudinal reinforcement ratio within a certain range can improve the ductility and energy dissipation capacity and almost has no effect on load capacity. The aalysis results ae instructive and valuable for reference in designing ECC structures.
基金Project(2011BAE27B04)supported by the National Key Technology R&D Program of ChinaProjects(CHD2011TD003,CHD2011ZD017)supported by the Special Fund for Basic Scientific Research of Central Colleges in Chang’an University,China
文摘A novel engineered cementitious composite(ECC) was prepared with the complex binder of Portland cement and asphalt emulsion.By adjusting the amount of asphalt emulsion,different mixture proportions were adopted in experiments,including four-point bending test,compressive test,and scanning electric microscopy(SEM).The SEM observation was conducted to evaluate the contribution of polyvinyl alcohol(PVA) fiber and asphalt emulsion to the composite toughening mechanism.The tests results show that the most remarkable deflection-hardening behavior and saturated multiple cracking are achieved when the content of asphalt emulsion is 10%.However,excessive content of asphalt emulsion causes severe damages on the deformation behavior as well as loss in compressive strength of the mixture.SEM observation indicates that the influence of asphalt emulsion on the fiber/matrix interfacial property changes the dominant fiber failure type from rupture into pull-out mode,and thus causes beneficial effects for strain-hardening behavior.
基金support from the National Natural Science Foundation of China(22073033,21873032,21673087,21903032)startup fund(2006013118 and 3004013105)from Huazhong University of Science and Technology+1 种基金the Fundamental Research Funds for the Central Universities(2019kfyRCPY116)the Innovation and Talent Recruitment Base of New Energy Chemistry and Device(B21003)
文摘In this work,we open an avenue toward rational design of potential efficient catalysts for sustainable ammonia synthesis through composition engineering strategy by exploiting the synergistic effects among the active sites as exemplified by diatomic metals anchored graphdiyne via the combination of hierarchical high-throughput screening,first-principles calculations,and molecular dynamics simulations.Totally 43 highly efficient catalysts feature ultralow onset potentials(|U_(onset)|≤0.40 V)with Rh-Hf and Rh-Ta showing negligible onset potentials of 0 and-0.04 V,respectively.Extremely high catalytic activities of Rh-Hf and Rh-Ta can be ascribed to the synergistic effects.When forming heteronuclears,the combinations of relatively weak(such as Rh)and relatively strong(such as Hf or Ta)components usually lead to the optimal strengths of adsorption Gibbs free energies of reaction intermediates.The origin can be ascribed to the mediate d-band centers of Rh-Hf and Rh-Ta,which lead to the optimal adsorption strengths of intermediates,thereby bringing the high catalytic activities.Our work provides a new and general strategy toward the architecture of highly efficient catalysts not only for electrocatalytic nitrogen reduction reaction(eNRR)but also for other important reactions.We expect that our work will boost both experimental and theoretical efforts in this direction.
基金supported by the National Natural Science Foundation of China (52002412 and 22072186)the Natural Science Foundation of Guangdong Province (2021A1515010575)the Fundamental Research Funds for the Central Universities, Sun Yat-sen University (23lgbj017)。
文摘Exploiting high-efficiency Ni-based materials for electrocatalytic urea oxidation reaction(UOR) is critical for urea-related technologies.The catalytic site density,intrinsic activity,charge transfer,and mass diffusion determine overall electrocatalytic efficiency.Simultaneous modulation over the above four factors promises advanced electrocatalysis,yet challenging.Herein we propose a systematic regulation tactic over composition and geometric structure,constructing a nanocomposite comprising Mn doped Ni_(3)N nanoparticles anchored on reduced graphene oxide(rGO/Mn-Ni_(3)N),achieving elegant integration of four design principles into one,thereby eminently boosting UOR.Particularly,Mn doping in Ni_(3)N can modulate electronic state to induce intrinsic activity regulation.Combining metallic Mn-Ni_(3)N with rGO to engineer hierarchical architecture not only promotes charge transfer,but also enriches active site population.Intriguingly,improved hydrophilicity could impart better electrolyte penetration and gas escape.Consequently,such system-optimized rGO/Mn-Ni_(3)N demonstrates state-of-the-art-level UOR electrocatalysis.This work offers a novel paradigm to create advanced catalysts via systematic and integrated modulation.
基金Supported by the National Natural Science Foundation of China(No.51278118)the Program for Special Talent in Six Fields of Jiangsu Province(No.2011JZ010)+1 种基金the Natural Science Foundation of Jiangsu Province(No.BK2012756)the Undergraduate Innovation Program(No.T13052007)
文摘In order to improve the seismic performance, deformation ability and ultimate load-carrying capacity of columns with rectangular cross section, engineered cementitious composite （ECC） is introduced to partially substitute concrete in the edge zone of reinforced concrete columns and form reinforced ECC/concrete composite columns. Firstly, based on the assumption of plane remaining plane and the simplified constitutive models, the calculation method of the load-carrying capacity of reinforced ECC/concrete columns is proposed. The stress and strain distribu- tions and crack propagation of the composite columns in different states of eccentric compressive loading are ana- lyzed. Then, nonlinear finite element analysis is conducted to study the mechanical performance of reinforced ECC/concrete composite columns with rectangular cross section. It is found that the simulation results are in good agreement with the theoretical results, indicating that the proposed method for calculating the load-carrying capacity of concrete/ECC composite columns is valid. Finally, based on the proposed method, the effects of ECC thickness, com- pressive strength of concrete and longitudinal reinforcement ratio on the mechanical performance of reinforced ECC/ concrete composite columns are analyzed. Calculation results indicate that increasing the thickness of ECC layer or longitudinal reinforcement ratio can effectively increase the ultimate load-carrying capacity of the composite column with both small and large eccentricity, but increasing the strength of concrete can only increase the ultimate Ioad- carrying capacity of the composite column with small eccentricity.
