This paper introduced basic situation and challenges of Block 9, Dongdajie, Chengdu City, expounded basic definition and design concept of "place making", briefed the design scheme from three aspects, namely...This paper introduced basic situation and challenges of Block 9, Dongdajie, Chengdu City, expounded basic definition and design concept of "place making", briefed the design scheme from three aspects, namely planning layout, space environment and architectural style, and concluded the application of the idea of "place making" in Block 9 design scheme in view of the multi-functional urban complex with high plot ratio.展开更多
Photoinduced electron transfer reaction between the excited state ruthenium (II) polypyridyl complexes and quinones has been investigated in cetyltrimethylammonium bromide using luminescent quenching techniques. The c...Photoinduced electron transfer reaction between the excited state ruthenium (II) polypyridyl complexes and quinones has been investigated in cetyltrimethylammonium bromide using luminescent quenching techniques. The complexes have the absorption and emission maximum in the range 452 - 468 nm and 594 - 617 nm respectively. The static nature of quenching is confirmed from the ground state absorption studies. The association constants for the complexes with quinones are calculated from the Benesi-Hildebrand plots using absorption spectral data. The value of quenching rate constant (kq) is highly sensitive to the nature of the ligand and the quencher, the medium, structure and size of the quenchers. Compared to the aqueous medium, the electron transfer rate is altered in CTAB medium. The oxidative nature of the quenching is confirmed by the formation of Ru3+ ion and quinone anion radical.展开更多
The mechanism for interactions of the 6-benzyl-amino-purine and its Co2+, Ni2+ complexes with DNA was studied by UV and fluorescence spectra using ethidium bromide (EB) as probe molecule. When pH=7.4, the action of 6-...The mechanism for interactions of the 6-benzyl-amino-purine and its Co2+, Ni2+ complexes with DNA was studied by UV and fluorescence spectra using ethidium bromide (EB) as probe molecule. When pH=7.4, the action of 6-benzyl-amino-purine-Co2+ and DNA was electrostatic effect and certain kind of intercalation action; when pH=9.86, the action of the two was electrostatic effect; when pH=2.85 , the action of 6-benzyl-amino-purine-Ni2+ and DNA was both electrostatic and intercalation action. But when pH=7.4, 6-benzyl-amino-purine hardly influenced the intercalation action of EB and DNA, the action of 6-benzyl-amino-purine and DNA was electrostatic action.展开更多
以乙酸镍和2,2′-联吡啶配合物为模板、4-乙烯吡啶为功能单体、乙二醇二甲基丙烯酸酯为交联剂,合成了具有类似金属螯合抗体结合位点的金属配合物印迹聚合物,系统研究了金属离子对模板聚合物选择性结合2,2′-联吡啶的调节作用。结果表明...以乙酸镍和2,2′-联吡啶配合物为模板、4-乙烯吡啶为功能单体、乙二醇二甲基丙烯酸酯为交联剂,合成了具有类似金属螯合抗体结合位点的金属配合物印迹聚合物,系统研究了金属离子对模板聚合物选择性结合2,2′-联吡啶的调节作用。结果表明:印迹聚合物对N i(Ⅱ)-2,2′-联吡啶配合物有选择性识别能力。采用Scatchard模型评价分子印迹聚合物的结合特性,得到高亲和力结合位点的平衡离解常数Kd1=0.082 mm o l/L,表观最大结合量Qm ax1=82.2μm o l/g,低亲和力结合位点的Kd2=0.400 mm o l/L,Qm ax2=91.3μm o l/g。展开更多
文摘This paper introduced basic situation and challenges of Block 9, Dongdajie, Chengdu City, expounded basic definition and design concept of "place making", briefed the design scheme from three aspects, namely planning layout, space environment and architectural style, and concluded the application of the idea of "place making" in Block 9 design scheme in view of the multi-functional urban complex with high plot ratio.
文摘Photoinduced electron transfer reaction between the excited state ruthenium (II) polypyridyl complexes and quinones has been investigated in cetyltrimethylammonium bromide using luminescent quenching techniques. The complexes have the absorption and emission maximum in the range 452 - 468 nm and 594 - 617 nm respectively. The static nature of quenching is confirmed from the ground state absorption studies. The association constants for the complexes with quinones are calculated from the Benesi-Hildebrand plots using absorption spectral data. The value of quenching rate constant (kq) is highly sensitive to the nature of the ligand and the quencher, the medium, structure and size of the quenchers. Compared to the aqueous medium, the electron transfer rate is altered in CTAB medium. The oxidative nature of the quenching is confirmed by the formation of Ru3+ ion and quinone anion radical.
文摘The mechanism for interactions of the 6-benzyl-amino-purine and its Co2+, Ni2+ complexes with DNA was studied by UV and fluorescence spectra using ethidium bromide (EB) as probe molecule. When pH=7.4, the action of 6-benzyl-amino-purine-Co2+ and DNA was electrostatic effect and certain kind of intercalation action; when pH=9.86, the action of the two was electrostatic effect; when pH=2.85 , the action of 6-benzyl-amino-purine-Ni2+ and DNA was both electrostatic and intercalation action. But when pH=7.4, 6-benzyl-amino-purine hardly influenced the intercalation action of EB and DNA, the action of 6-benzyl-amino-purine and DNA was electrostatic action.
文摘以乙酸镍和2,2′-联吡啶配合物为模板、4-乙烯吡啶为功能单体、乙二醇二甲基丙烯酸酯为交联剂,合成了具有类似金属螯合抗体结合位点的金属配合物印迹聚合物,系统研究了金属离子对模板聚合物选择性结合2,2′-联吡啶的调节作用。结果表明:印迹聚合物对N i(Ⅱ)-2,2′-联吡啶配合物有选择性识别能力。采用Scatchard模型评价分子印迹聚合物的结合特性,得到高亲和力结合位点的平衡离解常数Kd1=0.082 mm o l/L,表观最大结合量Qm ax1=82.2μm o l/g,低亲和力结合位点的Kd2=0.400 mm o l/L,Qm ax2=91.3μm o l/g。
