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Command-agent:Reconstructing warfare simulation and command decision-making using large language models
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作者 Mengwei Zhang Minchi Kuang +3 位作者 Heng Shi Jihong Zhu Jingyu Zhu Xiao Jiang 《Defence Technology(防务技术)》 2026年第2期294-313,共20页
War rehearsals have become increasingly important in national security due to the growing complexity of international affairs.However,traditional rehearsal methods,such as military chess simulations,are inefficient an... War rehearsals have become increasingly important in national security due to the growing complexity of international affairs.However,traditional rehearsal methods,such as military chess simulations,are inefficient and inflexible,with particularly pronounced limitations in command and decision-making.The overwhelming volume of information and high decision complexity hinder the realization of autonomous and agile command and control.To address this challenge,an intelligent warfare simulation framework named Command-Agent is proposed,which deeply integrates large language models(LLMs)with digital twin battlefields.By constructing a highly realistic battlefield environment through real-time simulation and multi-source data fusion,the natural language interaction capabilities of LLMs are leveraged to lower the command threshold and to enable autonomous command through the Observe-Orient-Decide-Act(OODA)feedback loop.Within the Command-Agent framework,a multimodel collaborative architecture is further adopted to decouple the decision-generation and command-execution functions of LLMs.By combining specialized models such as Deep Seek-R1 and MCTool,the limitations of single-model capabilities are overcome.MCTool is a lightweight execution model fine-tuned for military Function Calling tasks.The framework also introduces a Vector Knowledge Base to mitigate hallucinations commonly exhibited by LLMs.Experimental results demonstrate that Command-Agent not only enables natural language-driven simulation and control but also deeply understands commander intent.Leveraging the multi-model collaborative architecture,during red-blue UAV confrontations involving 2 to 8 UAVs,the integrated score is improved by an average of 41.8%compared to the single-agent system(MCTool),accompanied by a 161.8%optimization in the battle loss ratio.Furthermore,when compared with multi-agent systems lacking the knowledge base,the inclusion of the Vector Knowledge Base further improves overall performance by 16.8%.In comparison with the general model(Qwen2.5-7B),the fine-tuned MCTool leads by 5%in execution efficiency.Therefore,the proposed Command-Agent introduces a novel perspective to the military command system and offers a feasible solution for intelligent battlefield decision-making. 展开更多
关键词 Digital twin battlefield Large language models Multi-agent system Military command
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One-to-Any Command and Control Model:Precisely Coordinated Operation on Uncooperative Controlled Nodes 被引量:1
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作者 QIU Han LI Yufeng +1 位作者 LI Heshuai ZHU Junhu 《Wuhan University Journal of Natural Sciences》 CAS CSCD 2015年第6期490-498,共9页
New precisely cooperative attacks, such as the coordi- nated cross plane session termination (CXPST) attack, need thou- sands upon thousands machines to attack diverse selected links simultaneously with the given ra... New precisely cooperative attacks, such as the coordi- nated cross plane session termination (CXPST) attack, need thou- sands upon thousands machines to attack diverse selected links simultaneously with the given rate. However, almost all command and control(C&C) mechanisms only provide publishing one com- mand to the whole once, so-called one-to-all C&C model, and are not productive to support CXPST-alike attacks. In this paper, we present one-to-any C&C model on coordination among the unco- operative controlled nodes. As an instance of one-to-any C&C model, directional command publishing (DCP) mechanism lever- aging on Kademlia is provided with a range-mapping key creating algorithm for commands to compute the publishing range and a statistically stochastic node querying scheme to obtain the com- mands immediately. With theoretical analysis and simulation, it is indicated that one-to-any C&C model fits for precisely coordi- nated operation on uncooperative controlled nodes with least complexity, better accuracy and efficiency. Furthermore, DCP mechanism can support one-to-all command publishing at the same time. As an example of future C&C model, studying on one-to-any C&C model may help to promote the development of more efficient countermeasures. 展开更多
关键词 one-to-any command and control(C&C) model directional command publishing(DCP) mechanism precisely cooperative attack uncooperative controlled node
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基于24Model-GRA的危化品较大燃爆事故致因关联度分析
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作者 杨比 付净 +2 位作者 谭有菊 王雪松 付顺 《安全》 2025年第11期39-46,共8页
为精准定位事故致因关键要素、突破危化品较大燃爆事故防控瓶颈,本文将事故致因“2-4”模型(24Model)信息分类编码与灰色关联度分析法(GRA)用于小样本危化品较大燃爆事故,评估组织各层面致因模块对事故后果的影响,并刻画关键致因要素的... 为精准定位事故致因关键要素、突破危化品较大燃爆事故防控瓶颈,本文将事故致因“2-4”模型(24Model)信息分类编码与灰色关联度分析法(GRA)用于小样本危化品较大燃爆事故,评估组织各层面致因模块对事故后果的影响,并刻画关键致因要素的表征及作用路径。结果表明:防控危化品较大燃爆事故的关键在于提升全员对化工过程HSE管理重要性的认知、承诺与践行(γ_(SC)=0.7397),落实全时空网格化燃爆风险防控知识及特殊作业安全技能培训(γ_(UA_(2)) =0.9635)。研究为危化品企业有效防控较大燃爆事故提供致因数据支撑,也为小样本数据规律挖掘提供方法和依据。 展开更多
关键词 危化品 较大燃爆事故 事故致因“2-4”模型(24model) 灰色关联分析(GRA)
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基于24Model-D-ISM的地铁站火灾疏散影响因素研究 被引量:2
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作者 孙世梅 张家严 《中国安全科学学报》 CAS CSCD 北大核心 2024年第4期153-159,共7页
为预防地铁站火灾事故,深入了解地铁站火灾人员疏散影响因素间的内在联系与层次结构,基于第6版“2-4”模型(24Model)分析63起地铁站火灾疏散事故,充分考虑各个因素之间的交互作用,提取19个影响地铁站人员疏散的关键因素,建立地铁站火灾... 为预防地铁站火灾事故,深入了解地铁站火灾人员疏散影响因素间的内在联系与层次结构,基于第6版“2-4”模型(24Model)分析63起地铁站火灾疏散事故,充分考虑各个因素之间的交互作用,提取19个影响地铁站人员疏散的关键因素,建立地铁站火灾人员疏散影响因素指标体系;采用算子客观赋权法(C-OWA)改进决策试验与评价实验法(DEMATEL),确定地铁站火灾人员疏散的重要影响因素;在此基础上,采用解释结构模型(ISM)分析各个因素间的层次结构及相互作用路径,构建地铁站火灾人员疏散影响因素的多级递阶结构模型。研究结果表明:疏散引导、恐慌从众行为、人员拥挤为地铁站火灾人员疏散的关键影响因素;地铁站火灾人员疏散受表层因素、中间层因素、深层因素共同作用的影响,其中,疏散教育与培训、设施维护与检查、疏散预案等因素是根源影响因素,重视根源影响因素的改善有利于从本质上预防和控制事故的发生。 展开更多
关键词 “2-4”模型(24model) 决策试验与评价实验法(DEMATEL) 解释结构模型(ISM) 地铁站 火灾疏散 影响因素
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Parameter Extraction for 2-π Equivalent Circuit Model of RF CMOS Spiral Inductors 被引量:1
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作者 高巍 余志平 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2006年第4期667-673,共7页
A novel parameter extraction method with rational functions is presented for the 2-πequivalent circuit model of RF CMOS spiral inductors. The final S-parameters simulated by the circuit model closely match experiment... A novel parameter extraction method with rational functions is presented for the 2-πequivalent circuit model of RF CMOS spiral inductors. The final S-parameters simulated by the circuit model closely match experimental data. The extraction strategy is straightforward and can be easily implemented as a CAD tool to model spiral inductors. The resulting circuit models will be very useful for RF circuit designers. 展开更多
关键词 2-π compact model parameters extraction RF CMOS spiral inductors
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From the Area to the Point-Study on the Key Technology of 3D Geological Hazard Modeling in Three Gorges Reservoir Area 被引量:9
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作者 刘军旗 黄学斌 +3 位作者 吴冲龙 程温鸣 项伟 夏鹤 《Journal of Earth Science》 SCIE CAS CSCD 2012年第2期199-206,共8页
Taking hundreds of pieces of hazardous geological maps (1 : 10 000) of Three Gorges res-ervoir area (3GR) as background, we establish regional three-dimensional (3D) geo-hazard modelusing DEM (digital elevatio... Taking hundreds of pieces of hazardous geological maps (1 : 10 000) of Three Gorges res-ervoir area (3GR) as background, we establish regional three-dimensional (3D) geo-hazard modelusing DEM (digital elevation model) superposed surface images and geo-hazards elements. Based on landslides and other geo-hazard survey data,using improved B-REP(boundary representa-tion)entity data structure (two-body 3D data structure), we set up 3D solid models for each hazardous bodies in each hazardous geological maps. Then we integrate the two types of 3D models with different scales from area to point, which are the regional geo-hazard 3D model and the solid models of each disaster body, in order to provide a visual processing and analysis plat-form for danger partition, stability evaluation, disaster prevention and control, early warning and command. 展开更多
关键词 investigation database regional 3D geological model three-dimensional solid model of disaster body disaster prevention and control early warning command.
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基于PE-KNN算法驱动的DCCS仿真系统评估模型及应用研究
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作者 邱生敏 李慧勇 +2 位作者 吴亮 张晓声 孙焜 《国外电子测量技术》 2025年第10期121-126,共6页
针对任务需求复杂、外界干扰性强等问题导致的电网调度指挥控制系统在运行过程中控制精度低、稳定性弱的问题,提出一种基于排列熵和K最近邻(Permutation Entropy-K-Nearest Neighbor,PE-KNN)算法的评估模型,通过评估结果不断调整仿真系... 针对任务需求复杂、外界干扰性强等问题导致的电网调度指挥控制系统在运行过程中控制精度低、稳定性弱的问题,提出一种基于排列熵和K最近邻(Permutation Entropy-K-Nearest Neighbor,PE-KNN)算法的评估模型,通过评估结果不断调整仿真系统的控制精度和稳定性,以对其进行优化。先对评估模型的性能进行分析,再对优化后仿真系统的性能进行分析。研究结果表明,评估模型准确率能够达到98.6%,评估耗时仅需2.1 s;根据评估结果调整后,仿真系统的控制精度提高了21.25%,系统在不同场景的控制精度均能够达到94.5%,具有较强的稳定性。因此,方法能够提升调度指挥系统的稳定性和控制精度,为系统的优化与改进提供技术支持。 展开更多
关键词 调度指挥控制系统 排列熵 K最近邻 评估模型
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A hybrid Lagrangian-Eulerian numerical model for sea-ice dynamics 被引量:3
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作者 JI Shunying LI Hai +2 位作者 SHEN Hung Tao WANG Ruixue YUE Qianjin 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2007年第5期12-24,共13页
A hybrid Lagrangian - Eulerian (HLE) method is developed for sea ice dynamics, which combines the high computational efficiency of finite difference method (FDM) with the high numerical accuracy of smoothed partic... A hybrid Lagrangian - Eulerian (HLE) method is developed for sea ice dynamics, which combines the high computational efficiency of finite difference method (FDM) with the high numerical accuracy of smoothed particle hydrodynamics (SPH). In this HLE model, the sea ice cover is represented by a group of Lagrangian ice particles with their own thicknesses and concentrations. These ice variables are interpolated to the Eularian gird nodes using the Gaussian interpolation function. The FDM is used to determine the ice velocities at Eulerian grid nodes, and the velocities of Lagrangian ice particles are interpolated from these grid velocities with the Gaussian function also. The thicknesses and concentrations of ice particles are determined based on their new locations. With the HLE numerical model, the ice ridging process in a rectangular basin is simulated, and the simulated results are validated with the analytical solution. This method is also applied to the simulation of sea ice dynamics in a vortex wind field. At last, this HLE model is applied to the Bohai Sea, and the simulated concentration, thickness and velocity match the satellite images and the field observed data well. 展开更多
关键词 hybrid Lagrangian - Eulerian model sea-ice dynamics numerical model
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Analytical models for the penetration of semi-infinite targets by rigid,deformable and erosive long rods 被引量:18
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作者 He-Ming Wen Bin Lan 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第4期573-583,共11页
A theoretical study is presented herein on the pen- etration of a semi-infinite target by a spherical-headed long rod for Yp 〉 S, where Yp is the penetrator strength and S is the static target resistance. For Yp 〉 S... A theoretical study is presented herein on the pen- etration of a semi-infinite target by a spherical-headed long rod for Yp 〉 S, where Yp is the penetrator strength and S is the static target resistance. For Yp 〉 S, depending upon initial impact velocity, there exist three types of penetration, namely, penetration by a rigid long rod, penetration by a deforming non-erosive long rod and penetration by an erosive long rod. If the impact velocity of the penetrator is higher than the hydrodynamic velocity (VH), it will penetrate the target in an erosive mode; if the impact velocity lies between the hydrodynamic velocity (VH) and the rigid body velocity (VR), it will penetrate the target in a deformable mode; if the impact velocity is less than the rigid body velocity (VR), it will penetrate the target in a rigid mode. The critical conditions for the transition among these three penetration modes are proposed. It is demonstrated that the present model predictions correlate well with the experimental observations in terms of depth of penetration (DOP) and the critical transition conditions. 展开更多
关键词 Long rod Semi-infinite target - Penetration Alekseevskii-Tate model Rigid body velocity - Hydrodynamic velocity
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Analysis of axial strain in one-dimensional loading by different models 被引量:2
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作者 G.Aryanpour M.Farzaneh 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第5期745-753,共9页
Different phenomenological equations based on plasticity, primary creep (as a viscoplastic mechanism), secondary creep (as another viscoplastic mechanism) and different combinations of these equations are presente... Different phenomenological equations based on plasticity, primary creep (as a viscoplastic mechanism), secondary creep (as another viscoplastic mechanism) and different combinations of these equations are presented and used to describe the material inelastic deformation in uniaxial test. Agreement of the models with experimental results and with the theoretical concepts and physical realities is the criterion of choosing the most appropriate formulation for uniaxial test. A model is thus proposed in which plastic deformation, primary creep and secondary creep contribute to the inelastic deformation. However, it is believed that the hardening parameter is composed of plastic and primary creep parts. Accordingly, the axial plastic strain in a uniaxial test may no longer be considered as the hardening parameter. Therefore, a proportionality concept is proposed to calculate the plastic contribution of deformation. 展开更多
关键词 modelling Uniaxial test Plastic - Creep Strain hardening - Proportionality
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Numerical analysis of the failure process of soil-rock mixtures through computed tomography and PFC3D models 被引量:24
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作者 Yang Ju Huafei Sun +2 位作者 Mingxu Xing Xiaofei Wang Jiangtao Zheng 《International Journal of Coal Science & Technology》 EI 2018年第2期126-141,共16页
Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurat... Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurately characterize and predict the SRM's mechanical properties. This study reports a novel numerical method incorporating microfocus computed tomography and PFC3D codes to probe the deformation and failure processes of SRM. The three-dimensional (3D) PFC models that represent the SRM's complex structures were built. By simulating the entire failure process in PFC3D, the SRM's strength, elastic modulus and crack growth were obtained. The influence of rock ratios on the SRM's strength, deformation and failure processes, as well as its internal mesoscale mechanism, were analyzed. By comparing simulation results with experimental data, it was verified that the 3D PFC models were in good agreement with SRM's real structure and the SRM's compression process, deformation and failure patterns; its intrinsic mesomechanism can be effectively analyzed based on such 3D PFC models. 展开更多
关键词 Soil-rock mixture (SRM) - PFC3D model Three-dimensional structure Microfocus computed tomography (μCT) Failure mechanism Crack growth
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Periodic Packing Mode for Trickle-Bed Reactors: Experiments and Modeling 被引量:2
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作者 刘国柱 米镇涛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第3期372-378,共7页
A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determini... A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determining whether the periodic packing mode is advantageous. The effects of operating conditions and packing type on TBR performance were experimentally examined to demonstrate the cause-effect relationships. A mathe-matic model of TBR considering axial dispersion and fractional wetting was developed to quantitatively illuminate the reason of performance enhancement. 展开更多
关键词 trickle-bed reactor periodic packing mode modelING HYDROGENATION 2- ethylanthraquinone
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Roll System and Stock's Multi-parameter Coupling Dynamic Modeling Based on the Shape Control of Steel Strip 被引量:3
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作者 Yang ZHANG Yan PENG +1 位作者 Jianliang SUN Yong ZANG 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第3期614-624,共11页
The existence of rolling deformation area in the rolling mill system is the main characteristic which dis- tinguishes the other machinery. In order to analyze the dynamic property of roll system's flexural deformatio... The existence of rolling deformation area in the rolling mill system is the main characteristic which dis- tinguishes the other machinery. In order to analyze the dynamic property of roll system's flexural deformation, it is necessary to consider the transverse periodic movement of stock in the rolling deformation area which is caused by the flexural deformation movement of roll system simul- taneously. Therefore, the displacement field of roll system and flow of metal in the deformation area is described by kinematic analysis in the dynamic system. Through intro- ducing the lateral displacement function of metal in the deformation area, the dynamic variation of per unit width rolling force can be determined at the same time. Then the coupling law caused by the co-effect of rigid movement and flexural deformation of the system structural elements is determined. Furthermore, a multi-parameter coupling dynamic model of the roll system and stock is established by the principle of virtual work. More explicitly, the cou- pled motion modal analysis was made for the roll system. Meanwhile, the analytical solutions for the flexural defor- mation movement's mode shape functions of rolls are discussed. In addition, the dynamic characteristic of the lateral flow of metal in the rolling deformation area has been analyzed at the same time. The establishment ofdynamic lateral displacement function of metal in the deformation area makes the foundation for analyzing the coupling law between roll system and rolling deformation area, and provides a theoretical basis for the realization of the dynamic shape control of steel strip. 展开更多
关键词 Roll system Rolling deformation area Coupling dynamic model Mode shape function - Lateraldisplacement function
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Investment in deepwater oil and gas exploration projects:a multi-factor analysis with a real options model 被引量:5
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作者 Xin-Hua Qiu Zhen Wang Qing Xue 《Petroleum Science》 SCIE CAS CSCD 2015年第3期525-533,共9页
Deepwater oil and gas projects embody high risks from geology and engineering aspects, which exert substantial influence on project valuation. But the uncer- tainties may be converted to additional value to the projec... Deepwater oil and gas projects embody high risks from geology and engineering aspects, which exert substantial influence on project valuation. But the uncer- tainties may be converted to additional value to the projects in the case of flexible management. Given the flexibility of project management, this paper extends the classical real options model to a multi-factor model which contains oil price, geology, and engineering uncertainties. It then gives an application example of the new model to evaluate deepwater oil and gas projects with a numerical analytical method. Compared with other methods and models, this multi-factor real options model contains more project information. It reflects the potential value deriving not only from oil price variation but also from geology and engi- neering uncertainties, which provides more accurate and reliable valuation information for decision makers. 展开更多
关键词 Investment decision - Real options Multi-factor model Option pricing - Deepwater oil and gas
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Modelling of Quasi 3-D Groundwater Flow and Studying of Equivalent Drainage Boundary in Beihai Peninsula,Guangxi 被引量:2
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作者 Chen Chongxi Lin Min Li GuominChina University of Geosciences , Wuhan 430074Jiang Jianmin Ye Shanshi Wu NaidongGeology Bureau of Guangxi Autonomous Region , Naming 530023 《Journal of Earth Science》 SCIE CAS CSCD 1992年第1期109-119,共11页
This paper describes a quasi 3-D finite element model of the groundwater flow in two -aquifer system which is constructed from a sequence of aquifer flow equations coupled by leakage terms representing flow through th... This paper describes a quasi 3-D finite element model of the groundwater flow in two -aquifer system which is constructed from a sequence of aquifer flow equations coupled by leakage terms representing flow through the aquitard . It is applied to evaluate the maximum rate of groundwater resources exploited from the coastal aquifer without seawater intrusion . The main task in this model is to determine the drainage boundary of the aquifer extending under the sea . The information of the boundary can be obtained from the fluctuations of the groundwater level caused by sea-tide fluctuations . A new idea, Equivalent Drainage Boundary (EDB), is proposed and the corresponding methods , determining the EDB, are developed with tidal fluctuations data observed in boreholes . The quasi 3-D model and the methods determining EDB have been applied to the aquifer system of Beihai peninsula , Guangxi Autonomous Region of China for calculating the available groundwater resources . 展开更多
关键词 quad 3 - D model coastal aquifer Equivalent Drainage Boundary available groundwater resources Beihai peninsula .
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A Numerical Algorithm Based on Quadratic Finite Element for Two-Dimensional Nonlinear Time Fractional Thermal Diffusion Model 被引量:3
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作者 Yanlong Zhang Baoli Yin +2 位作者 Yue Cao Yang Liu Hong Li 《Computer Modeling in Engineering & Sciences》 SCIE EI 2020年第3期1081-1098,共18页
In this article,a high-order scheme,which is formulated by combining the quadratic finite element method in space with a second-order time discrete scheme,is developed for looking for the numerical solution of a two-d... In this article,a high-order scheme,which is formulated by combining the quadratic finite element method in space with a second-order time discrete scheme,is developed for looking for the numerical solution of a two-dimensional nonlinear time fractional thermal diffusion model.The time Caputo fractional derivative is approximated by using the L2-1formula,the first-order derivative and nonlinear term are discretized by some second-order approximation formulas,and the quadratic finite element is used to approximate the spatial direction.The error accuracy O(h3+t2)is obtained,which is verified by the numerical results. 展开更多
关键词 Quadratic finite element two-dimensional nonlinear time fractional thermal diffusion model L2-1formula.
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Thermodynamic modeling and phase diagram prediction of salt lake brine systemsⅡ.Aqueous Li^(+)-Na^(+)-K^(+)-SO_(4)^(2-) and its subsystems 被引量:8
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作者 Huan Zhou Peng Wu +3 位作者 Wenxuan Li Xingfan Wang Kuo Zhou Qing Hao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第6期134-149,共16页
It is still a challenging task to accurately and temperature-continuously express the thermodynamic properties and phase equilibrium behaviors of the salt-lake brine with multi-component,multitemperature and high conc... It is still a challenging task to accurately and temperature-continuously express the thermodynamic properties and phase equilibrium behaviors of the salt-lake brine with multi-component,multitemperature and high concentration.The essential subsystem of sulfate type brine,aqueous Li^(+)-Na^(+)-K^(+)-SO_(4)^(2-) and its subsystems across a temperature range from 250 K to 643 K are investigated with the improved comprehensive thermodynamic model.Liquid parameters(Δg_(IJ),Δh_(IJ),and ΔC_(p,IJ))associated with the contributions of Gibbs energy,enthalpy,and heat capacity to the binary interaction parameters,i.e.the temperature coefficients of eNRTL parameters formulated with a Gibbs Helmholtz expression,are determined via multi-objective optimization method.The solid constantsΔ_(f)G_(k)°^((298.15))andΔ_(f)H_(k)°^((298.15))of11 solid species occurred in the quaternary system are rebuilt from multi-temperature solubilities.The modeling results show the accurate representation of(1)solution properties and binary phase diagram at temperature ranges from eutectic points to 643 K;(2)isothermal phase diagrams for Li_(2)SO_(4)-Na_(2)SO_(4)-H_(2)O,Li_(2)SO_(4)-K_(2)SO_(4)-H_(2)O and Na_(2)SO_(4)-K_(2)SO_(4)-H_(2)O ternary systems.The predicted results of complete structure and polythermal phase diagram of ternary systems and the isothermal phase diagrams of quaternary system excellently match with the experimental data. 展开更多
关键词 Aqueous electrolytes Comprehensive thermodynamic model Aqueous Li^(+)-Na^(+)-K^(+)-SO_(4)^(2-) Phase diagram Thermodynamic properties
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Kinetic Modeling the Formation of Low-mature Gases and Analysis of the Possibility to Be Accumulated 被引量:2
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作者 SHUAI Yanhua WANG Hui ZHANG Shuichang SU Aiguo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第3期537-542,共6页
At present, shallow gases have received much attention due to low cost in exploration and production. Low-mature gases, as one significant origin to shallow gas, turns to be an important research topic. The present un... At present, shallow gases have received much attention due to low cost in exploration and production. Low-mature gases, as one significant origin to shallow gas, turns to be an important research topic. The present understanding of low-mature gases is confined within some geological cases, and few laboratory studies have been reported. Therefore, the potential and characters of low- mature gases are not clear up to now. Here, two premature samples (one coal and the other shale) were pyrolyzed in a gold confined system. The gaseous components including hydrocarbon gases and non-hydrocarbon gases were analyzed. Based on kinetic modeling, the formation of low-mature gases was modeled. The results showed that during low mature stage, about 178 mL/gTOC gas was generated from the shale and 100 mL/gTOC from the coal. Two third to three fourth of the generated gases are non-hydrocarbon gases such as H2S and CO2. The total yields of C1-5 for the two samples are almost the same, 30-40 mL/gTOC, but individual gaseous hydrocarbon is different. The shale has much lower C1 but higher C2-5, whereas the coal has higher C1 but lower C2-5. Hydrocarbon gases formed during low-mature stage are very wet. The stable carbon isotope ratios of methane range from -40‰ to -50‰ (PDB), in good consistence with empiric criterion for low-mature gases summed up by the previous researchers. The generation characters suggest that the low-mature gases could be accumulated to form an economic gas reservoir, but most of them occur only as associated gases. 展开更多
关键词 low-mature gases kinetic modeling carbon isotope ratio of methane potential of C1-5
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Solubility of CO_(2) in nonaqueous system of 2-(butylamino)ethanol with 2-butoxyethanol:Experimental data and model representation 被引量:2
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作者 Yu Dong Tiantian Ping Shufeng Shen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第1期441-448,共8页
Nonaqueous amine-based system is an attractive solution to overcome high-energy-intensive CO_(2) capture process using the conventional aqueous amines.Advanced nonaqueous absorbent of 2-(butylamino)ethanol(BAE)with 2-... Nonaqueous amine-based system is an attractive solution to overcome high-energy-intensive CO_(2) capture process using the conventional aqueous amines.Advanced nonaqueous absorbent of 2-(butylamino)ethanol(BAE)with 2-butoxyethanol(2-BE)has been recently proposed for low-energyconsumption CO_(2) capture.In this work,Henry’s law constants of CO_(2) in the BAE/2-BE blend were obtained by N_(2)O/CO_(2) analogy,and correlated in the temperature range of(283–333)K.Vapor-liquid equilibrium(VLE)data for the BAE+CO_(2)+2-BE system at 65.4%(mass)BAE were also determined in a stirred equilibrium cell at temperatures of(313–393)K and CO_(2) partial pressures up to 275 kPa.A single apparent equilibrium constant KCO_(2);app was proposed for this system and correlated as a function of temperature,carbonated degree of amine and CO_(2) loading.Solubility data were well represented by the modified Kent-Eisenberg model with an average absolute relative deviation(AARD)of 13%. 展开更多
关键词 SOLUBILITY CO_(2)capture Nonaqueous absorbent 2-(Butylamino)ethanol 2-Butoxyethanol model
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Aeroelastic modeling of wind loading on a cable-net supported glass wall 被引量:1
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作者 Zhifu Gu Letian Yang Yan Li Bin Chen 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第3期409-415,共7页
Wind loading study on a cable-net supported glass wall is conducted by means of wind tunnel tests. An equiva- lent aeroelastic model is designed and constructed. Response of displacements of the wall is measured and a... Wind loading study on a cable-net supported glass wall is conducted by means of wind tunnel tests. An equiva- lent aeroelastic model is designed and constructed. Response of displacements of the wall is measured and analyzed. In order to design a glass wall under wind loading, the "wind- vibration factor" is estimated and discussed. In fact, the mech- anism of wind acting on the wall is commonly known not only as positive pressure, but also as negative pressure caused by the flow separation on the corners of the building. Due to the diffidence in the mechanism of wind acting, two typi- cal response cases are classified. The results show that the dynamic response of the structure caused by the negative pressure is stronger than that of the positive pressure case. To determine the aerodynamic wind loading on a flexible part of structure on a building, wind tunnel study may be useful and play an important role. 展开更多
关键词 Wind tunnel study Cable-net supported glasswall - Wind-vibration factor Aeroelastic model
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