Membrane-assisted antisolvent crystallization(MAAC)is a separation process that allows for precise regulation of the crystallization process in pharmaceutical,finechemical engineering,energy chemistry,etc.After decade...Membrane-assisted antisolvent crystallization(MAAC)is a separation process that allows for precise regulation of the crystallization process in pharmaceutical,finechemical engineering,energy chemistry,etc.After decades of development,the current MAAC engineering lacks highly robust specialized instruments,which limits the further industrial application of the MAAC process.Herein,to guide the design and optimization of the advanced MAAC instrument(DUT-iMC),we developed a parameter evaluation strategy based on cold model experiments.This approach utilizes the average particle size variation rate and the counts variation rate to characterize crystal size changes.The layout of the internal membrane module in DUT-iMC and the arrangement of the conveying pipeline were optimized.This improvement enhanced particle conveying characteristics,promoting more efficienttransport and circulation within the module.The advanced MAAC instrument substantially automates the production process,and the internal probes accurately monitor and record process variables,allowing for precise regulation of crystal size and morphology.The optimal operating range was expanded by 150%compared to the laboratory instrument.The range of shell side flow rate options increased by 50%,and the production time can be shortened by up to 30%.This paper provides ideas and guidance for the industrialization of MAAC processes and the development of related instruments.展开更多
The service facility or server is the key constituent to keep a system operational for desired period of time. As any eventuality with the system necessitates immediate presence of it (server) so the time point of arr...The service facility or server is the key constituent to keep a system operational for desired period of time. As any eventuality with the system necessitates immediate presence of it (server) so the time point of arrival and treatment of server significantly affects the system performance. This paper works out the steady state behavior of a cold standby system equipped with two similar units and a server with elapsed arrival and treatment times following general probability distributions. It practices the theory of semi-Markov processes, regenerative point technique and Laplace transforms to derive the expressions for state transition probabilities, mean sojourn times, mean time to system failure, system availability, server busy period and expected frequencies of repairs and treatments. The profit function is also developed taking different costs and revenue in to account. For tracing wider applicability of the model for different reliability and cost-effective systems, a particular case study is also presented as an illustration.展开更多
A novel vapor-liquid distributor was developed on the basis of sufficient study on the existing distributors applied in hydroprocessing reactors. The cold model test data showed that the fluid distribution performance...A novel vapor-liquid distributor was developed on the basis of sufficient study on the existing distributors applied in hydroprocessing reactors. The cold model test data showed that the fluid distribution performance of the novel vapor-liquid distributor was evidently better than the traditional one. Com- mercial tests of the new distributor were carded out in the 300 kt/a gas oil hydrotreating reactor at SINOPEC Changling Branch Company, showing that the new vapor-liquid distributor could improve the fluid distribution, promote the hydrotreating efficiency and lead to better performance than the traditional one.展开更多
Based on the similarity theory, taking the horseshoe, city-gate and round linings as examples, the value and distribution regularities of normal frost heaving pressures （hereinafter as frost heaving pressures） in tu...Based on the similarity theory, taking the horseshoe, city-gate and round linings as examples, the value and distribution regularities of normal frost heaving pressures （hereinafter as frost heaving pressures） in tunnels excavated in fractured rock mass in cold regions under different constraints and freezing depths were studied by a test model. It was found that the larger the frozen depth, the larger the frost heaving pressure, and the stronger the top constraint, the larger the frost heaving pressure. For the horseshoe lining and city-gate lining, the top constraint has a greater effect on the frost heaving pressures on the arch and the inverted arch. For the round lining, the influences of the top constraint on the frost heaving pressure in all linings are almost the same. The frost heaving pressure is maximum on the city-gate lining and minimal on the round lining. The largest frost heaving pressure all occur near the foot of the inverted arch for the three kinds of lining. Thus, the test data basically coincide with the observed in situ data.展开更多
This paper investigates the comparison problem of the reliability index between a parallel and a cold-standby system,both of which are consisting of two identical units.On the contrary to the general intuitive result,...This paper investigates the comparison problem of the reliability index between a parallel and a cold-standby system,both of which are consisting of two identical units.On the contrary to the general intuitive result,we proved that,under the condition that the system is shocked by a Poisson stream,the life time of the parallel system is longer than that of the cold-standby one in the sense of probability.展开更多
Short residence time of the sorbent in the gas stream and formation of a dense layer of reaction product surrounding its surface influence the sulfur removal efficiency. A practical means of improving the process perf...Short residence time of the sorbent in the gas stream and formation of a dense layer of reaction product surrounding its surface influence the sulfur removal efficiency. A practical means of improving the process performance is to employ fluidized bed reaction in replacement of entrained bed reaction on normally used in cool side desulfurizaiton. This paper describes cold modeling study of a circulating fluidized bed reactor. Several aspects of the problem are discussed: fluidization behavior of CaO, attrition of the sorbent and solids entrainment from the fluidized bed. Mechanisms and key controlling parameters are identified, and an integral model based on rate of attrition and mass balance is developed for predicting steady state mass flows and particle size distributions of the system. A process flow scheme is finally presented for conducting desulfurization tests in the second stage of the study.展开更多
The purpose of this paper is to present the flow field in the 300MW tangential firing utility boiler that used the Low NOx Concentric Firing System （LNCFS）. Using the method of cold isothermal simulation ensures the...The purpose of this paper is to present the flow field in the 300MW tangential firing utility boiler that used the Low NOx Concentric Firing System （LNCFS）. Using the method of cold isothermal simulation ensures the geometric and boundary condition similarity. At the same time the condition of self-modeling is met. The experimental results show that the mixture of primary air and secondary air becomes slower, the average turbulence magnitude the relative diameter of the tangential firing enlarges of the main combustion zone becomes less and when the secondary air deflection angle increases When the velocity pressure ratio of the secondary air to the primary air （p2/p1） enlarges, the mixture of the secondary air and the primary air becomes stronger, the average turbulence magnitude of the main combustion zone increases, and the relative diameter of the tangential firing becomes larger. Because the over fire air （OFA） laid out near the wall has a powerful penetration, the relative diameter of the tangential firing on the section of the OFA is very little, but the average turbulence magnitude is great. When the velocity pressure ratio of the OFA to the primary air POFA/p1 increases, the relative diameter of the tangential firing on the section of the OFA grows little, the average turbulence magnitude becomes larger and the penetration of the OFA becomes more powerful.展开更多
In this paper, cold simulation experiments and numerical calculations are conducted to predict 3 D flow field aerodynamics for an oil furnace after being retrofitted due to its fuel variation. K ε model and SIMPLE ...In this paper, cold simulation experiments and numerical calculations are conducted to predict 3 D flow field aerodynamics for an oil furnace after being retrofitted due to its fuel variation. K ε model and SIMPLE program under body fit coordination (BFC) system, in which TTM non orthogonal method is used to control the irregular geometric boundary, are adopted to solve the control equations. Model tests are conducted to check the calculation results, showing that they are in agreement with each other. Three different alternatives with different side window locations are also calculated to optimize the designs. The field retrofitting results show that the combination of cold tests with numerical calculations has prosperous application in retrofitting or renewing medium and small boilers.展开更多
<span style="font-family:Verdana;">A successful single parameter model has be</span><span style="font-family:Verdana;">en </span><span style="font-family:Verdana;&qu...<span style="font-family:Verdana;">A successful single parameter model has be</span><span style="font-family:Verdana;">en </span><span style="font-family:Verdana;">formulated to match the observations of photons from type 1a supernovae which were previously used to corroborate the standard </span><span style="font-family:Verdana;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">𝛬</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;"> cold dark matter model. The new single parameter model extrapolates all the way back to the cosmic background radiation (CMB) without requiring a separate model to describe inflation of the space dimensions after the Big Bang. This single parameter model assumes that spacetime forms a finite symmetrical manifold with positive curvature. For the spacetime manifold to be finite, the time dimension must also have positive curvature. This model was formulated to consider whether the curvature of the time dimension may be related to the curvature of the space dimensions. This possibility is not considered in the more complex models previously used to fit the available redshift data. The geometry for the finite spacetime manifold was selected to be compatible with the Friedmann equation with positive curvature. The manifold shape was motivated by an assumption that there exists a matter hemisphere (when considering time together with a single space dimension) and an antimatter hemisphere to give a symmetrical and spherical overall spacetime manifold. Hence, the space dimension expands from a pole to the equator, at a maximum value for the time dimension. This is analogous to the expansion of a circle of latitude on a globe from a pole to the equator. The three space dimensions are identical so that any arbitrary single space direction may be selected. The initial intention was to modify the assumed geometry for the spacetime manifold to account for the presence of matter. It was surprisingly found that, within the error of the reported measurements, no further modification was necessary to fit the data. The Friedmann equation reduces to the Schwarzschild equation at the equator so this can be used to predict the total amount of mass in the Universe. The resulting prediction is of the order of 10</span><sup><span style="font-family:Verdana;">51</span></sup><span style="font-family:Verdana;"> kg. The corresponding density of matter at the current time is approxima</span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">tely 1.6 × 10</span><sup><span style="font-family:Verdana;">-28</span></sup><span style="font-family:Verdana;"> kg<span style="color:#636363;"><span style="font-size:13.3333px;"><span style="white-space:nowrap;">·</span></span></span>m</span><sup><span style="font-family:Verdana;">-3</span></sup><span style="font-family:Verdana;">.</span></span>展开更多
Shape is an important quality index of cold rolling strip. Up to now, many problems in the shape control domain have not been solved satisfactorily, and a review on the research progress in the shape control domain ca...Shape is an important quality index of cold rolling strip. Up to now, many problems in the shape control domain have not been solved satisfactorily, and a review on the research progress in the shape control domain can help to seek new breakthrough directions. In the past 10 years, researches and applications of shape control models, shape control means, shape detection technology, and shape con- trol system have achieved significant progress. In the aspect of shape control models, the researches in the past improve the accuracy, speed and robustness of the models. The intelligentization of shape control models should be strengthened in the future. In the aspect of the shape control means, the researches in the past focus on the roll opti- mization, mill type selection, process optimization, local strip shape control, edge drop control, and so on. In the future, more attention should be paid to the coordination control of both strip shape and other quality indexes, and the refinement of control objective should be strengthened. In the aspects of shape detection technology and shape control system, some new types of shape detection meters and shape control systems are developed and have successfully indus- trial applications. In the future, the standardization of shape detection technology and shape control system should be promoted to solve the problem of compatibility. In general,the four expected development trends of shape control for cold roiling strip in the future are intelligentization, coordi- nation, refinement, and standardization. The proposed research provides new breakthrough directions for improv- ing shape quality.展开更多
A cold flow model of an 8 MW dual fluidized bed （DFB） system is simulated using the commercial compu- tational particle fluid dynamics （CPFD） software package Barracuda. The DFB system comprises a bubbling bed con...A cold flow model of an 8 MW dual fluidized bed （DFB） system is simulated using the commercial compu- tational particle fluid dynamics （CPFD） software package Barracuda. The DFB system comprises a bubbling bed connected to a fast fluidized bed with the bed material circulating between them. As the hydrodynam- ics in hot DFB plants are complex because of high temperatures and many chemical reaction processes, cold flow models are used. Performing numerical simulations of cold flows enables a focus on the hydro- dynamics as the chemistry and heat and mass transfer processes can be put aside. The drag law has a major influence on the hydrodynamics, and therefore its influence on pressure, particle distribution, and bed material recirculation rate is calculated using Barracuda and its results are compared with experimental results. The drag laws used were energy-minimization multiscale （EMMS）, Ganser, Turton-Levenspiel, and a combination of Wen-Yu]Ergun. Eleven operating points were chosen for that study and each was calculated with the aforementioned drag laws. The EMMS drag law best predicted the pressure and dis- tribution of the bed material in the different parts of the DFB system. For predicting the bed material recirculation rate, the Ganser drag law showed the best results. However, the drag laws often were not able to predict the experimentally found trends of the bed material recirculation rate. Indeed, the drag law significantly influences the hydrodynamic outcomes in a DFB system and must be chosen carefully to obtain meaningful simulation results. More research may enable recommendations as to which drag law is useful in simulations ofa DFB system with CPFD.展开更多
首先介绍了以液体循环热回收、双温冷源空调系统构成的多级新风处理过程,然后通过建立冷水机组、循环水泵、风机、热回收模块的数学模型,利用Simulink软件进行仿真计算,并结合实际工程案例分析了不同空气处理方式各主要设备的能耗变化...首先介绍了以液体循环热回收、双温冷源空调系统构成的多级新风处理过程,然后通过建立冷水机组、循环水泵、风机、热回收模块的数学模型,利用Simulink软件进行仿真计算,并结合实际工程案例分析了不同空气处理方式各主要设备的能耗变化趋势。结果表明,热回收+双温冷源空调能带来5.86%的能耗节省。最后,通过计算临界工况点,划分全年运行的多工况区,采取新风旁通和机组启停控制又能带来全年14756.89 k Wh的能耗节省。展开更多
基金financial contribution from the National Natural Science Foundation of China(22021005,22378041)Supporting Plan of Scientificand Technology Innovative Talents in Dalian(2023RJ001)Central Guidance on Local Science and Technology Development Fund of Liaoning Province(2025040052-JH6/1011)。
文摘Membrane-assisted antisolvent crystallization(MAAC)is a separation process that allows for precise regulation of the crystallization process in pharmaceutical,finechemical engineering,energy chemistry,etc.After decades of development,the current MAAC engineering lacks highly robust specialized instruments,which limits the further industrial application of the MAAC process.Herein,to guide the design and optimization of the advanced MAAC instrument(DUT-iMC),we developed a parameter evaluation strategy based on cold model experiments.This approach utilizes the average particle size variation rate and the counts variation rate to characterize crystal size changes.The layout of the internal membrane module in DUT-iMC and the arrangement of the conveying pipeline were optimized.This improvement enhanced particle conveying characteristics,promoting more efficienttransport and circulation within the module.The advanced MAAC instrument substantially automates the production process,and the internal probes accurately monitor and record process variables,allowing for precise regulation of crystal size and morphology.The optimal operating range was expanded by 150%compared to the laboratory instrument.The range of shell side flow rate options increased by 50%,and the production time can be shortened by up to 30%.This paper provides ideas and guidance for the industrialization of MAAC processes and the development of related instruments.
文摘The service facility or server is the key constituent to keep a system operational for desired period of time. As any eventuality with the system necessitates immediate presence of it (server) so the time point of arrival and treatment of server significantly affects the system performance. This paper works out the steady state behavior of a cold standby system equipped with two similar units and a server with elapsed arrival and treatment times following general probability distributions. It practices the theory of semi-Markov processes, regenerative point technique and Laplace transforms to derive the expressions for state transition probabilities, mean sojourn times, mean time to system failure, system availability, server busy period and expected frequencies of repairs and treatments. The profit function is also developed taking different costs and revenue in to account. For tracing wider applicability of the model for different reliability and cost-effective systems, a particular case study is also presented as an illustration.
文摘A novel vapor-liquid distributor was developed on the basis of sufficient study on the existing distributors applied in hydroprocessing reactors. The cold model test data showed that the fluid distribution performance of the novel vapor-liquid distributor was evidently better than the traditional one. Com- mercial tests of the new distributor were carded out in the 300 kt/a gas oil hydrotreating reactor at SINOPEC Changling Branch Company, showing that the new vapor-liquid distributor could improve the fluid distribution, promote the hydrotreating efficiency and lead to better performance than the traditional one.
文摘Based on the similarity theory, taking the horseshoe, city-gate and round linings as examples, the value and distribution regularities of normal frost heaving pressures （hereinafter as frost heaving pressures） in tunnels excavated in fractured rock mass in cold regions under different constraints and freezing depths were studied by a test model. It was found that the larger the frozen depth, the larger the frost heaving pressure, and the stronger the top constraint, the larger the frost heaving pressure. For the horseshoe lining and city-gate lining, the top constraint has a greater effect on the frost heaving pressures on the arch and the inverted arch. For the round lining, the influences of the top constraint on the frost heaving pressure in all linings are almost the same. The frost heaving pressure is maximum on the city-gate lining and minimal on the round lining. The largest frost heaving pressure all occur near the foot of the inverted arch for the three kinds of lining. Thus, the test data basically coincide with the observed in situ data.
文摘This paper investigates the comparison problem of the reliability index between a parallel and a cold-standby system,both of which are consisting of two identical units.On the contrary to the general intuitive result,we proved that,under the condition that the system is shocked by a Poisson stream,the life time of the parallel system is longer than that of the cold-standby one in the sense of probability.
文摘Short residence time of the sorbent in the gas stream and formation of a dense layer of reaction product surrounding its surface influence the sulfur removal efficiency. A practical means of improving the process performance is to employ fluidized bed reaction in replacement of entrained bed reaction on normally used in cool side desulfurizaiton. This paper describes cold modeling study of a circulating fluidized bed reactor. Several aspects of the problem are discussed: fluidization behavior of CaO, attrition of the sorbent and solids entrainment from the fluidized bed. Mechanisms and key controlling parameters are identified, and an integral model based on rate of attrition and mass balance is developed for predicting steady state mass flows and particle size distributions of the system. A process flow scheme is finally presented for conducting desulfurization tests in the second stage of the study.
基金This paper is supported by National Natural Science Foundation of China under Grant No50476050Natural Science Basic Research Plan in Shaanxi Province of China under Grant No2005E221
文摘The purpose of this paper is to present the flow field in the 300MW tangential firing utility boiler that used the Low NOx Concentric Firing System （LNCFS）. Using the method of cold isothermal simulation ensures the geometric and boundary condition similarity. At the same time the condition of self-modeling is met. The experimental results show that the mixture of primary air and secondary air becomes slower, the average turbulence magnitude the relative diameter of the tangential firing enlarges of the main combustion zone becomes less and when the secondary air deflection angle increases When the velocity pressure ratio of the secondary air to the primary air （p2/p1） enlarges, the mixture of the secondary air and the primary air becomes stronger, the average turbulence magnitude of the main combustion zone increases, and the relative diameter of the tangential firing becomes larger. Because the over fire air （OFA） laid out near the wall has a powerful penetration, the relative diameter of the tangential firing on the section of the OFA is very little, but the average turbulence magnitude is great. When the velocity pressure ratio of the OFA to the primary air POFA/p1 increases, the relative diameter of the tangential firing on the section of the OFA grows little, the average turbulence magnitude becomes larger and the penetration of the OFA becomes more powerful.
文摘In this paper, cold simulation experiments and numerical calculations are conducted to predict 3 D flow field aerodynamics for an oil furnace after being retrofitted due to its fuel variation. K ε model and SIMPLE program under body fit coordination (BFC) system, in which TTM non orthogonal method is used to control the irregular geometric boundary, are adopted to solve the control equations. Model tests are conducted to check the calculation results, showing that they are in agreement with each other. Three different alternatives with different side window locations are also calculated to optimize the designs. The field retrofitting results show that the combination of cold tests with numerical calculations has prosperous application in retrofitting or renewing medium and small boilers.
文摘<span style="font-family:Verdana;">A successful single parameter model has be</span><span style="font-family:Verdana;">en </span><span style="font-family:Verdana;">formulated to match the observations of photons from type 1a supernovae which were previously used to corroborate the standard </span><span style="font-family:Verdana;"><span style="white-space:nowrap;"><span style="white-space:nowrap;">𝛬</span></span></span><span style="font-family:;" "=""><span style="font-family:Verdana;"> cold dark matter model. The new single parameter model extrapolates all the way back to the cosmic background radiation (CMB) without requiring a separate model to describe inflation of the space dimensions after the Big Bang. This single parameter model assumes that spacetime forms a finite symmetrical manifold with positive curvature. For the spacetime manifold to be finite, the time dimension must also have positive curvature. This model was formulated to consider whether the curvature of the time dimension may be related to the curvature of the space dimensions. This possibility is not considered in the more complex models previously used to fit the available redshift data. The geometry for the finite spacetime manifold was selected to be compatible with the Friedmann equation with positive curvature. The manifold shape was motivated by an assumption that there exists a matter hemisphere (when considering time together with a single space dimension) and an antimatter hemisphere to give a symmetrical and spherical overall spacetime manifold. Hence, the space dimension expands from a pole to the equator, at a maximum value for the time dimension. This is analogous to the expansion of a circle of latitude on a globe from a pole to the equator. The three space dimensions are identical so that any arbitrary single space direction may be selected. The initial intention was to modify the assumed geometry for the spacetime manifold to account for the presence of matter. It was surprisingly found that, within the error of the reported measurements, no further modification was necessary to fit the data. The Friedmann equation reduces to the Schwarzschild equation at the equator so this can be used to predict the total amount of mass in the Universe. The resulting prediction is of the order of 10</span><sup><span style="font-family:Verdana;">51</span></sup><span style="font-family:Verdana;"> kg. The corresponding density of matter at the current time is approxima</span></span><span style="font-family:;" "=""><span style="font-family:Verdana;">tely 1.6 × 10</span><sup><span style="font-family:Verdana;">-28</span></sup><span style="font-family:Verdana;"> kg<span style="color:#636363;"><span style="font-size:13.3333px;"><span style="white-space:nowrap;">·</span></span></span>m</span><sup><span style="font-family:Verdana;">-3</span></sup><span style="font-family:Verdana;">.</span></span>
基金Supported by National Key Technology Support Program of China (Grant No. 2011BAF15B00)Hebei Provincial Natural Science Foundation of China (Grant No. E2016203482)+1 种基金Hebei Provincial Science and Technology Research Foundation of China (Grant No. ZD2014034)Youth Independent Research Program of Yanshan University of China (Grant No. 14LGA003)
文摘Shape is an important quality index of cold rolling strip. Up to now, many problems in the shape control domain have not been solved satisfactorily, and a review on the research progress in the shape control domain can help to seek new breakthrough directions. In the past 10 years, researches and applications of shape control models, shape control means, shape detection technology, and shape con- trol system have achieved significant progress. In the aspect of shape control models, the researches in the past improve the accuracy, speed and robustness of the models. The intelligentization of shape control models should be strengthened in the future. In the aspect of the shape control means, the researches in the past focus on the roll opti- mization, mill type selection, process optimization, local strip shape control, edge drop control, and so on. In the future, more attention should be paid to the coordination control of both strip shape and other quality indexes, and the refinement of control objective should be strengthened. In the aspects of shape detection technology and shape control system, some new types of shape detection meters and shape control systems are developed and have successfully indus- trial applications. In the future, the standardization of shape detection technology and shape control system should be promoted to solve the problem of compatibility. In general,the four expected development trends of shape control for cold roiling strip in the future are intelligentization, coordi- nation, refinement, and standardization. The proposed research provides new breakthrough directions for improv- ing shape quality.
文摘A cold flow model of an 8 MW dual fluidized bed （DFB） system is simulated using the commercial compu- tational particle fluid dynamics （CPFD） software package Barracuda. The DFB system comprises a bubbling bed connected to a fast fluidized bed with the bed material circulating between them. As the hydrodynam- ics in hot DFB plants are complex because of high temperatures and many chemical reaction processes, cold flow models are used. Performing numerical simulations of cold flows enables a focus on the hydro- dynamics as the chemistry and heat and mass transfer processes can be put aside. The drag law has a major influence on the hydrodynamics, and therefore its influence on pressure, particle distribution, and bed material recirculation rate is calculated using Barracuda and its results are compared with experimental results. The drag laws used were energy-minimization multiscale （EMMS）, Ganser, Turton-Levenspiel, and a combination of Wen-Yu]Ergun. Eleven operating points were chosen for that study and each was calculated with the aforementioned drag laws. The EMMS drag law best predicted the pressure and dis- tribution of the bed material in the different parts of the DFB system. For predicting the bed material recirculation rate, the Ganser drag law showed the best results. However, the drag laws often were not able to predict the experimentally found trends of the bed material recirculation rate. Indeed, the drag law significantly influences the hydrodynamic outcomes in a DFB system and must be chosen carefully to obtain meaningful simulation results. More research may enable recommendations as to which drag law is useful in simulations ofa DFB system with CPFD.
文摘首先介绍了以液体循环热回收、双温冷源空调系统构成的多级新风处理过程,然后通过建立冷水机组、循环水泵、风机、热回收模块的数学模型,利用Simulink软件进行仿真计算,并结合实际工程案例分析了不同空气处理方式各主要设备的能耗变化趋势。结果表明,热回收+双温冷源空调能带来5.86%的能耗节省。最后,通过计算临界工况点,划分全年运行的多工况区,采取新风旁通和机组启停控制又能带来全年14756.89 k Wh的能耗节省。
