This paper proposes an equivalent modeling method for photovoltaic(PV)power stations via a particle swarm optimization(PSO)K-means clustering(KMC)algorithm with passive filter parameter clustering to address the compl...This paper proposes an equivalent modeling method for photovoltaic(PV)power stations via a particle swarm optimization(PSO)K-means clustering(KMC)algorithm with passive filter parameter clustering to address the complexities,simulation time cost and convergence problems of detailed PV power station models.First,the amplitude–frequency curves of different filter parameters are analyzed.Based on the results,a grouping parameter set for characterizing the external filter characteristics is established.These parameters are further defined as clustering parameters.A single PV inverter model is then established as a prerequisite foundation.The proposed equivalent method combines the global search capability of PSO with the rapid convergence of KMC,effectively overcoming the tendency of KMC to become trapped in local optima.This approach enhances both clustering accuracy and numerical stability when determining equivalence for PV inverter units.Using the proposed clustering method,both a detailed PV power station model and an equivalent model are developed and compared.Simulation and hardwarein-loop(HIL)results based on the equivalent model verify that the equivalent method accurately represents the dynamic characteristics of PVpower stations and adapts well to different operating conditions.The proposed equivalent modeling method provides an effective analysis tool for future renewable energy integration research.展开更多
We employed random distributions and gradient descent methods for the Generator Coordinate Method(GCM)to identify effective basis wave functions,taking halo nuclei ^(6)He and ^(6)Li as examples.By comparing the ground...We employed random distributions and gradient descent methods for the Generator Coordinate Method(GCM)to identify effective basis wave functions,taking halo nuclei ^(6)He and ^(6)Li as examples.By comparing the ground state(0^(+))energy of ^(6)He and the excited state(0^(+))energy of 6 Li calculated with various random distributions and manually selected generation coordinates,we found that the heavy tail characteristic of the logistic distribution better describes the features of the halo nuclei.Subsequently,the Adam algorithm from machine learning was applied to optimize the basis wave functions,indicating that a limited number of basis wave functions can approximate the converged values.These results offer some empirical insights for selecting basis wave functions and contribute to the broader application of machine learning methods in predicting effective basis wave functions.展开更多
Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients a...Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients and the server.However,the presence of data heterogeneity can lead to inefficient model training and even reduce the final model’s accuracy and generalization capability.Meanwhile,data scarcity can result in suboptimal cluster distributions for few-shot clients in centralized clustering tasks,and standalone personalization tasks may cause severe overfitting issues.To address these limitations,we introduce a federated learning dual optimization model based on clustering and personalization strategy(FedCPS).FedCPS adopts a decentralized approach,where clients identify their cluster membership locally without relying on a centralized clustering algorithm.Building on this,FedCPS introduces personalized training tasks locally,adding a regularization term to control deviations between local and cluster models.This improves the generalization ability of the final model while mitigating overfitting.The use of weight-sharing techniques also reduces the computational cost of central machines.Experimental results on MNIST,FMNIST,CIFAR10,and CIFAR100 datasets demonstrate that our method achieves better personalization effects compared to other personalized federated learning methods,with an average test accuracy improvement of 0.81%–2.96%.Meanwhile,we adjusted the proportion of few-shot clients to evaluate the impact on accuracy across different methods.The experiments show that FedCPS reduces accuracy by only 0.2%–3.7%,compared to 2.1%–10%for existing methods.Our method demonstrates its advantages across diverse data environments.展开更多
Regard to the real-time dynamic digital twin modelling problem of a new-type distribution network that includes distributed resources such as distributed photovoltaic,energy storage,charging pile,and electric vehicle,...Regard to the real-time dynamic digital twin modelling problem of a new-type distribution network that includes distributed resources such as distributed photovoltaic,energy storage,charging pile,and electric vehicle,a new-type distribution network digital twin topology modeling method based on Common Information Model(CIM)specifications and spectral clustering is proposed.Firstly,according to the specifications of the CIM standard,the digital twin topology models of distributed resources are extended and established.Secondly,based on the digital twin topology models of distributed resources,a digital twin aggregation modelling method for new-type distribution network is proposed based on spectral clustering.Furthermore,an online linked update strategy for the digital twin model of new-type distribution network that integrates real-time topology states is proposed.Finally,a case study is conducted on a distribution network in a certain demonstration area in China,and the results verify the practicability and effectiveness of the method proposed in this paper.This lays the foundation for the application of electrical network twin analysis,such as power flow calculation,optimal power flow,economic dispatch,and safety check,in a new-type distribution network that includes diversified distributed resources.展开更多
Data-driven reduced-order modeling opens new avenues of understanding,predicting,controlling,and optimizing system behavior.Simple systems may have state spaces in which sparse human-interpretable dynamical systems ca...Data-driven reduced-order modeling opens new avenues of understanding,predicting,controlling,and optimizing system behavior.Simple systems may have state spaces in which sparse human-interpretable dynamical systems can be identified.This approach has been pioneered by Brunton et al.(2016,PNAS)with sparse identification of nonlinear dynamics.Complex systems,however,cannot be expected to benefit from such simple analytical descriptions.Yet,smoothness may be exploited by analytical local descriptions.In this paper,we identify a clusterwise polynomial dynamics from time-resolved snapshot data.The full state space is partitioned into clusters with a reduced-order polynomial description for each cluster and a global patching strategy.The resulting clusterwise modeling is entirely data-driven and requires no prior knowledge of the system dynamics.We illustrate the approach on the well-known chaotic Lorenz and Rössler systems,on the more challenging chaotic fluid flow dynamics of higher state-space dimensions,on a noisy electrocardiogram signal,and finally on the time evolution of the monthly sunspot number.Clusterwise modeling offers a powerful and interpretable paradigm for dynamical modeling.Nonlinear dynamics can be approximated by assembling many simple local models of different resolutions,opening new paths to understand and control intricate nonlinearities.展开更多
In recent years,there has been a concerted effort to improve anomaly detection tech-niques,particularly in the context of high-dimensional,distributed clinical data.Analysing patient data within clinical settings reve...In recent years,there has been a concerted effort to improve anomaly detection tech-niques,particularly in the context of high-dimensional,distributed clinical data.Analysing patient data within clinical settings reveals a pronounced focus on refining diagnostic accuracy,personalising treatment plans,and optimising resource allocation to enhance clinical outcomes.Nonetheless,this domain faces unique challenges,such as irregular data collection,inconsistent data quality,and patient-specific structural variations.This paper proposed a novel hybrid approach that integrates heuristic and stochastic methods for anomaly detection in patient clinical data to address these challenges.The strategy combines HPO-based optimal Density-Based Spatial Clustering of Applications with Noise for clustering patient exercise data,facilitating efficient anomaly identification.Subsequently,a stochastic method based on the Interquartile Range filters unreliable data points,ensuring that medical tools and professionals receive only the most pertinent and accurate information.The primary objective of this study is to equip healthcare pro-fessionals and researchers with a robust tool for managing extensive,high-dimensional clinical datasets,enabling effective isolation and removal of aberrant data points.Furthermore,a sophisticated regression model has been developed using Automated Machine Learning(AutoML)to assess the impact of the ensemble abnormal pattern detection approach.Various statistical error estimation techniques validate the efficacy of the hybrid approach alongside AutoML.Experimental results show that implementing this innovative hybrid model on patient rehabilitation data leads to a notable enhance-ment in AutoML performance,with an average improvement of 0.041 in the R2 score,surpassing the effectiveness of traditional regression models.展开更多
In order to solve the problems of short network lifetime and high data transmission delay in data gathering for wireless sensor network(WSN)caused by uneven energy consumption among nodes,a hybrid energy efficient clu...In order to solve the problems of short network lifetime and high data transmission delay in data gathering for wireless sensor network(WSN)caused by uneven energy consumption among nodes,a hybrid energy efficient clustering routing base on firefly and pigeon-inspired algorithm(FF-PIA)is proposed to optimise the data transmission path.After having obtained the optimal number of cluster head node(CH),its result might be taken as the basis of producing the initial population of FF-PIA algorithm.The L′evy flight mechanism and adaptive inertia weighting are employed in the algorithm iteration to balance the contradiction between the global search and the local search.Moreover,a Gaussian perturbation strategy is applied to update the optimal solution,ensuring the algorithm can jump out of the local optimal solution.And,in the WSN data gathering,a onedimensional signal reconstruction algorithm model is developed by dilated convolution and residual neural networks(DCRNN).We conducted experiments on the National Oceanic and Atmospheric Administration(NOAA)dataset.It shows that the DCRNN modeldriven data reconstruction algorithm improves the reconstruction accuracy as well as the reconstruction time performance.FF-PIA and DCRNN clustering routing co-simulation reveals that the proposed algorithm can effectively improve the performance in extending the network lifetime and reducing data transmission delay.展开更多
Transient stability assessment(TSA)based on artificial intelligence typically has two distinct model management approaches:a unified management approach for all faulted lines and a separate management approach for eac...Transient stability assessment(TSA)based on artificial intelligence typically has two distinct model management approaches:a unified management approach for all faulted lines and a separate management approach for each faulted line.To address the shortcomings of the aforementioned approaches,namely accuracy,training time,and model management complexity,a multi-model management approach for power system TSA based on multi-moment feature clustering has been proposed.First,the steady-state and transient features present under fault conditions were obtained through a transient simulation of line faults.The input sample set was then constructed using the aforementioned multi-moment electrical features and the embedded faulty line numbers.Subsequently,K-means clustering was conducted on each line based on the similarity of their electrical features,employing t-SNE dimensionality reduction.The PSO-CNN model was trained separately for each cluster to generate several independent TSA models.Finally,a model effectiveness evaluation system consisting of five metrics was established,and the effect of the sample imbalance ratio on the model effectiveness was investigated.The model effectiveness was evaluated using the IEEE 39-bus system algorithm.The results showed that the multi-model management strategy based on multi-moment feature clustering can effectively combine the two advantages of superior evaluation performance and streamlined model management by fully extracting system features.Moreover,this approach allows for more flexible adjustments to line topology changes.展开更多
The distillation process is an important chemical process,and the application of data-driven modelling approach has the potential to reduce model complexity compared to mechanistic modelling,thus improving the efficie...The distillation process is an important chemical process,and the application of data-driven modelling approach has the potential to reduce model complexity compared to mechanistic modelling,thus improving the efficiency of process optimization or monitoring studies.However,the distillation process is highly nonlinear and has multiple uncertainty perturbation intervals,which brings challenges to accurate data-driven modelling of distillation processes.This paper proposes a systematic data-driven modelling framework to solve these problems.Firstly,data segment variance was introduced into the K-means algorithm to form K-means data interval(KMDI)clustering in order to cluster the data into perturbed and steady state intervals for steady-state data extraction.Secondly,maximal information coefficient(MIC)was employed to calculate the nonlinear correlation between variables for removing redundant features.Finally,extreme gradient boosting(XGBoost)was integrated as the basic learner into adaptive boosting(AdaBoost)with the error threshold(ET)set to improve weights update strategy to construct the new integrated learning algorithm,XGBoost-AdaBoost-ET.The superiority of the proposed framework is verified by applying this data-driven modelling framework to a real industrial process of propylene distillation.展开更多
Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study comp...Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study compares the performance of practical iterative reallocation algorithms with model-based clustering algorithms.The data is from forest vegetation in Virginia(United States),the Hyrcanian Forest(Asia),and European beech forests.Practical iterative reallocation algorithms were applied as non-hierarchical methods and Finite Gaussian mixture modeling was used as a model-based clustering method.Due to limitations on dimensionality in model-based clustering,principal coordinates analysis was employed to reduce the dataset’s dimensions.A log transformation was applied to achieve a normal distribution for the pseudo-species data before calculating the Bray-Curtis dissimilarity.The findings indicate that the reallocation of misclassified objects based on silhouette width(OPTSIL)with Flexible-β(-0.25)had the highest mean among the tested clustering algorithms with Silhouette width 1(REMOS1)with Flexible-β(-0.25)second.However,model-based clustering performed poorly.Based on these results,it is recommended using OPTSIL with Flexible-β(-0.25)and REMOS1 with Flexible-β(-0.25)for forest vegetation classification instead of model-based clustering particularly for heterogeneous datasets common in forest vegetation community data.展开更多
Cluster-basedmodels have numerous application scenarios in vehicular ad-hoc networks(VANETs)and can greatly help improve the communication performance of VANETs.However,the frequent movement of vehicles can often lead...Cluster-basedmodels have numerous application scenarios in vehicular ad-hoc networks(VANETs)and can greatly help improve the communication performance of VANETs.However,the frequent movement of vehicles can often lead to changes in the network topology,thereby reducing cluster stability in urban scenarios.To address this issue,we propose a clustering model based on the density peak clustering(DPC)method and sparrow search algorithm(SSA),named SDPC.First,the model constructs a fitness function based on the parameters obtained from the DPC method and deploys the SSA for iterative optimization to select cluster heads(CHs).Then,the vehicles that have not been selected as CHs are assigned to appropriate clusters by comprehensively considering the distance parameter and link-reliability parameter.Finally,cluster maintenance strategies are considered to tackle the changes in the clusters’organizational structure.To verify the performance of the model,we conducted a simulation on a real-world scenario for multiple metrics related to clusters’stability.The results show that compared with the APROVE and the GAPC,SDPC showed clear performance advantages,indicating that SDPC can effectively ensure VANETs’cluster stability in urban scenarios.展开更多
In recent years,with the rapid development of software systems,the continuous expansion of software scale and the increasing complexity of systems have led to the emergence of a growing number of software metrics.Defe...In recent years,with the rapid development of software systems,the continuous expansion of software scale and the increasing complexity of systems have led to the emergence of a growing number of software metrics.Defect prediction methods based on software metric elements highly rely on software metric data.However,redundant software metric data is not conducive to efficient defect prediction,posing severe challenges to current software defect prediction tasks.To address these issues,this paper focuses on the rational clustering of software metric data.Firstly,multiple software projects are evaluated to determine the preset number of clusters for software metrics,and various clustering methods are employed to cluster the metric elements.Subsequently,a co-occurrence matrix is designed to comprehensively quantify the number of times that metrics appear in the same category.Based on the comprehensive results,the software metric data are divided into two semantic views containing different metrics,thereby analyzing the semantic information behind the software metrics.On this basis,this paper also conducts an in-depth analysis of the impact of different semantic view of metrics on defect prediction results,as well as the performance of various classification models under these semantic views.Experiments show that the joint use of the two semantic views can significantly improve the performance of models in software defect prediction,providing a new understanding and approach at the semantic view level for defect prediction research based on software metrics.展开更多
Bubbles within an elastic shell,which undergo ultrasound-driven oscillation to treat tumors and soft tissues,are frequently treated as viscoelastic media.Therefore,studying the dynamic behavior of bubbles wrapped in a...Bubbles within an elastic shell,which undergo ultrasound-driven oscillation to treat tumors and soft tissues,are frequently treated as viscoelastic media.Therefore,studying the dynamic behavior of bubbles wrapped in a viscoelastic medium while considering an elastic shell can provide theoretical support for ultrasound biotherapy.Bubbles are always in the form of clusters.Therefore,a model of spherical bubble clusters in a liquid cavity wrapped by an elastic shell was constructed,the coupled oscillation equations of bubbles were obtained by taking into account the dynamic effects of the elastic shell and the viscoelastic media outside the cavity,and the oscillation behaviors of the bubbles were analyzed.Acoustic waves at 1.5 MHz could cause bubbles with a radius of 1μm to resonate.Increasing the number of bubbles increased the suppressing effect of bubble oscillation caused by bubble interaction.The bubble cluster oscillation caused the elastic shell to oscillate and be stressed,and the stress trend was the inverse of the bubble oscillation trend with maximal tensile and compressive stresses.Bubbles with an equilibrium radius of 2μm exhibited the lowest inertial cavitation threshold,making inertial cavitation more likely under high-frequency acoustic excitation.The inertial cavitation threshold of bubbles was heavily influenced by the acoustic wave frequency,bubble number density,and bubble cluster radius.The nonspherical oscillation stability of bubbles was primarily affected by the driving acoustic pressure amplitude and frequency,bubble initial radius,bubble number density,and bubble cluster radius.The acoustic frequency and amplitude exhibited a synergistic effect,with a minimum unstable driving acoustic pressure threshold of approximately 0.13 MPa.The initial radius within the elastic shell affected the minimum unstable driving acoustic pressure threshold.展开更多
We propose a robust earthquake clustering method:the Bayesian Gaussian mixture model with nearest-neighbor distance(BGMM-NND)algorithm.Unlike the conventional nearest neighbor distance method,the BGMM-NND algorithm el...We propose a robust earthquake clustering method:the Bayesian Gaussian mixture model with nearest-neighbor distance(BGMM-NND)algorithm.Unlike the conventional nearest neighbor distance method,the BGMM-NND algorithm eliminates the need for hyperparameter tuning or reliance on fixed thresholds,offering enhanced flexibility for clustering across varied seismic scales.By integrating cumulative probability and BGMM with principal component analysis(PCA),the BGMM-NND algorithm effectively distinguishes between background and triggered earthquakes while maintaining the magnitude component and resolving the issue of excessively large spatial cluster domains.We apply the BGMM-NND algorithm to the Sichuan–Yunnan seismic catalog from 1971 to 2024,revealing notable variations in earthquake frequency,triggering characteristics,and recurrence patterns across different fault zones.Distinct clustering and triggering behaviors are identified along different segments of the Longmenshan Fault.Multiple seismic modes,namely,the short-distance mode,the medium-distance mode,the repeating-like mode,the uniform background mode,and the Wenchuan mode,are uncovered.The algorithm's flexibility and robust performance in earthquake clustering makes it a valuable tool for exploring seismicity characteristics,offering new insights into earthquake clustering and the spatiotemporal patterns of seismic activity.展开更多
Recent work analysing magnesium hydrogenation using Reflecting Electron Energy Loss Spectroscopy(REELS)and Density Function Theory(DFT)has indicated interfacial polarisation and interstitial hydrogen clustering influe...Recent work analysing magnesium hydrogenation using Reflecting Electron Energy Loss Spectroscopy(REELS)and Density Function Theory(DFT)has indicated interfacial polarisation and interstitial hydrogen clustering influence the reaction rate.The site availability model has been modified to include interstitial hydrogen clustering within the site availability factor and interface polarisation using interface treatment.The new model,SAM-CV-S,has demonstrated improved modelling of magnesium hydrogenation across wide operating conditions,such as temperatures from 330 to 400℃and pressures up to 40 bar.This wide applicability makes it a robust model that can be used to simulate bed performance in solid-state hydrogen stores.Thus,the site availability factor successfully combines interstitial hydrogen clustering with thermal resistance effects,which are known to strongly influence metal hydride reactor designs at scale.The next phase of the model is to incorporate a predictive hydrogen capacity method into the model.展开更多
With the continuous expansion of the power system scale and the increasing complexity of operational mode,the interaction between transmission and distribution systems is becoming more and more significant,placing hig...With the continuous expansion of the power system scale and the increasing complexity of operational mode,the interaction between transmission and distribution systems is becoming more and more significant,placing higher requirements on the accuracy and efficiency of the power system state estimation to address the challenge of balancing computational efficiency and estimation accuracy in traditional coupled transmission and distribution state estimation methods,this paper proposes a collaborative state estimation method based on distribution systems state clustering and load model parameter identification.To resolve the scalability issue of coupled transmission and distribution power systems,clustering is first carried out based on the distribution system states.As the data and models of the transmission system and distribution systems are not shared.For the transmission system,equating the power transmitted from the transmission system to the distribution system is the same as equating the distribution system.Further,the power transmitted from the transmission system to different types of distribution systems is equivalent to different polynomial equivalent load models.Then,a parameter identification method is proposed to obtain the parameters of the equivalent load model.Finally,a transmission and distribution collaborative state estimation model is constructed based on the equivalent load model.The results of the numerical analysis show that compared with the traditional master-slave splitting method,the proposed method significantly enhances computational efficiency while maintaining high estimation accuracy.展开更多
This study demonstrates a novel integration of large language models,machine learning,and multicriteria decision-making to investigate self-moderation in small online communities,a topic under-explored compared to use...This study demonstrates a novel integration of large language models,machine learning,and multicriteria decision-making to investigate self-moderation in small online communities,a topic under-explored compared to user behavior and platform-driven moderation on social media.The proposed methodological framework(1)utilizes large language models for social media post analysis and categorization,(2)employs k-means clustering for content characterization,and(3)incorporates the TODIM(Tomada de Decisão Interativa Multicritério)method to determine moderation strategies based on expert judgments.In general,the fully integrated framework leverages the strengths of these intelligent systems in a more systematic evaluation of large-scale decision problems.When applied in social media moderation,this approach promotes nuanced and context-sensitive self-moderation by taking into account factors such as cultural background and geographic location.The application of this framework is demonstrated within Facebook groups.Eight distinct content clusters encompassing safety,harassment,diversity,and misinformation are identified.Analysis revealed a preference for content removal across all clusters,suggesting a cautious approach towards potentially harmful content.However,the framework also highlights the use of other moderation actions,like account suspension,depending on the content category.These findings contribute to the growing body of research on self-moderation and offer valuable insights for creating safer and more inclusive online spaces within smaller communities.展开更多
Resilience studies for water distribution systems(WDS)coupled with other interdependent infrastructure systems attract increasing attention from stakeholders and researchers.However,most existing large-scale WDS model...Resilience studies for water distribution systems(WDS)coupled with other interdependent infrastructure systems attract increasing attention from stakeholders and researchers.However,most existing large-scale WDS models are single infrastructure-based without consideration of other infrastructure systems.This is due to a lack of needed information on systems coupling,the structure of the simulator used,and the computation load involved.To address these gaps,this paper presents a synthetic modeling framework for a real-world WDS as coordinating with other infrastructure systems via a building-mediated clustering approach through consideration of physical distance and node capacity.First,the WDS network topology and operation parameters are inferred via bulk open-source information.A building-mediated clustering approach is designed to systematically derive the interdependence between the WDS and the power system similarly created as a case study.Second,a novel linearization method is developed in formulating the WDS model that can relieve computation load while maintaining accuracy.Finally,a disruption-recovery framework is developed to demonstrate the proposed methodology in modelling WDS resilience.The framework is applied to a neighborhood in Queenstown,Singapore,an area of 20.43 km^(2) and 96,000 population.The near-real-time simulations on the coupled system involving 308 nodes and 384 links showcase the effectiveness and application of the proposed synthetic modeling and formulation.展开更多
Low visibility conditions,particularly those caused by fog,significantly affect road safety and reduce drivers’ability to see ahead clearly.The conventional approaches used to address this problem primarily rely on i...Low visibility conditions,particularly those caused by fog,significantly affect road safety and reduce drivers’ability to see ahead clearly.The conventional approaches used to address this problem primarily rely on instrument-based and fixed-threshold-based theoretical frameworks,which face challenges in adaptability and demonstrate lower performance under varying environmental conditions.To overcome these challenges,we propose a real-time visibility estimation model that leverages roadside CCTV cameras to monitor and identify visibility levels under different weather conditions.The proposedmethod begins by identifying specific regions of interest(ROI)in the CCTVimages and focuses on extracting specific features such as the number of lines and contours detected within these regions.These features are then provided as an input to the proposed hierarchical clusteringmodel,which classifies them into different visibility levels without the need for predefined rules and threshold values.In the proposed approach,we used two different distance similaritymetrics,namely dynamic time warping(DTW)and Euclidean distance,alongside the proposed hierarchical clustering model and noted its performance in terms of numerous evaluation measures.The proposed model achieved an average accuracy of 97.81%,precision of 91.31%,recall of 91.25%,and F1-score of 91.27% using theDTWdistancemetric.We also conducted experiments for other deep learning(DL)-based models used in the literature and compared their performances with the proposed model.The experimental results demonstrate that the proposedmodel ismore adaptable and consistent compared to themethods used in the literature.The proposedmethod provides drivers real-time and accurate visibility information and enhances road safety during low visibility conditions.展开更多
Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully construct...Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24.展开更多
基金supported by the Research Project of China Southern Power Grid(No.056200KK52222031).
文摘This paper proposes an equivalent modeling method for photovoltaic(PV)power stations via a particle swarm optimization(PSO)K-means clustering(KMC)algorithm with passive filter parameter clustering to address the complexities,simulation time cost and convergence problems of detailed PV power station models.First,the amplitude–frequency curves of different filter parameters are analyzed.Based on the results,a grouping parameter set for characterizing the external filter characteristics is established.These parameters are further defined as clustering parameters.A single PV inverter model is then established as a prerequisite foundation.The proposed equivalent method combines the global search capability of PSO with the rapid convergence of KMC,effectively overcoming the tendency of KMC to become trapped in local optima.This approach enhances both clustering accuracy and numerical stability when determining equivalence for PV inverter units.Using the proposed clustering method,both a detailed PV power station model and an equivalent model are developed and compared.Simulation and hardwarein-loop(HIL)results based on the equivalent model verify that the equivalent method accurately represents the dynamic characteristics of PVpower stations and adapts well to different operating conditions.The proposed equivalent modeling method provides an effective analysis tool for future renewable energy integration research.
基金supported by the National Key R&D Program of China(No.2023YFA1606701)the National Natural Science Foundation of China(Nos.12175042,11890710,11890714,12047514,12147101,and 12347106)+1 种基金Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030008)China National Key R&D Program(No.2022YFA1602402).
文摘We employed random distributions and gradient descent methods for the Generator Coordinate Method(GCM)to identify effective basis wave functions,taking halo nuclei ^(6)He and ^(6)Li as examples.By comparing the ground state(0^(+))energy of ^(6)He and the excited state(0^(+))energy of 6 Li calculated with various random distributions and manually selected generation coordinates,we found that the heavy tail characteristic of the logistic distribution better describes the features of the halo nuclei.Subsequently,the Adam algorithm from machine learning was applied to optimize the basis wave functions,indicating that a limited number of basis wave functions can approximate the converged values.These results offer some empirical insights for selecting basis wave functions and contribute to the broader application of machine learning methods in predicting effective basis wave functions.
基金supported by the Foundation of President of Hebei University(XZJJ202303).
文摘Federated learning is a machine learning framework designed to protect privacy by keeping training data on clients’devices without sharing private data.It trains a global model through collaboration between clients and the server.However,the presence of data heterogeneity can lead to inefficient model training and even reduce the final model’s accuracy and generalization capability.Meanwhile,data scarcity can result in suboptimal cluster distributions for few-shot clients in centralized clustering tasks,and standalone personalization tasks may cause severe overfitting issues.To address these limitations,we introduce a federated learning dual optimization model based on clustering and personalization strategy(FedCPS).FedCPS adopts a decentralized approach,where clients identify their cluster membership locally without relying on a centralized clustering algorithm.Building on this,FedCPS introduces personalized training tasks locally,adding a regularization term to control deviations between local and cluster models.This improves the generalization ability of the final model while mitigating overfitting.The use of weight-sharing techniques also reduces the computational cost of central machines.Experimental results on MNIST,FMNIST,CIFAR10,and CIFAR100 datasets demonstrate that our method achieves better personalization effects compared to other personalized federated learning methods,with an average test accuracy improvement of 0.81%–2.96%.Meanwhile,we adjusted the proportion of few-shot clients to evaluate the impact on accuracy across different methods.The experiments show that FedCPS reduces accuracy by only 0.2%–3.7%,compared to 2.1%–10%for existing methods.Our method demonstrates its advantages across diverse data environments.
基金Supported by Science and Technology Project of State Grid Corporation of China(5108-202218280A-2-396-XG).
文摘Regard to the real-time dynamic digital twin modelling problem of a new-type distribution network that includes distributed resources such as distributed photovoltaic,energy storage,charging pile,and electric vehicle,a new-type distribution network digital twin topology modeling method based on Common Information Model(CIM)specifications and spectral clustering is proposed.Firstly,according to the specifications of the CIM standard,the digital twin topology models of distributed resources are extended and established.Secondly,based on the digital twin topology models of distributed resources,a digital twin aggregation modelling method for new-type distribution network is proposed based on spectral clustering.Furthermore,an online linked update strategy for the digital twin model of new-type distribution network that integrates real-time topology states is proposed.Finally,a case study is conducted on a distribution network in a certain demonstration area in China,and the results verify the practicability and effectiveness of the method proposed in this paper.This lays the foundation for the application of electrical network twin analysis,such as power flow calculation,optimal power flow,economic dispatch,and safety check,in a new-type distribution network that includes diversified distributed resources.
基金supported by the National Natural Science Foundation of China(Grant Nos.12172109,12202121,and 12302293)the China Postdoctoral Science Foundation(Grant Nos.2023M730866 and 2023T160166)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(Grant No.2022A1515011492)the Shenzhen Science and Technology Program(Grant Nos.JCYJ20220531095605012,KJZD20230923115210021,and 29853MKCJ202300205).
文摘Data-driven reduced-order modeling opens new avenues of understanding,predicting,controlling,and optimizing system behavior.Simple systems may have state spaces in which sparse human-interpretable dynamical systems can be identified.This approach has been pioneered by Brunton et al.(2016,PNAS)with sparse identification of nonlinear dynamics.Complex systems,however,cannot be expected to benefit from such simple analytical descriptions.Yet,smoothness may be exploited by analytical local descriptions.In this paper,we identify a clusterwise polynomial dynamics from time-resolved snapshot data.The full state space is partitioned into clusters with a reduced-order polynomial description for each cluster and a global patching strategy.The resulting clusterwise modeling is entirely data-driven and requires no prior knowledge of the system dynamics.We illustrate the approach on the well-known chaotic Lorenz and Rössler systems,on the more challenging chaotic fluid flow dynamics of higher state-space dimensions,on a noisy electrocardiogram signal,and finally on the time evolution of the monthly sunspot number.Clusterwise modeling offers a powerful and interpretable paradigm for dynamical modeling.Nonlinear dynamics can be approximated by assembling many simple local models of different resolutions,opening new paths to understand and control intricate nonlinearities.
文摘In recent years,there has been a concerted effort to improve anomaly detection tech-niques,particularly in the context of high-dimensional,distributed clinical data.Analysing patient data within clinical settings reveals a pronounced focus on refining diagnostic accuracy,personalising treatment plans,and optimising resource allocation to enhance clinical outcomes.Nonetheless,this domain faces unique challenges,such as irregular data collection,inconsistent data quality,and patient-specific structural variations.This paper proposed a novel hybrid approach that integrates heuristic and stochastic methods for anomaly detection in patient clinical data to address these challenges.The strategy combines HPO-based optimal Density-Based Spatial Clustering of Applications with Noise for clustering patient exercise data,facilitating efficient anomaly identification.Subsequently,a stochastic method based on the Interquartile Range filters unreliable data points,ensuring that medical tools and professionals receive only the most pertinent and accurate information.The primary objective of this study is to equip healthcare pro-fessionals and researchers with a robust tool for managing extensive,high-dimensional clinical datasets,enabling effective isolation and removal of aberrant data points.Furthermore,a sophisticated regression model has been developed using Automated Machine Learning(AutoML)to assess the impact of the ensemble abnormal pattern detection approach.Various statistical error estimation techniques validate the efficacy of the hybrid approach alongside AutoML.Experimental results show that implementing this innovative hybrid model on patient rehabilitation data leads to a notable enhance-ment in AutoML performance,with an average improvement of 0.041 in the R2 score,surpassing the effectiveness of traditional regression models.
基金partially supported by the National Natural Science Foundation of China(62161016)the Key Research and Development Project of Lanzhou Jiaotong University(ZDYF2304)+1 种基金the Beijing Engineering Research Center of Highvelocity Railway Broadband Mobile Communications(BHRC-2022-1)Beijing Jiaotong University。
文摘In order to solve the problems of short network lifetime and high data transmission delay in data gathering for wireless sensor network(WSN)caused by uneven energy consumption among nodes,a hybrid energy efficient clustering routing base on firefly and pigeon-inspired algorithm(FF-PIA)is proposed to optimise the data transmission path.After having obtained the optimal number of cluster head node(CH),its result might be taken as the basis of producing the initial population of FF-PIA algorithm.The L′evy flight mechanism and adaptive inertia weighting are employed in the algorithm iteration to balance the contradiction between the global search and the local search.Moreover,a Gaussian perturbation strategy is applied to update the optimal solution,ensuring the algorithm can jump out of the local optimal solution.And,in the WSN data gathering,a onedimensional signal reconstruction algorithm model is developed by dilated convolution and residual neural networks(DCRNN).We conducted experiments on the National Oceanic and Atmospheric Administration(NOAA)dataset.It shows that the DCRNN modeldriven data reconstruction algorithm improves the reconstruction accuracy as well as the reconstruction time performance.FF-PIA and DCRNN clustering routing co-simulation reveals that the proposed algorithm can effectively improve the performance in extending the network lifetime and reducing data transmission delay.
基金supported by the Science and Technology Project of SGCC(5100-202199558A-0-5-ZN).
文摘Transient stability assessment(TSA)based on artificial intelligence typically has two distinct model management approaches:a unified management approach for all faulted lines and a separate management approach for each faulted line.To address the shortcomings of the aforementioned approaches,namely accuracy,training time,and model management complexity,a multi-model management approach for power system TSA based on multi-moment feature clustering has been proposed.First,the steady-state and transient features present under fault conditions were obtained through a transient simulation of line faults.The input sample set was then constructed using the aforementioned multi-moment electrical features and the embedded faulty line numbers.Subsequently,K-means clustering was conducted on each line based on the similarity of their electrical features,employing t-SNE dimensionality reduction.The PSO-CNN model was trained separately for each cluster to generate several independent TSA models.Finally,a model effectiveness evaluation system consisting of five metrics was established,and the effect of the sample imbalance ratio on the model effectiveness was investigated.The model effectiveness was evaluated using the IEEE 39-bus system algorithm.The results showed that the multi-model management strategy based on multi-moment feature clustering can effectively combine the two advantages of superior evaluation performance and streamlined model management by fully extracting system features.Moreover,this approach allows for more flexible adjustments to line topology changes.
基金supported by the National Key Research and Development Program of China(2023YFB3307801)the National Natural Science Foundation of China(62394343,62373155,62073142)+3 种基金Major Science and Technology Project of Xinjiang(No.2022A01006-4)the Programme of Introducing Talents of Discipline to Universities(the 111 Project)under Grant B17017the Fundamental Research Funds for the Central Universities,Science Foundation of China University of Petroleum,Beijing(No.2462024YJRC011)the Open Research Project of the State Key Laboratory of Industrial Control Technology,China(Grant No.ICT2024B70).
文摘The distillation process is an important chemical process,and the application of data-driven modelling approach has the potential to reduce model complexity compared to mechanistic modelling,thus improving the efficiency of process optimization or monitoring studies.However,the distillation process is highly nonlinear and has multiple uncertainty perturbation intervals,which brings challenges to accurate data-driven modelling of distillation processes.This paper proposes a systematic data-driven modelling framework to solve these problems.Firstly,data segment variance was introduced into the K-means algorithm to form K-means data interval(KMDI)clustering in order to cluster the data into perturbed and steady state intervals for steady-state data extraction.Secondly,maximal information coefficient(MIC)was employed to calculate the nonlinear correlation between variables for removing redundant features.Finally,extreme gradient boosting(XGBoost)was integrated as the basic learner into adaptive boosting(AdaBoost)with the error threshold(ET)set to improve weights update strategy to construct the new integrated learning algorithm,XGBoost-AdaBoost-ET.The superiority of the proposed framework is verified by applying this data-driven modelling framework to a real industrial process of propylene distillation.
基金financially supported by the vice chancellor for research and technology of Urmia University
文摘Numerous clustering algorithms are valuable in pattern recognition in forest vegetation,with new ones continually being proposed.While some are well-known,others are underutilized in vegetation science.This study compares the performance of practical iterative reallocation algorithms with model-based clustering algorithms.The data is from forest vegetation in Virginia(United States),the Hyrcanian Forest(Asia),and European beech forests.Practical iterative reallocation algorithms were applied as non-hierarchical methods and Finite Gaussian mixture modeling was used as a model-based clustering method.Due to limitations on dimensionality in model-based clustering,principal coordinates analysis was employed to reduce the dataset’s dimensions.A log transformation was applied to achieve a normal distribution for the pseudo-species data before calculating the Bray-Curtis dissimilarity.The findings indicate that the reallocation of misclassified objects based on silhouette width(OPTSIL)with Flexible-β(-0.25)had the highest mean among the tested clustering algorithms with Silhouette width 1(REMOS1)with Flexible-β(-0.25)second.However,model-based clustering performed poorly.Based on these results,it is recommended using OPTSIL with Flexible-β(-0.25)and REMOS1 with Flexible-β(-0.25)for forest vegetation classification instead of model-based clustering particularly for heterogeneous datasets common in forest vegetation community data.
文摘Cluster-basedmodels have numerous application scenarios in vehicular ad-hoc networks(VANETs)and can greatly help improve the communication performance of VANETs.However,the frequent movement of vehicles can often lead to changes in the network topology,thereby reducing cluster stability in urban scenarios.To address this issue,we propose a clustering model based on the density peak clustering(DPC)method and sparrow search algorithm(SSA),named SDPC.First,the model constructs a fitness function based on the parameters obtained from the DPC method and deploys the SSA for iterative optimization to select cluster heads(CHs).Then,the vehicles that have not been selected as CHs are assigned to appropriate clusters by comprehensively considering the distance parameter and link-reliability parameter.Finally,cluster maintenance strategies are considered to tackle the changes in the clusters’organizational structure.To verify the performance of the model,we conducted a simulation on a real-world scenario for multiple metrics related to clusters’stability.The results show that compared with the APROVE and the GAPC,SDPC showed clear performance advantages,indicating that SDPC can effectively ensure VANETs’cluster stability in urban scenarios.
基金supported by the CCF-NSFOCUS‘Kunpeng’Research Fund(CCF-NSFOCUS2024012).
文摘In recent years,with the rapid development of software systems,the continuous expansion of software scale and the increasing complexity of systems have led to the emergence of a growing number of software metrics.Defect prediction methods based on software metric elements highly rely on software metric data.However,redundant software metric data is not conducive to efficient defect prediction,posing severe challenges to current software defect prediction tasks.To address these issues,this paper focuses on the rational clustering of software metric data.Firstly,multiple software projects are evaluated to determine the preset number of clusters for software metrics,and various clustering methods are employed to cluster the metric elements.Subsequently,a co-occurrence matrix is designed to comprehensively quantify the number of times that metrics appear in the same category.Based on the comprehensive results,the software metric data are divided into two semantic views containing different metrics,thereby analyzing the semantic information behind the software metrics.On this basis,this paper also conducts an in-depth analysis of the impact of different semantic view of metrics on defect prediction results,as well as the performance of various classification models under these semantic views.Experiments show that the joint use of the two semantic views can significantly improve the performance of models in software defect prediction,providing a new understanding and approach at the semantic view level for defect prediction research based on software metrics.
基金supported by the National Natural Science Foundation of China(Grant No.12374441)。
文摘Bubbles within an elastic shell,which undergo ultrasound-driven oscillation to treat tumors and soft tissues,are frequently treated as viscoelastic media.Therefore,studying the dynamic behavior of bubbles wrapped in a viscoelastic medium while considering an elastic shell can provide theoretical support for ultrasound biotherapy.Bubbles are always in the form of clusters.Therefore,a model of spherical bubble clusters in a liquid cavity wrapped by an elastic shell was constructed,the coupled oscillation equations of bubbles were obtained by taking into account the dynamic effects of the elastic shell and the viscoelastic media outside the cavity,and the oscillation behaviors of the bubbles were analyzed.Acoustic waves at 1.5 MHz could cause bubbles with a radius of 1μm to resonate.Increasing the number of bubbles increased the suppressing effect of bubble oscillation caused by bubble interaction.The bubble cluster oscillation caused the elastic shell to oscillate and be stressed,and the stress trend was the inverse of the bubble oscillation trend with maximal tensile and compressive stresses.Bubbles with an equilibrium radius of 2μm exhibited the lowest inertial cavitation threshold,making inertial cavitation more likely under high-frequency acoustic excitation.The inertial cavitation threshold of bubbles was heavily influenced by the acoustic wave frequency,bubble number density,and bubble cluster radius.The nonspherical oscillation stability of bubbles was primarily affected by the driving acoustic pressure amplitude and frequency,bubble initial radius,bubble number density,and bubble cluster radius.The acoustic frequency and amplitude exhibited a synergistic effect,with a minimum unstable driving acoustic pressure threshold of approximately 0.13 MPa.The initial radius within the elastic shell affected the minimum unstable driving acoustic pressure threshold.
基金supported by the National Key Research and Development Program of China(Grant Nos.2021YFC3000705 and 2021YFC3000705-05)the National Natural Science Foundation of China(Grant No.42074049)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.2023471).
文摘We propose a robust earthquake clustering method:the Bayesian Gaussian mixture model with nearest-neighbor distance(BGMM-NND)algorithm.Unlike the conventional nearest neighbor distance method,the BGMM-NND algorithm eliminates the need for hyperparameter tuning or reliance on fixed thresholds,offering enhanced flexibility for clustering across varied seismic scales.By integrating cumulative probability and BGMM with principal component analysis(PCA),the BGMM-NND algorithm effectively distinguishes between background and triggered earthquakes while maintaining the magnitude component and resolving the issue of excessively large spatial cluster domains.We apply the BGMM-NND algorithm to the Sichuan–Yunnan seismic catalog from 1971 to 2024,revealing notable variations in earthquake frequency,triggering characteristics,and recurrence patterns across different fault zones.Distinct clustering and triggering behaviors are identified along different segments of the Longmenshan Fault.Multiple seismic modes,namely,the short-distance mode,the medium-distance mode,the repeating-like mode,the uniform background mode,and the Wenchuan mode,are uncovered.The algorithm's flexibility and robust performance in earthquake clustering makes it a valuable tool for exploring seismicity characteristics,offering new insights into earthquake clustering and the spatiotemporal patterns of seismic activity.
基金funded through Engineering and Physical Sciences Research Council(EPSRC)[grant numbers EP/W005131/1,EP/V042556/1].
文摘Recent work analysing magnesium hydrogenation using Reflecting Electron Energy Loss Spectroscopy(REELS)and Density Function Theory(DFT)has indicated interfacial polarisation and interstitial hydrogen clustering influence the reaction rate.The site availability model has been modified to include interstitial hydrogen clustering within the site availability factor and interface polarisation using interface treatment.The new model,SAM-CV-S,has demonstrated improved modelling of magnesium hydrogenation across wide operating conditions,such as temperatures from 330 to 400℃and pressures up to 40 bar.This wide applicability makes it a robust model that can be used to simulate bed performance in solid-state hydrogen stores.Thus,the site availability factor successfully combines interstitial hydrogen clustering with thermal resistance effects,which are known to strongly influence metal hydride reactor designs at scale.The next phase of the model is to incorporate a predictive hydrogen capacity method into the model.
基金State Grid Jiangsu Electric Power Co.,Ltd.Technology Project(J2023121).
文摘With the continuous expansion of the power system scale and the increasing complexity of operational mode,the interaction between transmission and distribution systems is becoming more and more significant,placing higher requirements on the accuracy and efficiency of the power system state estimation to address the challenge of balancing computational efficiency and estimation accuracy in traditional coupled transmission and distribution state estimation methods,this paper proposes a collaborative state estimation method based on distribution systems state clustering and load model parameter identification.To resolve the scalability issue of coupled transmission and distribution power systems,clustering is first carried out based on the distribution system states.As the data and models of the transmission system and distribution systems are not shared.For the transmission system,equating the power transmitted from the transmission system to the distribution system is the same as equating the distribution system.Further,the power transmitted from the transmission system to different types of distribution systems is equivalent to different polynomial equivalent load models.Then,a parameter identification method is proposed to obtain the parameters of the equivalent load model.Finally,a transmission and distribution collaborative state estimation model is constructed based on the equivalent load model.The results of the numerical analysis show that compared with the traditional master-slave splitting method,the proposed method significantly enhances computational efficiency while maintaining high estimation accuracy.
基金funded by the Office of the Vice-President for Research and Development of Cebu Technological University.
文摘This study demonstrates a novel integration of large language models,machine learning,and multicriteria decision-making to investigate self-moderation in small online communities,a topic under-explored compared to user behavior and platform-driven moderation on social media.The proposed methodological framework(1)utilizes large language models for social media post analysis and categorization,(2)employs k-means clustering for content characterization,and(3)incorporates the TODIM(Tomada de Decisão Interativa Multicritério)method to determine moderation strategies based on expert judgments.In general,the fully integrated framework leverages the strengths of these intelligent systems in a more systematic evaluation of large-scale decision problems.When applied in social media moderation,this approach promotes nuanced and context-sensitive self-moderation by taking into account factors such as cultural background and geographic location.The application of this framework is demonstrated within Facebook groups.Eight distinct content clusters encompassing safety,harassment,diversity,and misinformation are identified.Analysis revealed a preference for content removal across all clusters,suggesting a cautious approach towards potentially harmful content.However,the framework also highlights the use of other moderation actions,like account suspension,depending on the content category.These findings contribute to the growing body of research on self-moderation and offer valuable insights for creating safer and more inclusive online spaces within smaller communities.
文摘Resilience studies for water distribution systems(WDS)coupled with other interdependent infrastructure systems attract increasing attention from stakeholders and researchers.However,most existing large-scale WDS models are single infrastructure-based without consideration of other infrastructure systems.This is due to a lack of needed information on systems coupling,the structure of the simulator used,and the computation load involved.To address these gaps,this paper presents a synthetic modeling framework for a real-world WDS as coordinating with other infrastructure systems via a building-mediated clustering approach through consideration of physical distance and node capacity.First,the WDS network topology and operation parameters are inferred via bulk open-source information.A building-mediated clustering approach is designed to systematically derive the interdependence between the WDS and the power system similarly created as a case study.Second,a novel linearization method is developed in formulating the WDS model that can relieve computation load while maintaining accuracy.Finally,a disruption-recovery framework is developed to demonstrate the proposed methodology in modelling WDS resilience.The framework is applied to a neighborhood in Queenstown,Singapore,an area of 20.43 km^(2) and 96,000 population.The near-real-time simulations on the coupled system involving 308 nodes and 384 links showcase the effectiveness and application of the proposed synthetic modeling and formulation.
文摘Low visibility conditions,particularly those caused by fog,significantly affect road safety and reduce drivers’ability to see ahead clearly.The conventional approaches used to address this problem primarily rely on instrument-based and fixed-threshold-based theoretical frameworks,which face challenges in adaptability and demonstrate lower performance under varying environmental conditions.To overcome these challenges,we propose a real-time visibility estimation model that leverages roadside CCTV cameras to monitor and identify visibility levels under different weather conditions.The proposedmethod begins by identifying specific regions of interest(ROI)in the CCTVimages and focuses on extracting specific features such as the number of lines and contours detected within these regions.These features are then provided as an input to the proposed hierarchical clusteringmodel,which classifies them into different visibility levels without the need for predefined rules and threshold values.In the proposed approach,we used two different distance similaritymetrics,namely dynamic time warping(DTW)and Euclidean distance,alongside the proposed hierarchical clustering model and noted its performance in terms of numerous evaluation measures.The proposed model achieved an average accuracy of 97.81%,precision of 91.31%,recall of 91.25%,and F1-score of 91.27% using theDTWdistancemetric.We also conducted experiments for other deep learning(DL)-based models used in the literature and compared their performances with the proposed model.The experimental results demonstrate that the proposedmodel ismore adaptable and consistent compared to themethods used in the literature.The proposedmethod provides drivers real-time and accurate visibility information and enhances road safety during low visibility conditions.
文摘Under hydrothermal and solvothermal conditions,two novel cobalt-based complexes,{[Co_(2)(CIA)(OH)(1,4-dtb)]·3.2H_(2)O}n(HU23)and{[Co_(2)(CIA)(OH)(1,4-dib)]·3.5H2O·DMF}n(HU24),were successfully constructed by coordinatively assembling the semi-rigid multidentate ligand 5-(1-carboxyethoxy)isophthalic acid(H₃CIA)with the Nheterocyclic ligands 1,4-di(4H-1,2,4-triazol-4-yl)benzene(1,4-dtb)and 1,4-di(1H-imidazol-1-yl)benzene(1,4-dib),respectively,around Co^(2+)ions.Single-crystal X-ray diffraction analysis revealed that in both complexes HU23 and HU24,the CIA^(3-)anions adopt aκ^(7)-coordination mode,bridging six Co^(2+)ions via their five carboxylate oxygen atoms and one ether oxygen atom.This linkage forms tetranuclear[Co4(μ3-OH)2]^(6+)units.These Co-oxo cluster units were interconnected by CIA^(3-)anions to assemble into 2D kgd-type structures featuring a 3,6-connected topology.The 2D layers were further connected by 1,4-dtb and 1,4-dib,resulting in 3D pillar-layered frameworks for HU23 and HU24.Notably,despite the similar configurations of 1,4-dtb and 1,4-dib,differences in their coordination spatial orientations lead to topological divergence in the 3D frameworks of HU23 and HU24.Topological analysis indicates that the frameworks of HU23 and HU24 can be simplified into a 3,10-connected net(point symbol:(4^(10).6^(3).8^(2))(4^(3))_(2))and a 3,8-connected tfz-d net(point symbol:(4^(3))_(2)((4^(6).6^(18).8^(4)))),respectively.This structural differentiation confirms the precise regulatory role of ligands on the topology of metal-organic frameworks.Moreover,the ultraviolet-visible absorption spectra confirmed that HU23 and HU24 have strong absorption capabilities for ultraviolet and visible light.According to the Kubelka-Munk method,their bandwidths were 2.15 and 2.08 eV,respectively,which are consistent with those of typical semiconductor materials.Variable-temperature magnetic susceptibility measurements(2-300 K)revealed significant antiferromagnetic coupling in both complexes,with their effective magnetic moments decreasing markedly as the temperature lowered.CCDC:2457554,HU23;2457553,HU24.
