Cadmium is one of the important contaminative heavy metals. Due to continuous increase of discharge of Cadmium in industrial and agriculture production, cadmium contamination of soil is more and more serious day by da...Cadmium is one of the important contaminative heavy metals. Due to continuous increase of discharge of Cadmium in industrial and agriculture production, cadmium contamination of soil is more and more serious day by day, which seriously threatens ecological environment and human health. Treatment of cadmium becomes an urgent issue and research hot point. At present, remedy for cadmium pollution upon soil mainly are physical restoration, chemical restoration and biological restoration, also there are measurements by means of adding external source matter and selecting low-Cd-accumulation varieties so as to reduce cadmium harm upon agricultural products. This article introduces in detail the resource of cadmium in soil and the present condition of cadmium pollution in farmland and processing of domestic cadmium pollution research, processing stage of domestic and foreign research of restoration of cadmium polluted soil as well as various peculiarities of repair methods. Finally, the expectation of research is discussed.展开更多
To modify two-step experimental etch-and-rinse dentin adhesive with different concentrations of riboflavin and to study its effect on the bond strength,degree of conversion,along with resin infiltration within the dem...To modify two-step experimental etch-and-rinse dentin adhesive with different concentrations of riboflavin and to study its effect on the bond strength,degree of conversion,along with resin infiltration within the demineralized dentin substrate,an experimental adhesive-system was modified with different concentrations of riboflavin（mlm,0,1%,3%,5%and 10%）.Dentin surfaces were etched with 37%phosphoric acid,bonded with respective adhesives,restored with restorative composite-resin,and sectioned into resin-dentin slabs and beams to be stored for 24 h or 9 months in artificial saliva.Micro-tensile bond testing was performed with scanning electron microscopy to analyse the failure of debonded beams.The degree of conversion was evaluated with Fourier transform infrared spectroscopy（FTIR） at different time points along with micro-Raman spectroscopy analysis.Data was analyzed with one-way and two-way analysis of variance followed by Tukey＇s for pair-wise comparison.Modification with 1%and 3%riboflavin increased the micro-tensile bond strength compared to the control at 24 h and 9-month storage with no significant differences in degree of conversion（P〈0.05）.The most predominant failure mode was the mixed fracture among all specimens except 10%riboflavin-modified adhesive specimens where cohesive failure was predominant.Raman analysis revealed that 1%and 3%riboflavin adhesives specimens showed relatively higher resin infiltration.The incorporation of riboflavin in the experimental two-step etch-and-rinse adhesive at 3%（mlm） improved the immediate bond strengths and bond durability after 9-month storage in artificial saliva without adversely affecting the degree of conversion of the adhesive monomers and resin infiltration.展开更多
基金Supported by the National Natural Science Foundation of China(20477032)China Agriculture Research System(Nycytx-25)
文摘Cadmium is one of the important contaminative heavy metals. Due to continuous increase of discharge of Cadmium in industrial and agriculture production, cadmium contamination of soil is more and more serious day by day, which seriously threatens ecological environment and human health. Treatment of cadmium becomes an urgent issue and research hot point. At present, remedy for cadmium pollution upon soil mainly are physical restoration, chemical restoration and biological restoration, also there are measurements by means of adding external source matter and selecting low-Cd-accumulation varieties so as to reduce cadmium harm upon agricultural products. This article introduces in detail the resource of cadmium in soil and the present condition of cadmium pollution in farmland and processing of domestic cadmium pollution research, processing stage of domestic and foreign research of restoration of cadmium polluted soil as well as various peculiarities of repair methods. Finally, the expectation of research is discussed.
基金supported,in part,by the Ministry of Education,Singapore,NUS/ARF grants R221000039133 and R221000052112
文摘To modify two-step experimental etch-and-rinse dentin adhesive with different concentrations of riboflavin and to study its effect on the bond strength,degree of conversion,along with resin infiltration within the demineralized dentin substrate,an experimental adhesive-system was modified with different concentrations of riboflavin（mlm,0,1%,3%,5%and 10%）.Dentin surfaces were etched with 37%phosphoric acid,bonded with respective adhesives,restored with restorative composite-resin,and sectioned into resin-dentin slabs and beams to be stored for 24 h or 9 months in artificial saliva.Micro-tensile bond testing was performed with scanning electron microscopy to analyse the failure of debonded beams.The degree of conversion was evaluated with Fourier transform infrared spectroscopy（FTIR） at different time points along with micro-Raman spectroscopy analysis.Data was analyzed with one-way and two-way analysis of variance followed by Tukey＇s for pair-wise comparison.Modification with 1%and 3%riboflavin increased the micro-tensile bond strength compared to the control at 24 h and 9-month storage with no significant differences in degree of conversion（P〈0.05）.The most predominant failure mode was the mixed fracture among all specimens except 10%riboflavin-modified adhesive specimens where cohesive failure was predominant.Raman analysis revealed that 1%and 3%riboflavin adhesives specimens showed relatively higher resin infiltration.The incorporation of riboflavin in the experimental two-step etch-and-rinse adhesive at 3%（mlm） improved the immediate bond strengths and bond durability after 9-month storage in artificial saliva without adversely affecting the degree of conversion of the adhesive monomers and resin infiltration.
