Mechanochromic polyolefins represent a novel class of functionalized polyolefins,which still remains significant challenges.Pd(II)-catalyzed coordination-insertion copolymerization is a feasible method for achieving t...Mechanochromic polyolefins represent a novel class of functionalized polyolefins,which still remains significant challenges.Pd(II)-catalyzed coordination-insertion copolymerization is a feasible method for achieving this kind of polymers,yet with linear microstructures.Ringopening metathesis polymerization(ROMP)offers another promising avenue for affording functionalized polyolefins.This method exhibits high polar group tolerance and the ability to precisely regulate polymer branches.In this study,we report the method for producing mechanochromic branched polyethylenes via ROMP.By employing the terpolymerization of a well-designed monomer containing the mechanochromic group,NB-ABF,with cyclooctene(COE)and long-chain 5-hexylcyclooctene(COE-C6),following by hydrogenation process,we synthesized a range of functionalized branched polyethylenes characterized by varied branching density and polar monomer incorporation.These polymers bear a structural resemblance to functionalized ethylene-octene copolymers.After crosslinking,mechanochromophores are generated,and mechanochromism is achieved in uniaxial tensile testing.A comprehensive assessment reveals that both the incorporation of polar monomers and variations in branching density significantly influence their mechanical properties.Notably,upon stretching,these materials display pronounced visible color change,confirming the successful development of mechanochromic branched polyethylenes.展开更多
A study was conducted at Msekera Regional Agricultural Research Station in eastern Zambia to （1） describe canopy branching properties of Acacia angustissima, Gliricidia sepium and Leucaena collinsii in short rotatio...A study was conducted at Msekera Regional Agricultural Research Station in eastern Zambia to （1） describe canopy branching properties of Acacia angustissima, Gliricidia sepium and Leucaena collinsii in short rotation forests, （2） test the existence of self similarity from repeated iteration of a structural unit in tree canopies, （3） examined intra-specifie relationships between functional branching characteristics, and （4） determine whether allometric equations for relating aboveground tree biomass to fractal properties could accurately predict aboveground biomass. Measurements of basal diameter （Din0） at 10em aboveground and total height （H）, and aboveground biomass of 27 trees were taken, but only nine trees representative of variability of the stand and the three species were processed for functional branching analyses （FBA） of the shoot systems. For each species, fractal properties of three trees, includ- ing fractal dimension （Dfract）, bifurcation ratios （p） and proportionality ratios （q） of branching points were assessed. The slope of the linear re- gression ofp on proximal diameter was not significantly different （P 〈 0.01） from zero and hence the assumption that p is independent of scale, a pre-requisite for use of fraetal branching rules to describe a fraetal tree canopy, was fulfilled at branching orders with link diameters 〉1.5 cm. The proportionality ration q for branching patterns of all tree species was constant at all scales. The proportion of q values 〉0.9 （fq） was 0.8 for all species. Mean fraetal dimension （Df^ct） values （1.5-1.7） for all species showed that branching patterns had an increasing magnitude of intricacy. Since Dfraet values were 〉1.5, branching patterns within species were self similar. Basal diameter （D10）, proximal diameter and Dfraet described most of variations in aboveground biomass, suggesting that allometric equa- tions for relating aboveground tree biomass to fractal properties could accurately predict aboveground biomass. Thus, assessed Acacia, Gliri- cidia and Leucaena trees were fractals and their branching propertiescould be used to describe variability in size and aboveground biomass.展开更多
An improved single-π equivalent circuit model for on-chip inductors in the GaAs process is presented in this paper. Considering high order parasites, the model is established by comprising an improved skin effect bra...An improved single-π equivalent circuit model for on-chip inductors in the GaAs process is presented in this paper. Considering high order parasites, the model is established by comprising an improved skin effect branch and a substrate lateral coupling branch. The parameter extraction is based on an improved characteristic function approach and vector fitting method. The model has better simulation than the previous work over the measured data of 2.5r and 4.5r on-chip inductors in the GaAs process.展开更多
It is proved that the occupation time of the catalytic super-Brownian motion is absolutely continuous for d = 1, and the occupation density field is jointly continuous and jointly Holder continuous.
基金supported by the National Natural Science Foundation of China(No.U23B6011)the Jilin Provincial Science and Technology Department Program(No.20230101347JC)。
文摘Mechanochromic polyolefins represent a novel class of functionalized polyolefins,which still remains significant challenges.Pd(II)-catalyzed coordination-insertion copolymerization is a feasible method for achieving this kind of polymers,yet with linear microstructures.Ringopening metathesis polymerization(ROMP)offers another promising avenue for affording functionalized polyolefins.This method exhibits high polar group tolerance and the ability to precisely regulate polymer branches.In this study,we report the method for producing mechanochromic branched polyethylenes via ROMP.By employing the terpolymerization of a well-designed monomer containing the mechanochromic group,NB-ABF,with cyclooctene(COE)and long-chain 5-hexylcyclooctene(COE-C6),following by hydrogenation process,we synthesized a range of functionalized branched polyethylenes characterized by varied branching density and polar monomer incorporation.These polymers bear a structural resemblance to functionalized ethylene-octene copolymers.After crosslinking,mechanochromophores are generated,and mechanochromism is achieved in uniaxial tensile testing.A comprehensive assessment reveals that both the incorporation of polar monomers and variations in branching density significantly influence their mechanical properties.Notably,upon stretching,these materials display pronounced visible color change,confirming the successful development of mechanochromic branched polyethylenes.
基金funded by the Gates Cambridge Trust at Cambridge University
文摘A study was conducted at Msekera Regional Agricultural Research Station in eastern Zambia to （1） describe canopy branching properties of Acacia angustissima, Gliricidia sepium and Leucaena collinsii in short rotation forests, （2） test the existence of self similarity from repeated iteration of a structural unit in tree canopies, （3） examined intra-specifie relationships between functional branching characteristics, and （4） determine whether allometric equations for relating aboveground tree biomass to fractal properties could accurately predict aboveground biomass. Measurements of basal diameter （Din0） at 10em aboveground and total height （H）, and aboveground biomass of 27 trees were taken, but only nine trees representative of variability of the stand and the three species were processed for functional branching analyses （FBA） of the shoot systems. For each species, fractal properties of three trees, includ- ing fractal dimension （Dfract）, bifurcation ratios （p） and proportionality ratios （q） of branching points were assessed. The slope of the linear re- gression ofp on proximal diameter was not significantly different （P 〈 0.01） from zero and hence the assumption that p is independent of scale, a pre-requisite for use of fraetal branching rules to describe a fraetal tree canopy, was fulfilled at branching orders with link diameters 〉1.5 cm. The proportionality ration q for branching patterns of all tree species was constant at all scales. The proportion of q values 〉0.9 （fq） was 0.8 for all species. Mean fraetal dimension （Df^ct） values （1.5-1.7） for all species showed that branching patterns had an increasing magnitude of intricacy. Since Dfraet values were 〉1.5, branching patterns within species were self similar. Basal diameter （D10）, proximal diameter and Dfraet described most of variations in aboveground biomass, suggesting that allometric equa- tions for relating aboveground tree biomass to fractal properties could accurately predict aboveground biomass. Thus, assessed Acacia, Gliri- cidia and Leucaena trees were fractals and their branching propertiescould be used to describe variability in size and aboveground biomass.
基金Project supported by the National Natural Science Foundation of China(No.61674036)
文摘An improved single-π equivalent circuit model for on-chip inductors in the GaAs process is presented in this paper. Considering high order parasites, the model is established by comprising an improved skin effect branch and a substrate lateral coupling branch. The parameter extraction is based on an improved characteristic function approach and vector fitting method. The model has better simulation than the previous work over the measured data of 2.5r and 4.5r on-chip inductors in the GaAs process.
文摘It is proved that the occupation time of the catalytic super-Brownian motion is absolutely continuous for d = 1, and the occupation density field is jointly continuous and jointly Holder continuous.
