Single and binary adsorption behaviors of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents,i.e.NDA-101 and NDA-99 were investigated.The Freundlich model can successfully describe all...Single and binary adsorption behaviors of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents,i.e.NDA-101 and NDA-99 were investigated.The Freundlich model can successfully describe all the adsorption isotherms tested,which indicates a favorable and exothermic adsorption process.The adsorption of salicylic acid relies on π-π interaction,while the electrostatic interaction further influences the adsorption of 5-sulfosalicylic acid onto NDA-99.The adsorptive capacity of salicylic acid on NDA-99 decreases but increases on NDA-101 with 5-sulfosalicylic acid as the background component in a binary solute system.The amount of 5-sulfosalicylic acid adsorbed was decreased with the increase in initial concentration of salicylic acid on both adsorbents.The competition for the adsorption sites is considered to be predominant in the solid-to-liquid interaction process.The adsorption selectivity of salicylic acid onto NDA-101 is higher than onto NDA-99 by more than an order of magnitude.Thus,combination technique involving NDA-101 followed by NDA-99 can be effectively applied to separate and recover salicylic acid and 5-sulfosalicylic acid from wastewater.展开更多
Although extensive research has been conducted on CO_(2)-enhanced coalbed methane(CO_(2)-ECBM)recovery,most prior studies have focused on the impact of gas adsorption-induced swelling on coal permeability under equili...Although extensive research has been conducted on CO_(2)-enhanced coalbed methane(CO_(2)-ECBM)recovery,most prior studies have focused on the impact of gas adsorption-induced swelling on coal permeability under equilibrium conditions.This paper presents a comprehensive thermo-hydro-mechanical-chemical(THMC)model that integrates thermal expansion and heat conduction(T),gas diffusion in the matrix and gas-water two-phase flow in the fractures(H),matrix and fracture deformation due to poroelasticity(M),and non-equilibrium binary gas adsorption-induced matrix swelling(C)during CO_(2)-ECBM recovery.The accuracy of the proposed model was verified through experimental data,and the model was simulated using finite element method(FEM)software.Simulation results indicate that the permeability evolution can be categorized into three stages.Ignoring the impact of water on gas adsorption properties would lead to an overestimation of the influence of adsorption-induced swelling,while disregarding non-equilibrium adsorption underestimates it.An examination of five designed cases identified critical factors influencing permeability.Parametric analysis shows that increases in the injection pressure,the injection temperature,and the initial permeability promote the competitive adsorption-induced swelling between CH_(4)and CO_(2),leading to increased CH_(4)production and CO_(2)storage.Conversely,an increase in initial water saturation reduces available gas flow space,decreasing both CH_(4)production and CO_(2)storage.Higher irreducible water saturation favors early gas recovery,while lower irreducible water saturation is more advantageous for long-term recovery.展开更多
A study of nonlinear competitive adsorption equilibria of proteins is of fundamental importance in understanding the behavior of preparative chromatographic separation.This work describes the nonlinear binary protein ...A study of nonlinear competitive adsorption equilibria of proteins is of fundamental importance in understanding the behavior of preparative chromatographic separation.This work describes the nonlinear binary protein adsorption equilibria on ion exchangers by the statistical thermodynamic(ST)model.The single-component and binary protein adsorption isotherms of bovine hemoglobin(Hb)and bovine serum albumin(BSA)on SP Sepharose FF were determined by batch adsorption experiments in 0.05 mol/L sodium acetate buffer at three pH values(4.5,5.0 and 5.5)and three NaCl concentrations(0.05,0.10 and 0.15 mol/L)at pH 5.0.The ST model was found to depict the effects of pH and ionic strength on the single-component equilibria well,with model parameters depending on the pH and ionic strength.Moreover,the ST model gave acceptable fitting to the binary adsorption data with the fitted single-component model parameters,leading to the estimation of the binary ST model parameter.The effects of pH and ionic strength on the model parameters are reasonably interpreted by the electrostatic and thermodynamic theories.Results demonstrate the availability of the ST model for describing nonlinear competitive protein adsorption equilibria in the presence of two proteins.展开更多
基金This work was supported by the National Natural Science Foundation of China(No.20274017)
文摘Single and binary adsorption behaviors of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents,i.e.NDA-101 and NDA-99 were investigated.The Freundlich model can successfully describe all the adsorption isotherms tested,which indicates a favorable and exothermic adsorption process.The adsorption of salicylic acid relies on π-π interaction,while the electrostatic interaction further influences the adsorption of 5-sulfosalicylic acid onto NDA-99.The adsorptive capacity of salicylic acid on NDA-99 decreases but increases on NDA-101 with 5-sulfosalicylic acid as the background component in a binary solute system.The amount of 5-sulfosalicylic acid adsorbed was decreased with the increase in initial concentration of salicylic acid on both adsorbents.The competition for the adsorption sites is considered to be predominant in the solid-to-liquid interaction process.The adsorption selectivity of salicylic acid onto NDA-101 is higher than onto NDA-99 by more than an order of magnitude.Thus,combination technique involving NDA-101 followed by NDA-99 can be effectively applied to separate and recover salicylic acid and 5-sulfosalicylic acid from wastewater.
基金the support from the National Natural Science Foundation of China(No.52079077)Natural Science Foundation of Hubei Provincial(2025AFB358).
文摘Although extensive research has been conducted on CO_(2)-enhanced coalbed methane(CO_(2)-ECBM)recovery,most prior studies have focused on the impact of gas adsorption-induced swelling on coal permeability under equilibrium conditions.This paper presents a comprehensive thermo-hydro-mechanical-chemical(THMC)model that integrates thermal expansion and heat conduction(T),gas diffusion in the matrix and gas-water two-phase flow in the fractures(H),matrix and fracture deformation due to poroelasticity(M),and non-equilibrium binary gas adsorption-induced matrix swelling(C)during CO_(2)-ECBM recovery.The accuracy of the proposed model was verified through experimental data,and the model was simulated using finite element method(FEM)software.Simulation results indicate that the permeability evolution can be categorized into three stages.Ignoring the impact of water on gas adsorption properties would lead to an overestimation of the influence of adsorption-induced swelling,while disregarding non-equilibrium adsorption underestimates it.An examination of five designed cases identified critical factors influencing permeability.Parametric analysis shows that increases in the injection pressure,the injection temperature,and the initial permeability promote the competitive adsorption-induced swelling between CH_(4)and CO_(2),leading to increased CH_(4)production and CO_(2)storage.Conversely,an increase in initial water saturation reduces available gas flow space,decreasing both CH_(4)production and CO_(2)storage.Higher irreducible water saturation favors early gas recovery,while lower irreducible water saturation is more advantageous for long-term recovery.
基金supported by the National Natural Science Foundation of China(Grant No.20636040)the Specialized Research Fund for the Doctoral Program of Higher Education(Grant No.20050056001).
文摘A study of nonlinear competitive adsorption equilibria of proteins is of fundamental importance in understanding the behavior of preparative chromatographic separation.This work describes the nonlinear binary protein adsorption equilibria on ion exchangers by the statistical thermodynamic(ST)model.The single-component and binary protein adsorption isotherms of bovine hemoglobin(Hb)and bovine serum albumin(BSA)on SP Sepharose FF were determined by batch adsorption experiments in 0.05 mol/L sodium acetate buffer at three pH values(4.5,5.0 and 5.5)and three NaCl concentrations(0.05,0.10 and 0.15 mol/L)at pH 5.0.The ST model was found to depict the effects of pH and ionic strength on the single-component equilibria well,with model parameters depending on the pH and ionic strength.Moreover,the ST model gave acceptable fitting to the binary adsorption data with the fitted single-component model parameters,leading to the estimation of the binary ST model parameter.The effects of pH and ionic strength on the model parameters are reasonably interpreted by the electrostatic and thermodynamic theories.Results demonstrate the availability of the ST model for describing nonlinear competitive protein adsorption equilibria in the presence of two proteins.
