Recent geological study and survey on the scale of 1: 50000 in northern Guangxi have made some advancements: meta-basic-ultrabasic rocks which occured as bedding injection sheets in the Sanrnenjie formation of the Pro...Recent geological study and survey on the scale of 1: 50000 in northern Guangxi have made some advancements: meta-basic-ultrabasic rocks which occured as bedding injection sheets in the Sanrnenjie formation of the Proterozoic Danzhou group and caused contact metamorphism or hydrothermal alteration in adjacent wallrocks, were originated in extensional environment. Basic rocks belong to deep-sea tholeiite. TLe meta-basic -ultrabasic rocks sufferred intense deformation partitioning, resulting in lenticular network which was composed of mylonite zones in highly de formed field and lensoids in less- or non-deformed field. This structural pattern was explained as "melange" or "non-rooted cool intrusion " by previous workers. The deformation partitioning was mainly pure shearing in the early stage plus simple shearing in the later stage. This evolution was closely related to progressive deformation of the Guangxi orogeny.展开更多
Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the st...Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the stress development within the backfill material,leaving the influence of stope backfilling on stress distribution in surrounding rock mass and ground stability largely unexplored.Therefore,this paper presents numerical models in FLAC3D to investigate,for the first time,the time-dependent stress redistribution around a vertical backfilled stope and its implications on ground stability,considering the creep of surrounding rock mass.Using the Soft Soil constitutive model,the compressibility of backfill under large pressure was captured.It is found that the creep deformation of rock mass exercises compression on backfill and results in a less void ratio and increased modulus for fill material.The compacted backfill conversely influenced the stress distribution and ground stability of rock mass which was a combined effect of wall creep and compressibility of backfill.With the increase of time or/and creep deformation,the minimum principal stress in the rocks surrounding the backfilled stope increased towards the pre-mining stress state,while the deviatoric stress reduces leading to an increased factor of safety and improved ground stability.This improvement effect of backfill on ground stability increased with the increase of mine depth and stope height,while it is also more pronounced for the narrow stope,the backfill with a smaller compression index,and the soft rocks with a smaller viscosity coefficient.Furthermore,the results emphasize the importance of minimizing empty time and backfilling extracted stope as soon as possible for ground control.Reduction of filling gap height enhances the local stability around the roof of stope.展开更多
The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Pa...The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.展开更多
Energy is an important resource that supports the development of human society,and energy security is even more relevant to the strength of a country.In order to ensure energy security,countries around the world are t...Energy is an important resource that supports the development of human society,and energy security is even more relevant to the strength of a country.In order to ensure energy security,countries around the world are taking measures to carry out energy transformation and construct new energy systems.As an important part of the new energy system,energy storage technology is highly valued by all countries.Among many large-scale energy storage technologies,salt cavern compressed air energy storage(CAES)technology stands out for its safety and economy,which is recognized and valued by scholars from various countries.For the construction of salt cavern CAES power station,it is very important to ensure the stability of salt cavern.Therefore,scholars have investigated the mechanical properties of salt rocks and the stability of salt caverns for CAES.This paper synthesizes the findings of current research on the creep and fatigue properties of salt rock,highlighting three key points:The factors influencing the creep and fatigue characteristics of salt rock include its composition,stress levels,and temperature.Notably,impurities and surrounding pressure tend to inhibit the deformation of salt rock,whereas elevated temperature and differential stress facilitate its deformation;The mechanisms governing creep and fatigue damage in salt rock are primarily associated with dislocation movement and microcracking;Most existing constitutive models for creep and fatigue are based on viscoelastic-plasticity theory,with fewer models derived from micro-mechanical perspectives.Additionally,this paper reviews studies on the stability of salt cavern CAES reservoirs utilizing numerical simulation methods and offers insights into future research directions concerning the creep and fatigue properties of salt rocks.展开更多
Forced imbibition,the invasion of a wetting fluid into porous rocks,plays an important role in the effective exploitation of hydrocarbon resources and the geological sequestration of carbon dioxide.However,the interfa...Forced imbibition,the invasion of a wetting fluid into porous rocks,plays an important role in the effective exploitation of hydrocarbon resources and the geological sequestration of carbon dioxide.However,the interface dynamics influenced by complex topology commonly leads to non-wetting fluid trapping.Particularly,the underlying mechanisms under viscously unfavorable conditions remain unclear.This study employs a direct numerical simulation method to simulate forced imbibition through the reconstructed digital rocks of sandstone.The interface dynamics and fluid–fluid interactions are investigated through transient simulations,while the pore topology metrics are introduced to analyze the impact on steady-state residual fluid distribution obtained by a pseudo-transient scheme.The results show that the cooperative pore-filling process promoted by corner flow is dominant at low capillary numbers.This leads to unstable inlet pressure,mass flow,and interface curvature,which correspond to complicated interface dynamics and higher residual fluid saturation.During forced imbibition,the interface curvature gradually increases,with the pore-filling mechanisms involving the cooperation of main terminal meniscus movement and arc menisci filling.Complex topology with small diameter pores may result in the destabilization of interface curvature.The residual fluid saturation is negatively correlated with porosity and pore throat size,and positively correlated with tortuosity and aspect ratio.A large mean coordination number characterizing global connectivity promotes imbibition.However,high connectivity characterized by the standardized Euler number corresponding to small pores is associated with a high probability of non-wetting fluid trapping.展开更多
Significant exploration progress has been made in ultra-deep clastic rocks in the Kuqa Depression,Tarim Basin,over recent years.A new round of comprehensive geological research has formed four new understandings:(1)Es...Significant exploration progress has been made in ultra-deep clastic rocks in the Kuqa Depression,Tarim Basin,over recent years.A new round of comprehensive geological research has formed four new understandings:(1)Establish structural model consisting of multi-detachment composite,multi-stage structural superposition and multi-layer deformation.Multi-stage structural traps are overlapped vertically,and a series of structural traps are discovered in underlying ultra-deep layers.(2)Five sets of high-quality large-scale source rocks of three types of organic phases are developed in the Triassic and Jurassic systems,and forming a good combination of source-reservoir-cap rocks in ultra-deep layers with three sets of large-scale regional reservoir and cap rocks.(3)The formation of large oil and gas fields is controlled by four factors which are source,reservoir,cap rocks and fault.Based on the spatial configuration relationship of these four factors,a new three-dimensional reservoir formation model for ultra-deep clastic rocks in the Kuqa Depression has been established.(4)The next key exploration fields for ultra-deep clastic rocks in the Kuqa Depression include conventional and unconventional oil and gas.The conventional oil and gas fields include the deep multi-layer oil-gas accumulation zone in Kelasu,tight sandstone gas of Jurassic Ahe Formation in the northern structural zone,multi-target layer lithological oil and gas reservoirs in Zhongqiu–Dina structural zone,lithologic-stratigraphic and buried hill composite reservoirs in south slope and other favorable areas.Unconventional oil and gas fields include deep coal rock gas of Jurassic Kezilenuer and Yangxia formations,Triassic Tariqike Formation and Middle-Lower Jurassic and Upper Triassic continental shale gas.The achievements have important reference significance for enriching the theory of ultra-deep clastic rock oil and gas exploration and guiding the future oil and gas exploration deployment.展开更多
Based on the finite-discrete element method,a three-dimensional numerical model for axial impact rock breaking was established and validated.A computational method for energy conversion during impact rock breaking was...Based on the finite-discrete element method,a three-dimensional numerical model for axial impact rock breaking was established and validated.A computational method for energy conversion during impact rock breaking was proposed,and the effects of conical tooth forward rake angle,rock temperature,and impact velocity on rock breaking characteristics and energy transfer laws were analyzed.The results show that during single impact rock breaking with conical tooth bits,merely 7.52%to 12.51%of the energy is utilized for rock breaking,while a significant 57.26%to 78.10%is dissipated as frictional loss.An insufficient forward rake angle increases tooth penetration depth and frictional loss,whereas an excessive forward rake angle reduces penetration capability,causing bit rebound and greater energy absorption by the drill rod.Thus,an optimal forward rake angle exists.Regarding environmental factors,high temperatures significantly enhance impact-induced rock breaking.Thermal damage from high temperatures reduces rock strength and inhibits its energy absorption.Finally,higher impact velocities intensify rock damage,yet excessively high velocities increase frictional loss and reduce the proportion of energy absorbed by the rock,thereby failing to substantially improve rock breaking efficiency.An optimal impact velocity exists.展开更多
The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significan...The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significance to accurately characterize the actual microstructures and their influence on stress and damage evolution inside the rocks. In this study, an image-based fast Fourier transform (FFT) method is developed for reconstructing the actual rock microstructures by combining it with the digital image processing (DIP) technique. A series of experimental investigations were conducted to acquire information regarding the actual microstructure and the mechanical properties. Based on these experimental evidences, the processed microstructure information, in conjunction with the proposed micromechanical model, is incorporated into the numerical calculation. The proposed image-based FFT method was firstly validated through uniaxial compression tests. Subsequently, it was employed to predict and analyze the influence of microstructure on macroscopic mechanical behaviors, local stress distribution and the internal crack evolution process in brittle rocks. The distribution of feldspar is considerably more heterogeneous and scattered than that of quartz, which results in a greater propensity for the formation of cracks in feldspar. It is observed that initial cracks and new cracks, including intragranular and boundary ones, ultimately coalesce and connect as the primary through cracks, which are predominantly distributed along the boundary of the feldspar. This phenomenon is also predicted by the proposed numerical method. The results indicate that the proposed numerical method provides an effective approach for analyzing, understanding and predicting the nonlinear mechanical and cracking behaviors of brittle rocks by taking into account the actual microstructure characteristics.展开更多
Layered rocks(LR)exhibit inherent anisotropic stiffness and strength induced by oriented rough weakness planes,along with stress induced anisotropy and friction related plastic deformation occurs during loading.Furthe...Layered rocks(LR)exhibit inherent anisotropic stiffness and strength induced by oriented rough weakness planes,along with stress induced anisotropy and friction related plastic deformation occurs during loading.Furthermore,microcracks located in intact rock matrix(IRM)of LR are also critically important for friction and damage dissipation processes.In this paper,we first present a novel multiscale friction-damage(MFD)model using a two-step Mori-Tanaka homogenization scheme,with the aim of describing the multiscale friction-damage mechanics in LR.Physically,the initiation and propagation of flaws at different scales(i.e.microcracks and weakness planes)induced damage,and the plastic deformation is closely associated with frictional sliding along these flaws.In the thermodynamics framework,the macroscopic stress-strain relations,the local driving forces respectively conjuncted with flaws propagation and plastic deformation are derived.An analytical macroscopic strength criterion is subsequently deduced,which takes into account the variation of inclination angle and confining pressure.Notably,the failure mechanisms of IRM shearing and weakness planes sliding are inherent included in the criterion.As an original contribution,a new multisurface semi-implicit return mapping algorithm(MSRM)is developed to integrate the proposed MFD model.The robustness of MSRM algorithm is assessed by numerical tests with different loading steps sizes and convergence conditions.Finally,the effectiveness of the MFD model is confirmed using data from experiments under conventional triaxial compression,all main features of mechanical behaviors of LR are well captured by the proposed model,including initial anisotropy,stress-induced anisotropy and strain hardening/softening.展开更多
The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu...The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu(LH)granitic rocks in the western NQTB.LA-ICP-MS U-Pb dating of zircons from LH granitic rocks yields emplacement ages of 253±4 Ma and 264±4 Ma,indicating a two-stage emplacement process.Geochemi-cal analyses show that the LH granitic rocks have low ACNK values and are enriched in LILEs(Rb,Th,Ba)and depleted in HFSEs(Sr,Nd,and Ta).The samples are enriched in LREEs(LREE/HREE=1.5-7.3).Values of(La/Yb)N range between 0.9 and 6.5,and all samples show negative Eu anomalies(δEu=0.2-0.6),with typical characteristics of island arc magmatism.The LH granitic rocks haveεHf(t)values of-3.7 to+8.0 and yield a TCDM age of 1.51-0.78 Ga.The data suggest that the LH granitic rocks were derived from partial melting of Proterozoic crust-related mafic to intermediate rocks with significant crust-mantle interac-tions.The results,combined with regional magmatic informa-tion,indicate that the Late Permian-early Triassic magmatism in western NQTB were controlled by subduction rollback-retraction of South Kunlun Oceanic plate under the Kun-lun-Qaidam Block.展开更多
The origin of magnesium and iron isotope variations in mafic–ultramafic rocks has long been debated.In particular,a substantial lack of understanding exists regarding how the variation in the Mg and Fe isotopic compo...The origin of magnesium and iron isotope variations in mafic–ultramafic rocks has long been debated.In particular,a substantial lack of understanding exists regarding how the variation in the Mg and Fe isotopic compositions of arc magmas relates to fractional crystallization.Here,we report new Mg and Fe isotopic analyses of mafic–ultramafic rocks formed by co-genetic magmatic evolution in the Eastern Kunlun orogenic belt.The ultramafic and gabbro samples present mantle-like Mg isotopic compositions,with δ^(26)Mg values ranging from−0.279‰to−0.266‰for wehrlite,−0.266‰to−0.243‰for clinopyroxenite,and−0.284‰to−0.253‰for gabbro.In contrast,the δ^(26)Mg values of the hornblende gabbro samples are significantly higher(−0.195‰to−0.176‰).These rocks have similar heavy Fe isotopic compositions,withδ56Fe values ranging from 0.020‰to 0.157‰.The high δ^(26)Mg values observed in the hornblende gabbro are interpreted as indicating a maximum of 6%olivine fractionation,whereas the slightly high δ^(26)Mg values in the clinopyroxenite are ascribed to the accumulation of titanomagnetite.The Fe isotopic signatures of these rocks are inherited from magmatic sources.A comparison of the studied rocks with other mafic-ultramafic rocks implies that partial melting of mantle wedges induced by metasomatism of marine sediment-derived melts could generate“dry”arc magmatism,which would necessitate a more comprehensive and detailed analysis in further investigations.展开更多
This paper is a synthetic use of carbon isotope composition,Rock-Eval data,organic petrology,element composition of kerogen,major and trace elements,and biomarker characteristic of the Permian Pingdiquan(P_(2)p)source...This paper is a synthetic use of carbon isotope composition,Rock-Eval data,organic petrology,element composition of kerogen,major and trace elements,and biomarker characteristic of the Permian Pingdiquan(P_(2)p)source rocks in the Wucaiwan sag,Junggar Basin,China as proxies(1)for evaluations of hydrocarbon potential,organic matter(OM)composition and thermal maturity of the OM in the source rocks,(2)for reconstruction of paleodepositional environment,and(3)for analysis of controlling factor of organic carbon accumulation.The P_(2)p Formation developed good-excellent source rocks with thermal maturity of OM ranging from low-mature to mature stages.The OM was mainly composed of C_(3)terrestrial higher plants and aquatic organisms including aerobic bacteria,green sulfur bacteria,saltwater and fresh algae,Sphagnum moss species,submerged macrophytes,Nymphaea,and aquatic pollen taxa.The proportion of terrestrial higher plants decreased and that of aquatic organisms increased from margin to center of the sag.The benthic water within reducing environment and brackishwater column were superposed by periodic/occasional fresh-water influx(e.g.,rainfall and river drain),which led to fresh-water conditions and well oxygenating in the water column during overturn process.The whole study area developed lacustrine source rocks without seawater intrusion.During periodic/occasional fresh-water influx periods with plenty of terrestrial plant inputs,the paleoredox conditions of the sag were relatively oxic in the shallow fresh-water which experienced strong oxidation and decomposition of OM,therefore were not conducive for the OM preservation.However,the overall middle primary productivity made up for this deficiency,and was the main controlling factor on the organic carbon accumulation.A suitable supply from terrestrial inputs can promote biotic paleoproductivity,and a relatively high sedimentation rate can reduce oxidation and decomposition times of OM.On the contrary,during the intervals of the fresh-water influxes,relatively reducing conditions are a more important controlling factor on the OM accumulation in the case that the decrease of the terrestrial biotic source.展开更多
Alkaline igneous rocks represent one of the most economically important resources of radioactive minerals and rare metals.New field observations and petrographic studies are integrated with whole-rock geochemical anal...Alkaline igneous rocks represent one of the most economically important resources of radioactive minerals and rare metals.New field observations and petrographic studies are integrated with whole-rock geochemical analyses and Gamma ray spectroscopy data of alkaline rocks associated with the Amreit complex.The fieldwork was achieved by the collection of more than forty samples from alkaline granites and alkaline syenites.The youngest rocks cropping out in the study area are the cogenetic alkaline rocks,ranging from alkaline granite to alkaline syenite.These alkaline rocks are composed essentially of K-feldspar,alkali amphiboles(arfvedsonite),and sodic pyroxene,with accessories such as zircon,apatite,and ilmenite.Mineral characterization of the highly radioactive zones in both alkaline granite and alkaline syenite displays enrichment in monazite,thorite,zircon,ferro-columbite,xenotime,and allanite minerals.Geochemical analyses indicate that the Amreit rocks are alkaline with peralkaline affinity and have high concentrations of total alkalis(K_(2)O+Na_(2)O),large ion lithophile elements(LILEs;Ba and Rb),high field strength elements(HFSEs;Y,Zr and Nb),rare earth elements(REEs)and significantly depleted in K,Sr,P,Ti,and Eu,typically of post-collision A-type granites.Typically,the Amreit alkaline igneous rocks are classified as within plate granites and display A2 subtype characteristics.The fractionation of K-feldspars played a distinctive role during the magmatic evolution of these alkaline rocks.The geochemical characteristics indicate that the studied alkaline igneous rocks which were originated by fractional crystallization of alkaline magmas were responsible for the enrichment of the REE and rare metals in the residual melt.The high radioactivity is essentially related to accessory minerals,such as zircon,allanite,and monazite.The alkaline granite is the most U-and Thrich rock,where radioactivity level reaches up to 14.7 ppm(181.55 Bq/kg)e U,40.6 ppm(164.84 Bq/kg)e Th,whereas in alkaline syenite radioactivity level is 8.5 ppm(104.96 Bq/kg)e U,30.2 ppm(122.61 Bq/kg)e Th.These observations suppose that these alkaline rocks may be important targets for REEs and radioactive mineral exploration.展开更多
The Ning-Wu Basin is an important part of the Middle-Lower Yangtze River Metallogenic Belt in eastern China.It contains well-preserved Mesozoic volcanic sequences that document significant geodynamic evolution.However...The Ning-Wu Basin is an important part of the Middle-Lower Yangtze River Metallogenic Belt in eastern China.It contains well-preserved Mesozoic volcanic sequences that document significant geodynamic evolution.However,uncertainties surrounding the ages of eruptions and the temporal relationships between the four main volcanic cycles—the Longwangshan,Dawangshan,Gushan and Niangniangshan formations—have hindered our understanding of magmatic pulsation and its connection to iron mineralisation.Here,high-precision LA-ICP-MS zircon U-Pb dating of four fresh volcanic samples(one per formation)reveals weighted mean ages of 132.3±1.0 Ma(Longwangshan;MSWD=1.3),130.4±1.6 Ma(Dawangshan;MSWD=1.3),128.1±1.9 Ma(Gushan;MSWD=2.0)and 127.2±1.1 Ma(Niangniangshan;MSWD=0.23).These dates constrain volcanic activity to the Early Cretaceous Valanginian-Hauterivian interval and show a systematic trend of increasingly younger ages spanning~8 Ma(133-125 Ma).This magmatism can be subdivided into three phases:initiation(133-132 Ma),peak activity(132-130 Ma)and cessation(128-125 Ma).The episodic volcanism correlates with the accelerating rollback of the Pacific subduction zone,which drives crustal melting and asthenospheric upwelling.Notably,these cycles supplied the thermal energy,fluids and iron-rich melts that were essential for the formation of porphyritic iron deposits in the basin.By establishing a highresolution chronostratigraphic framework,this study sheds light on the spatiotemporal evolution of the Ning-Wu Basin,elucidating the coupling between crust-mantle dynamics,volcanic cyclicity and ore-forming processes across eastern China’s metallogenic belt.展开更多
The North China Craton(NCC)experienced significant lithospheric thinning of over 100 km during the Mesozoic,accompanied by extensive magmatic activity and extensional tectonics.However,the timing and mechanism of this...The North China Craton(NCC)experienced significant lithospheric thinning of over 100 km during the Mesozoic,accompanied by extensive magmatic activity and extensional tectonics.However,the timing and mechanism of this thinning remain the subjects of debate.This study presents zircon U-Pb ages,Hf isotopic data and whole-rock elemental and Sr-Nd isotopic compositions of the Guanshui monzonites and diorites in the eastern NCC.Zircon U-Pb dating reveals that both rock types formed at ca.130 Ma.The monzonites,characterized by high Mg^(#)(50.9-57.9),low Nb/U ratios(2.53-3.89)and depleted isotopic compositions,suggest derivation from asthenospheric mantle modified by slab-derived fluids.The diorites,distinguished by low SiO_(2)(49.5-50.8),high Mg^(#)(66.7-68.5)and an EM2-type enriched mantle isotopic signature,point to a lithospheric mantle source modified by subducted sediment melts.The coexistence of monzonites and diorites suggests a transition in magma source from lithospheric to asthenospheric mantle,implying that lithospheric thinning may have commenced around 130 Ma.The destruction of the NCC was likely driven by localized,small-scale drip-style detachment processes,rather than wholesale lithospheric removal.展开更多
The pore structures of the Majiagou Formation in the Ordos Basin are complex,featuring micro-and nano-scale intra-crystalline and inter-crystalline pores that significantly impact hydrocarbon storage and flow.Precisel...The pore structures of the Majiagou Formation in the Ordos Basin are complex,featuring micro-and nano-scale intra-crystalline and inter-crystalline pores that significantly impact hydrocarbon storage and flow.Precisely characterizing the rock internal structures is crucial for reservoir exploration and development.However,it is difficult to accurately characterize the pore structure of rock using traditional imaging methods to meet the simulation requirements.In this context,this study focuses on high-resolution 3D digital core reconstruction using the SliceGAN model.Specifically,the Modular Automated Processing System(MAPS)image and Quanti-tative Evaluation of Minerals by Scanning Electron Microscopy(QEMSCAN)image were combined to divide MAPS into three categories:pore,dolomite,and calcite.Then,through the SliceGAN algorithm,the 3D digital core was reconstructed.To evaluate the reconstruction,the auto-correlation function,two-point probability function,porosity,mineral content,and specific surface area were employed.The results show that the SliceGAN can effectively capture the micro-features in the core,and the internal structure of the generated core was consistent with that of the original core.This study provided a new sight for reconstructing cores with complex pore structures and strong heterogeneity and innovatively supports tight carbonate reservoir characterization and evaluation.展开更多
As one of the micro-blocks dispersed in the South China Sea(SCS),the Xisha Islands are covered by thick Cenozoic sedimentary layers,making it challenging to obtain magmatic rocks.Well CK-2 is a kilometer-scale scienti...As one of the micro-blocks dispersed in the South China Sea(SCS),the Xisha Islands are covered by thick Cenozoic sedimentary layers,making it challenging to obtain magmatic rocks.Well CK-2 is a kilometer-scale scientific drilling project on the Xisha Islands in the northwestern SCS.It penetrates the thick reef limestone and reaches basaltic pyroclastic rocks.This study presents the whole-rock and olivine compositions of the basaltic volcaniclastic rocks from Well CK-2.These rocks exhibited ocean island basalt signatures characterized by the enrichment of light rare earth elements and high-field-strength elements.Compared with partial melting products derived from mantle peridotite,whole-rock compositions showed elevated Fe/Mn and Zn/Fe mass ratios.Additionally,olivines were characterized by a lower Ca content,higher Ni content,elevated Fe/Mn mass ratios,and moderate Mn/Zn mass ratios compared to those crystallized from peridotitic melts.The compositions of both the whole-rock and olivine phenocrysts indicate the presence of pyroxenite in the mantle source,which likely formed through the reaction of recycled oceanic crust with the surrounding mantle peridotite.Using the olivine-liquid Mg-Fe exchange thermometer,this study derived mantle potential temperatures(T_(p))ranging from 1502℃to 1756℃,which is consistent with those of plume-related ocean island basalts.Furthermore,the basaltic volcaniclastic rocks exhibit low H_(2)O contents(0.01%–1.47%),which were significantly lower than those found in the primary magmas of Large Igneous Provinces.These results suggest that the basaltic volcaniclastic rocks on the Xisha Islands originated from a volatile-poor mantle plume source.展开更多
Argillaceous rocks are considered ideal host geomaterials for deep geological disposal of radioactive waste due to their low permeability,notable sorption capacity,low diffusion coefficient,limited natural fracturing,...Argillaceous rocks are considered ideal host geomaterials for deep geological disposal of radioactive waste due to their low permeability,notable sorption capacity,low diffusion coefficient,limited natural fracturing,and capacity for self-sealing.In line with this objective,substantial efforts have been made in the literature over the past decades to model their behavior numerically.Yet,accurately modeling the hydromechanical behavior of argillaceous rocks remains a significant challenge in geomechanics,highlighting the need for further research.Despite the wide variety of geomaterials in this class,common behavioral features are observed,such as anisotropy,structural degradation,strain localization,creep,heterogeneity,and self-sealing.This study summarizes these common features observed in laboratory and field settings and reviews the developed approaches for modeling each behavioral aspect.The goal is to establish a comprehensive framework for the practical modeling of these geomaterials,specifically aimed at applications in the geological disposal of radioactive waste.展开更多
In this paper,we present a novel approach to study the electrical properties of intact rock by combining impedance and vector network analyzer measurements in the frequency range from 5 Hz to 3 GHz.For the firsttime,t...In this paper,we present a novel approach to study the electrical properties of intact rock by combining impedance and vector network analyzer measurements in the frequency range from 5 Hz to 3 GHz.For the firsttime,this study enables electrical characterization of the exact same rock sample over nine orders of magnitude in frequency range,utilizing a coaxial cell apparatus with specificallyprepared rock samples.Three types of rocks(basalt,sandstone and granite)with low to intermediate porosity(12.24%,16.9%and 7.49%,respectively)were characterized at varying saturation levels.The relaxation behavior of the samples was quantifiedusing an advanced phenomenological model incorporating both the dielectric constant and electrical conductivity in the form of Debye and Cole-Cole representations.Across the frequency range,three distinct relaxation processes were identified:a high-frequency water process and two interfacial processes related to interactions between the aqueous pore solution and mineral particles(membrane relaxation and Maxwell-Wagner effects).Additionally,an apparent direct current conductivity was observed.This comprehensive broadband analysis represents a further step toward the in situ characterization of rocks using electromagnetic fieldmeasurement methods and demonstrates advancements in both methodology and understanding of rock properties compared to existing studies.展开更多
The publisher regrets that the article type for this publication was incorrectly labeled as a Research Article.The correct designation should be Review Article.
文摘Recent geological study and survey on the scale of 1: 50000 in northern Guangxi have made some advancements: meta-basic-ultrabasic rocks which occured as bedding injection sheets in the Sanrnenjie formation of the Proterozoic Danzhou group and caused contact metamorphism or hydrothermal alteration in adjacent wallrocks, were originated in extensional environment. Basic rocks belong to deep-sea tholeiite. TLe meta-basic -ultrabasic rocks sufferred intense deformation partitioning, resulting in lenticular network which was composed of mylonite zones in highly de formed field and lensoids in less- or non-deformed field. This structural pattern was explained as "melange" or "non-rooted cool intrusion " by previous workers. The deformation partitioning was mainly pure shearing in the early stage plus simple shearing in the later stage. This evolution was closely related to progressive deformation of the Guangxi orogeny.
基金the funding support from the National Natural Science Foundation of China(Grant Nos.52304101 and 52004206)the China Postdoctoral Science Foundation(Grant No.2023MD734215)。
文摘Backfill is often employed in mining operations for ground support,with its positive impact on ground stability acknowledged in many underground mines.However,existing studies have predominantly focused only on the stress development within the backfill material,leaving the influence of stope backfilling on stress distribution in surrounding rock mass and ground stability largely unexplored.Therefore,this paper presents numerical models in FLAC3D to investigate,for the first time,the time-dependent stress redistribution around a vertical backfilled stope and its implications on ground stability,considering the creep of surrounding rock mass.Using the Soft Soil constitutive model,the compressibility of backfill under large pressure was captured.It is found that the creep deformation of rock mass exercises compression on backfill and results in a less void ratio and increased modulus for fill material.The compacted backfill conversely influenced the stress distribution and ground stability of rock mass which was a combined effect of wall creep and compressibility of backfill.With the increase of time or/and creep deformation,the minimum principal stress in the rocks surrounding the backfilled stope increased towards the pre-mining stress state,while the deviatoric stress reduces leading to an increased factor of safety and improved ground stability.This improvement effect of backfill on ground stability increased with the increase of mine depth and stope height,while it is also more pronounced for the narrow stope,the backfill with a smaller compression index,and the soft rocks with a smaller viscosity coefficient.Furthermore,the results emphasize the importance of minimizing empty time and backfilling extracted stope as soon as possible for ground control.Reduction of filling gap height enhances the local stability around the roof of stope.
基金supported by the CNPC Science and Technology Major Project of the Fourteenth Five-Year Plan(2021DJ0101)the National Natural Science Foundation of China(U19B600302,41872148)。
文摘The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.
基金supported by the Natural Science Fund of China(No.51834003,52274073,52022014).
文摘Energy is an important resource that supports the development of human society,and energy security is even more relevant to the strength of a country.In order to ensure energy security,countries around the world are taking measures to carry out energy transformation and construct new energy systems.As an important part of the new energy system,energy storage technology is highly valued by all countries.Among many large-scale energy storage technologies,salt cavern compressed air energy storage(CAES)technology stands out for its safety and economy,which is recognized and valued by scholars from various countries.For the construction of salt cavern CAES power station,it is very important to ensure the stability of salt cavern.Therefore,scholars have investigated the mechanical properties of salt rocks and the stability of salt caverns for CAES.This paper synthesizes the findings of current research on the creep and fatigue properties of salt rock,highlighting three key points:The factors influencing the creep and fatigue characteristics of salt rock include its composition,stress levels,and temperature.Notably,impurities and surrounding pressure tend to inhibit the deformation of salt rock,whereas elevated temperature and differential stress facilitate its deformation;The mechanisms governing creep and fatigue damage in salt rock are primarily associated with dislocation movement and microcracking;Most existing constitutive models for creep and fatigue are based on viscoelastic-plasticity theory,with fewer models derived from micro-mechanical perspectives.Additionally,this paper reviews studies on the stability of salt cavern CAES reservoirs utilizing numerical simulation methods and offers insights into future research directions concerning the creep and fatigue properties of salt rocks.
基金supported by the National Natural Science Foundation of China(Grant Nos.42172159 and 42302143)the Postdoctora Fellowship Program of the China Postdoctoral Science Foundation(CPSF)(Grant No.GZB20230864).
文摘Forced imbibition,the invasion of a wetting fluid into porous rocks,plays an important role in the effective exploitation of hydrocarbon resources and the geological sequestration of carbon dioxide.However,the interface dynamics influenced by complex topology commonly leads to non-wetting fluid trapping.Particularly,the underlying mechanisms under viscously unfavorable conditions remain unclear.This study employs a direct numerical simulation method to simulate forced imbibition through the reconstructed digital rocks of sandstone.The interface dynamics and fluid–fluid interactions are investigated through transient simulations,while the pore topology metrics are introduced to analyze the impact on steady-state residual fluid distribution obtained by a pseudo-transient scheme.The results show that the cooperative pore-filling process promoted by corner flow is dominant at low capillary numbers.This leads to unstable inlet pressure,mass flow,and interface curvature,which correspond to complicated interface dynamics and higher residual fluid saturation.During forced imbibition,the interface curvature gradually increases,with the pore-filling mechanisms involving the cooperation of main terminal meniscus movement and arc menisci filling.Complex topology with small diameter pores may result in the destabilization of interface curvature.The residual fluid saturation is negatively correlated with porosity and pore throat size,and positively correlated with tortuosity and aspect ratio.A large mean coordination number characterizing global connectivity promotes imbibition.However,high connectivity characterized by the standardized Euler number corresponding to small pores is associated with a high probability of non-wetting fluid trapping.
基金Supported by the National Natural Science Foundation of China(U22B6002)PetroChina Science and Technology Project(2023ZZ14).
文摘Significant exploration progress has been made in ultra-deep clastic rocks in the Kuqa Depression,Tarim Basin,over recent years.A new round of comprehensive geological research has formed four new understandings:(1)Establish structural model consisting of multi-detachment composite,multi-stage structural superposition and multi-layer deformation.Multi-stage structural traps are overlapped vertically,and a series of structural traps are discovered in underlying ultra-deep layers.(2)Five sets of high-quality large-scale source rocks of three types of organic phases are developed in the Triassic and Jurassic systems,and forming a good combination of source-reservoir-cap rocks in ultra-deep layers with three sets of large-scale regional reservoir and cap rocks.(3)The formation of large oil and gas fields is controlled by four factors which are source,reservoir,cap rocks and fault.Based on the spatial configuration relationship of these four factors,a new three-dimensional reservoir formation model for ultra-deep clastic rocks in the Kuqa Depression has been established.(4)The next key exploration fields for ultra-deep clastic rocks in the Kuqa Depression include conventional and unconventional oil and gas.The conventional oil and gas fields include the deep multi-layer oil-gas accumulation zone in Kelasu,tight sandstone gas of Jurassic Ahe Formation in the northern structural zone,multi-target layer lithological oil and gas reservoirs in Zhongqiu–Dina structural zone,lithologic-stratigraphic and buried hill composite reservoirs in south slope and other favorable areas.Unconventional oil and gas fields include deep coal rock gas of Jurassic Kezilenuer and Yangxia formations,Triassic Tariqike Formation and Middle-Lower Jurassic and Upper Triassic continental shale gas.The achievements have important reference significance for enriching the theory of ultra-deep clastic rock oil and gas exploration and guiding the future oil and gas exploration deployment.
基金Supported by Major Instrument Project of National Natural Science Foundation of China(52327803)Major Project of National Natural Science Foundation of China(52192622).
文摘Based on the finite-discrete element method,a three-dimensional numerical model for axial impact rock breaking was established and validated.A computational method for energy conversion during impact rock breaking was proposed,and the effects of conical tooth forward rake angle,rock temperature,and impact velocity on rock breaking characteristics and energy transfer laws were analyzed.The results show that during single impact rock breaking with conical tooth bits,merely 7.52%to 12.51%of the energy is utilized for rock breaking,while a significant 57.26%to 78.10%is dissipated as frictional loss.An insufficient forward rake angle increases tooth penetration depth and frictional loss,whereas an excessive forward rake angle reduces penetration capability,causing bit rebound and greater energy absorption by the drill rod.Thus,an optimal forward rake angle exists.Regarding environmental factors,high temperatures significantly enhance impact-induced rock breaking.Thermal damage from high temperatures reduces rock strength and inhibits its energy absorption.Finally,higher impact velocities intensify rock damage,yet excessively high velocities increase frictional loss and reduce the proportion of energy absorbed by the rock,thereby failing to substantially improve rock breaking efficiency.An optimal impact velocity exists.
基金supported by the National Natural Science Foundation of China(Grant No.11802332)the China Scholarship Council(Grant No.202206435003)the Fundamental Research Funds for the Central Universities(Grant No.2024ZKPYLJ03).
文摘The internal microstructures of rock materials, including mineral heterogeneity and intrinsic microdefects, exert a significant influence on their nonlinear mechanical and cracking behaviors. It is of great significance to accurately characterize the actual microstructures and their influence on stress and damage evolution inside the rocks. In this study, an image-based fast Fourier transform (FFT) method is developed for reconstructing the actual rock microstructures by combining it with the digital image processing (DIP) technique. A series of experimental investigations were conducted to acquire information regarding the actual microstructure and the mechanical properties. Based on these experimental evidences, the processed microstructure information, in conjunction with the proposed micromechanical model, is incorporated into the numerical calculation. The proposed image-based FFT method was firstly validated through uniaxial compression tests. Subsequently, it was employed to predict and analyze the influence of microstructure on macroscopic mechanical behaviors, local stress distribution and the internal crack evolution process in brittle rocks. The distribution of feldspar is considerably more heterogeneous and scattered than that of quartz, which results in a greater propensity for the formation of cracks in feldspar. It is observed that initial cracks and new cracks, including intragranular and boundary ones, ultimately coalesce and connect as the primary through cracks, which are predominantly distributed along the boundary of the feldspar. This phenomenon is also predicted by the proposed numerical method. The results indicate that the proposed numerical method provides an effective approach for analyzing, understanding and predicting the nonlinear mechanical and cracking behaviors of brittle rocks by taking into account the actual microstructure characteristics.
基金jointly supported by Science and Technology Projects in Guangzhou(Grant No.SL2023A04J01079)Zhejiang ProvincialWater Conservancy Science and Technology Plan Project(Grant No.RC2405)Thematic Five of the Second Scientific Expedition of Qinghai-Tibet Plateau(Grant No.2019QZKK0905).
文摘Layered rocks(LR)exhibit inherent anisotropic stiffness and strength induced by oriented rough weakness planes,along with stress induced anisotropy and friction related plastic deformation occurs during loading.Furthermore,microcracks located in intact rock matrix(IRM)of LR are also critically important for friction and damage dissipation processes.In this paper,we first present a novel multiscale friction-damage(MFD)model using a two-step Mori-Tanaka homogenization scheme,with the aim of describing the multiscale friction-damage mechanics in LR.Physically,the initiation and propagation of flaws at different scales(i.e.microcracks and weakness planes)induced damage,and the plastic deformation is closely associated with frictional sliding along these flaws.In the thermodynamics framework,the macroscopic stress-strain relations,the local driving forces respectively conjuncted with flaws propagation and plastic deformation are derived.An analytical macroscopic strength criterion is subsequently deduced,which takes into account the variation of inclination angle and confining pressure.Notably,the failure mechanisms of IRM shearing and weakness planes sliding are inherent included in the criterion.As an original contribution,a new multisurface semi-implicit return mapping algorithm(MSRM)is developed to integrate the proposed MFD model.The robustness of MSRM algorithm is assessed by numerical tests with different loading steps sizes and convergence conditions.Finally,the effectiveness of the MFD model is confirmed using data from experiments under conventional triaxial compression,all main features of mechanical behaviors of LR are well captured by the proposed model,including initial anisotropy,stress-induced anisotropy and strain hardening/softening.
基金supported by the National Natural Science Foundation of China(No.41702204)the China Geology Survey(grant number DD20189614)the Basic Science Founda-tion of the Institute of Geomechanics(grant DZLXJK202004).
文摘The late Palaeozoic tectonic magmatism in the north-ern Qaidam tectonic belt(NQTB)related to the Palaeo-Tethys Ocean has become a critical issue.We performed a detailed geochronological and geochemical study of Lenghu(LH)granitic rocks in the western NQTB.LA-ICP-MS U-Pb dating of zircons from LH granitic rocks yields emplacement ages of 253±4 Ma and 264±4 Ma,indicating a two-stage emplacement process.Geochemi-cal analyses show that the LH granitic rocks have low ACNK values and are enriched in LILEs(Rb,Th,Ba)and depleted in HFSEs(Sr,Nd,and Ta).The samples are enriched in LREEs(LREE/HREE=1.5-7.3).Values of(La/Yb)N range between 0.9 and 6.5,and all samples show negative Eu anomalies(δEu=0.2-0.6),with typical characteristics of island arc magmatism.The LH granitic rocks haveεHf(t)values of-3.7 to+8.0 and yield a TCDM age of 1.51-0.78 Ga.The data suggest that the LH granitic rocks were derived from partial melting of Proterozoic crust-related mafic to intermediate rocks with significant crust-mantle interac-tions.The results,combined with regional magmatic informa-tion,indicate that the Late Permian-early Triassic magmatism in western NQTB were controlled by subduction rollback-retraction of South Kunlun Oceanic plate under the Kun-lun-Qaidam Block.
基金This research was financially co-supported by the National Natural Science Foundation of China(Grant Nos.42121002 and 91755207).
文摘The origin of magnesium and iron isotope variations in mafic–ultramafic rocks has long been debated.In particular,a substantial lack of understanding exists regarding how the variation in the Mg and Fe isotopic compositions of arc magmas relates to fractional crystallization.Here,we report new Mg and Fe isotopic analyses of mafic–ultramafic rocks formed by co-genetic magmatic evolution in the Eastern Kunlun orogenic belt.The ultramafic and gabbro samples present mantle-like Mg isotopic compositions,with δ^(26)Mg values ranging from−0.279‰to−0.266‰for wehrlite,−0.266‰to−0.243‰for clinopyroxenite,and−0.284‰to−0.253‰for gabbro.In contrast,the δ^(26)Mg values of the hornblende gabbro samples are significantly higher(−0.195‰to−0.176‰).These rocks have similar heavy Fe isotopic compositions,withδ56Fe values ranging from 0.020‰to 0.157‰.The high δ^(26)Mg values observed in the hornblende gabbro are interpreted as indicating a maximum of 6%olivine fractionation,whereas the slightly high δ^(26)Mg values in the clinopyroxenite are ascribed to the accumulation of titanomagnetite.The Fe isotopic signatures of these rocks are inherited from magmatic sources.A comparison of the studied rocks with other mafic-ultramafic rocks implies that partial melting of mantle wedges induced by metasomatism of marine sediment-derived melts could generate“dry”arc magmatism,which would necessitate a more comprehensive and detailed analysis in further investigations.
基金financially supported by the National Natural Science Foundation of China(NSFC)(No.42202154)the Science Foundation of China University of Petroleum,Beijing(No.ZX20220074)。
文摘This paper is a synthetic use of carbon isotope composition,Rock-Eval data,organic petrology,element composition of kerogen,major and trace elements,and biomarker characteristic of the Permian Pingdiquan(P_(2)p)source rocks in the Wucaiwan sag,Junggar Basin,China as proxies(1)for evaluations of hydrocarbon potential,organic matter(OM)composition and thermal maturity of the OM in the source rocks,(2)for reconstruction of paleodepositional environment,and(3)for analysis of controlling factor of organic carbon accumulation.The P_(2)p Formation developed good-excellent source rocks with thermal maturity of OM ranging from low-mature to mature stages.The OM was mainly composed of C_(3)terrestrial higher plants and aquatic organisms including aerobic bacteria,green sulfur bacteria,saltwater and fresh algae,Sphagnum moss species,submerged macrophytes,Nymphaea,and aquatic pollen taxa.The proportion of terrestrial higher plants decreased and that of aquatic organisms increased from margin to center of the sag.The benthic water within reducing environment and brackishwater column were superposed by periodic/occasional fresh-water influx(e.g.,rainfall and river drain),which led to fresh-water conditions and well oxygenating in the water column during overturn process.The whole study area developed lacustrine source rocks without seawater intrusion.During periodic/occasional fresh-water influx periods with plenty of terrestrial plant inputs,the paleoredox conditions of the sag were relatively oxic in the shallow fresh-water which experienced strong oxidation and decomposition of OM,therefore were not conducive for the OM preservation.However,the overall middle primary productivity made up for this deficiency,and was the main controlling factor on the organic carbon accumulation.A suitable supply from terrestrial inputs can promote biotic paleoproductivity,and a relatively high sedimentation rate can reduce oxidation and decomposition times of OM.On the contrary,during the intervals of the fresh-water influxes,relatively reducing conditions are a more important controlling factor on the OM accumulation in the case that the decrease of the terrestrial biotic source.
文摘Alkaline igneous rocks represent one of the most economically important resources of radioactive minerals and rare metals.New field observations and petrographic studies are integrated with whole-rock geochemical analyses and Gamma ray spectroscopy data of alkaline rocks associated with the Amreit complex.The fieldwork was achieved by the collection of more than forty samples from alkaline granites and alkaline syenites.The youngest rocks cropping out in the study area are the cogenetic alkaline rocks,ranging from alkaline granite to alkaline syenite.These alkaline rocks are composed essentially of K-feldspar,alkali amphiboles(arfvedsonite),and sodic pyroxene,with accessories such as zircon,apatite,and ilmenite.Mineral characterization of the highly radioactive zones in both alkaline granite and alkaline syenite displays enrichment in monazite,thorite,zircon,ferro-columbite,xenotime,and allanite minerals.Geochemical analyses indicate that the Amreit rocks are alkaline with peralkaline affinity and have high concentrations of total alkalis(K_(2)O+Na_(2)O),large ion lithophile elements(LILEs;Ba and Rb),high field strength elements(HFSEs;Y,Zr and Nb),rare earth elements(REEs)and significantly depleted in K,Sr,P,Ti,and Eu,typically of post-collision A-type granites.Typically,the Amreit alkaline igneous rocks are classified as within plate granites and display A2 subtype characteristics.The fractionation of K-feldspars played a distinctive role during the magmatic evolution of these alkaline rocks.The geochemical characteristics indicate that the studied alkaline igneous rocks which were originated by fractional crystallization of alkaline magmas were responsible for the enrichment of the REE and rare metals in the residual melt.The high radioactivity is essentially related to accessory minerals,such as zircon,allanite,and monazite.The alkaline granite is the most U-and Thrich rock,where radioactivity level reaches up to 14.7 ppm(181.55 Bq/kg)e U,40.6 ppm(164.84 Bq/kg)e Th,whereas in alkaline syenite radioactivity level is 8.5 ppm(104.96 Bq/kg)e U,30.2 ppm(122.61 Bq/kg)e Th.These observations suppose that these alkaline rocks may be important targets for REEs and radioactive mineral exploration.
基金supported by The Special Funds for Natural Resource Development in Jiangsu Province(2200113-35)The Central Financial Geological Survey Project of the China Geological Survey(DD20230800702).
文摘The Ning-Wu Basin is an important part of the Middle-Lower Yangtze River Metallogenic Belt in eastern China.It contains well-preserved Mesozoic volcanic sequences that document significant geodynamic evolution.However,uncertainties surrounding the ages of eruptions and the temporal relationships between the four main volcanic cycles—the Longwangshan,Dawangshan,Gushan and Niangniangshan formations—have hindered our understanding of magmatic pulsation and its connection to iron mineralisation.Here,high-precision LA-ICP-MS zircon U-Pb dating of four fresh volcanic samples(one per formation)reveals weighted mean ages of 132.3±1.0 Ma(Longwangshan;MSWD=1.3),130.4±1.6 Ma(Dawangshan;MSWD=1.3),128.1±1.9 Ma(Gushan;MSWD=2.0)and 127.2±1.1 Ma(Niangniangshan;MSWD=0.23).These dates constrain volcanic activity to the Early Cretaceous Valanginian-Hauterivian interval and show a systematic trend of increasingly younger ages spanning~8 Ma(133-125 Ma).This magmatism can be subdivided into three phases:initiation(133-132 Ma),peak activity(132-130 Ma)and cessation(128-125 Ma).The episodic volcanism correlates with the accelerating rollback of the Pacific subduction zone,which drives crustal melting and asthenospheric upwelling.Notably,these cycles supplied the thermal energy,fluids and iron-rich melts that were essential for the formation of porphyritic iron deposits in the basin.By establishing a highresolution chronostratigraphic framework,this study sheds light on the spatiotemporal evolution of the Ning-Wu Basin,elucidating the coupling between crust-mantle dynamics,volcanic cyclicity and ore-forming processes across eastern China’s metallogenic belt.
基金supported by the Jiangsu Innovation and Entrepreneurship Project(JSSCBS20211225).
文摘The North China Craton(NCC)experienced significant lithospheric thinning of over 100 km during the Mesozoic,accompanied by extensive magmatic activity and extensional tectonics.However,the timing and mechanism of this thinning remain the subjects of debate.This study presents zircon U-Pb ages,Hf isotopic data and whole-rock elemental and Sr-Nd isotopic compositions of the Guanshui monzonites and diorites in the eastern NCC.Zircon U-Pb dating reveals that both rock types formed at ca.130 Ma.The monzonites,characterized by high Mg^(#)(50.9-57.9),low Nb/U ratios(2.53-3.89)and depleted isotopic compositions,suggest derivation from asthenospheric mantle modified by slab-derived fluids.The diorites,distinguished by low SiO_(2)(49.5-50.8),high Mg^(#)(66.7-68.5)and an EM2-type enriched mantle isotopic signature,point to a lithospheric mantle source modified by subducted sediment melts.The coexistence of monzonites and diorites suggests a transition in magma source from lithospheric to asthenospheric mantle,implying that lithospheric thinning may have commenced around 130 Ma.The destruction of the NCC was likely driven by localized,small-scale drip-style detachment processes,rather than wholesale lithospheric removal.
基金financially supported by the open fund of Key Lab-oratory of Exploration Technologies for Oil and Gas Resources(Yangtze University),Ministry of Education,NO PI2023-03the open foundation of the National Engineering Laboratory for Exploration and Develop-ment of Low-Permeability Oil&Gas Fields and the National Natural Science Foundation of China(No.42474159).
文摘The pore structures of the Majiagou Formation in the Ordos Basin are complex,featuring micro-and nano-scale intra-crystalline and inter-crystalline pores that significantly impact hydrocarbon storage and flow.Precisely characterizing the rock internal structures is crucial for reservoir exploration and development.However,it is difficult to accurately characterize the pore structure of rock using traditional imaging methods to meet the simulation requirements.In this context,this study focuses on high-resolution 3D digital core reconstruction using the SliceGAN model.Specifically,the Modular Automated Processing System(MAPS)image and Quanti-tative Evaluation of Minerals by Scanning Electron Microscopy(QEMSCAN)image were combined to divide MAPS into three categories:pore,dolomite,and calcite.Then,through the SliceGAN algorithm,the 3D digital core was reconstructed.To evaluate the reconstruction,the auto-correlation function,two-point probability function,porosity,mineral content,and specific surface area were employed.The results show that the SliceGAN can effectively capture the micro-features in the core,and the internal structure of the generated core was consistent with that of the original core.This study provided a new sight for reconstructing cores with complex pore structures and strong heterogeneity and innovatively supports tight carbonate reservoir characterization and evaluation.
基金The National Natural Science Foundation of China under contract No.42030502the Guangxi Scientific Projects under contract Nos.AD17129063,AA17204074,and 2025GXNSFAA069324the NSFC project under contract No.42166003。
文摘As one of the micro-blocks dispersed in the South China Sea(SCS),the Xisha Islands are covered by thick Cenozoic sedimentary layers,making it challenging to obtain magmatic rocks.Well CK-2 is a kilometer-scale scientific drilling project on the Xisha Islands in the northwestern SCS.It penetrates the thick reef limestone and reaches basaltic pyroclastic rocks.This study presents the whole-rock and olivine compositions of the basaltic volcaniclastic rocks from Well CK-2.These rocks exhibited ocean island basalt signatures characterized by the enrichment of light rare earth elements and high-field-strength elements.Compared with partial melting products derived from mantle peridotite,whole-rock compositions showed elevated Fe/Mn and Zn/Fe mass ratios.Additionally,olivines were characterized by a lower Ca content,higher Ni content,elevated Fe/Mn mass ratios,and moderate Mn/Zn mass ratios compared to those crystallized from peridotitic melts.The compositions of both the whole-rock and olivine phenocrysts indicate the presence of pyroxenite in the mantle source,which likely formed through the reaction of recycled oceanic crust with the surrounding mantle peridotite.Using the olivine-liquid Mg-Fe exchange thermometer,this study derived mantle potential temperatures(T_(p))ranging from 1502℃to 1756℃,which is consistent with those of plume-related ocean island basalts.Furthermore,the basaltic volcaniclastic rocks exhibit low H_(2)O contents(0.01%–1.47%),which were significantly lower than those found in the primary magmas of Large Igneous Provinces.These results suggest that the basaltic volcaniclastic rocks on the Xisha Islands originated from a volatile-poor mantle plume source.
基金financial support of the French National Radioactive Waste Management Agency(Andra)is gratefully acknowledged.
文摘Argillaceous rocks are considered ideal host geomaterials for deep geological disposal of radioactive waste due to their low permeability,notable sorption capacity,low diffusion coefficient,limited natural fracturing,and capacity for self-sealing.In line with this objective,substantial efforts have been made in the literature over the past decades to model their behavior numerically.Yet,accurately modeling the hydromechanical behavior of argillaceous rocks remains a significant challenge in geomechanics,highlighting the need for further research.Despite the wide variety of geomaterials in this class,common behavioral features are observed,such as anisotropy,structural degradation,strain localization,creep,heterogeneity,and self-sealing.This study summarizes these common features observed in laboratory and field settings and reviews the developed approaches for modeling each behavioral aspect.The goal is to establish a comprehensive framework for the practical modeling of these geomaterials,specifically aimed at applications in the geological disposal of radioactive waste.
文摘In this paper,we present a novel approach to study the electrical properties of intact rock by combining impedance and vector network analyzer measurements in the frequency range from 5 Hz to 3 GHz.For the firsttime,this study enables electrical characterization of the exact same rock sample over nine orders of magnitude in frequency range,utilizing a coaxial cell apparatus with specificallyprepared rock samples.Three types of rocks(basalt,sandstone and granite)with low to intermediate porosity(12.24%,16.9%and 7.49%,respectively)were characterized at varying saturation levels.The relaxation behavior of the samples was quantifiedusing an advanced phenomenological model incorporating both the dielectric constant and electrical conductivity in the form of Debye and Cole-Cole representations.Across the frequency range,three distinct relaxation processes were identified:a high-frequency water process and two interfacial processes related to interactions between the aqueous pore solution and mineral particles(membrane relaxation and Maxwell-Wagner effects).Additionally,an apparent direct current conductivity was observed.This comprehensive broadband analysis represents a further step toward the in situ characterization of rocks using electromagnetic fieldmeasurement methods and demonstrates advancements in both methodology and understanding of rock properties compared to existing studies.
文摘The publisher regrets that the article type for this publication was incorrectly labeled as a Research Article.The correct designation should be Review Article.
