The title compounds,C_(24)H_(32)Cl_2,N_2O_4(I)and C_(26)H_(32)BaCl_2N_4O_4S_2 (Ⅱ)have been synthesized and crystal structures determined. The crystallographic data are as follows: (I)M_r=483. 44,orthorhombic, space g...The title compounds,C_(24)H_(32)Cl_2,N_2O_4(I)and C_(26)H_(32)BaCl_2N_4O_4S_2 (Ⅱ)have been synthesized and crystal structures determined. The crystallographic data are as follows: (I)M_r=483. 44,orthorhombic, space group P2_12_12_1,a= 4. 852 (1), b= 11. 989(2), c=41. 231 (8) A, V=2398. 7(8) A￣3, Z=4, μ(MoKa)=3. 07 cm￣(-1), D_c=1. 338 g/cm￣3, F(000)=960, R=0. 0678, R_w=0. 0514. (Ⅱ) M_r=736.93, monoclinic, space group P2_1/c, a=8. 801 (2), b=11. 653(9) , c=15. 756(6) A,β=105. 96(3)°, V=1553. 7(14) A￣3, Z= 2, μ(MoKa)=16. 58 cm￣(-1), D_c=1. 575 g/ cm￣3, F(000)= 740. In compound Ⅱ, the Ba cation is coordinated by four oxygen atoms, two mitrogen atoms of diazo-18-crown-6 and two nitrogen atoms from SCN￣- to form a distorted D_(6h) geometry with the Ba￣(2+) at the center of crystallographic symmetry.展开更多
The single crystal of[Ba(H2O)2(C6H12O6)2Cl2]was obtained based on the phase equilibrium results.Its structure was determined by X-ray crystallographic analysis.The crystals are monoclinic and in space group C2/c with ...The single crystal of[Ba(H2O)2(C6H12O6)2Cl2]was obtained based on the phase equilibrium results.Its structure was determined by X-ray crystallographic analysis.The crystals are monoclinic and in space group C2/c with a=1.9017(2)nm,b=0.68213(8)nm,c=0.16260(2)nm,β=96.593(2)°and V=2.0953(4)nm3,Z=4,DC=1.917 g·cm-3.In its solid state,this supramolecular complex is a three-dimensional network with double layers connected by hydrogen bondings.The molecule structure of[Ba(H2O)2(C6H12O6)2Cl2]has a central barium ion that is coordinated to two water molecules,two chlorides,and four hydroxyls from the two inositols.Losing the coordinating water is controlled by random nucleation and growth mechanism(n=2/3)and 3-dimensional diffusion mechanism(n=2).展开更多
文摘The title compounds,C_(24)H_(32)Cl_2,N_2O_4(I)and C_(26)H_(32)BaCl_2N_4O_4S_2 (Ⅱ)have been synthesized and crystal structures determined. The crystallographic data are as follows: (I)M_r=483. 44,orthorhombic, space group P2_12_12_1,a= 4. 852 (1), b= 11. 989(2), c=41. 231 (8) A, V=2398. 7(8) A￣3, Z=4, μ(MoKa)=3. 07 cm￣(-1), D_c=1. 338 g/cm￣3, F(000)=960, R=0. 0678, R_w=0. 0514. (Ⅱ) M_r=736.93, monoclinic, space group P2_1/c, a=8. 801 (2), b=11. 653(9) , c=15. 756(6) A,β=105. 96(3)°, V=1553. 7(14) A￣3, Z= 2, μ(MoKa)=16. 58 cm￣(-1), D_c=1. 575 g/ cm￣3, F(000)= 740. In compound Ⅱ, the Ba cation is coordinated by four oxygen atoms, two mitrogen atoms of diazo-18-crown-6 and two nitrogen atoms from SCN￣- to form a distorted D_(6h) geometry with the Ba￣(2+) at the center of crystallographic symmetry.
文摘The single crystal of[Ba(H2O)2(C6H12O6)2Cl2]was obtained based on the phase equilibrium results.Its structure was determined by X-ray crystallographic analysis.The crystals are monoclinic and in space group C2/c with a=1.9017(2)nm,b=0.68213(8)nm,c=0.16260(2)nm,β=96.593(2)°and V=2.0953(4)nm3,Z=4,DC=1.917 g·cm-3.In its solid state,this supramolecular complex is a three-dimensional network with double layers connected by hydrogen bondings.The molecule structure of[Ba(H2O)2(C6H12O6)2Cl2]has a central barium ion that is coordinated to two water molecules,two chlorides,and four hydroxyls from the two inositols.Losing the coordinating water is controlled by random nucleation and growth mechanism(n=2/3)and 3-dimensional diffusion mechanism(n=2).
