As a sulfur-containing cathode material,sulfide polyacrylonitrile(SPAN)is expected to be used for longlife lithium-sulfur battery because there is no shuttle effect occurred in its charge process.However,its specific ...As a sulfur-containing cathode material,sulfide polyacrylonitrile(SPAN)is expected to be used for longlife lithium-sulfur battery because there is no shuttle effect occurred in its charge process.However,its specific capacity and discharge potential need to be further improved to satisfy the urgent demands for high-performance batteries.In this paper,Te0.045S0.955PAN composite was synthesized by co-heating TexS1-x and PAN,and the superior electrochemical performance to that of SPAN was obtained because of doping Te with high conductivity.The as-prepared Te0.045S0.955PAN composite possessed the specific capacity of 675 mAh g^-1 after 100 cycles at the current density of 0.1 A g^-1 with high capacity retention of96.6%compared to the second cycle.Especially,during cycling,Te0.045S0.955PAN showed average discharge voltages of 1.88-1.91 V,which were higher than 1.85-1.88 V for SPAN at the same current density.Thus doping Te provides a new strategy for increasing the energy density of SPAN.展开更多
Vortex diode,as an important component in power fluidics,has been used in nuclear reprocessing engineering where it is desirable to avoid pumps with moving parts.The performance of the fluidic system depends on the ma...Vortex diode,as an important component in power fluidics,has been used in nuclear reprocessing engineering where it is desirable to avoid pumps with moving parts.The performance of the fluidic system depends on the matched design parameters of vortex diodes and the supporting facilities.However,no clear guidelines for design and optimization of vortex diodes system are available.Therefore,we carried out detailed experimental study on hydraulic characteristics of the vortex diodes system with changeable parameters to evolve such guidelines.The study covered a wide range of a vortex diode and vortex diodes system.The variation of averaged discharge and volumetric efficiency in respect to air supply pressure,liquid level of water tank and liquid level stroke of gas-liquid energy converter was studies.The experimental results were analyzed to develop design guidelines.The guidelines are shown to be useful for obtaining the design parameters that would yield the desired hydrau- lic performance for the required operating conditions.展开更多
基金financially supported by the National Key Research and Development program of China(no.2016YFB0100200)Beijing Municipal Science and Technology Project(no.Z181100004518001)
文摘As a sulfur-containing cathode material,sulfide polyacrylonitrile(SPAN)is expected to be used for longlife lithium-sulfur battery because there is no shuttle effect occurred in its charge process.However,its specific capacity and discharge potential need to be further improved to satisfy the urgent demands for high-performance batteries.In this paper,Te0.045S0.955PAN composite was synthesized by co-heating TexS1-x and PAN,and the superior electrochemical performance to that of SPAN was obtained because of doping Te with high conductivity.The as-prepared Te0.045S0.955PAN composite possessed the specific capacity of 675 mAh g^-1 after 100 cycles at the current density of 0.1 A g^-1 with high capacity retention of96.6%compared to the second cycle.Especially,during cycling,Te0.045S0.955PAN showed average discharge voltages of 1.88-1.91 V,which were higher than 1.85-1.88 V for SPAN at the same current density.Thus doping Te provides a new strategy for increasing the energy density of SPAN.
基金supported by the National Natural Science Foundation of China(Grant No.51006087)
文摘Vortex diode,as an important component in power fluidics,has been used in nuclear reprocessing engineering where it is desirable to avoid pumps with moving parts.The performance of the fluidic system depends on the matched design parameters of vortex diodes and the supporting facilities.However,no clear guidelines for design and optimization of vortex diodes system are available.Therefore,we carried out detailed experimental study on hydraulic characteristics of the vortex diodes system with changeable parameters to evolve such guidelines.The study covered a wide range of a vortex diode and vortex diodes system.The variation of averaged discharge and volumetric efficiency in respect to air supply pressure,liquid level of water tank and liquid level stroke of gas-liquid energy converter was studies.The experimental results were analyzed to develop design guidelines.The guidelines are shown to be useful for obtaining the design parameters that would yield the desired hydrau- lic performance for the required operating conditions.