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Integrated Assembly Structure Design Within Concurrent Engineering
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作者 常向青 宁汝新 +2 位作者 姚珺 张旭 唐承统 《Journal of Beijing Institute of Technology》 EI CAS 2001年第3期306-311,共6页
Taking a microwave product as an example, a system of integrated assembly structure design is presented. Getting design constraints from the upstream design section through product data management(PDM), the system gen... Taking a microwave product as an example, a system of integrated assembly structure design is presented. Getting design constraints from the upstream design section through product data management(PDM), the system generates the assembly scheme using the case? based method, then assigns the design requirements into each component of the assembly. The detail design for each component can be performed under these design constraints. In order to practise concurrent design, the system sends the final design result to the upstream section and downstream section through PDM to achieve information sharing and integration. 展开更多
关键词 concurrent engineering assembly structure design case-based reasoning design constraints
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Robotic compliant assembly for complex-shaped composite aircraft frame based on Gaussian process considering uncertainties 被引量:1
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作者 Yingke YANG Dongsheng LI +3 位作者 Yunong ZHAI Jie WANG Lei XUE Zhiyong YANG 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2024年第10期471-482,共12页
Robots are finding increasing application in aircraft composite structure assembly due to their flexibility and the growing demand of aircraft manufacturers for high production rates.The contact force of the composite... Robots are finding increasing application in aircraft composite structure assembly due to their flexibility and the growing demand of aircraft manufacturers for high production rates.The contact force of the composite frame in a robotic assembly of the aircraft composite fuselage panel can hardly be controlled due to the multi-surface variable contact stiffness caused by compliance and complex shape with multiple mating surfaces.The paper proposes a robotic assembly system for the aircraft composite fuselage frame with a compliant contact force control strategy using the Gaussian process surrogate model.First,a robotic assembly system is introduced,and the global coordinate system transformation model is built.Then,a compliant force control architecture is designed to generate the desired output force.Subsequently,a Gaussian process surrogate model with uncertainties is utilized to model the complicated relationship between the robot’s output force and the normal contact force acting on the mating surface of the composite frame.Furthermore,an optimal contact force control strategy is implemented to improve the contact quality.Finally,an experiment demonstrates that the proposed methodology can ensure that the contact force on each surface is within the limit of the engineering specification and uniformly distributed,improving the quality compared to the traditional assembly process. 展开更多
关键词 AIRCRAFT Composite structure assembly Multi-surface contact Compliant control Gaussian process Uncertainty
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Mechanical properties of segmental joints strengthened by assembled reinforcement structures for shield tunnel linings
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作者 Zhiguo YAN Sihang AI +3 位作者 Xia YANG Long ZHOU Bing FAN Huan PANG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 CSCD 2024年第12期1037-1050,共14页
We develop assembled reinforcement structures(ARSs)composed of connection parts,connecting rods,and straight bolts to strengthen segmental joints in the lining of shield tunnels.Through full-scale bending experiments ... We develop assembled reinforcement structures(ARSs)composed of connection parts,connecting rods,and straight bolts to strengthen segmental joints in the lining of shield tunnels.Through full-scale bending experiments and numerical simulations,we investigate the deformation and failure characteristics of segmental joints strengthened by ARSs,and propose a novel optimization method for ARSs.The experimental results show that the ARSs can effectively limit the opening of a segmental joint,but also that separation can occur during loading if the connection between the ARSs and segments is not designed properly.Importantly,this connection can be improved by embedding anchor parts in the concrete.In numerical modeling,we investigate the failure modes of segmental joints strengthened by ARSs for both positive bending and negative bending loading cases.In the case of positive bending loading,first the concrete around the anchor parts cracks,and subsequently the concrete on the external side of the joint is crushed.The joint failure is caused by the crushing of concrete on the external side of the joint.While the un-strengthened segmental joint fails with an opening of 5.884 mm,the strengthened segmental joint only opens by 0.288 mm under the same loading,corresponding to a reduction of 95.1%.In the case of negative bending loading,the concrete around the anchor parts first cracks,and then the amount of joint opening exceeds a limiting value for waterproofing(6 mm),i.e.,the joint’s failure is caused by water leakage.While the opening of the un-strengthened segmental joint is 9.033 mm and experiences waterproofing failure,the opening of the strengthened segmental joint is only 2.793 mm under the same loading,corresponding to a reduction of 69.1%.When constructing a new shield tunnel,anchor parts could be embedded in the concrete segments in tandem with ARSs for improved resistance to joint opening.For existing shield tunnel linings,anchor parts cannot be embedded in the concrete segments;therefore,the connections between the ARSs and concrete need to be optimized to strengthen the segmental joint. 展开更多
关键词 Shield tunnel Segmental joint Assembled reinforcement structure(ARS) Mechanical properties
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Hierarchical model updating strategy of complex assembled structures with uncorrelated dynamic modes 被引量:4
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作者 Chengwei FEI Haotian LIU +2 位作者 Rhea PATRICIA LIEM Yatsze CHOY Lei HAN 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2022年第3期281-296,共16页
In structural simulation and design,an accurate computational model directly determines the effectiveness of performance evaluation.To establish a high-fidelity dynamic model of a complex assembled structure,a Hierarc... In structural simulation and design,an accurate computational model directly determines the effectiveness of performance evaluation.To establish a high-fidelity dynamic model of a complex assembled structure,a Hierarchical Model Updating Strategy(HMUS)is developed for Finite Element(FE)model updating with regard to uncorrelated modes.The principle of HMUS is first elaborated by integrating hierarchical modeling concept,model updating technology with proper uncorrelated mode treatment,and parametric modeling.In the developed strategy,the correct correlated mode pairs amongst the uncorrelated modes are identified by an error minimization procedure.The proposed updating technique is validated by the dynamic FE model updating of a simple fixed–fixed beam.The proposed HMUS is then applied to the FE model updating of an aeroengine stator system(casings)to demonstrate its effectiveness.Our studies reveal that(A)parametric modeling technique is able to build an efficient equivalent model by simplifying complex structure in geometry while ensuring the consistency of mechanical characteristics;(B)the developed model updating technique efficiently processes the uncorrelated modes and precisely identifies correct Correlated Mode Pairs(CMPs)between FE model and experiment;(C)the proposed HMUS is accurate and efficient in the FE model updating of complex assembled structures such as aeroengine casings with large-scale model,complex geometry,high-nonlinearity and numerous parameters;(D)it is appropriate to update a complex structural FE model parameterized.The efforts of this study provide an efficient updating strategy for the dynamic model updating of complex assembled structures with experimental test data,which is promising to promote the precision and feasibility of simulation-based design optimization and performance evaluation of complex structures. 展开更多
关键词 Aeroengine casings Assembled structures Correlated mode pair Hierarchical model updating Objective function Uncorrelated modes
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Response Spectrum Analysis of 7-story Assembled Frame Structure with Energy Dissipation System 被引量:1
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作者 Jin Zhao Yi Wang Zhengwei Ma 《Structural Durability & Health Monitoring》 EI 2023年第2期159-173,共15页
Viscoelastic damper is an effective passive damping device,which can reduce the seismic response of the structure by increasing the damping and dissipating the vibration energy of structures.It has a wide application ... Viscoelastic damper is an effective passive damping device,which can reduce the seismic response of the structure by increasing the damping and dissipating the vibration energy of structures.It has a wide application prospect in actual structural vibration control because of simple device and economical material.In view of the poor seismic behaviors of assembled frame structure connections,various energy dissipation devices are proposed to improve the seismic performance.The finite element numerical analysis method is adopted to analyze relevant energy dissipation structural parameters.The response spectrum of a 7-story assembled frame structure combined the ordinary steel support,ordinary viscoelastic damper,and viscoelastic damper with displacement amplification device is analyzed.The analysis results show that the mechanical behavior of assembled frame structure with ordinary steel supports are not significantly different from those without energy dissipation devices.The assembled frame structure with viscoelastic damper has better seismic performance and energy dissipation,especially for the viscoelastic damper with displacement amplification devices.The maximum value of inter-story displacement angle decreases by 32.24%;the maximum floor displacement decreases by 31.91%,and the base shear decreases by 13.62%compared with the assembled frame structures without energy dissipation devices.The results show that the seismic fortification ability of the structure is significantly improved,and the overall structure is more uniformly stressed.The damping structure with viscoelastic damper mainly reduces the dynamic response of the structure by increasing the damping coefficient,rather than by changing the natural vibration period of the structure.This paper provides an effective theoretical basis and reference for improving the energy dissipation system and the seismic performance of assembled frame structures. 展开更多
关键词 Assembled frame structure energy dissipation devices response spectrum analysis viscoelastic damper
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Design methods of rhombic tensegrity structures 被引量:2
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作者 Xi-Qiao Feng Yue Li +2 位作者 Yan-Ping Cao Shou-Wen Yu Yuan-Tong Gu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第4期559-565,共7页
As a special type of novel flexible structures, tensegrity holds promise for many potential applications in such fields as materials science, biomechanics, civil and aerospace engineering. Rhombic systems are an impor... As a special type of novel flexible structures, tensegrity holds promise for many potential applications in such fields as materials science, biomechanics, civil and aerospace engineering. Rhombic systems are an important class of tensegrity structures, in which each bar constitutes the longest diagonal of a rhombus of four strings. In this paper, we address the design methods of rhombic structures based on the idea that many tensegrity structures can be constructed by assembling one-bar elementary cells. By analyzing the properties of rhombic cells, we first develop two novel schemes, namely, direct enumeration scheme and cell-substitution scheme. In addition, a facile and efficient method is presented to integrate several rhombic systems into a larger tensegrity structure. To illustrate the applications of these methods, some novel rhombic tensegrity structures are constructed. 展开更多
关键词 Tensegrity Structural design Assembling method Flexible structure
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Fabrication of polymeric-Laponite composite hollow microspheres via LBL assembly 被引量:3
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作者 Wei Deng Hua-Chao Guo +1 位作者 Guo-An Li Cheng-You Kan 《Chinese Chemical Letters》 SCIE CAS CSCD 2017年第2期367-371,共5页
Hollow structure microspheres with composite polymeric-Laponite shells were prepared by electrostatic self-assembly of Laponite on the polymeric hollow microspheres in this work.The multilayer hydrophilic core/hydroph... Hollow structure microspheres with composite polymeric-Laponite shells were prepared by electrostatic self-assembly of Laponite on the polymeric hollow microspheres in this work.The multilayer hydrophilic core/hydrophobic shell polymer latex particles containing carboxyl groups inside were first synthesized via seeded emulsion polymerization,followed by alkali treatment,generating polymeric hollow microspheres.Then,polyethyleneimine(PEI) and Laponite were alternately electrostatic adsorbed on the prepared polymeric hollow microspheres to form polymeric-Laponite composite hollow microspheres.It was indicated that the morphology of alkali-treated microspheres could be tuned through simply altering the dosage of alkali used in the post-treatment process.Along with the increasing of the coating layers,the zeta potential of microspheres absorbed PEI or Laponite approximately tended to be constant respectively,and the thickness of Laponite layer around the hollow microspheres increased clearly,getting more uniform and homogenous.Furthermore,the corresponding polymeric-Laponite hollow microspheres showed high pressure resistance ability compared to the polymeric hollow microspheres. 展开更多
关键词 Composite microspheres Hollow structure Laponite Osmotic swelling LBL assembly
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Optimization Design of an Embedded Multi-Cell Thin-Walled Energy Absorption Structures with Local Surface Nanocrystallization
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作者 Kang Xu Tong Li +3 位作者 Gaofei Guan Jianlong Qu Zhen Zhao Xinsheng Xu 《Computer Modeling in Engineering & Sciences》 SCIE EI 2022年第2期987-1002,共16页
Bymeans of the local surface nanocrystallization that enables to change the material on local positions,an innovative embedded multi-cell(EMC)thin-walled energy absorption structures with local surface nanocrystalliza... Bymeans of the local surface nanocrystallization that enables to change the material on local positions,an innovative embedded multi-cell(EMC)thin-walled energy absorption structures with local surface nanocrystallization is proposed in this paper.The local surface nanacrystallization stripes are regarded as the moving morphable components in the domain for optimal design.Results reveal that after optimizing the local surface nanocrystallization layout,the specific energy absorption(SEA)is increased by 50.78%compared with the untreated counterpart.Besides,in contrast with the optimized 4-cell structure,the SEA of the nanocrystallized embedded 9-cell structure is further enhanced by 27.68%,in contrast with the 9-cell structure,the SEA of the nanocrystallized embedded clapboard type 9-cell structure is enhanced by 3.61%.Thismethod provides a guidance for the design of newenergy absorption devices. 展开更多
关键词 Local surface nanocrystallization EMC model assembled thin-walled energy absorption structures optimization design specific energy absorption
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Analysis of Soundproof Technology of Assembled Steel Structure Houses
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作者 Jing Sun 《Journal of World Architecture》 2023年第5期66-71,共6页
The problem of noise has always been highlighted in assembled steel structure houses.Therefore,it is necessary to use effective soundproof measures where steel beams intersect with the reserved line pipe openings,door... The problem of noise has always been highlighted in assembled steel structure houses.Therefore,it is necessary to use effective soundproof measures where steel beams intersect with the reserved line pipe openings,doors,windows,elevator shafts,and other locations.In this paper,we will investigate the areas with subpar soundproof performance in an assembled steel structure residential project and propose suitable noise control measures to address this issue. 展开更多
关键词 Assembled steel structure Residential engineering Sound insulation Construction technology Online publication:October 25 2023
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Review on multi-dimensional assembled S-scheme heterojunction photocatalysts 被引量:5
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作者 Jiani Lu Shaonan Gu +3 位作者 Hongda Li Yinan Wang Meng Guo Guowei Zhou 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第29期214-239,共26页
S-scheme heterostructure photocatalysts utilize the synergistic and superposition effects of materials,ef-fectively separating electrons and holes,maintaining strong redox capacity,and addressing issues en-countered b... S-scheme heterostructure photocatalysts utilize the synergistic and superposition effects of materials,ef-fectively separating electrons and holes,maintaining strong redox capacity,and addressing issues en-countered by current photocatalytic reactions.This review explores the origins and unique benefits of S-scheme heterojunctions.Specifically,we summarized and discussed the effects of different dimensions of semiconductors constituting S-scheme heterojunctions and the similarities and differences in elec-tron transfer processes when constructing heterojunctions.Additionally,we analyzed several methods for proving the formation of S-scheme heterojunctions and the electron transfer process,both directly and indirectly.Finally,we review the applications of S-scheme heterojunctions in various fields of photo-catalysis,including photocatalytic water splitting,pollution degradation,CO_(2) reduction and other related photocatalytic applications.Our hope is that this review will provide an essential reference for the devel-opment and application of S-scheme heterojunction photocatalysis. 展开更多
关键词 S-scheme heterojunctions Multi-dimensional assembled structures Photocatalysis Water splitting Pollution degradation Co_(2)reduction
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Layered and three-dimensional uranyl–organic assemblies with 4,4′-oxidiphthalic acid 被引量:1
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作者 Dai Wu Ying Gao +3 位作者 Wan-Guo Tian Yun-Hui Li Weiting Yang Zhong-Ming Sun 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第3期325-329,共5页
Hydrothermal reactions of uranyl nitrate and 4,4'-oxidiphthalic acid(H4L) resulted in the formation of three new uranyl-organic framework materials,namely(NH4)2[(UO2)3(L)2]·5H2O(1),(NEt4)[(UO2)3(... Hydrothermal reactions of uranyl nitrate and 4,4'-oxidiphthalic acid(H4L) resulted in the formation of three new uranyl-organic framework materials,namely(NH4)2[(UO2)3(L)2]·5H2O(1),(NEt4)[(UO2)3(H2O)(L)(HL)](2) and(UO2)7(H2O)2(phen)4(L)2(HL)2(3)(NEt4 = tetraethylammonium,phen = 1,10-phenanthroline).These three structures all comprise common uranyl pentagonal bipyramids.In 1,UO7polyhedra are linked by hexadentate ligands to form a 3D framework with 1D channels,in which are located NH4^+ ions and water molecules.While in 2,the organic ligands adopt pentadentate and hexadentate coordination modes,ligating UO7 units to create a layered structure with channels filled by NEt4^+ ions.For 3,uranyl square bipyramids are also accommodated together with pentagonal bipyramids,which are linked by tetradentate carboxylate ligands to produce the layered assembly.Phen molecules also coordinate to the uranyl centers to build up the structure.Luminescent studies indicate that 2 and 3 exhibit the characteristic uranyl emission. 展开更多
关键词 Uranyl–organic assemblies Carboxylates structures Luminescence
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Ordered mesoporous Cu-ZnO-Al_2O_3 adsorbents for reactive adsorption desulfurization with enhanced sulfur saturation capacity 被引量:6
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作者 YaqingLiua YuanPanb +2 位作者 HongyingWanga YunqiLiua ChenguangLiua 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第9期1543-1551,共9页
To enhance sulfur adsorption and reactive activity, ordered mesoporous Cu-ZnO-Al2O3 adsorbents were prepared by a novel one-pot evaporation-induced self-assembly strategy using P123 as a structure-directing agent and ... To enhance sulfur adsorption and reactive activity, ordered mesoporous Cu-ZnO-Al2O3 adsorbents were prepared by a novel one-pot evaporation-induced self-assembly strategy using P123 as a structure-directing agent and ethanol as the solvent for reactive adsorption desulfurization. The metal oxide precursor molecules around P123 micellized, and self-assembly simultaneously occurred during evaporation from an ethanol solution at 60 °C, leading to the formation of the p6 mm hexagonal symmetry mesoporous structure. Characterization results prove that the Cu-ZnO-Al2O3 adsorbents possess an ordered mesoporous structure with high thermal stability, large surface area(386–226 m2/g), large pore volume(0.60–0.46 cm3/g), and good dispersion of ZnO and Cu, which is beneficial for transforming S-compounds to ZnO. The sulfur saturation capacity of the ordered-mesoporous-structure Cu-ZnO-Al2O3 adsorbents is larger(49.4 mg/g) than that of the unordered mesoporous structure(13.5 mg/g). 展开更多
关键词 Cu‐ZnO‐Al2O3Or deredmesoporous structure One‐potevaporation‐induced self‐assembly Reactiveads orptiondesul furization Sulfursaturation capacity
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Recent progress of sugar amino acids: Synthetic strategies and applications as glycomimetics and peptidomimetics 被引量:1
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作者 Guang-Zong Tian Xiao-Li Wang +3 位作者 Jing Hu Xue-Bin Wang Xiao-Qiang Guo Jian Yin 《Chinese Chemical Letters》 SCIE CAS CSCD 2015年第8期922-930,共9页
In order to meet the increasing demands for the development of large varieties of new molecules for discovering new drugs and materials, organic chemists are developing many novel multifunctional building blocks, whic... In order to meet the increasing demands for the development of large varieties of new molecules for discovering new drugs and materials, organic chemists are developing many novel multifunctional building blocks, which are assembled rationally to create ‘nature-like' and yet unnatural organic molecules with well-defined structures and useful properties. Sugar amino acids(SAAs), the carbohydrate derivatives bearing both amino and carboxylic acid functional groups, are important ones of these multifunctional building blocks, which can be used to create novel materials with potential applications as glycomimetics and peptidomimetics. This review will focus on recent synthetic strategies of SAAs and their applications in creating large number of structurally diverse glycomimetics and peptidomimetics. 展开更多
关键词 structurally carboxylic oligomer blocks assembled Fmoc amide carbohydrate diverse protected
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Assembly mechanisms and energy transfer pathways deciphered in the cryo-EM structure of spinach photosystem Ⅱ-LHCⅡ supercomplex
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《Science Foundation in China》 CAS 2016年第4期36-,共1页
Funded by the National Natural Science Foundation of China(NSFC),Ministry of Science and Technology of China,and Chinese Academy of Sciences,ajoint team of three laboratories from the Institute of Biophysics of Chines... Funded by the National Natural Science Foundation of China(NSFC),Ministry of Science and Technology of China,and Chinese Academy of Sciences,ajoint team of three laboratories from the Institute of Biophysics of Chinese Academy of Sciences,led by Dr.Liu Zhenfeng(柳振峰),Dr.Zhang Xinzheng(章新政)and Dr.Li Mei(李梅)respectively,solved the structure of spinach photosystem II-LHCII supercom- 展开更多
关键词 PSII assembly mechanisms and energy transfer pathways deciphered in the cryo-EM structure of spinach photosystem SUPERCOMPLEX LHC EM
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Study on carbon emissions towards flange connection joints of assembled steel structures
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作者 Jinyang Guo Yanxia Zhang +2 位作者 Mingzhao Zheng Xi Zhao Binglong Wu 《Low-carbon Materials and Green Construction》 2024年第1期405-425,共21页
In order to comply with the trend of global climate change,countries are gradually promoting energy conservation and emission reduction,and prefabricated buildings have become one of the main paths for the constructio... In order to comply with the trend of global climate change,countries are gradually promoting energy conservation and emission reduction,and prefabricated buildings have become one of the main paths for the construction industry to develop towards carbon peaking and carbon neutrality goals.This paper takes the box-shaped column flange connection achieved by plug welding-core sleeve in the dormitory building of Tongzhou Campus of the Affiliated High School of Capital Normal University in China as the research object.Based on the consumption quota of prefabricated construction projects and the actual project quantity,the carbon emissions of steel structure column connection joints at different phases are calculated by the emission factor method,and it is proposed that the production consumption of building materials plays a key role in energy conservation and emission reduction.This paper concludes that the box-shaped column flange connection achieved by plug welding-core sleeve in the construction phase of an assembled steel building emits 49.5%less carbon dioxide than a conventional full fusion-welded joint.And the reason for the high carbon emissions of the latter is mainly from the amount of materials and machinery required for full penetration welding.It further affirms the green and environmental protection effect of the assembled steel structure plug welding-core sleeve flange connection joint in actual projects,and provides a reference for related research. 展开更多
关键词 Carbon peaking and carbon neutrality goals Assembled steel structure Flange connections achieved by plug welding-core sleeve Emission factor method
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Low-Friction Soft Robots for Targeted Bacterial Infection Treatment in Gastrointestinal Tract
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作者 Ben Wang Yunrui Chen +6 位作者 Zhicheng Ye Haidong Yu Kai Fung Chan Tiantian Xu Zhiguang Guo Weimin Liu Li Zhang 《Cyborg and Bionic Systems》 2024年第1期162-176,共15页
Untethered and self-transformable miniature robots are capable of performing reconfigurable deformation and on-demand locomotion,which aid the traversal toward various lumens,and bring revolutionary changes for target... Untethered and self-transformable miniature robots are capable of performing reconfigurable deformation and on-demand locomotion,which aid the traversal toward various lumens,and bring revolutionary changes for targeted delivery in gastrointestinal(GI)tract.However,the viscous non-Newtonian liquid environment and plicae gastricae obstacles severely hamper high-precision actuation and payload delivery.Here,we developed a low-friction soft robot by assembly of densely arranged cone structures and grafting of hydrophobic monolayers.The magnetic orientation encoded robot can move in multiple modes,with a substantially reduced drag,terrain adaptability,and improved motion velocity across the non-Newtonian liquids.Notably,the robot stiffness can be reversibly controlled with magnetically induced hardening,enabling on-site scratching and destruction of antibiotic-ineradicable polymeric matrix in biofilms with a low-frequency magnetic field.Furthermore,the magnetocaloric effect can be utilized to eradicate the bacteria by magnetocaloric effect under high-frequency alternating field.To verify the potential applications inside the body,the clinical imaging-guided actuation platforms were developed for vision-based control and delivery of the robots.The developed low-friction robots and clinical imaging-guided actuation platforms show their high potential to perform bacterial infection therapy in various lumens inside the body. 展开更多
关键词 gastrointestinal tract reconfigurable deformation targeted bacterial infection treatment low friction soft robots plicae gastricae obstacles assembly densely arranged cone structures targeted delivery grafting hy
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Ag_(2)S Quantum Dots Decorated on Porous Cubic-CdS Nanosheets-assembled Flowers for Photocatalytic CO_(2)Reduction 被引量:2
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作者 Wei Fu Jiajie Fan Quanjun Xiang 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2022年第6期39-47,共9页
The production of renewable fossil fuels such as CH_(4) and CO by photocatalytic CO_(2)reduction has attracted more and more attention.However,single photocatalyst is less efficient for photocatalytic reduction of CO_... The production of renewable fossil fuels such as CH_(4) and CO by photocatalytic CO_(2)reduction has attracted more and more attention.However,single photocatalyst is less efficient for photocatalytic reduction of CO_(2)due to the fast recombination of photogenerated electron pairs.Herein,we successfully prepare CdS-Ag_(2)S composite by assembling the Ag_(2)S QDs cocatalyst on the surface of CdS nanosheet-assembled flower through oil-bath solvothermal method.This composite is prepared through a simple self-assembly strategy using cadmium chloride,ammonia and thiourea as precursors of the CdS nanosheet-assembled flower and silver nitrate and 3-mercaptopropionic acid as the precursors of Ag_(2)S QDs.The average diameter of Ag_(2)S QDs is apparently 6.0 nm.The light absorption edge of the composite is at around 560 nm,with the corresponding band gap at 2.14 eV.The CdS-Ag_(2)S QDs composite with 5 wt%Ag_(2)S QDs loaded achieves CO evolution rate of 16.6μmol·g^(-1)·h^(-1)without noble-metal cocatalysts.This strengthened photocatalytic performance and photocatalytic stability were attributed to the energy band broadening of Ag_(2)S QDs caused by quantum size effect and the large specific surface area due to the assembled flower.The mechanism underlying the enhanced photocatalytic CO_(2)reduction activity is further proposed.This study demonstrates that semiconductor-based quantum dots are strong candidates for excellent cocatalysts in photocatalysis. 展开更多
关键词 CdS nanosheet Ag_(2)S quantum dots(QDs) assembled flower structure composite materials photocatalytic CO_(2)reduction
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Structural modulation and assembling of metal halide perovskites for solar cells and light-emitting diodes 被引量:2
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作者 Xixia Liu Zhaofu Zhang +1 位作者 Fen Lin Yuanhang Cheng 《InfoMat》 SCIE CAS 2021年第11期1218-1250,共33页
Metal halide perovskites possess appealing optoelectronic properties and have been widely applied for solar energy harvesting and light emitting.Although perovskite solar cells(PeSCs)and perovskite light-emitting diod... Metal halide perovskites possess appealing optoelectronic properties and have been widely applied for solar energy harvesting and light emitting.Although perovskite solar cells(PeSCs)and perovskite light-emitting diodes(PeLEDs)have been developed rapidly in recent years,there are still no universal rules for the selection of perovskites to achieve high-performance optoelectronic devices.In this review,the working mechanisms of PeSCs and PeLEDs are first demonstrated with the discussion on the factors which determine the device performance.We then examine the optoelectronic properties of perovskites with structures modulated from 3D,2D,1D to 0D,and analyze the corresponding structure-property relationships in terms of photo-electric and electric-photo conversion processes.Based on the unique optoelectronic properties of structurally modulated perovskites,we put forward the concept of structural assembling engineering that integrate the merits of different types of perovskites within one matrix and elaborate their excellent properties for applications of both PeSCs and PeLEDs.Finally,we discuss the potential challenges and provide our perspectives on the structural assembling engineering of perovskites for future optoelectronic applications. 展开更多
关键词 light-emitting diodes low-dimensional perovskites metal halide perovskites solar cells structural assembling structure modulation
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