Effects of alloying elements Ni,Co,Mn,Cr,and H on the stacking fault energy(SFE)ofγ-Fe and its microscopic mechanisms were systematically investigated.Generalized SFE calculations show that individual alloying elemen...Effects of alloying elements Ni,Co,Mn,Cr,and H on the stacking fault energy(SFE)ofγ-Fe and its microscopic mechanisms were systematically investigated.Generalized SFE calculations show that individual alloying elements Ni,Co,and H increase SFE ofγ-Fe,whereas Mn and Cr decrease SFE.The influence of alloying elements on SFE exhibits short-range characteristics.The effect of synergistic interaction of alloying elements and H on SFE was further investigated.Results show that the co-alloying of Ni/Co with H exacerbates the effect of H on the increase in SFE.In contrast,the synergistic effect of Mn/Cr with H tends to inhibit H from the increasing SFE.Finally,the electronic structure analysis elucidated the microscopic mechanism of the change in SFE.Alloying elements modulate SFE by changing the interatomic charge density at the stacking fault plane and the density of states of the stacking fault structure at the Fermi level.The present results add to the knowledge of alloying related influence on the mechanical property and hydrogen embrittlement ofγ-Fe.展开更多
The stability constants of some ternary mixed-ligand complexes, Pt(Phen)(CA)+, where Phen=1,10-phenanthroline and CA- =carboxylate, were determined by means of potentiometric pH titration in aqueous solutions(I=0.1 mo...The stability constants of some ternary mixed-ligand complexes, Pt(Phen)(CA)+, where Phen=1,10-phenanthroline and CA- =carboxylate, were determined by means of potentiometric pH titration in aqueous solutions(I=0.1 mol/L, KNO 3; 25 ℃), and the stability of them was compared with that of the corresponding binary complexes. It was revealed that the ternary complexes containing phenylalkane carboxylates ligands(PCA-) are much more stable than those formed with formate and acetate. The results indicate that there exist the intramolecular aromatic-ring interactions between the phenanthroline ring of Phen and the phenyl moiety of ligand PCA- in the ternary mixed-ligand Pt(Phen)(PCA)- complexes. The extent of the stacking interactions, which depends on the number of methylene groups between the phenyl moieties and the coordinated phenylalkane carboxylate groups, was calculated. The best-fitted stack was obtained for the complexes with 2-phenylacetate and 3-phenylpropionate as the ligands.展开更多
The intramolecular aromatic-ring stacking interaction of mixed- ligand complex Pd(A)(UTP)^(2-)in the system pd^(2+)-A-UTP^(4-)has been determined by ~1HNMR,where A=1,10-phenanthroline(phen),2,2'-bipyridyl(bpy)and ...The intramolecular aromatic-ring stacking interaction of mixed- ligand complex Pd(A)(UTP)^(2-)in the system pd^(2+)-A-UTP^(4-)has been determined by ~1HNMR,where A=1,10-phenanthroline(phen),2,2'-bipyridyl(bpy)and DL- tryptophan(trp^-);UTP^(4-)=uridine 5-triphosphate.The result indicates that it is the partial stacking between the uracil ring of UTP^(4-)and the heterocyclic ring of A that makes H(5),H(6)and H(1')in the UTP^(4-)shift upfield signifi- cantly.Accordingly,the order of aromatic-ring interaction in the mixed- ligand complex has been obtained as follows:Pd(phen)(UTP)^(2-)(?)Pd(bpy)(UTP)^(2-) Pd(trp)(UTP)^(3-).展开更多
Generalized stacking-fault energies （GSFEs） of basal-plane stacking faults 11 and 12 in Mg alloys have been studied based on first-principles calculations, where 43 alloying elements were considered. It is found tha...Generalized stacking-fault energies （GSFEs） of basal-plane stacking faults 11 and 12 in Mg alloys have been studied based on first-principles calculations, where 43 alloying elements were considered. It is found that the most contributing features of alloying elements to GSFEs are bulk modulus, equilibrium volume, binding energy, atomic radius and ionization energy. Both bulk modulus and ionization energy exhibit positive relationships with GSFEs, and the others show opposite relationships. Multiple regressions have been performed to offer a quantitative prediction for basal-plane GSFEs in Mg-X systems. GSFEs, alloying effects of elements and the prediction model established within this work may provide guidelines for new Mg alloys design with better ductility.展开更多
Intrinsic stacking-fault energy is a critical parameter influencing the various mechanical performances of aus- tenitic steels with high Mn concentrations. However, quantitative calculations of the stacking-fault ener...Intrinsic stacking-fault energy is a critical parameter influencing the various mechanical performances of aus- tenitic steels with high Mn concentrations. However, quantitative calculations of the stacking-fault energy （SFE） of the face-centered cubic （fcc） Fe, including the changes in concentrations and geometrical distribution of alloying atoms, cannot be obtained by using previous computation models. On the basis of the interaction energy model, we evaluated the effects of a single alloying atom （i.e., Mn, A1, Si, C and N）, as well as its aggregates, including the Mn-X dimer and Mn2-X trimer （X = A1, Si, C and N） on the SFE of the fcc Fe via first-principle calculations. Given low concentrations （〈10 wt%） of alloying atoms, dimers and trimers, theoretical calculations reveal the following： （1） Alloying atom Mn causes a decrease in the SFE, whereas A1, Si, C and N significantly increase the SFE; （2） combination with other alloying atoms to form the Mn-X dimer （X = A1, Si, C and N） exerts an effect on SFE that, to a certain extent, is close to that of the corresponding single X atom; （3） the interaction between Mnz-X and the stacking fault is stronger than that of the corresponding single X atom, inducing a significant increase in the SFE of fcc Fe. The theoretical results we obtained demonstrate that the increase in SFE in high-Mn steel originates from the synergistic effect of Mn and other trace alloy atoms.展开更多
The stabilities of the complexes of three pyridine-like ligands with M(II)(ATP)^(2-) and M(II)(M=Ni,Co)were studied by spectrophotometry and by comparing the stability constants of the ternary complexes with these of ...The stabilities of the complexes of three pyridine-like ligands with M(II)(ATP)^(2-) and M(II)(M=Ni,Co)were studied by spectrophotometry and by comparing the stability constants of the ternary complexes with these of the binary complexes.A stacking interaction between the pyridine ring and the purine ring of ATP is indicated.The general existence of the stacking interaction encourages us to interpret the antitumor mechanism of a new class of antitumor drugs.展开更多
Stack effect is a dominant driving force for building natural ventilation.Analytical models were developed for the evaluation of stack effect in a shaft,accounting for the heat transfer from shaft interior boundaries....Stack effect is a dominant driving force for building natural ventilation.Analytical models were developed for the evaluation of stack effect in a shaft,accounting for the heat transfer from shaft interior boundaries.Both the conditions with constant heat flux from boundaries to the airflow and the ones with constant boundary temperature were considered.The prediction capabilities of these analytical models were evaluated by using large eddy simulation(LES)for a hypothetical shaft.The results show that there are fairly good agreements between the predictions of the analytical models and the LES predictions in mass flow rate,vertical temperatures profile and pressure difference as well.Both the results of analytical models and LES show that the neutral plane could locate higher than one half of the shaft height when the upper opening area is identical with the lower opening area.Further,it is also shown that the analytical models perform better than KLOTE's model does in the mass flow rate prediction.展开更多
Since stack effect that occurs in high-rise buildings has an effect on the indoor environment of the buildings, energy loss and smoke control in case of a fire, there is a need to conduct research on this. For an anal...Since stack effect that occurs in high-rise buildings has an effect on the indoor environment of the buildings, energy loss and smoke control in case of a fire, there is a need to conduct research on this. For an analysis of the stack effect, analysis methods on the leakage flow through gap of interior door shall be formulated. Until now, studies related to the gap leakage flow in buildings have mainly analyzed flow field and pressure in the buildings one-dimensionally using pressure difference-leakage flowrate relations of Orifice Equation and a network numerical analysis algorithm that as- sumes each compartment in the buildings as a single point. In this study, the Momentum Loss Model which enables pressure drop to be proportional to the flow velocity through the gap of door in computational domain of 3-dimensional numerical analysis was proposed to reflect the gap flow phenomenon effectively in 3-dimensional numerical analysis. Using the proposed model, 3-dimensional numerical analysis of the stack effect on the stairs in buildings was performed, and the effects of separation door and lobby between stair and accommodation on the stack effect were investigated.展开更多
Ultra-high voltage(UHV)transmission lines are an important part of China’s power grid and are often surrounded by a complex electromagnetic environment.The ground total electric field is considered a main electromagn...Ultra-high voltage(UHV)transmission lines are an important part of China’s power grid and are often surrounded by a complex electromagnetic environment.The ground total electric field is considered a main electromagnetic environment indicator of UHV transmission lines and is currently employed for reliable long-term operation of the power grid.Yet,the accurate prediction of the ground total electric field remains a technical challenge.In this work,we collected the total electric field data from the Ningdong-Zhejiang±800 kV UHVDC transmission project,as of the Ling Shao line,and perform an outlier analysis of the total electric field data.We show that the Local Outlier Factor(LOF)elimination algorithm has a small average difference and overcomes the performance of Density-Based Spatial Clustering of Applications with Noise(DBSCAN)and Isolated Forest elimination algorithms.Moreover,the Stacking algorithm has been found to have superior prediction accuracy than a variety of similar prediction algorithms,including the traditional finite element.The low prediction error of the Stacking algorithm highlights the superior ability to accurately forecast the ground total electric field of UHVDC transmission lines.展开更多
After comparing the mechanism of tilted plume under stack effect with that of spill plume,the tilted plume model induced by stack effect in a vertical shaft is developed simply based on the theoretical results and a s...After comparing the mechanism of tilted plume under stack effect with that of spill plume,the tilted plume model induced by stack effect in a vertical shaft is developed simply based on the theoretical results and a series of full-scale tests. It is shown that the two sides of plume are symmetrical and have an accordant regulation that the plume radius has a linear relation to the height z. The profile of fire plume under stack effect is similar to the windblown flame in wind tunnel,and the range of flame deflection angle is about from 50 to 60 degree.展开更多
Higher-s dielectric LaLuO3, deposited by molecular beam deposition, with TiN as gate stack is integrated into high-mobility Si/SiGe/SOI quantum-well p-type metal-oxide-semiconduetor field effect transistors. Threshold...Higher-s dielectric LaLuO3, deposited by molecular beam deposition, with TiN as gate stack is integrated into high-mobility Si/SiGe/SOI quantum-well p-type metal-oxide-semiconduetor field effect transistors. Threshold voltage shift and capacitance equivalent thickness shrink are observed, resulting from oxygen scavenging effect in LaLuO3 with ti-rich TiN after high temperature annealing. The mechanism of oxygen scavenging and its potential for resistive memory applications are analyzed and discussed.展开更多
A stacked lateral double-diffused metal–oxide–semiconductor field-effect transistor(LDMOS) with enhanced depletion effect by surface substrate is proposed(ST-LDMOS), which is compatible with the traditional CMOS pro...A stacked lateral double-diffused metal–oxide–semiconductor field-effect transistor(LDMOS) with enhanced depletion effect by surface substrate is proposed(ST-LDMOS), which is compatible with the traditional CMOS processes. The new stacked structure is characterized by double substrates and surface dielectric trenches(SDT). The drift region is separated by the P-buried layer to form two vertically parallel devices. The doping concentration of the drift region is increased benefiting from the enhanced auxiliary depletion effect of the double substrates, leading to a lower specific on-resistance(Ron,sp). Multiple electric field peaks appear at the corners of the SDT, which improves the lateral electric field distribution and the breakdown voltage(BV). Compared to a conventional LDMOS(C-LDMOS), the BV in the ST-LDMOS increases from 259 V to 459 V, an improvement of 77.22%. The Ron,sp decreases from 39.62 m?·cm^2 to 23.24 m?·cm^2 and the Baliga's figure of merit(FOM) of is 9.07 MW/cm^2.展开更多
In this paper, the effect of floating body effect （FBE） on a single event transient generation mechanism in fully depleted （FD） silicon-on-insulator （SOI） technology is investigated using three-dimensional techn...In this paper, the effect of floating body effect （FBE） on a single event transient generation mechanism in fully depleted （FD） silicon-on-insulator （SOI） technology is investigated using three-dimensional technology computer-aided design （3D- TCAD） numerical simulation. The results indicate that the main SET generation mechanism is not carder drift/diffusion but floating body effect （FBE） whether for positive or negative channel metal oxide semiconductor （PMOS or NMOS）. Two stacking layout designs mitigating FBE are investigated as well, and the results indicate that the in-line stacking （IS） layout can mitigate FBE completely and is area penalty saving compared with the conventional stacking layout.展开更多
One of the typical phenomena of intramolecular ligand-ligand interaction in complexes is the aromatic-ring stacking which depends on the stacking of those non-coordinating aromatic rings. Since 1974 H. Sigel reported ...One of the typical phenomena of intramolecular ligand-ligand interaction in complexes is the aromatic-ring stacking which depends on the stacking of those non-coordinating aromatic rings. Since 1974 H. Sigel reported that the stacking interaction was observed between pyridine ring of bpy（bpy=2, 2′-bipyridyl） and purine ring of ATP<sup>4-</sup>(ATP<sup>4-</sup>=adenosine 5′-triphosphate) among the mixed-ligand Cu（bpy） （ATP）<sup>2-</sup> complexes. The study on this field has been extended to a large amount of ligands such as nucleotides, xanthosines,展开更多
Based on the exact resultant solution of two-dimensional Poisson＇s equation, the novel two-dimensional models, which include surface potential, threshold voltage, subthreshold current and subthreshold swing, have bee...Based on the exact resultant solution of two-dimensional Poisson＇s equation, the novel two-dimensional models, which include surface potential, threshold voltage, subthreshold current and subthreshold swing, have been developed for gate stack symmetrical double-gate strained-Si MOSFETs. The models are verified by numerical simulation. Besides offering the physical insight into device physics, the model provides the basic designing guidance of further immunity of short channel effect of complementary metal-oxide-semiconductor （CMOS）-based device in a nanoscale regime.展开更多
It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting th...It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting the stack performance. A step function is used to describe the effect of the air entrainment caused by the water discharged from branch pipes. An additional source term is introduced to reflect the gas-liquid interphase interaction （GLII） and stack base effect. The drainage stack is divided into upper and base parts. The air pressure in the upper part is predicted by a total variation diminishing （TVD） scheme, while in the base part, it is predicted by a characteristic line method （CLM）. The predicted results are compared with the data measured in a real-scale high- rise test building. It is found that the additional source term in the present model is effective. It intensively influences the air pressure distribution in the stack. The air pressure is also sensitive to the velocity-adjusting parameter （VAP）, the branch pipe air entrainment, and the conditions on the stack bottom.展开更多
Stimulus-responsive polymers containing dynamic bonds enable fascinating properties of self-healing,recycling and reprocessing due to enhanced relaxation of polymer chain/network with labile linkages.Here,we study the...Stimulus-responsive polymers containing dynamic bonds enable fascinating properties of self-healing,recycling and reprocessing due to enhanced relaxation of polymer chain/network with labile linkages.Here,we study the structure and properties of a new type of thermoplastic polyurethanes(TPUs)with trapped dynamic covalent bonds in the hard-phase domain and report the frustrated relaxation of TPUs containing weak dynamic bond andπ-πinteraction in hard segments.As detected by rheometry,the aromatic TPUs with alkyl disulfide in the hard segments possess the maximum network relaxation time in contrast to those without dynamic bonds and alicyclic TPUs.In situ FTIR and small-angle scattering results reveal that the alkyl disulfide facilitates stronger intermolecular interaction and more stable micro-phase morphology inπ-πinteraction based aromatic TPUs.Molecular dynamics simulation for pure hard segments of model molecules verify that the presence of disulfide bonds leads to strongerπ-πstacking of aromatic rings due to both enhanced assembling thermodynamics and kinetics.The enhancedπ-πpacking and micro-phase structure in TPUs further kinetically immobilize the dynamic bond.This kinetically interlocking between the weak dynamic bonds and strong molecular interaction in hard segments leads to much slower network relaxation of TPU.This work provides a new insight in tuning the network relaxation and heat resistance as well as molecular self-assembly in stimulus-responsive dynamic polymers by both molecular design and micro-phase control toward the functional applications of advanced materials.展开更多
Silicon-on-insulator (SOI) CMOS technology is a very attractive option for implementing digital integrated circuits for low power applications. This paper presents migration of standby subthreshold leakage control tec...Silicon-on-insulator (SOI) CMOS technology is a very attractive option for implementing digital integrated circuits for low power applications. This paper presents migration of standby subthreshold leakage control technique from a bulk CMOS to SOI CMOS technology. An improved SOI CMOS technology based circuit technique for effective reduction of standby subthreshold leakage power dissipation is proposed in this paper. The proposed technique is validated through design and simulation of a one-bit full adder circuit at a temperature of 27℃, supply voltage, VDD of 0.90 V in 120 nm SOI CMOS technology. Existing standby subthreshold leakage control techniques in CMOS bulk technology are compared with the proposed technique in SOI CMOS technology. Both the proposed and existing techniques are also implemented in SOI CMOS technology and compared. Reduction in standby subthreshold leakage power dissipation by reduction factors of 54x and 45x foraone-bit full adder circuit was achieved using our proposed SOI CMOS technology based circuit technique in comparison with existing techniques such as MTCMOS technique and SCCMOS technique respectively in CMOS bulk technology. Dynamic power dissipation was also reduced significantly by using this proposed SOI CMOS technology based circuit technique. Standby subthreshold leakage power dissipation and dynamic power dissipation were also reduced significantly using the proposed circuit technique in comparison with other existing techniques, when all circuit techniques were implemented in SOI CMOS technology. All simulations were performed using Microwindver 3.1 EDA tool.展开更多
基金supported by National Science and Technology Major Project(2025ZD0618901)National Natural Science Foundation of China(U2241245 and 52321001)+2 种基金Aeronautical Science Foundation of China(2022Z053092001)Natural Science Foundation of Shenyang(23-503-6-05)Science and Technology Major Project of Liaoning Province(2024JH1/11700028).
文摘Effects of alloying elements Ni,Co,Mn,Cr,and H on the stacking fault energy(SFE)ofγ-Fe and its microscopic mechanisms were systematically investigated.Generalized SFE calculations show that individual alloying elements Ni,Co,and H increase SFE ofγ-Fe,whereas Mn and Cr decrease SFE.The influence of alloying elements on SFE exhibits short-range characteristics.The effect of synergistic interaction of alloying elements and H on SFE was further investigated.Results show that the co-alloying of Ni/Co with H exacerbates the effect of H on the increase in SFE.In contrast,the synergistic effect of Mn/Cr with H tends to inhibit H from the increasing SFE.Finally,the electronic structure analysis elucidated the microscopic mechanism of the change in SFE.Alloying elements modulate SFE by changing the interatomic charge density at the stacking fault plane and the density of states of the stacking fault structure at the Fermi level.The present results add to the knowledge of alloying related influence on the mechanical property and hydrogen embrittlement ofγ-Fe.
基金Supported by the Foundation of Academ y L eader of Zhejiang Gongshang U niversity(No.19972 0 0 2 )
文摘The stability constants of some ternary mixed-ligand complexes, Pt(Phen)(CA)+, where Phen=1,10-phenanthroline and CA- =carboxylate, were determined by means of potentiometric pH titration in aqueous solutions(I=0.1 mol/L, KNO 3; 25 ℃), and the stability of them was compared with that of the corresponding binary complexes. It was revealed that the ternary complexes containing phenylalkane carboxylates ligands(PCA-) are much more stable than those formed with formate and acetate. The results indicate that there exist the intramolecular aromatic-ring interactions between the phenanthroline ring of Phen and the phenyl moiety of ligand PCA- in the ternary mixed-ligand Pt(Phen)(PCA)- complexes. The extent of the stacking interactions, which depends on the number of methylene groups between the phenyl moieties and the coordinated phenylalkane carboxylate groups, was calculated. The best-fitted stack was obtained for the complexes with 2-phenylacetate and 3-phenylpropionate as the ligands.
文摘The intramolecular aromatic-ring stacking interaction of mixed- ligand complex Pd(A)(UTP)^(2-)in the system pd^(2+)-A-UTP^(4-)has been determined by ~1HNMR,where A=1,10-phenanthroline(phen),2,2'-bipyridyl(bpy)and DL- tryptophan(trp^-);UTP^(4-)=uridine 5-triphosphate.The result indicates that it is the partial stacking between the uracil ring of UTP^(4-)and the heterocyclic ring of A that makes H(5),H(6)and H(1')in the UTP^(4-)shift upfield signifi- cantly.Accordingly,the order of aromatic-ring interaction in the mixed- ligand complex has been obtained as follows:Pd(phen)(UTP)^(2-)(?)Pd(bpy)(UTP)^(2-) Pd(trp)(UTP)^(3-).
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0701202)the National Natural Science Foundation of China(General Program No.51474149 and Key Program No.51631006)
文摘Generalized stacking-fault energies （GSFEs） of basal-plane stacking faults 11 and 12 in Mg alloys have been studied based on first-principles calculations, where 43 alloying elements were considered. It is found that the most contributing features of alloying elements to GSFEs are bulk modulus, equilibrium volume, binding energy, atomic radius and ionization energy. Both bulk modulus and ionization energy exhibit positive relationships with GSFEs, and the others show opposite relationships. Multiple regressions have been performed to offer a quantitative prediction for basal-plane GSFEs in Mg-X systems. GSFEs, alloying effects of elements and the prediction model established within this work may provide guidelines for new Mg alloys design with better ductility.
基金supported by the National Key Research and Development Program of China(No. 2016YFB0300801)the National Natural Science Foundation of China(Nos.11427806,51471067,51371081,51671082 and 51601060)+1 种基金the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20120161110036)the Hunan Provincial Natural Science Foundation of China(No.14JJ4052)
文摘Intrinsic stacking-fault energy is a critical parameter influencing the various mechanical performances of aus- tenitic steels with high Mn concentrations. However, quantitative calculations of the stacking-fault energy （SFE） of the face-centered cubic （fcc） Fe, including the changes in concentrations and geometrical distribution of alloying atoms, cannot be obtained by using previous computation models. On the basis of the interaction energy model, we evaluated the effects of a single alloying atom （i.e., Mn, A1, Si, C and N）, as well as its aggregates, including the Mn-X dimer and Mn2-X trimer （X = A1, Si, C and N） on the SFE of the fcc Fe via first-principle calculations. Given low concentrations （〈10 wt%） of alloying atoms, dimers and trimers, theoretical calculations reveal the following： （1） Alloying atom Mn causes a decrease in the SFE, whereas A1, Si, C and N significantly increase the SFE; （2） combination with other alloying atoms to form the Mn-X dimer （X = A1, Si, C and N） exerts an effect on SFE that, to a certain extent, is close to that of the corresponding single X atom; （3） the interaction between Mnz-X and the stacking fault is stronger than that of the corresponding single X atom, inducing a significant increase in the SFE of fcc Fe. The theoretical results we obtained demonstrate that the increase in SFE in high-Mn steel originates from the synergistic effect of Mn and other trace alloy atoms.
基金Supported by the National Natural Science Foundation of Chinathe Doctoral Program Foundation of Institution of High Education the Research Foundation of State Key Laboratory of Coordination Chemistry,Nanjing University.
文摘The stabilities of the complexes of three pyridine-like ligands with M(II)(ATP)^(2-) and M(II)(M=Ni,Co)were studied by spectrophotometry and by comparing the stability constants of the ternary complexes with these of the binary complexes.A stacking interaction between the pyridine ring and the purine ring of ATP is indicated.The general existence of the stacking interaction encourages us to interpret the antitumor mechanism of a new class of antitumor drugs.
基金Project(50838009)supported by the National Natural Science Foundation of ChinaProject(2010DFA72740-03)supported by the National Key Technology Research and Development Program of China
文摘Stack effect is a dominant driving force for building natural ventilation.Analytical models were developed for the evaluation of stack effect in a shaft,accounting for the heat transfer from shaft interior boundaries.Both the conditions with constant heat flux from boundaries to the airflow and the ones with constant boundary temperature were considered.The prediction capabilities of these analytical models were evaluated by using large eddy simulation(LES)for a hypothetical shaft.The results show that there are fairly good agreements between the predictions of the analytical models and the LES predictions in mass flow rate,vertical temperatures profile and pressure difference as well.Both the results of analytical models and LES show that the neutral plane could locate higher than one half of the shaft height when the upper opening area is identical with the lower opening area.Further,it is also shown that the analytical models perform better than KLOTE's model does in the mass flow rate prediction.
文摘Since stack effect that occurs in high-rise buildings has an effect on the indoor environment of the buildings, energy loss and smoke control in case of a fire, there is a need to conduct research on this. For an analysis of the stack effect, analysis methods on the leakage flow through gap of interior door shall be formulated. Until now, studies related to the gap leakage flow in buildings have mainly analyzed flow field and pressure in the buildings one-dimensionally using pressure difference-leakage flowrate relations of Orifice Equation and a network numerical analysis algorithm that as- sumes each compartment in the buildings as a single point. In this study, the Momentum Loss Model which enables pressure drop to be proportional to the flow velocity through the gap of door in computational domain of 3-dimensional numerical analysis was proposed to reflect the gap flow phenomenon effectively in 3-dimensional numerical analysis. Using the proposed model, 3-dimensional numerical analysis of the stack effect on the stairs in buildings was performed, and the effects of separation door and lobby between stair and accommodation on the stack effect were investigated.
基金funded by a science and technology project of State Grid Corporation of China“Comparative Analysis of Long-Term Measurement and Prediction of the Ground Synthetic Electric Field of±800 kV DC Transmission Line”(GYW11201907738)Paulo R.F.Rocha acknowledges the support and funding from the European Research Council(ERC)under the European Union’s Horizon 2020 Research and Innovation Program(Grant Agreement No.947897).
文摘Ultra-high voltage(UHV)transmission lines are an important part of China’s power grid and are often surrounded by a complex electromagnetic environment.The ground total electric field is considered a main electromagnetic environment indicator of UHV transmission lines and is currently employed for reliable long-term operation of the power grid.Yet,the accurate prediction of the ground total electric field remains a technical challenge.In this work,we collected the total electric field data from the Ningdong-Zhejiang±800 kV UHVDC transmission project,as of the Ling Shao line,and perform an outlier analysis of the total electric field data.We show that the Local Outlier Factor(LOF)elimination algorithm has a small average difference and overcomes the performance of Density-Based Spatial Clustering of Applications with Noise(DBSCAN)and Isolated Forest elimination algorithms.Moreover,the Stacking algorithm has been found to have superior prediction accuracy than a variety of similar prediction algorithms,including the traditional finite element.The low prediction error of the Stacking algorithm highlights the superior ability to accurately forecast the ground total electric field of UHVDC transmission lines.
基金supported by the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science &Technology of China ( Grant No: 2006BAJ13B03)the RGCCERG Grant #CityU1253/04E from Hong Kong Re-search Grant Council, HKSAR
文摘After comparing the mechanism of tilted plume under stack effect with that of spill plume,the tilted plume model induced by stack effect in a vertical shaft is developed simply based on the theoretical results and a series of full-scale tests. It is shown that the two sides of plume are symmetrical and have an accordant regulation that the plume radius has a linear relation to the height z. The profile of fire plume under stack effect is similar to the windblown flame in wind tunnel,and the range of flame deflection angle is about from 50 to 60 degree.
基金Supported by the National Natural Science Foundation of China under Grant No 61306126
文摘Higher-s dielectric LaLuO3, deposited by molecular beam deposition, with TiN as gate stack is integrated into high-mobility Si/SiGe/SOI quantum-well p-type metal-oxide-semiconduetor field effect transistors. Threshold voltage shift and capacitance equivalent thickness shrink are observed, resulting from oxygen scavenging effect in LaLuO3 with ti-rich TiN after high temperature annealing. The mechanism of oxygen scavenging and its potential for resistive memory applications are analyzed and discussed.
基金supported by the National Natural Science Foundation of China(Grant No.61464003)the Guangxi Natural Science Foundation,China(Grant Nos.2015GXNSFAA139300 and 2018JJA170010)
文摘A stacked lateral double-diffused metal–oxide–semiconductor field-effect transistor(LDMOS) with enhanced depletion effect by surface substrate is proposed(ST-LDMOS), which is compatible with the traditional CMOS processes. The new stacked structure is characterized by double substrates and surface dielectric trenches(SDT). The drift region is separated by the P-buried layer to form two vertically parallel devices. The doping concentration of the drift region is increased benefiting from the enhanced auxiliary depletion effect of the double substrates, leading to a lower specific on-resistance(Ron,sp). Multiple electric field peaks appear at the corners of the SDT, which improves the lateral electric field distribution and the breakdown voltage(BV). Compared to a conventional LDMOS(C-LDMOS), the BV in the ST-LDMOS increases from 259 V to 459 V, an improvement of 77.22%. The Ron,sp decreases from 39.62 m?·cm^2 to 23.24 m?·cm^2 and the Baliga's figure of merit(FOM) of is 9.07 MW/cm^2.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61376109,61434007,and 61176030)the Advanced Research Project of National University of Defense Technology,China(Grant No.0100066314001)
文摘In this paper, the effect of floating body effect （FBE） on a single event transient generation mechanism in fully depleted （FD） silicon-on-insulator （SOI） technology is investigated using three-dimensional technology computer-aided design （3D- TCAD） numerical simulation. The results indicate that the main SET generation mechanism is not carder drift/diffusion but floating body effect （FBE） whether for positive or negative channel metal oxide semiconductor （PMOS or NMOS）. Two stacking layout designs mitigating FBE are investigated as well, and the results indicate that the in-line stacking （IS） layout can mitigate FBE completely and is area penalty saving compared with the conventional stacking layout.
基金Project supported by the National Natural Science Foundation of China
文摘One of the typical phenomena of intramolecular ligand-ligand interaction in complexes is the aromatic-ring stacking which depends on the stacking of those non-coordinating aromatic rings. Since 1974 H. Sigel reported that the stacking interaction was observed between pyridine ring of bpy（bpy=2, 2′-bipyridyl） and purine ring of ATP<sup>4-</sup>(ATP<sup>4-</sup>=adenosine 5′-triphosphate) among the mixed-ligand Cu（bpy） （ATP）<sup>2-</sup> complexes. The study on this field has been extended to a large amount of ligands such as nucleotides, xanthosines,
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60976068 and 60936005)Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China (Grant No. 708083),Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China (Grant No. 200807010010)
文摘Based on the exact resultant solution of two-dimensional Poisson＇s equation, the novel two-dimensional models, which include surface potential, threshold voltage, subthreshold current and subthreshold swing, have been developed for gate stack symmetrical double-gate strained-Si MOSFETs. The models are verified by numerical simulation. Besides offering the physical insight into device physics, the model provides the basic designing guidance of further immunity of short channel effect of complementary metal-oxide-semiconductor （CMOS）-based device in a nanoscale regime.
基金Project supported by the National Natural Science Foundation of China (No. 10972212)
文摘It is necessary to understand the features of air pressure in a drainage stack of a high-rise building for properly designing and operating a drainage system. This paper presents a mathematical model for predicting the stack performance. A step function is used to describe the effect of the air entrainment caused by the water discharged from branch pipes. An additional source term is introduced to reflect the gas-liquid interphase interaction （GLII） and stack base effect. The drainage stack is divided into upper and base parts. The air pressure in the upper part is predicted by a total variation diminishing （TVD） scheme, while in the base part, it is predicted by a characteristic line method （CLM）. The predicted results are compared with the data measured in a real-scale high- rise test building. It is found that the additional source term in the present model is effective. It intensively influences the air pressure distribution in the stack. The air pressure is also sensitive to the velocity-adjusting parameter （VAP）, the branch pipe air entrainment, and the conditions on the stack bottom.
基金financially supported by the National Natural Science Foundation of China(No.21774135)。
文摘Stimulus-responsive polymers containing dynamic bonds enable fascinating properties of self-healing,recycling and reprocessing due to enhanced relaxation of polymer chain/network with labile linkages.Here,we study the structure and properties of a new type of thermoplastic polyurethanes(TPUs)with trapped dynamic covalent bonds in the hard-phase domain and report the frustrated relaxation of TPUs containing weak dynamic bond andπ-πinteraction in hard segments.As detected by rheometry,the aromatic TPUs with alkyl disulfide in the hard segments possess the maximum network relaxation time in contrast to those without dynamic bonds and alicyclic TPUs.In situ FTIR and small-angle scattering results reveal that the alkyl disulfide facilitates stronger intermolecular interaction and more stable micro-phase morphology inπ-πinteraction based aromatic TPUs.Molecular dynamics simulation for pure hard segments of model molecules verify that the presence of disulfide bonds leads to strongerπ-πstacking of aromatic rings due to both enhanced assembling thermodynamics and kinetics.The enhancedπ-πpacking and micro-phase structure in TPUs further kinetically immobilize the dynamic bond.This kinetically interlocking between the weak dynamic bonds and strong molecular interaction in hard segments leads to much slower network relaxation of TPU.This work provides a new insight in tuning the network relaxation and heat resistance as well as molecular self-assembly in stimulus-responsive dynamic polymers by both molecular design and micro-phase control toward the functional applications of advanced materials.
文摘Silicon-on-insulator (SOI) CMOS technology is a very attractive option for implementing digital integrated circuits for low power applications. This paper presents migration of standby subthreshold leakage control technique from a bulk CMOS to SOI CMOS technology. An improved SOI CMOS technology based circuit technique for effective reduction of standby subthreshold leakage power dissipation is proposed in this paper. The proposed technique is validated through design and simulation of a one-bit full adder circuit at a temperature of 27℃, supply voltage, VDD of 0.90 V in 120 nm SOI CMOS technology. Existing standby subthreshold leakage control techniques in CMOS bulk technology are compared with the proposed technique in SOI CMOS technology. Both the proposed and existing techniques are also implemented in SOI CMOS technology and compared. Reduction in standby subthreshold leakage power dissipation by reduction factors of 54x and 45x foraone-bit full adder circuit was achieved using our proposed SOI CMOS technology based circuit technique in comparison with existing techniques such as MTCMOS technique and SCCMOS technique respectively in CMOS bulk technology. Dynamic power dissipation was also reduced significantly by using this proposed SOI CMOS technology based circuit technique. Standby subthreshold leakage power dissipation and dynamic power dissipation were also reduced significantly using the proposed circuit technique in comparison with other existing techniques, when all circuit techniques were implemented in SOI CMOS technology. All simulations were performed using Microwindver 3.1 EDA tool.
