From a life cycle perspective,the material flow analysis is utilized to investigate the lithium material flows in international trade from 2000 to 2019.The results reveal that at the global level,the total volume of l...From a life cycle perspective,the material flow analysis is utilized to investigate the lithium material flows in international trade from 2000 to 2019.The results reveal that at the global level,the total volume of lithium trade grew rapidly,reaching 121116 t in 2019.Lithium trade was dominated by lithium minerals,lithium carbonate and lithium hydroxide rather than final lithium products,indicating an immaturity in global lithium industry.At the intercontinental level,Asia’s import trade and Oceania’s export trade led the world,accounting for 81.22%and 39.68%,respectively.At the national level,China,Japan and Korea became the main importers,while Chile and Australia were the main exporters.In addition,China’s trade volume far exceeded that of the United States.China’s exports were dominated by lithium-ion batteries,while the United States mainly imported lithium-ion batteries,proving that the development of China’s lithium industry was relatively faster.展开更多
The occurrence of geogenic arsenic(As)in groundwater is a global public health concern.However,there remain large gaps in groundwater As data,making it difficult to identify non-compliant domestic wells,partly due to ...The occurrence of geogenic arsenic(As)in groundwater is a global public health concern.However,there remain large gaps in groundwater As data,making it difficult to identify non-compliant domestic wells,partly due to lack of low-cost methods capable of rapid As analysis.Therefore,the development of high through-put and reliable on-site determination methods for inorganic As is essential.Herein,a portable automated analyzer was developed for the determination of arsenite(As(Ⅲ)),arsenate(As(Ⅴ))and phosphate in As contaminated groundwater based on a previously adapted method for molybdenum blue spectrophotometry.After the optimization of the chemical reactions and flow manifold,the system demonstrated a high sample through-put(4.8/h for As(Ⅲ),As(Ⅴ)and phosphate analysis),allowing this system to screen 125 samples in 24 h.Other advantages include low operational costs(0.3 CNY per sample),appropriate sensitivity for contaminated groundwater(detection limits of 4.7μg/L,8.3μg/L and 5.4μg/L for As(Ⅲ),As(Ⅴ)and phosphate,respectively),good linearity(R^(2)>0.9996 at As concentrations up to 1600μg/L)and high precision(relative standard deviations of 3.5% and 2.8% for As(Ⅲ)and As(Ⅴ),respectively).The portable system was successfully used for As speciation analysis in 5 groundwater samples collected from multi-level wells at Yinchuan Plain,northwestern China,with total As concentrations ranging from 75.7 to 295.0μg/L,independently assessing As speciation,providing a promising novel method for the rapid on-site screening of As in tens of millions of domestic wells worldwide.展开更多
This study assesses the potential and benefits of reducing plastic consumption at the institutional level by taking the Beijing Institute of Petrochemical Technology(BIPT)in China as the case.By tracking the plastic m...This study assesses the potential and benefits of reducing plastic consumption at the institutional level by taking the Beijing Institute of Petrochemical Technology(BIPT)in China as the case.By tracking the plastic material flow on the BIPT campus,we provide insights into the efforts required to achieve a plastic-free campus.A mixed-methods approach was employed,encompassing material flow analysis,quantitative analysis of influencing factors,examination of best practices in universities,and market price-based valuation of plastic reduction.The main conclusions are as follows:(1)Each student consumed an average of 9.2 kg of plastics for daily use on BIPT campus in the base year of 2020,with campus canteens,off-campus cafés,and shops(offline and online)contributing to 36%,31%and 30%respectively.(2)BIPT has a reduction potential of 45%,equivalent to 4.1 kg per student annually,yielding benefits of 45 RMB from savings in oil material and production energy,avoiding plastic waste,and reducing carbon emission.(3)If all global tertiary institutions set a target of reducing plastics by 4.1 kg per student,1.94 Mt of plastics could be avoided by 2035.(4)Greater reductions and benefits could be achieved if tertiary institutions extend their efforts across all campus activities,with substantial indirect and long-term contributions ranging from more sustainable campus management to fostering a transition towards a green economy.These findings highlight that plastic-free initiatives require contextual construction and environmental education both on and off campus.展开更多
To accurately acquire deep-sea live biological samples,a hydraulic suction macro-biological pressure-retaining sampler(HSMPS)was designed to achieve active capture of seafloor biological by a suction pump.The complex ...To accurately acquire deep-sea live biological samples,a hydraulic suction macro-biological pressure-retaining sampler(HSMPS)was designed to achieve active capture of seafloor biological by a suction pump.The complex flow fields of deep-sea biologicals at three different locations were simulated.The deep-sea biologicals cause the flow field pressure and velocity to rise at different locations of the sampler,and the magnitude of the rise varies at different locations.The internal flow properties of the sampler were analyzed for different pumping flow rates the sampler.When the flow rate of the sampler pump was greater than 14 m3/h,the velocity of the inlet of the inflow area was greater than the limiting velocity of the deep-sea biologicals.The pumping test of deep-sea biologicals pumping sampler was carried out in the laboratory,and the test results were basically consistent with the simulation analysis.In order to balance the deep-sea biologicals damage and escape rate,the pumping flow of the sampler should be controlled between 14 and 16 m3/h.The test results provide a theoretical basis for the design of deep-sea biologicals sampling equipment.展开更多
With the acceleration of industrialization and urbanization,ammonia nitrogen pollution in water bodies has become increasingly severe,making the development of efficient and low-consumption wastewater treatment tech-n...With the acceleration of industrialization and urbanization,ammonia nitrogen pollution in water bodies has become increasingly severe,making the development of efficient and low-consumption wastewater treatment tech-nologies highly significant.This study employs three-dimensional computational fluid dynamics(CFD)to investigate the cavitation mechanisms and flow field characteristics in a novel jet impingement-negative pressure ammonia removal reactor.The simulation,validated by experimental pressure data with a high degree of consistency,utilizes the Mixture model,the Realizable k-εturbulence model,and the Schnerr-Sauer cavitation model.The results demonstrate that the flow velocity undergoes a substantial acceleration within the orifice nozzle,triggering a dramatic pressure drop from an inlet value of approximately 1.17 MPa to below the saturated vapor pressure,reaching as low as−109 kPa,which induces intense cavitation.Cavitation bubbles primarily originate on the inner wall of the nozzle,with the vapor volume fraction peaking at about 0.42 within the orifice.A strong positive correlation was observed between the local vapor fraction and the flow velocity,indicating that cavitation enhances jet intensity.Furthermore,vortex structures near the wall and within the jacket sustain low-pressure zones,facilitating continuous cavitation and efficient mixing.This study quantitatively elucidates the cavitation dynamics and its interplay with the flow field,providing a solid theoretical and numerical basis for optimizing the reactor design to enhance ammonia removal efficiency.展开更多
The flow characteristics of shell-side fluid in the tube-and-shell heat exchangers with trisection helical baffles with 35° inclined angles are numerically analyzed. The secondary flow distribution of the fluid i...The flow characteristics of shell-side fluid in the tube-and-shell heat exchangers with trisection helical baffles with 35° inclined angles are numerically analyzed. The secondary flow distribution of the fluid in the shell-side channel is focused on. The results on meridian planes indicate that in the shell-side channel, the center part of fluid has an outward tendency because of the centrifugal force, and the peripheral region fluid has an inward tendency under the centripetal force. So in a spiral cycle, the fluid is divided into the upper and lower beams of streamlines, at the same time the Dean vortices are formed near the left baffle, and then the fluid turns to centripetal flow near the right baffle. Finally the two beams of streamlines merge in the main flow. The results of a number of parallel slices between two parallel baffles with the same sector in a swirl cycle also show the existence of the secondary flow and some backward flows at the V-gaps of the adjacent baffles. The secondary flows have a positive effect on mixing fluid by promoting the momentum and mass exchange between fluid particles near the tube wall and in the main stream, and thus they will enhance the heat transfer of the helix heat exchanger.展开更多
Substance flow analysis was applied to analyzing the lead emissions in 2010. It turns out that in 2010, for every 1 kg of lead consumed, 0.48 kg lead is lost into the environment. The emissions in 2010 were estimated ...Substance flow analysis was applied to analyzing the lead emissions in 2010. It turns out that in 2010, for every 1 kg of lead consumed, 0.48 kg lead is lost into the environment. The emissions in 2010 were estimated to be 1.89×10^6 t, which were mainly from use （39.20%） and waste management＆recycling （33.13%）. The accumulative lead in 1960-2010 from the anthropogenic flow was estimated and the results show that the total accumulative lead in this period amounted to 19.54×10^6 t, which was equivalent to 14.26 kg and 2.04 g/m^2 at the present population and territory.展开更多
The metabolism of copper and arsenic in a copper pyrometallurgy process was studied through substance flow analysis method.The mass balance accounts and substance flow charts of copper and arsenic were established,ind...The metabolism of copper and arsenic in a copper pyrometallurgy process was studied through substance flow analysis method.The mass balance accounts and substance flow charts of copper and arsenic were established,indicators including direct recovery,waste recycle ratio,and resource efficiency were used to evaluate the metabolism efficiency of the system.The results showed that,the resource efficiency of copper was 97.58%,the direct recovery of copper in smelting,converting,and refining processes was 91.96%,97.13%and 99.47%,respectively.Meanwhile,for producing 1 t of copper,10 kg of arsenic was carried into the system,with the generation of 1.07 kg of arsenic in flotation tailing,8.50 kg of arsenic in arsenic waste residue,and 0.05 kg of arsenic in waste water.The distribution and transformation behaviors of arsenic in the smelting,converting,and refining processes were also analyzed,and some recommendations for improving copper resource efficiency and pollution control were proposed based on substance flow analysis.展开更多
The existing research of the flow behavior in emitter micro-channels mainly focuses on the single-phase flow behavior.And the recent micro-particle image velocimetry（PIV） experimental research on the flow characteri...The existing research of the flow behavior in emitter micro-channels mainly focuses on the single-phase flow behavior.And the recent micro-particle image velocimetry（PIV） experimental research on the flow characteristics in various micro-channels mainly focuses on the single-phase fluid flow.However,using an original-size emitter prototype to perform the experiments on the two-phase flow characteristics of the labyrinth channels is seldom reported.In this paper,the practical flow of water,mixed with sand escaped from filtering,in the labyrinth channel,is investigated.And some research work on the clogging mechanism of the labyrinth channel＇s structure is conducted.Computational fluid dynamics（CFD） analysis has been performed on liquid-solid two-phase flow in labyrinth-channel emitters.Based on flow visualization technology-micro-PIV,the flow in labyrinth channel has been photographed and recorded.The path line graph and velocity vector graph are obtained through the post-treatment of experimental results.The graphs agree well with CFD analysis results,so CFD analysis can be used in optimal design of labyrinth-channel emitters.And the optimized anti-clogging structures of the rectangular channel and zigzag channel have been designed here.The CFD numerical simulation and the micro-PIV experiments analysis on labyrinth-channel emitter,make the ＂black box＂ of the flow behavior in the emitter channel broken.Furthermore,the proposed research promotes an advanced method to evaluate the emitter＇s performance and can be used to conducting the optimal design of the labyrinth-channel emitters.展开更多
Sulfur flow for new generation steel manufacturing process is analyzed by the method of material flow analysis, and measures for SO2 emission reduction are put forward as assessment and target intervention of the resu...Sulfur flow for new generation steel manufacturing process is analyzed by the method of material flow analysis, and measures for SO2 emission reduction are put forward as assessment and target intervention of the results. The results of sulfur flow analysis indicate that 90 % of sulfur comes from fuels. Sulfur finally discharges from the steel manufacturing route in various steps, and the main point is BF and BOF slag desulfurization. In sintering process, the sulfur is removed by gasification, and sintering process is the main source of SO2 emission. The sulfur content of coke oven gas （COG） is an important factor affecting SO2 emission. Therefore, SO2 emission reduction should be started from the optimization and integration of steel manufacturing route, sulfur burden should be reduced through energy saving and consumption reduction, and the sulfur content of fuel should be controlled. At the same time, BF and BOF slag desulfurization should be optimized further and coke oven gas and sintering exhausted gas desulfurization should be adopted for SO2 emission reduction and reuse of resource, to achieve harmonic coordination of economic, social, and environmental effects for sustainable development.展开更多
Submerged horizontal plate can be considered as a new concept breakwater. In order to reveal the wave elimination mechanism of this type breakwater, boundary element method is utilized to investigate the velocity fiel...Submerged horizontal plate can be considered as a new concept breakwater. In order to reveal the wave elimination mechanism of this type breakwater, boundary element method is utilized to investigate the velocity field around plate carefully. The flow field analysis shows that the interaction between incident wave and reverse flow caused by submerged plate will lead to the formation of wave elimination area around both sides of the plate. The velocity magnitude of flow field has been reduced and this is the main reason of wave elimination.展开更多
Increase of sewage sludge(SS)has led to the construction of more incineration plants,exacerbating to the production of SS incineration residues.However,few studies have considered the mass balance of elements in large...Increase of sewage sludge(SS)has led to the construction of more incineration plants,exacerbating to the production of SS incineration residues.However,few studies have considered the mass balance of elements in large-scale SS incineration plants,affecting the residues treatment and utilization.In this study,flow analysis was conducted for major and trace elements in the SS,the fly ash(sewage sludge ash,SSA)and bottom ash from two large-scale SS incineration plants.The elemental characteristics were compared with those of coal fly ash(CFA),and air pollution control residues from municipal solid waste incineration(MSWIA),as well as related criteria.The results showed that the most abundant major element in SSA was Si,ranging from 120 to 240 g/kg,followed by Al(76–348 g/kg),Ca(26–113 g/kg),Fe(35–80 g/kg),and P(26–104 g/kg),and the trace elements were mainly Zn,Ba,Cu,and Mn.Not all the major elements were derived from SS.Most trace elements in the SS incineration residues accounted for 82.4%–127%of those from SS,indicating that SS was the main source of trace elements.The partitioning of heavy metals in the SS incineration residues showed that electrostatic precipitator ash or cyclone ash with high production rates were the major pollutant sinks.The differences in some major and trace elements could be indicators to differentiate SSA from CFA and MSWIA.Compared with related land criteria,the pollutants in SSA should not be ignored during disposal and utilization.展开更多
With the structure of two air gaps and two rotors, the electromagnetic continuously variable transmission（EMCVT） is a novel power-split continuously variable transmission（CVT）. There are two kinds of power flowing...With the structure of two air gaps and two rotors, the electromagnetic continuously variable transmission（EMCVT） is a novel power-split continuously variable transmission（CVT）. There are two kinds of power flowing through the EMCVT, one is mechanical power and the other is electric power. In the mean time, there are three power ports in the EMCVT, one is the outer rotor named mechanical power port and the other two are the inner rotor and the stator named electric power ports. The mechanical power port is connected to the driving wheels through the final gear and the electric ports are connected to the batteries through the transducers. The two kinds of power are coupled on the outer rotor of the EMCVT. The EMCVT can be equipped on the conventional vehicle being regarded as the CVT and it also can be equipped on the hybrid electric vehicle（HEV） as the multi-energy sources assembly. The power flows of these two kinds of applications are analysed. The back electromotive force（EMF） equations are illatively studied and so the dynamic mathematic model is theorized. In order to certify the feasibility of the above theories, three simulations are carried out in allusion to the above two kinds of mentioned applications of the EMCVT and a five speed automatic transmission（AT） vehicle. The simulation results illustrate that the efficiency of the EMCVT vehicles is higher than that of the AT vehicle owed to the optimized operation area of the engine. Hence the fuel consumption of the EMCVT vehicles is knock-down.展开更多
Three-dimensional flow field of turbine in torque converter is simulated by numerical calculation in order to improve the performance of torque converter. Calculation model of a torque converter is presented based on ...Three-dimensional flow field of turbine in torque converter is simulated by numerical calculation in order to improve the performance of torque converter. Calculation model of a torque converter is presented based on the mixing-plane technology. In the calculation of flow field, the 3D N-S equations are separated by finite-volume method and solved by semi-implicit method for pressure-linked equations（SIMPLE）. Based on flow field calculation, the flow field of turbine is simulated. The velocity and pressure in the flow field of turbine are analyzed. The external performance of the torque converter is also calculated. Results of flow simulation show that there are secondary flow, off flow and velocity gradient in turbine passage. The validity of numerical simulation is verified by comparing the results of numerical simulation with experiment data.展开更多
The chemiluminescence reactions between lucigenin and reductants such as Mo(LII),V( II), U(III), W(III), Cr(II), Ti(III) and Fe( II), which were produced on-line by passing Mo(VI),V(V),U(VI), W(VI), Cr(VI,III),Ti(IV) ...The chemiluminescence reactions between lucigenin and reductants such as Mo(LII),V( II), U(III), W(III), Cr(II), Ti(III) and Fe( II), which were produced on-line by passing Mo(VI),V(V),U(VI), W(VI), Cr(VI,III),Ti(IV) and Fe(III) through a micro Jones column, are studied in detail. Results show that the reactions can be used directly for the determination of these substances. The mechanism of the reactions is also investigated.展开更多
Several methods for analysis of dissolved total phosphorus in seawater were reviewed. Discussions were focused on UVirradiation and persulphate oxidation methods which are the most popular dissolved organic phosphorus...Several methods for analysis of dissolved total phosphorus in seawater were reviewed. Discussions were focused on UVirradiation and persulphate oxidation methods which are the most popular dissolved organic phosphorus determinationmethods presently. The compounds used for the phosphorus recovery test were categorized into three groups accordingto their chemical structure. It was found that low power UV irradiation can decompose POC or PC bonds efficientlybut may be inefficient for POP bonds. Heating-bath in acid condition is useful for decomposing POP bonds. Usingthe continuous flow analysis system (Auto-analyzer II), UV digestion and heating-bath, series experiments were carriedout based on the above analysis. Eleven model compounds were employed for the phosphorus recovery test and thefactors influencing the decomposition efficiency of dissolved compounds containing phosphorus were clarified. Finally,the optimal design for determination of dissolved total phosphorus in seawater based on the routine continuous flowanalysis system was presented. For the organic mono-phosphate, the recovery is more than 90% and a recovery of33%~51% was obtained for inorganic or organic polyphosphates. Up to now, this is the highest decompositionefficiency for dissolved phosphorus based on the continuous flow analysis system.展开更多
Lactate dehydrogenase (LDH) release test, 3 H-thymidine (3 H-TdR) and 3 H-leucine (3 H-Leu) incoopration tests and flow cytometric analysis (FCM) of cell cycle were empoyed to elucidate cellular and molecular mechanis...Lactate dehydrogenase (LDH) release test, 3 H-thymidine (3 H-TdR) and 3 H-leucine (3 H-Leu) incoopration tests and flow cytometric analysis (FCM) of cell cycle were empoyed to elucidate cellular and molecular mechanism of nitrofen-induced toxicity in cultured keratinocytes.The results showed that cell morphologic damages were observed after exposure to 1.0 mmol/L and 10.0 mmol/L nitrofen. LDH release increased in a dose- and time-dependent manner. Depressions in 3H -TdR and 3 H-Leu incorpration were found even at 0.01 mmol/L, and increased with the exposure dose. Cell cycle was analyzed from the DNA- histogram with propidium iodde stain. The results showed that there was no pronounced alteration in cell cycle after cells exposed to 0.01 and 0.1 mmol/L nitrofen. At dose of 1.0 mmol/L, S phase cells increased 2 times of that of control. With the increase of dose, G2/M phase cells became to increase about 5 times of that of the control. At 1 .0 mmol/L, time course of cell cycle after exposure was observed. At the beginning of exposure, cells in S phase and G2/M phase were about 8 .7 % and 11 %. Following 24 h incubation with nitrofen, cells in S phase increased to 18.0% with almost no change in G2/M. 72 h after exposure, G2/M phase cells increased to 63 .3%. The forve results demonstrated that S phase and G2/M phase blockage in cultured keratinocytes after exposed to nitrofen seems of importance in the mechanism of nitrofen-induced toxicity.展开更多
Poly（pheniothiazine） films were prepared on a porous carbon felt（CF） electrode surface by an electrooxidative polymerization of three phenothiazine derivatives（i.e.,Tthionine（TN）,Toluidine Blue（TB） and Methyl...Poly（pheniothiazine） films were prepared on a porous carbon felt（CF） electrode surface by an electrooxidative polymerization of three phenothiazine derivatives（i.e.,Tthionine（TN）,Toluidine Blue（TB） and Methylene Blue（MB）） from 0.1 mol/L phosphate buffer solution（pH 7.0）.Among the three phenothiazies,the poly（TB） film-modified CF exhibited an excellent electrocatalytic activity for the oxidation of nicotinamide adenine dinucleotide reduced form（NADH） at ＋0.2 V vs.Ag/AgCl.The poly（TB） film-modified CF was successfully used as working electrode unit of highly sensitive amperometric flow-through detector for NADH.The peak currents（peak heights） were almost unchanged,irrespective of a carrier flow rate ranging from 2.0 to 4.1 mL/min,resulting in the measurement of NADH（ca.30 samples/hr） at 4.1 mL/min.The peak current responses of NADH showed linear relationship over the concentration range from 1 to 30 μmol/L（sensitivity：0.318 μA/（μmol/L）;correlation coefficient：0.997）.The lower detection limit was found to be 0.3 μmol/L（S/N = 3）.展开更多
That flow is the common feature of substance flow and fluid flow is the viewpoint emphasized in the paper. Some notes on fluid mechanics, including the two approaches of fluid flow description, were given. The concept...That flow is the common feature of substance flow and fluid flow is the viewpoint emphasized in the paper. Some notes on fluid mechanics, including the two approaches of fluid flow description, were given. The concepts of the chain and the chain group of product life cycles, which are essential for understanding the specific features of substance flow, were advanced. Taking the specific feature of substance flow into consideration, on the analogy of the two approaches in fluid mechanics, two approaches of substance flow analysis, i.e. L method and E model, were formulated. Illustrative models of steady and unsteady substance flow were sketched by both methods, and comparison between them was made in general.展开更多
A dynamic transient flow analysis method considering complex factors such as the cyclic injection and production history in a gas field storage facility was established in view of the limitations of the existing metho...A dynamic transient flow analysis method considering complex factors such as the cyclic injection and production history in a gas field storage facility was established in view of the limitations of the existing methods for transient flow analysis and the characteristics of the injection-production operation of strongly heterogeneous gas reservoirs, and the corresponding theoretical charts were drawn. In addition, an injection-production dynamic transient flow analysis model named "three points and two stages" suitable for an underground gas storage(UGS) well with alternate working conditions was proposed. The "three points" refer to three time points during cyclic injection and production, namely, the starting point of gas injection for UGS construction, the beginning and ending points of the injection-production analysis stage;and the "two stages" refer to historical flow stage and injection-production analysis stage. The study shows that the dimensionless pseudo-pressure and dimensionless pseudo-pressure integral curves of UGS well flex downward in the early stage of the injection and production process, and the dimensionless pseudo-pressure integral derivative curve is convex during the gas production period and concave during the gas injection period, and the curves under different flow histories have atypical features. The new method present in this paper can analyze transient flow of UGS accurately. The application of this method to typical wells in Hutubi gas storage shows that the new method can fit the pressure history accurately, and obtain reliable parameters and results.展开更多
基金supported by the National Natural Science Foundation of China(Nos.71671187,71874210,71633006)the Natural Science Foundation of Hunan Province,China(No.2024JJ6539)+1 种基金the National Social Science Fund of China(No.22&ZD098)the Social Sciences Fund of Hunan Province,China(No.24YBQ138)。
文摘From a life cycle perspective,the material flow analysis is utilized to investigate the lithium material flows in international trade from 2000 to 2019.The results reveal that at the global level,the total volume of lithium trade grew rapidly,reaching 121116 t in 2019.Lithium trade was dominated by lithium minerals,lithium carbonate and lithium hydroxide rather than final lithium products,indicating an immaturity in global lithium industry.At the intercontinental level,Asia’s import trade and Oceania’s export trade led the world,accounting for 81.22%and 39.68%,respectively.At the national level,China,Japan and Korea became the main importers,while Chile and Australia were the main exporters.In addition,China’s trade volume far exceeded that of the United States.China’s exports were dominated by lithium-ion batteries,while the United States mainly imported lithium-ion batteries,proving that the development of China’s lithium industry was relatively faster.
基金supported by the Natural Science Foundation of Fujian Province(No.2020J06008)for Distinguished Young Scholarsthe Fujian Provincial Central Guided Local Science and Technology Development Special Project(No.2022L3078).
文摘The occurrence of geogenic arsenic(As)in groundwater is a global public health concern.However,there remain large gaps in groundwater As data,making it difficult to identify non-compliant domestic wells,partly due to lack of low-cost methods capable of rapid As analysis.Therefore,the development of high through-put and reliable on-site determination methods for inorganic As is essential.Herein,a portable automated analyzer was developed for the determination of arsenite(As(Ⅲ)),arsenate(As(Ⅴ))and phosphate in As contaminated groundwater based on a previously adapted method for molybdenum blue spectrophotometry.After the optimization of the chemical reactions and flow manifold,the system demonstrated a high sample through-put(4.8/h for As(Ⅲ),As(Ⅴ)and phosphate analysis),allowing this system to screen 125 samples in 24 h.Other advantages include low operational costs(0.3 CNY per sample),appropriate sensitivity for contaminated groundwater(detection limits of 4.7μg/L,8.3μg/L and 5.4μg/L for As(Ⅲ),As(Ⅴ)and phosphate,respectively),good linearity(R^(2)>0.9996 at As concentrations up to 1600μg/L)and high precision(relative standard deviations of 3.5% and 2.8% for As(Ⅲ)and As(Ⅴ),respectively).The portable system was successfully used for As speciation analysis in 5 groundwater samples collected from multi-level wells at Yinchuan Plain,northwestern China,with total As concentrations ranging from 75.7 to 295.0μg/L,independently assessing As speciation,providing a promising novel method for the rapid on-site screening of As in tens of millions of domestic wells worldwide.
基金funded by Key Project of Education and Teaching Reform and Research at Beijing Institute of Petrochemical Technology(ZD20200508).
文摘This study assesses the potential and benefits of reducing plastic consumption at the institutional level by taking the Beijing Institute of Petrochemical Technology(BIPT)in China as the case.By tracking the plastic material flow on the BIPT campus,we provide insights into the efforts required to achieve a plastic-free campus.A mixed-methods approach was employed,encompassing material flow analysis,quantitative analysis of influencing factors,examination of best practices in universities,and market price-based valuation of plastic reduction.The main conclusions are as follows:(1)Each student consumed an average of 9.2 kg of plastics for daily use on BIPT campus in the base year of 2020,with campus canteens,off-campus cafés,and shops(offline and online)contributing to 36%,31%and 30%respectively.(2)BIPT has a reduction potential of 45%,equivalent to 4.1 kg per student annually,yielding benefits of 45 RMB from savings in oil material and production energy,avoiding plastic waste,and reducing carbon emission.(3)If all global tertiary institutions set a target of reducing plastics by 4.1 kg per student,1.94 Mt of plastics could be avoided by 2035.(4)Greater reductions and benefits could be achieved if tertiary institutions extend their efforts across all campus activities,with substantial indirect and long-term contributions ranging from more sustainable campus management to fostering a transition towards a green economy.These findings highlight that plastic-free initiatives require contextual construction and environmental education both on and off campus.
基金Supported by National Key Research and Development Program of China(Grant Nos.2023YFC2809304,2022YFC2805904)National Natural Science Foundation of China(Grant No.52275106)Special Project for the Construction of Innovative City in Xiangtan of China(Grant No.ZX-ZD20221005).
文摘To accurately acquire deep-sea live biological samples,a hydraulic suction macro-biological pressure-retaining sampler(HSMPS)was designed to achieve active capture of seafloor biological by a suction pump.The complex flow fields of deep-sea biologicals at three different locations were simulated.The deep-sea biologicals cause the flow field pressure and velocity to rise at different locations of the sampler,and the magnitude of the rise varies at different locations.The internal flow properties of the sampler were analyzed for different pumping flow rates the sampler.When the flow rate of the sampler pump was greater than 14 m3/h,the velocity of the inlet of the inflow area was greater than the limiting velocity of the deep-sea biologicals.The pumping test of deep-sea biologicals pumping sampler was carried out in the laboratory,and the test results were basically consistent with the simulation analysis.In order to balance the deep-sea biologicals damage and escape rate,the pumping flow of the sampler should be controlled between 14 and 16 m3/h.The test results provide a theoretical basis for the design of deep-sea biologicals sampling equipment.
基金supported by Chongqing Natural Science Foundation Innovation and Development Joint Fund(CSTB2023NSCQ-LZX0095)Chongqing Natural Science Foundation General Project(CSTB2025NSCQ-GPX0955)+3 种基金Science and Technology Research Program of Chongqing Municipal Education Commission of China(KJQN202401157)The Open and Innovation Fund of Hubei Three Gorges Laboratory(SK250005)The Key Laboratory of Manufacturing and Application of Intelligent Well Control for Oil and Gas Production and Transportation of Luzhou(2024LZOGB-05)postgraduate Innovation Project of Chongqing University of Technology(CYS240709).
文摘With the acceleration of industrialization and urbanization,ammonia nitrogen pollution in water bodies has become increasingly severe,making the development of efficient and low-consumption wastewater treatment tech-nologies highly significant.This study employs three-dimensional computational fluid dynamics(CFD)to investigate the cavitation mechanisms and flow field characteristics in a novel jet impingement-negative pressure ammonia removal reactor.The simulation,validated by experimental pressure data with a high degree of consistency,utilizes the Mixture model,the Realizable k-εturbulence model,and the Schnerr-Sauer cavitation model.The results demonstrate that the flow velocity undergoes a substantial acceleration within the orifice nozzle,triggering a dramatic pressure drop from an inlet value of approximately 1.17 MPa to below the saturated vapor pressure,reaching as low as−109 kPa,which induces intense cavitation.Cavitation bubbles primarily originate on the inner wall of the nozzle,with the vapor volume fraction peaking at about 0.42 within the orifice.A strong positive correlation was observed between the local vapor fraction and the flow velocity,indicating that cavitation enhances jet intensity.Furthermore,vortex structures near the wall and within the jacket sustain low-pressure zones,facilitating continuous cavitation and efficient mixing.This study quantitatively elucidates the cavitation dynamics and its interplay with the flow field,providing a solid theoretical and numerical basis for optimizing the reactor design to enhance ammonia removal efficiency.
基金The National Natural Science Foundation of China (No.50976022)the National Key Technology R&D Program of China during the 11th Five-Year Plan Period (No.2008BAJ12B02)
文摘The flow characteristics of shell-side fluid in the tube-and-shell heat exchangers with trisection helical baffles with 35° inclined angles are numerically analyzed. The secondary flow distribution of the fluid in the shell-side channel is focused on. The results on meridian planes indicate that in the shell-side channel, the center part of fluid has an outward tendency because of the centrifugal force, and the peripheral region fluid has an inward tendency under the centripetal force. So in a spiral cycle, the fluid is divided into the upper and lower beams of streamlines, at the same time the Dean vortices are formed near the left baffle, and then the fluid turns to centripetal flow near the right baffle. Finally the two beams of streamlines merge in the main flow. The results of a number of parallel slices between two parallel baffles with the same sector in a swirl cycle also show the existence of the secondary flow and some backward flows at the V-gaps of the adjacent baffles. The secondary flows have a positive effect on mixing fluid by promoting the momentum and mass exchange between fluid particles near the tube wall and in the main stream, and thus they will enhance the heat transfer of the helix heat exchanger.
基金Project (41171361) supported by the National Natural Science Foundation of China
文摘Substance flow analysis was applied to analyzing the lead emissions in 2010. It turns out that in 2010, for every 1 kg of lead consumed, 0.48 kg lead is lost into the environment. The emissions in 2010 were estimated to be 1.89×10^6 t, which were mainly from use （39.20%） and waste management＆recycling （33.13%）. The accumulative lead in 1960-2010 from the anthropogenic flow was estimated and the results show that the total accumulative lead in this period amounted to 19.54×10^6 t, which was equivalent to 14.26 kg and 2.04 g/m^2 at the present population and territory.
基金financial supports from the National Key R&D Program of China(No.2019YFC1907400)the National Natural Science Foundation of China(Nos.51904351,51620105013)。
文摘The metabolism of copper and arsenic in a copper pyrometallurgy process was studied through substance flow analysis method.The mass balance accounts and substance flow charts of copper and arsenic were established,indicators including direct recovery,waste recycle ratio,and resource efficiency were used to evaluate the metabolism efficiency of the system.The results showed that,the resource efficiency of copper was 97.58%,the direct recovery of copper in smelting,converting,and refining processes was 91.96%,97.13%and 99.47%,respectively.Meanwhile,for producing 1 t of copper,10 kg of arsenic was carried into the system,with the generation of 1.07 kg of arsenic in flotation tailing,8.50 kg of arsenic in arsenic waste residue,and 0.05 kg of arsenic in waste water.The distribution and transformation behaviors of arsenic in the smelting,converting,and refining processes were also analyzed,and some recommendations for improving copper resource efficiency and pollution control were proposed based on substance flow analysis.
基金supported by National Natural Science Foundation of China (Grant Nos. 50675172,50975227)Foundation for the Author of National Excellent Doctoral Dissertation of China (Grant No.FANEDD200740)National Hi-tech Research and Development of China (863 Program,Grant No. 2011AA100507-04)
文摘The existing research of the flow behavior in emitter micro-channels mainly focuses on the single-phase flow behavior.And the recent micro-particle image velocimetry（PIV） experimental research on the flow characteristics in various micro-channels mainly focuses on the single-phase fluid flow.However,using an original-size emitter prototype to perform the experiments on the two-phase flow characteristics of the labyrinth channels is seldom reported.In this paper,the practical flow of water,mixed with sand escaped from filtering,in the labyrinth channel,is investigated.And some research work on the clogging mechanism of the labyrinth channel＇s structure is conducted.Computational fluid dynamics（CFD） analysis has been performed on liquid-solid two-phase flow in labyrinth-channel emitters.Based on flow visualization technology-micro-PIV,the flow in labyrinth channel has been photographed and recorded.The path line graph and velocity vector graph are obtained through the post-treatment of experimental results.The graphs agree well with CFD analysis results,so CFD analysis can be used in optimal design of labyrinth-channel emitters.And the optimized anti-clogging structures of the rectangular channel and zigzag channel have been designed here.The CFD numerical simulation and the micro-PIV experiments analysis on labyrinth-channel emitter,make the ＂black box＂ of the flow behavior in the emitter channel broken.Furthermore,the proposed research promotes an advanced method to evaluate the emitter＇s performance and can be used to conducting the optimal design of the labyrinth-channel emitters.
基金Item Sponsored by National Natural Science Foundation of China(50334020)
文摘Sulfur flow for new generation steel manufacturing process is analyzed by the method of material flow analysis, and measures for SO2 emission reduction are put forward as assessment and target intervention of the results. The results of sulfur flow analysis indicate that 90 % of sulfur comes from fuels. Sulfur finally discharges from the steel manufacturing route in various steps, and the main point is BF and BOF slag desulfurization. In sintering process, the sulfur is removed by gasification, and sintering process is the main source of SO2 emission. The sulfur content of coke oven gas （COG） is an important factor affecting SO2 emission. Therefore, SO2 emission reduction should be started from the optimization and integration of steel manufacturing route, sulfur burden should be reduced through energy saving and consumption reduction, and the sulfur content of fuel should be controlled. At the same time, BF and BOF slag desulfurization should be optimized further and coke oven gas and sintering exhausted gas desulfurization should be adopted for SO2 emission reduction and reuse of resource, to achieve harmonic coordination of economic, social, and environmental effects for sustainable development.
基金supported by the Fundamental Research Funds for the Dalian University of Technology(Grant No.DUT10LK43)the National Key Basic Research Program of China(Grant No.2013CB036101)
文摘Submerged horizontal plate can be considered as a new concept breakwater. In order to reveal the wave elimination mechanism of this type breakwater, boundary element method is utilized to investigate the velocity field around plate carefully. The flow field analysis shows that the interaction between incident wave and reverse flow caused by submerged plate will lead to the formation of wave elimination area around both sides of the plate. The velocity magnitude of flow field has been reduced and this is the main reason of wave elimination.
基金supported by the Major Science and Technology Program for Water Pollution Control and Treatment(No.2017ZX07202005)National Natural Science Foundation of China(No.21577102)。
文摘Increase of sewage sludge(SS)has led to the construction of more incineration plants,exacerbating to the production of SS incineration residues.However,few studies have considered the mass balance of elements in large-scale SS incineration plants,affecting the residues treatment and utilization.In this study,flow analysis was conducted for major and trace elements in the SS,the fly ash(sewage sludge ash,SSA)and bottom ash from two large-scale SS incineration plants.The elemental characteristics were compared with those of coal fly ash(CFA),and air pollution control residues from municipal solid waste incineration(MSWIA),as well as related criteria.The results showed that the most abundant major element in SSA was Si,ranging from 120 to 240 g/kg,followed by Al(76–348 g/kg),Ca(26–113 g/kg),Fe(35–80 g/kg),and P(26–104 g/kg),and the trace elements were mainly Zn,Ba,Cu,and Mn.Not all the major elements were derived from SS.Most trace elements in the SS incineration residues accounted for 82.4%–127%of those from SS,indicating that SS was the main source of trace elements.The partitioning of heavy metals in the SS incineration residues showed that electrostatic precipitator ash or cyclone ash with high production rates were the major pollutant sinks.The differences in some major and trace elements could be indicators to differentiate SSA from CFA and MSWIA.Compared with related land criteria,the pollutants in SSA should not be ignored during disposal and utilization.
基金supported by National Natural Science Foundation of China(No.50605020)Guangdong Provincial Science and Technology Project of China(No.2006A10501001).
文摘With the structure of two air gaps and two rotors, the electromagnetic continuously variable transmission（EMCVT） is a novel power-split continuously variable transmission（CVT）. There are two kinds of power flowing through the EMCVT, one is mechanical power and the other is electric power. In the mean time, there are three power ports in the EMCVT, one is the outer rotor named mechanical power port and the other two are the inner rotor and the stator named electric power ports. The mechanical power port is connected to the driving wheels through the final gear and the electric ports are connected to the batteries through the transducers. The two kinds of power are coupled on the outer rotor of the EMCVT. The EMCVT can be equipped on the conventional vehicle being regarded as the CVT and it also can be equipped on the hybrid electric vehicle（HEV） as the multi-energy sources assembly. The power flows of these two kinds of applications are analysed. The back electromotive force（EMF） equations are illatively studied and so the dynamic mathematic model is theorized. In order to certify the feasibility of the above theories, three simulations are carried out in allusion to the above two kinds of mentioned applications of the EMCVT and a five speed automatic transmission（AT） vehicle. The simulation results illustrate that the efficiency of the EMCVT vehicles is higher than that of the AT vehicle owed to the optimized operation area of the engine. Hence the fuel consumption of the EMCVT vehicles is knock-down.
基金This project is supported by National Natural Science Foundation of China (No. 50175042).
文摘Three-dimensional flow field of turbine in torque converter is simulated by numerical calculation in order to improve the performance of torque converter. Calculation model of a torque converter is presented based on the mixing-plane technology. In the calculation of flow field, the 3D N-S equations are separated by finite-volume method and solved by semi-implicit method for pressure-linked equations（SIMPLE）. Based on flow field calculation, the flow field of turbine is simulated. The velocity and pressure in the flow field of turbine are analyzed. The external performance of the torque converter is also calculated. Results of flow simulation show that there are secondary flow, off flow and velocity gradient in turbine passage. The validity of numerical simulation is verified by comparing the results of numerical simulation with experiment data.
文摘The chemiluminescence reactions between lucigenin and reductants such as Mo(LII),V( II), U(III), W(III), Cr(II), Ti(III) and Fe( II), which were produced on-line by passing Mo(VI),V(V),U(VI), W(VI), Cr(VI,III),Ti(IV) and Fe(III) through a micro Jones column, are studied in detail. Results show that the reactions can be used directly for the determination of these substances. The mechanism of the reactions is also investigated.
基金The research was supported by the National Basic Research Program(“973”Program)of China under contract No.2002CB412405the Key Science and Technology Plan of the Ministry of Education of China under contract No.[2000]156-00079the Joint Sino-German Project under contract No.03F0189A.
文摘Several methods for analysis of dissolved total phosphorus in seawater were reviewed. Discussions were focused on UVirradiation and persulphate oxidation methods which are the most popular dissolved organic phosphorus determinationmethods presently. The compounds used for the phosphorus recovery test were categorized into three groups accordingto their chemical structure. It was found that low power UV irradiation can decompose POC or PC bonds efficientlybut may be inefficient for POP bonds. Heating-bath in acid condition is useful for decomposing POP bonds. Usingthe continuous flow analysis system (Auto-analyzer II), UV digestion and heating-bath, series experiments were carriedout based on the above analysis. Eleven model compounds were employed for the phosphorus recovery test and thefactors influencing the decomposition efficiency of dissolved compounds containing phosphorus were clarified. Finally,the optimal design for determination of dissolved total phosphorus in seawater based on the routine continuous flowanalysis system was presented. For the organic mono-phosphate, the recovery is more than 90% and a recovery of33%~51% was obtained for inorganic or organic polyphosphates. Up to now, this is the highest decompositionefficiency for dissolved phosphorus based on the continuous flow analysis system.
文摘Lactate dehydrogenase (LDH) release test, 3 H-thymidine (3 H-TdR) and 3 H-leucine (3 H-Leu) incoopration tests and flow cytometric analysis (FCM) of cell cycle were empoyed to elucidate cellular and molecular mechanism of nitrofen-induced toxicity in cultured keratinocytes.The results showed that cell morphologic damages were observed after exposure to 1.0 mmol/L and 10.0 mmol/L nitrofen. LDH release increased in a dose- and time-dependent manner. Depressions in 3H -TdR and 3 H-Leu incorpration were found even at 0.01 mmol/L, and increased with the exposure dose. Cell cycle was analyzed from the DNA- histogram with propidium iodde stain. The results showed that there was no pronounced alteration in cell cycle after cells exposed to 0.01 and 0.1 mmol/L nitrofen. At dose of 1.0 mmol/L, S phase cells increased 2 times of that of control. With the increase of dose, G2/M phase cells became to increase about 5 times of that of the control. At 1 .0 mmol/L, time course of cell cycle after exposure was observed. At the beginning of exposure, cells in S phase and G2/M phase were about 8 .7 % and 11 %. Following 24 h incubation with nitrofen, cells in S phase increased to 18.0% with almost no change in G2/M. 72 h after exposure, G2/M phase cells increased to 63 .3%. The forve results demonstrated that S phase and G2/M phase blockage in cultured keratinocytes after exposed to nitrofen seems of importance in the mechanism of nitrofen-induced toxicity.
基金financially supported in part by the Open Research Center Project of the Ministry of Education,Science and Culture of Japan
文摘Poly（pheniothiazine） films were prepared on a porous carbon felt（CF） electrode surface by an electrooxidative polymerization of three phenothiazine derivatives（i.e.,Tthionine（TN）,Toluidine Blue（TB） and Methylene Blue（MB）） from 0.1 mol/L phosphate buffer solution（pH 7.0）.Among the three phenothiazies,the poly（TB） film-modified CF exhibited an excellent electrocatalytic activity for the oxidation of nicotinamide adenine dinucleotide reduced form（NADH） at ＋0.2 V vs.Ag/AgCl.The poly（TB） film-modified CF was successfully used as working electrode unit of highly sensitive amperometric flow-through detector for NADH.The peak currents（peak heights） were almost unchanged,irrespective of a carrier flow rate ranging from 2.0 to 4.1 mL/min,resulting in the measurement of NADH（ca.30 samples/hr） at 4.1 mL/min.The peak current responses of NADH showed linear relationship over the concentration range from 1 to 30 μmol/L（sensitivity：0.318 μA/（μmol/L）;correlation coefficient：0.997）.The lower detection limit was found to be 0.3 μmol/L（S/N = 3）.
文摘That flow is the common feature of substance flow and fluid flow is the viewpoint emphasized in the paper. Some notes on fluid mechanics, including the two approaches of fluid flow description, were given. The concepts of the chain and the chain group of product life cycles, which are essential for understanding the specific features of substance flow, were advanced. Taking the specific feature of substance flow into consideration, on the analogy of the two approaches in fluid mechanics, two approaches of substance flow analysis, i.e. L method and E model, were formulated. Illustrative models of steady and unsteady substance flow were sketched by both methods, and comparison between them was made in general.
基金Supported by the CNPC Major Scientific and Technological Project(2019B-3204)PetroChina Major Scientific and Technological Project(kt2020-16-01)。
文摘A dynamic transient flow analysis method considering complex factors such as the cyclic injection and production history in a gas field storage facility was established in view of the limitations of the existing methods for transient flow analysis and the characteristics of the injection-production operation of strongly heterogeneous gas reservoirs, and the corresponding theoretical charts were drawn. In addition, an injection-production dynamic transient flow analysis model named "three points and two stages" suitable for an underground gas storage(UGS) well with alternate working conditions was proposed. The "three points" refer to three time points during cyclic injection and production, namely, the starting point of gas injection for UGS construction, the beginning and ending points of the injection-production analysis stage;and the "two stages" refer to historical flow stage and injection-production analysis stage. The study shows that the dimensionless pseudo-pressure and dimensionless pseudo-pressure integral curves of UGS well flex downward in the early stage of the injection and production process, and the dimensionless pseudo-pressure integral derivative curve is convex during the gas production period and concave during the gas injection period, and the curves under different flow histories have atypical features. The new method present in this paper can analyze transient flow of UGS accurately. The application of this method to typical wells in Hutubi gas storage shows that the new method can fit the pressure history accurately, and obtain reliable parameters and results.
