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Ligand Size Effect on PdLn Oxidative Addition with Aryl Bromide: A DFT Study
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作者 孙文晶 储伟 +1 位作者 余良军 江成发 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第2期175-179,I0001,共6页
The process and mechanism of the ligand volume controlled Pd(PR3)2 (PR3=PH3, PMe3, and PtBu3) oxidative addition with aryl bromide were investigated, using density functional theory method with the conductor-like ... The process and mechanism of the ligand volume controlled Pd(PR3)2 (PR3=PH3, PMe3, and PtBu3) oxidative addition with aryl bromide were investigated, using density functional theory method with the conductor-like screening model. Association pathway and dissocia-tion pathway were investigated by the comparison of several energies. The cleavage energy of Pd(PR3)2 complex was calculated, as well as the oxidative addition reaction barrier energy of Pd(PR3)n (n=1,2) with aryl bromide in N,N-dimethylformamide solvent. This study proved that the ligands volume possessed a great impact on the mechanism of oxidative addition: less bulky ligand palladium associated with aryl bromide via two donor ligands,but larger bulky ligand palladium coordinated via monoligand. 展开更多
关键词 Process simulation Ligand size effect Oxidative addition Cross-coupling reaction DFT method
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Effects of Ta Addition on NiTi Shape Memory Alloys 被引量:3
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作者 Jianlu MA, Jiangnan LIU+, Zhengpin WANG and Fei XUE (Dept. of Materials Science & Engineering, Xi’an Institute of Technology, Xi’an 710032, China) Kuang-Hsi WU and Zhongjie PU (Department of Mechanical Engineering, Florida International University, USA) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2000年第5期534-536,共3页
The effect of Ta addition on the martensitic transformation characteristics and the X-ray visibility on NiTi shape memory alloy have been studied in (Ni51Ti49)1-xTax system. It was found that the transformation temper... The effect of Ta addition on the martensitic transformation characteristics and the X-ray visibility on NiTi shape memory alloy have been studied in (Ni51Ti49)1-xTax system. It was found that the transformation temperatures of the Ni51Ti49 binary alloy increased drastically by an addition of 0~4 at. pet Ta, but only slightly when the concentration exceeded 4 at. pct; the addition of Ta greatly decreases the sensitivity of the martensitic transformations to the variation in the Ni-Ti ratio. The addition of Ta to the NiTi binary alloy can improve its X-ray visibility. 展开更多
关键词 NITI effects of Ta addition on NiTi Shape Memory Alloys TA
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Effects of Additional Elements on Microstructure and Precipitation Behaviour in Rapidly Solidified Al-Ti Base Alloys 被引量:3
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作者 Won-Wook Park Chul-Jin Choi and Bong-Sun You (Dept. of Materials Processing, Korea Institute of Machinery and Metals, 66 Sangnam-Dong,Changwon, Kyungnam, Korea 641-010)(To whom correspondence should be addressed) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1996年第3期195-198,共4页
Rapidly solidified Al-Ti base alloys were prepared by melt spinning at the cooling rate about 107 K/s. The melt-spun ribbons were used to observe the dricrostructures after heat treatment.In the supersaturated Al-Tl-S... Rapidly solidified Al-Ti base alloys were prepared by melt spinning at the cooling rate about 107 K/s. The melt-spun ribbons were used to observe the dricrostructures after heat treatment.In the supersaturated Al-Tl-Si alloy, age hardening occurred after 1 h anneal in the temperature range of 4000~500℃, which seems to be attributed to the precipitation of metastable Ll2- (Al,Si)3Ti phase. However. the microhardness was relatively low because of the low v/o and the insufflcient stability of precipitates. Thus. Cr was added to Al-Ti-Si alloys in order to stabilize the microstructures and to increase the v/o of precipitate5. As a result. the alIoys containing Cr were evaluated to possess the improved properties at the service temperature. 展开更多
关键词 Ti BASE Al effects of additional Elements on Microstructure and Precipitation Behaviour in Rapidly Solidified Al-Ti Base Alloys
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Effect of Respective Additions of Ga, Zr and Combined Additions of Co, Ga, Zr on Magnetic Properties of Remanence-enhanced Nd_(8.4) Fe_(87.1) B_(4.5) Alloy 被引量:1
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作者 Baozhi CUI, Xiaokai SUN, Wei LIU, Zhidong ZHANG, Dianyu GENG and Xinguo ZHAO (Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110015, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2000年第2期118-120,共3页
The effect of a partial substitution of Zr, Ga; Co and Ga; Co. Ga and Zr; respectively, for Fe on the structure and magnetic properties of Nd_8.4Fe_87.1B_4.5 alloy prepared by mechanical alloying has been studied in d... The effect of a partial substitution of Zr, Ga; Co and Ga; Co. Ga and Zr; respectively, for Fe on the structure and magnetic properties of Nd_8.4Fe_87.1B_4.5 alloy prepared by mechanical alloying has been studied in detail. It has been shown that, intrinsic coercivity μ0 H_c and maximum magnetic energy product (BH)_max increase for only Zr or Ga-containing samples, which is mainly due to the refinement of soft grains. The combined addition of Co and Ga is less effective for improving μoH_c and (BH)_max than the respective addition of Co or Ga. which may be due to the formation of CsCl-type CoGa. μoH_c and (BH)_max for combined Co, Ga. Zr-added alloy are higher than those for the combined Co, Ga-added alloy but lower than those for only Zr-containing alloy. 展开更多
关键词 ALLOY Fe Zr on Magnetic Properties of Remanence-enhanced Nd effect of Respective additions of Ga ND
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Effects of Ta Addition on Microstructure and Transformation Behavior of Ni-Ti Alloys
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作者 K.H.Wu and JL.Ma Department of Mechanical Engineering, Florida International University, Miami, FL 33174, U.S.A. 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第1期5-6,共2页
The effect of adding Ta on the changes of microstructure and Ms temperature of a dualphase shape memory alloy with compositions of (Ni51 Ti49)1 -x.Tax. and Ni50-Ti50 -g.Ta.g were systematically studied. An optical mi... The effect of adding Ta on the changes of microstructure and Ms temperature of a dualphase shape memory alloy with compositions of (Ni51 Ti49)1 -x.Tax. and Ni50-Ti50 -g.Ta.g were systematically studied. An optical microscope, SEM, X-ray diffraction and DSC were utilized in this work. The evolution of the microstructure as a function of Ta content was characterized. The variation of the Ni/Ti ratio in the NiTi phase plays an important role in the change of the Ms temperatures due to the addition of Ta. A pseudobinary NiTi-Ta phase diagram was proposed based on these results. 展开更多
关键词 Ti TA effects of Ta addition on Microstructure and Transformation Behavior of Ni-Ti Alloys
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Effect of Al Addition on the Glass-Forming Ability and Magnetic Properties of a Gd-Co Binary Amorphous Alloy
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作者 武城 丁鼎 夏雷 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第1期96-99,共4页
The glass-forming ability (CFA) and magnetic properties of the Cd50 Co50-based amorphous alloy with AI addition substitution for Co are investigated. It is found that the CFA and magneto-caloric effect of the Gd50Co... The glass-forming ability (CFA) and magnetic properties of the Cd50 Co50-based amorphous alloy with AI addition substitution for Co are investigated. It is found that the CFA and magneto-caloric effect of the Gd50Co45Al5 amorphous alloy are better than Cd50Co50 amorphous alloy. The maximum magnetic entropy change (-△ Sm^peak) and the magnetic refrigerant capacity- of the amorphous alloy under a field of 5 T are about 6.64 J·kg^-1 K^-1 and 764 J·kg^-1, respectively. The field dependence of magnetic entropy change meets the one predicted by the mean field theory, which is investigated for a better understanding of the magneto-caloric behaviors of the Gdso Co45Al5 amorphous alloy. 展开更多
关键词 of Co Gd effect of Al addition on the Glass-Forming Ability and Magnetic Properties of a Gd-Co Binary Amorphous Alloy AL on
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Effects of A1 Additions on Microstructure and Mechanical Properties of MoSi_2
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作者 Jianlin LI Dongliang JIANG and Shouhong TAN(Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1999年第6期578-580,共3页
The effects of Al additions on the microstructure and mechanical properties of MoSi2 have been studied. With the A1 additions from 2.5 wt pct to 5 wt pct, the siliceous grain boundary phase in hot pressed samples was ... The effects of Al additions on the microstructure and mechanical properties of MoSi2 have been studied. With the A1 additions from 2.5 wt pct to 5 wt pct, the siliceous grain boundary phase in hot pressed samples was eliminated because of the formation of Al2O3 particles. It was shown that Al and SiO2 reacted at 860℃. During the reaction, A1 atoms were mainly transferred to Al2O3 particles, and to some extent, diffused into MoSi2 grains. Both the toughness and strength of Al containing composites exceeded those of pure MoSi2 material. Bending strength and fracture toughness reach the highest value of 350 MPa, 4.05 MPa.m1/2, respectively, at ambient temperature when Al addition was of 3.5 wt pct. 展开更多
关键词 FIGURE MPa effects of A1 additions on Microstructure and Mechanical Properties of MoSi2
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Effect of Li and Ti Additions on Lα(Al)+Mg_2Si Pseudobinary Eutectic Reaction
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作者 Shengxu ZHAO Shunpu LI +1 位作者 Deqian ZHAO Mingxiang PAN and Xichen CHEN(Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1997年第6期487-490,共4页
Effect of Li and Ti additions on Lα(AI)+Mg2Si pseudobinary eutectic reaction in ternary Al-Mg-Si system has been investigated by thermoanalysis, directional solidification and metallographic techniques in this study.... Effect of Li and Ti additions on Lα(AI)+Mg2Si pseudobinary eutectic reaction in ternary Al-Mg-Si system has been investigated by thermoanalysis, directional solidification and metallographic techniques in this study. It has been found that Li addition causes decreasing of the volume fraction of Mg2Si, while a little amount of Ti causes to increasing, which is of a great importance to the adjustment of phase constitution and alloy properties. Doping components have little influence on the eutectic temperature. 展开更多
关键词 Si AL Mg2Si Pseudobinary Eutectic Reaction effect of Li and Ti additions on L LI Ti
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Additive mixed models to study the effect of tree age and climatic factors on stem radial growth of Eucalyptus trees 被引量:1
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作者 Sileshi F.Melesse Temesgen Zewotir 《Journal of Forestry Research》 SCIE CAS CSCD 2020年第2期463-473,共11页
The effect of tree age and climatic variables on stem radial growth of two hybrid clones of Eucalyptus was determined using longitudinal data from eastern South Africa.The stem radius of was measured weekly as the res... The effect of tree age and climatic variables on stem radial growth of two hybrid clones of Eucalyptus was determined using longitudinal data from eastern South Africa.The stem radius of was measured weekly as the response variable.In addition to tree age,average weekly temperature,solar radiation,relative humidity and wind speed were simultaneously recorded with total rainfall at the site.An additive mixed effects model that incorporates a non-parametric smooth function was used.The results of the analysis indicate that the relationship between stem radius and each of the covariates can be explained by nonlinear functions.Models that account for the effect of clone and season together with their interaction in the parametric part of the additive mixed model were also fitted.The interaction between clone and season was not significant in all cases.For analyzing the joint effect all the covariates,additive mixed models that included two or more covariates were fitted.A significant effect of tree age was found in all cases.Although tree age was the key determinant of stem radial growth,weather variables also had a significant effect that was dependent on season. 展开更多
关键词 Additive mixed effects Dendrometer trial Parametric modelling Penalized splines Weather variables
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Cobalt-catalyzed asymmetric hydrogenation of ketones:A remarkable additive effect on enantioselectivity
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作者 Tian Du Biwen Wang +2 位作者 Chao Wang Jianliang Xiao Weijun Tang 《Chinese Chemical Letters》 SCIE CAS CSCD 2021年第3期1241-1244,共4页
A chiral cobalt pincer complex,when combined with an achiral electron-rich mono-phosphine ligand,catalyzes efficient asymmetric hydrogenation of a wide range of aryl ketones,affording chiral alcohols with high yields ... A chiral cobalt pincer complex,when combined with an achiral electron-rich mono-phosphine ligand,catalyzes efficient asymmetric hydrogenation of a wide range of aryl ketones,affording chiral alcohols with high yields and moderate to excellent enantioselectivities(29 examples,up to 93%ee).Notably,the achiral mono-phosphine ligand shows a remarkable effect on the enantioselectivity of the reaction. 展开更多
关键词 COBALT Asymmetric hydrogenation KETONES Additive effect Pincer complex
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Enantioselective synthesis of 2-amino-3-nitrile-chromenes catalyzed by cinchona alkaloids:A remarkable additive effect
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作者 Yuan-Qin Zheng Chun-Feng Luan +5 位作者 Zhi-Jing Wang Yong-Qi Yao Zhi-Chuan Shi Xue-Feng Li Zhi-Gang Zhao Feng Chen 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第1期25-30,共6页
2-Amino-3-nitrile-chromenes with potential antitumor activity were constructed by a novel catalytic system. In combination with a-naphthol, quinine could effectively promote the Michael-cyclization process of malononi... 2-Amino-3-nitrile-chromenes with potential antitumor activity were constructed by a novel catalytic system. In combination with a-naphthol, quinine could effectively promote the Michael-cyclization process of malononitrile with functionalized chalcones in high yields and moderate to good enantioselectivity(up to 84% ee). It is notable that the enantioselectivity could be greatly improved when a-naphthol was employed as additive. 展开更多
关键词 Additive effect 2-Amino-3-nitrile-chromene Functionalized chalcones ENANTIOSELECTIVE
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Genetic Effect on Yield and Fiber Quality Traits of 16 Chromosome Substitution Lines in Upland Cotton
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作者 LUAN Ming-bao GUO Xiang-mo ZHANG Yong-shan YAO Jin-bo 《Agricultural Sciences in China》 CAS CSCD 2008年第11期1290-1297,共8页
Evaluation of the genetic effect on yield and fiber quality can provide useful information on cotton breeding. Sixteen CSB lines and TM-1 introduced from USDA/ARS were used as male and top-crossed with three elite cul... Evaluation of the genetic effect on yield and fiber quality can provide useful information on cotton breeding. Sixteen CSB lines and TM-1 introduced from USDA/ARS were used as male and top-crossed with three elite cultivars and the 51 F1 hybrids, 16 CSB lines, TM-1, and 3 elite cultivars were planted at the Cotton Research Institute of CAAS, Anyang, Henan Province and Xiajin, Shandong Province, China. The yield traits and fiber quality data were obtained and additive and dominance effect on each trait were measured by AD model. Boll weight takes the largest additive proration, whereas boll number takes the least additive proration. The largest and the least dominant proration for lint yield and boll weight were measured, respectively. Fiber length has the additive and dominance effect, and dominance effect was slightly more than additive effect. Larger additive and no dominance effect on uniformity, micronaire, and fiber strength were measured. Significantly, positive additive effect on boll weight of CSB06 and CSB12Sh was observed. CSB14Sh and CSB01 have significantly positive additive effect on 4 and 3 traits of fiber quality, respectively. CSB01 has the greatest dominant effect on lint yield among CSB lines. The dominant effect on fiber length of CSB lines showed positive. It is beneficial to use CSB06 and CSB12Sh as parents to improve boll size, to use CSB14Sh and CSB01 as parents to improve fiber quality. As for hybrid cotton breeding, it is reasonable using CSB01 to improve lint yield traits, and using CSB01, CSB11Sh, and CSB06 to improve fiber length. 展开更多
关键词 chromosome substitution lines in upland cotton additive genetic effect dominance genetic effect AD model
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Path analysis and estimation of additive and epistatic gene effects of barley SSD lines
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作者 Jan Bocianowski Katarzyna Górczak +2 位作者 Kamila Nowosad Wojciech Rybiński Dariusz Piesik 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2016年第9期1983-1990,共8页
In the paper presented, 99 single seed descent barley lines as well as their parental forms Roland and Apex were studied. The grain weight components and their interrelations were analyzed using simple coefficients of... In the paper presented, 99 single seed descent barley lines as well as their parental forms Roland and Apex were studied. The grain weight components and their interrelations were analyzed using simple coefficients of correlation. The direct and indirect effects of such components on grain weight per plant and 1 000-grain weight were estimated using path analysis. In the 2006 and 2007, the spike length and number of spikelets per spike were the determinants of grain weight. Genetic parameters as additive and epistasis effects were estimated for all studied traits. The results indicate the importance of both additive and epistasis gene effects of number of spikes per plant, grain weight per spike, grain number per plant and grain weight per plant in this study. 展开更多
关键词 path analysis additive effect epistasis single seed descent(SSD) barley
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Lack of an Additive Effect between the Deletions of Klf5 and Nkx3-1 in Mouse Prostatic Tumorigenesis
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作者 Changsheng Xing Xiaoying Fu +1 位作者 Xiaodong Sun Jin-Tang Dong 《Journal of Genetics and Genomics》 SCIE CAS CSCD 2013年第6期315-318,共4页
Prostate cancer is one of the most common malignancies.The development and progression of prostate cancer are driven by a series of genetic and epigenetic events including gene amplification that activates oncogenes a... Prostate cancer is one of the most common malignancies.The development and progression of prostate cancer are driven by a series of genetic and epigenetic events including gene amplification that activates oncogenes and chromosomal deletion that inactivates tumor suppressor genes.Whereas gene amplification occurs in human prostate cancer,gene deletion is more common, 展开更多
关键词 Lack of an Additive effect between the Deletions of Klf5 and Nkx3-1 in Mouse Prostatic Tumorigenesis
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Antioxidant and Immunopotentiating Effects of <i>Cordyceps </i>Mycelium Extract, Chicken Essence, and Their Combination in Experimental Models
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作者 Hoi Yan Leung Choly Tat Ming Yan Kam Ming Ko 《Chinese Medicine》 2021年第1期1-9,共9页
<i><span style="font-family:Verdana;">Cordyceps</span></i><span style="font-family:Verdana;"> mycelium extract (Cs-4), Chicken Essence (CE), and their combination were... <i><span style="font-family:Verdana;">Cordyceps</span></i><span style="font-family:Verdana;"> mycelium extract (Cs-4), Chicken Essence (CE), and their combination were investigated for antioxidant and immunomodulatory activities in mouse models. Long-term treatment with Cs-4 or CE at equivalent human doses improved antioxidant status in various tissues, as evidenced by the enhancement of mitochondrial glutathione redox status in the brain, liver, heart, and kidney of mice. Cs-4 or CE treatment also produced an immunomodulatory action, as indicated by the potentiation of Concanavalin A-/lipopolysaccharide-induced proliferation of mouse splenocytes <i></i></span><i><i><span style="font-family:Verdana;">ex vivo</span></i><span style="font-family:Verdana;"></span></i>. While doubling of the equivalent human doses of Cs-4 and CE did not further enhance their antioxidant or immunopotentiating effects, the combined treatment with Cs-4 and CE at their respective equivalent human doses produced an additive effect, with the extents of stimulation being larger than those produced by Cs-4 or CE alone. The results have demonstrated for the first time that the combined use of Cs-4 and CE can produce an additive effect on both antioxidation and immunopotentiation that cannot otherwise be achieved by increasing the equivalent human doses of Cs-4 or CE alone. 展开更多
关键词 Cordyceps Chicken Essence Glutathione Redox Status IMMUNOPOTENTIATION Additive effect
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The Effect and Mechanism of Nano-Cu Lubricating Additives on the Electroless Deposited Ni-W-P Coating
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作者 陈敏 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第5期815-820,共6页
The coating and deposition process with excellent anti wear and suitable for industrial application were developed, and the optimum bath composition and process were obtained by studying the influence of the bath comp... The coating and deposition process with excellent anti wear and suitable for industrial application were developed, and the optimum bath composition and process were obtained by studying the influence of the bath composition, temperature and pH value on the deposition rate and the plating solution stability. Moreover, the tribological properties of nano-Cu lubricating additives and electroless deposited Ni-W-P coating as well as their synergistic effect are researched using ring-block abrasion testing machine and energy dispersive spectrometer. Research results show that Ni-W-P alloy coating and nano-Cu lubricating additive have excellent synergistic effect, e g, the wear resistance of Ni-W-P alloy coating (with heat treatment and the oil with nano-Cu additives) has increased hundreds times than 45 steel as the metal substrate with the basic oil, and zero wear is achieved, which breaks through the bottleneck of previous separate research of the above-mentioned two aspects. 展开更多
关键词 Ni-W-P alloy coating nano Cu lubricating additives friction-Wear mechanism synergistic effect
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Effects of Thermal Annealing on the Solvent Additive P3HT PC61BM Bulk Heterojunction Solar Cells
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作者 樊星 赵谡玲 +5 位作者 陈雨 张杰 杨倩倩 龚伟 徐征 徐叙瑢 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第5期161-165,共5页
Effects of thermal annealing on the optical, electrical and structural properties of 3 vol% 1,8-diiodoctane added P3HT:PC61BM active layers are investigated, concerning the performance of the bulk heterojunction poly... Effects of thermal annealing on the optical, electrical and structural properties of 3 vol% 1,8-diiodoctane added P3HT:PC61BM active layers are investigated, concerning the performance of the bulk heterojunction polymer so- lar cells by changing the heat temperature. The structure information of the active layer is analyzed by using the grazing incidence wide angle scattering diffraction combined with the optical microscope, light absorption, pho- toluminescence and the external quantum efficiency spectra. The relationship between the detail of morphology and the optical, electrical properties is investigated. 展开更多
关键词 effects of Thermal Annealing on the Solvent Additive P3HT PC HT
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Sunflower (Helianthus annuus L.) Hybrids: Strategic Crossbreeding Techniques to Efficiently Enhance Yield and Oil Quality
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作者 Fida Hussain Farooq Khan +5 位作者 Javed Ahmad Heqiang Huo Tao Jiang Iqrar Rana Sajida Habib Muhammad Umer Farooq 《Phyton-International Journal of Experimental Botany》 2025年第10期3231-3249,共19页
The analysis of combining ability and heterosis is very important in enhancing the yield and oil quality of sunflowers under adverse conditions,and it reveals the potential of the parents and the mechanism of gene act... The analysis of combining ability and heterosis is very important in enhancing the yield and oil quality of sunflowers under adverse conditions,and it reveals the potential of the parents and the mechanism of gene action.In this study,twenty-one hybrids were developed by crossing seven cytoplasmic male sterile(CMS)lines with three restorer lines and evaluated for agronomic and quality traits.Highly significant general combining ability(GCA)and specific combining ability(SCA)effects were observed,confirming the role of both additive and non-additive gene actions.Among the tested crosses,A-42×R-86,A-92×R-86,and A-92×R-114 exhibited the greatest heterotic advantage,with seed yields exceeding 340 kg ha^(−1) over the better parent,oil contents above 19%,and 100-seed weights greater than 27 g.The hybrid A-92×R-114 was particularly notable for its elevated oleic acid level and balanced fatty acid profile,making it a strong candidate for premium oilseed production.In contrast,hybrids like A-20×R-39 exhibited moderate heterosis and less quality superiority.The oleic-to-linoleic acid ratio,a key determinant of oil stability,was strongly controlled by genetic factors.Oil content was largely influenced by additive effects,whereas yield heterosis was predominantly governed by non-additive effects.Overall,A-42×R-86 and A-92×R-114 emerged as the most promising hybrids,combining yield benefits with improved oil quality,and offering practical guidance for parental selection in sunflower breeding programs. 展开更多
关键词 SUNFLOWER combining ability HETEROSIS line×tester achene yield components oleic acid edible oil quality additive and non-additive gene effects
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高新技术企业认定政策的创新增量效应及作用机制 被引量:17
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作者 徐军玲 刘莉 《科研管理》 CSSCI CSCD 北大核心 2020年第8期135-141,共7页
以湖北2015—2017年新三板年报披露的463家公司数据,从信号传递与股权集中度的调节角度,运用“倾向得分匹配”方法,评估了高新技术企业认定政策的创新增量效应及其作用机制。实证发现:①高新技术企业认定政策能有效激励产出增量,策略性... 以湖北2015—2017年新三板年报披露的463家公司数据,从信号传递与股权集中度的调节角度,运用“倾向得分匹配”方法,评估了高新技术企业认定政策的创新增量效应及其作用机制。实证发现:①高新技术企业认定政策能有效激励产出增量,策略性创新激励效应大于实质性创新激励效应;②信号传递的调节作用存在异质性。金融支撑体系对认定政策的投入增量和产出增量效应具有负向调节作用,股权流通性对认定政策的产出增量效应具有正向调节作用;③股权集中度对认定政策的产出增量效应具有负向调节作用。研究结果从投入与产出增量视角丰富了创新激励影响因素研究的文献,并为高新技术企业认证的政策完善提供了实证指导。 展开更多
关键词 高新技术企业认定 增量效应 信号传递 股权集中度
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增量效应与信号功能:理解政府科技计划的两个前沿问题 被引量:9
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作者 李彰 苏竣 《科学学与科学技术管理》 CSSCI CSCD 北大核心 2017年第7期3-14,共12页
科技计划是政府开展公共科技活动的基本形式。随着政府财政科技投入的持续增长,考察并评估科技计划的实际效果,已成为近20年来创新研究,尤其是创新经济学与创新政策研究关注的焦点问题。增量效应与信号功能是学者们为准确认识政府科技... 科技计划是政府开展公共科技活动的基本形式。随着政府财政科技投入的持续增长,考察并评估科技计划的实际效果,已成为近20年来创新研究,尤其是创新经济学与创新政策研究关注的焦点问题。增量效应与信号功能是学者们为准确认识政府科技计划的作用,减少评估的认知偏误而逐渐发展起来的两个前沿概念。回顾上述两个概念的缘起、发展、内涵与相关的实证研究发现。未来,基于中国现实的治理情境,开展基于"增量"概念的评估研究,深入分析"信号功能"的作用逻辑。 展开更多
关键词 科技计划 政策评估 增量效应 信号功能
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