The hybridization between oxygen 2p and transition-metal 3d states largely determines the electronic structure near the Fermi level and related functionalities of transition-metal oxides(TMOs).Considerable efforts hav...The hybridization between oxygen 2p and transition-metal 3d states largely determines the electronic structure near the Fermi level and related functionalities of transition-metal oxides(TMOs).Considerable efforts have been made to manipulate the p-d hybridization in TMOs by tailoring the spatial orbital overlap via structural engineering.Here,we demonstrate enhanced p-d hybridization in Ba^(2+)-doped LaNiO_(3)epitaxial films by simultaneously modifying both the spatial and energetic overlaps between the O-2p and Ni-3d orbitals.Combining x-ray absorption spectroscopy and firstprinciples calculations,we reveal that the enhanced hybridization stems from the synergistic effects of a reduced chargetransfer energy due to hole injection and an increased spatial orbital overlap due to straightening of Ni-O-Ni bonds.We further show that the enhanced p-d hybridization can be utilized to promote the oxygen evolution activity of LaNiO_(3).This work sheds new insights into the fine-tuning of the electronic structures of TMOs for enhanced functionalities.展开更多
The Wenchuan earthquake that occurred on 12 May 2008 induced numerous landslides.Loose landslide materials were deposited on hillslopes,and deep channels were easily remobilized and transformed into debris flows by ex...The Wenchuan earthquake that occurred on 12 May 2008 induced numerous landslides.Loose landslide materials were deposited on hillslopes,and deep channels were easily remobilized and transformed into debris flows by extreme rainstorms.Twelve years after the Wenchuan earthquake,debris flows were still active in the Qipangou Ravine in the quake-hit area.In this paper,we continuously tracked the spatiotemporal evolution of the landslides and vegetation restoration and evaluated the evolution of debris flow activity in the Qipan catchment with the aid of a GIS platform and field investigations from 2008 to 2019.We observed that the area with active landslides increased sharply immediately following the earthquake,and then decreased with time;however,the total area of landslides continued to increase from 6.93 km^(2)in 2008 to 10.55 km^(2)in 2019.The active landslides shifted towards lower angles and higher elevations after 2013.Since 2009,the vegetation coverage has been gradually increasing and approaching the coverage present before the earthquake as of 2019.The landslide activity was high and the vegetation recovery rates were rapidly rising during the first five years after the earthquake;the recovery rates then slowed over time.Therefore,we divided the evolution that occurred during the post landslide period into an active period(2008-2013),a self-adjustment period(2013-2026)and a stable period(after 2026).We then proposed a quantitative model to determine the trends of landslide activity rates and NDVI values in the catchment,which indicated that the landslide activities and postseismic vegetation restoration rates in this catchment will return to preseismic levels within approximately two decades.We also analysed the runout volumes of the debris flows after the earthquakes(Diexi and Wenchuan)and the standard deviation of the vegetation coverage and predicted that the debris flow activities will last for an additional 50 years or more.展开更多
Taking the 13-point smoothed monthly sunspot number,Ri, and the deviation of the 13 associated monthly sunspot numbers from the smoothed one, Di, as a number-pair describing the global level of sunspot activity, the e...Taking the 13-point smoothed monthly sunspot number,Ri, and the deviation of the 13 associated monthly sunspot numbers from the smoothed one, Di, as a number-pair describing the global level of sunspot activity, the evolution of the level is statistically studied for the period from the month which is just 48 months before the minimum to the minimum in the descending phase, using the observed data of Solar Cycles 10 to 22. Our results show （1） for 46 months （94%） of the studied 49 months it is found that for a given month, the distribution of the 13 pairs which come from the 13 solar cycles on a log Ri - Di plane may be fitted by a straight line with a correlation coefficient larger than the critical one at confidence level a = 5%, and for 36 months （73%） the fitting is even better, for a = 1%; （2） time variations of these two parameters and their correlations in the studied period can be described respectively by functions of time, whose main trends may be expressed by a linear or simple curvilinear function; （3） the evolutionary path of the level of sunspot activity may be represented by a logarithmic function as log/~ = 0.704 lnDi - 0.291.展开更多
A long-lived sunspot group (AR9604) on the south hemisphere that lasted five solar rotations and produced some strong bursts is analyzed. The focus is on its evolving features. Its whole life was successfully maintain...A long-lived sunspot group (AR9604) on the south hemisphere that lasted five solar rotations and produced some strong bursts is analyzed. The focus is on its evolving features. Its whole life was successfully maintained by four Emerging Flux Regions (EFRs). Apart from the one that lasted only a short time and did not produce any bursts, the other three EFRs have the following common features: (1) A positive writhe of magnetic flux tubes and a twist of the field lines of the same sign, indicating kink instability. (2) A clockwise rotation and a high tilt because the writhe was right-handed. (3) A compact 'island δ' structure of the sunspot group indicating concentrated kink instability. Since magnetic reconnection easily occurs at the kinked point of a very kink-unstable flux tube, these features should be the inducement of the strong bursts.展开更多
A cost-effective,facile solution-based hot-injection synthetic route has been developed to synthesize NiSb nanoparticles in oleylamine(OAm)using commercially available inexpensive precursor with reducing toxicity at a...A cost-effective,facile solution-based hot-injection synthetic route has been developed to synthesize NiSb nanoparticles in oleylamine(OAm)using commercially available inexpensive precursor with reducing toxicity at a relatively low temperature of 160℃.Especially,an organic reductant of borane-tert-butylamine complex is intentionally involved in the reaction system to promote a fast reduction of metallic Ni and Sb for the formation of the NiSb nanoparticles.Structural characterizations reveal that the NiSb nanoparticles are hexagonal phase with space group P63/mmc and they are composed of small granules with size about 10 nm that tend to form agglomerates with porous-like geometries.This is the first report on the generation of transition metal antimonide via solution-based strategy,and the asfabricated nanoparticles possess actively electrocatalytic hydrogen evolution reaction(HER)property in acidic electrolytes when the long-chain ligand of OAm adhered on the surface of the nanoparticles is exchanged by ligand-removal and exchange procedure.It is found that the NiSb nanoparticles as a new kind of non-noble-metal HER electrocatalysts only require overpotentials of 437 and 531 mV to achieve high current densities of 10 and 50 mA/cm^2 respectively,as well as exhibit low charge transfer resistance and excellent HER stability.展开更多
A spinel oxide NiCo204 prepared by thermal decomposition is of very high activity for the oxygen evolution reaction(OER)in alkaline solution.The oxygen evolution overpotential on NiCo204 is 0.252-0.262V in 10 M NaOH s...A spinel oxide NiCo204 prepared by thermal decomposition is of very high activity for the oxygen evolution reaction(OER)in alkaline solution.The oxygen evolution overpotential on NiCo204 is 0.252-0.262V in 10 M NaOH solution at 343K and current density 100 mAcm^(-2).展开更多
Understanding galaxy formation is one of the most pressing issues in cos- mology. We review the current status of galaxy formation from both an observational and a theoretical perspective, and summarize the prospects ...Understanding galaxy formation is one of the most pressing issues in cos- mology. We review the current status of galaxy formation from both an observational and a theoretical perspective, and summarize the prospects for future advances.展开更多
In order to explore the relationship between properties of Polycyclic Aromatic Hydrocarbons （PAHs） and AGN activities in Type-I AGNs, we compiled a sample of 47 Type-I AGNs with measured PAH 11.3 μm and 7.7 μm emi...In order to explore the relationship between properties of Polycyclic Aromatic Hydrocarbons （PAHs） and AGN activities in Type-I AGNs, we compiled a sample of 47 Type-I AGNs with measured PAH 11.3 μm and 7.7 μm emission lines. The PAH emission and optical properties of these AGNs are taken from the literature. It is found that the equivalent width （EW） of 11.3 μm emission from PAHs shows a weak correlation with the ratio of the EWs of the FelI complex between λ4434 and A4684 to H/3 （RFe）. The PAH 11.3/7.7 ratio is correlated with various elements defined by the first eigenvector space, which are RFe, [OIII]A5007 luminosity and H/3 asymmetry. These correlations infer that AGNs with high RFe, weak [OIII] emission and a strong H/3 blue-wing are likely to have low PAH ionization, and hence a larger amount of neutral PAHs.展开更多
Subject Code:B01With the support by the National Natural Science Foundation of China,a creative study by the research group led by Prof.Chen Qianwang(陈乾旺)from the University of Science and Technology of China and H...Subject Code:B01With the support by the National Natural Science Foundation of China,a creative study by the research group led by Prof.Chen Qianwang(陈乾旺)from the University of Science and Technology of China and High Magnetic Field Laboratory,Hefei Institutes of Physical Science,Chinese Academy of展开更多
Alkaline hydrogen evolution reaction(HER)offers a near-zero-emission approach to advance hydrogen energy.However,the activity limited by the multiple reaction steps involving H_(2)O molecules transfer,absorption,and a...Alkaline hydrogen evolution reaction(HER)offers a near-zero-emission approach to advance hydrogen energy.However,the activity limited by the multiple reaction steps involving H_(2)O molecules transfer,absorption,and activation still unqualified the thresholds of economic viability.Herein,we proposed a multisite complementary strategy that incorporates hydrophilic Mo and electrophilic V into Ni-based catalysts to divide the distinct steps on atomically dispersive sites and thus realize sequential regulation of the HER process.The Isotopic labeled in situ Raman spectroscopy describes 4-coordinated hydrogen bonded H_(2)O to be free H_(2)O passing the inner Helmholtz plane in the vicinity of the catalysts under the action of hydrophilic Mo sites.Furthermore,potential-dependent electrochemical impedance spectroscopy(EIS)reveals that electrophilic V sites with abundant 3d empty orbitals could activate the lone-pair electrons in the free H_(2)O molecules to produce more protic hydrogen,and dimerize into H_(2) at the Ni sites.By the sequential management of reactive H_(2)O molecules,NiMoV oxides multisite catalysts surpass Pt/C hydrogen evolution activity(49 mV@10 mA∙cm^(-2) over 140 h).Profoundly,this study provides a tangible model to deepen the comprehension of the catalyst–electrolyte interface and create efficient catalysts for diverse reactions.展开更多
The development of low-cost,stable,and robust non-noble metal catalysts for water oxidation is a pivotal challenge for sustainable hydrogen production through electrocatalytic water splitting.Currently,such catalysts ...The development of low-cost,stable,and robust non-noble metal catalysts for water oxidation is a pivotal challenge for sustainable hydrogen production through electrocatalytic water splitting.Currently,such catalysts suffer from high overpotential and sluggish kinetics in oxygen evolution reactions(OERs).Herein,we report a“continuous”single-crystal honeycomb-like MXene/NiFeP_(x)–N-doped carbon(NC)heterostructure,in which ultrasmall NiFeP_(x)nanoparticles(NPs)encapsulated in the NC are tightly anchored on a layered MXene.Interestingly,this MXene/NiFeP_(x)–NC delivers outstanding OER catalytic performance,which stems from“continuous”single-crystal characteristics,abundant active sites derived from the ultrasmall NiFeP_(x)NPs,and the stable honeycomb-like heterostructure with an open structure.The experimental results are rationalized theoretically(by density functional theory(DFT)calculations),which suggests that it is the unique MXene/NiFeP_(x)–NC heterostructure that promotes the sluggish OER,thereby enabling superior durability and excellent activity with an ultralow overpotential of 240 mV at a current density of 10 mA×cm^(−2).展开更多
Lunar exploration is deemed crucial for uncovering the origins of the Earth-Moon system and is the first step for advancing humanity’s exploration of deep space.Over the past decade,the Chinese Lunar Exploration Prog...Lunar exploration is deemed crucial for uncovering the origins of the Earth-Moon system and is the first step for advancing humanity’s exploration of deep space.Over the past decade,the Chinese Lunar Exploration Program(CLEP),also known as the Chang’e(CE)Project,has achieved remarkable milestones.It has successfully developed and demonstrated the engineering capability required to reach and return from the lunar surface.Notably,the CE Project has made historic firsts with the landing and on-site exploration of the far side of the Moon,along with the collection of the youngest volcanic samples from the Procellarum KREEP Terrane.These achievements have significantly enhanced our understanding of lunar evolution.Building on this success,China has proposed an ambitious crewed lunar exploration strategy,aiming to return to the Moon for scientific exploration and utilization.This plan encompasses two primary phases:the first crewed lunar landing and exploration,followed by a thousand-kilometer scale scientific expedition to construct a geological cross-section across the lunar surface.Recognizing the limitations of current lunar exploration efforts and China’s engineering and technical capabilities,this paper explores the benefits of crewed lunar exploration while leveraging synergies with robotic exploration.The study refines fundamental lunar scientific questions that could lead to significant breakthroughs,considering the respective engineering and technological requirements.This research lays a crucial foundation for defining the objectives of future lunar exploration,emphasizing the importance of crewed missions and offering insights into potential advancements in lunar science.展开更多
The research indicates that there is a positive correlation between the negative CG flash rate and the area of radar echo with its reflectivity being equal to or greater than 30 dBz in the mesoscale convective system ...The research indicates that there is a positive correlation between the negative CG flash rate and the area of radar echo with its reflectivity being equal to or greater than 30 dBz in the mesoscale convective system in Beijing area.A max- imum of the positive CG flash rate exists at both the initial and the dissipating stages.The CG flashes are usually located near but not within the high reflectivity center.The negative flashes are associated with.the positions of the updraft re- gion,and with the regions of wind convergence and wind shear.Generally,the negative CG flashes are concentrative and the positive ones are dispersive.展开更多
Geomicrobiology is a sub-discipline of geobiology and emphasizes the interaction between microorganisms and their environment on Earth. There is a need to explicitly emphasize the biogeochemical processes performed by...Geomicrobiology is a sub-discipline of geobiology and emphasizes the interaction between microorganisms and their environment on Earth. There is a need to explicitly emphasize the biogeochemical processes performed by microorganisms associated with Earth's tectonic activities, especially under the framework of the modern theory of plate tectonics. Tectonomicrobiology aims to create a better synergy between microbial and active tectonic processes. This explicit synergy should also foster better communications between solid Earth scientists and life scientists in terms of holistic Earth system dynamics at both tectonic and micro-scales.展开更多
This study examines the geomorphic evolution of Dingzi Bay, East China in response to human activity and variations in fluvial input since the 1950s. The analysis is based on data from multiple mathematical methods, a...This study examines the geomorphic evolution of Dingzi Bay, East China in response to human activity and variations in fluvial input since the 1950s. The analysis is based on data from multiple mathematical methods, along with information obtained from Remote Sensing, Geographic Information System and Global Position System technology. The results show that the annual runoff and sediment load discharged into Dingzi Bay display significant decreasing trends overall, and marked downward steps were observed in 1966 and 1980. Around 60%-80% of the decline is attributed to decreasing precipitation in the Wulong River Basin. The landform types in Dingzi Bay have changed significantly since the 1950s, especially over the period between 1981 and 1995. Large areas of tidal fiats, swamp, salt fields, and paddy fields have been reclaimed, and aquaculture ponds have been constructed. Consequently, the patterns of erosion and deposition in the bay have changed substantially. Despite a reduction in sediment input of 65.68% after 1966, low rates of sediment deposition continued in the bay. However, deposition rates changed significantly after 1981 owing to large-scale development in the bay, with a net depositional area approximately 10 times larger than that during 1961-1981. This geomorphic evolution stabilized following the termination of large-scale human activity in the bay after 1995. Overall, Dingzi Bay has shown a tendency towards silting-up during 1952-2010, with the bay head migrating seaward, the number of channels in the tidal creek system decreasing, and the tidal inlet becoming narrower and shorter. In conclusion, large- scale development and human activity in Dingzi Bay have controlled the geomorphic evolution of the bay since the 1950s.展开更多
基金supported by the National Key R&D Program of China(Grant No.2022YFA1402902)the National Natural Science Foundation of China(Grant Nos.12374179,12074119,12374145,051B22001,12104157,12134003,and 12304218)the Shanghai Pujiang Program(Grant No.23PJ1402200).
文摘The hybridization between oxygen 2p and transition-metal 3d states largely determines the electronic structure near the Fermi level and related functionalities of transition-metal oxides(TMOs).Considerable efforts have been made to manipulate the p-d hybridization in TMOs by tailoring the spatial orbital overlap via structural engineering.Here,we demonstrate enhanced p-d hybridization in Ba^(2+)-doped LaNiO_(3)epitaxial films by simultaneously modifying both the spatial and energetic overlaps between the O-2p and Ni-3d orbitals.Combining x-ray absorption spectroscopy and firstprinciples calculations,we reveal that the enhanced hybridization stems from the synergistic effects of a reduced chargetransfer energy due to hole injection and an increased spatial orbital overlap due to straightening of Ni-O-Ni bonds.We further show that the enhanced p-d hybridization can be utilized to promote the oxygen evolution activity of LaNiO_(3).This work sheds new insights into the fine-tuning of the electronic structures of TMOs for enhanced functionalities.
基金supported by the National Key Research and Development Program of China(No.2017YFC1501004)the National Natural Science Foundation of China(No.41672299)。
文摘The Wenchuan earthquake that occurred on 12 May 2008 induced numerous landslides.Loose landslide materials were deposited on hillslopes,and deep channels were easily remobilized and transformed into debris flows by extreme rainstorms.Twelve years after the Wenchuan earthquake,debris flows were still active in the Qipangou Ravine in the quake-hit area.In this paper,we continuously tracked the spatiotemporal evolution of the landslides and vegetation restoration and evaluated the evolution of debris flow activity in the Qipan catchment with the aid of a GIS platform and field investigations from 2008 to 2019.We observed that the area with active landslides increased sharply immediately following the earthquake,and then decreased with time;however,the total area of landslides continued to increase from 6.93 km^(2)in 2008 to 10.55 km^(2)in 2019.The active landslides shifted towards lower angles and higher elevations after 2013.Since 2009,the vegetation coverage has been gradually increasing and approaching the coverage present before the earthquake as of 2019.The landslide activity was high and the vegetation recovery rates were rapidly rising during the first five years after the earthquake;the recovery rates then slowed over time.Therefore,we divided the evolution that occurred during the post landslide period into an active period(2008-2013),a self-adjustment period(2013-2026)and a stable period(after 2026).We then proposed a quantitative model to determine the trends of landslide activity rates and NDVI values in the catchment,which indicated that the landslide activities and postseismic vegetation restoration rates in this catchment will return to preseismic levels within approximately two decades.We also analysed the runout volumes of the debris flows after the earthquakes(Diexi and Wenchuan)and the standard deviation of the vegetation coverage and predicted that the debris flow activities will last for an additional 50 years or more.
基金Supported by the National Natural Science Foundation of China.
文摘Taking the 13-point smoothed monthly sunspot number,Ri, and the deviation of the 13 associated monthly sunspot numbers from the smoothed one, Di, as a number-pair describing the global level of sunspot activity, the evolution of the level is statistically studied for the period from the month which is just 48 months before the minimum to the minimum in the descending phase, using the observed data of Solar Cycles 10 to 22. Our results show （1） for 46 months （94%） of the studied 49 months it is found that for a given month, the distribution of the 13 pairs which come from the 13 solar cycles on a log Ri - Di plane may be fitted by a straight line with a correlation coefficient larger than the critical one at confidence level a = 5%, and for 36 months （73%） the fitting is even better, for a = 1%; （2） time variations of these two parameters and their correlations in the studied period can be described respectively by functions of time, whose main trends may be expressed by a linear or simple curvilinear function; （3） the evolutionary path of the level of sunspot activity may be represented by a logarithmic function as log/~ = 0.704 lnDi - 0.291.
文摘A long-lived sunspot group (AR9604) on the south hemisphere that lasted five solar rotations and produced some strong bursts is analyzed. The focus is on its evolving features. Its whole life was successfully maintained by four Emerging Flux Regions (EFRs). Apart from the one that lasted only a short time and did not produce any bursts, the other three EFRs have the following common features: (1) A positive writhe of magnetic flux tubes and a twist of the field lines of the same sign, indicating kink instability. (2) A clockwise rotation and a high tilt because the writhe was right-handed. (3) A compact 'island δ' structure of the sunspot group indicating concentrated kink instability. Since magnetic reconnection easily occurs at the kinked point of a very kink-unstable flux tube, these features should be the inducement of the strong bursts.
基金supported by the National Natural Science Foundation of China(No.21571166 and No.51271173)
文摘A cost-effective,facile solution-based hot-injection synthetic route has been developed to synthesize NiSb nanoparticles in oleylamine(OAm)using commercially available inexpensive precursor with reducing toxicity at a relatively low temperature of 160℃.Especially,an organic reductant of borane-tert-butylamine complex is intentionally involved in the reaction system to promote a fast reduction of metallic Ni and Sb for the formation of the NiSb nanoparticles.Structural characterizations reveal that the NiSb nanoparticles are hexagonal phase with space group P63/mmc and they are composed of small granules with size about 10 nm that tend to form agglomerates with porous-like geometries.This is the first report on the generation of transition metal antimonide via solution-based strategy,and the asfabricated nanoparticles possess actively electrocatalytic hydrogen evolution reaction(HER)property in acidic electrolytes when the long-chain ligand of OAm adhered on the surface of the nanoparticles is exchanged by ligand-removal and exchange procedure.It is found that the NiSb nanoparticles as a new kind of non-noble-metal HER electrocatalysts only require overpotentials of 437 and 531 mV to achieve high current densities of 10 and 50 mA/cm^2 respectively,as well as exhibit low charge transfer resistance and excellent HER stability.
文摘A spinel oxide NiCo204 prepared by thermal decomposition is of very high activity for the oxygen evolution reaction(OER)in alkaline solution.The oxygen evolution overpotential on NiCo204 is 0.252-0.262V in 10 M NaOH solution at 343K and current density 100 mAcm^(-2).
文摘Understanding galaxy formation is one of the most pressing issues in cos- mology. We review the current status of galaxy formation from both an observational and a theoretical perspective, and summarize the prospects for future advances.
基金Supported by the National Natural Science Foundation of China
文摘In order to explore the relationship between properties of Polycyclic Aromatic Hydrocarbons （PAHs） and AGN activities in Type-I AGNs, we compiled a sample of 47 Type-I AGNs with measured PAH 11.3 μm and 7.7 μm emission lines. The PAH emission and optical properties of these AGNs are taken from the literature. It is found that the equivalent width （EW） of 11.3 μm emission from PAHs shows a weak correlation with the ratio of the EWs of the FelI complex between λ4434 and A4684 to H/3 （RFe）. The PAH 11.3/7.7 ratio is correlated with various elements defined by the first eigenvector space, which are RFe, [OIII]A5007 luminosity and H/3 asymmetry. These correlations infer that AGNs with high RFe, weak [OIII] emission and a strong H/3 blue-wing are likely to have low PAH ionization, and hence a larger amount of neutral PAHs.
文摘Subject Code:B01With the support by the National Natural Science Foundation of China,a creative study by the research group led by Prof.Chen Qianwang(陈乾旺)from the University of Science and Technology of China and High Magnetic Field Laboratory,Hefei Institutes of Physical Science,Chinese Academy of
文摘Alkaline hydrogen evolution reaction(HER)offers a near-zero-emission approach to advance hydrogen energy.However,the activity limited by the multiple reaction steps involving H_(2)O molecules transfer,absorption,and activation still unqualified the thresholds of economic viability.Herein,we proposed a multisite complementary strategy that incorporates hydrophilic Mo and electrophilic V into Ni-based catalysts to divide the distinct steps on atomically dispersive sites and thus realize sequential regulation of the HER process.The Isotopic labeled in situ Raman spectroscopy describes 4-coordinated hydrogen bonded H_(2)O to be free H_(2)O passing the inner Helmholtz plane in the vicinity of the catalysts under the action of hydrophilic Mo sites.Furthermore,potential-dependent electrochemical impedance spectroscopy(EIS)reveals that electrophilic V sites with abundant 3d empty orbitals could activate the lone-pair electrons in the free H_(2)O molecules to produce more protic hydrogen,and dimerize into H_(2) at the Ni sites.By the sequential management of reactive H_(2)O molecules,NiMoV oxides multisite catalysts surpass Pt/C hydrogen evolution activity(49 mV@10 mA∙cm^(-2) over 140 h).Profoundly,this study provides a tangible model to deepen the comprehension of the catalyst–electrolyte interface and create efficient catalysts for diverse reactions.
基金supported by the National Natural Science Foundation of China(No.22269010)the Training Program for Academic and Technical Leaders of Major Disciplines in Jiangxi Province(No.20212BCJ23020)+1 种基金the Science and Technology Project of Jiangxi Provincial Department of Education(No.GJJ211305)Jingdezhen Science and Technology Planning Project(No.20212GYZD009-04)。
文摘The development of low-cost,stable,and robust non-noble metal catalysts for water oxidation is a pivotal challenge for sustainable hydrogen production through electrocatalytic water splitting.Currently,such catalysts suffer from high overpotential and sluggish kinetics in oxygen evolution reactions(OERs).Herein,we report a“continuous”single-crystal honeycomb-like MXene/NiFeP_(x)–N-doped carbon(NC)heterostructure,in which ultrasmall NiFeP_(x)nanoparticles(NPs)encapsulated in the NC are tightly anchored on a layered MXene.Interestingly,this MXene/NiFeP_(x)–NC delivers outstanding OER catalytic performance,which stems from“continuous”single-crystal characteristics,abundant active sites derived from the ultrasmall NiFeP_(x)NPs,and the stable honeycomb-like heterostructure with an open structure.The experimental results are rationalized theoretically(by density functional theory(DFT)calculations),which suggests that it is the unique MXene/NiFeP_(x)–NC heterostructure that promotes the sluggish OER,thereby enabling superior durability and excellent activity with an ultralow overpotential of 240 mV at a current density of 10 mA×cm^(−2).
基金supported by the National Natural Science Foundation of China(L2224032)the Research Project on the Discipline Development Strategy of Academic Divisions of the Chinese Academy of Sciences(XK2022DXC004).
文摘Lunar exploration is deemed crucial for uncovering the origins of the Earth-Moon system and is the first step for advancing humanity’s exploration of deep space.Over the past decade,the Chinese Lunar Exploration Program(CLEP),also known as the Chang’e(CE)Project,has achieved remarkable milestones.It has successfully developed and demonstrated the engineering capability required to reach and return from the lunar surface.Notably,the CE Project has made historic firsts with the landing and on-site exploration of the far side of the Moon,along with the collection of the youngest volcanic samples from the Procellarum KREEP Terrane.These achievements have significantly enhanced our understanding of lunar evolution.Building on this success,China has proposed an ambitious crewed lunar exploration strategy,aiming to return to the Moon for scientific exploration and utilization.This plan encompasses two primary phases:the first crewed lunar landing and exploration,followed by a thousand-kilometer scale scientific expedition to construct a geological cross-section across the lunar surface.Recognizing the limitations of current lunar exploration efforts and China’s engineering and technical capabilities,this paper explores the benefits of crewed lunar exploration while leveraging synergies with robotic exploration.The study refines fundamental lunar scientific questions that could lead to significant breakthroughs,considering the respective engineering and technological requirements.This research lays a crucial foundation for defining the objectives of future lunar exploration,emphasizing the importance of crewed missions and offering insights into potential advancements in lunar science.
基金supported by grants from State Planning Commission under Grants No.75-09-02-19
文摘The research indicates that there is a positive correlation between the negative CG flash rate and the area of radar echo with its reflectivity being equal to or greater than 30 dBz in the mesoscale convective system in Beijing area.A max- imum of the positive CG flash rate exists at both the initial and the dissipating stages.The CG flashes are usually located near but not within the high reflectivity center.The negative flashes are associated with.the positions of the updraft re- gion,and with the regions of wind convergence and wind shear.Generally,the negative CG flashes are concentrative and the positive ones are dispersive.
基金supported by the National Natural Science Foundation of China(Grant Nos.41530105,41373072,91628301&U1606401)the Chinese Academy of Sciences(Grant Nos.Y4SL021001&QYZDY-SSW-DQC005)the Southern University of Science and Technology(Grant No.Y01316209)
文摘Geomicrobiology is a sub-discipline of geobiology and emphasizes the interaction between microorganisms and their environment on Earth. There is a need to explicitly emphasize the biogeochemical processes performed by microorganisms associated with Earth's tectonic activities, especially under the framework of the modern theory of plate tectonics. Tectonomicrobiology aims to create a better synergy between microbial and active tectonic processes. This explicit synergy should also foster better communications between solid Earth scientists and life scientists in terms of holistic Earth system dynamics at both tectonic and micro-scales.
文摘This study examines the geomorphic evolution of Dingzi Bay, East China in response to human activity and variations in fluvial input since the 1950s. The analysis is based on data from multiple mathematical methods, along with information obtained from Remote Sensing, Geographic Information System and Global Position System technology. The results show that the annual runoff and sediment load discharged into Dingzi Bay display significant decreasing trends overall, and marked downward steps were observed in 1966 and 1980. Around 60%-80% of the decline is attributed to decreasing precipitation in the Wulong River Basin. The landform types in Dingzi Bay have changed significantly since the 1950s, especially over the period between 1981 and 1995. Large areas of tidal fiats, swamp, salt fields, and paddy fields have been reclaimed, and aquaculture ponds have been constructed. Consequently, the patterns of erosion and deposition in the bay have changed substantially. Despite a reduction in sediment input of 65.68% after 1966, low rates of sediment deposition continued in the bay. However, deposition rates changed significantly after 1981 owing to large-scale development in the bay, with a net depositional area approximately 10 times larger than that during 1961-1981. This geomorphic evolution stabilized following the termination of large-scale human activity in the bay after 1995. Overall, Dingzi Bay has shown a tendency towards silting-up during 1952-2010, with the bay head migrating seaward, the number of channels in the tidal creek system decreasing, and the tidal inlet becoming narrower and shorter. In conclusion, large- scale development and human activity in Dingzi Bay have controlled the geomorphic evolution of the bay since the 1950s.
