The thermal equilibrium state of the reference electrode was investigated. The results show that the temperature difference between the inside and the outside of zirconia tube was very small and the Seebeck effect can...The thermal equilibrium state of the reference electrode was investigated. The results show that the temperature difference between the inside and the outside of zirconia tube was very small and the Seebeck effect can be ignored after the sensor was dipped into liquid steel for more than 2 s. A special sensor was designed to test the relation between the EMF （electromotive force） of sensor and the thermal equilibrium state of the reference elec- trode. Based on these results, it is suggested that the peak in EMF curve was caused by the change of oxygen potential in reference electrode before the thermal equilibrium was reached. If NiO was added by 2 M- 5 M to the Cr/Cr2O3 reference electrode, the peak in EMF curve could be eliminated.展开更多
The ZrO2 (9mol% Y2O3) coating was prepared evenly on the surface of MgO partially stabilized zirconia (Mg-PSZ) tube (oxygen sensor probe) by dipping the green Mg-PSZ tube in a ZrO2 (9mol% Y2O3) slurry and then co-fir...The ZrO2 (9mol% Y2O3) coating was prepared evenly on the surface of MgO partially stabilized zirconia (Mg-PSZ) tube (oxygen sensor probe) by dipping the green Mg-PSZ tube in a ZrO2 (9mol% Y2O3) slurry and then co-firing at 1750°C for 8 h. The double-cell method was employed to measure the electronic conductivity parameter and exam the reproducibility of the coated Mg- PSZ tube. The experimental results indicate that the good thermal shock resistance of the Mg-PSZ tube can be retained when the coating thickness is not more than 3.4 μm. The ZrO2 (9mol% Y2O3) coating reduces the electronic conductivity parameter remarka- bly, probably due to the lower electronic conductivity of Y2O,-stabilized ZrO2 than that of MgO-stabilized ZrO2. Moreover, the ZrO2 (9mol% Y2O3) coating can improve the reproducibility and accuracy of the Mg-PSZ tube significantly in the low oxygen measure- ment. The smooth surface feature and lower electronic conductivity of the coated Mg-PSZ tube should be responsible for this im- provement.展开更多
ZrO2/Graphene nanocomposites are fabricated from graphene oxide by one-step, green, facile and low-cost SCCO2 method. The as-prepared nanocomposites are characterized by means of X-ray photoelectron, transmission elec...ZrO2/Graphene nanocomposites are fabricated from graphene oxide by one-step, green, facile and low-cost SCCO2 method. The as-prepared nanocomposites are characterized by means of X-ray photoelectron, transmission electron microscopy and catalytic chemiluminescence measurement. The ZrO2 nanoparticles with size of several nanometers are uniformly coated on the graphene surface. The chemiluminescence characteristic to ethanol of the as-prepared nanocomposite paper is also investigated. The nanocomposite paper obtained displays high catalytic chemiluminescence sensitivity and highly selectivity to the ethanol gas. This study provides a facile, green and low-cost route to prepare nanoscopic gas sensing devices with application in safe protection, food fermentation, medical process and traffic safe.展开更多
设计一种基于氧化锆(Zr O2)的高温非共烧陶瓷压力传感器。在已有的低温共烧陶瓷(LTCC)工艺的基础上,经过改进采用了高温非共烧技术进行陶瓷传感器的制作。先进行传感器基底的制作,再制作传感器的金属电路部分。这样解决了高温共烧技术...设计一种基于氧化锆(Zr O2)的高温非共烧陶瓷压力传感器。在已有的低温共烧陶瓷(LTCC)工艺的基础上,经过改进采用了高温非共烧技术进行陶瓷传感器的制作。先进行传感器基底的制作,再制作传感器的金属电路部分。这样解决了高温共烧技术中各材料高温烧结热膨胀系数不匹配的问题。传感器信号读取采用两个电感耦合的方式,实现了非接触压力测量。制作的传感器高温环境下力学特性稳定。测试结果显示:传感器的谐振频率随外加压力的增加而减小,其谐振频率变化对压力的响应灵敏度约为491.10 k Hz/bar。展开更多
文摘The thermal equilibrium state of the reference electrode was investigated. The results show that the temperature difference between the inside and the outside of zirconia tube was very small and the Seebeck effect can be ignored after the sensor was dipped into liquid steel for more than 2 s. A special sensor was designed to test the relation between the EMF （electromotive force） of sensor and the thermal equilibrium state of the reference elec- trode. Based on these results, it is suggested that the peak in EMF curve was caused by the change of oxygen potential in reference electrode before the thermal equilibrium was reached. If NiO was added by 2 M- 5 M to the Cr/Cr2O3 reference electrode, the peak in EMF curve could be eliminated.
文摘The ZrO2 (9mol% Y2O3) coating was prepared evenly on the surface of MgO partially stabilized zirconia (Mg-PSZ) tube (oxygen sensor probe) by dipping the green Mg-PSZ tube in a ZrO2 (9mol% Y2O3) slurry and then co-firing at 1750°C for 8 h. The double-cell method was employed to measure the electronic conductivity parameter and exam the reproducibility of the coated Mg- PSZ tube. The experimental results indicate that the good thermal shock resistance of the Mg-PSZ tube can be retained when the coating thickness is not more than 3.4 μm. The ZrO2 (9mol% Y2O3) coating reduces the electronic conductivity parameter remarka- bly, probably due to the lower electronic conductivity of Y2O,-stabilized ZrO2 than that of MgO-stabilized ZrO2. Moreover, the ZrO2 (9mol% Y2O3) coating can improve the reproducibility and accuracy of the Mg-PSZ tube significantly in the low oxygen measure- ment. The smooth surface feature and lower electronic conductivity of the coated Mg-PSZ tube should be responsible for this im- provement.
文摘ZrO2/Graphene nanocomposites are fabricated from graphene oxide by one-step, green, facile and low-cost SCCO2 method. The as-prepared nanocomposites are characterized by means of X-ray photoelectron, transmission electron microscopy and catalytic chemiluminescence measurement. The ZrO2 nanoparticles with size of several nanometers are uniformly coated on the graphene surface. The chemiluminescence characteristic to ethanol of the as-prepared nanocomposite paper is also investigated. The nanocomposite paper obtained displays high catalytic chemiluminescence sensitivity and highly selectivity to the ethanol gas. This study provides a facile, green and low-cost route to prepare nanoscopic gas sensing devices with application in safe protection, food fermentation, medical process and traffic safe.
文摘设计一种基于氧化锆(Zr O2)的高温非共烧陶瓷压力传感器。在已有的低温共烧陶瓷(LTCC)工艺的基础上,经过改进采用了高温非共烧技术进行陶瓷传感器的制作。先进行传感器基底的制作,再制作传感器的金属电路部分。这样解决了高温共烧技术中各材料高温烧结热膨胀系数不匹配的问题。传感器信号读取采用两个电感耦合的方式,实现了非接触压力测量。制作的传感器高温环境下力学特性稳定。测试结果显示:传感器的谐振频率随外加压力的增加而减小,其谐振频率变化对压力的响应灵敏度约为491.10 k Hz/bar。
