Liquid crystal Pacharatnam-Berry phase optical elements(PBOEs)have found promising applications in augmented reality and virtual reality because of their slim formfactor,lightweight,and high optical efficiency.However...Liquid crystal Pacharatnam-Berry phase optical elements(PBOEs)have found promising applications in augmented reality and virtual reality because of their slim formfactor,lightweight,and high optical efficiency.However,chromatic aberration remains a serious longstanding problem for diffractive optics,hindering their broader adoption.To overcome the chromatic aberrations for red,green and blue(RGB)light sources,in this paper,we propose a counterintuitive multi-twist structure to achieve narrowband PBOEs without crosstalk,which plays a vital role to eliminate the chromatic aberration.The performance of our designed and fabricated narrowband Pacharatnam-Berry lenses(PBLs)aligns well with our simulation results.Furthermore,in a feasibility demonstration experiment using a laser projector,our proposed PBL system indeed exhibits a diminished chromatic aberration as compared to a broadband PBL.Additionally,polarization raytracing is implemented to demonstrate the versatility of the multi-twist structure for designing any RGB wavelengths with high contrast ratios.This analysis explores the feasibility of using RGB laser lines and quantum dot light-emitting diodes.Overall,our approach enables high optical efficiency,low fabrication complexity,and high degree of design freedom to accommodate any liquid crystal material and RGB light sources,holding immense potential for widespread applications of achromatic PBOEs.展开更多
Diffractive optical elements（DOEs） with spectrum separation and beam concentration（SSBC） functions have important applications in solar cell systems. With the SSBC DOEs, the sunlight radiation is divided into seve...Diffractive optical elements（DOEs） with spectrum separation and beam concentration（SSBC） functions have important applications in solar cell systems. With the SSBC DOEs, the sunlight radiation is divided into several wave bands so as to be effectively absorbed by photovoltaic materials with different band gaps. A new method is proposed for designing high-efficiency SSBC DOEs, which is physically simple, numerically fast, and universally applicable. The SSBC DOEs are designed by the new design method, and their performances are analyzed by the Fresnel diffraction integral method.The new design method takes two advantages over the previous design method. Firstly, the optical focusing efficiency is heightened by up to 10%. Secondly, focal positions of all the designed wavelengths can be designated arbitrarily and independently. It is believed that the designed SSBC DOEs should have practical applications to solar cell systems.展开更多
In the Fresnel transform domain, an effective improvement to the conventional iterative algorithm for designing the diffractive optical elements (DOEs) used for spatial beam shaping has been proposed. The algorithm ca...In the Fresnel transform domain, an effective improvement to the conventional iterative algorithm for designing the diffractive optical elements (DOEs) used for spatial beam shaping has been proposed. The algorithm can successfully achieve to design DOEs for beam shaping. Compared with conventional algorithm, this algorithm can provide faster convergence, more powerful ability to overcome local minimum problem and better shaping quality. By computer simulation, the result has shown that the DOEs designed by this algorithm has snch advantages as high uniformity at the main lobe, low profile error and steep edge.展开更多
1 Introduction 1.1 Advantages of DOE 1)High diffraction efficiency; 2)Dispersive; 3)More selectivity of designing parameters; 4)More selectivity of primary materials; 5)Can make components miniature,forming array and ...1 Introduction 1.1 Advantages of DOE 1)High diffraction efficiency; 2)Dispersive; 3)More selectivity of designing parameters; 4)More selectivity of primary materials; 5)Can make components miniature,forming array and integration. 1.2 1.3 megapixel triplet plastic mobile展开更多
In this paper,a novel method is proposed and employed to design a single diffractive optical element（DOE） for implementing spectrum-splitting and beam-concentration（SSBC） functions simultaneously.We develop an opt...In this paper,a novel method is proposed and employed to design a single diffractive optical element（DOE） for implementing spectrum-splitting and beam-concentration（SSBC） functions simultaneously.We develop an optimization algorithm,through which the SSBC DOE can be optimized within an arbitrary thickness range according to the limitations of modern photolithography technology.Theoretical simulation results reveal that the designed SSBC DOE has a high optical focusing efficiency.It is expected that the designed SSBC DOE should have practical applications in high-efficiency solar cell systems.展开更多
Based on the facts that multijunction solar cells can increase the efficiency and concentration can reduce the cost dramatically, a special design of parallel multijunction solar cells was presented. The design employ...Based on the facts that multijunction solar cells can increase the efficiency and concentration can reduce the cost dramatically, a special design of parallel multijunction solar cells was presented. The design employed a diffractive optical element （DOE） to split and concentrate the sunlight. A rainbow region and a zero-order diffraction region were generated on the output plane where solar cells with corresponding band gaps were placed. An analytical expression of the light intensity distribution on the output plane of the special DOE was deduced, and the limiting photovoltaic efficiency of such parallel multijunction solar ceils was obtained based on Shockley-Queisser＇s theory. An efficiency exceeding the Shockley--Queisser limit （33%） can be expected using multijunction solar cells consisting of separately fabricated subcells. The results provide an important alternative approach to realize high photovoltaic efficiency without the need for expensive epitaxial technology widely used in tandem solar cells, thus stimulating the research and application of high efficiency and low cost solar cells.展开更多
Two improved algorithms are proposed to extend a diffractive optical element （DOE） to work under the broad spec- trum of sunlight. An optimum design has been found for the DOE, with a weighted average optical effici...Two improved algorithms are proposed to extend a diffractive optical element （DOE） to work under the broad spec- trum of sunlight. An optimum design has been found for the DOE, with a weighted average optical efficiency of about 6.8% better than that of the previous design. The optimization of designing high optical efficiency DOEs will pave the way for future designs of high-efficiency, low-cost lateral multijunction solar cells based on such a DOE.展开更多
The bauxite mineral obtained from Araku, Vishakapatnam district of Andhra Pradesh, India is used in the present work. Structural characterization was performed by X-ray diffraction (XRD). The mineral was found to be g...The bauxite mineral obtained from Araku, Vishakapatnam district of Andhra Pradesh, India is used in the present work. Structural characterization was performed by X-ray diffraction (XRD). The mineral was found to be gibbsite in phase. The transitional metal ions present were investigated using electron paramagnetic resonance (EPR) and optical absorption spectra. The EPR results suggest that Fe3+ has replaced Al3+ in the unit cell of bauxite. The optical absorption spectrum is due to Fe3+ which indicates that it is in distorted octahedral environment. The near-infrared (NIR) spectrum is due to water fundamentals and combination overtones, which confirm the formula of the compound. The impurities in the mineral are identified using spectroscopic techniques.展开更多
We propose a promising method to develop flexible,compact,and tunable light-activated film diffractive optical elements(FDOEs)with exceptional diffraction efficiency,by integrating liquid crystal(LC)geometric phase-ba...We propose a promising method to develop flexible,compact,and tunable light-activated film diffractive optical elements(FDOEs)with exceptional diffraction efficiency,by integrating liquid crystal(LC)geometric phase-based diffractive optical elements(DOEs)with a specifically designed light-activated LC polymer(LCP)film.Arbitrary film bending induced by UV/Vis irradiation is realized through precise mesogens arrangement within the LCP film,enabling 1D and 2D beam steering,as well as dynamic and reversible switching between structured and Gaussian lights after cooperating with the DOE design.Furthermore,remarkable fatigue resistance,solvent resistance,and thermal stability are demonstrated,providing a solid material platform for advanced optical applications.展开更多
Diffractive optics is an important technique for beam shaping with high light efficiency and strong diffraction pattern flexibility. Since the diffraction angle is limited by the unit size of the diffractive optical e...Diffractive optics is an important technique for beam shaping with high light efficiency and strong diffraction pattern flexibility. Since the diffraction angle is limited by the unit size of the diffractive optical element （DOE）, the size of the required diffraction pattern is always rather small. In this Letter, refractive/diffractive hybrid optical elements （RDHOEs） consisting of a DOE and a lens are used to realize beam shaping for a large diffraction pattern. The lens, as the component of the RDHOEs, can not only be concave but also convex, and the double sampling Fresnel diffraction algorithm is developed for the design of these two types of RDHOEs. The simulation and experimental results provide solid evidence to demonstrate the proposed method with the pure phase spatial light modulator.展开更多
Novel red emitting Eu3＋ doped SrGd2O4 phosphors were synthesized by homogeneous precipitation method followed by a subsequent combustion process at various temperatures. A systematic study on the consequent structura...Novel red emitting Eu3＋ doped SrGd2O4 phosphors were synthesized by homogeneous precipitation method followed by a subsequent combustion process at various temperatures. A systematic study on the consequent structural evolution and optical properties were investigated as a function of various processing temperatures. With the enhancement of processing temperature, SrGd2O4 phosphor showed a gradual transformation from a mixed phase to monophasic nature, with minimized volatile imptwities. The microscopic images exhibited homogeneous aggregates of varying shapes and sizes with an average length of about 0.5-5μl. Eu3＋ doped SrGd2O4 phosphors prepared at low temperatures, showed miserably low values of red emission upon UV excitation owing to the presence of volatile impurities. The SrGd2O4：Eu3＋ phosphors prepared at relatively high temperature exhibited strong red-orange emissions due to homogeneously occupied Eu3＋ ions in the host lattice. The dominant red to orange （R/O） emission intensity ratios and CIE parameters of EU3＋ ions substantiated the site occupation of higher asymmetry sites of Gd3＋ ions and the strong covalent nature. Dexter theory and critical distance calculation suggested that the dipole-dipole interaction could be responsible for the concentration quenching of Eu3＋ （4 mol.%） doped SrGd2O4 phosphors. Elevated physical and chemical durability and stable photoluminescence made these phosphors suitable for white LEDs and other display applications.展开更多
Copper nitride （Cu3N） films were prepared by reactive radio frequency magnetron sputtering at various nitrogen partial pressures, and the films were annealed at different temperatures. The crystal structure of the f...Copper nitride （Cu3N） films were prepared by reactive radio frequency magnetron sputtering at various nitrogen partial pressures, and the films were annealed at different temperatures. The crystal structure of the films was identified by X-ray diffraction technique. The Cu3N films have a cubic anti-ReO3 structure, and lattice constant is 0.3855 nm. With increasing nitrogen partial pressure, the Cu3N films are strongly textured with the crystal direction [100]. The atomic force microscope images show that the films presence a smooth and compact morphology with nanocrystallites of about 70 nm in size. The films were further characterized by UV-visible spectrometer, and the optical band gap of the films was calculated from the Tauc equation. The typical value of optical band gap of the films is about 1.75 eV, and it increases with increasing nitrogen partial pressure. The thermal property of the films was measured by thermogravimetry, and the decomposition temperature of the films was about 530 K.展开更多
Diffractive optical elements(DOEs)are intricately designed devices with the purpose of manipulating light fields by precisely modifying their wavefronts.The concept of DOEs has its origins dating back to 1948 when D.G...Diffractive optical elements(DOEs)are intricately designed devices with the purpose of manipulating light fields by precisely modifying their wavefronts.The concept of DOEs has its origins dating back to 1948 when D.Gabor first introduced holography.Subsequently,researchers introduced binary optical elements(BOEs),including computer-generated holograms(CGHs),as a distinct category within the realm of DOEs.This was the first revolution in optical devices.The next major breakthrough in light field manipulation occurred during the early 21st century,marked by the advent of metamaterials and metasurfaces.Metasurfaces are particularly appealing due to their ultra-thin,ultra-compact properties and their capacity to exert precise control over virtually every aspect of light fields,including amplitude,phase,polarization,wavelength/frequency,angular momentum,etc.The advancement of light field manipulation with micro/nano-structures has also enabled various applications in fields such as information acquisition,transmission,storage,processing,and display.In this review,we cover the fundamental science,cutting-edge technologies,and wide-ranging applications associated with micro/nano-scale optical devices for regulating light fields.We also delve into the prevailing challenges in the pursuit of developing viable technology for real-world applications.Furthermore,we offer insights into potential future research trends and directions within the realm of light field manipulation.展开更多
The SiO2-Fe3O4 core-shell nanostructures were synthesized by sol-gel chemistry. The morphological features of the nanostructures were examined by field emission scanning electron microscopy which revealed the core-she...The SiO2-Fe3O4 core-shell nanostructures were synthesized by sol-gel chemistry. The morphological features of the nanostructures were examined by field emission scanning electron microscopy which revealed the core-shell nature of the nanoparticles. X-ray diffraction studies evidenced the formation of SiO2-Fe3O4 core-shell nanostructures with high degree of homogeneity. The elemental composition of the SiO2-Fe3O4 core-shell nanostructures was determined by energy-dispersive X-ray spectroscopy analysis. Fourier transform infrared spectroscopy showed the Si-O-Fe stretching vibrations. On analysis of the optical properties with UV-Vis spectra and Tauc＇s plot, it was found that the band gap of SiO2-Fe3O4 core-shell nanostructures diminished to 1.5 eV. Investigation of the electrical properties of the core-shell nanostructures using field-dependent conductivity measurements presented a significant increase in photoconductivity as compared to those of its single components, thereby rendering them as promising candidates for application as photo- electrodes in dye-sensitized solar cells.展开更多
zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is character...zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is characterized by using the X-ray Powder diffraction(XRPD) and infrared (IR) spectroscopy at room temperature. TheAbsorptions of intrinsic ions and ZCTC in a solution state arediscussed as well as Transmission properties of the ZCTC crystal. Aneffective method of reducing the surface Reflection loss of ZCTCcrystal is introduced.展开更多
YPO4：Eu3＋ phosphors were synthesized by solution coprecipitation method assisted by urea in the precursor reaction solution. X-ray diffraction spectral analysis showed that the samples synthesized with urea had smal...YPO4：Eu3＋ phosphors were synthesized by solution coprecipitation method assisted by urea in the precursor reaction solution. X-ray diffraction spectral analysis showed that the samples synthesized with urea had smaller particle size and lower crystaUinity than those samples synthesized without urea. Moreover, the calculated strain result indicated that the Eu^3＋ site in the former exhibited a lower crystal field symmetry-than that in the latter. Hence, the influence of crystal field symmetry dominated luminescence efficiency rather than crystallinity because the luminescence intensity observed in Eu0.05Y0.95PO4 synthesized with 1.0 g urea was six-fold higher than that of the as-synthesized sample. With increased concentration of Eu^3＋ ion, the luminescence intensity initially increased, and then subsequently decreased as the concentration of Eu^3＋ ion exceeded 12 mol.% due to concentration quenching. The optimal condition for YPO4：Eu^3＋ phosphor was Eu0.12Y0.88PO4 with 1.0 g urea added in the precursor. The luminescence intensity of the optimal condition was again enhanced 1.6-fold relative to that of Eu0.05Y0.95PO4 synthesized with 1.0 g urea.展开更多
Au nanoparticles dispersed NiO composite films were prepared by a chemical solution method.The phase structure,microstructure,surface chemical state,and optical absorption properties of the films were characterized by...Au nanoparticles dispersed NiO composite films were prepared by a chemical solution method.The phase structure,microstructure,surface chemical state,and optical absorption properties of the films were characterized by X-ray diffraction,transmission electron microscopy,X-ray photoelectron spectroscopy,and Uv-vis spectrometer.The results indicate that Au particles with the average diameters of 35-42 nm are approximately spherical and disperse in the NiO matrix.The optical absorption peaks due to the surface plasmon resonance of Au particles shift to the shorter wavelength and intensify with the increase of Au content.The bandwidth narrows when the Au content increases from 8.4wt% to 45.2wt%,but widens by further increasing the Au content from 45.2wt% to 60.5wt%.The band gap Eg increases with the increase of Au contents from 8.4wt% to 45.2wt%,but decreases by further increasing the Au content.展开更多
This paper presented the studies on the optical properties and calculation of spectral parameters of europium doped lanthanum oxychloride nanophosphor for their possible applications in optoelectronic devices. The com...This paper presented the studies on the optical properties and calculation of spectral parameters of europium doped lanthanum oxychloride nanophosphor for their possible applications in optoelectronic devices. The compound was doped with 0.1 mol% Eu3＋ ions. The X-ray diffraction study of prepared sample suggested the tetragonal structure with particle size in the range of 18–21 nm. The photoluminescence （PL） emission spectra showed the bright emission in orange-red region from 580 to 630 nm. The most intense emission peak at 621 nm was due to transition 5D0→7F2 in energy levels of Eu3＋ ions. The spectral parameters were calculated from the absorption and emission spectra using Judd-Ofelt intensity parameters. The calculated values of the oscillator strength corresponding to the three transitions 7F1→5D1, 7F1→5D2 and 7F0→5D2 observed at 535, 472 and 465 nm in absorption spectra were 0.30×10–6, 1.36×10–6 and 0.63×10–6, respectively. The value of transi- tion probability （A）, stimulated emission cross-section （ ） and radiative lifetime （τrad） corresponding to 621 nm emission peak （transition 5D0→7F2） were 308 s–1, 1.22×10–21 cm2 and 3.24×10–3 s, respectively.展开更多
Bulk materials were synthesized by the Bridgman technique using the elements Cu, Ga, Se. These samples were characterized by Energy Dispersive Spectrometry (EDS) to determine the elemental composition, as well as by X...Bulk materials were synthesized by the Bridgman technique using the elements Cu, Ga, Se. These samples were characterized by Energy Dispersive Spectrometry (EDS) to determine the elemental composition, as well as by X-ray diffraction for structure, hot point probe method for type of conductivity. Optical response (Photoconductivity) and Photoluminescence (PL) and PL-excitation (PLE) at temperatures from 4.2 to 77 K were also used to estimate the band-gap energy of Cu-Ga<sub>3</sub>Se<sub>5</sub>. They show a nearly perfect stoechiometry and present p-type conductivity. CuGa<sub>3</sub>Se<sub>5</sub> either have an Ordered Defect Chalcopyrite structure (ODC), or an Ordered Vacancy Chalcopyrite structure (OVC). The gap energy obtained by Photoconductivity and Photoluminescence (PL) for the different samples is 1.85 eV. Studying the variation of the gap as a function of the temperature shows that the transition is a D-A type. The defects that appear are probably Ga<sub>Cu</sub>.展开更多
Thin films of zinc-doped cadmium oxide with different Zn-doping levels（0, 2, 4, 6, and 8 at%） were deposited on glass substrates by employing an inexpensive, simplified spray technique using perfume atomizer at rela...Thin films of zinc-doped cadmium oxide with different Zn-doping levels（0, 2, 4, 6, and 8 at%） were deposited on glass substrates by employing an inexpensive, simplified spray technique using perfume atomizer at relatively low substrate temperature（375 °C） compared with the conventional spray method. The effect of Zn doping on the structural,morphological, optical, and electrical properties of the films was investigated. XRD patterns revealed that all the films are polycrystalline in nature having cubic crystal structure with a preferential orientation along the（1 1 1） plane irrespective of Zn-doping level. Zn-doping level causes a slight shift in the（1 1 1） diffraction peak toward higher angle. The crystallite size of the films was found to be in the range of 28–37 nm. The band gap value increases with Zn doping and reaches a maximum of 2.65 eV for the film coated with 6 at% Zn doping and for further higher doping concentration it decreases.Electrical studies indicate that Zn doping causes a reduction in the resistivity of the films and a minimum resistivity of15.69 X cm is observed for the film coated with 6 at% Zn.展开更多
基金supports from the National Key Research and Development Program of China(2023YFB2806803)the National Natural Science Foundation of China(62075127).
文摘Liquid crystal Pacharatnam-Berry phase optical elements(PBOEs)have found promising applications in augmented reality and virtual reality because of their slim formfactor,lightweight,and high optical efficiency.However,chromatic aberration remains a serious longstanding problem for diffractive optics,hindering their broader adoption.To overcome the chromatic aberrations for red,green and blue(RGB)light sources,in this paper,we propose a counterintuitive multi-twist structure to achieve narrowband PBOEs without crosstalk,which plays a vital role to eliminate the chromatic aberration.The performance of our designed and fabricated narrowband Pacharatnam-Berry lenses(PBLs)aligns well with our simulation results.Furthermore,in a feasibility demonstration experiment using a laser projector,our proposed PBL system indeed exhibits a diminished chromatic aberration as compared to a broadband PBL.Additionally,polarization raytracing is implemented to demonstrate the versatility of the multi-twist structure for designing any RGB wavelengths with high contrast ratios.This analysis explores the feasibility of using RGB laser lines and quantum dot light-emitting diodes.Overall,our approach enables high optical efficiency,low fabrication complexity,and high degree of design freedom to accommodate any liquid crystal material and RGB light sources,holding immense potential for widespread applications of achromatic PBOEs.
基金Project supported by the National Basic Research Program of China(Grant No.2013CBA01702)the National Natural Science Foundation of China(Grant Nos.11474206,91233202,11374216,and 11404224)+1 种基金the Scientific Research Project of Beijing Education Commission,China(Grant No.KM201310028005)the Scientific Research Base Development Program of the Beijing Municipal Commission of Education and the Beijing Youth Top-Notch Talent Training Plan,China(Grant No.CIT&TCD201504080)
文摘Diffractive optical elements（DOEs） with spectrum separation and beam concentration（SSBC） functions have important applications in solar cell systems. With the SSBC DOEs, the sunlight radiation is divided into several wave bands so as to be effectively absorbed by photovoltaic materials with different band gaps. A new method is proposed for designing high-efficiency SSBC DOEs, which is physically simple, numerically fast, and universally applicable. The SSBC DOEs are designed by the new design method, and their performances are analyzed by the Fresnel diffraction integral method.The new design method takes two advantages over the previous design method. Firstly, the optical focusing efficiency is heightened by up to 10%. Secondly, focal positions of all the designed wavelengths can be designated arbitrarily and independently. It is believed that the designed SSBC DOEs should have practical applications to solar cell systems.
文摘In the Fresnel transform domain, an effective improvement to the conventional iterative algorithm for designing the diffractive optical elements (DOEs) used for spatial beam shaping has been proposed. The algorithm can successfully achieve to design DOEs for beam shaping. Compared with conventional algorithm, this algorithm can provide faster convergence, more powerful ability to overcome local minimum problem and better shaping quality. By computer simulation, the result has shown that the DOEs designed by this algorithm has snch advantages as high uniformity at the main lobe, low profile error and steep edge.
文摘1 Introduction 1.1 Advantages of DOE 1)High diffraction efficiency; 2)Dispersive; 3)More selectivity of designing parameters; 4)More selectivity of primary materials; 5)Can make components miniature,forming array and integration. 1.2 1.3 megapixel triplet plastic mobile
基金Project supported by the National Basic Research Program of China (Grant No. 2011CB301801)the National Natural Science Foundation of China (GrantNos. 91233202,10904099,11204188,61205097,and 11174211)
文摘In this paper,a novel method is proposed and employed to design a single diffractive optical element（DOE） for implementing spectrum-splitting and beam-concentration（SSBC） functions simultaneously.We develop an optimization algorithm,through which the SSBC DOE can be optimized within an arbitrary thickness range according to the limitations of modern photolithography technology.Theoretical simulation results reveal that the designed SSBC DOE has a high optical focusing efficiency.It is expected that the designed SSBC DOE should have practical applications in high-efficiency solar cell systems.
基金supported by the National Natural Science Foundation of China(Grant Nos.91233202,21173260,and 51072221)the National Basic Research Program of China(Grant No.2012CB932903)
文摘Based on the facts that multijunction solar cells can increase the efficiency and concentration can reduce the cost dramatically, a special design of parallel multijunction solar cells was presented. The design employed a diffractive optical element （DOE） to split and concentrate the sunlight. A rainbow region and a zero-order diffraction region were generated on the output plane where solar cells with corresponding band gaps were placed. An analytical expression of the light intensity distribution on the output plane of the special DOE was deduced, and the limiting photovoltaic efficiency of such parallel multijunction solar ceils was obtained based on Shockley-Queisser＇s theory. An efficiency exceeding the Shockley--Queisser limit （33%） can be expected using multijunction solar cells consisting of separately fabricated subcells. The results provide an important alternative approach to realize high photovoltaic efficiency without the need for expensive epitaxial technology widely used in tandem solar cells, thus stimulating the research and application of high efficiency and low cost solar cells.
基金Project supported by the National Natural Science Foundation of China(Grants Nos.91233202,21173260,and 51072221)the National Basic Research Program of China(Grant No.2012CB932903
文摘Two improved algorithms are proposed to extend a diffractive optical element （DOE） to work under the broad spec- trum of sunlight. An optimum design has been found for the DOE, with a weighted average optical efficiency of about 6.8% better than that of the previous design. The optimization of designing high optical efficiency DOEs will pave the way for future designs of high-efficiency, low-cost lateral multijunction solar cells based on such a DOE.
文摘The bauxite mineral obtained from Araku, Vishakapatnam district of Andhra Pradesh, India is used in the present work. Structural characterization was performed by X-ray diffraction (XRD). The mineral was found to be gibbsite in phase. The transitional metal ions present were investigated using electron paramagnetic resonance (EPR) and optical absorption spectra. The EPR results suggest that Fe3+ has replaced Al3+ in the unit cell of bauxite. The optical absorption spectrum is due to Fe3+ which indicates that it is in distorted octahedral environment. The near-infrared (NIR) spectrum is due to water fundamentals and combination overtones, which confirm the formula of the compound. The impurities in the mineral are identified using spectroscopic techniques.
基金the National Key Research and Development Program of China(No.2022YFA1203700)the National Natural Science Foundation of China(Nos.62275081,62035008,and 22305079)+4 种基金the Innovation Program of Shanghai Municipal Education Commission,Scientific Committee of Shanghai(No.2021-01-07-00-02-E00107)the“Shuguang Program”of Shanghai Education Development Foundation,the Shanghai Municipal Education Commission(No.21SG29)the Shanghai Sailing Program(No.23YF1409000)the Fellowship of China National Postdoctoral Program for Innovative Talents(No.BX20230125)the Postdoctoral Fellowship Program of CPSF(No.GZB20240218)。
文摘We propose a promising method to develop flexible,compact,and tunable light-activated film diffractive optical elements(FDOEs)with exceptional diffraction efficiency,by integrating liquid crystal(LC)geometric phase-based diffractive optical elements(DOEs)with a specifically designed light-activated LC polymer(LCP)film.Arbitrary film bending induced by UV/Vis irradiation is realized through precise mesogens arrangement within the LCP film,enabling 1D and 2D beam steering,as well as dynamic and reversible switching between structured and Gaussian lights after cooperating with the DOE design.Furthermore,remarkable fatigue resistance,solvent resistance,and thermal stability are demonstrated,providing a solid material platform for advanced optical applications.
基金partially supported by the National Key Basic Research Program of China(No.2013CB329202)the National Scientific Equipment Development SpecialFoundation of China(No.2011YQ03013401)+1 种基金the National Natural Science Foundation of China(No.61475021)the Beijing Natural Science Foundation(No.4152015)
文摘Diffractive optics is an important technique for beam shaping with high light efficiency and strong diffraction pattern flexibility. Since the diffraction angle is limited by the unit size of the diffractive optical element （DOE）, the size of the required diffraction pattern is always rather small. In this Letter, refractive/diffractive hybrid optical elements （RDHOEs） consisting of a DOE and a lens are used to realize beam shaping for a large diffraction pattern. The lens, as the component of the RDHOEs, can not only be concave but also convex, and the double sampling Fresnel diffraction algorithm is developed for the design of these two types of RDHOEs. The simulation and experimental results provide solid evidence to demonstrate the proposed method with the pure phase spatial light modulator.
基金Project supported by ISM Research Scholars Funding by Government of India
文摘Novel red emitting Eu3＋ doped SrGd2O4 phosphors were synthesized by homogeneous precipitation method followed by a subsequent combustion process at various temperatures. A systematic study on the consequent structural evolution and optical properties were investigated as a function of various processing temperatures. With the enhancement of processing temperature, SrGd2O4 phosphor showed a gradual transformation from a mixed phase to monophasic nature, with minimized volatile imptwities. The microscopic images exhibited homogeneous aggregates of varying shapes and sizes with an average length of about 0.5-5μl. Eu3＋ doped SrGd2O4 phosphors prepared at low temperatures, showed miserably low values of red emission upon UV excitation owing to the presence of volatile impurities. The SrGd2O4：Eu3＋ phosphors prepared at relatively high temperature exhibited strong red-orange emissions due to homogeneously occupied Eu3＋ ions in the host lattice. The dominant red to orange （R/O） emission intensity ratios and CIE parameters of EU3＋ ions substantiated the site occupation of higher asymmetry sites of Gd3＋ ions and the strong covalent nature. Dexter theory and critical distance calculation suggested that the dipole-dipole interaction could be responsible for the concentration quenching of Eu3＋ （4 mol.%） doped SrGd2O4 phosphors. Elevated physical and chemical durability and stable photoluminescence made these phosphors suitable for white LEDs and other display applications.
基金supported by the National Natural Science Foundation of China (Garnt No. 11064003)the Guangxi Natural Science Foundation of China(2010GXNSFA013122)
文摘Copper nitride （Cu3N） films were prepared by reactive radio frequency magnetron sputtering at various nitrogen partial pressures, and the films were annealed at different temperatures. The crystal structure of the films was identified by X-ray diffraction technique. The Cu3N films have a cubic anti-ReO3 structure, and lattice constant is 0.3855 nm. With increasing nitrogen partial pressure, the Cu3N films are strongly textured with the crystal direction [100]. The atomic force microscope images show that the films presence a smooth and compact morphology with nanocrystallites of about 70 nm in size. The films were further characterized by UV-visible spectrometer, and the optical band gap of the films was calculated from the Tauc equation. The typical value of optical band gap of the films is about 1.75 eV, and it increases with increasing nitrogen partial pressure. The thermal property of the films was measured by thermogravimetry, and the decomposition temperature of the films was about 530 K.
基金supported by the Guangdong Major Project of Basic and Applied Basic Research(No.2020B0301030009)the National Natural Science Foundation of China(Nos.62235009,62035003,62205173,61935013,62375181,61975133,and 12104318)+1 种基金the Science and Technology Innovation Commission of Shenzhen(Nos.KQTD20170330110444030 and JCYJ20200109114018750)the Scientific Instrument Developing Project of Shenzhen University(No.2023YQ001).
文摘Diffractive optical elements(DOEs)are intricately designed devices with the purpose of manipulating light fields by precisely modifying their wavefronts.The concept of DOEs has its origins dating back to 1948 when D.Gabor first introduced holography.Subsequently,researchers introduced binary optical elements(BOEs),including computer-generated holograms(CGHs),as a distinct category within the realm of DOEs.This was the first revolution in optical devices.The next major breakthrough in light field manipulation occurred during the early 21st century,marked by the advent of metamaterials and metasurfaces.Metasurfaces are particularly appealing due to their ultra-thin,ultra-compact properties and their capacity to exert precise control over virtually every aspect of light fields,including amplitude,phase,polarization,wavelength/frequency,angular momentum,etc.The advancement of light field manipulation with micro/nano-structures has also enabled various applications in fields such as information acquisition,transmission,storage,processing,and display.In this review,we cover the fundamental science,cutting-edge technologies,and wide-ranging applications associated with micro/nano-scale optical devices for regulating light fields.We also delve into the prevailing challenges in the pursuit of developing viable technology for real-world applications.Furthermore,we offer insights into potential future research trends and directions within the realm of light field manipulation.
文摘The SiO2-Fe3O4 core-shell nanostructures were synthesized by sol-gel chemistry. The morphological features of the nanostructures were examined by field emission scanning electron microscopy which revealed the core-shell nature of the nanoparticles. X-ray diffraction studies evidenced the formation of SiO2-Fe3O4 core-shell nanostructures with high degree of homogeneity. The elemental composition of the SiO2-Fe3O4 core-shell nanostructures was determined by energy-dispersive X-ray spectroscopy analysis. Fourier transform infrared spectroscopy showed the Si-O-Fe stretching vibrations. On analysis of the optical properties with UV-Vis spectra and Tauc＇s plot, it was found that the band gap of SiO2-Fe3O4 core-shell nanostructures diminished to 1.5 eV. Investigation of the electrical properties of the core-shell nanostructures using field-dependent conductivity measurements presented a significant increase in photoconductivity as compared to those of its single components, thereby rendering them as promising candidates for application as photo- electrodes in dye-sensitized solar cells.
文摘zinc cadmium thiocyanate (ZCTC), ZnCd(SCN)_4, has been discoveredas a UV second-order nonlinear optical coordination crystal. Titsthermal and transmission Properties are reported. The thermaldecomposition is characterized by using the X-ray Powder diffraction(XRPD) and infrared (IR) spectroscopy at room temperature. TheAbsorptions of intrinsic ions and ZCTC in a solution state arediscussed as well as Transmission properties of the ZCTC crystal. Aneffective method of reducing the surface Reflection loss of ZCTCcrystal is introduced.
基金the National Natural Scientific Foundation of China(10874144)the Scientific Foundation of Education Department of Hunan Province,China(06C818)
文摘YPO4：Eu3＋ phosphors were synthesized by solution coprecipitation method assisted by urea in the precursor reaction solution. X-ray diffraction spectral analysis showed that the samples synthesized with urea had smaller particle size and lower crystaUinity than those samples synthesized without urea. Moreover, the calculated strain result indicated that the Eu^3＋ site in the former exhibited a lower crystal field symmetry-than that in the latter. Hence, the influence of crystal field symmetry dominated luminescence efficiency rather than crystallinity because the luminescence intensity observed in Eu0.05Y0.95PO4 synthesized with 1.0 g urea was six-fold higher than that of the as-synthesized sample. With increased concentration of Eu^3＋ ion, the luminescence intensity initially increased, and then subsequently decreased as the concentration of Eu^3＋ ion exceeded 12 mol.% due to concentration quenching. The optimal condition for YPO4：Eu^3＋ phosphor was Eu0.12Y0.88PO4 with 1.0 g urea added in the precursor. The luminescence intensity of the optimal condition was again enhanced 1.6-fold relative to that of Eu0.05Y0.95PO4 synthesized with 1.0 g urea.
基金supported by the Major State Basic Research Development Program of China(No.2007CB613301)the National Natural Science Foundation of China(Nos.50842028 and 50972012)
文摘Au nanoparticles dispersed NiO composite films were prepared by a chemical solution method.The phase structure,microstructure,surface chemical state,and optical absorption properties of the films were characterized by X-ray diffraction,transmission electron microscopy,X-ray photoelectron spectroscopy,and Uv-vis spectrometer.The results indicate that Au particles with the average diameters of 35-42 nm are approximately spherical and disperse in the NiO matrix.The optical absorption peaks due to the surface plasmon resonance of Au particles shift to the shorter wavelength and intensify with the increase of Au content.The bandwidth narrows when the Au content increases from 8.4wt% to 45.2wt%,but widens by further increasing the Au content from 45.2wt% to 60.5wt%.The band gap Eg increases with the increase of Au contents from 8.4wt% to 45.2wt%,but decreases by further increasing the Au content.
文摘This paper presented the studies on the optical properties and calculation of spectral parameters of europium doped lanthanum oxychloride nanophosphor for their possible applications in optoelectronic devices. The compound was doped with 0.1 mol% Eu3＋ ions. The X-ray diffraction study of prepared sample suggested the tetragonal structure with particle size in the range of 18–21 nm. The photoluminescence （PL） emission spectra showed the bright emission in orange-red region from 580 to 630 nm. The most intense emission peak at 621 nm was due to transition 5D0→7F2 in energy levels of Eu3＋ ions. The spectral parameters were calculated from the absorption and emission spectra using Judd-Ofelt intensity parameters. The calculated values of the oscillator strength corresponding to the three transitions 7F1→5D1, 7F1→5D2 and 7F0→5D2 observed at 535, 472 and 465 nm in absorption spectra were 0.30×10–6, 1.36×10–6 and 0.63×10–6, respectively. The value of transi- tion probability （A）, stimulated emission cross-section （ ） and radiative lifetime （τrad） corresponding to 621 nm emission peak （transition 5D0→7F2） were 308 s–1, 1.22×10–21 cm2 and 3.24×10–3 s, respectively.
文摘Bulk materials were synthesized by the Bridgman technique using the elements Cu, Ga, Se. These samples were characterized by Energy Dispersive Spectrometry (EDS) to determine the elemental composition, as well as by X-ray diffraction for structure, hot point probe method for type of conductivity. Optical response (Photoconductivity) and Photoluminescence (PL) and PL-excitation (PLE) at temperatures from 4.2 to 77 K were also used to estimate the band-gap energy of Cu-Ga<sub>3</sub>Se<sub>5</sub>. They show a nearly perfect stoechiometry and present p-type conductivity. CuGa<sub>3</sub>Se<sub>5</sub> either have an Ordered Defect Chalcopyrite structure (ODC), or an Ordered Vacancy Chalcopyrite structure (OVC). The gap energy obtained by Photoconductivity and Photoluminescence (PL) for the different samples is 1.85 eV. Studying the variation of the gap as a function of the temperature shows that the transition is a D-A type. The defects that appear are probably Ga<sub>Cu</sub>.
文摘Thin films of zinc-doped cadmium oxide with different Zn-doping levels（0, 2, 4, 6, and 8 at%） were deposited on glass substrates by employing an inexpensive, simplified spray technique using perfume atomizer at relatively low substrate temperature（375 °C） compared with the conventional spray method. The effect of Zn doping on the structural,morphological, optical, and electrical properties of the films was investigated. XRD patterns revealed that all the films are polycrystalline in nature having cubic crystal structure with a preferential orientation along the（1 1 1） plane irrespective of Zn-doping level. Zn-doping level causes a slight shift in the（1 1 1） diffraction peak toward higher angle. The crystallite size of the films was found to be in the range of 28–37 nm. The band gap value increases with Zn doping and reaches a maximum of 2.65 eV for the film coated with 6 at% Zn doping and for further higher doping concentration it decreases.Electrical studies indicate that Zn doping causes a reduction in the resistivity of the films and a minimum resistivity of15.69 X cm is observed for the film coated with 6 at% Zn.
