Owing to its high theoretical capacity and low cost,Sn has attracted significant attention in sodium-ion batteries.However,the slow kinetics of electrochemical reactions and the rapid decay of capacity resulting from ...Owing to its high theoretical capacity and low cost,Sn has attracted significant attention in sodium-ion batteries.However,the slow kinetics of electrochemical reactions and the rapid decay of capacity resulting from drastic changes in the volume of Sn,as well as persistent side reactions between Sn and the organic electrolyte during the(de)sodium process,have limited its commercialization.To improve the electrochemical performance of Sn-based materials,the bottom-up method is normally used to prepare carbon-coated nanoparticles.However,its complex preparation processes and harsh conditions make it unsuitable for practical applications.Herein,a carbon-coated hybrid crystal composite(Sn/SnO_(x)@C)was prepared using an up-bottom method with commercial Sn/SnO nanoparticles.Various effects accelerate the electrochemical kinetics and inhibit the coarsening of Sn crystals.The Sn/SnO_(x)@C composite electrode exhibited capacity retention of 80.7%even after approximately 1000 cycles(360.4 mAh·g^(−1)) at a current density of 1 A·g^(−1).The high-load Na_(3)V_(2)(PO4)3||Sn/SnO_(x)@C full cell presents a capacity retention rate of 91.7%after 150 cycles at the current density of 0.5 A·g^(−1).This work may significantly accelerate the commercialization of the Sn/SnO_(x)@C composite in sodium-ion batteries with high energy density.展开更多
This paper studied the preparation and mechanical properties of glass fiber reinforced polymer-matrix composite rings prepared by filament winding assisted by ultraviolet(UV)curing.A ray-tracing method was used to cal...This paper studied the preparation and mechanical properties of glass fiber reinforced polymer-matrix composite rings prepared by filament winding assisted by ultraviolet(UV)curing.A ray-tracing method was used to calculate the penetration ability of UV light in the resin casting,and then a typical composite ring with dual⁃curing characteristics was prepared by UV-assisted curing.The effects of winding speed and thermal initiator concentration on the distribution of fiber fraction and mechanical properties were studied.Microscopic morphology was used for the observation of the differences in fiber volume fraction.Mechanical properties tests and scanning electron micrographs were performed to investigate the failure and damage mechanisms of the composite ring samples.The ray tracing results indicate that the UV light can pass through a single yarn thickness and the energy transmitted is sufficient to cure the back side quickly.The experimental results show that the mechanical properties of the composite ring prepared in this paper are comparable to those of the heat-cured samples,which is sufficient to meet the requirements of the flywheel.展开更多
Drug detection is highly important,yet reversible and highly sensitive sensing materials are still scarce.A novel ionogel sensor material,poly(ethylene glycol)diacrylate(PEGDA)/1-butyl-3-methylimidazole tetrafluorobor...Drug detection is highly important,yet reversible and highly sensitive sensing materials are still scarce.A novel ionogel sensor material,poly(ethylene glycol)diacrylate(PEGDA)/1-butyl-3-methylimidazole tetrafluoroborate,was developed for reproducible N-methylphenylethylamine(MPEA)detection.It was fabricated by immobilizing a flowable ionic liquid within a PEGDA network via UV curing.The immobilized ions retain mobility,enabling efficient ionic conduction.Integrated on a flexible poly(ethylene naphthalate)substrate,the sensor is fully transparent and flexible,showing over 72.6% transmittance in the visible spectrum.This allows it to be discreetly attached to surfaces for concealed detection.Using non-covalent interactions,the sensor achieves reproducible MPEA detection at sub ppb levels at room temperature,with a theoretical detection limit of 317 ppt.It also exhibits high selectivity and consistency.Ionic conductivity was confirmed through current voltage tests and impedance spectroscopy,and the sensing mechanism was clarified.The device performs reliably under bending,proving suitable for dynamic environments.With a Bluetooth module for wireless transmission,the sensor shows strong potential for practical and discreet drug monitoring in real world applications.展开更多
Polydimethylsiloxane containing methacryloyloxy and methoxy silane groups(MAPDMS)-microcapsule-SiO_(2)(MPMS)functional materials were prepared by constructing micro-nano hierarchical structures on the surface of MAPDM...Polydimethylsiloxane containing methacryloyloxy and methoxy silane groups(MAPDMS)-microcapsule-SiO_(2)(MPMS)functional materials were prepared by constructing micro-nano hierarchical structures on the surface of MAPDMS matrix.Herein,MAPDMS@1,1-stilbene-modified hydrolyzed polyglycidyl methacrylate/graphene oxide/dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride(MAPDMS@PGMA_(m)/GO/QC18)self-healing microcapsules with compact multi-shell structure were synthesized and combined with nano-SiO_(2)to construct the hierarchical structures.Furthermore,ultraviolet(UV)/moisture dual curing mode was introduced into deep curing reaction and efficient self-healing reaction of the MPMS.The results show that the introduction of UV/moisture dual curing mode and micro-nano hierarchical structure gives MPMS functional materials excellent mechanical properties,antifouling properties,self-healing properties,antibacterial properties.The shear strength and tensile strength of MPMS increase from 3.32 and 4.26 MPa of MAPDMS to 3.81 and 5.06 MPa,respectively.Its static contact angle increases from 115.9°of MAPDMS to 156.5°,its slide angle decreases from 68.5°of MAPDMS to 7.8°,respectively.The antifouling performance of MPMS against seawater,soy sauce,juice,coffee,protein,other contaminants is effectively improved compared with MAPDMS matrix.At the same time,the tensile strength and elongation at break of MPMS after healing reach 98.22%and 96.57%of those in original state,respectively.In addition,the antibacterial rates of MPMS against Escherichia coli and Staphylococcus aureus reach 99.85%and 100%,respectively.The MPMS prepared in this paper is expected to be widely used in marine antifouling,pipeline network,anti-icing,microfluidics,wearable devices,medical devices,electrochemical biosensors,other fields.展开更多
基金This study was financially supported by the National Natural Science Foundation of China(Nos.50835002 and 51105102).
文摘Owing to its high theoretical capacity and low cost,Sn has attracted significant attention in sodium-ion batteries.However,the slow kinetics of electrochemical reactions and the rapid decay of capacity resulting from drastic changes in the volume of Sn,as well as persistent side reactions between Sn and the organic electrolyte during the(de)sodium process,have limited its commercialization.To improve the electrochemical performance of Sn-based materials,the bottom-up method is normally used to prepare carbon-coated nanoparticles.However,its complex preparation processes and harsh conditions make it unsuitable for practical applications.Herein,a carbon-coated hybrid crystal composite(Sn/SnO_(x)@C)was prepared using an up-bottom method with commercial Sn/SnO nanoparticles.Various effects accelerate the electrochemical kinetics and inhibit the coarsening of Sn crystals.The Sn/SnO_(x)@C composite electrode exhibited capacity retention of 80.7%even after approximately 1000 cycles(360.4 mAh·g^(−1)) at a current density of 1 A·g^(−1).The high-load Na_(3)V_(2)(PO4)3||Sn/SnO_(x)@C full cell presents a capacity retention rate of 91.7%after 150 cycles at the current density of 0.5 A·g^(−1).This work may significantly accelerate the commercialization of the Sn/SnO_(x)@C composite in sodium-ion batteries with high energy density.
基金supported by the National Key Laboratory of Science and Technology on Helicopter Transmission(Nanjing University of Aeronautics and Astronautics)(No.HTL-A-20K01)the Pretension and Relaxation Mechanism of Thermoplastic Prepreg Tape Winding with Tension Used to Hi-Speed Permanent Magnet Machine Sleeve(No.51903249)the Priority Academic Program Development of Jiangsu Higher Education Institutions and the Fundamental Research Funds for the Central Universities。
文摘This paper studied the preparation and mechanical properties of glass fiber reinforced polymer-matrix composite rings prepared by filament winding assisted by ultraviolet(UV)curing.A ray-tracing method was used to calculate the penetration ability of UV light in the resin casting,and then a typical composite ring with dual⁃curing characteristics was prepared by UV-assisted curing.The effects of winding speed and thermal initiator concentration on the distribution of fiber fraction and mechanical properties were studied.Microscopic morphology was used for the observation of the differences in fiber volume fraction.Mechanical properties tests and scanning electron micrographs were performed to investigate the failure and damage mechanisms of the composite ring samples.The ray tracing results indicate that the UV light can pass through a single yarn thickness and the energy transmitted is sufficient to cure the back side quickly.The experimental results show that the mechanical properties of the composite ring prepared in this paper are comparable to those of the heat-cured samples,which is sufficient to meet the requirements of the flywheel.
基金supported by the National Key Research and Development Program of China(2022YFB3203502)the National Natural Science Foundation of China(62374115,624B2103,and 22405136)the Natural Science Foundation of the Jiangsu Higher Education Institutions(24KJB430034)。
文摘Drug detection is highly important,yet reversible and highly sensitive sensing materials are still scarce.A novel ionogel sensor material,poly(ethylene glycol)diacrylate(PEGDA)/1-butyl-3-methylimidazole tetrafluoroborate,was developed for reproducible N-methylphenylethylamine(MPEA)detection.It was fabricated by immobilizing a flowable ionic liquid within a PEGDA network via UV curing.The immobilized ions retain mobility,enabling efficient ionic conduction.Integrated on a flexible poly(ethylene naphthalate)substrate,the sensor is fully transparent and flexible,showing over 72.6% transmittance in the visible spectrum.This allows it to be discreetly attached to surfaces for concealed detection.Using non-covalent interactions,the sensor achieves reproducible MPEA detection at sub ppb levels at room temperature,with a theoretical detection limit of 317 ppt.It also exhibits high selectivity and consistency.Ionic conductivity was confirmed through current voltage tests and impedance spectroscopy,and the sensing mechanism was clarified.The device performs reliably under bending,proving suitable for dynamic environments.With a Bluetooth module for wireless transmission,the sensor shows strong potential for practical and discreet drug monitoring in real world applications.
基金the financial support from the National Natural Science Foundation of China(No.52003148)the State Key Laboratory of Marine Resource Utilization in South China Sea,Hainan University(No.MRUKF2021023)+3 种基金the Key Research and Development Project of Shaanxi Province(No.2023-YBGY-475)the Key Scientific Research Project of Education Department of Shaanxi Province(No.22JS003)the Industrialization Project of the State Key Laboratory of Biological Resources and Ecological Environment(Cultivation)of Qinba Region(No.SXC-2310)the start-up funds from the Shaanxi University of Technology(No.SLGRCQD2004).
文摘Polydimethylsiloxane containing methacryloyloxy and methoxy silane groups(MAPDMS)-microcapsule-SiO_(2)(MPMS)functional materials were prepared by constructing micro-nano hierarchical structures on the surface of MAPDMS matrix.Herein,MAPDMS@1,1-stilbene-modified hydrolyzed polyglycidyl methacrylate/graphene oxide/dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride(MAPDMS@PGMA_(m)/GO/QC18)self-healing microcapsules with compact multi-shell structure were synthesized and combined with nano-SiO_(2)to construct the hierarchical structures.Furthermore,ultraviolet(UV)/moisture dual curing mode was introduced into deep curing reaction and efficient self-healing reaction of the MPMS.The results show that the introduction of UV/moisture dual curing mode and micro-nano hierarchical structure gives MPMS functional materials excellent mechanical properties,antifouling properties,self-healing properties,antibacterial properties.The shear strength and tensile strength of MPMS increase from 3.32 and 4.26 MPa of MAPDMS to 3.81 and 5.06 MPa,respectively.Its static contact angle increases from 115.9°of MAPDMS to 156.5°,its slide angle decreases from 68.5°of MAPDMS to 7.8°,respectively.The antifouling performance of MPMS against seawater,soy sauce,juice,coffee,protein,other contaminants is effectively improved compared with MAPDMS matrix.At the same time,the tensile strength and elongation at break of MPMS after healing reach 98.22%and 96.57%of those in original state,respectively.In addition,the antibacterial rates of MPMS against Escherichia coli and Staphylococcus aureus reach 99.85%and 100%,respectively.The MPMS prepared in this paper is expected to be widely used in marine antifouling,pipeline network,anti-icing,microfluidics,wearable devices,medical devices,electrochemical biosensors,other fields.
