The metal cutting process is accompanied by complex stress field,strain field,temperature field.The comprehensive effects of process parameters on chip morphology,cutting force,tool wear and residual stress are comple...The metal cutting process is accompanied by complex stress field,strain field,temperature field.The comprehensive effects of process parameters on chip morphology,cutting force,tool wear and residual stress are complex and inter-connected.Finite element method(FEM)is considered as an effective method to predict process variables and reveal microscopic physical phenomena in the cutting process.Therefore,the finite element(FE)simulation is used to research the conventional and micro scale cutting process,and the differences in the establishment of process variable FE simulation models are distinguished,thereby improving the accuracy of FE simulation.The reliability and effectiveness of FE simulation model largely depend on the accuracy of the simulation method,constitutive model,friction model,damage model in describing mesh element,the dynamic mechanical behavior of materials,the tool-chip-workpiece contact process and the chip formation mechanism.In this paper,the FE models of conventional and micro process variables are comprehensively and up-to-date reviewed for different materials and machining methods.The purpose is to establish a FE model that is more in line with the real cutting conditions,and to provide the possibility for optimizing the cutting process variables.The development direction of FE simulation of metal cutting process is discussed,which provides guidance for future cutting process modeling.展开更多
Electrocatalysis has been extensively explored for the storage and conversion of renewable electric power.Understanding the physisorption and chemisorption processes at electrified solid–liquid interfaces(ESLIs)is cr...Electrocatalysis has been extensively explored for the storage and conversion of renewable electric power.Understanding the physisorption and chemisorption processes at electrified solid–liquid interfaces(ESLIs)is crucial for revealing the typical surface restructuring and catalyst dissolution during electrocatalysis.Although advanced in situ tools and theoretical models have been proposed[1,2],identifying the nature of the active sites with atomic-scale spatial resolution remains a challenge,especially at ESLIs.In a recent work published in Nature,Zhang et al.[3]reported a groundbreaking atomic-resolution imaging of the structural dynamics of Cu nanowire catalysts in ESLIs for electrochemical CO_(2)reduction(ECR).展开更多
Landscape ecology provides new theoretical frameworks and methodologies for understanding complex ecological phenomena at multiple scales.Studies of landscape ecology focus on understanding the dynamics of eco-logical...Landscape ecology provides new theoretical frameworks and methodologies for understanding complex ecological phenomena at multiple scales.Studies of landscape ecology focus on understanding the dynamics of eco-logical patterns and processes,and highlight the integration of multiple disciplines.In this paper,we discussed the problems and challenges that landscape ecology is currently facing,emphasizing the limitations of current methods used to describe dynamic landscape patterns and processes.We suggested that the focus should be on the integration of ground-based observation,mobile monitoring,transect survey,and remote-sensing monitoring,as well as improved coupling of experimental and model simulations.In addition,we outlined the research frontiers in landscape ecology,including scaling,integrated pattern and process modeling,and regional synthesis.Lastly,a brief review of pat-tern-process-scale coupling studies in China was provided.We concluded by pointing out that pattern-process-scale interactions,correlations between natural,economic,and social processes,and the coupling of human and natural systems will be major research areas in landscape ecology in the future.展开更多
The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic sheari...The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media.展开更多
Due to the scale effect, the uniform distribution of reagents in continuous flow reactor becomes bad when the channel is enlarged to tens of millimeters. Microfluidic field strategy was proposed to produce high mixing...Due to the scale effect, the uniform distribution of reagents in continuous flow reactor becomes bad when the channel is enlarged to tens of millimeters. Microfluidic field strategy was proposed to produce high mixing efficiency in large-scale channel. A 3D spiral baffle structure(3SBS) was designed and optimized to form microfluidic field disturbed by continuous secondary flow in millimeter scale Y-shaped tube mixer(YSTM). Enhancement effect of the 3SBS in liquid-liquid homogeneous chemical processes was verified and evaluated through the combination of simulation and experiment. Compared with 1 mm YSTM, 10 mm YSTM with 3SBS increased the treatment capacity by 100 times, shortened the basic complete mixing time by 0.85 times, which proves the potential of microfluidic field strategy in enhancement and scale-up of liquid-liquid homogeneous chemical process.展开更多
In India, with ever increasing population and stress on natural resources, especially water, rejuvenation of rainwater harvesting (RWH) technique which was forgotten over the days is becoming very essential. Large num...In India, with ever increasing population and stress on natural resources, especially water, rejuvenation of rainwater harvesting (RWH) technique which was forgotten over the days is becoming very essential. Large number of RWH methods that are available in the literature are demand specific and site specific, since RWH system depends on the topography, land use, land cover, rainfall and demand pattern. Thus for each and every case, a detailed evaluation of RWH structures is required for implementation, including the analy-sis of hydrology, topography and other aspects like site availability and economics, however a common methodology could be evolved. The present study was aimed at evaluation of various RWH techniques in order to identify the most appropriate technique suitable for a large scale industrial area to meet its daily wa-ter demand. An attempt is made to determine the volume of water to be stored using mass balance method, Ripple diagram method, analytical method, and sequent peak algorithm method. Based on various satisfying criteria, analytical hierarchy process (AHP) is employed to determine the most appropriate type of RWH method and required number of RWH structures in the study area. If economy alone is considered along with hydrological and site specific parameters, recharging the aquifer has resulted as a better choice. However other criteria namely risk, satisfaction in obtaining required volume of water for immediate utilization etc. has resulted in opting for concrete storage structures method. From the results it is found that AHP, if used with all possible criteria can result in a better tool for evaluation of RWH methods and structures. This RWH structures not only meets the demand but saves transportation cost of water and reduces the dependability of the industry on irrigation reservoir. Besides monetary benefits it is hoped that the micro environment inside the industry will improve due to the cooling effect of the stored water.展开更多
Gray scale grades for color change of dyed fabrics are assessed via image processing technology.Digital images of groups of specimens are obtained,cropped,and saved as JPEG format.Relationships between gray scale grad...Gray scale grades for color change of dyed fabrics are assessed via image processing technology.Digital images of groups of specimens are obtained,cropped,and saved as JPEG format.Relationships between gray scale grades for color change and the corresponding color differences calculated via image processing technology are investigated,compared with those obtained from high accurate computer color matching system.Results show that the new method is acceptable with an accuracy of 92.0% when the grading errors are of not more than one grade.展开更多
Annular centrifugal extractors(ACEs) offer advantages including excellent hydraulic and mass-transfer performance, small hold-up volume, short residence time,and thus low solvent degradation, high nuclear criticality,...Annular centrifugal extractors(ACEs) offer advantages including excellent hydraulic and mass-transfer performance, small hold-up volume, short residence time,and thus low solvent degradation, high nuclear criticality,easy start-up and shut-down, high compact structure.Therefore, ACEs have attracted increasing interest for future nuclear processing schemes, including the partitioning of high-level liquid waste(HLLW). Laboratoryscale and pilot-scale ACEs have been applied in demonstration tests of the trialkyl phosphine oxide(TRPO) process for HLLW partitioning. In this study, an industrialscale ACE(260 mm in rotor diameter) with magnetic coupling and a ‘‘hanging'' rotor structure was developed for the TRPO process. Moreover, a series of hydraulic and mass-transfer tests were carried out in the industrial-scale ACE. The maximum throughput can reach 10 m^3/h under suitable operation parameters when kerosene is used as the organic phase, and water is used as the aqueous phase. The influence of the total flowrate, the flow ratio(aqueous/organic, A/O), and the rotor speed on the liquid hold-up volume was determined. The extraction stage efficiency is higher than 98% under test parameters for extraction of Nd^(3+) and HNO_3, using 30% TRPO kerosene as theextractant from an HNO_3 solution containing Nd. All results show good performance of the industrial-scale ACE for the TRPO process.展开更多
A multi-scale numerical method coupled with the reactor,sheath and trench model is constructed to simulate dry etching of SiO_2 in inductively coupled C_4F_8 plasmas.Firstly,ion and neutral particle densities in the r...A multi-scale numerical method coupled with the reactor,sheath and trench model is constructed to simulate dry etching of SiO_2 in inductively coupled C_4F_8 plasmas.Firstly,ion and neutral particle densities in the reactor are decided using the CFD-ACE＋ commercial software.Then,the ion energy and angular distributions（IEDs and IADs） are obtained in the sheath model with the sheath boundary conditions provided with CFD-ACE＋.Finally,the trench profile evolution is simulated in the trench model.What we principally focus on is the effects of the discharge parameters on the etching results.It is found that the discharge parameters,including discharge pressure,radio-frequency（rf） power,gas mixture ratios,bias voltage and frequency,have synergistic effects on IEDs and IADs on the etched material surface,thus further affecting the trench profiles evolution.展开更多
In the procedure of the steady-state hierarchical optimization with feedback for large-scale industrial processes, a sequence of set-point changes with different magnitudes is carried out on the optimization layer. To...In the procedure of the steady-state hierarchical optimization with feedback for large-scale industrial processes, a sequence of set-point changes with different magnitudes is carried out on the optimization layer. To improve the dynamic performance of transient response driven by the set-point changes, a filter-based iterative learning control strategy is proposed. In the proposed updating law, a local-symmetric-integral operator is adopted for eliminating the measurement noise of output information,a set of desired trajectories are specified according to the set-point changes sequence, the current control input is iteratively achieved by utilizing smoothed output error to modify its control input at previous iteration, to which the amplified coefficients related to the different magnitudes of set-point changes are introduced. The convergence of the algorithm is conducted by incorporating frequency-domain technique into time-domain analysis. Numerical simulation demonstrates the effectiveness of the proposed strategy,展开更多
Geological discontinuity(GD)plays a pivotal role in determining the catastrophic mechanical failure of jointed rock masses.Accurate and efficient acquisition of GD networks is essential for characterizing and understa...Geological discontinuity(GD)plays a pivotal role in determining the catastrophic mechanical failure of jointed rock masses.Accurate and efficient acquisition of GD networks is essential for characterizing and understanding the progressive damage mechanisms of slopes based on monitoring image data.Inspired by recent advances in computer vision,deep learning(DL)models have been widely utilized for image-based fracture identification.The multi-scale characteristics,image resolution and annotation quality of images will cause a scale-space effect(SSE)that makes features indistinguishable from noise,directly affecting the accuracy.However,this effect has not received adequate attention.Herein,we try to address this gap by collecting slope images at various proportional scales and constructing multi-scale datasets using image processing techniques.Next,we quantify the intensity of feature signals using metrics such as peak signal-to-noise ratio(PSNR)and structural similarity(SSIM).Combining these metrics with the scale-space theory,we investigate the influence of the SSE on the differentiation of multi-scale features and the accuracy of recognition.It is found that augmenting the image's detail capacity does not always yield benefits for vision-based recognition models.In light of these observations,we propose a scale hybridization approach based on the diffusion mechanism of scale-space representation.The results show that scale hybridization strengthens the tolerance of multi-scale feature recognition under complex environmental noise interference and significantly enhances the recognition accuracy of GD.It also facilitates the objective understanding,description and analysis of the rock behavior and stability of slopes from the perspective of image data.展开更多
Fluvial processes comprise water flow,sediment transport and bed evolution,which normally feature distinct time scales.The time scales of sediment transport and bed deformation relative to the flow essentially measure...Fluvial processes comprise water flow,sediment transport and bed evolution,which normally feature distinct time scales.The time scales of sediment transport and bed deformation relative to the flow essentially measure how fast sediment transport adapts to capacity region in line with local flow scenario and the bed deforms in comparison with the flow,which literally dictates if a capacity based and/or decoupled model is justified.This paper synthesizes the recently developed multiscale theory for sediment-laden flows over erodible bed,with bed load and suspended load transport,respectively.It is unravelled that bed load transport can adapt to capacity sufficiently rapidly even under highly unsteady flows and thus a capacity model is mostly applicable,whereas a non-capacity model is critical for suspended sediment because of the lower rate of adaptation to capacity.Physically coupled modelling is critical for fluvial processes characterized by rapid bed variation.Applications are outlined on very active bed load sediment transported by flash floods and landslide dam break floods.展开更多
A Three-Scale Fuzzy Analytical Hierarchy Process (T-FAHP) is proposed by introducing the Three-Scale Analytical Hierarchy Process (T-AHP) and the trapezoid fuzzy number. A multi-objective optimization model based on t...A Three-Scale Fuzzy Analytical Hierarchy Process (T-FAHP) is proposed by introducing the Three-Scale Analytical Hierarchy Process (T-AHP) and the trapezoid fuzzy number. A multi-objective optimization model based on the T-FAHP is presented subsequently, in which many factors influencing the lectotype of offshore platform are taken into account synthetically, such as the original investment, the maintenance, cost, the ability of resisting fatigue and corrosion, the construction period, the threat to the environment, and so on. With this method, the experts can give the relatively precise ranking weight of each index and at the same time the requirement of consistence checking can be met, The result of a calculation example shows that the T-FAHP is practical.展开更多
The dynamics of zero-range processes on complex networks is expected to be influenced by the topological structure of underlying networks.A real space complete condensation phase transition in the stationary state may...The dynamics of zero-range processes on complex networks is expected to be influenced by the topological structure of underlying networks.A real space complete condensation phase transition in the stationary state may occur.We study the finite density effects of the condensation transition in both the stationary and dynamical zero-range processes on scale-free networks.By means of grand canonical ensemble method,we predict analytically the scaling laws of the average occupation number with respect to the finite density for the steady state.We further explore the relaxation dynamics of the condensation phase transition.By applying the hierarchical evolution and scaling ansatz,a scaling law for the relaxation dynamics is predicted.Monte Carlo simulations are performed and the predicted density scaling laws are nicely validated.展开更多
Solid-state impedance spectroscopy(SS-IS)was used to investigate the influence of structural modifications resulting from the addition of Nb2O5 on the dielectric properties and relaxation processes in the quaternary m...Solid-state impedance spectroscopy(SS-IS)was used to investigate the influence of structural modifications resulting from the addition of Nb2O5 on the dielectric properties and relaxation processes in the quaternary mixed glass former(MGF)system 35Na_(2)O–10V_(2)O_(5)–(55-x)P_(2)O_(5)–xNb_(2)O_(5)(x=0–40,mol%).The dielectric parameters,including the dielectric strength and dielectric loss,are determined from the frequency and temperature-dependent complex permittivity data,revealing a significant dependence on the Nb2O5 content.The transition from a predominantly phosphate glass network(x<10,region I)to a mixed niobate–phosphate glass net-work(10≤x≤20,region II)leads to an increase in the dielectric parameters,which correlates with the observed trend in the direct-cur-rent(DC)conductivity.In the predominantly niobate network(x≥25,region III),the highly polarizable nature of Nb5+ions leads to a fur-ther increase in the dielectric permittivity and dielectric strength.This is particularly evident in Nb-40 glass-ceramic,which contains Na_(13)Nb_(35)O_(94) crystalline phase with a tungsten bronze structure and exhibits the highest dielectric permittivity of 61.81 and the lowest loss factor of 0.032 at 303 K and 10 kHz.The relaxation studies,analyzed through modulus formalism and complex impedance data,show that DC conductivity and relaxation processes are governed by the same mechanism,attributed to ionic conductivity.In contrast to glasses with a single peak in frequency dependence of imaginary part of electrical modulus,M″(ω),Nb-40 glass-ceramic exhibits two distinct contributions with similar relaxation times.The high-frequency peak indicates bulk ionic conductivity,while the additional low-fre-quency peak is associated with the grain boundary effect,confirmed by the electrical equivalent circuit(EEC)modelling.The scaling characteristics of permittivity and conductivity spectra,along with the electrical modulus,validate time-temperature superposition and demonstrate a strong correlation with composition and modification of the glass structure upon Nb_(2)O_(5) incorporation.展开更多
2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction ti...2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction time is typically in hours or days.Herein,we developed a green route for the continuous and high-throughput synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole via photochemical intramolecular cyclization of 3–hydroxy-2–chloro-diphenylamine using a self-designed millimeter scale photoreactor,which was designed based on sizing-up and numbering-up strategies for a decent liquid holdup(6.8 m L)and fabricated via femtosecond laser engraving technique.The photochemical synthesis was carried out continuously under the illumination of 365 nm UV-LED with dimethyl sulfoxide as solvent and potassium t-butoxide as catalyst.It was found that under optimized conditions a 2-hydroxycarbazole yield of 31.6%and a 4-hydroxycarbazole yield of 11.1%were obtained with a residence time of 1 min.Compared to semibatch operations,the reaction time was shortened by 1–2 orders of magnitude.As a result,a throughput of 11.3 g/day 2-hydroxycarbazole and 4.0 g/day 4-hydroxycarbazole can be achieved from the photoreactor.It was proposed that the short reaction time and high product yield are resulted from higher photon transfer rates and more uniform photon distribution provided by the millimeter scale photoreactor,which enhances the reaction rates and mitigates overreaction.展开更多
Multi-scales relaxation processes of short fiber of a nematic liquid crystalline copolymer(LCP)in polycarbonate matrix were investigated.First,the structure relaxation of LCP was studied by rheology.The relaxation spe...Multi-scales relaxation processes of short fiber of a nematic liquid crystalline copolymer(LCP)in polycarbonate matrix were investigated.First,the structure relaxation of LCP was studied by rheology.The relaxation spectrum of the nematic liquid crystalline copolymer at 295℃was calculated from the combined dynamic modulus.There are three kinds of relaxation mechanisms for nematic liquid crystalline copotymer:the relaxation of chain orientation,the relaxation of deformed polydomains and the coalescence of pol...展开更多
Geological Society Special Publications No.253,London,2006,456 pp.,Price List:£85.00,US$170 ISBN 1-86239-191-2 Earth science began with the observation of the Earth materials and processes,then asking specific qu...Geological Society Special Publications No.253,London,2006,456 pp.,Price List:£85.00,US$170 ISBN 1-86239-191-2 Earth science began with the observation of the Earth materials and processes,then asking specific questions,proposing and testing hypotheses,formulating general concepts and theories,and finally experimenting and modelling.On a larger scale,this has been the pattern of Earth science history;and on a smaller scale this also is how a comprehensive Earth science research project proceeds.Experimentation,modelling and simulation are relatively recent developments in Earth science,and in this regard Earth scientists have a long way to go compared with their colleagues in physics and chemistry.But serious steps have been taken in recent decades.This new book is a testimony to these developments in the field of tectonic modelling.展开更多
We point out that a suitable scale of time for the Schrödinger perturbation process is a closed line having rather a circular and not a conventional straight-linear character. A circular nature of the scale c...We point out that a suitable scale of time for the Schrödinger perturbation process is a closed line having rather a circular and not a conventional straight-linear character. A circular nature of the scale concerns especially the time associated with a particular order N of the perturbation energy which provides us with a full number of the perturbation terms predicted by Huby and Tong. On the other hand, a change of the order N—connected with an increased number of the special time points considered on the scale—requires a progressive character of time. A classification of the perturbation terms is done with the aid of the time-point contractions present on a scale characteristic for each N. This selection of terms can be simplified by a partition procedure of the integer numbers representing N-1. The detailed calculations are performed for the perturbation energy of orders N=7 and N=8 .展开更多
基金supported by the National Natural Science Foundation of China(No.52175393)。
文摘The metal cutting process is accompanied by complex stress field,strain field,temperature field.The comprehensive effects of process parameters on chip morphology,cutting force,tool wear and residual stress are complex and inter-connected.Finite element method(FEM)is considered as an effective method to predict process variables and reveal microscopic physical phenomena in the cutting process.Therefore,the finite element(FE)simulation is used to research the conventional and micro scale cutting process,and the differences in the establishment of process variable FE simulation models are distinguished,thereby improving the accuracy of FE simulation.The reliability and effectiveness of FE simulation model largely depend on the accuracy of the simulation method,constitutive model,friction model,damage model in describing mesh element,the dynamic mechanical behavior of materials,the tool-chip-workpiece contact process and the chip formation mechanism.In this paper,the FE models of conventional and micro process variables are comprehensively and up-to-date reviewed for different materials and machining methods.The purpose is to establish a FE model that is more in line with the real cutting conditions,and to provide the possibility for optimizing the cutting process variables.The development direction of FE simulation of metal cutting process is discussed,which provides guidance for future cutting process modeling.
基金financially supported by the Natural Science Foundation of Shandong(ZR2023ME014)。
文摘Electrocatalysis has been extensively explored for the storage and conversion of renewable electric power.Understanding the physisorption and chemisorption processes at electrified solid–liquid interfaces(ESLIs)is crucial for revealing the typical surface restructuring and catalyst dissolution during electrocatalysis.Although advanced in situ tools and theoretical models have been proposed[1,2],identifying the nature of the active sites with atomic-scale spatial resolution remains a challenge,especially at ESLIs.In a recent work published in Nature,Zhang et al.[3]reported a groundbreaking atomic-resolution imaging of the structural dynamics of Cu nanowire catalysts in ESLIs for electrochemical CO_(2)reduction(ECR).
基金Under the auspices of National Natural Science Foundation of China (No.40930528)State Forestry Administration of China (No.201004058)
文摘Landscape ecology provides new theoretical frameworks and methodologies for understanding complex ecological phenomena at multiple scales.Studies of landscape ecology focus on understanding the dynamics of eco-logical patterns and processes,and highlight the integration of multiple disciplines.In this paper,we discussed the problems and challenges that landscape ecology is currently facing,emphasizing the limitations of current methods used to describe dynamic landscape patterns and processes.We suggested that the focus should be on the integration of ground-based observation,mobile monitoring,transect survey,and remote-sensing monitoring,as well as improved coupling of experimental and model simulations.In addition,we outlined the research frontiers in landscape ecology,including scaling,integrated pattern and process modeling,and regional synthesis.Lastly,a brief review of pat-tern-process-scale coupling studies in China was provided.We concluded by pointing out that pattern-process-scale interactions,correlations between natural,economic,and social processes,and the coupling of human and natural systems will be major research areas in landscape ecology in the future.
基金supported by Laboratory Directed Research and Development(LDRD)funding from Berkeley Labsupported by Open Fund of the State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(Grant No.Z017004)。
文摘The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media.
基金supported by the National Key Research and Development Program of China (2021YFC2101900 and 2019YFA0905000)National Natural Science Foundation of China (21908094, 21776130 and 22078150)+1 种基金Nanjing International Joint Research and Development Project (202002037)Top-notch Academic Programs Project of Jiangsu Higher Education Institutions。
文摘Due to the scale effect, the uniform distribution of reagents in continuous flow reactor becomes bad when the channel is enlarged to tens of millimeters. Microfluidic field strategy was proposed to produce high mixing efficiency in large-scale channel. A 3D spiral baffle structure(3SBS) was designed and optimized to form microfluidic field disturbed by continuous secondary flow in millimeter scale Y-shaped tube mixer(YSTM). Enhancement effect of the 3SBS in liquid-liquid homogeneous chemical processes was verified and evaluated through the combination of simulation and experiment. Compared with 1 mm YSTM, 10 mm YSTM with 3SBS increased the treatment capacity by 100 times, shortened the basic complete mixing time by 0.85 times, which proves the potential of microfluidic field strategy in enhancement and scale-up of liquid-liquid homogeneous chemical process.
文摘In India, with ever increasing population and stress on natural resources, especially water, rejuvenation of rainwater harvesting (RWH) technique which was forgotten over the days is becoming very essential. Large number of RWH methods that are available in the literature are demand specific and site specific, since RWH system depends on the topography, land use, land cover, rainfall and demand pattern. Thus for each and every case, a detailed evaluation of RWH structures is required for implementation, including the analy-sis of hydrology, topography and other aspects like site availability and economics, however a common methodology could be evolved. The present study was aimed at evaluation of various RWH techniques in order to identify the most appropriate technique suitable for a large scale industrial area to meet its daily wa-ter demand. An attempt is made to determine the volume of water to be stored using mass balance method, Ripple diagram method, analytical method, and sequent peak algorithm method. Based on various satisfying criteria, analytical hierarchy process (AHP) is employed to determine the most appropriate type of RWH method and required number of RWH structures in the study area. If economy alone is considered along with hydrological and site specific parameters, recharging the aquifer has resulted as a better choice. However other criteria namely risk, satisfaction in obtaining required volume of water for immediate utilization etc. has resulted in opting for concrete storage structures method. From the results it is found that AHP, if used with all possible criteria can result in a better tool for evaluation of RWH methods and structures. This RWH structures not only meets the demand but saves transportation cost of water and reduces the dependability of the industry on irrigation reservoir. Besides monetary benefits it is hoped that the micro environment inside the industry will improve due to the cooling effect of the stored water.
基金Scientific Research Fund of Yancheng Institute of Technology,China(No. XKY2009029)
文摘Gray scale grades for color change of dyed fabrics are assessed via image processing technology.Digital images of groups of specimens are obtained,cropped,and saved as JPEG format.Relationships between gray scale grades for color change and the corresponding color differences calculated via image processing technology are investigated,compared with those obtained from high accurate computer color matching system.Results show that the new method is acceptable with an accuracy of 92.0% when the grading errors are of not more than one grade.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT13026)the National 863 Program for the Nuclear Fuel Cycling and Nuclear Safety Technology Project(No.2009AA050703)
文摘Annular centrifugal extractors(ACEs) offer advantages including excellent hydraulic and mass-transfer performance, small hold-up volume, short residence time,and thus low solvent degradation, high nuclear criticality,easy start-up and shut-down, high compact structure.Therefore, ACEs have attracted increasing interest for future nuclear processing schemes, including the partitioning of high-level liquid waste(HLLW). Laboratoryscale and pilot-scale ACEs have been applied in demonstration tests of the trialkyl phosphine oxide(TRPO) process for HLLW partitioning. In this study, an industrialscale ACE(260 mm in rotor diameter) with magnetic coupling and a ‘‘hanging'' rotor structure was developed for the TRPO process. Moreover, a series of hydraulic and mass-transfer tests were carried out in the industrial-scale ACE. The maximum throughput can reach 10 m^3/h under suitable operation parameters when kerosene is used as the organic phase, and water is used as the aqueous phase. The influence of the total flowrate, the flow ratio(aqueous/organic, A/O), and the rotor speed on the liquid hold-up volume was determined. The extraction stage efficiency is higher than 98% under test parameters for extraction of Nd^(3+) and HNO_3, using 30% TRPO kerosene as theextractant from an HNO_3 solution containing Nd. All results show good performance of the industrial-scale ACE for the TRPO process.
基金supported by National Natural Science Foundation of China(No.11375040)the Important National Science&Technology Specific Project of China(No.2011ZX02403-002)
文摘A multi-scale numerical method coupled with the reactor,sheath and trench model is constructed to simulate dry etching of SiO_2 in inductively coupled C_4F_8 plasmas.Firstly,ion and neutral particle densities in the reactor are decided using the CFD-ACE＋ commercial software.Then,the ion energy and angular distributions（IEDs and IADs） are obtained in the sheath model with the sheath boundary conditions provided with CFD-ACE＋.Finally,the trench profile evolution is simulated in the trench model.What we principally focus on is the effects of the discharge parameters on the etching results.It is found that the discharge parameters,including discharge pressure,radio-frequency（rf） power,gas mixture ratios,bias voltage and frequency,have synergistic effects on IEDs and IADs on the etched material surface,thus further affecting the trench profiles evolution.
基金This work was supported by the National Natural Science Foundation of China (No. 60274055)
文摘In the procedure of the steady-state hierarchical optimization with feedback for large-scale industrial processes, a sequence of set-point changes with different magnitudes is carried out on the optimization layer. To improve the dynamic performance of transient response driven by the set-point changes, a filter-based iterative learning control strategy is proposed. In the proposed updating law, a local-symmetric-integral operator is adopted for eliminating the measurement noise of output information,a set of desired trajectories are specified according to the set-point changes sequence, the current control input is iteratively achieved by utilizing smoothed output error to modify its control input at previous iteration, to which the amplified coefficients related to the different magnitudes of set-point changes are introduced. The convergence of the algorithm is conducted by incorporating frequency-domain technique into time-domain analysis. Numerical simulation demonstrates the effectiveness of the proposed strategy,
基金supported by the National Natural Science Foundation of China(Grant No.52090081)the State Key Laboratory of Hydro-science and Hydraulic Engineering(Grant No.2021-KY-04).
文摘Geological discontinuity(GD)plays a pivotal role in determining the catastrophic mechanical failure of jointed rock masses.Accurate and efficient acquisition of GD networks is essential for characterizing and understanding the progressive damage mechanisms of slopes based on monitoring image data.Inspired by recent advances in computer vision,deep learning(DL)models have been widely utilized for image-based fracture identification.The multi-scale characteristics,image resolution and annotation quality of images will cause a scale-space effect(SSE)that makes features indistinguishable from noise,directly affecting the accuracy.However,this effect has not received adequate attention.Herein,we try to address this gap by collecting slope images at various proportional scales and constructing multi-scale datasets using image processing techniques.Next,we quantify the intensity of feature signals using metrics such as peak signal-to-noise ratio(PSNR)and structural similarity(SSIM).Combining these metrics with the scale-space theory,we investigate the influence of the SSE on the differentiation of multi-scale features and the accuracy of recognition.It is found that augmenting the image's detail capacity does not always yield benefits for vision-based recognition models.In light of these observations,we propose a scale hybridization approach based on the diffusion mechanism of scale-space representation.The results show that scale hybridization strengthens the tolerance of multi-scale feature recognition under complex environmental noise interference and significantly enhances the recognition accuracy of GD.It also facilitates the objective understanding,description and analysis of the rock behavior and stability of slopes from the perspective of image data.
基金supported by the National Natural Science Foundation of China (10932012 and 10972164)State Key Basic Research and Development Program (973) of China (2007CB714106)
文摘Fluvial processes comprise water flow,sediment transport and bed evolution,which normally feature distinct time scales.The time scales of sediment transport and bed deformation relative to the flow essentially measure how fast sediment transport adapts to capacity region in line with local flow scenario and the bed deforms in comparison with the flow,which literally dictates if a capacity based and/or decoupled model is justified.This paper synthesizes the recently developed multiscale theory for sediment-laden flows over erodible bed,with bed load and suspended load transport,respectively.It is unravelled that bed load transport can adapt to capacity sufficiently rapidly even under highly unsteady flows and thus a capacity model is mostly applicable,whereas a non-capacity model is critical for suspended sediment because of the lower rate of adaptation to capacity.Physically coupled modelling is critical for fluvial processes characterized by rapid bed variation.Applications are outlined on very active bed load sediment transported by flash floods and landslide dam break floods.
基金This work was financially supported by the National Natural Science Foundation of China(Grant No.59895410)
文摘A Three-Scale Fuzzy Analytical Hierarchy Process (T-FAHP) is proposed by introducing the Three-Scale Analytical Hierarchy Process (T-AHP) and the trapezoid fuzzy number. A multi-objective optimization model based on the T-FAHP is presented subsequently, in which many factors influencing the lectotype of offshore platform are taken into account synthetically, such as the original investment, the maintenance, cost, the ability of resisting fatigue and corrosion, the construction period, the threat to the environment, and so on. With this method, the experts can give the relatively precise ranking weight of each index and at the same time the requirement of consistence checking can be met, The result of a calculation example shows that the T-FAHP is practical.
基金the National Natural Science Foundation of China(Grant No.11505115).
文摘The dynamics of zero-range processes on complex networks is expected to be influenced by the topological structure of underlying networks.A real space complete condensation phase transition in the stationary state may occur.We study the finite density effects of the condensation transition in both the stationary and dynamical zero-range processes on scale-free networks.By means of grand canonical ensemble method,we predict analytically the scaling laws of the average occupation number with respect to the finite density for the steady state.We further explore the relaxation dynamics of the condensation phase transition.By applying the hierarchical evolution and scaling ansatz,a scaling law for the relaxation dynamics is predicted.Monte Carlo simulations are performed and the predicted density scaling laws are nicely validated.
文摘Solid-state impedance spectroscopy(SS-IS)was used to investigate the influence of structural modifications resulting from the addition of Nb2O5 on the dielectric properties and relaxation processes in the quaternary mixed glass former(MGF)system 35Na_(2)O–10V_(2)O_(5)–(55-x)P_(2)O_(5)–xNb_(2)O_(5)(x=0–40,mol%).The dielectric parameters,including the dielectric strength and dielectric loss,are determined from the frequency and temperature-dependent complex permittivity data,revealing a significant dependence on the Nb2O5 content.The transition from a predominantly phosphate glass network(x<10,region I)to a mixed niobate–phosphate glass net-work(10≤x≤20,region II)leads to an increase in the dielectric parameters,which correlates with the observed trend in the direct-cur-rent(DC)conductivity.In the predominantly niobate network(x≥25,region III),the highly polarizable nature of Nb5+ions leads to a fur-ther increase in the dielectric permittivity and dielectric strength.This is particularly evident in Nb-40 glass-ceramic,which contains Na_(13)Nb_(35)O_(94) crystalline phase with a tungsten bronze structure and exhibits the highest dielectric permittivity of 61.81 and the lowest loss factor of 0.032 at 303 K and 10 kHz.The relaxation studies,analyzed through modulus formalism and complex impedance data,show that DC conductivity and relaxation processes are governed by the same mechanism,attributed to ionic conductivity.In contrast to glasses with a single peak in frequency dependence of imaginary part of electrical modulus,M″(ω),Nb-40 glass-ceramic exhibits two distinct contributions with similar relaxation times.The high-frequency peak indicates bulk ionic conductivity,while the additional low-fre-quency peak is associated with the grain boundary effect,confirmed by the electrical equivalent circuit(EEC)modelling.The scaling characteristics of permittivity and conductivity spectra,along with the electrical modulus,validate time-temperature superposition and demonstrate a strong correlation with composition and modification of the glass structure upon Nb_(2)O_(5) incorporation.
基金funded by the National Natural Science Foundation of China(Nos.21991103,21991104,22008074,22008072)Natural Science Foundation of Shanghai(No.20ZR1415700)China Postdoctoral Science Foundation(Nos.2020M671025,2019TQ0093)。
文摘2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction time is typically in hours or days.Herein,we developed a green route for the continuous and high-throughput synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole via photochemical intramolecular cyclization of 3–hydroxy-2–chloro-diphenylamine using a self-designed millimeter scale photoreactor,which was designed based on sizing-up and numbering-up strategies for a decent liquid holdup(6.8 m L)and fabricated via femtosecond laser engraving technique.The photochemical synthesis was carried out continuously under the illumination of 365 nm UV-LED with dimethyl sulfoxide as solvent and potassium t-butoxide as catalyst.It was found that under optimized conditions a 2-hydroxycarbazole yield of 31.6%and a 4-hydroxycarbazole yield of 11.1%were obtained with a residence time of 1 min.Compared to semibatch operations,the reaction time was shortened by 1–2 orders of magnitude.As a result,a throughput of 11.3 g/day 2-hydroxycarbazole and 4.0 g/day 4-hydroxycarbazole can be achieved from the photoreactor.It was proposed that the short reaction time and high product yield are resulted from higher photon transfer rates and more uniform photon distribution provided by the millimeter scale photoreactor,which enhances the reaction rates and mitigates overreaction.
基金This work was financially supported by the National Natural Science Foundation of China(Nos. 20174024,20204007 and 50290090).
文摘Multi-scales relaxation processes of short fiber of a nematic liquid crystalline copolymer(LCP)in polycarbonate matrix were investigated.First,the structure relaxation of LCP was studied by rheology.The relaxation spectrum of the nematic liquid crystalline copolymer at 295℃was calculated from the combined dynamic modulus.There are three kinds of relaxation mechanisms for nematic liquid crystalline copotymer:the relaxation of chain orientation,the relaxation of deformed polydomains and the coalescence of pol...
文摘Geological Society Special Publications No.253,London,2006,456 pp.,Price List:£85.00,US$170 ISBN 1-86239-191-2 Earth science began with the observation of the Earth materials and processes,then asking specific questions,proposing and testing hypotheses,formulating general concepts and theories,and finally experimenting and modelling.On a larger scale,this has been the pattern of Earth science history;and on a smaller scale this also is how a comprehensive Earth science research project proceeds.Experimentation,modelling and simulation are relatively recent developments in Earth science,and in this regard Earth scientists have a long way to go compared with their colleagues in physics and chemistry.But serious steps have been taken in recent decades.This new book is a testimony to these developments in the field of tectonic modelling.
文摘We point out that a suitable scale of time for the Schrödinger perturbation process is a closed line having rather a circular and not a conventional straight-linear character. A circular nature of the scale concerns especially the time associated with a particular order N of the perturbation energy which provides us with a full number of the perturbation terms predicted by Huby and Tong. On the other hand, a change of the order N—connected with an increased number of the special time points considered on the scale—requires a progressive character of time. A classification of the perturbation terms is done with the aid of the time-point contractions present on a scale characteristic for each N. This selection of terms can be simplified by a partition procedure of the integer numbers representing N-1. The detailed calculations are performed for the perturbation energy of orders N=7 and N=8 .
