The accelerating factor （AF） method is a simple and appropriate way to investigate the atomic long-time deep diffusion at solid-solid interface. In the framework of AF hyperdynamics （HD） simulation, the relationsh...The accelerating factor （AF） method is a simple and appropriate way to investigate the atomic long-time deep diffusion at solid-solid interface. In the framework of AF hyperdynamics （HD） simulation, the relationship between the diffusion coefficient along the direction of z-axis which is normal to the Mg/Zn interface and temperature was investigated, and the AF＇s impact on the diffusion constant （D0） and activation energy （Q^＊） was studied. Then, two steps were taken to simulate the atomic diffusion process and the formation of new phases： one for acceleration and the other for equilibration. The results show that： the Arrhenius equation works well for the description of Dz with different accelerating factors; the AF has no effect on the diffusion constant Do in the case of no phase transition; and the relationship between Q＊ and Q conforms to Q^＊=Q/A. Then, the new Arrhenius equation for AFHD is successfully constructed as Dz=Doexp[-Q/（ART）]. Meanwhile, the authentic equilibrium conformations at any dynamic moment can only be reproduced by the equilibration simulation of the HD-simulated configurations. Key words： accelerating factor method; Arrhenius equation; two-steps scheme; Mg/Zn interface; hyperdynamic simulation展开更多
As blockchain technology rapidly evolves,smart contracts have seen widespread adoption in financial transactions and beyond.However,the growing prevalence of malicious Ponzi scheme contracts presents serious security ...As blockchain technology rapidly evolves,smart contracts have seen widespread adoption in financial transactions and beyond.However,the growing prevalence of malicious Ponzi scheme contracts presents serious security threats to blockchain ecosystems.Although numerous detection techniques have been proposed,existing methods suffer from significant limitations,such as class imbalance and insufficient modeling of transaction-related semantic features.To address these challenges,this paper proposes an oversampling-based detection framework for Ponzi smart contracts.We enhance the Adaptive Synthetic Sampling(ADASYN)algorithm by incorporating sample proximity to decision boundaries and ensuring realistic sample distributions.This enhancement facilitates the generation of high-quality minority class samples and effectively mitigates class imbalance.In addition,we design a Contract Transaction Graph(CTG)construction algorithm to preserve key transactional semantics through feature extraction from contract code.A graph neural network(GNN)is then applied for classification.This study employs a publicly available dataset from the XBlock platform,consisting of 318 verified Ponzi contracts and 6498 benign contracts.Sourced from real Ethereum deployments,the dataset reflects diverse application scenarios and captures the varied characteristics of Ponzi schemes.Experimental results demonstrate that our approach achieves an accuracy of 96%,a recall of 92%,and an F1-score of 94%in detecting Ponzi contracts,outperforming state-of-the-art methods.展开更多
In this paper,a stochastic linear two-step scheme has been presented to approximate backward stochastic differential equations(BSDEs).A necessary and sufficient condition is given to judge the L 2-stability of our num...In this paper,a stochastic linear two-step scheme has been presented to approximate backward stochastic differential equations(BSDEs).A necessary and sufficient condition is given to judge the L 2-stability of our numerical schemes.This stochastic linear two-step method possesses a family of 3-order convergence schemes in the sense of strong stability.The coefficients in the numerical methods are inferred based on the constraints of strong stability and n-order accuracy(n∈N^(+)).Numerical experiments illustrate that the scheme is an efficient probabilistic numerical method.展开更多
This paper proposes a new two-step non-oscillatory shape-preserving positive definite finite difference advection transport scheme, which merges the advantages of small dispersion error in the simple first-order upstr...This paper proposes a new two-step non-oscillatory shape-preserving positive definite finite difference advection transport scheme, which merges the advantages of small dispersion error in the simple first-order upstream scheme and small dissipation error in the simple second-order Lax-Wendroff scheme and is completely different from most of present positive definite advection schemes which are based on revising the upstream scheme results. The proposed scheme is much less time consuming than present shape-preserving or non-oscillatory advection transport schemes and produces results which are comparable to the results obtained from the present more complicated schemes. Elementary tests are also presented to examine the behavior of the scheme.展开更多
In this paper, a new numerical scheme of Total Variation Diminishing (TVD) MacCormack type for MagnetoHydroDynamic (MHD) equations is proposed by taking into account of the characteristics such as convergence, stabili...In this paper, a new numerical scheme of Total Variation Diminishing (TVD) MacCormack type for MagnetoHydroDynamic (MHD) equations is proposed by taking into account of the characteristics such as convergence, stability, resolution. This new scheme is established by solving the MHD equations with a TVD modified MacCormack scheme for the purpose of developing a scheme of quick convergence as well as of TVD property. To show the validation, simplicity and practicability of the scheme for modelling MHD problems, a self-similar Cauchy problem with the discontinuous initial data consisting of constant states, and the collision of two fast MHD shocks, and two-dimensional Orszag and Tang's MHD vortex problem are discussed with the numerical results conforming to the existing results obtained by the Roe type TVD, the high-order Godunov scheme,and Weighted Essentially Non-Oscillatory (WENO) scheme. The numerical tests show that this two-step TVD MacCormack numerical scheme for MHD system is of robust operation in the presence of very strong waves, thin shock fronts, thin contact and slip surface discontinuities.展开更多
An Eulerian flux-form advection scheme, called the Two-step Shape-Preserving Advection Scheme （TSPAS）, was generalized and implemented on a spherical icosahedral hexagonal grid （also referred to as a geodesic grid...An Eulerian flux-form advection scheme, called the Two-step Shape-Preserving Advection Scheme （TSPAS）, was generalized and implemented on a spherical icosahedral hexagonal grid （also referred to as a geodesic grid） to solve the transport equation. The C grid discretization was used for the spatial discretization. To implement TSPAS on an unstructured grid, the original finite-difference scheme was further generalized. The two-step integration utilizes a combination of two separate schemes （a low-order monotone scheme and a high-order scheme that typically cannot ensure monotonicity） to calculate the fluxes at the cell walls （one scheme corresponds to one cell wall）. The choice between these two schemes for each edge depends on a pre-updated scalar value using slightly increased fluxes. After the determination of an appropriate scheme, the final integration at a target cell is achieved by summing the fluxes that are computed by the different schemes. The conservative and shape-preserving properties of the generalized scheme are demonstrated. Numerical experiments are conducted at several horizontal resolutions. TSPAS is compared with the Flux Corrected Transport （FCT） approach to demonstrate the differences between the two methods, and several transport tests are performed to examine the accuracy, efficiency and robustness of the two schemes.展开更多
Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method mor...Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method more easily controls the crystallization rate and is suitable for preparing large-area per-ovskite devices.However,the residual low-conductivity iodide layer in the two-step method can affect carrier transport and device stability,and the different crystallization rates of Sn-and Pb-based per-ovskites may result in poor film quality.Therefore,Sn-Pb mixed perovskites are mainly prepared by a one-step method.Herein,a MAPb_(0.5)Sn_(0.5)I_(3)-based self-powered photodetector without a hole transport layer is fabricated by a two-step method.By adjusting the concentration of the ascorbic acid(AA)addi-tive,the final perovskite film exhibited a pure phase without residues,and the optimal device exhibited a high responsivity(0.276 A W^(-1)),large specific detectivity(2.38×10^(12) Jones),and enhanced stability.This enhancement is mainly attributed to the inhibition of Sn2+oxidation,the control of crystal growth,and the sufficient reaction between organic ammonium salts and bottom halides due to the AA-induced pore structure.展开更多
A custom micro-arc oxidation(MAO)apparatus is employed to produce coatings under optimized constant voltage–current two-step power supply mode.Various analytical techniques,including scanning electron microscopy,conf...A custom micro-arc oxidation(MAO)apparatus is employed to produce coatings under optimized constant voltage–current two-step power supply mode.Various analytical techniques,including scanning electron microscopy,confocal laser microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,transmission electron microscopy,and electrochemical analysis,are employed to characterize MAO coatings at different stages of preparation.MAO has MgO,hydroxyapatite,Ca_(3)(PO_(4))_(2),and Mg2SiO4 phases.Its microstructure of the coating is characterized by"multiple breakdowns,pores within pores",and"repaired blind pores".The porosity and the uniformity of MAO coating first declines in the constant voltage mode,then augments while the discharge phenomenon takes place,and finally decreases in the repair stage.These analyses reveal a four-stage growth pattern for MAO coatings:anodic oxidation stage,micro-arc oxidation stage,breakdown stage,and repairing stage.During anodic oxidation and MAO stages,inward growth prevails,while the breakdown stage sees outward and accelerated growth.Simultaneous inward and outward growth in the repair stage results in a denser,more uniform coating with increased thickness and improved corrosion resistance.展开更多
In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to character...In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.展开更多
BACKGROUND Elderly patients undergoing laparoscopic colorectal cancer surgery are at high risk for hypothermia-related complications.This study explores the efficacy of periop-erative composite insulation intervention...BACKGROUND Elderly patients undergoing laparoscopic colorectal cancer surgery are at high risk for hypothermia-related complications.This study explores the efficacy of periop-erative composite insulation interventions in maintaining normothermia and reducing postoperative risks in this vulnerable group.AIM To evaluate the efficacy of perioperative composite insulation in older patients undergoing colorectal cancer surgery.METHODS We selected 100 older patients who underwent laparoscopic surgery for colorectal cancer at Huzhou Central Hospital from September 2023 to April 2024.Using a random number table,patients were divided into a control group and inter-vention group of 50 patients each.After returning to the regular ward,the con-ventional group received traditional insulation intervention measures,while the intervention group received composite insulation nursing intervention.We ob-served and recorded postoperative blood pressure and heart rate changes,as well as postoperative anesthesia recovery time and incidence of complications.RESULTS The statistical results showed significant differences(P<0.05)in heart rate changes and systolic blood pressure between the two groups.There was a sig-nificant change in heart rate between the groups immediately after surgery and at 15 and 30 minutes after surgery(P<0.05).The heart rate and systolic blood pressure of the intervention group were significantly lower than those of the control group at 15 and 30 minutes after surgery(P<0.05).The rewarming time of the intervention group was shorter than that of the control group,and the overall incidence of postoperative complications was significantly lower than that of the control group(P<0.05).CONCLUSION For elderly patients undergoing laparoscopic colorectal cancer surgery,a composite insulation intervention during the perioperative period can maintain body temperature,reduce postoperative stress,and significantly reduce the incidence of hypothermia and related complications.展开更多
High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production meth...High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.展开更多
Multiple quantum well(MQW) Ⅲ-nitride diodes that can simultaneously emit and detect light feature an overlapping region between their electroluminescence and responsivity spectra, which allows them to be simultaneous...Multiple quantum well(MQW) Ⅲ-nitride diodes that can simultaneously emit and detect light feature an overlapping region between their electroluminescence and responsivity spectra, which allows them to be simultaneously used as both a transmitter and a receiver in a wireless light communication system. Here, we demonstrate a mobile light communication system using a time-division multiplexing(TDM) scheme to achieve bidirectional data transmission via the same optical channel.Two identical blue MQW diodes are defined by software as a transmitter or a receiver. To address the light alignment issue, an image identification module integrated with a gimbal stabilizer is used to automatically detect the locations of moving targets;thus, underwater audio communication is realized via a mobile blue-light TDM communication mode. This approach not only uses a single link but also integrates mobile nodes in a practical network.展开更多
ADER-WAF methods were first introduced by researchers E.F. Toro and V.A. Titarev. The linear stability criterion for the model equation for the ADER-WAF schemes is CCFL≤1, where CCFLdenotes the Courant-Friedrichs-Lew...ADER-WAF methods were first introduced by researchers E.F. Toro and V.A. Titarev. The linear stability criterion for the model equation for the ADER-WAF schemes is CCFL≤1, where CCFLdenotes the Courant-Friedrichs-Lewy (CFL) coefficient. Toro and Titarev employed CCFL=0.95for their experiments. Nonetheless, we noted that the experiments conducted in this study with CCFL=0.95produced solutions exhibiting spurious oscillations, particularly in the high-order ADER-WAF schemes. The homogeneous one-dimensional (1D) non-linear Shallow Water Equations (SWEs) are the subject of these experiments, specifically the solution of the Riemann Problem (RP) associated with the SWEs. The investigation was conducted on four test problems to evaluate the ADER-WAF schemes of second, third, fourth, and fifth order of accuracy. Each test problem constitutes a RP characterized by different wave patterns in its solution. This research has two primary objectives. We begin by illustrating the procedure for implementing the ADER-WAF schemes for the SWEs, providing the required relations. Afterward, following comprehensive testing, we present the range for the CFL coefficient for each test that yields solutions with diminished or eliminated spurious oscillations.展开更多
In this paper,we develop a fourth-order conservative wavelet-based shock-capturing scheme.The scheme is constructed by combining a wavelet collocation upwind method with the monotonic tangent of hyperbola for interfac...In this paper,we develop a fourth-order conservative wavelet-based shock-capturing scheme.The scheme is constructed by combining a wavelet collocation upwind method with the monotonic tangent of hyperbola for interface capturing(THINC)technique.We employ boundary variation diminishing(BVD)reconstruction to enhance the scheme’s effectiveness in handling shocks.First,we prove that wavelet collocation upwind schemes based on interpolating wavelets can be reformulated into a conservative form within the framework of wavelet theory,forming the foundation of the proposed scheme.The new fourthorder accurate scheme possesses significantly better spectral resolution than the fifth-and even seventh-order WENO-Z(weighted essentially non-oscillatory)schemes over the entire wave-number range.Moreover,the inherent low-pass filtering property of the wavelet bases allows them to filter high-frequency numerical oscillations,endowing the wavelet upwind scheme with robustness and accuracy in solving problems under extreme conditions.Notably,due to the wavelet multiresolution approximation,the proposed scheme possesses a distinctive shape-preserving property absent in the WENO-Z schemes and the fifth-order schemes with BVD reconstruction based on polynomials.Furthermore,compared to the fifth-order scheme with BVD reconstruction based on polynomials—which is significantly superior to the WENO schemes—the proposed scheme further enhances the ability to capture discontinuities.展开更多
Magnesium alloy thin-walled cylindrical components with the advantages of high specific stiffness and strength present broad prospect for the lightweight of aerospace components.However,poor formability resulting from...Magnesium alloy thin-walled cylindrical components with the advantages of high specific stiffness and strength present broad prospect for the lightweight of aerospace components.However,poor formability resulting from the hexagonal close-packed crystal structure in magnesium alloy puts forwards a great challenge for thin-walled cylindrical components fabrication,especially for extreme structure with the thicknesschanging web and the high thin-wall.In this research,an ZK61 magnesium alloy thin-walled cylindrical component was successfully fabricated by two-step forging,i.e.,the pre-forging and final-forging is mainly used for wed and thin-wall formation,respectively.Microstructure and mechanical properties at the core,middle and margin of the web and the thin-wall of the pre-forged and final-forged components are studied in detail.Due to the large strain-effectiveness and metal flow along the radial direction(RD),the grains of the web are all elongated along RD for the pre-forged component,where an increasingly elongated trend is found from the core to the margin of the wed.A relatively low recrystallized degree occurs during pre-forging,and the web at different positions are all with prismatic and pyramid textures.During finalforging,the microstructures of the web and the thin-wall are almost equiaxed due to the remarkable occurrence of dynamic recrystallization.Similarity,except for few basal texture of the thin-wall,only prismatic and pyramid textures are found for the final-forged component.Compared with the initial billet,an obviously improved mechanical isotropy is achieved during pre-forging,which is well-maintained during final-forging.展开更多
Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of un...Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over.展开更多
Ti-based bulk metallic glasses(BMGs)have attracted increasing attention due to their high specific strength.However,a fundamental conflict exists between the specific strength and glass-forming ability(GFA)of Ti-based...Ti-based bulk metallic glasses(BMGs)have attracted increasing attention due to their high specific strength.However,a fundamental conflict exists between the specific strength and glass-forming ability(GFA)of Ti-based BMGs,restricting their commercial applications significantly.In this study,this challenge was addressed by introducing a two-step alloying strategy to mitigate the remarkable density increment effect associated with heavy alloying elements required for enhancing the GFA.Consequently,through two-step alloying with Al and Fe in sequence,simultaneous enhancements in specific strength and GFA were achieved based on a Ti-Zr-Be ternary metallic glass,resulting in the development of a series of centimeter-sized metallic glasses exhibiting ultrahigh-specific strength.Notably,the newly developed(Ti_(45)Zr_(20)Be_(31)A_(l4))_(94)Fe_(6)alloy established a new record for the specific strength of Ti-based BMGs.Along with a critical diameter(D_(c))of 10 mm,it offers the optimal scheme for balancing the specific strength and GFA of Ti-based BMGs.The present results further brighten the application prospects of Ti-based BMGs as lightweight materials.展开更多
Numerical models play an important role in convective-scale forecasting,and dual-polarization radar observations can provide detailed microphysical data.In this study,we implement a direct assimilation operator for du...Numerical models play an important role in convective-scale forecasting,and dual-polarization radar observations can provide detailed microphysical data.In this study,we implement a direct assimilation operator for dual-polarization radar data using the hydrometeor background error covariance(HBEC)in the China Meteorological Administration MESO-scale weather forecasting system(CMA-MESO,formerly GRAPES-MESO)and conducted assimilation and forecasting experiments with X-band and S-band dual-polarization radar data on two cases.The results indicate that the direct assimilation of dual-polarization radar data enhanced the microphysical fields and the thermodynamic structure of convective systems to some extent based on the HBEC,thereby improving precipitation forecasts.Among the sensitivity tests of microphysical parameterization schemes,including the LIUMA scheme,the THOMPSON scheme,and the WSM6scheme(WRF Single-Moment 6-class),we find that the greatest improvement in the equivalent potential temperature,relative humidity,wind,and accumulated precipitation forecasts occurred in the experiment using the WSM6 scheme,as the distribution of solid precipitation particles was closer to the hydrometeor classification algorithm from the dualpolarization radar observations in our cases.展开更多
Reasonable greening design can effectively alleviate campus heat environment issues.This study uses the ENVI-met numerical model,along with in-situ observations and simulations,to analyze the thermal environment under...Reasonable greening design can effectively alleviate campus heat environment issues.This study uses the ENVI-met numerical model,along with in-situ observations and simulations,to analyze the thermal environment under three different greening schemes in typical areas of the Guangzhou University campus.The results indicate that the outdoor thermal environment is significantly influenced by the underlying surface materials and vegetation.The temperature of brick-paved surface is 0.9℃higher than that of natural soil surfaces under tree shade.Numerical simulations further confirm that increasing vegetation coverage effectively reduces outdoor air temperature.When the greening rate increases to 40%,the outdoor average temperature decreases by 0.7℃and relative humidity increases by approximately 4%,while wind speed remains minimal change.The cooling effect of vegetation is found to extend vertically to an altitude of 13 m.As the greening rate increases from 15%to 40%,the Mean Radiant Temperature(MRT)decreases from 50.6℃to 28.9℃,which is lower than the average ambient temperature,indicating improved thermal conditions.The Physiological Equivalent Temperature(PET)decreases from 40.2℃to 30.0℃,with the proportion of the areas classified as″very hot″reducing by 36.8%,significantly improving thermal comfort across most areas.Therefore,changing the ground material and greening landscape design can effectively alter the outdoor wind and thermal environment of the campus,thereby enhancing the thermal comfort for the campus community.展开更多
In this paper,we report the design of ultrafine ordered PtFeZn ternary intermetallics uniformly supported on ZIF-8-derived Zn,N-codoped graphitic carbon(ZnNC)via a green aqueous impregnation method followed by a two-s...In this paper,we report the design of ultrafine ordered PtFeZn ternary intermetallics uniformly supported on ZIF-8-derived Zn,N-codoped graphitic carbon(ZnNC)via a green aqueous impregnation method followed by a two-step annealing protocol(H_(2)/Ar,600 and 800℃)to circumvent the sintering issues imposed by conventional thermodynamics.Physical characterizations(X-ray diffraction,high-angle annular dark-field scanning transmission electron microscopy,X-ray absorption spectroscopy)and theoretical calculations reveal that low-temperature annealing at 600℃stabilizes sub-nano disordered PtFe alloys via the strong metal-support interactions(SMSI)between Zn in ZnNC and Pt precursors,while high-temperature treatment at 800℃promotes Zn diffusion from the support into the alloy bulk and simultaneously triggers the disorder-to-order phase transition.The as-prepared ZnNC-15PtFeZn exhibits an initial mass activity of 0.769 mA/μgPt and retains 61.7%of its activity after 30000 cycles of accelerated stress testing(AST).Notably,when used as a cathode catalyst in MEA,ZnNC-15PtFeZn achieves superior power density(2.018 W/cm^(2)under H_(2)-O_(2))at half the Pt loading(0.05 mg/cm^(2))of state-of-the-art commercial Pt/C,highlighting its potential for low-Pt PEMFCs.Density functional theory confirms that Fe enhances ORR activity via ligand effects,while Zn strengthens Pt-Fe/Zn bonding(elevating vacancy formation energies),thereby improving structural stability.This mild,scalable aqueous impregnation strategy offers a general approach for synthesizing multi-component ordered alloys in electrocatalysis.展开更多
基金Project (2012CB722805) supported by the National Basic Research Program of ChinaProjects (50974083, 51174131) supported by the National Natural Science Foundation of China+1 种基金Project (50774112) supported by the Joint Fund of NSFC and Baosteel, ChinaProject(07QA4021) supported by the Shanghai "Phosphor" Science Foundation, China
文摘The accelerating factor （AF） method is a simple and appropriate way to investigate the atomic long-time deep diffusion at solid-solid interface. In the framework of AF hyperdynamics （HD） simulation, the relationship between the diffusion coefficient along the direction of z-axis which is normal to the Mg/Zn interface and temperature was investigated, and the AF＇s impact on the diffusion constant （D0） and activation energy （Q^＊） was studied. Then, two steps were taken to simulate the atomic diffusion process and the formation of new phases： one for acceleration and the other for equilibration. The results show that： the Arrhenius equation works well for the description of Dz with different accelerating factors; the AF has no effect on the diffusion constant Do in the case of no phase transition; and the relationship between Q＊ and Q conforms to Q^＊=Q/A. Then, the new Arrhenius equation for AFHD is successfully constructed as Dz=Doexp[-Q/（ART）]. Meanwhile, the authentic equilibrium conformations at any dynamic moment can only be reproduced by the equilibration simulation of the HD-simulated configurations. Key words： accelerating factor method; Arrhenius equation; two-steps scheme; Mg/Zn interface; hyperdynamic simulation
基金supported by the Key Project of Joint Fund of the National Natural Science Foundation of China“Research on Key Technologies and Demonstration Applications for Trusted and Secure Data Circulation and Trading”(U24A20241)the National Natural Science Foundation of China“Research on Trusted Theories and Key Technologies of Data Security Trading Based on Blockchain”(62202118)+4 种基金the Major Scientific and Technological Special Project of Guizhou Province([2024]014)Scientific and Technological Research Projects from the Guizhou Education Department(Qian jiao ji[2023]003)the Hundred-Level Innovative Talent Project of the Guizhou Provincial Science and Technology Department(Qiankehe Platform Talent-GCC[2023]018)the Major Project of Guizhou Province“Research and Application of Key Technologies for Trusted Large Models Oriented to Public Big Data”(Qiankehe Major Project[2024]003)the Guizhou Province Computational Power Network Security Protection Science and Technology Innovation Talent Team(Qiankehe Talent CXTD[2025]029).
文摘As blockchain technology rapidly evolves,smart contracts have seen widespread adoption in financial transactions and beyond.However,the growing prevalence of malicious Ponzi scheme contracts presents serious security threats to blockchain ecosystems.Although numerous detection techniques have been proposed,existing methods suffer from significant limitations,such as class imbalance and insufficient modeling of transaction-related semantic features.To address these challenges,this paper proposes an oversampling-based detection framework for Ponzi smart contracts.We enhance the Adaptive Synthetic Sampling(ADASYN)algorithm by incorporating sample proximity to decision boundaries and ensuring realistic sample distributions.This enhancement facilitates the generation of high-quality minority class samples and effectively mitigates class imbalance.In addition,we design a Contract Transaction Graph(CTG)construction algorithm to preserve key transactional semantics through feature extraction from contract code.A graph neural network(GNN)is then applied for classification.This study employs a publicly available dataset from the XBlock platform,consisting of 318 verified Ponzi contracts and 6498 benign contracts.Sourced from real Ethereum deployments,the dataset reflects diverse application scenarios and captures the varied characteristics of Ponzi schemes.Experimental results demonstrate that our approach achieves an accuracy of 96%,a recall of 92%,and an F1-score of 94%in detecting Ponzi contracts,outperforming state-of-the-art methods.
基金supported by the National Natural Science of China No.11971263,11871458Shandong Provincial Natural Science Foundation No.ZR2019ZD41National Key R&D Program of China No.2018YFA0703900。
文摘In this paper,a stochastic linear two-step scheme has been presented to approximate backward stochastic differential equations(BSDEs).A necessary and sufficient condition is given to judge the L 2-stability of our numerical schemes.This stochastic linear two-step method possesses a family of 3-order convergence schemes in the sense of strong stability.The coefficients in the numerical methods are inferred based on the constraints of strong stability and n-order accuracy(n∈N^(+)).Numerical experiments illustrate that the scheme is an efficient probabilistic numerical method.
基金This work is supported by the Ntional Natural Science Foundation of China.
文摘This paper proposes a new two-step non-oscillatory shape-preserving positive definite finite difference advection transport scheme, which merges the advantages of small dispersion error in the simple first-order upstream scheme and small dissipation error in the simple second-order Lax-Wendroff scheme and is completely different from most of present positive definite advection schemes which are based on revising the upstream scheme results. The proposed scheme is much less time consuming than present shape-preserving or non-oscillatory advection transport schemes and produces results which are comparable to the results obtained from the present more complicated schemes. Elementary tests are also presented to examine the behavior of the scheme.
基金the National Natural Science Foundation of China(No.49925412,49990450),the National Basic Research Science Foundation(No.G2000078405)
文摘In this paper, a new numerical scheme of Total Variation Diminishing (TVD) MacCormack type for MagnetoHydroDynamic (MHD) equations is proposed by taking into account of the characteristics such as convergence, stability, resolution. This new scheme is established by solving the MHD equations with a TVD modified MacCormack scheme for the purpose of developing a scheme of quick convergence as well as of TVD property. To show the validation, simplicity and practicability of the scheme for modelling MHD problems, a self-similar Cauchy problem with the discontinuous initial data consisting of constant states, and the collision of two fast MHD shocks, and two-dimensional Orszag and Tang's MHD vortex problem are discussed with the numerical results conforming to the existing results obtained by the Roe type TVD, the high-order Godunov scheme,and Weighted Essentially Non-Oscillatory (WENO) scheme. The numerical tests show that this two-step TVD MacCormack numerical scheme for MHD system is of robust operation in the presence of very strong waves, thin shock fronts, thin contact and slip surface discontinuities.
基金supported by the National Natural Science Foundation of China(Grant No.41505066)the Basic Scientific Research and Operation Foundation of Chinese Academy Meteorological Sciences(Grant Nos.2015Z002,2015Y005)the National Research and Development Key Program:Global Change and Mitigation Strategies(No.2016YFA0602101)
文摘An Eulerian flux-form advection scheme, called the Two-step Shape-Preserving Advection Scheme （TSPAS）, was generalized and implemented on a spherical icosahedral hexagonal grid （also referred to as a geodesic grid） to solve the transport equation. The C grid discretization was used for the spatial discretization. To implement TSPAS on an unstructured grid, the original finite-difference scheme was further generalized. The two-step integration utilizes a combination of two separate schemes （a low-order monotone scheme and a high-order scheme that typically cannot ensure monotonicity） to calculate the fluxes at the cell walls （one scheme corresponds to one cell wall）. The choice between these two schemes for each edge depends on a pre-updated scalar value using slightly increased fluxes. After the determination of an appropriate scheme, the final integration at a target cell is achieved by summing the fluxes that are computed by the different schemes. The conservative and shape-preserving properties of the generalized scheme are demonstrated. Numerical experiments are conducted at several horizontal resolutions. TSPAS is compared with the Flux Corrected Transport （FCT） approach to demonstrate the differences between the two methods, and several transport tests are performed to examine the accuracy, efficiency and robustness of the two schemes.
基金supported by the National Natural Science Foun-dation of China(Nos.52025028,52332008,52372214,52202273,and U22A20137)the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions.
文摘Tin(Sn)-lead(Pb)mixed halide perovskites have attracted widespread interest due to their wider re-sponse wavelength and lower toxicity than lead halide perovskites,Among the preparation methods,the two-step method more easily controls the crystallization rate and is suitable for preparing large-area per-ovskite devices.However,the residual low-conductivity iodide layer in the two-step method can affect carrier transport and device stability,and the different crystallization rates of Sn-and Pb-based per-ovskites may result in poor film quality.Therefore,Sn-Pb mixed perovskites are mainly prepared by a one-step method.Herein,a MAPb_(0.5)Sn_(0.5)I_(3)-based self-powered photodetector without a hole transport layer is fabricated by a two-step method.By adjusting the concentration of the ascorbic acid(AA)addi-tive,the final perovskite film exhibited a pure phase without residues,and the optimal device exhibited a high responsivity(0.276 A W^(-1)),large specific detectivity(2.38×10^(12) Jones),and enhanced stability.This enhancement is mainly attributed to the inhibition of Sn2+oxidation,the control of crystal growth,and the sufficient reaction between organic ammonium salts and bottom halides due to the AA-induced pore structure.
文摘A custom micro-arc oxidation(MAO)apparatus is employed to produce coatings under optimized constant voltage–current two-step power supply mode.Various analytical techniques,including scanning electron microscopy,confocal laser microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,transmission electron microscopy,and electrochemical analysis,are employed to characterize MAO coatings at different stages of preparation.MAO has MgO,hydroxyapatite,Ca_(3)(PO_(4))_(2),and Mg2SiO4 phases.Its microstructure of the coating is characterized by"multiple breakdowns,pores within pores",and"repaired blind pores".The porosity and the uniformity of MAO coating first declines in the constant voltage mode,then augments while the discharge phenomenon takes place,and finally decreases in the repair stage.These analyses reveal a four-stage growth pattern for MAO coatings:anodic oxidation stage,micro-arc oxidation stage,breakdown stage,and repairing stage.During anodic oxidation and MAO stages,inward growth prevails,while the breakdown stage sees outward and accelerated growth.Simultaneous inward and outward growth in the repair stage results in a denser,more uniform coating with increased thickness and improved corrosion resistance.
基金Project(51378510) supported by the National Natural Science Foundation of China。
文摘In existing studies, most slope stability analyses concentrate on conditions with constant temperature, assuming the slope is intact, and employ the Mohr-Coulomb (M-C) failure criterion for saturated soil to characterize the strength of the backfill. However, the actual working temperature of slopes varies, and natural phenomena such as rainfall and groundwater infiltration commonly result in unsaturated soil conditions, with cracks typically present in cohesive slopes. This study introduces a novel approach for assessing the stability of unsaturated soil stepped slopes under varying temperatures, incorporating the effects of open and vertical cracks. Utilizing the kinematic approach and gravity increase method, we developed a three-dimensional (3D) rotational wedge failure mechanism to simulate slope collapse, enhancing the traditional two-dimensional analyses. We integrated temperature-dependent functions and nonlinear shear strength equations to evaluate the impact of temperature on four typical unsaturated soil types. A particle swarm optimization algorithm was employed to calculate the safety factor, ensuring our method’s accuracy by comparing it with existing studies. The results indicate that considering 3D effects yields a higher safety factor, while cracks reduce slope stability. Each unsaturated soil exhibits a distinctive temperature response curve, highlighting the importance of understanding soil types in the design phase.
文摘BACKGROUND Elderly patients undergoing laparoscopic colorectal cancer surgery are at high risk for hypothermia-related complications.This study explores the efficacy of periop-erative composite insulation interventions in maintaining normothermia and reducing postoperative risks in this vulnerable group.AIM To evaluate the efficacy of perioperative composite insulation in older patients undergoing colorectal cancer surgery.METHODS We selected 100 older patients who underwent laparoscopic surgery for colorectal cancer at Huzhou Central Hospital from September 2023 to April 2024.Using a random number table,patients were divided into a control group and inter-vention group of 50 patients each.After returning to the regular ward,the con-ventional group received traditional insulation intervention measures,while the intervention group received composite insulation nursing intervention.We ob-served and recorded postoperative blood pressure and heart rate changes,as well as postoperative anesthesia recovery time and incidence of complications.RESULTS The statistical results showed significant differences(P<0.05)in heart rate changes and systolic blood pressure between the two groups.There was a sig-nificant change in heart rate between the groups immediately after surgery and at 15 and 30 minutes after surgery(P<0.05).The heart rate and systolic blood pressure of the intervention group were significantly lower than those of the control group at 15 and 30 minutes after surgery(P<0.05).The rewarming time of the intervention group was shorter than that of the control group,and the overall incidence of postoperative complications was significantly lower than that of the control group(P<0.05).CONCLUSION For elderly patients undergoing laparoscopic colorectal cancer surgery,a composite insulation intervention during the perioperative period can maintain body temperature,reduce postoperative stress,and significantly reduce the incidence of hypothermia and related complications.
基金Natural Science Foundation of Shanghai(24ZR1400800)he Natural Science Foundation of China(U23A20685,52073058,91963204)+1 种基金the National Key R&D Program of China(2021YFB3701400)Shanghai Sailing Program(23YF1400200)。
文摘High-performance graphite materials have important roles in aerospace and nuclear reactor technologies because of their outstanding chemical stability and high-temperature performance.Their traditional production method relies on repeated impregnation-carbonization and graphitization,and is plagued by lengthy preparation cycles and high energy consumption.Phase transition-assisted self-pressurized selfsintering technology can rapidly produce high-strength graphite materials,but the fracture strain of the graphite materials produced is poor.To solve this problem,this study used a two-step sintering method to uniformly introduce micro-nano pores into natural graphite-based bulk graphite,achieving improved fracture strain of the samples without reducing their density and mechanical properties.Using natural graphite powder,micron-diamond,and nano-diamond as raw materials,and by precisely controlling the staged pressure release process,the degree of diamond phase transition expansion was effectively regulated.The strain-to-failure of the graphite samples reached 1.2%,a 35%increase compared to samples produced by fullpressure sintering.Meanwhile,their flexural strength exceeded 110 MPa,and their density was over 1.9 g/cm^(3).The process therefore produced both a high strength and a high fracture strain.The interface evolution and toughening mechanism during the two-step sintering process were investigated.It is believed that the micro-nano pores formed have two roles:as stress concentrators they induce yielding by shear and as multi-crack propagation paths they significantly lengthen the crack propagation path.The two-step sintering phase transition strategy introduces pores and provides a new approach for increasing the fracture strain of brittle materials.
基金jointly supported by the National Natural Science Foundation of China (U21A20495)Natural Science Foundation of Jiangsu Province (BG2024023)+1 种基金National Key Research and Development Program of China (2022YFE0112000)111 Project (D17018)。
文摘Multiple quantum well(MQW) Ⅲ-nitride diodes that can simultaneously emit and detect light feature an overlapping region between their electroluminescence and responsivity spectra, which allows them to be simultaneously used as both a transmitter and a receiver in a wireless light communication system. Here, we demonstrate a mobile light communication system using a time-division multiplexing(TDM) scheme to achieve bidirectional data transmission via the same optical channel.Two identical blue MQW diodes are defined by software as a transmitter or a receiver. To address the light alignment issue, an image identification module integrated with a gimbal stabilizer is used to automatically detect the locations of moving targets;thus, underwater audio communication is realized via a mobile blue-light TDM communication mode. This approach not only uses a single link but also integrates mobile nodes in a practical network.
文摘ADER-WAF methods were first introduced by researchers E.F. Toro and V.A. Titarev. The linear stability criterion for the model equation for the ADER-WAF schemes is CCFL≤1, where CCFLdenotes the Courant-Friedrichs-Lewy (CFL) coefficient. Toro and Titarev employed CCFL=0.95for their experiments. Nonetheless, we noted that the experiments conducted in this study with CCFL=0.95produced solutions exhibiting spurious oscillations, particularly in the high-order ADER-WAF schemes. The homogeneous one-dimensional (1D) non-linear Shallow Water Equations (SWEs) are the subject of these experiments, specifically the solution of the Riemann Problem (RP) associated with the SWEs. The investigation was conducted on four test problems to evaluate the ADER-WAF schemes of second, third, fourth, and fifth order of accuracy. Each test problem constitutes a RP characterized by different wave patterns in its solution. This research has two primary objectives. We begin by illustrating the procedure for implementing the ADER-WAF schemes for the SWEs, providing the required relations. Afterward, following comprehensive testing, we present the range for the CFL coefficient for each test that yields solutions with diminished or eliminated spurious oscillations.
基金supported by the National Natural Science Foundation of China(Grant No.11925204).
文摘In this paper,we develop a fourth-order conservative wavelet-based shock-capturing scheme.The scheme is constructed by combining a wavelet collocation upwind method with the monotonic tangent of hyperbola for interface capturing(THINC)technique.We employ boundary variation diminishing(BVD)reconstruction to enhance the scheme’s effectiveness in handling shocks.First,we prove that wavelet collocation upwind schemes based on interpolating wavelets can be reformulated into a conservative form within the framework of wavelet theory,forming the foundation of the proposed scheme.The new fourthorder accurate scheme possesses significantly better spectral resolution than the fifth-and even seventh-order WENO-Z(weighted essentially non-oscillatory)schemes over the entire wave-number range.Moreover,the inherent low-pass filtering property of the wavelet bases allows them to filter high-frequency numerical oscillations,endowing the wavelet upwind scheme with robustness and accuracy in solving problems under extreme conditions.Notably,due to the wavelet multiresolution approximation,the proposed scheme possesses a distinctive shape-preserving property absent in the WENO-Z schemes and the fifth-order schemes with BVD reconstruction based on polynomials.Furthermore,compared to the fifth-order scheme with BVD reconstruction based on polynomials—which is significantly superior to the WENO schemes—the proposed scheme further enhances the ability to capture discontinuities.
基金supported by the National Natural Science Foundation of China(No.52405408,No.U21A20131,No.U2037204,No.52422510)the Natural Science Foundation of Hubei Province(No.2023AFB116)+1 种基金the State Key Laboratory of Materials Processing and Die&Mould TechnologyHuazhong University of Science and Technology(No.P2022-005)。
文摘Magnesium alloy thin-walled cylindrical components with the advantages of high specific stiffness and strength present broad prospect for the lightweight of aerospace components.However,poor formability resulting from the hexagonal close-packed crystal structure in magnesium alloy puts forwards a great challenge for thin-walled cylindrical components fabrication,especially for extreme structure with the thicknesschanging web and the high thin-wall.In this research,an ZK61 magnesium alloy thin-walled cylindrical component was successfully fabricated by two-step forging,i.e.,the pre-forging and final-forging is mainly used for wed and thin-wall formation,respectively.Microstructure and mechanical properties at the core,middle and margin of the web and the thin-wall of the pre-forged and final-forged components are studied in detail.Due to the large strain-effectiveness and metal flow along the radial direction(RD),the grains of the web are all elongated along RD for the pre-forged component,where an increasingly elongated trend is found from the core to the margin of the wed.A relatively low recrystallized degree occurs during pre-forging,and the web at different positions are all with prismatic and pyramid textures.During finalforging,the microstructures of the web and the thin-wall are almost equiaxed due to the remarkable occurrence of dynamic recrystallization.Similarity,except for few basal texture of the thin-wall,only prismatic and pyramid textures are found for the final-forged component.Compared with the initial billet,an obviously improved mechanical isotropy is achieved during pre-forging,which is well-maintained during final-forging.
基金supported by the National Natural Science Foundation of China(No.92252201)the Fundamental Research Funds for the Central Universitiesthe Academic Excellence Foundation of Beihang University(BUAA)for PhD Students。
文摘Efficient and accurate simulation of unsteady flow presents a significant challenge that needs to be overcome in computational fluid dynamics.Temporal discretization method plays a crucial role in the simulation of unsteady flows.To enhance computational efficiency,we propose the Implicit-Explicit Two-Step Runge-Kutta(IMEX-TSRK)time-stepping discretization methods for unsteady flows,and develop a novel adaptive algorithm that correctly partitions spatial regions to apply implicit or explicit methods.The novel adaptive IMEX-TSRK schemes effectively handle the numerical stiffness of the small grid size and improve computational efficiency.Compared to implicit and explicit Runge-Kutta(RK)schemes,the IMEX-TSRK methods achieve the same order of accuracy with fewer first derivative calculations.Numerical case tests demonstrate that the IMEX-TSRK methods maintain numerical stability while enhancing computational efficiency.Specifically,in high Reynolds number flows,the computational efficiency of the IMEX-TSRK methods surpasses that of explicit RK schemes by more than one order of magnitude,and that of implicit RK schemes several times over.
基金supported by the National Natural Science Foundation of China(Nos.52271148 and 51871129).
文摘Ti-based bulk metallic glasses(BMGs)have attracted increasing attention due to their high specific strength.However,a fundamental conflict exists between the specific strength and glass-forming ability(GFA)of Ti-based BMGs,restricting their commercial applications significantly.In this study,this challenge was addressed by introducing a two-step alloying strategy to mitigate the remarkable density increment effect associated with heavy alloying elements required for enhancing the GFA.Consequently,through two-step alloying with Al and Fe in sequence,simultaneous enhancements in specific strength and GFA were achieved based on a Ti-Zr-Be ternary metallic glass,resulting in the development of a series of centimeter-sized metallic glasses exhibiting ultrahigh-specific strength.Notably,the newly developed(Ti_(45)Zr_(20)Be_(31)A_(l4))_(94)Fe_(6)alloy established a new record for the specific strength of Ti-based BMGs.Along with a critical diameter(D_(c))of 10 mm,it offers the optimal scheme for balancing the specific strength and GFA of Ti-based BMGs.The present results further brighten the application prospects of Ti-based BMGs as lightweight materials.
基金sponsored by the National Natural Science Foundation of China(U2442601 and U2442218)the High Performance Computing Platform of Nanjing University of Information Science&Technology(NUIST)for their support of this work。
文摘Numerical models play an important role in convective-scale forecasting,and dual-polarization radar observations can provide detailed microphysical data.In this study,we implement a direct assimilation operator for dual-polarization radar data using the hydrometeor background error covariance(HBEC)in the China Meteorological Administration MESO-scale weather forecasting system(CMA-MESO,formerly GRAPES-MESO)and conducted assimilation and forecasting experiments with X-band and S-band dual-polarization radar data on two cases.The results indicate that the direct assimilation of dual-polarization radar data enhanced the microphysical fields and the thermodynamic structure of convective systems to some extent based on the HBEC,thereby improving precipitation forecasts.Among the sensitivity tests of microphysical parameterization schemes,including the LIUMA scheme,the THOMPSON scheme,and the WSM6scheme(WRF Single-Moment 6-class),we find that the greatest improvement in the equivalent potential temperature,relative humidity,wind,and accumulated precipitation forecasts occurred in the experiment using the WSM6 scheme,as the distribution of solid precipitation particles was closer to the hydrometeor classification algorithm from the dualpolarization radar observations in our cases.
基金Science and Technology Research Project of Guang-dong Meteorological Bureau(GRMC2022M21)Guangdong Basic and Applied Basic Research Foundation(2023A1515012240)Research Project of Guangzhou Meteor-ological Bureau(M202218)。
文摘Reasonable greening design can effectively alleviate campus heat environment issues.This study uses the ENVI-met numerical model,along with in-situ observations and simulations,to analyze the thermal environment under three different greening schemes in typical areas of the Guangzhou University campus.The results indicate that the outdoor thermal environment is significantly influenced by the underlying surface materials and vegetation.The temperature of brick-paved surface is 0.9℃higher than that of natural soil surfaces under tree shade.Numerical simulations further confirm that increasing vegetation coverage effectively reduces outdoor air temperature.When the greening rate increases to 40%,the outdoor average temperature decreases by 0.7℃and relative humidity increases by approximately 4%,while wind speed remains minimal change.The cooling effect of vegetation is found to extend vertically to an altitude of 13 m.As the greening rate increases from 15%to 40%,the Mean Radiant Temperature(MRT)decreases from 50.6℃to 28.9℃,which is lower than the average ambient temperature,indicating improved thermal conditions.The Physiological Equivalent Temperature(PET)decreases from 40.2℃to 30.0℃,with the proportion of the areas classified as″very hot″reducing by 36.8%,significantly improving thermal comfort across most areas.Therefore,changing the ground material and greening landscape design can effectively alter the outdoor wind and thermal environment of the campus,thereby enhancing the thermal comfort for the campus community.
文摘In this paper,we report the design of ultrafine ordered PtFeZn ternary intermetallics uniformly supported on ZIF-8-derived Zn,N-codoped graphitic carbon(ZnNC)via a green aqueous impregnation method followed by a two-step annealing protocol(H_(2)/Ar,600 and 800℃)to circumvent the sintering issues imposed by conventional thermodynamics.Physical characterizations(X-ray diffraction,high-angle annular dark-field scanning transmission electron microscopy,X-ray absorption spectroscopy)and theoretical calculations reveal that low-temperature annealing at 600℃stabilizes sub-nano disordered PtFe alloys via the strong metal-support interactions(SMSI)between Zn in ZnNC and Pt precursors,while high-temperature treatment at 800℃promotes Zn diffusion from the support into the alloy bulk and simultaneously triggers the disorder-to-order phase transition.The as-prepared ZnNC-15PtFeZn exhibits an initial mass activity of 0.769 mA/μgPt and retains 61.7%of its activity after 30000 cycles of accelerated stress testing(AST).Notably,when used as a cathode catalyst in MEA,ZnNC-15PtFeZn achieves superior power density(2.018 W/cm^(2)under H_(2)-O_(2))at half the Pt loading(0.05 mg/cm^(2))of state-of-the-art commercial Pt/C,highlighting its potential for low-Pt PEMFCs.Density functional theory confirms that Fe enhances ORR activity via ligand effects,while Zn strengthens Pt-Fe/Zn bonding(elevating vacancy formation energies),thereby improving structural stability.This mild,scalable aqueous impregnation strategy offers a general approach for synthesizing multi-component ordered alloys in electrocatalysis.
