In this paper,we present a necessary and sufficient condition for hyponormal block Toeplitz operators T on the vector-valued weighted Bergman space with symbolsΦ(z)=G^(*)(z)+F(z),where F(z)=∑^(N)_(i)=1 A_(i)z^(i)and...In this paper,we present a necessary and sufficient condition for hyponormal block Toeplitz operators T on the vector-valued weighted Bergman space with symbolsΦ(z)=G^(*)(z)+F(z),where F(z)=∑^(N)_(i)=1 A_(i)z^(i)and G(z)=∑^(N)_(i)=1 A_(−i)z^(i),A_(i)ae culants.展开更多
When patients initially present with atrial fibrillation along with an enlarged heart and heart failure, followed by atrioventricular block, it's essential to consider genetic factors.^([1])Genetic testing can off...When patients initially present with atrial fibrillation along with an enlarged heart and heart failure, followed by atrioventricular block, it's essential to consider genetic factors.^([1])Genetic testing can offer crucial diagnostic evidence, aiding in prognosis assessment and the adoption of appropriate treatment strategies.展开更多
The diagnostic efficacy of contemporary bioimaging technologies remains constrained by inherent limitations of conventional imaging agents,including suboptimal sensitivity,off-target biodistribution,and inherent cytot...The diagnostic efficacy of contemporary bioimaging technologies remains constrained by inherent limitations of conventional imaging agents,including suboptimal sensitivity,off-target biodistribution,and inherent cytotoxicity.These limitations have catalyzed the development of intelligent stimuli-responsive block copolymers-based bioimaging agents,which was engineered to dynamically respond to endogenous biochemical cues(e.g.,p H gradients,redox potential,enzyme activity,hypoxia environment) or exogenous physical triggers(e.g.,photoirradiation,thermal gradients,ultrasound(US)/magnetic stimuli).Through spatiotemporally controlled structural transformations,stimuli-responsive block copolymers enable precise contrast targeting,activatable signal amplification,and theranostic integration,thereby substantially enhancing signal-to-noise ratios of bioimaging and diagnostic specificity.Hence,this mini-review systematically examines molecular engineering principles for designing p H-,redox-,enzyme-,light-,thermo-,and US/magnetic-responsive polymers,with emphasis on structure-property relationships governing imaging performance modulation.Furthermore,we critically analyze emerging strategies for optical imaging,US synergies,and magnetic resonance imaging(MRI).Multimodal bioimaging has also been elaborated,which could overcome the inherent trade-offs between resolution,penetration depth,and functional specificity in single-modal approaches.By elucidating mechanistic insights and translational challenges,this mini-review aims to establish a design framework of stimuli-responsive block copolymersbased for high fidelity bioimaging agents and accelerate their clinical translation in precise diagnosis and therapy.展开更多
Switchable polymerization is emerging as a powerful tool to construct block copolymers directly from mixtures of monomers.However,current achievements typically iterate between two polymerization cycles to afford prod...Switchable polymerization is emerging as a powerful tool to construct block copolymers directly from mixtures of monomers.However,current achievements typically iterate between two polymerization cycles to afford products with fixed sequences and compositions.Herein,we report the triethylborane/1,8-diazabicyclo[5.4.0]undec-7-ene(Et_3B/DBU)pair-mediated four-component switchable polymerization of propylene oxide(PO),CO_(2),phthalic anhydride(PA),and racemic lactide(rac-LA),which enables the on-demand synthesis of four different block copolymers,i.e.,poly(propylene phthalate)-b-polylactide(PPE-b-PLA),PPE-b-PLA-b-poly(propylene carbonate)(PPC),PPE-b-PPC-b-PLA,and PPE-b-PPCb-poly(propylene oxide)(PPO),through rationally modulating the Lewis pair(LP)ratio.Core to this protocol is that increasing the loading of Et_(3)B accelerates the ring-opening of PO while impeding the reactivity of rac-LA,thus allowing for fine-tuning of the thermodynamic and kinetic of the switchable polymerization.Therefore,the four polymerization cycles involving PO/PA ring-opening copolymerization(ROCOP),PO/CO_(2) ROCOP,rac-LA ring-opening polymerization(ROP),and PO ROP can be connected and discriminated in precisely programmed manners.展开更多
This paper presents a novel artificial intelligence(AI)-assisted two-stage method for optimising rock slope stability by integrating advanced 3D modelling with rock support design,aiming at minimising risks,material u...This paper presents a novel artificial intelligence(AI)-assisted two-stage method for optimising rock slope stability by integrating advanced 3D modelling with rock support design,aiming at minimising risks,material usage,and costs.In the first stage,an extended key block analysis identifies key blocks and key block groups,accounting for progressive failure and force interactions.The second stage uses AI algorithms to optimise rockbolting design,balancing stability,cost,and material use.The most efficient algorithms include the multi-objective tree-structured Parzen estimator(MOTPE)and non-dominated sorting genetic algorithms(NSGA-II and NSGA-III).Applied to the Larvik rock slope,the optimised solution uses 18 pre-tensioned cablebolts,providing 13.2 MN of active force and achieving a factor of safety of 1.31 while reducing the average anchorage length by approximately 16%compared to traditional design.The AI-assisted approach also reduces computation time by over 90%compared to Quasi-Monte Carlo(QMC)methods,demonstrating its efficiency for small-scale civil engineering projects and large-scale mining operations.The developed tool is practical,compatible with Building Information Modelling(BIM),and ready for engineering implementation,supporting sustainable and cost-effective rock slope stabilisation.While the method is largely automated,professional judgement remains crucial for verifying ground conditions and selecting the final solution.Future work will focus on integrating data uncertainties,addressing complex block deformation mechanisms,refining optimisation objectives,and improving the performance of multi-objective optimisation for slope rockboling applications to further enhance the method's versatility.展开更多
Waste graphitization cathode carbon blocks are a type of hazardous solid waste generated during the aluminum electrolysis process,and their proper disposal is a key step in the resource utilization of discarded graphi...Waste graphitization cathode carbon blocks are a type of hazardous solid waste generated during the aluminum electrolysis process,and their proper disposal is a key step in the resource utilization of discarded graphite.This study utilizes the porous“defect advantage”of a cathode carbon block matrix to prepare silicon-doped and asphalt-coated detoxified and purified waste graphitization cathode carbon blocks for use as high-performance silicon/carbon composite anode materials.The results show that the uniformly silicondoped silicon/carbon composite material features a unique amorphous carbon-encapsulated“locked silicon”structure,which effectively addresses issues such as cathode volume expansion,excessive growth of the solid electrolyte interphase(SEI)film,and poor electrical contact between active materials.Consequently,electrochemical performance is enhanced.After assembly in a half-cell,the PSCC/10%Si@C(purified waste graphitization cathode carbon/10%Si@C)material exhibits optimal electrochemical stability,with an initial charging specific capacity of 514.5 mAh/g at 0.1 C(1 C=170 mA/g)and a capacity retention rate of 95.1%after 100 cycles.At a charge rate of 2.0 C,a specific capacity of 216.9 mAh/g is achieved.This technology provides a new pathway for the economical and high-value utilization of waste cathode carbon blocks and the development of low-cost,high-performance anode materials.展开更多
Star-shaped six-arm polymers with hexaaza[2_(6)]orthoparacyclophane core and arms of block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine were synthesized successfully using cat...Star-shaped six-arm polymers with hexaaza[2_(6)]orthoparacyclophane core and arms of block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine were synthesized successfully using cationic ring-opening polymerization.The ratio of blocks,the order of their attachment to the core,and arm length were varied.Conformation of synthesized stars was determined by methods of molecular hydrodynamics and optics.It has been shown that star-shaped molecules were characterized by high intramolecular density,and the arm folding increased with their lengthening.The influence of the structure of block copolymers and their molar mass on the critical micelle concentration has been established.Complexes of synthesized star-shaped block copolymers with curcumin were obtained and the efficient binding of curcumin to polymer molecules was demonstrated.The behavior of the aqueous solutions of the prepared polymer stars and their complexes with curcumin was investigated by light scattering and turbidimetry methods.The influence of the structure and molar mass of star polymers on their thermoresponsiveness and the phase separation temperatures in aqueous solutions was analyzed.A slight increase in the phase separation temperature was found on passage from polymer solutions to solutions of polymer complexes with hydrophobic curcumin.展开更多
For the large sparse block two-by-two real nonsingular matrices, we establish a general framework of structured preconditioners through matrix transformation and matrix approximations. For the specific versions such a...For the large sparse block two-by-two real nonsingular matrices, we establish a general framework of structured preconditioners through matrix transformation and matrix approximations. For the specific versions such as modified block Jacobi-type, modified block Gauss-Seidel-type, and modified block unsymmetric (symmetric) Gauss-Seidel-type preconditioners, we precisely describe their concrete expressions and deliberately analyze eigenvalue distributions and positive definiteness of the preconditioned matrices. Also, we show that when these structured preconditioners are employed to precondition the Krylov subspace methods such as GMRES and restarted GMRES, fast and effective iteration solvers can be obtained for the large sparse systems of linear equations with block two-by-two coefficient matrices. In particular, these structured preconditioners can lead to high-quality preconditioning matrices for some typical matrices from the real-world applications.展开更多
A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relati...A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relative permeability number＇ （RPN） was firstly defined, and then used to describe the degree of water block. Imbibition process simulations show that the RPN drops in accordance with the extension of the averaged pore throat radius from 0.05 to 1.5 μm, and yet once beyond that point of 1.5 μm, the RPN reaches a higher value, indicating the existence of a critical pore throat radius where water block is the maximum. When the wettability of the samples changes from water-wet to weakly water-wet, weakly gas-wet, or gas（oil）-wet, the gas RPN increases consistently, but this consistency is disturbed by the RPN dropping for weakly water-wet samples for water saturations less than 0.4, which means weakly waterwet media are more easily water blocked than water-wet systems. In the situation where the initial water saturation exceeds 0.05, water block escalates along with an increase in initial water saturation.展开更多
Blockage is a kind of phenomenon occurring frequently in modern transportation network. This paper deals with the research work on the blocking now in a network with the help of network flow theory. The blockage pheno...Blockage is a kind of phenomenon occurring frequently in modern transportation network. This paper deals with the research work on the blocking now in a network with the help of network flow theory. The blockage phenomena can be divided intO local blockage and network blockage. In this paper, which deals mainly with the latter, the fundamental concepts and definitions of network blocking flow, blocking outset are presented and the related theorems are proved. It is proved that the sufficient and necessary condition for the emergence of a blocking now in a network is the existence of the blocking outset. The necessary conditions for the existence of the blocking outset in a network are analysed and the characteristic cutset of blockage which reflects the all possible situation of blocking nows in the network is defined.In the last part of the paper the mathematical model of the minimum blocking now is developed and the solution to a small network is given.展开更多
Exercise-induced left bundle branch block(EI-LBBB)is infrequent phenomenon.We present two patients with angina pectoris who developed EI-LBBB during exercise tolerance test.The first patient with typical angina pector...Exercise-induced left bundle branch block(EI-LBBB)is infrequent phenomenon.We present two patients with angina pectoris who developed EI-LBBB during exercise tolerance test.The first patient with typical angina pectoris had significant obstructive coronary artery disease(CAD)requiring percutaneous coronary intervention of multiple lesions including placement of drug eluting stents.The second patient had atypical chest pain without signs of CAD at all.EI-LBBB occurred at a heart rate of 80 bpm and 141 bpm in the first and second patient,respectively.EI-LBBB remained visible through the test till the recovery period in the first patient at a heart rate of 83 bpm and disappeared at 96bpm in the second patient.Both patients with this infrequent phenomenon are discussed and the literature is reviewed.展开更多
The self-assembly of block copolymer in solution has proven to be an effective strategy for building up a wide range of nanomaterials with diverse structures and applications.This paper reports a facile self-assembly ...The self-assembly of block copolymer in solution has proven to be an effective strategy for building up a wide range of nanomaterials with diverse structures and applications.This paper reports a facile self-assembly approach towards two-dimensional(2D)sandwich-like mesoporous nitrogen-doped carbon/reduced graphene oxide nanocomposites(denoted as mNC/rGO)with well-defined large mesopores.The strategy involves the synergistic self-assembly ofpolystyrene-block-poly(ethylene oxide)(PS-b-PEO)spherical micelles,m-phenylenediamine(mPD)monomers and GO in solution and the subsequent carbonization at 900~C.The resultant mNC/rGO nanosheets have an average pore size of 19 nm,a high specific surface of 812 m^(2)'g^(-1)and a nitrogen content of 2.2 wt%.As an oxygen reduction reaction(ORR)catalyst,the unique structural features render the metal-free nanosheets excellent electrocatalytic performance.In a 0.1 mol.L-~KOH alkaline medium,mNC/rGO exhibits a four-electron transfer pathway with a high half-wave-potential(El/2)of+0.77 V versus reversible hydrogen electrode(RHE)and a limiting current density(JL)of 5.2 mA'cm^(-2),which are well comparable with those of the commercial Pt/C catalysts.展开更多
Aim: To diagnose COVID-19 more efficiently and more correctly, this study proposed a novel attention network forCOVID-19 (ANC). Methods: Two datasets were used in this study. An 18-way data augmentation was proposed t...Aim: To diagnose COVID-19 more efficiently and more correctly, this study proposed a novel attention network forCOVID-19 (ANC). Methods: Two datasets were used in this study. An 18-way data augmentation was proposed toavoid overfitting. Then, convolutional block attention module (CBAM) was integrated to our model, the structureof which is fine-tuned. Finally, Grad-CAM was used to provide an explainable diagnosis. Results: The accuracyof our ANC methods on two datasets are 96.32% ± 1.06%, and 96.00% ± 1.03%, respectively. Conclusions: Thisproposed ANC method is superior to 9 state-of-the-art approaches.展开更多
In this paper, we propose a novel block cryptographic scheme based on a spatiotemporal chaotic system and a chaotic neural network （CNN）. The employed CNN comprises a 4-neuron layer called a chaotic neuron layer （...In this paper, we propose a novel block cryptographic scheme based on a spatiotemporal chaotic system and a chaotic neural network （CNN）. The employed CNN comprises a 4-neuron layer called a chaotic neuron layer （CNL）, where the spatiotemporal chaotic system participates in generating its weight matrix and other parameters. The spatiotemporal chaotic system used in our scheme is the typical coupled map lattice （CML）, which can be easily implemented in parallel by hard- ware. A 160-bit-long binary sequence is used to generate the initial conditions of the CML. The decryption process is symmetric relative to the encryption process. Theoretical analysis and experimental results prove that the block cryptosys- tem is secure and practical, and suitable for image encryption.展开更多
Nickel nitrate was introduced into carbon blocks by using ECA aggregates as catalyst-carrier.The Ni-containing anthracite aggregates were firstly prepared by mixing anthracite aggregates in nickel nitrate ethanol solu...Nickel nitrate was introduced into carbon blocks by using ECA aggregates as catalyst-carrier.The Ni-containing anthracite aggregates were firstly prepared by mixing anthracite aggregates in nickel nitrate ethanol solution and then incorporated into carbon blocks after pre-treating.The phase composition,microstructure and properties of all carbon blocks fired at 1 000℃or 1 400℃in a coke bed were studied with the aid of an X-ray diffractomer,a field emission scanning electron microscope,a mercury porosimetry and a laser thermal conductivity meter.The results showed that the addition of Ni-containing anthracite aggregates promoted the formation of one-dimensional nanocarbon andβ-SiC whiskers at 1 000℃and the growth ofβ-Sialon at 1 400℃,respectively.Moreover,the cold compressive strength and microporosity characteristics of the carbon blocks with the addition of Ni-containing anthracite aggregates were enhanced and the thermal conductivity was remarkably improved attributing to the high heat conductive network formed by the ceramic phases.展开更多
The Heyuan Fault,is one of the main NE-trending faults in the southernmost South China Block and is close to the northernmost South China Sea to the south.The fault features multi-stage deformation and controlled the ...The Heyuan Fault,is one of the main NE-trending faults in the southernmost South China Block and is close to the northernmost South China Sea to the south.The fault features multi-stage deformation and controlled the formation of late Cretaceous to Cenozoic basins.Based on detailed field investigations and comprehensive geochronological research,including zircon U-Pb,Rb-Sr isochron,zircon U-Th-He dating,two episodic tectono-thermal events are recognized.The first occurred during~79 Ma to 66 Ma,which is characterized by large-scale quartz-fluid emplacement.The other occurred at~34 Ma,which features the eruption of a set of basalts.The two events show a changing on material source from siliceous hydrotherm to basalt magma,supporting obvious lithospheric thinning of the southernmost South China Block,which shed light on the geological evolution and the interaction mechanisms between the SCB and the northern South China Sea since the Late Cretaceous.展开更多
We report two high risk patients undergoing inguinal herniorraphy and testicular biopsy under ultrasound-guided ilioinguinal/iliohypogastric and genitofemoral nerve blocks. The addition of the genitofemoral nerve bloc...We report two high risk patients undergoing inguinal herniorraphy and testicular biopsy under ultrasound-guided ilioinguinal/iliohypogastric and genitofemoral nerve blocks. The addition of the genitofemoral nerve block may enhance the ilioinguinal/iliohypogastric block to achieve complete anesthesia and thus avoid general and neuraxial anesthesia related hypotension that may be detrimental in patients with low cardiac reserve.展开更多
Based on the heat flow data published in 1990 and 2001, a study of the factors influencing the terrestrial heat flow distribution in the China continent and its quantitative expression is carried out using the ＂Netli...Based on the heat flow data published in 1990 and 2001, a study of the factors influencing the terrestrial heat flow distribution in the China continent and its quantitative expression is carried out using the ＂Netlike Plastic-Flow＂ continental dynamics model and the methods of statistic analysis and optimum fitting. The result indicates that the factors influencing the heat flow distribution is classified into two groups, i.e. background and tectonic ones, in which the former mainly involves the non- uniform distribution of mantle heat flow, heat production of radioactive dements in the crust, heattransfer media and hydrothermal circulation, while the latter mainly involves plastic-flow networks and relatively-stable blocks. The plastic-flow network is a manifestation of shear localization in the netlike plastic-flow process in the lower lithosphere, which is composed of two sets of plastic-flow belts （PFBs） intersecting each other and, as one of the basic action regimes, controls the intraplate tectonic deformation. Relatively stable blocks （RSBs）, which are the tectonic units with relatively-high viscosities existing in the netlike plastic-flow field, as one of the principal origins, result in the development of large-seale compressional basins. PFB and RSB, as the active and quiet states of tectonic deformation, give rise to the higher and lower heat flow values, respectivdy. The provincial average heat flow in continent can be estimated using the expression qav = q0 ＋ a Pbt-c Pbk, where the three terms of the right side are background heat flow, PFB-positive contribution and RSB-negative contribution, Pbt and Pbk are the PFB- and RSB-coverage ratios, respectively, a is the coefficient of PFB- positive contribution depending mainly on the strain in the lower lithosphere, and c is the coefficient of RSB-negative contribution related mainly to the thickness of the lithosphere, the aseismic-area ratio and the tectonic age. For the major portion of the China continent excluding some of the southeastern region of China, the confidence interval of the provincial average background heat flow is qo=57.25±24.8 mW/m^2 and the PFB-positive- and RSB-negative-contribution coefficients are a=14.8-71.9 mW/m^2 and c=0-25.6 mW/m^2, respectively. The concepts of PFB and RSB effects and the heat flow expression suggested provide a new choice of the approach to the quantitative description of the characteristics of heat flow distribution in continent and their physical mechanisms.展开更多
文摘In this paper,we present a necessary and sufficient condition for hyponormal block Toeplitz operators T on the vector-valued weighted Bergman space with symbolsΦ(z)=G^(*)(z)+F(z),where F(z)=∑^(N)_(i)=1 A_(i)z^(i)and G(z)=∑^(N)_(i)=1 A_(−i)z^(i),A_(i)ae culants.
基金Military Healthcare Special Scientific Research Project(25BJZ31, awarded to SHI XM)。
文摘When patients initially present with atrial fibrillation along with an enlarged heart and heart failure, followed by atrioventricular block, it's essential to consider genetic factors.^([1])Genetic testing can offer crucial diagnostic evidence, aiding in prognosis assessment and the adoption of appropriate treatment strategies.
基金supported by the National Natural Science Foundation of China (Nos.22208218,22078196,and 22278268)the Natural Science Foundation of Shanghai (No.22ZR1460400)Collaborative Innovation Center of Fragrance Flavour and Cosmetics,and Collaborative Innovation Project of Shanghai Institute of Technology (No.XTCX2023-07)。
文摘The diagnostic efficacy of contemporary bioimaging technologies remains constrained by inherent limitations of conventional imaging agents,including suboptimal sensitivity,off-target biodistribution,and inherent cytotoxicity.These limitations have catalyzed the development of intelligent stimuli-responsive block copolymers-based bioimaging agents,which was engineered to dynamically respond to endogenous biochemical cues(e.g.,p H gradients,redox potential,enzyme activity,hypoxia environment) or exogenous physical triggers(e.g.,photoirradiation,thermal gradients,ultrasound(US)/magnetic stimuli).Through spatiotemporally controlled structural transformations,stimuli-responsive block copolymers enable precise contrast targeting,activatable signal amplification,and theranostic integration,thereby substantially enhancing signal-to-noise ratios of bioimaging and diagnostic specificity.Hence,this mini-review systematically examines molecular engineering principles for designing p H-,redox-,enzyme-,light-,thermo-,and US/magnetic-responsive polymers,with emphasis on structure-property relationships governing imaging performance modulation.Furthermore,we critically analyze emerging strategies for optical imaging,US synergies,and magnetic resonance imaging(MRI).Multimodal bioimaging has also been elaborated,which could overcome the inherent trade-offs between resolution,penetration depth,and functional specificity in single-modal approaches.By elucidating mechanistic insights and translational challenges,this mini-review aims to establish a design framework of stimuli-responsive block copolymersbased for high fidelity bioimaging agents and accelerate their clinical translation in precise diagnosis and therapy.
基金financially supported by National Key R&D Program Young Scientists Project(No.2023YFC3903100)the National Natural Science Foundation of China(No.22322503)analytical and testing assistance from the Analysis and Testing Center of HUST。
文摘Switchable polymerization is emerging as a powerful tool to construct block copolymers directly from mixtures of monomers.However,current achievements typically iterate between two polymerization cycles to afford products with fixed sequences and compositions.Herein,we report the triethylborane/1,8-diazabicyclo[5.4.0]undec-7-ene(Et_3B/DBU)pair-mediated four-component switchable polymerization of propylene oxide(PO),CO_(2),phthalic anhydride(PA),and racemic lactide(rac-LA),which enables the on-demand synthesis of four different block copolymers,i.e.,poly(propylene phthalate)-b-polylactide(PPE-b-PLA),PPE-b-PLA-b-poly(propylene carbonate)(PPC),PPE-b-PPC-b-PLA,and PPE-b-PPCb-poly(propylene oxide)(PPO),through rationally modulating the Lewis pair(LP)ratio.Core to this protocol is that increasing the loading of Et_(3)B accelerates the ring-opening of PO while impeding the reactivity of rac-LA,thus allowing for fine-tuning of the thermodynamic and kinetic of the switchable polymerization.Therefore,the four polymerization cycles involving PO/PA ring-opening copolymerization(ROCOP),PO/CO_(2) ROCOP,rac-LA ring-opening polymerization(ROP),and PO ROP can be connected and discriminated in precisely programmed manners.
基金support from Research Council of Norway via STIPINST PhD grant(Grant No.323307),Bever Control AS,and Bane NOR.
文摘This paper presents a novel artificial intelligence(AI)-assisted two-stage method for optimising rock slope stability by integrating advanced 3D modelling with rock support design,aiming at minimising risks,material usage,and costs.In the first stage,an extended key block analysis identifies key blocks and key block groups,accounting for progressive failure and force interactions.The second stage uses AI algorithms to optimise rockbolting design,balancing stability,cost,and material use.The most efficient algorithms include the multi-objective tree-structured Parzen estimator(MOTPE)and non-dominated sorting genetic algorithms(NSGA-II and NSGA-III).Applied to the Larvik rock slope,the optimised solution uses 18 pre-tensioned cablebolts,providing 13.2 MN of active force and achieving a factor of safety of 1.31 while reducing the average anchorage length by approximately 16%compared to traditional design.The AI-assisted approach also reduces computation time by over 90%compared to Quasi-Monte Carlo(QMC)methods,demonstrating its efficiency for small-scale civil engineering projects and large-scale mining operations.The developed tool is practical,compatible with Building Information Modelling(BIM),and ready for engineering implementation,supporting sustainable and cost-effective rock slope stabilisation.While the method is largely automated,professional judgement remains crucial for verifying ground conditions and selecting the final solution.Future work will focus on integrating data uncertainties,addressing complex block deformation mechanisms,refining optimisation objectives,and improving the performance of multi-objective optimisation for slope rockboling applications to further enhance the method's versatility.
基金supported by the National Natural Science Foundation of China(No.52274346).
文摘Waste graphitization cathode carbon blocks are a type of hazardous solid waste generated during the aluminum electrolysis process,and their proper disposal is a key step in the resource utilization of discarded graphite.This study utilizes the porous“defect advantage”of a cathode carbon block matrix to prepare silicon-doped and asphalt-coated detoxified and purified waste graphitization cathode carbon blocks for use as high-performance silicon/carbon composite anode materials.The results show that the uniformly silicondoped silicon/carbon composite material features a unique amorphous carbon-encapsulated“locked silicon”structure,which effectively addresses issues such as cathode volume expansion,excessive growth of the solid electrolyte interphase(SEI)film,and poor electrical contact between active materials.Consequently,electrochemical performance is enhanced.After assembly in a half-cell,the PSCC/10%Si@C(purified waste graphitization cathode carbon/10%Si@C)material exhibits optimal electrochemical stability,with an initial charging specific capacity of 514.5 mAh/g at 0.1 C(1 C=170 mA/g)and a capacity retention rate of 95.1%after 100 cycles.At a charge rate of 2.0 C,a specific capacity of 216.9 mAh/g is achieved.This technology provides a new pathway for the economical and high-value utilization of waste cathode carbon blocks and the development of low-cost,high-performance anode materials.
基金financially supported by the Russian Science Foundation(No.23-13-00205)。
文摘Star-shaped six-arm polymers with hexaaza[2_(6)]orthoparacyclophane core and arms of block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine were synthesized successfully using cationic ring-opening polymerization.The ratio of blocks,the order of their attachment to the core,and arm length were varied.Conformation of synthesized stars was determined by methods of molecular hydrodynamics and optics.It has been shown that star-shaped molecules were characterized by high intramolecular density,and the arm folding increased with their lengthening.The influence of the structure of block copolymers and their molar mass on the critical micelle concentration has been established.Complexes of synthesized star-shaped block copolymers with curcumin were obtained and the efficient binding of curcumin to polymer molecules was demonstrated.The behavior of the aqueous solutions of the prepared polymer stars and their complexes with curcumin was investigated by light scattering and turbidimetry methods.The influence of the structure and molar mass of star polymers on their thermoresponsiveness and the phase separation temperatures in aqueous solutions was analyzed.A slight increase in the phase separation temperature was found on passage from polymer solutions to solutions of polymer complexes with hydrophobic curcumin.
文摘For the large sparse block two-by-two real nonsingular matrices, we establish a general framework of structured preconditioners through matrix transformation and matrix approximations. For the specific versions such as modified block Jacobi-type, modified block Gauss-Seidel-type, and modified block unsymmetric (symmetric) Gauss-Seidel-type preconditioners, we precisely describe their concrete expressions and deliberately analyze eigenvalue distributions and positive definiteness of the preconditioned matrices. Also, we show that when these structured preconditioners are employed to precondition the Krylov subspace methods such as GMRES and restarted GMRES, fast and effective iteration solvers can be obtained for the large sparse systems of linear equations with block two-by-two coefficient matrices. In particular, these structured preconditioners can lead to high-quality preconditioning matrices for some typical matrices from the real-world applications.
基金support from the National Key Technology R&D Program in the 11th Five-Year Plan Period (Grant No: 2008ZX05054)the Non-main Petroleum Subject Cultivating Fund of China University of Petroleum.
文摘A pore network model was used in this paper to investigate the factors, in particular, throat radius, wettability and initial water saturation, causing water block in low permeability reservoirs. A new term - ＇relative permeability number＇ （RPN） was firstly defined, and then used to describe the degree of water block. Imbibition process simulations show that the RPN drops in accordance with the extension of the averaged pore throat radius from 0.05 to 1.5 μm, and yet once beyond that point of 1.5 μm, the RPN reaches a higher value, indicating the existence of a critical pore throat radius where water block is the maximum. When the wettability of the samples changes from water-wet to weakly water-wet, weakly gas-wet, or gas（oil）-wet, the gas RPN increases consistently, but this consistency is disturbed by the RPN dropping for weakly water-wet samples for water saturations less than 0.4, which means weakly waterwet media are more easily water blocked than water-wet systems. In the situation where the initial water saturation exceeds 0.05, water block escalates along with an increase in initial water saturation.
文摘Blockage is a kind of phenomenon occurring frequently in modern transportation network. This paper deals with the research work on the blocking now in a network with the help of network flow theory. The blockage phenomena can be divided intO local blockage and network blockage. In this paper, which deals mainly with the latter, the fundamental concepts and definitions of network blocking flow, blocking outset are presented and the related theorems are proved. It is proved that the sufficient and necessary condition for the emergence of a blocking now in a network is the existence of the blocking outset. The necessary conditions for the existence of the blocking outset in a network are analysed and the characteristic cutset of blockage which reflects the all possible situation of blocking nows in the network is defined.In the last part of the paper the mathematical model of the minimum blocking now is developed and the solution to a small network is given.
文摘Exercise-induced left bundle branch block(EI-LBBB)is infrequent phenomenon.We present two patients with angina pectoris who developed EI-LBBB during exercise tolerance test.The first patient with typical angina pectoris had significant obstructive coronary artery disease(CAD)requiring percutaneous coronary intervention of multiple lesions including placement of drug eluting stents.The second patient had atypical chest pain without signs of CAD at all.EI-LBBB occurred at a heart rate of 80 bpm and 141 bpm in the first and second patient,respectively.EI-LBBB remained visible through the test till the recovery period in the first patient at a heart rate of 83 bpm and disappeared at 96bpm in the second patient.Both patients with this infrequent phenomenon are discussed and the literature is reviewed.
基金financially supported by the National Natural Science Foundation of China(Nos.51573091,21774076,21320102006 and 91527304)Program of the Shanghai Committee of Science and Technology(Nos.17JC1403200 and 16JC1400703)Program for Shanghai Eastern Scholar
文摘The self-assembly of block copolymer in solution has proven to be an effective strategy for building up a wide range of nanomaterials with diverse structures and applications.This paper reports a facile self-assembly approach towards two-dimensional(2D)sandwich-like mesoporous nitrogen-doped carbon/reduced graphene oxide nanocomposites(denoted as mNC/rGO)with well-defined large mesopores.The strategy involves the synergistic self-assembly ofpolystyrene-block-poly(ethylene oxide)(PS-b-PEO)spherical micelles,m-phenylenediamine(mPD)monomers and GO in solution and the subsequent carbonization at 900~C.The resultant mNC/rGO nanosheets have an average pore size of 19 nm,a high specific surface of 812 m^(2)'g^(-1)and a nitrogen content of 2.2 wt%.As an oxygen reduction reaction(ORR)catalyst,the unique structural features render the metal-free nanosheets excellent electrocatalytic performance.In a 0.1 mol.L-~KOH alkaline medium,mNC/rGO exhibits a four-electron transfer pathway with a high half-wave-potential(El/2)of+0.77 V versus reversible hydrogen electrode(RHE)and a limiting current density(JL)of 5.2 mA'cm^(-2),which are well comparable with those of the commercial Pt/C catalysts.
基金This paper is partially supported by Open Fund for Jiangsu Key Laboratory of Advanced Manufacturing Technology(HGAMTL-1703)Guangxi Key Laboratory of Trusted Software(kx201901)+5 种基金Fundamental Research Funds for the Central Universities(CDLS-2020-03)Key Laboratory of Child Development and Learning Science(Southeast University),Ministry of EducationRoyal Society International Exchanges Cost Share Award,UK(RP202G0230)Medical Research Council Confidence in Concept Award,UK(MC_PC_17171)Hope Foundation for Cancer Research,UK(RM60G0680)British Heart Foundation Accelerator Award,UK.
文摘Aim: To diagnose COVID-19 more efficiently and more correctly, this study proposed a novel attention network forCOVID-19 (ANC). Methods: Two datasets were used in this study. An 18-way data augmentation was proposed toavoid overfitting. Then, convolutional block attention module (CBAM) was integrated to our model, the structureof which is fine-tuned. Finally, Grad-CAM was used to provide an explainable diagnosis. Results: The accuracyof our ANC methods on two datasets are 96.32% ± 1.06%, and 96.00% ± 1.03%, respectively. Conclusions: Thisproposed ANC method is superior to 9 state-of-the-art approaches.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 61173183, 60973152, and 60573172)the Doctoral Program Foundation of Institution of Higher Education of China (Grant No. 20070141014)+2 种基金the Program for Excellent Talents in Universities of Liaoning Province, China (Grant No. LR2012003)the Natural Science Foundation of Liaoning Province, China (Grant No. 20082165)the Fundamental Research Funds for the Central Universities of China (Grant No. DUT12JB06)
文摘In this paper, we propose a novel block cryptographic scheme based on a spatiotemporal chaotic system and a chaotic neural network （CNN）. The employed CNN comprises a 4-neuron layer called a chaotic neuron layer （CNL）, where the spatiotemporal chaotic system participates in generating its weight matrix and other parameters. The spatiotemporal chaotic system used in our scheme is the typical coupled map lattice （CML）, which can be easily implemented in parallel by hard- ware. A 160-bit-long binary sequence is used to generate the initial conditions of the CML. The decryption process is symmetric relative to the encryption process. Theoretical analysis and experimental results prove that the block cryptosys- tem is secure and practical, and suitable for image encryption.
基金financial support from the National Natural Science Foundation of China (51574186)
文摘Nickel nitrate was introduced into carbon blocks by using ECA aggregates as catalyst-carrier.The Ni-containing anthracite aggregates were firstly prepared by mixing anthracite aggregates in nickel nitrate ethanol solution and then incorporated into carbon blocks after pre-treating.The phase composition,microstructure and properties of all carbon blocks fired at 1 000℃or 1 400℃in a coke bed were studied with the aid of an X-ray diffractomer,a field emission scanning electron microscope,a mercury porosimetry and a laser thermal conductivity meter.The results showed that the addition of Ni-containing anthracite aggregates promoted the formation of one-dimensional nanocarbon andβ-SiC whiskers at 1 000℃and the growth ofβ-Sialon at 1 400℃,respectively.Moreover,the cold compressive strength and microporosity characteristics of the carbon blocks with the addition of Ni-containing anthracite aggregates were enhanced and the thermal conductivity was remarkably improved attributing to the high heat conductive network formed by the ceramic phases.
基金jointly supported by projects,including the Study on the Lithospheric Thermal Structure,the Formation Mechanism of Geothermal Systems,and the Assessment of Geothermal Resources of the Guangdong-Hong Kong-Macao Greater Bay Area(Grant No.U20A2096)The Huizhou Multi-factors Urban Geological Survey Project(Grant No.DD20190287)the Update and Sharing of China Geological Maps of Land and Sea areas(Grant No.DD20190370)。
文摘The Heyuan Fault,is one of the main NE-trending faults in the southernmost South China Block and is close to the northernmost South China Sea to the south.The fault features multi-stage deformation and controlled the formation of late Cretaceous to Cenozoic basins.Based on detailed field investigations and comprehensive geochronological research,including zircon U-Pb,Rb-Sr isochron,zircon U-Th-He dating,two episodic tectono-thermal events are recognized.The first occurred during~79 Ma to 66 Ma,which is characterized by large-scale quartz-fluid emplacement.The other occurred at~34 Ma,which features the eruption of a set of basalts.The two events show a changing on material source from siliceous hydrotherm to basalt magma,supporting obvious lithospheric thinning of the southernmost South China Block,which shed light on the geological evolution and the interaction mechanisms between the SCB and the northern South China Sea since the Late Cretaceous.
文摘We report two high risk patients undergoing inguinal herniorraphy and testicular biopsy under ultrasound-guided ilioinguinal/iliohypogastric and genitofemoral nerve blocks. The addition of the genitofemoral nerve block may enhance the ilioinguinal/iliohypogastric block to achieve complete anesthesia and thus avoid general and neuraxial anesthesia related hypotension that may be detrimental in patients with low cardiac reserve.
文摘Based on the heat flow data published in 1990 and 2001, a study of the factors influencing the terrestrial heat flow distribution in the China continent and its quantitative expression is carried out using the ＂Netlike Plastic-Flow＂ continental dynamics model and the methods of statistic analysis and optimum fitting. The result indicates that the factors influencing the heat flow distribution is classified into two groups, i.e. background and tectonic ones, in which the former mainly involves the non- uniform distribution of mantle heat flow, heat production of radioactive dements in the crust, heattransfer media and hydrothermal circulation, while the latter mainly involves plastic-flow networks and relatively-stable blocks. The plastic-flow network is a manifestation of shear localization in the netlike plastic-flow process in the lower lithosphere, which is composed of two sets of plastic-flow belts （PFBs） intersecting each other and, as one of the basic action regimes, controls the intraplate tectonic deformation. Relatively stable blocks （RSBs）, which are the tectonic units with relatively-high viscosities existing in the netlike plastic-flow field, as one of the principal origins, result in the development of large-seale compressional basins. PFB and RSB, as the active and quiet states of tectonic deformation, give rise to the higher and lower heat flow values, respectivdy. The provincial average heat flow in continent can be estimated using the expression qav = q0 ＋ a Pbt-c Pbk, where the three terms of the right side are background heat flow, PFB-positive contribution and RSB-negative contribution, Pbt and Pbk are the PFB- and RSB-coverage ratios, respectively, a is the coefficient of PFB- positive contribution depending mainly on the strain in the lower lithosphere, and c is the coefficient of RSB-negative contribution related mainly to the thickness of the lithosphere, the aseismic-area ratio and the tectonic age. For the major portion of the China continent excluding some of the southeastern region of China, the confidence interval of the provincial average background heat flow is qo=57.25±24.8 mW/m^2 and the PFB-positive- and RSB-negative-contribution coefficients are a=14.8-71.9 mW/m^2 and c=0-25.6 mW/m^2, respectively. The concepts of PFB and RSB effects and the heat flow expression suggested provide a new choice of the approach to the quantitative description of the characteristics of heat flow distribution in continent and their physical mechanisms.
