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A 4TH ORDER FULLY INTEGRATED ACTIVE RC COMPLEX FILTER WITH NOVEL AUTOMATIC TUNING SYSTEMS 被引量:1
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作者 Chen Dianyu Qi Feitao Sun Weiming Qin Shicai Xiong Shaozhen 《Journal of Electronics(China)》 2007年第6期854-858,共5页
This letter introduces a 4th order active RC complex filter with 1.SMHz center frequency and 1MHz bandwidth. The total harmonic distortion of the filter is less than -60dB and the image rejection ratio is greater than... This letter introduces a 4th order active RC complex filter with 1.SMHz center frequency and 1MHz bandwidth. The total harmonic distortion of the filter is less than -60dB and the image rejection ratio is greater than 60dB. A novel technique is also proposed in this letter to automatically adjust the variation of the time constant. The advantages of the proposed method are its high precision and simplicity. Using 5bits control words, the tuning error is less than ±1.6%. 展开更多
关键词 Active RC filter Complex filter Automatic tuning system
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Achieving 40% room-temperature ODMR contrast in molecular systems through chemical tuning
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作者 Fushan Geng Bingwen Hu 《Magnetic Resonance Letters》 2025年第3期97-99,共3页
Optically detected magnetic resonance(ODMR)has emerged as a powerful technique for quantum sensing,enabling high-sensitivity detection of physical quantities even at room temperature.Solid-state defects,such as nitrog... Optically detected magnetic resonance(ODMR)has emerged as a powerful technique for quantum sensing,enabling high-sensitivity detection of physical quantities even at room temperature.Solid-state defects,such as nitrogen-vacancy(NV)centers in diamond,have demonstrated remarkable capabilities in this domain[1–4].However,these systems are limited by their rigid lattice structures and lack tunability. 展开更多
关键词 room temperature ODMR chemical tuning quantum sensingenabling detection physical quantities optically detected magnetic resonance odmr nitrogen vacancy centers quantum sensing molecular systems
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Quantum Interference and Optical Tuning of Self-Trapped Exciton State in Double Halide Perovskite
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作者 Kai-Xuan Xu Xin-Bao Liu +9 位作者 Simin Pang Zhe Zhang Yubin Wang Haonan Chang Jiajun Luo Jiang Tang Qihua Xiong Sheng Meng Shiwu Gao Jun Zhang 《Chinese Physics Letters》 2026年第3期87-101,共15页
Self-trapped excitons(STEs),known for their unique radiative properties,have been harnessed in diverse photonic devices;however,their comprehensive understanding and manipulation remain elusive.In this study,we presen... Self-trapped excitons(STEs),known for their unique radiative properties,have been harnessed in diverse photonic devices;however,their comprehensive understanding and manipulation remain elusive.In this study,we present novel experimental and theoretical evidence revealing the hybrid nature and optical tunability of STE state in Cs_(2)Ag_(0.4)Na_(0.6)InCl_(6).The detection of the Fano resonance in laser energy-dependent Raman and photoluminescence spectra indicates the emergence of an exciton-phonon hybrid state,arising from robust quantum interference between the discrete phonon and continuum exciton states.Moreover,we demonstrate continuous tuning of this hybrid state with the energy and intensity of the laser field.These findings lay the foundation for a comprehensive understanding of the nature of STE and their potential for state control. 展开更多
关键词 photonic deviceshowevertheir self trapped exciton state optical tuning exciton phonon hybrid state fano resonance photoluminescence spectra quantum interference double halide perovskite
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CIT-Rec:Enhancing Sequential Recommendation System with Large Language Models
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作者 Ziyu Li Zhen Chen +2 位作者 Xuejing Fu Tong Mo Weiping Li 《Computers, Materials & Continua》 2026年第3期2328-2343,共16页
Recommendation systems are key to boosting user engagement,satisfaction,and retention,particularly on media platforms where personalized content is vital.Sequential recommendation systems learn from user-item interact... Recommendation systems are key to boosting user engagement,satisfaction,and retention,particularly on media platforms where personalized content is vital.Sequential recommendation systems learn from user-item interactions to predict future items of interest.However,many current methods rely on unique user and item IDs,limiting their ability to represent users and items effectively,especially in zero-shot learning scenarios where training data is scarce.With the rapid development of Large Language Models(LLMs),researchers are exploring their potential to enhance recommendation systems.However,there is a semantic gap between the linguistic semantics of LLMs and the collaborative semantics of recommendation systems,where items are typically indexed by IDs.Moreover,most research focuses on item representations,neglecting personalized user modeling.To address these issues,we propose a sequential recommendation framework using LLMs,called CIT-Rec,a model that integrates Collaborative semantics for user representation and Image and Text information for item representation to enhance Recommendations.Specifically,by aligning intuitive image information with text containing semantic features,we can more accurately represent items,improving item representation quality.We focus not only on item representations but also on user representations.To more precisely capture users’personalized preferences,we use traditional sequential recommendation models to train on users’historical interaction data,effectively capturing behavioral patterns.Finally,by combining LLMs and traditional sequential recommendation models,we allow the LLM to understand linguistic semantics while capturing collaborative semantics.Extensive evaluations on real-world datasets show that our model outperforms baseline methods,effectively combining user interaction history with item visual and textual modalities to provide personalized recommendations. 展开更多
关键词 Large language models vision language models sequential recommendation instruction tuning
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Active Disturbance Rejection Control for Unmanned Helicopter with Adaptive Tuning
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作者 Zhaoji Wang Yanfeng Liu Shouzhao Sheng 《Journal of Beijing Institute of Technology》 2026年第1期21-30,共10页
In this paper,a practical method named linear active disturbance rejection control(LADRC)with adaptive tuning is proposed for attitude control of small-scale unmanned helicopter.The proposed method accounts for both e... In this paper,a practical method named linear active disturbance rejection control(LADRC)with adaptive tuning is proposed for attitude control of small-scale unmanned helicopter.The proposed method accounts for both external disturbances and internal dynamic uncertainties,as well as parameter deviations arising from parameter uncertainty,while maintaining a relatively small number of adjustable parameters.Furthermore,it addresses the limitation that conventional active disturbance rejection control methods cannot be rigorously analyzed for stability.The total disturbance of unmanned helicopter is estimated and compensated by designed LADRC.The introduction of adaptive control realizes online parameter tuning,which eliminates parameter deviation and further improves control precision.Moreover,it also provides a novel idea to prove the stability of controller,so that it can be analyzed by Lyapunov function.Finally,the anti-disturbance performance and effectiveness of proposed method are verified by numerical simulation. 展开更多
关键词 unmanned helicopter adaptive control linear active disturbance rejection control(LADRC) parameters online tuning
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Fast step heterodyne light-induced thermoelastic spectroscopy gas sensing based on a quartz tuning fork with high-frequency of 100 kHz
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作者 Yuanzhi Wang Ying He +4 位作者 Shunda Qiao Xiaonan Liu Chu Zhang Xiaoming Duan Yufei Ma 《Opto-Electronic Advances》 2026年第1期36-48,共13页
In this paper,a fast step heterodyne light-induced thermoelastic spectroscopy(SH-LITES)sensor using a high-frequency quartz tuning fork(QTF)with resonant frequency of~100 kHz is reported for the first time.The theoret... In this paper,a fast step heterodyne light-induced thermoelastic spectroscopy(SH-LITES)sensor using a high-frequency quartz tuning fork(QTF)with resonant frequency of~100 kHz is reported for the first time.The theoretical principle of heterodyne LITES(H-LITES)signal generation is analyzed firstly,and an acetylene(C_(2)H_(2))H-LITES sensor is established to verify its performance.Experimental comparisons between the high-frequency QTF and a standard commercial QTF with resonant frequency of~32.768 kHz reveal that the high-frequency QTF exhibits a tenfold faster response time.Specifically,the H-LITES sensor with this QTF achieves a 33 ms measurement cycle,90%shorter than commercial counterparts.Furthermore,The SH-LITES technique is proposed to further shorten the scanning time to 15 ms,which achieves the shortest LITES measurement time known to date.To demonstrate its advantages in dynamic gas detection,an H_(2)O-LITES system integrating both QTF types is constructed for real-time monitoring of H_(2)O concentration during different respiration patterns.Comparative measurements show that the SH-LITES more accurately captures dynamic H_(2)O concentration fluctuations during respiration,outperforming the commercial QTF-based H-LITES sensor in rapid response scenarios. 展开更多
关键词 fast heterodyne light-induced thermoelastic spectroscopy(H-LITES) high-frequency quartz tuning fork(QTF) step heterodyne light-induced thermoelastic spectroscopy(SH-LITES) respiration detection
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Design of rapid tuning system for a ferrite-loaded cavity 被引量:2
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作者 Xiao Li Hong Sun +6 位作者 Chun-Lin Zhang Wei Long Yang Liu Jun-Yu Zhu Sheng-Yi Chen Bin Wu Xiang Li 《Radiation Detection Technology and Methods》 CSCD 2021年第3期324-331,共8页
Introduction A high power,broadband and rapid frequency sweeping RF system was developed to satisfy the demand of China Spallation Neutron Source(CSNS)/Rapid Cycling Synchrotron(RCS).Material and methods The cavity tu... Introduction A high power,broadband and rapid frequency sweeping RF system was developed to satisfy the demand of China Spallation Neutron Source(CSNS)/Rapid Cycling Synchrotron(RCS).Material and methods The cavity tuning is the key issue which has a great impact on the performance of the whole RF system.To satisfy the requirements of cavity dynamic tuning caused by the nonlinear characteristics of ferrite,some new technologies were developed and applied.Conclusion In this paper,the overall design of the tuning system is introduced.The ensuing discussion focuses on the com-parison between different types of bias supplies,the control algorithm of low-level RF(LLRF)system.The commissioning results with beam power of 100 kW are also shown and discussed. 展开更多
关键词 tuning system Ferrite-loaded cavity Bias supply LLRF
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A tuning system for BEPC II
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《Chinese Physics C》 SCIE CAS CSCD 2013年第8期64-68,共5页
The tuning system plays a very important role when a superconducting cavity is in operation. It cooperates with other control loops to adjust the cavity frequency with high precision, reduce the reflection power, guar... The tuning system plays a very important role when a superconducting cavity is in operation. It cooperates with other control loops to adjust the cavity frequency with high precision, reduce the reflection power, guarantee the stability of beam, and ensure the safety of the superconducting cavity. This paper focuses mainly on the tuning system working principle, the working state and problems that Beijing Electron Positron Collider (BEPC |I ) has encountered during operation. 展开更多
关键词 tuning system 500 MHz cavity tuner frequency tuner
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Effect of Length Scale Tuning of Background Error in WRF-3DVAR System on Assimilation of High-Resolution Surface Data for Heavy Rainfall Simulation 被引量:5
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作者 Ji-Hyun HA Dong-Kyou LEE 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2012年第6期1142-1158,共17页
We investigated the impact of tuning the length scale of the background error covariance in the Weather Research and Forecasting (WRF) three-dimensional variational assimilation (3DVAR) system. In particular, we s... We investigated the impact of tuning the length scale of the background error covariance in the Weather Research and Forecasting (WRF) three-dimensional variational assimilation (3DVAR) system. In particular, we studied the effect of this parameter on the assimilation of high-resolution surface data for heavy rainfall forecasts associated with mesoscale convective systems over the Korean Peninsula. In the assimilation of high-resolution surface data, the National Meteorological Center method tended to exaggerate the length scale that determined the shape and extent to which observed information spreads out. In this study, we used the difference between observation and background data to tune the length scale in the assimilation of high-resolution surface data. The resulting assimilation clearly showed that the analysis with the tuned length scale was able to reproduce the small-scale features of the ideal field effectively. We also investigated the effect of a double-iteration method with two different length scales, representing large and small-length scales in the WRF-3DVAR. This method reflected the large and small-scale features of observed information in the model fields. The quantitative accuracy of the precipitation forecast using this double iteration with two different length scales for heavy rainfall was high; results were in good agreement with observations in terms of the maximum rainfall amount and equitable threat scores. The improved forecast in the experiment resulted from the development of well-identified mesoscale convective systems by intensified low-level winds and their consequent convergence near the rainfall area. 展开更多
关键词 WRF 3DVAR tuning surface data heavy rainfall
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A Real Time Self-Tuning Motion Controller for Mobile Robot Systems 被引量:6
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作者 Mohamed Boukens Abdelkrim Boukabou Mohammed Chadli 《IEEE/CAA Journal of Automatica Sinica》 EI CSCD 2019年第1期84-96,共13页
This paper proposes an intelligent controller for motion control of robotic systems to obtain high precision tracking without the need for a real-time trial and error method.In addition, a new self-tuning algorithm ha... This paper proposes an intelligent controller for motion control of robotic systems to obtain high precision tracking without the need for a real-time trial and error method.In addition, a new self-tuning algorithm has been developed based on both the ant colony algorithm and a fuzzy system for real-time tuning of controller parameters. Simulations and experiments using a real robot have been addressed to demonstrate the success of the proposed controller and validate the theoretical analysis. Obtained results confirm that the proposed controller ensures robust performance in the presence of disturbances and parametric uncertainties without the need for adjustment of control law parameters by a trial and error method. 展开更多
关键词 Learning and adaptive systemS motion CONTROL METAHEURISTIC robust CONTROL real-time tuning SELF-tuning WHEELED mobile robot
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Tuning PID Parameters Based on a Combination of the Expert System and the Improved Genetic Algorithms 被引量:3
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作者 Zuo Xin Zhang Junfeng Luo Xionglin 《Petroleum Science》 SCIE CAS CSCD 2005年第4期71-76,共6页
a new strategy combining an expert system and improved genetic algorithms is presented for tuning proportional-integral-derivative (PID) parameters for petrochemical processes. This retains the advantages of genetic... a new strategy combining an expert system and improved genetic algorithms is presented for tuning proportional-integral-derivative (PID) parameters for petrochemical processes. This retains the advantages of genetic algorithms, namely rapid convergence and attainment of the global optimum. Utilization of an orthogonal experiment method solves the determination of the genetic factors. Combination with an expert system can make best use of the actual experience of the plant operators. Simulation results of typical process systems examples show a good control performance and robustness. 展开更多
关键词 PID parameters tuning orthogonal experiment method genetic algorithm expert system
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Development of seam tracking system with ultrasonic sensor using self-tuning fuzzy control 被引量:1
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作者 胡绳荪 孟英谦 刘勇 《China Welding》 EI CAS 2001年第1期39-42,共4页
One kind of the SAW seam tracking system with contactless ultrasonic sensor is presented in this paper. The new contactless ultrasonic sensor for seam tracking and the working principle of the seam tracking with the s... One kind of the SAW seam tracking system with contactless ultrasonic sensor is presented in this paper. The new contactless ultrasonic sensor for seam tracking and the working principle of the seam tracking with the sensor are introduced. Based on the experiments, the optimal values of the fuzzy control parameters α and k 3 are defined by means of the off line adjusting method. Because the self tuning fuzzy control is adopted in the seam tracking system, the overshoot of the system is restrained, the steady state error is reduced, and the system's response speed is improved effectively. The results of the SAW seam tracking experiments show that this system's tracking accuracy is up to ±0.5 mm and the system can satisfy the requirements of the engineering application. 展开更多
关键词 seam tracking ultrasonic sensor self tuning fuzzy control
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Control parameter optimal tuning method based on annealing-genetic algorithm for complex electromechanical system 被引量:1
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作者 贺建军 喻寿益 钟掘 《Journal of Central South University of Technology》 2003年第4期359-363,共5页
A new searching algorithm named the annealing-genetic algorithm(AGA) was proposed by skillfully merging GA with SAA. It draws on merits of both GA and SAA ,and offsets their shortcomings.The difference from GA is that... A new searching algorithm named the annealing-genetic algorithm(AGA) was proposed by skillfully merging GA with SAA. It draws on merits of both GA and SAA ,and offsets their shortcomings.The difference from GA is that AGA takes objective function as adaptability function directly,so it cuts down some unnecessary time expense because of float-point calculation of function conversion.The difference from SAA is that AGA need not execute a very long Markov chain iteration at each point of temperature, so it speeds up the convergence of solution and makes no assumption on the search space,so it is simple and easy to be implemented.It can be applied to a wide class of problems.The optimizing principle and the implementing steps of AGA were expounded. The example of the parameter optimization of a typical complex electromechanical system named temper mill shows that AGA is effective and superior to the conventional GA and SAA.The control system of temper mill optimized by AGA has the optimal performance in the adjustable ranges of its parameters. 展开更多
关键词 GENETIC ALGORITHM SIMULATED ANNEALING ALGORITHM annealing-genetic ALGORITHM complex electro-mechanical system PARAMETER tuning OPTIMAL control
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Pole-placement self-tuning control of nonlinear Hammerstein system and its application to pH process control 被引量:2
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作者 邹志云 赵丹丹 +4 位作者 刘兴红 郭宇晴 管臣 冯文强 郭宁 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第8期1364-1368,共5页
By taking advantage of the separation characteristics of nonlinear gain and dynamic sector inside a Hammerstein model, a novel pole placement self tuning control scheme for nonlinear Hammerstein system was put forward... By taking advantage of the separation characteristics of nonlinear gain and dynamic sector inside a Hammerstein model, a novel pole placement self tuning control scheme for nonlinear Hammerstein system was put forward based on the linear system pole placement self tuning control algorithm. And the nonlinear Hammerstein system pole placement self tuning control(NL-PP-STC) algorithm was presented in detail. The identi fication ability of its parameter estimation algorithm of NL-PP-STC was analyzed, which was always identi fiable in closed loop. Two particular problems including the selection of poles and the on-line estimation of model parameters, which may be met in applications of NL-PP-STC to real process control, were discussed. The control simulation of a strong nonlinear p H neutralization process was carried out and good control performance was achieved. 展开更多
关键词 Nonlinear system Hammerstein model Pole placement Self tuning control pH control
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Closed-loop identification of systems using hybrid Box–Jenkins structure and its application to PID tuning 被引量:1
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作者 李全善 李大字 曹柳林 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第12期1997-2004,共8页
The paper describes a closed-loop system identification procedure for hybrid continuous-time Box–Jenkins models and demonstrates how it can be used for IMC based PID controller tuning. An instrumental variable algori... The paper describes a closed-loop system identification procedure for hybrid continuous-time Box–Jenkins models and demonstrates how it can be used for IMC based PID controller tuning. An instrumental variable algorithm is used to identify hybrid continuous-time transfer function models of the Box–Jenkins form from discretetime prefiltered data, where the process model is a continuous-time transfer function, while the noise is represented as a discrete-time ARMA process. A novel penalized maximum-likelihood approach is used for estimating the discrete-time ARMA process and a circulatory noise elimination identification method is employed to estimate process model. The input–output data of a process are affected by additive circulatory noise in a closedloop. The noise-free input–output data of the process are obtained using the proposed method by removing these circulatory noise components. The process model can be achieved by using instrumental variable estimation method with prefiltered noise-free input–output data. The performance of the proposed hybrid parameter estimation scheme is evaluated by the Monte Carlo simulation analysis. Simulation results illustrate the efficacy of the proposed procedure. The methodology has been successfully applied in tuning of IMC based flow controller and a practical application demonstrates the applicability of the algorithm. 展开更多
关键词 Hybrid Box–Jenkins models ARMA models Instrumental variable Closed-loop identification PID tuning
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Lorentz detuning and tuning system study of 3+1/2cell DC-SC photo-injector for PKU-FEL
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作者 徐文灿 全胜文 +1 位作者 赵夔 朱凤 《Chinese Physics C》 SCIE CAS CSCD 北大核心 2008年第3期215-217,共3页
A 3+1/2cell DC-SC photo-injector for PKU-FEL facility is under development, which is an upgrade design of the successful 1-4-1/2cell DC-SC photo-injector. The Lorentz detuning and tuning structure for the 3+1/2cell ... A 3+1/2cell DC-SC photo-injector for PKU-FEL facility is under development, which is an upgrade design of the successful 1-4-1/2cell DC-SC photo-injector. The Lorentz detuning and tuning structure for the 3+1/2cell superconducting cavity is presented in this paper. The Lorentz force detuning coefficient is 1.2 Hz/(MV/m)^2 with double stiffening rings for the half cell and single stiffening rings between the adjacent TESLA cells. With the special stiffening structure, the 3+1/2cell whole cavity needs only one tuner. The influences of the tuning on frequency shift, field flatness and average gradient are discussed in this paper. The simulation results show that the stiffening rings' design is successful. 展开更多
关键词 3+1/2cell DC-SC photo-injector Lorentz detuning tuning structure
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A Novel Tuning Method for Predictive Control of VAV Air Conditioning System Based on Machine Learning and Improved PSO
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作者 Ning He Kun Xi +1 位作者 Mengrui Zhang Shang Li 《Journal of Beijing Institute of Technology》 EI CAS 2022年第4期350-361,共12页
The variable air volume(VAV)air conditioning system is with strong coupling and large time delay,for which model predictive control(MPC)is normally used to pursue performance improvement.Aiming at the difficulty of th... The variable air volume(VAV)air conditioning system is with strong coupling and large time delay,for which model predictive control(MPC)is normally used to pursue performance improvement.Aiming at the difficulty of the parameter selection of VAV MPC controller which is difficult to make the system have a desired response,a novel tuning method based on machine learning and improved particle swarm optimization(PSO)is proposed.In this method,the relationship between MPC controller parameters and time domain performance indices is established via machine learning.Then the PSO is used to optimize MPC controller parameters to get better performance in terms of time domain indices.In addition,the PSO algorithm is further modified under the principle of population attenuation and event triggering to tune parameters of MPC and reduce the computation time of tuning method.Finally,the effectiveness of the proposed method is validated via a hardware-in-the-loop VAV system. 展开更多
关键词 model predictive control(MPC) parameter tuning machine learning improved particle swarm optimization(PSO)
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Automated Performance Tuning of Data Management Systems with Materializations and Indices
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作者 Nan N. Noon Janusz R. Getta 《Journal of Computer and Communications》 2016年第5期46-52,共7页
Automated performance tuning of data management systems offer various benefits such as improved performance, declined administration costs, and reduced workloads to database administrators (DBAs). Currently, DBAs tune... Automated performance tuning of data management systems offer various benefits such as improved performance, declined administration costs, and reduced workloads to database administrators (DBAs). Currently, DBAs tune the performance of database systems with a little help from the database servers. In this paper, we propose a new technique for automated performance tuning of data management systems. Firstly, we show how to use the periods of low workload time for performance improvements in the periods of high workload time. We demonstrate that extensions of a database system with materialised views and indices when a workload is low may contribute to better performance for a successive period of high workload. The paper proposes several online algorithms for continuous processing of estimated database workloads and for the discovery of the best plan for materialised view and index database extensions and of elimination of the extensions that are no longer needed. We present the results of experiments that show how the proposed automated performance tuning technique improves the overall performance of a data management system.   展开更多
关键词 Automated Performance tuning Query Processing MATERIALIZATION INDEXING Data Management systems
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Highly sensitive laser spectroscopy sensing based on a novel four-prong quartz tuning fork 被引量:1
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作者 Runqiu Wang Shunda Qiao +1 位作者 Ying He Yufei Ma 《Opto-Electronic Advances》 2025年第4期6-16,共11页
In this paper,a novel four-prong quartz tuning fork(QTF)was designed with enlarged deformation area,large prong gap,and low resonant frequency to improve its performance in laser spectroscopy sensing.A theoretical sim... In this paper,a novel four-prong quartz tuning fork(QTF)was designed with enlarged deformation area,large prong gap,and low resonant frequency to improve its performance in laser spectroscopy sensing.A theoretical simulation model was established to optimize the design of the QTF structure.In the simulation of quartz-enhanced photoacoustic spectroscopy(QEPAS)technology,the maximum stress and the surface charge density of the four-prong QTF demonstrated increases of 11.1-fold and 15.9-fold,respectively,compared to that of the standard two-prong QTF.In the simulation of light-induced thermoelastic spectroscopy(LITES)technology,the surface temperature difference of the four-prong QTF was found to be 11.4 times greater than that of the standard QTF.Experimental results indicated that the C_(2)H_(2)-QEPAS system based on this innovative design improved the signal-to-noise-ratio(SNR)by 4.67 times compared with the standard QTF-based system,and the SNR could increase up to 147.72 times when the four-prong QTF was equipped with its optimal acoustic micro-resonator(AmR).When the average time of the system reached 370 s,the system achieved a MDL as low as 21 ppb.The four-prong QTF-based C_(2)H_(2)-LITES system exhibited a SNR improvement by a factor of 4.52,and a MDL of 96 ppb was obtained when the average time of the system reached 100 s.The theoretical and experimental results effectively demonstrated the superiority of the four-prong QTF in the field of laser spectroscopy sensing. 展开更多
关键词 four-prong quartz tuning fork C2H2 detection quartz-enhanced photoacoustic spectroscopy light-induced thermoelastic spectroscopy
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Dual-surface capped hydroxyapatite nano-amendment with tuned alternate long-short chain configuration for efficient adsorption towards multi-heavy metal ions in complex-contaminated systems
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作者 GAO Mochou MENG Shan +7 位作者 ZHANG Jinzhong FENG Wenhua DONG Shuo CHEN Jianping ZHAO Yanbao YU Laigui YING Rongrong ZOU Xueyan 《无机化学学报》 北大核心 2025年第7期1427-1438,共12页
Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)an... Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides. 展开更多
关键词 heavy metal HYDROXYAPATITE nano-amendment configuration tuning synergistic adsorption
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