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Vibrations induced by time-delayed double blastholes in underground rocks:Experimental study and theoretical analysis
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作者 Yonggang Gou Gui Yang +2 位作者 Xianyang Qiu Kun Ji Yumin Chen 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第2期1108-1125,共18页
Time-delayed blasting is widely utilized in engineering to mitigate induced vibration hazards and enhance fragmentation.The underlying vibration reduction principle is the decrease of the charge weight per delay,while... Time-delayed blasting is widely utilized in engineering to mitigate induced vibration hazards and enhance fragmentation.The underlying vibration reduction principle is the decrease of the charge weight per delay,while the potential for further vibration reduction remains debated,largely due to unclear underlying mechanisms.In light of the popularization of electronic detonators and the representativeness of double-hole configurationsfor multiple blastholes,it is essential to investigate the vibration characteristics induced by time-delayed double blastholes.Therefore,a series of doubleborehole experimental blasts was conducted in an underground roadway to clarify the variation in vibration from single-hole to dual-hole conditions.Based on the experimental data and inherent limitations,an exact full-fieldtheoretical model was further employed to systematically analyze the effects of delay time,charge length,and borehole inclination angle on vibrations induced by various doublehole configurations.The experimental data and theoretical analysis reveal that the general scaled distance effectively predicts vibrations in delayed blasting but does not reflectvibration reduction.Increasing delay time causes fluctuatingPPVs,which stabilize slightly above single-hole PPVs as delay times exceed a certain value.The delayed blasting primarily reduces near-fieldfrequencies.Longer charge lengths in double boreholes increase PPV levels and attenuation rates within a certain length,and the vibration behavior of combined long and short charge lengths is governed by the long blasthole.Larger blasthole inclination angles enhance vibration amplitude and reduce PPV attenuation rates.Optimizing inclination angles is more critical than adjusting delay times,and parallel boreholes offer the best vibration control. 展开更多
关键词 Vibration of double blastholes Experimental data Theoretical model delay time Wave superposition
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Modified Fixed-Time Synchronization Criteria of Complex Networks with Time-Varying Delays via Continuous or Discontinuous Control
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作者 WU Huan WU Ailong ZHANG Jin'e 《Wuhan University Journal of Natural Sciences》 2025年第2期150-158,共9页
This paper investigates modified fixed-time synchronization(FxTS)of complex networks(CNs)with time-varying delays based on continuous and discontinuous controllers.First,for the sake of making the settling time(ST)of ... This paper investigates modified fixed-time synchronization(FxTS)of complex networks(CNs)with time-varying delays based on continuous and discontinuous controllers.First,for the sake of making the settling time(ST)of FxTS is independent of the initial values and parameters of the CNs,a modified fixed-time(FxT)stability theorem is proposed,where the ST is determined by an arbitrary positive number given in advance.Then,continuous controller and discontinuous controller are designed to realize the modified FxTS target of CNs.In addition,based on the designed controllers,CNs can achieve synchronization at any given time,or even earlier.And control strategies effectively solve the problem of ST related to the parameters of CNs.Finally,an appropriate simulation example is conducted to examine the effectiveness of the designed control strategies. 展开更多
关键词 complex networks settling time fixed-time synchronization controllers time-varying delays
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Impact of the chaotic semiconductor laser output power on time-delay-signature of chaos and random bit generation
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作者 Chenpeng Xue Xu Wang +3 位作者 Likai Zheng Haoyu Zhang Yanhua Hong Zuxing Zhang 《Chinese Physics B》 2025年第3期325-330,共6页
We experimentally analyze the effect of the optical power on the time delay signature identification and the random bit generation in chaotic semiconductor laser with optical feedback.Due to the inevitable noise durin... We experimentally analyze the effect of the optical power on the time delay signature identification and the random bit generation in chaotic semiconductor laser with optical feedback.Due to the inevitable noise during the photoelectric detection and analog-digital conversion,the varying of output optical power would change the signal to noise ratio,then impact time delay signature identification and the random bit generation.Our results show that,when the optical power is less than-14 dBm,with the decreasing of the optical power,the actual identified time delay signature degrades and the entropy of the chaotic signal increases.Moreover,the extracted random bit sequence with lower optical power is more easily pass through the randomness testing. 展开更多
关键词 CHAOS time delay signature entropy estimation random bit generation
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Global adaptive output feedback control of nonlinear time-delay systems with measurement uncertainty
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作者 Weiguo Cai Xianglei Jia Xinxu Ju 《Control Theory and Technology》 2025年第1期145-152,共8页
In this paper,a pair of dynamic high-gain observer and output feedback controller is proposed for nonlinear systems with multiple unknown time delays.By constructing Lyapunov-Krasovskii functionals,it shows that globa... In this paper,a pair of dynamic high-gain observer and output feedback controller is proposed for nonlinear systems with multiple unknown time delays.By constructing Lyapunov-Krasovskii functionals,it shows that global state asymptotic regulation can be ensured by introducing a single dynamic gain;furthermore,global asymptotic stabilization can be achieved by choosing a sufficiently large static scaling gain when the upper bounds of all system parameters are known.Especially,the output coefficient is allowed to be non-differentiable with unknown upper bound.This paper proposes a generalized Lyapunov matrix inequality based dynamic-gain scaling method,which significantly simplifies the design computational complexity by comparing with the classic backstepping method. 展开更多
关键词 Output feedback Measurement uncertainty Nonlinear adaptive control Time delays
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Predictor-based sampled-data output-feedback control for feedforward nonlinear time-delay systems
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作者 Wenjie Zhang Weihao Pan +1 位作者 Xianfu Zhang Qingrong Liu 《Control Theory and Technology》 2025年第1期105-117,共13页
This paper studies global stabilization via predictor-based sampled-data output feedback for a class of feedforward nonlinear time-delay systems.Note that the traditional sampled-data observer via zero-order holder ma... This paper studies global stabilization via predictor-based sampled-data output feedback for a class of feedforward nonlinear time-delay systems.Note that the traditional sampled-data observer via zero-order holder may result in the performance degradation of the observer.In this paper,an improved predictor-based observer is designed to compensate for the influence of the unmeasurable states,sampling errors and output delay.In addition,a sampled-data output-feedback controller is also constructed using the gain scaling technique.By the Lyapunov-Krasovskii functional method,the global exponential stability of the resulting closed-loop system can be guaranteed under some sufficient conditions.The simulation results are provided to demonstrate the main results. 展开更多
关键词 Feedforward nonlinear systems Time delay Predictor-based observer Sampled-data output-feedback controller
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Stability and Hopf Bifurcation of a Reaction-Diffusion-Advection Model with Nonlocal Delay
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作者 ZHAN Jidan YU Ke PENG Yahong 《应用数学》 北大核心 2026年第2期373-387,共15页
In ecological environments,the survival environment of species is often inhomogeneous,and the reproductive process is affected by time delay.System with nonlocal effects and delay can more accurately simulate changes ... In ecological environments,the survival environment of species is often inhomogeneous,and the reproductive process is affected by time delay.System with nonlocal effects and delay can more accurately simulate changes in population density.In this paper,we consider a reaction-diffusion-advection model with nonlocal delay and Dirichlet boundary conditions.First of all,we investigate the well-posedness of solution of model.Then,the existence of positive steady state is proofed by implicit function theorem.Based on a priori estimate for the eigenvalue,we prove the stability of the positive steady state and conclude the associated distribution of Hopf bifurcation.Our research indicates that the combined effects of nonlocal and time delays have a certain impact on the dynamics of the model. 展开更多
关键词 NONLOCALITY Time delay Reaction-diffusion-advection Hopf bifurcation STABILITY
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Hilbert−Huang Time-Delay Compensation Control Strategy Based on Gauss-DeepAR for Ship Heave Motion Prediction
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作者 ZHANG Qin HE Dai-jing +1 位作者 GU Bang-ping HU Xiong 《China Ocean Engineering》 2025年第2期209-224,共16页
The prediction and compensation control of marine ship motion is crucial for ensuring the safety of offshore wind turbine loading and unloading operations.However,the accuracy of prediction and control is significantl... The prediction and compensation control of marine ship motion is crucial for ensuring the safety of offshore wind turbine loading and unloading operations.However,the accuracy of prediction and control is significantly affected by the hysteresis phenomenon in the wave compensation system.To address this issue,a ship heave motion prediction is proposed in this paper on the basis of the Gauss-DeepAR(AR stands for autoregressive recurrent)model and the Hilbert−Huang time-delay compensation control strategy.Initially,the zero upward traveling wave period of the level 4−6 sea state ship heave motion is analyzed,which serves as the input sliding window for the Gauss-DeepAR prediction model,and probability predictions at different wave direction angles are conducted.Next,considering the hysteresis characteristics of the ship heave motion compensation platform,the Hilbert−Huang transform is employed to analyze and calculate the hysteresis delay of the compensation platform.After the optimal control action value is subsequently calculated,simulations and hardware platform tests are conducted.The simulation results demonstrated that the Gauss-DeepAR model outperforms autoregressive integrated moving average model(ARIMA),support vector machine(SVM),and longshort-term memory(LSTM)in predicting non-independent identically distributed datasets at a 90°wave direction angle in the level 4−6 sea states.Furthermore,the model has good predictive performance and generalizability for non-independent and non-uniformly distributed datasets at a 180°wave direction angle.The hardware platform compensation test results revealed that the Hilbert–Huang method has an outstanding effect on determining the hysteretic delay and selecting the optimal control action value,and the compensation efficiency was higher than 90%in the level 4−6 sea states. 展开更多
关键词 heave motion Gauss-DeepAR prediction model Hilbert−Huang transform delay compensation control
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Double-side delay alignment modulation for multi-user millimeter wave and terahertz communications
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作者 Xingwei Wang Haiquan Lu +1 位作者 Jieni Zhang Yong Zeng 《Digital Communications and Networks》 2026年第1期11-24,共14页
Delay Alignment Modulation(DAM)is an innovative broadband modulation technique well-suited for millimeter Wave(mm Wave)and Terahertz(THz)massive Multiple-Input Multiple-Output(MIMO)communication systems.Leveraging the... Delay Alignment Modulation(DAM)is an innovative broadband modulation technique well-suited for millimeter Wave(mm Wave)and Terahertz(THz)massive Multiple-Input Multiple-Output(MIMO)communication systems.Leveraging the high spatial resolution and sparsity of multi-path channels,DAM effectively mitigates Inter-Symbol Interference(ISI)by aligning all multi-path components through a combination of delay pre-compensation(or post-compensation)and path-based beamforming.As such,ISI is eliminated while preserving multi-path power gains.In this paper,we investigate multi-user double-side DAM,which incorporates both delay pre-compensation at the transmitter and post-compensation at the receiver,in contrast to prior works that primarily focus on singleside DAM with only delay pre-compensation.Firstly,we derive the constraint on the number of introduced delays and formulate the corresponding delay pre/post-compensation vectors tailored for multi-user double-side DAM,given a specific number of delay compensations.Furthermore,we demonstrate that when the number of Base Stations(BSs)/User Equipment(UE)antennas is sufficiently large,single-side DAM—where delay compensation is performed only at the BS/UE—is preferable to double-side DAM,since the former results in less ISI to be spatially eliminated.Next,we propose two low-complexity path-based beamforming strategies based on the eigen-beamforming transmission and ISI-Zero Forcing(ZF),respectively.On this basis,we further analyze the achievable sum rates.Simulation results verify that with a sufficiently large number of BS/UE antennas,singleside DAM is adequate for ISI elimination.Moreover,compared to the benchmarking scheme of Orthogonal Frequency Division Multiplexing(OFDM),multi-user BS-side DAM achieves higher spectral efficiency and lower Peak-to-Average Power Ratio(PAPR). 展开更多
关键词 delay alignment modulation delay pre-compensation delay post-compensation Path-based beamforming Fractional channel delay
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Neural network control for mitigating actuator delay in ATR engines using predictive compensation and stability reward
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作者 Weidong CAI Wei ZHAO +3 位作者 Xiaorong XIANG Sanqun REN Xuesen YANG Qingjun ZHAO 《Chinese Journal of Aeronautics》 2026年第2期301-327,共27页
The flight envelope of Air Turbo Rocket(ATR)engines is broader compared to conventional aero-engines,and designing a full-envelope controller using traditional methods poses significant challenges due to a burdensome ... The flight envelope of Air Turbo Rocket(ATR)engines is broader compared to conventional aero-engines,and designing a full-envelope controller using traditional methods poses significant challenges due to a burdensome design process.To address this issue,this paper proposes a self-learning neural network controller design method based on Reinforcement Learning(RL).Additionally,a method for predictive compensation and stability rewards is proposed to reduce the system oscillation caused by actuator delay.This approach simplifies the actuator to a firstorder inertial element exhibiting pure delay.A simulation environment for the ATR engineactuator system is first established.Based on this environment,a self-learning neural network controller using a predictive compensator and the Proximal Policy Optimization(PPO)algorithm is then developed.Furthermore,the temporal difference signals from the controller output are integrated into the reward function to enhance system stability.The proposed method is validated through numerical simulations and semi-physical experiments.The numerical simulation results demonstrate that the proposed method increases the system's tolerance to delays from 20 ms to 400 ms.Under an actuator delay of 400 ms,the average steady-state error remains less than0.1%,the overshoot is limited to 1%,and the settling time does not exceed 3 s.Moreover,compared to the traditional method,the proposed method exhibits higher adaptability to model errors and variations in flight conditions.In the conducted semi-physical simulation experiments,the proposed method achieves stable control of a real electric pump. 展开更多
关键词 Actuator delay ATR engines Neural network control Reinforcement learning Semi-physical simulation
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In situ Generation of Carbazole-triazine Thermally Activated Delayed Fluoresscence Emitters within the Conjugated Polymer Chain
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作者 Alexander M.Mitroshin Serguei A.Miltsov +9 位作者 Ilya E.Kolesnikov Dmitriy A.Lypenko Artem V.Dmitriev Larisa S.Litvinova Vladislav M.Korshunov Ilya V.Taydakov Elena V.Ushakova Anastasia V.Rogova Felix N.Tomilin Alexander V.Yakimansky 《Chinese Journal of Polymer Science》 2026年第2期361-370,I0009,共11页
The development of polymeric materials that exhibit blue thermally activated delayed fluorescence(TADF)is of great interest for optoelectronic applications.However,achieving TADF in polymers often requires an elaborat... The development of polymeric materials that exhibit blue thermally activated delayed fluorescence(TADF)is of great interest for optoelectronic applications.However,achieving TADF in polymers often requires an elaborate monomer design.The high-energy local triplet state(^(3)LE)of carbazole complicates its application despite the molecular orbital arrangement being suitable for blue emission.Here,we present an approach to polymer design that makes it possible to solve this problem.We demonstrate the in situ formation of a TADF donor-acceptor system during Suzuki polycondensation,creating an extended carbazole-based donor matrix coupled with a triazine acceptor.The resulting polymer exhibited efficient TADF with a low energy gap(ΔE_(ST))value if a phenyl N-substituent,enabling essential electron delocalization,was present in the carbazole moiety.This work establishes a versatile platform for developing carbazole-based TADF polymers,overcoming the fundamental limitations that hinder their widespread application. 展开更多
关键词 Thermally activated delayed fluorescence(TADF) POLYCARBAZOLE Suzuki polycondensation Photoluminescence
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Machine learning approaches to early detection of delayed wound healing following gastric cancer surgery
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作者 Duygu Kirkik Huseyin Murat Ozadenc Sevgi Kalkanli Tas 《World Journal of Gastrointestinal Oncology》 2026年第1期287-290,共4页
Delayed wound healing following radical gastrectomy remains an important yet underappreciated complication that prolongs hospitalization,increases costs,and undermines patient recovery.In An et al’s recent study,the ... Delayed wound healing following radical gastrectomy remains an important yet underappreciated complication that prolongs hospitalization,increases costs,and undermines patient recovery.In An et al’s recent study,the authors present a machine learning-based risk prediction approach using routinely available clinical and laboratory parameters.Among the evaluated algorithms,a decision tree model demonstrated excellent discrimination,achieving an area under the curve of 0.951 in the validation set and notably identifying all true cases of delayed wound healing at the Youden index threshold.The inclusion of variables such as drainage duration,preoperative white blood cell and neutrophil counts,alongside age and sex,highlights the pragmatic appeal of the model for early postoperative monitoring.Nevertheless,several aspects warrant critical reflection,including the reliance on a postoperative variable(drainage duration),internal validation only,and certain reporting inconsistencies.This letter underscores both the promise and the limitations of adopting interpretable machine learning models in perioperative care.We advocate for transparent reporting,external validation,and careful consideration of clinically actionable timepoints before integration into practice.Ultimately,this work represents a valuable step toward precision risk stratification in gastric cancer surgery,and sets the stage for multicenter,prospective evaluations. 展开更多
关键词 Gastric cancer Radical gastrectomy delayed wound healing Machine learning Decision tree Risk prediction
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Theoretical study on the thermally activated delayed fluorescence,and efficiency roll‑off characteristics of a series of blue and blue‑green Ir(Ⅲ)complexes
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作者 QIN Zhengkun BAO Lixin +4 位作者 ZHANG Yunkai CUI Lin WANG Jinyu WANG Yuhao SONG Mingxing 《无机化学学报》 北大核心 2026年第2期365-374,共10页
A series of blue and blue‑green Ir(Ⅲ)complexes has been investigated theoretically to explore their electronic structures,photophysical properties,efficiency roll‑off effect,and thermal activation delayed fluorescenc... A series of blue and blue‑green Ir(Ⅲ)complexes has been investigated theoretically to explore their electronic structures,photophysical properties,efficiency roll‑off effect,and thermal activation delayed fluorescence(TADF)properties.All calculations were performed using density functional theory(DFT)and time‑dependent density functional theory(TDDFT).Calculations for electronic structures,frontier molecular orbital characteristics(which determine the efficiency roll‑off effect of the complexes),and photophysical properties were conducted using the Gaussian 09 software package.The calculation of spin‑orbit coupling matrix elements<T|HSOC|S>,which determine the TADF properties of the complexes,was performed using the ORCA software package.The calculation results show that the auxiliary ligand tetraphenylimidodiphosphinate(tpip),a strong electron‑withdrawing group,can mitigate the efficiency roll‑off effect of the complex.Furthermore,TADF is observed in one of the designed complexes,(F_(3)Phppy)_(2)Ir(tpip),where F_(3)Phppy=2‑[4‑(2,4,6‑trifluorophenyl)phenyl]pyridine. 展开更多
关键词 organic light‑emitting diodes Ir(Ⅲ)complex time‑dependent density functional theory thermal activation delayed fluorescence property efficiency roll‑off effect
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Empirical tropospheric zenith wet delay models with strong generalization capability based on a robust machine learning fusion algorithm
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作者 Jiahao Zhang Qin Liang Yunqing Huang 《Geodesy and Geodynamics》 2026年第2期211-224,共14页
Tropospheric zenith wet delay(ZWD)plays a vital role in the analysis of space geodetic observations.In recent years,machine learning methods have been increasingly applied to improve the accuracy of ZWD calculations.H... Tropospheric zenith wet delay(ZWD)plays a vital role in the analysis of space geodetic observations.In recent years,machine learning methods have been increasingly applied to improve the accuracy of ZWD calculations.However,a single machine learning model has limited generalization capabilities.To address these limitations,this study introduces a novel machine learning fusion(MLF)algorithm with stronger generalization capabilities to enhance ZWD modeling and prediction accuracy.The MLF algorithm utilizes a two-layer structure integrating extra trees(ET),backpropagation neural network(BPNN),and linear regression models.By comparing the root mean square error(RMSE)of these models,we found that both ET-based and MLF-based models outperform RF-based and BPNN-based models in terms of internal and external accuracy,across both surface meteorological data-based and blind models.The improvement in exte rnal accuracy is particularly significant in the blind models.Our re sults show that the MLF(with an RMSE of 3.93 cm)and ET(3.99 cm)models outperform the traditional GPT3model(4.07 cm),while the RF(4.21 cm)and BPNN(4.14 cm)have worse external accuracies than the GPT3 model.It is worth noting that the BPNN suffered from overfitting during external accuracy tests,which was avoided by the MLF.In summary,regardless of the availability of surface meteorological data,the MLF-based empirical models demonstrate superior internal and external accuracy compared to the other tested models in this study. 展开更多
关键词 Tropospheric zenith wet delay Machine learning Extra trees Machine learning fusion algorithm Empirical models
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Elastomer Doping Strategy for High-efficiency Stretchable Thermally Activated Delayed Fluorescence Polymer Organic Light-emitting Diodes
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作者 Zhao Yang Wen-Kang Shi +9 位作者 Zhi-Hao Shao Zi-Han Xiong Yi-Fan Li Ming-Liang Zhu Wei Wen Cheng Li Long-Bin Ren Zhi-Yuan Zhao Yun-Long Guo Yun-Qi Liu 《Chinese Journal of Polymer Science》 2026年第4期970-979,I0010,共11页
The increasing demand for flexible displays and wearable electronics has driven extensive efforts to develop stretchable organic lightemitting diodes(OLEDs).A critical challenge in this field is the creation of emissi... The increasing demand for flexible displays and wearable electronics has driven extensive efforts to develop stretchable organic lightemitting diodes(OLEDs).A critical challenge in this field is the creation of emissive layers that combine high efficiency with mechanical robustness.Thermally activated delayed fluorescence(TADF)materials have attracted significant attention as third-generation emitters capable of achieving 100%internal quantum efficiency;however,their application in stretchable OLEDs has been limited.In this study,we propose an elastomer doping strategy.Polyurethane(PU)is incorporated into TADF polymers to improve their mechanical flexibility while maintaining a high luminescent efficiency.The resulting composite films exhibited excellent TADF characteristics and remarkable stretchability(75%).OLEDs fabricated from these materials achieved a maximum external quantum efficiency(EQE)of 14.26%and a peak luminance of 73570 cd·m^(-2),with the PUdoped devices showing a significantly suppressed efficiency roll-off.Additionally,a fully stretchable OLED architecture was designed and operated under tensile strain to maintain stable electroluminescent performance.These results demonstrate that elastomer doping is an effective strategy for balancing the mechanical compliance with optoelectronic performance,offering a promising pathway for the development of high-performance stretchable OLEDs for flexible electronics. 展开更多
关键词 Thermally activated delayed fluorescence(TADF) Elastomer doping Stretchable OLEDs Polyurethane(PU) Flexible electronics
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Mechanism of action of synaptic mitochondrial damage in delayed cognitive recovery
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作者 Huihui Miao Qiang Liu +7 位作者 Yan-Ping Liu Bin-Bin Yan Xin-Hao Jiao Hai-Bi Wang Cheng-Hua Zhou Tianzuo Li Zhongcong Xie Yuqing Wu 《Neural Regeneration Research》 2026年第6期2457-2466,共10页
Delayed neurocognitive recovery following anesthesia and surgery is a common complication in older adult patients.Synapses are fundamental to cognitive function.The activity of synapses heavily depends on the energy s... Delayed neurocognitive recovery following anesthesia and surgery is a common complication in older adult patients.Synapses are fundamental to cognitive function.The activity of synapses heavily depends on the energy supplied by synaptic mitochondria,which are significantly influenced by oxidative stress.Sirtuin 3 is a histone deacetylase located in the mitochondrial matrix that plays a pivotal role in regulating mitochondrial function.However,it remains unclear whether and how sirtuin 3 is involved in the development of delayed cognitive recovery.Therefore,in this study,we investigated the potential role of sirtuin 3 in synapses during delayed neurocognitive recovery.Our results showed that anesthesia and surgery induced cognitive impairment in mice and reduced sirtuin 3 protein expression.Overexpression of sirtuin 3 inhibited opening of the mitochondrial permeability transition pore by reducing acetylation of K166 on cyclophilin D and also rescued cognitive impairment.Aged mice carrying the cyclophilin D-K166R mutation exhibited significantly reduced cognitive impairment.Similarly,administering the mitochondrial permeability transition pore blocker,cyclosporine A,effectively alleviated the decline in synaptic mitochondrial function and cognitive impairment caused by anesthesia and surgery in aged mice.These results indicate that the sirtuin 3/cyclophilin D-K166/mPTP signaling pathway in hippocampal synaptic mitochondria is involved in delayed neurocognitive recovery of aged mice,suggesting this pathway could serve as a potential target for treatment. 展开更多
关键词 acetylase aged mice cyclophilin D delayed neurocognitive recovery hippocampus long-term potentiation mitochondrial permeability transition pore sirtuin 3 synaptic mitochondria SYNAPTOSOME
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A Cost-Effective Approach to Precisely Estimate Singlet-Triplet Energy Gaps in MR-TADF Molecules:Combining Delta Self-Consistent Field and Time-Dependent Density Functional Theory Methods
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作者 Qian Jina Dong Wang 《Chinese Journal of Chemical Physics》 2026年第1期41-50,I0021-I0032,I0042,共23页
As a novel class of purely organic fluores-cent materials,multiple resonance thermal-ly activated delayed fluorescence(MR-TADF)compounds hold significant promise for next-generation display technologies.The efficiency... As a novel class of purely organic fluores-cent materials,multiple resonance thermal-ly activated delayed fluorescence(MR-TADF)compounds hold significant promise for next-generation display technologies.The efficiency of exciton utilization and the overall performance of organic light-emit-ting devices are closely linked to the singlet-triplet energy gap(ΔE_(ST))of MR-TADF emitters.Identifying an economic and accu-rate theoretical approach to predictΔE_(ST)would be beneficial for high-throughput screening and facilitate the inverse design of MR-TADF molecules.In this study,we evaluated the S_(1)state energy(E(S_(1))),T_(1)state ener-gy(E(T_(1))),andΔE_(ST)using three different physical interpretations:adiabatic excitation ener-gy,vertical absorption energy,and vertical emission energy.We employed the time-depen-dent density functional theory(TDDFT)and delta self-consistent field(ΔSCF)methods to calculate E(S_(1)),E(T_(1)),andΔE_(ST)for 20 MR-TADF molecules reported in the literature.We compared these calculated values with experimental data obtained from fluorescence spec-troscopy at room-temperature(or 77 K)and phosphorescence spectroscopy conducted at 77 K.Our findings indicate that the vertical absorption energy at the S0 state minimum,deter-mined by theΔSCF method,accurately predicts the S_(1)state energy.Similarly,the vertical absorption energy at the S0 state minimum,calculated using the TDDFT method,effectively predicts the T_(1)state energy.TheΔE_(ST)derived from the difference between these two excita-tion energies exhibited the smallest mean absolute error of only 0.039 eV compared to the ex-perimental values.This combination represents the most accurate and cost-effective method reported to date for predicting theΔE_(ST)of MR-TADF molecules,and can be integrated into AI-driven inverse design workflows for new emitters. 展开更多
关键词 Organic light-emitting diode Multiple resonance thermally activated delayed fluorescence emitter Single-triplet energy gap Delta self-consistent field method time-de-pendent density functional theory method
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New criterion for delay-dependent absolute stability of Lurie system with interval time-varying delay 被引量:1
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作者 薛明香 费树岷 +1 位作者 李涛 潘俊涛 《Journal of Southeast University(English Edition)》 EI CAS 2011年第4期375-378,共4页
The delay-dependent absolute stability for a class of Lurie systems with interval time-varying delay is studied. By employing an augmented Lyapunov functional and combining a free-weighting matrix approach and the rec... The delay-dependent absolute stability for a class of Lurie systems with interval time-varying delay is studied. By employing an augmented Lyapunov functional and combining a free-weighting matrix approach and the reciprocal convex technique, an improved stability condition is derived in terms of linear matrix inequalities (LMIs). By retaining some useful terms that are usually ignored in the derivative of the Lyapunov function, the proposed sufficient condition depends not only on the lower and upper bounds of both the delay and its derivative, but it also depends on their differences, which has wider application fields than those of present results. Moreover, a new type of equality expression is developed to handle the sector bounds of the nonlinear function, which achieves fewer LMIs in the derived condition, compared with those based on the convex representation. Therefore, the proposed method is less conservative than the existing ones. Simulation examples are given to demonstrate the validity of the approach. 展开更多
关键词 Lurie system reciprocal convex technique absolute stability interval time-varying delay linear matrix inequality (LMI)
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Improved delay-dependent stability criteria for stochastic systems with time-varying interval delay
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作者 于建江 张侃健 费树岷 《Journal of Southeast University(English Edition)》 EI CAS 2009年第2期213-218,共6页
The problem of the stability for a class of stochastic systems with time-varying interval delay and the norm-bounded uncertainty is investigated. Utilizing the information of both the lower and the upper bounds of the... The problem of the stability for a class of stochastic systems with time-varying interval delay and the norm-bounded uncertainty is investigated. Utilizing the information of both the lower and the upper bounds of the interval time-varying delay, a novel Lyapunov-Krasovskii functional is constructed. The delay-dependent sufficient criteria are derived in terms of linear matrix inequalities (LMIs), which can be easily checked by the LMI in the Matlab toolbox. Based on the Jensen integral inequality, neither model transformations nor bounding techniques for cross terms is employed, so the derived criteria are less conservative than the existing results. Meanwhile, the computational complexity of the obtained stability conditions is reduced because no redundant matrix is introduced. A numerical example is given to show the effectiveness and the benefits of the proposed method. 展开更多
关键词 delay-dependent stability stochastic system interval delay linear matrix inequalities(LMIs)
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Time-stamped predictive functional control for networked control systems with random delays
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作者 张奇智 张卫东 《Journal of Southeast University(English Edition)》 EI CAS 2005年第2期149-152,共4页
The random delays in a networked control system (NCS) degrade control performance and can even destabilize the control system.To deal with this problem,the time-stamped predictive functional control (PFC) algorithm is... The random delays in a networked control system (NCS) degrade control performance and can even destabilize the control system.To deal with this problem,the time-stamped predictive functional control (PFC) algorithm is proposed,which generalizes the standard PFC algorithm to networked control systems with random delays.The algorithm uses the time-stamp method to estimate the control delay,predicts the future outputs based on a discrete time delay state space model,and drives the control law that applies to an NCS from the idea of a PFC algorithm.A networked control system was constructed based on TrueTime simulator,with which the time-stamped PFC algorithm was compared with the standard PFC algorithm.The response curves show that the proposed algorithm has better control performance. 展开更多
关键词 networked control systems random delays predictive functional control industrial Ethernet
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A new reduction-based LQ control for dynamic systems with a slowly time-varying delay 被引量:5
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作者 Masakazu Haraguchi 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2009年第4期529-537,共9页
Time delays in the feedback control often dete- riorate the control performance or even cause the instability of a dynamic system. This paper presents a control strategy for the dynamic system with a constant or a slo... Time delays in the feedback control often dete- riorate the control performance or even cause the instability of a dynamic system. This paper presents a control strategy for the dynamic system with a constant or a slowly time-varying input delay based on a transformation, which sire-plifies the time-delay system the relation is discussed for into a delay-free one. Firstly, two existing reduction-based linear quadratic controls. One is continuous and the other is discrete. By extending the relation, a new reduction-based control is then developed with a numerical algorithm presented for practical control implementation. The controller suggested by the proposed method has such a promising property that it can be used for the cases of different values of an input time delay without redesign of controller. This property provides the potential for stabilizing the dynamic system with a time-varying input delay. Consequently, the application of the proposed method to the dynamic system with a slowly time-varying delay is discussed. Finally, numerical simulations are given to show the efficacy and the applicability of the method. 展开更多
关键词 Time delay time-varying delay State transformation System reduction Linear quadratic control
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